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CN101851946B - Water generating method by utilizing separating membrane to enrich air water vapor and device thereof - Google Patents

Water generating method by utilizing separating membrane to enrich air water vapor and device thereof Download PDF

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CN101851946B
CN101851946B CN2010101757538A CN201010175753A CN101851946B CN 101851946 B CN101851946 B CN 101851946B CN 2010101757538 A CN2010101757538 A CN 2010101757538A CN 201010175753 A CN201010175753 A CN 201010175753A CN 101851946 B CN101851946 B CN 101851946B
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冯诗愚
高秀峰
李云
王赞社
侯雄坡
顾兆林
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Nanjing University of Aeronautics and Astronautics
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Abstract

本发明公开了一种利用分离膜富集空气水蒸气的制水方法和装置,该制水方法采用膜除湿组件、运用压缩法进行空气的除湿处理,再通过管道向膜除湿组件的水蒸气渗透侧输入吹扫气实现水蒸气的富集,最后对前述富集水蒸气的高湿度吹扫气进行冷凝,即可获得液态或者固态水,因此,本发明与吸附方法相比,工作过程连续、无腐蚀问题、易维护、能耗低;所采用的制冷工质为空气,不存在污染问题,加之压缩机和膨胀机均为离心式机械,转速高,因此单位产水量下设备体积小重量轻;同时,为了提高系统性能,将主制水器冷侧通道出口的低温水蒸气冷却介质再次引入辅制水器冷侧通道,以对来自大气环境的空气降温,获得额外水量。

Figure 201010175753

The invention discloses a water production method and device for enriching air water vapor by using a separation membrane. The water production method adopts a membrane dehumidification component, uses a compression method to perform air dehumidification treatment, and then penetrates into the water vapor of the membrane dehumidification component through a pipeline. The side input purge gas realizes the enrichment of water vapor, and finally condenses the aforementioned high-humidity purge gas enriched with water vapor to obtain liquid or solid water. Therefore, compared with the adsorption method, the present invention has a continuous working process, No corrosion problem, easy maintenance, low energy consumption; the refrigerant used is air, so there is no pollution problem, and the compressor and expander are both centrifugal machines with high speed, so the equipment is small in size and light in weight per unit of water production ; At the same time, in order to improve system performance, the low-temperature water vapor cooling medium at the outlet of the cold side channel of the main water generator is reintroduced into the cold side channel of the auxiliary water generator to cool the air from the atmospheric environment and obtain additional water.

Figure 201010175753

Description

利用分离膜富集空气水蒸气的制水方法和装置Water production method and device for enriching air water vapor by using separation membrane

技术领域 technical field

本发明属于减湿技术领域,涉及一种制水方法及其装置,特别涉及一种利用分离膜从空气中制取液态水的方法和装置。  The invention belongs to the technical field of dehumidification, and relates to a water production method and a device thereof, in particular to a method and a device for producing liquid water from air by using a separation membrane. the

背景技术Background technique

人们在野外干旱地区,特别在是沙漠地区长期工作时,淡水供应是在此类地区所有活动的先决条件,一般水的取得方式主要是依靠少量的降雨蓄积或者由基地补给,因此所获取的水量不稳定或者费用高。事实上,空气中含有一定量的水蒸气,例如撒哈拉沙漠的全年平均相对湿度在20~30%左右,夜晚空气中的湿度更大,如果能够采用一定的方法和装置,将空气中的水蒸气转化为液态水,则可供长期在于旱地区工作的人们使用,特别适合野外科考站、边境兵站等。  When people work in arid areas, especially in desert areas for a long time, fresh water supply is a prerequisite for all activities in such areas. Generally, the way to obtain water is mainly to rely on a small amount of rainfall accumulation or replenishment from the base, so the amount of water obtained Unstable or expensive. In fact, the air contains a certain amount of water vapor. For example, the annual average relative humidity of the Sahara Desert is about 20-30%, and the humidity in the air at night is even greater. The steam is converted into liquid water, which can be used by people who work in dry areas for a long time, especially suitable for field research stations, border military stations, etc. the

将水蒸气转化为液态水的唯一方法就是冷凝,但是通常采用以下两大类做法,第一类是直接将空气降温,达到露点温度以下,空气中的水蒸气就会转化为液态水或者固态冰(霜),此类方法虽然原理简单,但是由于需要对干空气和水蒸气整体降温,而降温后的干空气实际是无用的,且空气中水蒸气含量越低,则露点温度也越低,因此能耗十分巨大;另外一类是首先将空气中的水蒸气富集,然后再冷凝,例如采用吸附方法,使空气通过吸附材料,空气中的水蒸气附着在吸附剂上直至达到一定的浓度,然后再对吸附剂加热,水蒸气就扩散到空气中,这时空气中的水蒸气含量很高,露点温度也较高,因此将空气中水蒸气转化为液态水所需的冷量也会减少,因此先对空气中的水蒸气进行分离达到富集的目的,再采用冷凝方法转化为液态水是一种较好的过程。  The only way to convert water vapor into liquid water is to condense, but the following two methods are usually used. The first type is to directly cool the air below the dew point temperature, and the water vapor in the air will be converted into liquid water or solid ice. (Frost), although the principle of this type of method is simple, but due to the need to cool down the dry air and water vapor as a whole, the dry air after cooling is actually useless, and the lower the water vapor content in the air, the lower the dew point temperature. Therefore, the energy consumption is very huge; the other type is to enrich the water vapor in the air first, and then condense it, such as using an adsorption method to make the air pass through the adsorption material, and the water vapor in the air is attached to the adsorbent until it reaches a certain concentration , and then heat the adsorbent, and the water vapor will diffuse into the air. At this time, the water vapor content in the air is very high, and the dew point temperature is also high, so the cooling capacity required to convert the water vapor in the air into liquid water will also increase. Therefore, it is a better process to separate the water vapor in the air to achieve the purpose of enrichment, and then convert it into liquid water by condensation. the

