CN101928442A - Material for manufacturing modified phenolic fireproofing insulation board - Google Patents
Material for manufacturing modified phenolic fireproofing insulation board Download PDFInfo
- Publication number
- CN101928442A CN101928442A CN201010022544XA CN201010022544A CN101928442A CN 101928442 A CN101928442 A CN 101928442A CN 201010022544X A CN201010022544X A CN 201010022544XA CN 201010022544 A CN201010022544 A CN 201010022544A CN 101928442 A CN101928442 A CN 101928442A
- Authority
- CN
- China
- Prior art keywords
- modified phenolic
- parts
- insulation board
- formaldehyde
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 title claims abstract description 27
- 239000000463 material Substances 0.000 title claims abstract description 14
- 238000004079 fireproofing Methods 0.000 title abstract 3
- 238000009413 insulation Methods 0.000 title abstract 3
- 238000004519 manufacturing process Methods 0.000 title abstract 3
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 17
- 229920001568 phenolic resin Polymers 0.000 claims description 8
- 239000005011 phenolic resin Substances 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 4
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical group CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 235000011089 carbon dioxide Nutrition 0.000 claims description 2
- 229920002545 silicone oil Polymers 0.000 claims description 2
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 abstract description 24
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 abstract description 7
- 238000002360 preparation method Methods 0.000 abstract description 4
- 239000004566 building material Substances 0.000 abstract description 2
- 238000010276 construction Methods 0.000 abstract description 2
- 239000006260 foam Substances 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 239000004088 foaming agent Substances 0.000 abstract 1
- 239000004094 surface-active agent Substances 0.000 abstract 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 4
- 239000004202 carbamide Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 238000005187 foaming Methods 0.000 description 3
- 229920003987 resole Polymers 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 150000001299 aldehydes Chemical class 0.000 description 2
- 238000004132 cross linking Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- CQRYARSYNCAZFO-UHFFFAOYSA-N salicyl alcohol Chemical compound OCC1=CC=CC=C1O CQRYARSYNCAZFO-UHFFFAOYSA-N 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000006057 Non-nutritive feed additive Substances 0.000 description 1
- 229920006328 Styrofoam Polymers 0.000 description 1
- 229920001807 Urea-formaldehyde Polymers 0.000 description 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 230000000977 initiatory effect Effects 0.000 description 1
- 239000012774 insulation material Substances 0.000 description 1
- QUBQYFYWUJJAAK-UHFFFAOYSA-N oxymethurea Chemical compound OCNC(=O)NCO QUBQYFYWUJJAAK-UHFFFAOYSA-N 0.000 description 1
- 229950005308 oxymethurea Drugs 0.000 description 1
- 230000021715 photosynthesis, light harvesting Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000376 reactant Substances 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 239000008261 styrofoam Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Building Environments (AREA)
Abstract
The invention relates to the technical field of building materials, in particular to a material for manufacturing a modified phenolic fireproofing insulation board and a preparation method thereof. The material for manufacturing the modified phenolic fireproofing insulation board comprises the following components in part by weight: 100 parts of modified phenolic resin, 2 to 4 parts of surfactant, 5 to 7 parts of foaming agent and 8 to 10 parts of curing agent. Due to the adoption of the technical scheme, the free phenol of the material is 0.09 percent, the free formaldehyde is less than 0.1 percent, the release amount of the formaldehyde is reduced obviously, and the physical and chemical properties of the material have no obvious difference compared with those of phenolic foam prepared under the normal condition, so the material can be applied to interior wall construction (interior wall heat-insulating systems) of buildings.
Description
Technical field
The present invention relates to building material technical field, especially relate to a kind of material for preparing modified phenolic fireproof insulating plate.
Background technology
Because building energy consumption is higher, energy dissipation seriously is a kind of very general problem, so building energy conservation is direct, a cheap systems engineering alleviating energy scarcity.Owing to inflammable, shortcomings such as toxic smoke big, water absorbing properties difference, there is potential safety hazard as extruded sheet, styrofoam etc. in present employed building thermal insulation material.Phenol formaldehyde foam can be good at being applied in the heat insulating inner wall system, so is subjected to the people's attention just day by day owing to have that raw material is easy to get, cheap, characteristics such as product performance are good, difficult fire, put out certainly, low smog, water-proof breathable properties are good.But the prior art phenol formaldehyde foam is to add tensio-active agent by resol, whipping agent, and multiple processing aid such as solidifying agent is through stirring foaming, the foam that slaking forms.Yet the content of free phenol and free aldehyde is higher in the resol, and toxicity is big, harm environment and HUMAN HEALTH.Product colour is dark, influences outward appearance.How to reduce that the content of formaldehyde becomes an important problem in the phenol formaldehyde foam.
