Summary of the invention
The technical problem that the present invention will solve is: overcome the problem that prior art exists, provide a kind of cost low, be prone to that processing, ton paper paper delivery area are big, good penetrability, sun-resistant fastness and good wood-based plate facing spraying dedicated paper and the manufacturing approach thereof of washing fastness.
The technical solution adopted for the present invention to solve the technical problems is:
This wood-based plate facing sprays dedicated paper, it is characterized in that comprising the component of following weight percent content:
Wood pulp (in oven-dry weight) 40~65%
Filler 12~40%
Auxiliary agent 12~18%
Heatproof dyestuff 2~15%;
Wherein: described wood pulp is made up of following weight percentages:
Staple fibre wood pulp 70~100%
Long fiber wood pulp 0~30%;
Described filler is made up of following raw materials by weight percent:
Coating titanium white 70~90%
Lightweight aluminium oxide 10~30%;
Described auxiliary agent is made up of following raw materials by weight percent:
Calgon 0.5~1.9%
Aluminum sulfate 0.2~1%
Polyacrylamide 0.05~0.10%
Color-fixing agent 0.2~0.8%
Wet strength agent 96.20~99.05%.
Preferably,
Wood-based plate facing spraying dedicated paper comprises following components in weight percentage:
Wood pulp (in oven-dry weight) 45~60%
Filler 18~37%
Auxiliary agent 14~15%
Heatproof dyestuff 3~8%.
That described wood-based plate facing sprays dedicated paper quantitatively is 60~80g/m
2
The preparation method of the said wood-based plate facing spraying of a kind of claim 1 dedicated paper is characterized in that comprising the steps:
4.1 commercial wood pulp is carried out size degradation according to size degradation concentration 3.0~4.0%, and pulls an oar to 25~30 ° of SR of beating degree, must kowtow the back wood pulp through fiberizer;
4.2 the filler of coating titanium white 70~90%, lightweight aluminium oxide 10~30% compositions and the sodium hexametaphosphate solution that concentration is 0.5%-2% are mixed back high-speed stirred;
4.3 step 4.2 gained mixture added to fill out in the pond kowtows the back wood pulp with step 4.1 gained and mix;
4.4 it is 3.0% mixture that step 5.3 a handy backwater is adjusted to concentration, then heatproof dyestuff, color-fixing agent, wet strength agent, polyacrylamide and aluminum sulfate is added to fill out in the pond and fully mixes, and makes slurry;
Using paper machine recirculated water that step 4.4 gained slurry mix is adjusted to concentration before 4.5 manufacture paper with pulp is 0.95~1.1% online slurry; The online mashing pump that will prepare is then delivered to head box online dehydration, and control slurry speed and network speed ratio are 1.05: 1 to 1.15: 1;
4.6, promptly get wood-based plate facing spraying dedicated paper of the present invention with the paper stock oven dry.
All raw materials that adopt among the present invention are the commercial goods; Personnel in the present technique field can obtain on market easily; The function of each component is following: coating titanium white (Henan Baililian Chemical Co., Ltd.): adopted the high energy activation clad surface to handle; Dispersiveness, weatherability, oil absorption, whiteness etc. all are better than traditional titanium white powder, main raising as wood-based plate facing spraying dedicated paper covering property among the present invention; Lightweight aluminium oxide (Weifang Xi Lebaier imports and exports Co., Ltd): molecular formula Al (OH)
3, Al
2O
33H
2O or H
3AlO
3, auxiliary in the present invention coating titanium white hides; Polyacrylamide (opening shop double focusing Fine Chemical Works): be a kind of synthetic water-soluble linear macromolecular compound, be called for short PAM, its averagemolecular wt amount has more than 1,000,000.It is a kind of white, tasteless, be Powdered or contain the transparent colloid polymer of certain moisture; Calgon (Linzi, Shandong gold auspicious first chemical industry Co., Ltd): white powdery or powder, apparent density 0.35~0.90g/cm
3, 622 ℃ of fusing points, soluble in water, the aqueous solution is alkalescence, and 1% aqueous solution pH is 9.7, in water, is hydrolyzed into phosphite gradually, has the ability of good complexation of metal ions, and calgon is mainly as dispersant and complexing agent among the present invention; Aluminum sulfate (powerful water-purifying material Co., Ltd): have the effect of regulating the pH value, improving paper pulp mixed liquor charge balance; Color-fixing agent (environment-friendly type cationic homopolymer) (opening shop double focusing Fine Chemical Works): white in appearance transparency liquid (range estimation), solid content (%): 40, monomer residual volume (wt%) :≤0.8, viscosity (25 ℃, mpa.s) :≤40-160, density (25 ℃, g/cm
3): 1.06, pH:3-5, its effect is the good combination that realizes dye granule and wood pulp fibre; Wet strength agent (polyamide-epichlorohydrin resin) (Guangrao Huaxing chemical plant, Xidan stream are won industry and trade Co., Ltd): light yellow transparent solution; Solid content: 12.5 ± 0.5%; Viscosity: 35~70cp (25 ℃); PH:4~5, main among the present invention as raising wood-based plate facing spraying dedicated paper wet strength, and improve the dehydration of paper machine and use; Heatproof dyestuff (Clariant chemical industry (China) Co., Ltd): mainly consist of diaminobenzil disulfonic acid class etc.
