[go: up one dir, main page]

CN101936885B - Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system - Google Patents

Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system Download PDF

Info

Publication number
CN101936885B
CN101936885B CN201010238277XA CN201010238277A CN101936885B CN 101936885 B CN101936885 B CN 101936885B CN 201010238277X A CN201010238277X A CN 201010238277XA CN 201010238277 A CN201010238277 A CN 201010238277A CN 101936885 B CN101936885 B CN 101936885B
Authority
CN
China
Prior art keywords
optical fiber
transmitting
transceiver
fiber
telescope
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
CN201010238277XA
Other languages
Chinese (zh)
Other versions
CN101936885A (en
Inventor
魏永杰
陈文亮
徐可欣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
TIANJIN TONGYANG TECHNOLOGY DEVELOPMENT CO LTD
Tianjin Sunshine Optics Technology Co Ltd
Hebei University of Technology
Original Assignee
XIANSHI OPTICAL TECHNOLOGY Co Ltd TIANJIN CITY
TIANJIN TONGYANG SCIENCE &TECHNOLOGY DEVELOPMENT Co Ltd
Hebei University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by XIANSHI OPTICAL TECHNOLOGY Co Ltd TIANJIN CITY, TIANJIN TONGYANG SCIENCE &TECHNOLOGY DEVELOPMENT Co Ltd, Hebei University of Technology filed Critical XIANSHI OPTICAL TECHNOLOGY Co Ltd TIANJIN CITY
Priority to CN201010238277XA priority Critical patent/CN101936885B/en
Publication of CN101936885A publication Critical patent/CN101936885A/en
Application granted granted Critical
Publication of CN101936885B publication Critical patent/CN101936885B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Images

Landscapes

  • Investigating Or Analysing Materials By Optical Means (AREA)

Abstract

一种光纤收发一体式空气差分吸收光谱测量系统。解决现有典型DOAS系统光谱利用效率低,且仪器调整和光路对中困难的问题。本发明测量系统包括点光源、望远镜和光谱仪,还包括由发射光纤和接收光纤构成的具有收发光纤公共端的收发一体式结构光纤束。点光源发出的光谱由发射光纤的一端经收发光纤公共端射出,经望远镜内的球面反射镜准直,到达角锥棱镜后被沿原方向反射,再次经球面反射镜聚焦进入收发光纤公共端,最后经接收光纤另一端出射后导入光谱仪进行光谱检测。该系统与典型DOAS系统相比,减少了两块平面反射镜,避免了光束在传输过程中平面镜的遮挡,提高了光谱利用效率,同时简化了仪器调整和对中过程。

Figure 201010238277

An optical fiber transceiver integrated air differential absorption spectrum measurement system. It solves the problems of low spectrum utilization efficiency and difficulties in instrument adjustment and optical path alignment in existing typical DOAS systems. The measurement system of the present invention includes a point light source, a telescope and a spectrometer, and also includes a transceiver-integrated structure optical fiber bundle composed of a transmitting optical fiber and a receiving optical fiber with a common end of the transmitting and receiving optical fiber. The spectrum emitted by the point light source is emitted from one end of the transmitting fiber through the common end of the transmitting and receiving optical fiber, collimated by the spherical reflector in the telescope, and then reflected in the original direction after reaching the corner cube, and then focused by the spherical reflector again into the common end of the transmitting and receiving optical fiber. Finally, after exiting from the other end of the receiving fiber, it is imported into a spectrometer for spectral detection. Compared with the typical DOAS system, this system reduces two flat mirrors, avoids the shielding of the flat mirrors during the beam transmission process, improves the efficiency of spectrum utilization, and simplifies the instrument adjustment and centering process.

Figure 201010238277

Description

光纤收发一体式空气差分吸收光谱测量系统Optical Fiber Transceiver Integrated Air Differential Absorption Spectroscopy Measurement System

【技术领域】:【Technical field】:

本发明涉及一种差分吸收光谱空气质量监测系统,尤其是测量空气中痕量气体的监测系统。The invention relates to a differential absorption spectrum air quality monitoring system, in particular to a monitoring system for measuring trace gas in the air.

