CN101954269A - A health-care activating water purifier - Google Patents
A health-care activating water purifier Download PDFInfo
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- CN101954269A CN101954269A CN2009101616185A CN200910161618A CN101954269A CN 101954269 A CN101954269 A CN 101954269A CN 2009101616185 A CN2009101616185 A CN 2009101616185A CN 200910161618 A CN200910161618 A CN 200910161618A CN 101954269 A CN101954269 A CN 101954269A
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Abstract
The invention discloses a health-care activated water purifying agent which is prepared from the following raw materials in parts by weight: 30-50 parts of kaolin, 18-32 parts of medical stone, 16-30 parts of tourmaline and 25-40 parts of bentonite. The invention provides a health-care activated water purifying agent which can promote health and activate water quality, and more importantly, has high purification efficiency, small using amount, low cost and quick adsorption and adhesion of impurities.
Description
Technical field
The invention belongs to water-treatment technology field, relate to a kind of health care activation water purification agent.
Background technology
Along with industrial develop rapidly, water resource pollution is serious day by day, river in the natural environment, river, streams etc., the contaminated wastewater of discharging in constantly being produced by sanitary sewage, all types of industries, materials such as the organic matter in the water, heavy metal are more and more, the degeneration of the contaminated formation water of water quality and aging, a lot of diseases of human body and animals and plants are directly with water quality degeneration and aging relevant.In addition, in rainy season, water turbidity is very high.These water can not need to handle by physical sedimentation, chemical coacervation directly as drinking water, and coacervation chemical reagent commonly used adopts aluminum sulfate (abbreviation alum) and aluminium polychloride (being called for short PAC) more.
Aluminum sulfate is a kind of chemical reagent that people are used as water treatment the earliest, it mainly is flocculation sediment effect by aluminum sulfate, earth, impurity, organic matter and heavy metal in the water are got off by flocculation sediment, filtration, purification then, its production procedure is simple, cost is minimum, but exists defectives such as consumption is big, weak effect.The fast reaction of aluminium polychloride (PAC) energy, flocculation, precipitation, its amount ratio aluminum sulfate is few, can remove earth in the water, impurity, organic matter and heavy metal, clean-up effect surpasses aluminum sulfate, and can be used for city domestic sewage and bleaching and dyeing, paper industry institute sewage effluent handles, and can remove COD in the water, BOD and SS.But also there is significant disadvantages in aluminium polychloride (PAC): meet acid rain in spring, the pH value slant acidity of water, or when water turbidity is higher than 100NTU, the effect of earth, impurity, organic matter, heavy metal is very undesirable in its flocculation, the removal water, therefore to strengthen the injected volume of aluminium polychloride, but the injected volume increase causes cost to increase, and the metallic aluminium ion that remains in the water also increases greatly.
Summary of the invention
The technical problem to be solved in the present invention is, at defective on the prior art, provide a kind of can the bonding impurity of strong adsorption and heavy metal, fast coacervation precipitation, efficient height, cost is low, use amount is few, and can carry out activation processing to water quality, increase the health care activation water purification agent of beneficial mineral element.
The technical solution adopted for the present invention to solve the technical problems is: a kind of health care activation water purification agent, make by the raw material of following parts by weight: kaolin 30～50, medical stone 18～32, tourmaline 16～30, bentonite 25～40.
Described health care activation water purification agent is preferably made by the raw material of following parts by weight: kaolin 35～40, medical stone 20～30, tourmaline 20～28, bentonite 30～40.
Described health care activation water purification agent, be with feed kaolin, medical stone, tourmaline and bentonite through pre-treatment step remove heavy metal and impurity, calcining step, the powder process step is made.
Described pre-treatment step specifically is that feed kaolin, medical stone, tourmaline and bentonite are carried out pickling, alkali cleaning, washing, dry for standby then respectively successively.
The acid that described pickling is selected for use is hydrochloric acid or phosphoric acid.
The alkali that described alkali cleaning is selected for use is NaOH.
In the described calcining step, calcining heat is 900～1100 ℃, and calcination time is 10～15 hours.
Described powder process step is that raw material is ground to form 200～1200 purpose fine powders respectively, carries out ball milling after the mixing again and makes health care activation water purification agent, and the ball milling time is 3～6 hours.
Health care activation water purification agent fineness behind the described ball milling is 200～1200 orders.
