CN101885884B - Bamboo shell fiber/PVC composite material and preparation method thereof - Google Patents
Bamboo shell fiber/PVC composite material and preparation method thereof Download PDFInfo
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- CN101885884B CN101885884B CN2010102316458A CN201010231645A CN101885884B CN 101885884 B CN101885884 B CN 101885884B CN 2010102316458 A CN2010102316458 A CN 2010102316458A CN 201010231645 A CN201010231645 A CN 201010231645A CN 101885884 B CN101885884 B CN 101885884B
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- bamboo shoot
- case fibre
- pvc
- temperature
- bamboo
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- 235000017166 Bambusa arundinacea Nutrition 0.000 title claims abstract description 98
- 235000017491 Bambusa tulda Nutrition 0.000 title claims abstract description 98
- 241001330002 Bambuseae Species 0.000 title claims abstract description 98
- 235000015334 Phyllostachys viridis Nutrition 0.000 title claims abstract description 98
- 239000011425 bamboo Substances 0.000 title claims abstract description 98
- 239000000835 fiber Substances 0.000 title claims abstract description 45
- 238000002360 preparation method Methods 0.000 title claims description 15
- 239000002131 composite material Substances 0.000 title abstract description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims abstract description 20
- 239000000843 powder Substances 0.000 claims description 28
- 239000011159 matrix material Substances 0.000 claims description 23
- 238000002203 pretreatment Methods 0.000 claims description 13
- 239000012188 paraffin wax Substances 0.000 claims description 10
- 229920006242 ethylene acrylic acid copolymer Polymers 0.000 claims description 6
- SJOCPYUKFOTDAN-ZSOIEALJSA-N methyl (4z)-4-hydroxyimino-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophene-1-carboxylate Chemical compound C1C(C)(C)C\C(=N\O)C=2C1=C(C(=O)OC)SC=2SC SJOCPYUKFOTDAN-ZSOIEALJSA-N 0.000 claims description 4
- 239000012752 auxiliary agent Substances 0.000 abstract description 4
- 239000003795 chemical substances by application Substances 0.000 abstract description 2
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- UQLDLKMNUJERMK-UHFFFAOYSA-L di(octadecanoyloxy)lead Chemical group [Pb+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O UQLDLKMNUJERMK-UHFFFAOYSA-L 0.000 description 8
- 238000003756 stirring Methods 0.000 description 8
- 239000002699 waste material Substances 0.000 description 6
- 239000004135 Bone phosphate Substances 0.000 description 4
- 239000004709 Chlorinated polyethylene Substances 0.000 description 3
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000003647 oxidation Effects 0.000 description 3
- 238000007254 oxidation reaction Methods 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N Acrylic acid Chemical compound OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 241000256113 Culicidae Species 0.000 description 1
- 241000255925 Diptera Species 0.000 description 1
- 241000196324 Embryophyta Species 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 229920001587 Wood-plastic composite Polymers 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 238000009313 farming Methods 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 238000003754 machining Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 239000011155 wood-plastic composite Substances 0.000 description 1
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- Compositions Of Macromolecular Compounds (AREA)
- Dry Formation Of Fiberboard And The Like (AREA)
Abstract
一种笋壳纤维/PVC复合材料，包括以下重量份的各组分：PVC 100份、笋壳纤维20～100份、硅烷偶联剂1～8份、相容剂10～20份、抗氧剂1～4份、助剂10～20份。按以上配比量先在高速捏合机进行分散，然后经双辊混炼机混炼或双螺杆挤出机挤出，即得所述笋壳纤维/PVC复合材料。A bamboo shoot shell fiber/PVC composite material, comprising the following components in parts by weight: 100 parts of PVC, 20-100 parts of bamboo shoot fiber, 1-8 parts of silane coupling agent, 10-20 parts of compatibilizer, antioxidant 1-4 parts of agent, 10-20 parts of auxiliary agent. Disperse in a high-speed kneader according to the above ratio, and then knead with a twin-roller mixer or extrude with a twin-screw extruder to obtain the bamboo shoot shell fiber/PVC composite material.
Description
One, technical field
The present invention relates to a kind of Wood-plastic material and preparation method thereof, specifically a kind of bamboo shoot case fibre/PVC matrix material and preparation method thereof.
Two, background technology
The bamboo shoot shell is a kind of natural plant fibre, is a still undeveloped valuable source, and rainy season at a time when the listing of bright bamboo shoot, and bulk deposition, bright bamboo shoot shell rot very soon, cause environmental pollution.Along with developing rapidly of bamboo shoots processing industry, bamboo shoots processing is left over waste bamboo shoot shell etc. and environment has been caused severe contamination, has influenced the ecological construction in new rural area; Simultaneously, also cause the waste of ample resources, how to develop bamboo shoot shell resource; Turn waste into wealth; Improving its added value, is the needs of bamboo shoots industrial chain development, also is the needs of developing a circular economy.