【背景技术】:【Background technique】:

大气污染破坏生态系统并对人体健康造成极大危害,因此,首先要对各种大气污染物进行监测。我国许多城市的监测仪器采用点式采样,只能了解监测点采样空间的大气污染情况以及采样时段内的平均状况,时空代表性较差。利用差分吸收光谱学(DOAS)的遥测技术以其大范围、多组份检测、连续实时在线的测量方式正成为环境污染监测的理想工具。采用DOAS技术可以在同一光谱吸收波段同时监测几种污染物,可实现完全非接触在线自动监测;仪器的灵敏度高,监测浓度低;监测范围可达数百米甚至数千米,可反映一个区域的平均污染程度,监测结果比单点监测更具有代表性。DOAS技术是当前空气质量污染指标常规在线监测技术的发展方向。Air pollution destroys the ecosystem and causes great harm to human health. Therefore, it is necessary to monitor various air pollutants first. The monitoring instruments in many cities in my country adopt point sampling, which can only understand the air pollution situation in the sampling space of the monitoring point and the average condition during the sampling period, and the temporal and spatial representation is poor. The telemetry technology using differential absorption spectroscopy (DOAS) is becoming an ideal tool for environmental pollution monitoring due to its large-scale, multi-component detection, and continuous real-time online measurement methods. Using DOAS technology can simultaneously monitor several pollutants in the same spectral absorption band, which can realize complete non-contact online automatic monitoring; the instrument has high sensitivity and low monitoring concentration; the monitoring range can reach hundreds of meters or even thousands of meters, and can reflect an area The average pollution degree, the monitoring results are more representative than single-point monitoring. DOAS technology is the development direction of conventional online monitoring technology for air quality pollution indicators.

目前广泛采用的DOAS系统一般基于Cassegrain望远镜结构。在这种结构中,由氙灯发出的光谱经反射镜准直成平行光出射,经过几百米甚至数千米的光程,由位于另一端的角锥棱镜反射后由接收端将光汇聚耦合进入光纤,由光谱仪探测得到吸收光谱,如图1所示。在图1中,经点光源(氙灯)1发出的连续光谱经与光轴成45°角的平面反射镜2反射后照射在球面反射镜3上,再经球面反射镜3反射后照射在远方的角锥棱镜4上。角锥棱镜4将照射在它上面的光线沿原路反射后依次经球面镜3和平面反射镜5最后汇聚在接收点位置,由光纤接收后送入光谱仪进行分析。Currently widely used DOAS systems are generally based on the Cassegrain telescope structure. In this structure, the spectrum emitted by the xenon lamp is collimated by the reflector into a parallel light output, and after passing through an optical path of hundreds of meters or even thousands of meters, it is reflected by the corner cube prism at the other end and the light is converged and coupled by the receiving end. After entering the optical fiber, the absorption spectrum is detected by a spectrometer, as shown in Figure 1. In Figure 1, the continuous spectrum emitted by the point light source (xenon lamp) 1 is reflected by the plane reflector 2 at an angle of 45° to the optical axis and then irradiates on the spherical reflector 3, and then irradiates in the distance after being reflected by the spherical reflector 3 on the corner cube prism 4. The corner cube prism 4 reflects the light irradiated on it along the original path, passes through the spherical mirror 3 and the plane mirror 5 in sequence, and finally gathers it at the receiving point, receives it by the optical fiber, and sends it to the spectrometer for analysis.

这种基于Cassegrain望远镜结构的DOAS系统,由于光线多次经反射镜遮挡,造成光谱利用效率低,且仪器调整和光路对中困难。This kind of DOAS system based on the Cassegrain telescope structure, because the light is blocked by the mirror many times, the spectrum utilization efficiency is low, and the instrument adjustment and optical path alignment are difficult.

【发明内容】:【Invention content】:

本发明的目的是解决现有DOAS系统光谱利用效率低,且仪器调整和光路对中困难的问题,提供一种光纤收发一体式空气差分吸收光谱测量系统。The purpose of the present invention is to solve the problems of low spectrum utilization efficiency and difficulty in instrument adjustment and optical path alignment in the existing DOAS system, and provide an air differential absorption spectrum measurement system integrated with optical fiber transceiver.

