CN101880987A - Low-carbon wallpaper paint and preparation method thereof - Google Patents
Low-carbon wallpaper paint and preparation method thereof Download PDFInfo
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- CN101880987A CN101880987A CN201010207443XA CN201010207443A CN101880987A CN 101880987 A CN101880987 A CN 101880987A CN 201010207443X A CN201010207443X A CN 201010207443XA CN 201010207443 A CN201010207443 A CN 201010207443A CN 101880987 A CN101880987 A CN 101880987A
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- 239000003973 paint Substances 0.000 title claims abstract description 32
- 229910052799 carbon Inorganic materials 0.000 title claims abstract description 30
- 238000002360 preparation method Methods 0.000 title claims description 11
- 239000013530 defoamer Substances 0.000 claims abstract description 33
- 239000002562 thickening agent Substances 0.000 claims abstract description 29
- 239000000839 emulsion Substances 0.000 claims abstract description 20
- 230000000844 anti-bacterial effect Effects 0.000 claims abstract description 14
- 239000002904 solvent Substances 0.000 claims abstract description 14
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003899 bactericide agent Substances 0.000 claims abstract description 13
- 229920001296 polysiloxane Polymers 0.000 claims abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 11
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000002270 dispersing agent Substances 0.000 claims abstract description 9
- 239000000080 wetting agent Substances 0.000 claims abstract description 9
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 7
- 239000010703 silicon Substances 0.000 claims abstract description 7
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 6
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 6
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000004408 titanium dioxide Substances 0.000 claims abstract description 5
- 239000000843 powder Substances 0.000 claims abstract description 4
- 150000002895 organic esters Chemical class 0.000 claims abstract 5
- 239000003795 chemical substances by application Substances 0.000 claims description 35
- 239000000463 material Substances 0.000 claims description 23
- 238000003756 stirring Methods 0.000 claims description 21
- -1 lauryl alcohol ester Chemical class 0.000 claims description 15
- 230000002087 whitening effect Effects 0.000 claims description 11
- 239000002480 mineral oil Substances 0.000 claims description 10
- 235000010446 mineral oil Nutrition 0.000 claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 9
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000004814 polyurethane Substances 0.000 claims description 8
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000003513 alkali Substances 0.000 claims description 6
- ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical group O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000011256 inorganic filler Substances 0.000 claims description 6
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 6
- 230000008961 swelling Effects 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 3
- 239000004354 Hydroxyethyl cellulose Substances 0.000 claims description 3
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 claims description 3
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 claims description 3
- 239000002253 acid Substances 0.000 claims description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 3
- 230000002209 hydrophobic effect Effects 0.000 claims description 3
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 claims description 3
- 239000001863 hydroxypropyl cellulose Substances 0.000 claims description 3
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 3
- 229920000058 polyacrylate Polymers 0.000 claims description 3
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 3
- 239000002781 deodorant agent Substances 0.000 claims 6
- 239000000203 mixture Substances 0.000 claims 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims 2
- 230000000855 fungicidal effect Effects 0.000 claims 2
- 239000000417 fungicide Substances 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- 150000001412 amines Chemical class 0.000 claims 1
- 239000011737 fluorine Substances 0.000 claims 1
- 229910052731 fluorine Inorganic materials 0.000 claims 1
- 239000000377 silicon dioxide Substances 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 4
- 238000004383 yellowing Methods 0.000 abstract description 3
- 239000000306 component Substances 0.000 description 36