It is that raw material is made that the present invention adopts kaolin, medical stone, tourmaline and bentonite, health care activation water purification agent contains the hole compound, surface area with strong adsorption capacity, precipitation can reach (200～1000) meters squared per gram, speed fast, easily disperse, injected volume is few, strong, especially more obvious for the adaptation of handling water to ultra's treatment effect.Content of beary metal such as the colourity of purification back water and the plumbous cadmium of ferrimanganic are low, to the equipment non-corrosiveness.
Health care activation water purification agent of the present invention is except absorption impurity and heavy metal, also water quality there is the activation function of health care, mainly have following some: 1, reduce water clusters: can associate mutually between the hydrone, form macromolecular mass, the present invention's activation water purification agent that keeps healthy can radiate " far ir ray " (infrared rays that wavelength is 4～14 microns) and " low all electromagnetic waves " (that is: electromagnetic wave of work periodicity alternation in a kind of electric oscillation of low frequency), " far ir ray " (infrared rays that wavelength is 4～14 microns) and " low all electromagnetic waves " can both play and reduce the effect of associating between the hydrone, the water of original macromolecular mass is become the water of subset, small-micelle water is made up of 5-8 hydrone, has strong penetration, strong dissolving power, strong extension, alkalescent.Micromolecular water can improve the oxygen content (dissolved oxygen is greater than 6mg/l) in the water, brings more oxygen for the histocyte in the human body.After small-micelle water enters human body, can be penetrated into immediately in human body ten million hundred million cells, nutrition is brought into cell at faster speed, and metabolic waste in the cell and toxin are taken out of the extracellular quickly, the circulation of capillary is accelerated, enhance metabolism, present characteristics such as resistance enhancing.2, adjust water quality.The present invention's activation that keeps healthy contains in the water purification agent multiplely to the health beneficial trace elements, and health care activation water purification agent adds in the entry the indispensable micro element mineral of the human body of stripping.And the activation water purification agent can be releasing far infrared because the present invention keeps healthy, activated water molecule and bacteria growing inhibiting effectively, and break the reactive bond of noxious material structure, bring into play stronger oxicracking function.Decompose carcinogenicity organic molecule in the contaminated water, anti-sealing corruption, thus obtain activating high-quality water.
Raw material of the present invention is by calcining, increased the hole of raw material, strengthened molecular energy and its suction-operated of each mineral element, can better impurity in the water and heavy metal be adsorbed onto on the health care activation water purification agent, coprecipitation reaches the effect that strengthens purification efficiency.
In the raw material of the present invention, kaolin is mainly by less than kaolinite bunch mineral compositions such as 2 microns small sheet, tubulose, lamination shapes, and its essential mineral composition is kaolinite and halloysite, contains a large amount of AL in the kaolin
2O
3, SiO
2With a spot of Fe
2O
3, TiO
2Deng.The easy dispersion suspension of kaolin has high caking property in water, can be with the absorption of the bonding of the impurity in the water; And silicon oxide sio
2, aluminium oxide AL
2O
3Has very strong absorption affinity, as early as possible flocculation sediment such as impurity in the adsorbed water.
Medical stone is the mineral health cares remedies of biologically active, has following health care: 1, contain kind surplus potassium, sodium, calcium, magnesium, phosphorus, titanium, manganese, barium, cobalt, copper, zinc, lithium, strontium, molybdenum, niobium, germanium, tin, selenium, silicon and rare-earth elements of lanthanum, cerium, neodymium, the samarium etc. 30 in the fossil water of medical stone.Wherein selenium, zinc, manganese content are abundanter, and the indispensable micro element mineral of the human body of stripping can improve water quality in the fossil water of medical stone.Under usual conditions, four kinds of trace elements (metasilicic acid, Sr, Zn, F) content reaches or approaching national beverage mineral water standard in the medical stone dissolution fluid, is a kind of natural nutrition source therefore.2, medical stone can be releasing far infrared, far-infrared radiation rate＞0.88～0.92 under the normal temperature, and bacteriostasis rate under the normal temperature (Escherichia coli, staphylococcus aureus)＞90% can discharge micro-electric wave simultaneously, and micro-electric wave can change molecular structure water.Therefore, bacteria growing inhibiting is effectively broken the reactive bond of noxious material structure, brings into play stronger oxicracking function.Decompose carcinogenicity organic molecule in the contaminated water, anti-sealing corruption, thus obtain high-quality water.3, adjust water quality.With mineral matters such as iron, magnesium, fluorine and opinion, its then stripping when not existing in the water; On the contrary, it then adsorbs when existing in the water when too much.After in water, dropping into medical stone, the pH value of acid water is improved and approaching neutrality.Modern science analytical proof, medical stone are rich in multiple element, and biologically active can improve the physiological function of body, plays the effect of bidirectional modulation acid-base value.