本发明提供的光纤收发一体式空气差分吸收光谱测量系统,包括点光源、望远镜和光谱仪,该系统还包括由发射光纤和接收光纤构成的具有收发光纤公共端的收发一体式结构光纤束,所述的点光源发出的光谱首先耦合到收发一体式结构光纤束中的发射光纤的一端后,经发射光纤的另一端即收发光纤公共端射出,经望远镜内的球面反射镜准直,通过一段开放的大气,到达望远镜光程另一端的角锥棱镜,然后被沿原方向反射,携带大气中污染气体信息的反射光沿原方向返回,再次经望远镜内的球面反射镜聚焦进入收发光纤公共端,最后经接收光纤另一端出射后导入光谱仪进行光谱检测。The optical fiber transceiver integrated air differential absorption spectrum measurement system provided by the present invention includes a point light source, a telescope and a spectrometer, and the system also includes a transceiver optical fiber bundle with a common end of the transceiver optical fiber, which is composed of a transmitting optical fiber and a receiving optical fiber. The spectrum emitted by the point light source is first coupled to one end of the transmitting fiber in the optical fiber bundle with integrated transceiver structure, and then emitted through the other end of the transmitting fiber, which is the common end of the transmitting and receiving fiber, collimated by the spherical mirror in the telescope, and passes through an open atmosphere , reaching the corner cube prism at the other end of the telescope’s optical path, and then reflected in the original direction, the reflected light carrying the pollution gas information in the atmosphere returns along the original direction, and is focused by the spherical reflector in the telescope again into the common end of the transceiver optical fiber, and finally passes through the After the other end of the receiving fiber exits, it is imported into a spectrometer for spectral detection.

所述的收发一体式结构光纤束中的收发光纤公共端位于望远镜的光轴上,设球面反射镜的半径为R,则收发光纤公共端距离球面反射镜的距离为1/2R。The common end of the transmitting and receiving optical fiber in the optical fiber bundle of the integrated transceiver structure is located on the optical axis of the telescope, assuming that the radius of the spherical reflector is R, the distance from the common end of the transmitting and receiving optical fiber to the spherical reflector is 1/2R.

收发一体式结构光纤束中的收发光纤公共端可以安装在三维移动平台上并可进行三维调整。The common end of the transmitting and receiving optical fiber in the integrated optical fiber bundle of the transmitting and receiving structure can be installed on a three-dimensional mobile platform and can be adjusted in three dimensions.

本发明的优点和积极效果:本发明提供的收发一体式空气差分吸收光谱测量系统中,光谱收发采用具有公共端口的一体式光纤束,望远镜中只有一块反射球面镜,与现有典型基于Cassegrain望远镜结构的DOAS系统相比,减少了两块平面反射镜,避免了光束在传输过程中平面镜的遮挡,提高了光谱利用效率。同时,该系统在调整和对中过程中,只需对收发一体式的光纤束公共端进行三维调整,从而简化了仪器调整和对中过程,调整过程可采用三维电动微调整结构,可以提高自动化程度。Advantages and positive effects of the present invention: In the transceiver integrated air differential absorption spectrum measurement system provided by the present invention, the spectrum transceiver adopts an integrated optical fiber bundle with a common port, and there is only one reflective spherical mirror in the telescope, which is different from the existing typical structure based on Cassegrain telescope Compared with the existing DOAS system, two flat mirrors are reduced, which avoids the blocking of the flat mirror during the transmission of the beam, and improves the spectral utilization efficiency. At the same time, in the process of adjustment and alignment, the system only needs to perform three-dimensional adjustment on the common end of the integrated optical fiber bundle, which simplifies the instrument adjustment and alignment process. The adjustment process can adopt a three-dimensional electric micro-adjustment structure, which can improve automation. degree.

【附图说明】:[Description of drawings]:

图1是现有典型的基于Cassegrain望远镜结构的DOAS系统结构示意;Figure 1 is a schematic diagram of the existing typical DOAS system structure based on the Cassegrain telescope structure;

图2是本发明提供的光纤收发一体式空气差分吸收光谱测量系统示意图;Fig. 2 is a schematic diagram of an optical fiber transceiver integrated air differential absorption spectrum measurement system provided by the present invention;

图3收发一体式光纤束结构示意图。Fig. 3 is a schematic diagram of the structure of the transceiver-integrated optical fiber bundle.