Compared with prior art; The beneficial effect that the present invention had is: the present invention is employed in the wood pulp and adds the covering property that treated coating titanium white powder and lightweight alumina packing have improved wood-based plate facing spraying dedicated paper needs effectively; In the dip coated process, only need a spot of coating can realize good covering effect, not only overcome common finishing paper and hidden the performance difference band adverse effect of coming but also reduced product cost slightly.Simultaneously, in the mixture of wood pulp and filler, add special auxiliary agent and effectively improved wood-based plate facing spraying dedicated paper fibr tissue uniformity, become the paper hygral expansion, solved the bad problem of the surface effect of wood-based plate own.The consumption of the heatproof dyestuff that the present invention adds is through experiment sieving, and its sun-resistant fastness reaches 6~7 grades, and washing fastness reaches 3~4 grades, and is bright in luster, meets instructions for use.Preparation method; The bleaching commercial wood pulp through size degradation, defibrination (25~30 ° of SR of control beating degree), with the chemical assistant supervisor that reacts, the wood-based plate facing spraying dedicated paper that control (slurry speed is 1.05: 1 to 1.15: 1 with the network speed ratio) press section through paper machine approach system, the acting in conjunction of oven dry portion are processed.Product specific targets: quantitative 60-80/m
2, wet strength is 30-45mm/10min, is 0.5-1.5% to hygroexpansivity in length and breadth greater than 6.0-7.5N/15mm, water imbibition, meets client's instructions for use and relevant criterion.Wood-based plate facing spraying dedicated paper is after passing through dip coated, processing wood-based plate, and its light fastness reaches 7~8 grades.
The wood-based plate facing spraying dedicated paper that the present invention makes can substitute traditional finishing materials such as pottery, glass, wallpaper, plastics fully; Have that price is low, processing is simple, the beautiful characteristics such as various of environmental protection, color; Can greatly economize on resources simultaneously, have remarkable economic efficiency and social benefit.
The specific embodiment
Embodiment 1~5 and Comparative Examples 1~2
1) proportioning raw materials:
Table 1 proportioning raw materials table (unit: weight %)
Wherein, the wood pulp percentage by weight is made up of following raw materials according in oven-dry weight: staple fibre wood pulp 70%-100%, long fiber wood pulp 0%-30%; Filler is made up of following materials: coating titanium white 70%-90%, lightweight aluminium oxide 10%-30%.
Auxiliary agent is according to the following table proportioning:
Table 2 auxiliary agent proportioning table (unit: weight % is in oven-dry weight)
|
Prescription 1 |
Prescription 2 |
Prescription 3 |
Calgon |
0.5 |
1 |
1.9 |
Aluminum sulfate |
0.2 |
0.5 |
1 |
Polyacrylamide |
0.05 |
0.08 |
0.1 |
Color-fixing agent |
0.2 |
0.5 |
0.8 |
Wet strength agent |
99.05 |
97.92 |
96.2 |
Above-mentioned raw materials is the commercial goods.
2) preparation method:
Embodiment 1
The concentration of wood pulp (the wood pulp consumption is by the prescription of embodiment in the table 1 1) according to 3.0% is carried out size degradation, pull an oar to 25 ° of SR of beating degree, pump into to add by table 1 embodiment 1 required wood pulp amount and fill out the pond through fiberizer.And then according to table 1 embodiment 1 said filler weight to add concentration be 0.5% calgon (amount of calgon is pressed table 1 embodiment 1) solution than taking by weighing in the filler that comprises coating titanium white, lightweight aluminium oxide, high-speed stirred.Mixture after being mixed pumped into add in the wood pulp of filling out the pond; Using backwater to be adjusted to concentration is 3.0% mixture, in mixed slurry, adds environmental protection dyestuff (consumption is pressed embodiment 1 in the table 1), color-fixing agent, wet strength agent, aluminum sulfate, polyacrylamide (auxiliary dosage is pressed the numerical value of the embodiment 1 in the table 2) then successively.To be adjusted to concentration be 1.0% online slurry control slurry speed and the network speed ratio is that the wood-based plate facing of through paper machine producing according with process requirements at 1.05: 1 sprays dedicated paper with slurry mix before paper machine making, to use paper machine recirculated water.Product specific targets: quantitative 80g/m
2, wet strength is 45mm/10min, is 1.0% to hygroexpansivity in length and breadth greater than 7.5N/15mm, water imbibition, meets client's instructions for use and relevant criterion.