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 12
- 239000010408 film Substances 0.000 description 12
- 238000005282 brightening Methods 0.000 description 6
- 239000000796 flavoring agent Substances 0.000 description 5
- 235000019634 flavors Nutrition 0.000 description 5
- 239000012530 fluid Substances 0.000 description 4
- 239000002002 slurry Substances 0.000 description 4
- 238000005034 decoration Methods 0.000 description 3
- 239000004922 lacquer Substances 0.000 description 3
- 239000011863 silicon-based powder Substances 0.000 description 3
- 235000010215 titanium dioxide Nutrition 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 2
- 238000009825 accumulation Methods 0.000 description 2
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000003115 biocidal effect Effects 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical class [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000011164 primary particle Substances 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 238000010186 staining Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
本发明公开了一种低碳壁纸漆，其包括以下重量份的组成成分，A组分：增稠剂0.2～0.3份、分散剂4～7份、消泡剂0.1～0.3份、成膜剂1.5～2.5份、杀菌剂0.1～0.2份、润湿剂0.1～0.2份、溶剂1～2份、水15～20份；B组分：粉料4～7份、钛白粉10～15份、高岭土2～5份、硅微粉4～7份；C组分：乳液40～60份、消泡剂0.1～0.2份、成膜剂0.2～0.4份、非硅酮有机酯类消泡剂0.1～0.2份。该低碳壁纸漆达到了国际环保标准，能有效弥盖墙面细裂纹，并具有优异的耐擦洗性能和抗黄变性能，使用寿命长。The invention discloses a low-carbon wallpaper paint, which comprises the following components in parts by weight: component A: 0.2-0.3 parts of thickener, 4-7 parts of dispersant, 0.1-0.3 parts of defoamer, 1.5-2.5 parts of film former, 0.1-0.2 parts of bactericide, 0.1-0.2 parts of wetting agent, 1-2 parts of solvent, 15-20 parts of water; component B: 4-7 parts of powder, 10-15 parts of titanium dioxide, 2-5 parts of kaolin, 4-7 parts of silicon micropowder; component C: 40-60 parts of emulsion, 0.1-0.2 parts of defoamer, 0.2-0.4 parts of film former, 0.1-0.2 parts of non-silicone organic ester defoamer. The low-carbon wallpaper paint meets international environmental protection standards, can effectively cover fine cracks on the wall, has excellent scrub resistance and anti-yellowing performance, and has a long service life.
Description
Technical field
The present invention relates to a kind of wallpaper paint, relate in particular to a kind of low carbon wallpaper paint, the invention still further relates to the preparation method of this low carbon wallpaper paint.
Background technology
At present, be used for the wall finiss of indoor wall, be common synthetic resin emulsion paint at building field.Descended though these wall finisses can change indoor vision, beautified indoor environment, can also keep the body of wall neat and tidy, and hid the metope flaw, and had anti-staining property, abrasion resistance, antibacterial and mouldproof, can carry out secondary decoration.But existing wall finiss color is single, can not coat on the wallpaper, can only present plane texture at interior decoration, and is not suitable for moist space such as toilet, has only the service life in 5～10 years short.
Wallpaper has composite color and match volume, can change at any time as required, and is very easy to use.But its surface is a plastic material, is easy to generate seam and not environmental protection, can not carry out secondary decoration, and is not suitable for moist spaces such as toilet.
Summary of the invention
First purpose of the present invention provides a kind of low carbon wallpaper paint.This low carbon wallpaper paint has reached international environmental protection standard, can effectively cover metope hair check, and has excellent scrub performance and yellowing resistance energy, long service life.
Second purpose of the present invention provides the preparation method of above-mentioned low carbon wallpaper paint.
First purpose of the present invention is to realize by following technical measures: a kind of low carbon wallpaper paint, and it comprises the constituent of following weight portion:
The A component:
4～7 parts of 0.2～0.3 part of dispersants of thickener
1.5～2.5 parts of 0.1～0.3 part of film forming agents of defoamer
0.1～0.2 part of 0.1～0.2 part of wetting agent of bactericide
15～20 parts in 1～2 part of water of solvent;
The B component:
10～15 parts of 4～7 parts of titanium dioxides of inorganic filler
4～7 parts of 2～5 parts of silicon powders of kaolin;
The C component:
0.1～0.2 part of 40～60 parts of defoamer of emulsion
0.1～0.2 part of 0.2～0.4 part of non-silicone organosilane ester defoamer of film forming agent.