【具体实施方式】:【Detailed ways】:

图2所示为本发明提供的光纤收发一体式空气差分吸收光谱测量系统,该系统包括可发出宽光谱结构的点光源(氙灯)6、望远镜和光谱仪(图中未画出)。其中望远镜包括:球面反射镜9,及望远镜光程另一端的角锥棱镜10。此外该系统还包括收发一体式光纤束结构(如图3所示),该光纤束结构由发射光纤12和接收光纤13构成,其中一端固定在一起成为收发光纤公共端8,该公共端位于望远镜光轴上,假设球面反射镜9的半径为R,则收发光纤公共端距离球面反射镜的距离为1/2R,且该收发光纤公共端可以安装在现有的三维电动移动平台上并可进行三维调整。Fig. 2 shows the optical fiber transceiver integrated air differential absorption spectroscopy measurement system provided by the present invention, which includes a point light source (xenon lamp) 6, a telescope and a spectrometer (not shown) that can emit a wide spectrum structure. Wherein the telescope includes: a spherical reflector 9, and a corner cube prism 10 at the other end of the optical path of the telescope. In addition, the system also includes a transceiver-integrated optical fiber bundle structure (as shown in Figure 3), which is composed of a transmitting optical fiber 12 and a receiving optical fiber 13, one end of which is fixed together to become the common end 8 of the transmitting and receiving optical fiber, which is located at the telescope On the optical axis, assuming that the radius of the spherical reflector 9 is R, the distance between the common end of the transmitting and receiving optical fiber and the spherical reflecting mirror is 1/2R, and the common end of the transmitting and receiving optical fiber can be installed on an existing three-dimensional electric mobile platform and can be carried out Three-dimensional adjustment.

检测时,由氙灯6发出的光谱经耦合后首先进入发射光纤12的入射端口7,由发射光纤的另一端,即收发光纤公共端8射出,经望远镜内的球面反射镜9准直,通过一段开放的大气,到达望远镜光程另一端的角锥棱镜10,然后被沿原方向反射,携带大气中污染气体信息的反射光沿原方向返回,再次经望远镜内的球面反射镜9聚焦进入收发光纤公共端8,最后经接收光纤13的另一端口11出射后导入光谱仪进行光谱检测。光谱仪根据气体的特征吸收光谱可反演得到空气中痕量气体的浓度。During detection, the spectrum emitted by the xenon lamp 6 first enters the incident port 7 of the emission fiber 12 after being coupled, and is emitted from the other end of the emission fiber, that is, the common end 8 of the transceiver fiber, collimated by the spherical mirror 9 in the telescope, and passes through a section The open atmosphere reaches the corner cube prism 10 at the other end of the optical path of the telescope, and is then reflected in the original direction, and the reflected light carrying the information of the polluted gas in the atmosphere returns along the original direction, and is focused by the spherical reflector 9 in the telescope again into the transceiver optical fiber The common end 8 finally exits through the other port 11 of the receiving optical fiber 13 and then is introduced into a spectrometer for spectrum detection. The spectrometer can invert the concentration of trace gases in the air according to the characteristic absorption spectrum of the gas.

Claims (2)