但是,吸附剂再生过程比较麻烦,再生过程需要消耗大量的热能,特别是当空气中水蒸气含量较低时,获取一定量的水,需要有大量的空气通过吸附剂,因此吸附设备的体积也十分庞大,而且为了保证制水过程的连续,吸附过程和再生过程均各需要一套设备,两者交替运行,这无疑进一步增加了设备的体积重量。  However, the regeneration process of the adsorbent is cumbersome, and the regeneration process needs to consume a lot of heat energy, especially when the water vapor content in the air is low, to obtain a certain amount of water, a large amount of air needs to pass through the adsorbent, so the volume of the adsorption equipment is also large. It is very large, and in order to ensure the continuity of the water production process, each of the adsorption process and the regeneration process requires a set of equipment, and the two operate alternately, which undoubtedly further increases the volume and weight of the equipment. the

发明内容Contents of the invention

本发明的目的在于克服吸附法富集水蒸气制水的技术缺点,提供一种利用分离膜富集空气中的水蒸气,再通过对富集气体降温从而制造液体水的方法。  The purpose of the present invention is to overcome the technical disadvantage of enriching water vapor by adsorption method to produce water, and provide a method of using separation membrane to enrich water vapor in the air, and then cooling the enriched gas to produce liquid water. the

本发明的目的是通过以下技术方案来解决的:  The purpose of the present invention is to solve through the following technical solutions:

一种利用分离膜富集空气水蒸气的制水方法,包括以下步骤:(1)空气预处理采用空气滤清器、压缩机对空气进行除杂、压缩;(2)空气水蒸气的分离处理  采用膜除湿组件对经过步骤(1)处理的压缩空气进行除湿处理以获得分别处于膜两侧的除湿空气和水蒸气;(3)冷凝水凝聚  采用吹扫气法,将吹扫气引入步骤(2)中膜除湿组件的水蒸气渗透侧,进行膜壁表面上的水蒸气扫除,以获得高湿度吹扫气,实现空气水蒸气的富集;同时将步骤(2)获得的除湿空气依次经过冷却、膨胀后作为水蒸气冷却介质,对所获得的高湿度吹扫气进行冷凝,获得冷凝水;(4)冷凝水收集经步骤(3)处理后的冷凝水,若为液态水,直接通过水泵泵入水箱;若为固态水,先采用解冻介质将冷凝水融化为液态水后,再通过水泵泵入水箱。  A method for producing water by using a separation membrane to enrich air water vapor, comprising the following steps: (1) air pretreatment using an air filter and a compressor to remove impurities and compress the air; (2) separation treatment of air water vapor Use membrane dehumidification components to dehumidify the compressed air treated in step (1) to obtain dehumidified air and water vapor on both sides of the membrane; (3) condensed water condensation Use the sweeping gas method to introduce the sweeping gas into the step ( 2) The water vapor permeation side of the middle membrane dehumidification module sweeps the water vapor on the surface of the membrane wall to obtain high-humidity purge gas and realize the enrichment of air water vapor; at the same time, the dehumidified air obtained in step (2) passes through After cooling and expansion, it is used as a water vapor cooling medium to condense the obtained high-humidity purge gas to obtain condensed water; (4) the condensed water is collected from the condensed water treated in step (3), if it is liquid water, directly pass through The water pump is pumped into the water tank; if it is solid water, the condensed water is first melted into liquid water with a thawing medium, and then pumped into the water tank through the water pump. the

进一步地,步骤(3)中所用的吹扫气来源于除湿空气,其使用量占除湿空气的质量份数为10~30%。  Further, the sweeping gas used in step (3) is derived from dehumidified air, and its usage is 10-30% of the mass fraction of the dehumidified air. the

进一步地,步骤(4)中的解冻介质为经过步骤(1)预处理后的压缩空气。  Further, the thawing medium in step (4) is compressed air pretreated in step (1). the

进一步地,在步骤(3)中,水蒸气冷却介质对高湿度吹扫气冷却后,作为二次冷却介质,再次对经过空气滤清器除杂处理的辅制水除杂空气进行冷却,以获得液态或者固态水;同时,对辅制水除杂空气进行冷却后的二次冷却介质,再次作为压缩空气冷却介质,进行步骤(3)中压缩空气的冷却。  Further, in step (3), after the water vapor cooling medium cools the high-humidity purge gas, it is used as a secondary cooling medium to cool the auxiliary water-cleaned air that has been treated by the air filter to remove impurities again, so as to Liquid or solid water is obtained; at the same time, the secondary cooling medium after cooling the auxiliary water and impurity-removing air is used as the compressed air cooling medium again to cool the compressed air in step (3). the

本发明的另一发明目的是提供一种实现上述利用分离膜富集空气水蒸气的制水方法的制水装置,其采用膜除湿组件、运用压缩法进行空气的除湿处理,再通过管道向膜除湿组件的水蒸气渗透侧输入吹扫气实现水蒸气的富集,最后对前述富集水蒸气的高湿度吹扫气进行冷凝,即可获得液态或者固态水。  Another object of the present invention is to provide a water production device that realizes the above-mentioned water production method that utilizes separation membranes to enrich air water vapor. The water vapor permeation side of the dehumidification component inputs the purge gas to realize the enrichment of water vapor, and finally condenses the aforementioned high-humidity purge gas enriched in water vapor to obtain liquid or solid water. the

为实现以上的技术目的,本发明将采取以下的技术方案:  For realizing above technical purpose, the present invention will take following technical scheme:

一种利用分离膜富集空气水蒸气的制水装置,包括空气主制水装置,该空气主制水装置包括主制水空气预处理装置、膜除湿组件、吹扫气减压阀、除湿空气预冷器、除湿空气膨胀机、吹扫气预冷器、主制水器以及水箱,所述主制水空气预处理装置包括顺序连接的主制水空气滤清器和主制水空气压缩机,所述主制水空气滤清器的进气口与外界空气接通,所述膜除湿组件的高压进气口与主制水空气压缩机的出气口连接,而膜除湿组件的高压出气口、除湿空气预冷器的热侧通道、除湿空气膨胀机以及主制水机的冷侧通道进口则依次顺序连接,同时,吹扫气减压阀的出气口、膜除湿组件的低压进气侧、吹扫气预冷器的热侧通道、主制水机的热侧通道以及水箱依次顺序连接,且吹扫气减压阀的进气口与吹扫气输送管连通,另外,除湿空气预冷器和吹扫气预冷器的冷侧通道皆有冷却介质流通。  A water production device that utilizes a separation membrane to enrich air water vapor, comprising an air main water production device, the air main water production device includes a main water production air pretreatment device, a membrane dehumidification component, a purge gas pressure reducing valve, a dehumidified air Precooler, dehumidifying air expander, purge gas precooler, main water generator and water tank, the main water air pretreatment device includes main water air filter and main water air compressor connected in sequence , the air inlet of the main water-making air filter is connected with the outside air, the high-pressure air inlet of the membrane dehumidification component is connected with the air outlet of the main water-making air compressor, and the high-pressure gas outlet of the membrane dehumidification component , the hot side channel of the dehumidifying air precooler, the dehumidifying air expander and the inlet of the cold side channel of the main water generator are connected sequentially. , the hot side channel of the purge gas precooler, the hot side channel of the main water generator, and the water tank are connected in sequence, and the air inlet of the purge gas pressure reducing valve is connected with the purge gas delivery pipe. In addition, the dehumidification air pre-cooler Cooling medium flows through the cold side channels of the cooler and the purge gas precooler. the

进一步地,所述主制水空气压缩机与主制水器热侧通道连通,且主制水空气压缩机与主制水器热侧通道之间的连接管道上安装有主制水器除霜阀,同时主制水空气压缩机与膜 除湿组件的高压进气口之间的连接管道上连接有截止阀。  Further, the main water making air compressor is in communication with the hot side channel of the main water making device, and the connecting pipe between the main water making air compressor and the hot side channel of the main water making device is installed with a main water making device defrosting At the same time, there is a shut-off valve connected to the connecting pipe between the main water air compressor and the high-pressure air inlet of the membrane dehumidification component. the

进一步地,还包括空气辅制水装置,该空气辅制水装置包括辅制水空气引风机、辅制水空气滤清器以及辅制水器,所述辅制水空气引风机与外界空气接通,且辅制水空气引风机、辅制水空气滤清器、辅制水器热侧通道以及水箱依次顺序连接,同时,主制水器的冷侧通道出口与辅制水器的冷侧通道入口相连接。  Further, it also includes an air-assisted water-making device, the air-assisted water-making device includes an auxiliary water-making air-induced fan, an auxiliary water-air filter and an auxiliary water-making device, and the auxiliary water-making air-induced fan is in contact with the outside air. and the auxiliary water air induced draft fan, auxiliary water air filter, auxiliary water heater hot side channel and water tank are connected sequentially. The channel entrances are connected. the

进一步地,所述主制水空气压缩机与辅制水器热侧通道连通,且主制水空气压缩机与辅制水器热侧通道之间的连接管道上安装有辅制水器除霜阀。  Further, the main water-making air compressor communicates with the hot-side channel of the auxiliary water-making device, and the connecting pipe between the main water-making air compressor and the hot-side channel of the auxiliary water-making device is installed with an auxiliary water-making device for defrosting valve. the

所述除湿空气预冷器和除湿空气膨胀机之间还连接有除湿空气冷却器,所述除湿空气冷却器的热侧通道分别与除湿空气预冷器的热侧通道出口以及空气膨胀机进气口连接,而除湿空气冷却器的冷侧通道进口则与辅制水器的冷侧通道出口连接。  A dehumidifying air cooler is also connected between the dehumidifying air precooler and the dehumidifying air expander, and the hot side channel of the dehumidifying air cooler is connected with the outlet of the hot side channel of the dehumidifying air precooler and the air inlet of the air expander respectively. The inlet of the cold side channel of the desiccant air cooler is connected with the outlet of the cold side channel of the auxiliary water heater. the

进一步地,所述吹扫气输送管与膜除湿组件的高压出气口连接。  Further, the sweeping gas delivery pipe is connected to the high-pressure gas outlet of the membrane dehumidification module. the

根据以上的技术方案,可以实现以下的有益效果:  According to the above technical scheme, the following beneficial effects can be achieved:

1、采用除湿膜对空气中的水蒸气进行分离,达到空气中水蒸气富集的目的,与吸附方法相比,工作过程连续、无腐蚀问题、易维护、能耗低;  1. The dehumidification membrane is used to separate the water vapor in the air to achieve the purpose of enriching the water vapor in the air. Compared with the adsorption method, the working process is continuous, there is no corrosion problem, easy to maintain, and low energy consumption;

2、采用开式空气制冷循环对水蒸气富集的空气降温,工质不存在污染问题、且可长期连续工作,加之压缩机和膨胀机均为离心式机械,转速高,因此单位体积和重量的装置,其产水量高;  2. The open air refrigeration cycle is used to cool the air enriched with water vapor. There is no pollution problem of the working fluid, and it can work continuously for a long time. In addition, the compressor and expander are both centrifugal machines with high speed, so the unit volume and weight device with high water yield;