For the paint film appearance that strengthens the paper lacquer and be coated with brushing effects, the present invention can do following improvement, and promptly it also comprises following D component,
0.01～0.02 part of 0.2～0.5 part of eliminating smell agent of alkali swelling thickener
0.1～0.3 part of 0.4～0.7 part of polyurethane thickener of brightening agent
0.4～0.8 part in 0.4～0.7 part of water of solvent.
The defoamer of described A component is selected the siliceous thing of mineral oil based for use, and for example CF38, VG-508 perhaps select non-silicone organosilane ester for use, for example SN-DEFOAMER JK.
The thickener of described A component is selected hydroxyethylcellulose or hydroxypropyl cellulose for use.
The bactericide of described A component is selected bactericide HF or bactericide KSG-105S for use.
The dispersant of described A component is selected polycarboxylic acids amine for use, Sodium Polyacrylate or ammonium polyacrylate.
The wetting agent of described A component is selected X-405 or WET-991 for use.
The film forming agent of described A component is selected TEXANOL or 12 carbon alcohol esters for use.
Antimonous oxide or aluminium hydroxide are selected in the inorganic filler of described B component for use.
The emulsion of described C component is selected organic silicon emulsion for use, for example RS996AD, WGS-422 etc., perhaps acrylic emulsion, for example RS2806, VGA-261 etc., perhaps Organic fluoride emulsion, for example 9F-08, PF-1.
The film forming agent of described C component is selected 12 carbon alcohol ester or Texanol for use.
The defoamer of described C component is selected for use and is contained hydrophobic particles mineral oil, for example SPA-202, VG-103 or A10, the perhaps siliceous thing of mineral oil based, for example CF38, VG-508; Non-silicone organosilane ester defoamer is selected SN-DEFOAMERJK or SN-DEFOAMER 399 for use.
The alkali swelling thickener of described D component is selected RS9600 or TT-935 for use, and the polyurethane thickener of described D component is selected SN-THICKENER 612 or LS-020 for use.
The brightening agent of described D component is selected for use and is brightened slurry T50, brightens slurry YH-1001, whitening fluid Y-06 or whitening fluid APC.
The eliminating smell agent of described D component is selected emulsifying essence, essence, Eradicates flavor agent 732 or Eradicates flavor agent DX for use.
The solvent of described A component and D component is selected ethylene glycol or propylene glycol for use.
The preparation method of above-mentioned low carbon wallpaper paint, it may further comprise the steps:
(1) thickener in the A component, dispersant, defoamer, film forming agent, bactericide, wetting agent, solvent and water are stirred;
(2) be added into powder, titanium dioxide, kaolin and silicon powder in the B component while stirring successively in step (1) stirs the material of gained, stir, the fineness of dispersed material avoids causing the accumulation of material;
(3) in stirring the material of gained, step (2) is added into emulsion, defoamer, film forming agent and non-silicone organosilane ester defoamer in the C component while stirring;
(4) elder generation mixes polyurethane thickener, solvent and part water in the D group and obtains D1 solution, obtain D2 solution with what the alkali swelling thickener in the D component and remaining water mixed, slowly add eliminating smell agent and the brightening agent that in step (3), adds while stirring in the material of gained then in D1 solution, D2 solution and the D component successively, promptly obtain low carbon wallpaper paint after mixing.
The fineness with material in the described step (3) is dispersed in 30～50 micrometer ranges, enters next step then.Or the time of the fineness of the dispersed material in described step (3) be controlled between 50～70 minutes, enter next step then.Increase the paint film feel thereby make material reach desirable primary particle state, improve covering power.
Add the eliminating smell agent and brightening agent in D1 solution, D2 solution and the D component in the described step (4) in the material of gained while stirring in step (3) after, the time of mixing is controlled in 10～15 minutes scopes.
The present invention compared with prior art has following beneficial effect:
(1) low carbon wallpaper paint provided by the invention has and has reached international environmental protection standard, and VOC content is low, and it is antibiotic to distinguish the flavor of only, and can initiatively discharge the pure natural anion, is of value to physically and mentally healthy.