China is topmost in the world product bamboo state, is that kind, area, accumulation and the bamboo wood of bamboo, the output of bamboo shoots all rank first place, the world, the bamboo kind is known have Forest Park, Foochow 39 belong to 500 surplus kind, about 4,200,000 hm of the bamboo grove total area
2The whole world bamboo developed into one with about 2,500,000,000 people's production, the industry that life is closely related and annual value of production is nearly 5,000,000,000 dollars.China produces bright bamboo shoot more than 150 ten thousand t per year, goes out bamboo shoot rate 50%, has that bright bamboo shoot shell is dropped about 700,000 t an every year.Under this urgent and strict demand of environment protection, how bulk deposition bamboo shoot shell waste is effectively handled, and has become an extremely urgent problem of bamboo shoots processing enterprises.At present; The processing mode of " stacking " adopted is in the development that is restricting bamboo shoots processing enterprise in a different manner: worker's waste of stacking these thousands of tons; Not only take a large amount of soils, and this mode can not satisfy environmental requirement still in contaminate environment; And processing costs is also very expensive, causes bigger pressure to enterprise.And the bamboo shoot farming along with rotten peculiar smell is unpleasant, is grown mosquitos and flies with being intended to roadside, river bank discarded bamboo shells.Solve the problem that waste is left in bamboo shoots processing, basic outlet is to be to have wide market outlook, bigger market capacity, the various starting material or the goods of favorable economic benefit with its development process how.
At present; Domestic wood plastic composite is that main raw material carries out compound to PE, PP, PVC with the wood powder; As: CN1482166A, CN1445285A, CN1990599A, CN1513918A etc., but bamboo shoot case fibre/PVC composite study and patent are not seen relevant report as yet, the Application and Development of this matrix material helps the bamboo industry comprehensive utilization of resources; To improve additional value of farm products, environment protection is significant, market outlook are boundless.
Three, summary of the invention
The present invention is intended to fully utilize the bamboo shoot case fibre, and technical problem to be solved is to substitute wood powder and thermoplastic resin PVC machining composite material with the bamboo shoot case fibre.
Bamboo shoot case fibre/PVC matrix material that the present invention proposes comprises each component of following weight part:
100 parts of PVC
20～100 parts of bamboo shoot case fibres
10～20 parts of auxiliary agents
1～8 part of silane coupling agent
10～20 parts of compatilizers
1～4 part in oxidation inhibitor.
Its particulate median size of said bamboo shoot case fibre is at least 20 orders, water cut≤5%.
Said auxiliary agent is selected from paraffin, CaCO
3, Ca (HCO
3)
2Or talcum powder etc.
Said silane coupling agent is selected from KH-550, KH-560 or KH-570 etc.
Said resin compatible agent be selected from ethylene acrylic acid co polymer or/and ROHM or/and polyacrylic ester or/and chlorinatedpolyethylene etc.
Said oxidation inhibitor is selected from lead stearate, dibasic lead stearate or tribasic lead stearate etc.
Described composite material and preparation method thereof comprises bamboo shoot case fibre pre-treatment and mixing.
The pre-treatment of described bamboo shoot case fibre is meant the silane coupling agent physical mixed of bamboo shoot shell powder and proportional quantity.
The described mixing PVC that is meant proportional quantity, pre-treatment bamboo shoot case fibre, compatilizer, oxidation inhibitor and auxiliary agent disperse at the high speed kneader earlier, and mixing or twin screw extruder is extruded through double roll mill then.
Described high speed kneader rotating speed 1000～1500rpm, 50～60 ℃ of temperature, time 5～10min.
Described double roll mill mixing time 10～20min, 150～180 ℃ of temperature.
Described twin screw extruder is extruded under 150～180 ℃ of temperature and is extruded.
Bamboo shoot case fibre/PVC the matrix material of the present invention's preparation, high comprehensive performance, cost performance is high.Advantage of the present invention is mainly reflected in:
1. solve the problem of environmental pollution of bright bamboo shoot shell, helped the bamboo industry comprehensive utilization of resources, improved additional value of farm products.
2. production technique is simply clean, and product stability is good, and is with low cost.