3、用于在主制水器中降温的空气仍然具有较低温度,因此又设置了辅制水器,进一步回收冷量,提高装置运行的经济性。  3. The air used to cool down in the main water generator still has a relatively low temperature, so an auxiliary water generator is installed to further recover the cooling capacity and improve the economical efficiency of the device operation. the

附图说明 Description of drawings

图1是本发明所述制水装置的结构示意图;  Fig. 1 is the structural representation of water making device of the present invention;

其中,1为电动机;2为主制水空气滤清器;3为主制水空气压缩机;4为截止阀;5为膜除湿组件;6为吹扫气减压阀;7为除湿空气冷却介质引风机;8为除湿空气预冷器;9为除湿空气冷却器;10为除湿空气膨胀机;11为吹扫气预冷器;12为吹扫气冷却介质引风机;13为主制水器;14为主制水器除霜阀;15为辅制水器除霜阀;16为辅制水器;17为辅制水空气滤清器;18为辅制水空气引风机;19为水泵;20为水箱。  Among them, 1 is the motor; 2 is the main water air filter; 3 is the main water air compressor; 4 is the stop valve; 5 is the membrane dehumidification component; 6 is the purge gas pressure reducing valve; Medium induced fan; 8 is dehumidification air precooler; 9 is dehumidification air cooler; 10 is dehumidification air expander; 11 is purge gas precooler; 12 is purge air cooling medium induced fan; 13 is main water 14 is the defrosting valve of the main water maker; 15 is the defrosting valve of the auxiliary water maker; 16 is the auxiliary water maker; 17 is the auxiliary water air filter; 18 is the auxiliary water air induced draft fan; 19 is Water pump; 20 is a water tank. the

具体实施方式 Detailed ways

附图非限制性地公开了本发明的一个优选实施例,以下将结合附图详细地说明本发明的技术方案。  The accompanying drawings disclose a preferred embodiment of the present invention without limitation, and the technical solution of the present invention will be described in detail below in conjunction with the accompanying drawings. the

本发明所述的利用分离膜富集空气水蒸气的制水方法,包括以下步骤:(1)空气预处 理采用空气滤清器、压缩机对空气进行除杂、压缩;(2)空气水蒸气的分离处理采用膜除湿组件5对经过步骤(1)处理的压缩空气进行除湿处理以获得分别处于膜两侧的除湿空气和水蒸气;(3)冷凝水凝聚采用吹扫气法,将吹扫气引入步骤(2)中膜除湿组件5的水蒸气渗透侧,进行膜壁表面上的水蒸气扫除,以获得高湿度吹扫气,实现空气水蒸气的富集,所采用的吹扫气来源于步骤(2)获得的除湿空气,其使用量占除湿空气的质量份数为10~30%;同时将步骤(2)获得的除湿空气除去吹扫气份额后,余下部分依次经过冷却、膨胀后作为水蒸气冷却介质,对所获得的高湿度吹扫气进行冷凝,获得冷凝水,另外,水蒸气冷却介质对高湿度吹扫气冷却后,作为二次冷却介质,再次对经过空气滤清器除杂处理的辅制水除杂空气进行冷却,以获得液态或者固态水;同时,对辅制水除杂空气进行冷却后的二次冷却介质,再次作为压缩空气冷却介质,进行步骤(3)中压缩空气的冷却;(4)冷凝水收集  经步骤(3)处理后的冷凝水,若为液态水,直接通过水泵19泵入水箱20;若为固态水,先采用解冻介质将冷凝水融化为液态水后,再通过水泵19泵入水箱20,所述的解冻介质为经过步骤(1)预处理后的压缩空气。  The method for producing water utilizing a separation membrane to enrich air water vapor according to the present invention comprises the following steps: (1) air pretreatment adopts an air filter and a compressor to remove impurities and compress air; (2) air water For steam separation, the membrane dehumidification module 5 is used to dehumidify the compressed air treated in step (1) to obtain dehumidified air and water vapor on both sides of the membrane; Sweeping air is introduced into the water vapor permeation side of the membrane dehumidification module 5 in step (2), and the water vapor on the surface of the membrane wall is swept away to obtain high-humidity sweeping gas and realize the enrichment of air water vapor. The dehumidified air obtained in step (2) is used in an amount of 10-30% of the mass fraction of the dehumidified air; at the same time, the dehumidified air obtained in step (2) is removed from the purge gas, and the remaining part is sequentially cooled, After expansion, it is used as a water vapor cooling medium to condense the obtained high-humidity purge gas to obtain condensed water. In addition, after the water vapor cooling medium cools the high-humidity purge gas, it is used as a secondary cooling medium to condense the filtered air again. The auxiliary water and impurity-removing air of the cleaning device is cooled to obtain liquid or solid water; at the same time, the secondary cooling medium after cooling the auxiliary water and impurity-removing air is used as a compressed air cooling medium again, and the steps ( 3) cooling of compressed air; (4) condensed water collection If the condensed water treated in step (3) is liquid water, it is directly pumped into the water tank 20 through the water pump 19; After the water melts into liquid water, it is pumped into the water tank 20 through the water pump 19, and the thawing medium is compressed air pretreated in step (1). the