(2) low carbon wallpaper paint provided by the invention can effectively cover metope hair check, and has excellent scrub performance and yellowing resistance energy, and long service life can be used in various occasions, and can be applied on the wallpaper.But also can develop the product of many different styles at the individual sexual demand of different crowd, as have the color elaboration lacquer of skill of magnificent decorative effect, play the intelligent wall artistic paint of the moulding effect of metope, and the children's inspiration lacquer that helps developing children's imagination.
Table 1 the present invention and emulsion paint and wallpaper (wall paper or wall cloth) contrast table
(3) preparation method of the present invention is simple, and convenient, cost is low, is fit to extensive use.
The specific embodiment
Set forth content of the present invention by the following examples in further detail, but following embodiment just is used for content of the present invention is set forth, rather than restriction, therefore in implication suitable and any change in the scope, all should think to be included in the scope of claims with claims of the present invention.
In following examples one to five, in the A component, defoamer is selected the siliceous thing CF38 of mineral oil based for use, and perhaps the siliceous thing VG-508 of mineral oil based perhaps selects non-silicone organosilane ester SN-DEFOAMER JK for use; Thickener is selected hydroxyethylcellulose or hydroxypropyl cellulose for use; Bactericide is selected bactericide HF or bactericide KSG-105S for use; Dispersant is selected polycarboxylic acids amine, Sodium Polyacrylate or ammonium polyacrylate for use; Wetting agent is selected X-405 or WET-991 for use; Film forming agent is selected TEXANOL or 12 carbon alcohol esters for use.
In the B component, antimonous oxide or aluminium hydroxide are selected in inorganic filler for use.
In the C component, emulsion is selected organic silicon emulsion for use, for example RS996AD, WGS-422 etc., perhaps acrylic emulsion, for example RS2806, VGA-261 etc., perhaps Organic fluoride emulsion, for example 9F-08, PF-1 etc.; Film forming agent is selected 12 carbon alcohol ester or Texanol for use; Defoamer is selected for use and is contained hydrophobic particles mineral oil, for example SPA-202, VG-103 or A10 etc., the perhaps siliceous thing of mineral oil based, for example CF38, VG-508 etc.; Non-silicone organosilane ester defoamer is selected SN-DEFOAMER JK or SN-DEFOAMER 399 for use.
In the D component, alkali swelling thickener is selected RS9600 or TT-935 for use; Polyurethane thickener is selected SN-THICKENER 612 or LS-020 for use; Brightening agent is selected for use and is brightened slurry T50, brightens slurry YH-1001, whitening fluid Y-06 or whitening fluid APC; Eliminating smell agent is selected emulsifying essence, essence, Eradicates flavor agent 732 or Eradicates flavor agent DX for use.
Solvent in A component and the D component is selected ethylene glycol or propylene glycol for use.
The preparation method:
(1) thickener in the A component, dispersant, defoamer, film forming agent, bactericide, wetting agent, solvent and water are stirred;
(2) be added into powder, titanium dioxide, kaolin and silicon powder in the B component while stirring successively in step (1) stirs the material of gained, stir, the fineness to 50 of dispersed material micron avoids causing the accumulation of material;
(3) in stirring the material of gained, step (2) is added into emulsion, defoamer, film forming agent and non-silicone organosilane ester defoamer in the C component while stirring;
(4) elder generation mixes polyurethane thickener, solvent and part water in the D group and obtains D1 solution, obtain D2 solution with what the alkali swelling thickener thickener in the D group and remaining water mixed, in step (3), add eliminating smell agent and brightening agent in D1 solution, D2 solution and the D component then in the material of gained while stirring, stirred 10 minutes, and promptly obtained low carbon wallpaper paint after mixing.
In preparation method of the present invention, fineness to 30～50 of dispersed material micron in the step (3), perhaps the time of the fineness of dispersed material was controlled between 50～70 minutes; The time of mixing in the step (4) is controlled in 10～15 minutes scopes, all can realize purpose of the present invention.