Four, embodiment
Following non-limiting examples is narrated as follows:
Embodiment 1
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 1.0g silane resin acceptor kh-550 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 16g chlorinatedpolyethylene, 4g lead stearate, 4g paraffin, 16g CaCO
3Disperse at the high speed kneader, rotating speed 1000rpm, 50 ℃ of temperature, time 5min, at the mixing 10min of double roll mill, temperature is 160 ℃ then, obtains bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 2
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 1.0g silane coupling agent KH-560 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 10g chlorinatedpolyethylene, 2g lead stearate, 3g paraffin, 10g CaCO
3Disperse at the high speed kneader, rotating speed 1000rpm, 55 ℃ of temperature, time 8min, at the mixing 15min of double roll mill, temperature is 160 ℃ then, obtains bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 3
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 1.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 10g ethylene acrylic acid co polymer, 1g dibasic lead stearate, 4g paraffin, 12g Ca (HCO
3)
2Disperse at the high speed kneader, rotating speed 1500rpm, 55 ℃ of temperature, time 10min, at the mixing 20min of double roll mill, temperature is 170 ℃ then, obtains bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 4
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 2.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 15g ethylene acrylic acid co polymer, 4g dibasic lead stearate, 5g paraffin, 10g Ca (HCO
3)
2Disperse at the high speed kneader, rotating speed 1200rpm, 60 ℃ of temperature, time 10min extrudes through twin screw extruder then, and 180 ℃ of temperature obtain bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 5
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 4.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
Above-mentioned bamboo shoot case fibre, 100g PVC, the polymkeric substance of 20g propenoate, the tribasic lead stearate of 3g, 2g paraffin, 18g talcum powder are disperseed at the high speed kneader; Rotating speed 1000rpm; 60 ℃ of temperature, time 10min extrudes through twin screw extruder then; 170 ℃ of temperature obtain bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 6
30g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 8.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
Above-mentioned bamboo shoot case fibre, 100g PVC, the polymkeric substance of 16g propenoate, the tribasic lead stearate of 4g, 4g paraffin, 16g talcum powder are being disperseed at the high speed kneader; Rotating speed 1500rpm; 55 ℃ of temperature, time 20min extrudes through twin screw extruder then; 160 ℃ of temperature obtain bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 7
60g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 2.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 16g ethylene acrylic acid co polymer, 2g lead stearate, 5g paraffin, 5g CaCO
3Disperse at the high speed kneader, rotating speed 1400rpm, 60 ℃ of temperature, time 20min extrudes through twin screw extruder then, and 150 ℃ of temperature obtain bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
Embodiment 8
90g bamboo shoot shell powder (median size is that water cut is lower than 5% more than 20 orders) and 2.0g silane coupling agent KH-570 stir, and bamboo shoot shell powder is carried out pre-treatment, make silane coupling agent be coated on bamboo shoot shell powder surface full and uniformly.
With above-mentioned bamboo shoot case fibre, 100g PVC, 16g ethylene acrylic acid co polymer, the tribasic lead stearate of 4g, 4g paraffin, 10g CaCO
3In the high speed kneader, disperse, rotating speed 1500rpm, 55 ℃ of temperature, time 15min extrudes through twin screw extruder then, and 170 ℃ of temperature obtain bamboo shoot case fibre/PVC matrix material.
Mechanics Performance Testing is carried out in above-mentioned bamboo shoot case fibre/PVC matrix material compressing tablet, sample preparation on vulcanizing press.The vulcanizer temperature is controlled at 180 ℃, and pressure is 8MPa, time 10min.Testing standard and result are as shown in table 1.
The testing standard of table 1 sample and measuring mechanical property result
Claims (2)
1. bamboo shoot case fibre/PVC matrix material is characterized in that comprising each component of following weight part:
2. the preparation method of bamboo shoot case fibre as claimed in claim 1/PVC matrix material; Comprise bamboo shoot case fibre pre-treatment and mixing; It is characterized in that: the pre-treatment of described bamboo shoot case fibre is meant the silane coupling agent KH-570 physical mixed of bamboo shoot shell powder and proportional quantity, the described mixing PVC of proportional quantity, pretreated bamboo shoot case fibre, paraffin, the Ca (HCO of being meant
3)
2, ethylene acrylic acid co polymer and dibasic lead stearate disperse 10min at the high speed kneader earlier under rotating speed 1200rpm, 60 ℃ of conditions of temperature, extrude under 180 ℃ of temperature through twin screw extruder then.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102316458A CN101885884B (en) | 2010-07-15 | 2010-07-15 | Bamboo shell fiber/PVC composite material and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2010102316458A CN101885884B (en) | 2010-07-15 | 2010-07-15 | Bamboo shell fiber/PVC composite material and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101885884A CN101885884A (en) | 2010-11-17 |
| CN101885884B true CN101885884B (en) | 2012-06-13 |
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|---|---|---|---|
| CN2010102316458A Expired - Fee Related CN101885884B (en) | 2010-07-15 | 2010-07-15 | Bamboo shell fiber/PVC composite material and preparation method thereof |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102276896A (en) * | 2011-06-24 | 2011-12-14 | 合肥工业大学 | Bamboo shoot shell fiber/PE degradable composite material and preparation method thereof |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102408646A (en) * | 2001-09-25 | 2012-04-11 | 埃克森美孚化学专利公司 | Plasticised polyvinyl chloride |
| CN101173079B (en) * | 2007-10-19 | 2010-04-14 | 东北林业大学 | A kind of wood fiber-polyvinyl chloride composite material and preparation method thereof |
| CN101481477B (en) * | 2009-01-31 | 2011-05-04 | 戴福寿 | Wood-plastic material and preparation thereof |
| CN101747645B (en) * | 2009-04-02 | 2012-01-11 | 张义卿 | Method for preparing bamboo plastic composite material |
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