Embodiment 2
The concentration of wood pulp (the wood pulp consumption is by the prescription of embodiment in the table 1 3) according to 3.5% is carried out size degradation, pull an oar to 28 ° of SR of beating degree, pump into to add by table 1 embodiment 3 required wood pulp amounts and fill out the pond through fiberizer.And then according to table 1 embodiment 3 said filler weight to add concentration be 1% calgon (amount of calgon is pressed table 1 embodiment 3) solution than taking by weighing in the filler that comprises coating titanium white, lightweight aluminium oxide, high-speed stirred.Mixture after being mixed pumped into add in the wood pulp of filling out the pond; Using backwater to be adjusted to concentration is 3.0% mixture, in mixed slurry, adds dyestuff (consumption is pressed embodiment 3 in the table 1), color-fixing agent, wet strength agent, aluminum sulfate, polyacrylamide (auxiliary dosage is pressed the numerical value of the embodiment 2 in the table 2) then successively.Before paper machine making, using paper machine recirculated water that slurry mix is adjusted to concentration is 0.95% online slurry, and control slurry speed is 1.10: 1 with the network speed ratio, and the wood-based plate facing of producing according with process requirements through paper machine sprays dedicated paper.Its specific targets: quantitative 80g/m
2, wet strength is 40mm/10min, is 1.0% to hygroexpansivity in length and breadth greater than 6.5N/15mm, water imbibition, meets client's instructions for use and relevant criterion.
Embodiment 3
The concentration of wood pulp (the wood pulp consumption is by the prescription of embodiment in the table 1 5) according to 4.0% is carried out size degradation, pull an oar to 30 ° of SR of beating degree, pump into to add by table 1 embodiment 5 required wood pulp amounts and fill out the pond through fiberizer.And then be 1.9% calgon (amount of calgon is pressed table 1 embodiment 5) solution according to table 1 embodiment 5 said filler weight than adding concentration in the filler that comprises coating titanium white, lightweight aluminium oxide that takes by weighing, high-speed stirred.Mixture after being mixed pumped into add in the wood pulp of filling out the pond; Using backwater to be adjusted to concentration is 3.0% mixture, in mixed slurry, adds dyestuff (consumption is pressed embodiment 5 in the table 1), color-fixing agent, wet strength agent, aluminum sulfate, polyacrylamide (auxiliary dosage is pressed the numerical value of the embodiment 3 in the table 2) then successively.Before paper machine making, using paper machine recirculated water that slurry mix is adjusted to concentration is 1.1% online slurry, and slurrying material speed and network speed ratio are 1.15: 1, and the wood-based plate facing of producing according with process requirements through paper machine sprays dedicated paper.Its specific targets: quantitative 80g/m
2, wet strength is 32mm/10min, is 0.8% to hygroexpansivity in length and breadth greater than 6.2N/15mm, water imbibition, meets client's instructions for use and relevant criterion.
3) presentation of results:
Embodiment 1~5 qualified products, it quantitatively is 60~80g/m
2, wood-based plate facing spraying dedicated paper wet strength is 30~45mm/10min, is 0.5~1.5% to hygroexpansivity in length and breadth greater than 6.0N/15mm, water imbibition, meets client's instructions for use and relevant criterion.
The amount of filler of Comparative Examples 1 is too high, causes the production cost of wood-based plate facing spraying dedicated paper too high, and the downstream client carries out the dip coated operation again, and the dalle cost of output is too high, and the client can't accept;
Comparative Examples 2 composition of raw materials are no problem, but in process of production because beating degree is controlled at 33~35 ° of SR, and the suction head that causes into paper drops to 25mm/10min, time of penetration causes the dip coated difficulty at 10S.
The above only is preferred embodiment of the present invention, is not to be the restriction of the present invention being made other form, and any professional and technical personnel of being familiar with possibly utilize the technology contents of above-mentioned announcement to change or be modified as the equivalent embodiment of equivalent variations.But everyly do not break away from technical scheme content of the present invention, to any simple modification, equivalent variations and remodeling that above embodiment did, still belong to the protection domain of technical scheme of the present invention according to technical spirit of the present invention.