Claims (10)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010207443XA CN101880987A (en) | 2010-06-19 | 2010-06-19 | Low-carbon wallpaper paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201010207443XA CN101880987A (en) | 2010-06-19 | 2010-06-19 | Low-carbon wallpaper paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101880987A true CN101880987A (en) | 2010-11-10 |
Family
ID=43053114
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201010207443XA Pending CN101880987A (en) | 2010-06-19 | 2010-06-19 | Low-carbon wallpaper paint and preparation method thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN101880987A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102010228A (en) * | 2010-11-15 | 2011-04-13 | 上海贝恒化学建材有限公司 | Outer wall sealing impervious interface agent and preparing method thereof |
| CN102020921A (en) * | 2010-12-20 | 2011-04-20 | 贺佑康 | Low carbon humidity control function coating |
| CN102942830A (en) * | 2012-12-06 | 2013-02-27 | 浙江工商大学 | Water-resistant peeling-resistant paint for construction and preparation method thereof |
| CN103911914A (en) * | 2014-03-31 | 2014-07-09 | 宋旭 | Environment-friendly humidifying wallpaper and preparation method thereof |
| CN104559426A (en) * | 2014-12-30 | 2015-04-29 | 三棵树涂料股份有限公司 | Production technology of water-based woodware varnish |
| CN105297552A (en) * | 2015-11-02 | 2016-02-03 | 自贡市华尔美科技有限公司 | Preparation method of damp-proof water-based crack wallpaper |
| CN105505176A (en) * | 2016-01-29 | 2016-04-20 | 哈尔滨绿科科技有限公司 | Liquid state wallpaper and imposing process |
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| WO2008060006A1 (en) * | 2006-11-14 | 2008-05-22 | Han-Kook National Corp. | Method for paints with urushi lacquer using paper and paper and wall paper coated the paints thereof |
| CN101440231A (en) * | 2007-11-20 | 2009-05-27 | 陈莹 | Nano mercerization multicolor paint for wallpaper and wall painting |
| CN101481585A (en) * | 2009-01-19 | 2009-07-15 | 太原市伦嘉生物工程科技有限公司 | Tourmaline gloss oil and preparation thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102010228A (en) * | 2010-11-15 | 2011-04-13 | 上海贝恒化学建材有限公司 | Outer wall sealing impervious interface agent and preparing method thereof |
| CN102010228B (en) * | 2010-11-15 | 2015-05-06 | 上海贝恒化学建材有限公司 | Outer wall sealing impervious interface agent and preparing method thereof |
| CN102020921A (en) * | 2010-12-20 | 2011-04-20 | 贺佑康 | Low carbon humidity control function coating |
| CN102942830A (en) * | 2012-12-06 | 2013-02-27 | 浙江工商大学 | Water-resistant peeling-resistant paint for construction and preparation method thereof |
| CN103911914A (en) * | 2014-03-31 | 2014-07-09 | 宋旭 | Environment-friendly humidifying wallpaper and preparation method thereof |
| CN104559426A (en) * | 2014-12-30 | 2015-04-29 | 三棵树涂料股份有限公司 | Production technology of water-based woodware varnish |
| CN105297552A (en) * | 2015-11-02 | 2016-02-03 | 自贡市华尔美科技有限公司 | Preparation method of damp-proof water-based crack wallpaper |
| CN105297552B (en) * | 2015-11-02 | 2017-11-14 | 福建品派包装有限公司 | A kind of preparation method of the water-based crackle wallpaper of protection against the tide |
| CN105505176A (en) * | 2016-01-29 | 2016-04-20 | 哈尔滨绿科科技有限公司 | Liquid state wallpaper and imposing process |
| CN105505176B (en) * | 2016-01-29 | 2018-04-27 | 哈尔滨绿科科技有限公司 | A kind of liquid wallpaper and layout technique |
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Application publication date: 20101110 |