Three. tourmaline has another name called Tourmaline (Tourmaline), is because its charged and appellation tourmaline.Tourmaline has following characteristics: 1, produce anion: have the effect of the human body of adjusting ionic equilibrium, body and mind is loosened, activating cell improves effects such as nature cure rate, and can suppress the oxidation of health or aging, modern environment has many essential factors of impelling cation to generate, health is often in tension, and therefore, anion is the indispensable material of modern, in addition, anion also has the effect of deodorizing.2, brine electrolysis: behind the water electrolysis, can obtain the stabilization of active function, the chlorine at interface, the passivation of iron (prevent red iron rust to generate and red water takes place), water reducing, remove silica and binding various effects such as (microorganism aggregates).3, reduce water clusters: can associate mutually between the hydrone, form micel.The less water of micel can be removed chlorine or impurity, and taste is good, and can improve the penetration of health.4, emitting far infrared ray (infrared rays that wavelength is 4～14 microns), far infrared can be penetrated into health deep layer position, and warm cell stimulates circulation, and makes metabolism smooth and easy.Tourmaline far infrared emissivity nearly 100%, numerical value is than other mineral height.5, contain effective trace mineral.
Four. bentonite be a kind of be the clay rock of main component with the montmorillonite, cover that to take off rock be moisture aluminum laminate silicate.Bentonite has plasticity, thixotropy, rheological characteristic, absorption caking property, cation exchange etc., and the bentonite hygroscopicity is strong, and maximum water absorption is 15 times of its volumes, expands after the moisture absorption.Good dispersion in water can be colloidal suspensions.This suspension has certain thixotropy, rheological characteristic.Stronger ion-exchange capacity is arranged, absorption caking property etc., materials such as earth impurity, heavy metal in the adsorbed water fall clean-up effect thereby reach the wadding coagulation fast.
The specific embodiment
Below enumerate 8 embodiment and specify the present invention, the health care activation water purification agent of embodiment 1～8 is to be made by the raw material of following parts by weight:
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 | Embodiment 6 | Embodiment 7 | Embodiment 8 | |
| Kaolin | 45 | 50 | 40 | 30 | 36 | 38 | 40 | 35 |
| Medical stone | 32 | 28 | 20 | 23 | 18 | 25 | 29 | 30 |
| Tourmaline | 16 | 22 | 18 | 28 | 20 | 30 | 19 | 23 |
| Bentonite | 25 | 30 | 35 | 38 | 35 | 28 | 36 | 40 |
The preparation method of health care activation water purification agent:
1, at first feed kaolin, medical stone, tourmaline, the bentonite of weight deal in the above table carried out preliminary treatment.Raw material is carried out pickling, alkali cleaning, washing respectively successively, remove heavy metal and impurity.Wherein, the acid that pickling is selected for use is the watery hydrochloric acid of mass percent concentration 20～40% or the phosphoric acid solution of mass percent concentration 70～90%, carry out alkali cleaning after the pickling, the alkali that alkali cleaning is selected for use is the sodium hydroxide solution of mass percent concentration 30～70%, wash after the alkali cleaning, be used to remove remaining alkali lye on the raw material, oven dry is standby then.
2, the raw material of drying is calcined respectively, calcining heat is at 900～1100 ℃, and the time is 10～15 hours.The general calcining heat that adopts is 1000 ℃, can also be 900 ℃, 950 ℃, 1050 ℃, 1100 ℃ etc., and calcination time is for being generally 12 hours, can also be 10,11,13,14,15 hours etc.
3, grind.With the grinder grinding after crushed of calcining raw materials kaolin, medical stone, tourmaline, bentonite, the fineness after the grinding will reach 200～1200 orders respectively, and fineness is high more, its total surface area increases, the adsorption cleaning effect is good more, generally gets final product at 250 orders, then each raw material is mixed.