如图1所示,本发明所述利用分离膜富集空气水蒸气的制水装置,包括空气主制水装置,该空气主制水装置包括主制水空气预处理装置、膜除湿组件5、吹扫气减压阀6、除湿空气预冷器8、除湿空气膨胀机10、吹扫气预冷器11、主制水器13以及水箱20,所述主制水空气预处理装置包括顺序连接的主制水空气滤清器2和主制水空气压缩机3,所述主制水空气滤清器2的进气口与外界空气接通,所述膜除湿组件5的高压进气口与主制水空气压缩机3的出气口连接,而膜除湿组件5的高压出气口、除湿空气预冷器8的热侧通道、除湿空气膨胀机10以及主制水机的冷侧通道进口则依次顺序连接,同时,吹扫气减压阀6的出气口、膜除湿组件5的低压进气侧、吹扫气预冷器11的热侧通道、主制水机的热侧通道以及水箱20依次顺序连接,且吹扫气减压阀6的进气口与吹扫气输送管连通,另外,除湿空气预冷器8和吹扫气预冷器11的冷侧通道皆有冷却介质流通,所述除湿空气预冷器8和吹扫气预冷器11的冷侧通道进口分别通过管道与除湿空气冷却介质引风机7以及吹扫气冷却介质引风机12的引风口连接,而除湿空气预冷器8和吹扫气预冷器11的冷侧通道的出口均与外界环境连通。  As shown in Figure 1, the water production device utilizing the separation membrane to enrich air water vapor according to the present invention includes an air main water production device, the air main water production device includes a main water production air pretreatment device, a membrane dehumidification assembly 5, Sweep gas pressure reducing valve 6, dehumidification air pre-cooler 8, dehumidification air expander 10, purge gas pre-cooler 11, main water generator 13 and water tank 20, the main water air pretreatment device includes sequential connection The main water-air filter 2 and the main water-air compressor 3, the air inlet of the main water-air filter 2 is connected to the outside air, and the high-pressure air inlet of the membrane dehumidification assembly 5 is connected to the The air outlet of the main water-making air compressor 3 is connected, while the high-pressure air outlet of the membrane dehumidification module 5, the hot side channel of the dehumidifying air precooler 8, the dehumidifying air expander 10, and the inlet of the cold side channel of the main water machine are connected in sequence Sequentially connected, at the same time, the outlet of the purge gas pressure reducing valve 6, the low-pressure inlet side of the membrane dehumidification module 5, the hot side channel of the purge gas precooler 11, the hot side channel of the main water generator, and the water tank 20 in sequence connected in sequence, and the air inlet of the purge gas pressure reducing valve 6 is communicated with the purge gas delivery pipe. In addition, the cold side channels of the dehumidified air precooler 8 and the purge gas precooler 11 all have cooling medium circulating, so The cold side passage inlets of the dehumidified air precooler 8 and the purge air precooler 11 are respectively connected to the air inlets of the dehumidified air cooling medium induced draft fan 7 and the purge air cooling medium induced draft fan 12 through pipes, and the dehumidified air precooling The outlets of the cold side channels of the device 8 and the purge gas precooler 11 are all communicated with the external environment. the

由于采用主制水器13获得的冷凝水可能为固态水,因此,还需对这些固态水进行融化,才能引流到水箱20,所以本发明将主制水空气压缩机3与主制水器13热侧通道连通,且主制水空气压缩机3与主制水器13热侧通道之间的连接管道上安装有主制水器除霜阀14,同时主制水空气压缩机3与膜除湿组件5的高压进气口之间的连接管道上连接有截止阀4。  Since the condensed water obtained by the main water maker 13 may be solid water, it is necessary to melt the solid water before it can be diverted to the water tank 20, so the present invention combines the main water maker air compressor 3 with the main water maker 13 The hot side channel is connected, and the main water generator defrost valve 14 is installed on the connecting pipe between the main water generator air compressor 3 and the hot side channel of the main water generator 13, and the main water generator air compressor 3 and the membrane dehumidification A cut-off valve 4 is connected to the connection pipeline between the high-pressure air inlets of the assembly 5 . the

为进一步利用压缩空气膨胀机引出的作为主制水器13热侧通道中高湿度吹扫气的水蒸 气冷却介质的冷源,本发明还包括空气辅制水装置,该空气辅制水装置包括辅制水空气引风机18、辅制水空气滤清器17以及辅制水器16,所述辅制水空气引风机18与外界空气接通,且辅制水空气引风机18、辅制水空气滤清器17、辅制水器16热侧通道以及水箱20依次顺序连接,同时,主制水器13的冷侧通道出口与辅制水器16的冷侧通道入口相连接。同样,辅制水器16制出的冷凝也可能为固态水,因此,本发明将所述主制水空气压缩机3与辅制水器16热侧通道连通,且主制水空气压缩机3与辅制水器16热侧通道之间的连接管道上安装有辅制水器除霜阀16。  In order to further utilize the cooling source of the water vapor cooling medium drawn by the compressed air expander as the high-humidity purge gas in the hot side channel of the main water generator 13, the present invention also includes an air-assisted water production device, which includes Auxiliary water air induced fan 18, auxiliary water air filter 17 and auxiliary water device 16, said auxiliary water air induced fan 18 is connected with outside air, and auxiliary water air induced fan 18, auxiliary water The air filter 17 , the hot side channel of the auxiliary water generator 16 and the water tank 20 are sequentially connected, and at the same time, the outlet of the cold side channel of the main water generator 13 is connected with the inlet of the cold side channel of the auxiliary water generator 16 . Similarly, the condensation produced by the auxiliary water device 16 may also be solid water. Therefore, the present invention communicates the main water air compressor 3 with the hot side channel of the auxiliary water device 16, and the main water air compressor 3 A defrosting valve 16 of the auxiliary water device is installed on the connecting pipe with the hot side channel of the auxiliary water device 16 . the