Summary of the invention
Technical problem to be solved by this invention is the defective that exists at prior art, provides a kind of and can enhance product performance, and can reduce the material of the preparation modified phenolic fireproof insulating plate of formaldehyde content.The technical scheme that the present invention solves its technical problem employing is: a kind of material of making modified phenolic fireproof insulating plate, its component and parts by weight are: modified phenolic resins 100, tensio-active agent 2～4, whipping agent 5～7, solidifying agent 8～10.Technical problem to be solved by this invention also can further be solved by following technical solution: described tensio-active agent is silicone oil H230 or DC-193; Described whipping agent is Skellysolve A or carbonic acid gas; Described solidifying agent is xylene monosulfonic acid, tosic acid, phosphoric acid or sulfuric acid.All components among the present invention all at home market buy.The preparation method of the modified phenolic resins among the present invention is: with phenol and formaldehyde amount of substance ratio is 1: under the 1.5-3 condition, the sodium hydroxide of Dropwise 5 0% (with the mass ratio of phenol be 6-8: 100), then at 70～90 ℃ of reaction 150～180min, is 1-3 with urea and phenol by mass ratio: 100 add gradually, reaction 20min is cooled to room temperature, neutralizes with hydrochloric acid, the pH value that makes reaction soln is about 7, underpressure distillation cooling discharging during to required viscosity." modified phenolic resins " reaction mechanism among the present invention is to utilize urea and formaldehyde reaction to generate an Oxymethurea and dimethylolpropionic urea, generates urea-formaldehyde resin then, has consumed formaldehyde.In addition, reaction in the later stage resol a hydroxymethyl phenol and many hydroxymethyl phenols also can with remaining phenol reactant, but added after the urea, such reaction probability has reduced.Ultimate name of product of the present invention is called " phenol formaldehyde foam " in the present technique field.Each component of the present invention effect in the present invention is respectively: crosslinking reaction can take place in modified phenolic resins at a certain temperature, forms the needed crosslinking structure of phenol formaldehyde foam; Tensio-active agent plays a part modified phenolic resins in foaming system and whipping agent mixes; Whipping agent can make phenol formaldehyde foam produce microvoid structure; Solidifying agent is the crosslinked initiator of modified phenolic resins still not, and can also promote the whipping agent foaming because of the heat release of initiation reaction.Preparation method of the present invention evenly stirs.The present invention is owing to adopt technique scheme, and its free phenol is 0.09%, and free aldehyde has obviously reduced the burst size of formaldehyde less than 0.1%, makes the present invention can be applied in the interior wall construction (heat insulating inner wall system) of buildings.
Embodiment
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
| Modified phenolic resins | 100Kg? | 100Kg? | 100Kg? | 100Kg? | 100Kg? |
| Tensio-active agent | 2Kg? | 4Kg? | 3Kg? | 2.5Kg? | 3.5Kg? |
| Whipping agent | 7Kg? | 5Kg? | 6Kg? | 6.5Kg? | 5.5Kg? |
| Solidifying agent | 10Kg? | 8Kg? | 9Kg? | 8.5Kg? | 9.5Kg? |
Claims (4)
1. material of making modified phenolic fireproof insulating plate is characterized in that its component and parts by weight are:
Modified phenolic resins 100,
Tensio-active agent 2～4,
Whipping agent 5～7,
Solidifying agent 8～10.
2. a kind of material of making modified phenolic fireproof insulating plate according to claim 1 is characterized in that: tensio-active agent is silicone oil H230 or DC-193.
3. a kind of material of making modified phenolic fireproof insulating plate according to claim 1 is characterized in that: whipping agent is Skellysolve A or carbonic acid gas.
4. a kind of material of making modified phenolic fireproof insulating plate according to claim 1 is characterized in that: solidifying agent is xylene monosulfonic acid, tosic acid, phosphoric acid or sulfuric acid.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010022544XA CN101928442A (en) | 2010-01-07 | 2010-01-07 | Material for manufacturing modified phenolic fireproofing insulation board |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010022544XA CN101928442A (en) | 2010-01-07 | 2010-01-07 | Material for manufacturing modified phenolic fireproofing insulation board |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101928442A true CN101928442A (en) | 2010-12-29 |
Family
ID=43367893
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010022544XA Pending CN101928442A (en) | 2010-01-07 | 2010-01-07 | Material for manufacturing modified phenolic fireproofing insulation board |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101928442A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224689A (en) * | 2013-05-09 | 2013-07-31 | 山西新举节能建材科技有限公司 | Fireproof thermal insulation modified phenolic plate and making method thereof |
| CN103538197A (en) * | 2013-09-24 | 2014-01-29 | 江苏恒盛达环境科技有限公司 | Method for preparing novel cold storage installation composite board for ships |
| CN104194254A (en) * | 2014-08-28 | 2014-12-10 | 苏志刚 | Curing agent for phenol formaldehyde foamed resins and synthesis method thereof |
| CN109369950A (en) * | 2018-11-06 | 2019-02-22 | 山东天洋新材料有限公司 | A kind of supercritical carbon dioxide foaming phenol formaldehyde foam and preparation method thereof |
-
2010
- 2010-01-07 CN CN201010022544XA patent/CN101928442A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103224689A (en) * | 2013-05-09 | 2013-07-31 | 山西新举节能建材科技有限公司 | Fireproof thermal insulation modified phenolic plate and making method thereof |
| CN103538197A (en) * | 2013-09-24 | 2014-01-29 | 江苏恒盛达环境科技有限公司 | Method for preparing novel cold storage installation composite board for ships |
| CN104194254A (en) * | 2014-08-28 | 2014-12-10 | 苏志刚 | Curing agent for phenol formaldehyde foamed resins and synthesis method thereof |
| CN104194254B (en) * | 2014-08-28 | 2016-02-24 | 苏志刚 | Phenolic foam resin solidifying agent and synthetic method thereof |
| CN109369950A (en) * | 2018-11-06 | 2019-02-22 | 山东天洋新材料有限公司 | A kind of supercritical carbon dioxide foaming phenol formaldehyde foam and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| ASS | Succession or assignment of patent right |
Owner name: ADASH NEW BUILDING MATERIALS (SHANGHAI) CO., LTD. Effective date: 20120817 |
|
| C41 | Transfer of patent application or patent right or utility model | ||
| TA01 | Transfer of patent application right |
Effective date of registration: 20120817 Address after: 201314 Shanghai city Pudong New Area South Road No. 8615 Applicant after: Shanghai Adash Superior Paint Co., Ltd. Applicant after: The new building materials (Shanghai) Co., Ltd. astec Address before: 201314 Shanghai city Pudong New Area South Road No. 8615 Applicant before: Shanghai Adash Superior Paint Co., Ltd. |
|
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20101229 |