3, raw material carries out ball milling after mixing.Ball milling is that the raw material after grinding is put into ball mill, a certain amount of high aluminium ball is housed in the ball mill, electricity consumption drives the ball mill rolling then, utilizing high aluminium ball that putting into raw material are collided friction makes it evenly mixed, the ball milling time is 3～6 hours, and the ball milling time, the fineness of long products was high more more, and the preferred time of ball milling is 5～6 hours, under the general fineness requirement, ball milling got final product in 3,4 hours.
4, become 250～1200 order powder behind the ball milling, again packing.
Product effect experiment embodiment:
This detection is undertaken by Hong Kong standard and calibrating center Co., Ltd, detects and is numbered HC185132.One, aluminum sulfate, aluminium polychloride and described invention health care activate water purification agent under the same conditions, the treatment effect of test water turbidity.
Sample: river.
Test condition: stirred 20 minutes with the magnetite agitator, placed then 10 minutes, get the top clarified solution.
1, the aluminum sulfate addition is 60-70g/T (being that water per ton adds 60-70g)
| Add deal | Turbidity before handling | Handle the back turbidity | Reduce % | Add deal | Turbidity before handling | Handle the back turbidity | Reduce % |
| 0.06g/L | 101NTU | 62NTU | 38.60％ | 0.07g/L | 312NTU | 159NTU | 49.00％ |
| 0.06g/L | 215NTU | 147NTU | 31.60％ | 0.07g/L | 408NTU | 253NTU | 38.00％ |
2, aluminium polychloride (PAC) addition is 20-30g/T (being that water per ton adds 20-30g)
| Add component | Turbidity before handling | Handle the back turbidity | Reduce % | Add deal | Turbidity before handling | Handle the back turbidity | Reduce % |
| 0.02g/L | 98.3NTU | 77.5NTU | 21.2％ | 0.03g/L | 320NTU | 204NTU | 36.3％ |
| 0.02g/L | 226NTU | 101NTU | 55.3％ | 0.03g/L | 420NTU | 219NTU | 47.9％ |
3, the present invention's activation water purification agent addition that keeps healthy is 10-15g/T (being that water per ton adds 10-15g)
| Add component | Turbidity before handling | Handle the back turbidity | Reduce % | Add component | Raw water turbidity | Handle the back turbidity | Reduce % |
| 0.01g/L | 98.3NTU | 38.8NTU | 60.5％ | 0.015g/L | 320NTU | 82.8NTU | 74.1％ |
| 0.01g/L | 226NTU | 82.5NTU | 63.5％ | 0.015g/L | 420NTU | 173NTU | 58.8％ |
By above table as can be seen: the present invention has fine clean-up effect.With respect to aluminum sulfate, addition has only 1/6～1/7 of aluminum sulfate addition, but purification efficiency is 1 times～2.5 times of aluminum sulfate.With respect to aluminium polychloride, addition is only in half of aluminium polychloride addition, and to imitate be 1 times～3.5 times of aluminium polychloride but purify.
Two, aluminum sulfate, aluminium polychloride, the present invention keep healthy the activation water purification agent under the same conditions, and heavy metal ion situation in the water is removed in test.
1, the addition of aluminum sulfate is 0.06g/L, and water promptly per ton adds 60g.
| Test event | Before the processing | After the processing | Change % | Test event | Before the processing | After the processing | Change % |
| Aluminium (Al) | 0.79Mg/L | 2.9Mg/L | +267％ | Iron (Fe) | 0.85Mg/L | 0.34Mg/L | -60％ |
| Manganese (Mm) | 0.22Mg/L | 0.17Mg/L | -22.70％ | Plumbous (Pb) | 0.70Mg/l | 0.11Mg/L | -67.10％ |
2, the aluminium polychloride addition is 0.02g/L, and water promptly per ton adds 20g.