因此,主制水器13热侧通道有两个进口和出口,所述主制水器13热侧通道的两个进口分别通过管道与吹扫气预冷器11热侧通道出口及主制水器除霜阀14出口连接,而该主制水器13热侧通道的两个出口均与大气环境连通,同样,所述辅制水器16热侧通道也有两个进口和出口,该辅制水器16热侧通道的两个进口分别与空气滤清器出口及辅制水器除霜阀16连接,而其两个出口则直接与大气环境连通。  Therefore, the hot side passage of the main water generator 13 has two inlets and two outlets, and the two inlets of the hot side passage of the main water generator 13 are respectively connected to the outlet of the hot side passage of the purge gas precooler 11 and the main water generator through pipelines. The outlet of the device defrosting valve 14 is connected, and the two outlets of the hot side channel of the main water generator 13 are connected with the atmosphere. Similarly, the hot side channel of the auxiliary water generator 16 also has two inlets and outlets. The two inlets of the hot side channel of the water heater 16 are respectively connected with the outlet of the air filter and the auxiliary water heater defrosting valve 16, while the two outlets thereof are directly connected with the atmospheric environment. the

另外,所述除湿空气预冷器8和除湿空气膨胀机10之间还连接有除湿空气冷却器9,所述除湿空气冷却器9的热侧通道分别与除湿空气预冷器8的热侧通道出气口以及空气膨胀机进气口连接,而除湿空气冷却器9的冷侧通道进口则与辅制水器16的冷侧通道出气口连接,且除湿空气冷却器9的冷侧通道出气口则与大气环境连通,由此可知,压缩空气膨胀机输出的水蒸气冷却介质得到了更彻底的利用,极大地节约了能源以及制水成本。  In addition, a dehumidification air cooler 9 is also connected between the dehumidification air precooler 8 and the dehumidification air expander 10, and the hot side passages of the dehumidification air cooler 9 are connected with the hot side passages of the dehumidification air precooler 8 respectively. The air outlet is connected with the air inlet of the air expander, and the cold side channel inlet of the dehumidification air cooler 9 is connected with the cold side channel air outlet of the auxiliary water tank 16, and the cold side channel air outlet of the dehumidification air cooler 9 is Connected to the atmospheric environment, it can be seen that the water vapor cooling medium output by the compressed air expander has been more thoroughly utilized, which greatly saves energy and water production costs. the

本发明所述的吹扫气直接来源于膜除湿组件5高压出气口输出的除湿空气,因此,本发明将所述吹扫气输送管与膜除湿组件5的高压出气口连接。  The purge gas in the present invention is directly derived from the dehumidified air output from the high-pressure air outlet of the membrane dehumidification module 5 , therefore, the present invention connects the purge gas delivery pipe to the high-pressure air outlet of the membrane dehumidification module 5 . the

详细地说,附图1中所述各部件之间的连接关系如下:  In detail, the connection relationship between the components described in accompanying drawing 1 is as follows:

主制水空气滤清器2进气口与大气环境直接连通,而主制水空气滤清器2出气口经管道与所述主制水空气压缩机3进气口连接,该主制水空气压缩机3的出气口通过管道分别与截止阀4、主制水器除霜阀14及辅制水器除霜阀16的入口连接,截止阀4出口通过管道与膜除湿组件5的高压进气口连接,膜除湿组件5的高压出气口通过管道分别与减压阀进气口及除湿空气预冷器8热侧通道进气口连接,膜除湿组件5的低压进气口和低压出气口分别通过管道与减压阀的出气口及吹扫气预冷器11热侧通道进气口连接,吹扫气预冷器11冷侧通道进气口和出气口分别通过管道与吹扫气冷却介质引风机12的引风口及大气环境连接,而吹扫气冷却介质引风机12的进风口直接与大气环境连通,除湿空气预冷器8热侧通道出气口通过管道与除湿空气冷却器9热侧通道进气口连接,除湿空气预冷器8冷侧通道进气口和出气口分别与除湿空气冷却介质引风机7引风口及大气环境连接,该除湿空气冷 却介质引风机7的进气口与大气环境直接连接,除湿空气冷却器9冷侧通道进气口通过管道与辅制水器16冷侧通道出口连接,除湿空气冷却器9冷侧通道出气口与大气环境直接连通,除湿空气冷却器9热侧通道出气口通过管道与除湿空气膨胀机10进气口连接,除湿空气膨胀机10出气口通过管道与主制水器13冷侧通道进气口连接,主制水器13冷侧通道出气口通过管道与辅制水器16冷侧通道进气口连接,辅制水器16冷侧通道出气口通过管道与除湿空气冷却器9冷侧通道进气口连接,膨胀机冷却器冷侧通道出气口直接与大气环境连通,主制水器13热侧通道有两个进气口和出气口,该主制水器13热侧通道的两个进气口分别通过管道与吹扫气预冷器11热侧通道出气口及主制水器除霜阀14出气口连接,而其两个出气口均与大气环境连通,辅制水器16热侧通道也有两个进气口和出气口,该辅制水器16热侧通道的进气口分别与辅制水空气滤清器17出气口及辅制水器除霜阀16连接,而其两个出口也直接与大气环境连通,辅制水空气滤清器17的进气口通过管道与辅制水空气引风机18的引风口连接,而辅制水空气引风机18的入口与大气环境连通;吹扫气预冷器11、主制水器13和辅制水器16热侧均设置有出水口,这些出水口通过水管与水泵19入口连接,水泵19出口通过水管与水箱20入口连接。  The air inlet of the main water-air filter 2 is directly connected to the atmospheric environment, and the air outlet of the main water-air filter 2 is connected to the air inlet of the main water-air compressor 3 through a pipeline. The air outlet of the compressor 3 is respectively connected to the inlets of the shut-off valve 4, the defrosting valve 14 of the main water generator and the defrosting valve 16 of the auxiliary water generator through pipelines, and the outlet of the shut-off valve 4 is connected to the high-pressure air intake of the membrane dehumidification module 5 through pipelines. The high-pressure air outlet of the membrane dehumidification module 5 is respectively connected to the air inlet of the pressure reducing valve and the air inlet of the hot side channel of the dehumidification air precooler 8 through pipelines, and the low-pressure air inlet and the low-pressure air outlet of the membrane dehumidification module 5 are respectively Connect the air outlet of the pressure reducing valve and the air inlet of the hot side channel of the purge gas precooler 11 through the pipeline, and the air inlet and the air outlet of the cold side channel of the purge air precooler 11 are respectively connected with the purge air cooling medium through the pipeline The air inlet of the induced draft fan 12 is connected to the atmospheric environment, while the air inlet of the induced draft fan 12 for the purge air cooling medium is directly connected to the atmospheric environment, and the air outlet of the hot side channel of the dehumidified air pre-cooler 8 is connected to the hot side of the dehumidified air cooler 9 The air inlet of the channel is connected, and the air inlet and outlet of the cold side channel of the dehumidified air precooler 8 are respectively connected with the air inlet of the dehumidified air cooling medium induced fan 7 and the atmospheric environment, and the air inlet of the dehumidified air cooled medium induced fan 7 It is directly connected with the atmospheric environment, the air inlet of the dehumidifying air cooler 9 is connected to the outlet of the cold side channel of the auxiliary water cooler 16 through pipes, the air outlet of the dehumidifying air cooler 9 is directly connected with the atmospheric environment, and the dehumidifying air is cooled The air outlet of the hot side channel of the device 9 is connected to the air inlet of the dehumidifying air expander 10 through a pipeline, and the air outlet of the dehumidifying air expander 10 is connected to the air inlet of the cold side channel of the main water generator 13 through a pipeline, and the cold side of the main water generator 13 The air outlet of the channel is connected to the air inlet of the cold side channel of the auxiliary water device 16 through a pipe, the air outlet of the cold side channel of the auxiliary water device 16 is connected to the air inlet of the cold side channel of the dehumidification air cooler 9 through a pipe, and the cooling of the expander cooler The air outlet of the side channel is directly connected with the atmospheric environment. The hot side channel of the main water generator 13 has two air inlets and an air outlet. The air outlet of the hot side passage of the precooler 11 is connected with the air outlet of the defrosting valve 14 of the main water generator, and its two air outlets are connected with the atmospheric environment, and the hot side passage of the auxiliary water generator 16 also has two air inlets and outlets. Air port, the air inlet of the hot side channel of the auxiliary water heater 16 is respectively connected to the air outlet of the auxiliary water air filter 17 and the defrosting valve 16 of the auxiliary water heater, and its two outlets are also directly connected to the atmospheric environment. The inlet of the auxiliary water air filter 17 is connected with the air inlet of the auxiliary water air induced draft fan 18 through a pipeline, and the entrance of the auxiliary water air induced draft fan 18 is communicated with the atmospheric environment; the purge air precooler 11, Both the hot side of the main water generator 13 and the auxiliary water generator 16 are provided with water outlets, these outlets are connected to the inlet of the water pump 19 through water pipes, and the outlet of the water pump 19 is connected to the inlet of the water tank 20 through water pipes. the