1.一种光纤收发一体式空气差分吸收光谱测量系统,该系统包括点光源、望远镜和光谱仪,其特征在于该系统还包括由发射光纤和接收光纤构成的具有收发光纤公共端的收发一体式结构光纤束,所述的点光源发出的光谱首先耦合到收发一体式结构光纤束中的发射光纤的一端后,经发射光纤的另一端即收发光纤公共端射出,经望远镜内的球面反射镜准直,通过一段开放的大气,到达望远镜光程另一端的角锥棱镜,然后被沿原方向反射,携带大气中污染气体信息的反射光沿原方向返回,再次经望远镜内的球面反射镜聚焦进入收发光纤公共端,最后经接收光纤另一端出射后导入光谱仪进行光谱检测;所述的收发一体式结构光纤束中的收发光纤公共端位于望远镜的光轴上,设球面反射镜的半径为R,则收发光纤公共端距离球面反射镜的距离为1/2R。1. An optical fiber transceiver integrated air differential absorption spectrum measurement system, the system includes a point light source, a telescope and a spectrometer, it is characterized in that the system also includes a transceiver integrated structure optical fiber with a common end of the transceiver optical fiber made of a transmitting optical fiber and a receiving optical fiber The spectrum emitted by the point light source is first coupled to one end of the transmitting fiber in the optical fiber bundle with integrated transceiver structure, and then emitted through the other end of the transmitting fiber, that is, the common end of the transmitting and receiving fiber, and collimated by the spherical mirror in the telescope. Through an open atmosphere, it reaches the corner cube prism at the other end of the telescope’s optical path, and is reflected in the original direction. The reflected light carrying the pollution gas information in the atmosphere returns along the original direction, and is focused by the spherical mirror in the telescope again into the transceiver optical fiber. The common end is finally imported into the spectrometer for spectral detection after the other end of the receiving optical fiber exits; The distance between the fiber common end and the spherical reflector is 1/2R. 2.根据权利要求1所述的光纤收发一体式空气差分吸收光谱测量系统,其特征在于收发一体式结构光纤束中的收发光纤公共端安装在三维移动平台上并可进行三维调整。2. The optical fiber transceiver integrated air differential absorption spectroscopy measurement system according to claim 1, characterized in that the common end of the transceiver optical fiber in the transceiver integrated structural fiber bundle is installed on a three-dimensional mobile platform and can be adjusted in three dimensions.
CN201010238277XA 2010-07-28 2010-07-28 Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system Expired - Fee Related CN101936885B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201010238277XA CN101936885B (en) 2010-07-28 2010-07-28 Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201010238277XA CN101936885B (en) 2010-07-28 2010-07-28 Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system

Publications (2)

Publication Number Publication Date
CN101936885A CN101936885A (en) 2011-01-05
CN101936885B true CN101936885B (en) 2012-04-18

Family

ID=43390330

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201010238277XA Expired - Fee Related CN101936885B (en) 2010-07-28 2010-07-28 Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system

Country Status (1)

Country Link
CN (1) CN101936885B (en)

Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102788763A (en) * 2012-09-03 2012-11-21 四川大学 Difference absorption spectrum atmospheric monitoring system with laser induced breakdown spectrum serving as light source
KR101816675B1 (en) * 2014-06-23 2018-01-11 광주과학기술원 Optical Characteristics Measuring Apparatus Using Interrogation Optical Fiber, Optical Fiber Sensor System Comprising the Same and Method for Measuring Optical Characteristics
CN106568712B (en) * 2015-07-23 2019-01-15 苏州微纳激光光子技术有限公司 It is a kind of can remote adjustment long light path toxic and harmful gas monitor and its adjusting method
CN105136683A (en) * 2015-07-28 2015-12-09 安徽蓝盾光电子股份有限公司 Long optical path air quality automatic monitoring system with remote quality control function
CN106769738B (en) * 2017-01-18 2022-08-12 西安科技大学 A reflective fiber optic dust concentration measurement system

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2597968Y (en) * 2003-02-20 2004-01-07 中国科学院安徽光学精密机械研究所 Emitting and receiving system of laboratory differential absorption spectrometer
CN101105446A (en) * 2007-01-19 2008-01-16 华南理工大学 Differential Absorption Spectroscopy Air Quality Detection System

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN2597968Y (en) * 2003-02-20 2004-01-07 中国科学院安徽光学精密机械研究所 Emitting and receiving system of laboratory differential absorption spectrometer
CN101105446A (en) * 2007-01-19 2008-01-16 华南理工大学 Differential Absorption Spectroscopy Air Quality Detection System

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
司福祺等.光纤模式混合器在差分吸收光谱系统中的应用研究.《物理学报》.2007,第56卷(第3期),1825-1830. *