| Test event | Before the processing | After the processing | Change % | Test event | Before the processing | After the processing | Change % |
| Aluminium (Al) | 0.79mg/L | 2.0mg/L | +153％ | Iron (Fe) | 0.85mg/L | 0.14mg/L | -83.5％ |
| Arsenic (As) | 0.86mg/L | 0.22mg/L | -74.4％ | Mercury (Hg) | 0.90mg/L | 0.81mg/L | -3.33％ |
| Cadmium (Cd) | 0.87mg/L | 0.84mg/L | -3.45％ | Manganese (Mn) | 0.90mg/L | 0.70mg/L | -22.2％ |
| Chromium (Cr) | 0.81mg/L | 0.1mg/L | -87.7％ | Plumbous (Pb) | 0.70mg/L | 0.11mg/L | -67.1％ |
3, the present invention's activation water purification agent addition that keeps healthy is 0.02g/L, and water promptly per ton adds 20g
| Test event | Before the processing | After the processing | % changes | Test event | Before the processing | After the processing | % changes |
| Aluminium (Al) | 0.79mg/L | 0.71mg/L | -10.1％ | Iron (Fe) | 0.85mg/L | 0.08mg/L | -90.1％ |
| Arsenic (As) | 0.86mg/L | 0.16mg/L | -81.4％ | Mercury (Hg) | 0.90mg/L | 0.88mg/L | -2.22％ |
| Cadmium (Cd) | 0.87mg/L | 0.82mg/L | -5.75％ | Manganese (Mn) | 0.90mg/L | 0.69mg/L | -23.3％ |
| Chromium (Cr) | 0.81mg/L | 0.08mg/L | -90.1％ | Plumbous (Pb) | 0.70mg/L | 0.11mg/L | -84.3％ |
From above table as can be seen, the present invention keeps healthy and activates the water purification agent addition is 1/3 of aluminum sulfate, equate with the aluminium polychloride addition, the removal effect of heavy metal all is better than aluminum sulfate and aluminium polychloride basically, especially very high to health harm bigger heavy metal Hg, lead, arsenic, chromium clearance, and the present invention does not use the aluminium agent, does not only increase aluminum ions content in the water, has also reduced aluminum ions content.
Three, water quality detection experiment: this experiment is undertaken by the general notary in Hong Kong Co., Ltd (SGS HONG KONG Ltd.).
Choose river and handle through the present invention's activation water purification agent that keeps healthy, testing result is as follows:
| Project (parameter) | Detection method | Before the experiment | After the experiment |
| Silicon (mg/l) | APHA20 thed.4500-Si:F | ?＜0.01 | ?0.04 |
| Calcium (mg/l) | APHA20 thed.3500-Ca | ?＜0.05 | ?3 |
| Potassium (mg/l) | APHA20 thed.3500-K | ?＜0.05 | ?0.06 |
| Copper (mg/l) | USEPA?6020 | ?＜0.001 | ?0.006 |
| Manganese (mg/l) | USEPA?6020 | ?＜0.001 | ?＜0.001 |
| Zinc (mg/l) | USEPA?6020 | ?＜0.01 | ?0.026 |
| Lithium (mg/l) | USEPA?6020 | ?＜0.001 | ?0.002 |
| PH(21℃) | APHA21 sted.4500H +B | ?5.7 | ?6.0 |
As can be seen from the above table, after the present invention keeps healthy the processing of activation water purification agent, much health beneficial trace elements content is increased, and the rising of the pH value of water, acid water is transformed to neutral water.
Claims (9)
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102417793A (en) * | 2011-09-01 | 2012-04-18 | 丁一 | Electromagnetic wave preventing nanometer fragrant brightener capable of releasing trace element negative ions |
| CN102417793B (en) * | 2011-09-01 | 2013-04-24 | 丁一 | Electromagnetic wave shielding nanometer fragrant brightener capable of releasing trace element negative ions |
| CN104529420A (en) * | 2015-01-13 | 2015-04-22 | 唐山立雄峰汇材料科技有限公司 | Functional ceramic tea set |
| CN108576824A (en) * | 2018-03-16 | 2018-09-28 | 江力 | A kind of health composition and preparation method thereof for mouth containing |
| CN109234031A (en) * | 2018-09-25 | 2019-01-18 | 安顺市永烁科技有限公司 | A kind of washing cloth grass washing powder |
| CN109730355A (en) * | 2019-01-02 | 2019-05-10 | 深圳市紫莹新材料科技有限公司 | A kind of preparation method of aromatizing particles for cigarette filter rod |
| CN113354391A (en) * | 2021-07-01 | 2021-09-07 | 四川瑞泽科技有限责任公司 | Ecological environment-friendly slow-release brick with water body decontamination effect and preparation method and application thereof |
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