Also Published As

Publication number Publication date
CN101936885A (en) 2011-01-05

Similar Documents

Publication Publication Date Title
CN104007069B (en) Differential optical absorption spectroscopy measurement system based on off-axis paraboloid mirror
CN202083627U (en) Air Differential Absorption Spectroscopy Measurement System Based on Fiber-optic Cassegrain Telescope Structure
CN105424631B (en) A kind of hypersensitivity nitrogen oxides measuring system based on UV, visible light wave band absorption spectrum
CN101694460B (en) Self-adaptive differential absorption spectroscopy measurement method and device for flue gas pollutant concentration
CN103308432B (en) Continuous spectrum scattering type particle measurement method
CN103604501B (en) A kind of differential optical absorption spectrum measuring system utilizing polarization spectro
CN106970392A (en) High sensitivity gaseous contamination detecting laser radar system
CN101936885B (en) Optical fiber transceiver integrated air differential optical absorption spectroscopy (DOAS) measuring system
JPH04504908A (en) Light emitter/receiver
CN102636265A (en) Optical system based on portable efficient-measurement ultraviolet absorption spectrum
CN101980003B (en) Open long-path broad-spectrum gas measurement system
CN105675581B (en) A kind of free space gas Raman scattering collection device
CN101634626B (en) Active-passive integrated atmospheric pollution measuring system and measuring method thereof
CN103472014A (en) Gas multi-reflect pool detection device with multi-dimensional laser self-alignment function
CN102012357B (en) Bypass concentration calibration system with variable light path
CN102297841A (en) Flue gas automatic monitor based on optical fiber transmission and signal receiving
CN101241068A (en) Multi-path Optical Absorption Atmospheric Measuring Instrument
US7215428B2 (en) Absorption spectroscopy apparatus and method
CN204439539U (en) A kind of optical system of flue gas monitoring instrument and pick-up unit
CN103424369A (en) Pollution-gas differential optical absorption spectroscopy measurement system with optical fiber structure
CN212904513U (en) Multi-component real-time optical remote measuring device for motor vehicle tail gas
CN113607687A (en) Single-ended diffuse reflection multi-component measurement system based on gas absorption spectrum
CN102788763A (en) Difference absorption spectrum atmospheric monitoring system with laser induced breakdown spectrum serving as light source
CN201051075Y (en) Passive differential optical absorption spectrum analyzer
CN104614363A (en) Raman spectrum testing system based on liquid core waveguide

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
ASS Succession or assignment of patent right

Owner name: HEBEI UNIVERSITY OF TECHNOLOGY XIANSHI OPTICAL TEC

Free format text: FORMER OWNER: XIANSHI OPTICAL TECHNOLOGY CO LTD, TIANJIN CITY

C41 Transfer of patent application or patent right or utility model
C53 Correction of patent of invention or patent application
CB02 Change of applicant information

Address after: 300457, No. 41, Fifth Avenue, Tianjin Development Zone, No. five, zone 5, B

Applicant after: TIANJIN TONGYANG TECHNOLOGY DEVELOPMENT Co.,Ltd.

Co-applicant after: Hebei University of Technology

Co-applicant after: Tianjin Sunshine Optics Technolies Co.,Ltd.

Address before: 300457, No. 41, Fifth Avenue, Tianjin Development Zone, No. five, zone 5, B

Applicant before: TIANJIN TONGYANG TECHNOLOGY DEVELOPMENT Co.,Ltd.

Co-applicant before: Tianjin Sunshine Optics Technolies Co.,Ltd.

TA01 Transfer of patent application right

Effective date of registration: 20111110

Address after: 300457, No. 41, Fifth Avenue, Tianjin Development Zone, No. five, zone 5, B

Applicant after: TIANJIN TONGYANG TECHNOLOGY DEVELOPMENT Co.,Ltd.

Co-applicant after: Hebei University of Technology

Co-applicant after: Tianjin Sunshine Optics Technolies Co.,Ltd.

Address before: 300457, No. 41, Fifth Avenue, Tianjin Development Zone, No. five, zone 5, B

Applicant before: TIANJIN TONGYANG TECHNOLOGY DEVELOPMENT Co.,Ltd.

Co-applicant before: Tianjin Sunshine Optics Technolies Co.,Ltd.

C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20120418

Termination date: 20150728

EXPY Termination of patent right or utility model