上述主制水空气压缩机3和除湿空气膨胀机10为离心式机械;上述主制水空气压缩机3、除湿空气膨胀机10分别和电动机1同轴连接或相互之间通过皮带和齿轮等装置连接;  The above-mentioned main water-air compressor 3 and the dehumidifying air expander 10 are centrifugal machines; the above-mentioned main water-air compressor 3 and the dehumidifying air expander 10 are respectively coaxially connected with the electric motor 1 or are connected to each other through devices such as belts and gears. connect;

上述电动机1动力源为电网交流电、车载直流电、蓄电池、风力发电装置、太阳能发电装置;  The power source of the above-mentioned motor 1 is grid alternating current, vehicle direct current, storage battery, wind power generation device, solar power generation device;

上述膜除湿组件5为中空纤维式、平板式或卷式结构;  The above-mentioned membrane dehumidification module 5 is a hollow fiber type, flat type or roll type structure;

上述吹扫气预冷器11、除湿空气预冷器8、除湿空气冷却器9、主制水器13和辅制水器16为板翅式换热器;上述吹扫气预冷器11、除湿空气预冷器8、除湿空气冷却器9、主制水器13和辅制水器16也可以为换热管内外均有螺纹的列管式换热器  The above purge gas precooler 11, dehumidification air precooler 8, dehumidification air cooler 9, main water generator 13 and auxiliary water generator 16 are plate-fin heat exchangers; the above purge gas precooler 11, The dehumidifying air precooler 8, the dehumidifying air cooler 9, the main water generator 13 and the auxiliary water generator 16 can also be shell and tube heat exchangers with threads inside and outside the heat exchange tubes

本实施例的工作过程如下:  The working process of this embodiment is as follows:

当本发明所述制水装置需要从空气中制水的时候,主制水空气压缩机3吸入大气环境中一定湿度的主制水空气并通过压缩提高其压力后,由膜除湿组件5的高压进气口进入高压侧,在膜分离的作用下,主制水空气中的部分水蒸气渗透到膜除湿组件5低压侧,降低主制水空气湿度后的除湿空气通过膜除湿组件5的高压出气口排出,大部分除湿空气依次通过除湿空气预冷器8和除湿空气冷却器9的热侧通道降温,之后进入除湿空气膨胀机10吸气口,少部分除湿空气由减压阀等焓减压后,作为吹扫气通过膜除湿组件5的低压进气口进入低压侧,将通过膜渗透来的水蒸气吹扫离膜壁表面,该过程中吹扫气的湿度增加, 以获得高湿度吹扫气,该高湿度吹扫气接着通过膜除湿组件5低压出气口排出后,依次通过吹扫气预冷器11和主制水器13热侧通道,在主制水器13冷侧通道冷却介质的作用下,吹扫气中的水蒸气以液体水析出或者以霜或冰的形式附着在热侧通道壁面上,该主制水器13冷侧通道内流通的冷却介质由除湿空气膨胀机10输出。  When the water-making device of the present invention needs to make water from the air, the main water-making air compressor 3 inhales the main water-making air with a certain humidity in the atmospheric environment and increases its pressure through compression. The air inlet enters the high-pressure side. Under the action of membrane separation, part of the water vapor in the main water-air permeates into the low-pressure side of the membrane dehumidification module 5, and the dehumidified air after reducing the humidity of the main water-air passes through the high-pressure outlet of the membrane dehumidification module 5. The air port is discharged, and most of the dehumidified air passes through the hot side channel of the dehumidified air precooler 8 and the dehumidified air cooler 9 to cool down in turn, and then enters the suction port of the dehumidified air expander 10, and a small part of the dehumidified air is decompressed by the dehumidifying valve. Finally, as sweeping gas, it enters the low-pressure side through the low-pressure air inlet of the membrane dehumidification module 5, and the water vapor permeated through the membrane is swept away from the surface of the membrane wall. Sweeping air, the high-humidity sweeping gas is then discharged through the low-pressure air outlet of the membrane dehumidification module 5, then passes through the sweeping gas precooler 11 and the hot side channel of the main water generator 13 in turn, and is cooled in the cold side channel of the main water generator 13 Under the action of the medium, the water vapor in the purge gas is precipitated as liquid water or adheres to the wall of the hot side channel in the form of frost or ice, and the cooling medium circulating in the cold side channel of the main water generator 13 is supplied by the dehumidification air expander 10 outputs. the

另外,经过除湿空气膨胀机10处理后,除湿空气膨胀而温度降低,之后通过除湿空气膨胀机10排气口流出,首先作为水蒸气冷却介质通过主制水器13冷侧通道,然后温度有一定升高,接着作为二次冷却介质流入辅制水器16冷侧通道,将辅制水器16热侧通道中来自大气环境中辅制水空气温度降低,从而使辅制水空气中所含的水蒸气以液体水析出或者以霜或冰的形式附着在热侧通道壁面上,最后再次作为压缩空气冷却介质输入除湿空气冷却器9的冷侧通道,以对除湿空气冷却器9热侧通道内的除湿空气进行冷却,由此可知,本发明冷源的循环利用,有效地降低了制水成本;  In addition, after being processed by the dehumidifying air expander 10, the dehumidifying air expands and lowers its temperature, and then flows out through the exhaust port of the dehumidifying air expander 10, and first passes through the cold side channel of the main water generator 13 as a cooling medium of water vapor, and then the temperature has a certain Then, as the secondary cooling medium, it flows into the cold side channel of the auxiliary water device 16, and the temperature of the auxiliary water air from the atmospheric environment in the hot side channel of the auxiliary water device 16 is reduced, thereby reducing the temperature of the auxiliary water air contained in the auxiliary water device. Water vapor precipitates as liquid water or adheres to the wall surface of the hot side channel in the form of frost or ice, and finally enters the cold side channel of the dehumidification air cooler 9 again as a compressed air cooling medium to cool the hot side channel of the dehumidification air cooler 9 The dehumidified air is cooled, so it can be seen that the recycling of the cold source of the present invention effectively reduces the cost of water production;

当主制水器13或辅制水器16热侧通道壁面上霜层或冰层达到一定厚度后,这时进入除霜流程,关闭截止阀4并相应打开主制水器除霜阀14或辅制水器除霜阀16,使主制水空气压缩机3产生的高温排气直接进入主制水器13或辅制水器16热侧通道将霜或冰融化变成液态水,当霜层或冰层被完全融化后,打开截止阀4并相应关闭主制水器除霜阀14或辅制水器除霜阀16,再次进入制水流程;  When the frost layer or ice layer on the hot side channel wall of the main water generator 13 or the auxiliary water generator 16 reaches a certain thickness, the defrosting process is entered at this time, the stop valve 4 is closed and the main water generator defrosting valve 14 or the auxiliary water generator is opened correspondingly. The defrosting valve 16 of the water generator makes the high-temperature exhaust gas produced by the main water generator 3 directly enter the hot side channel of the main water generator 13 or the auxiliary water generator 16 to melt the frost or ice into liquid water. Or after the ice layer is completely melted, open the shut-off valve 4 and close the defrost valve 14 of the main water generator or the defrost valve 16 of the auxiliary water generator accordingly, and enter the water production process again;

制水流程或除霜流程中,在吹扫气预冷器11、主制水器13和辅制水器16产生的液态水由水泵19泵入水箱20;水箱20中的水通过适当的过滤、杀菌等净化步骤后,就可以提供给人们使用了。  In the water production process or the defrosting process, the liquid water produced in the purge gas precooler 11, the main water generator 13 and the auxiliary water generator 16 is pumped into the water tank 20 by the water pump 19; the water in the water tank 20 is filtered through appropriate , sterilization and other purification steps, it can be provided to people for use. the

Claims (10)

1. a process for preparing water that utilizes diffusion barrier enriched air By steam is characterized in that, may further comprise the steps:
(1) air preliminary treatment---adopt air filter, compressor that air is carried out removal of impurities, compression;
(2) separating treatment of air vapor---adopt film dehumidifying assembly that the compressed air of handling through step (1) is carried out dehumidification treatments to obtain to be in respectively the dehumidified air and the steam of film both sides;
(3) condensed water cohesion---a, adopt the sweep gas method that sweep gas is introduced the vapor permeation side of film dehumidifying assembly in the step (2), carry out the lip-deep steam cleaning of membranous wall,, realize the enrichment of air vapor to obtain the high humility sweep gas; B, dehumidified air that step (2) is obtained successively through supercooling, expand after as the steam cooling medium; C, the steam cooling medium among the step b is carried out condensation to the high humility sweep gas that is obtained among the step a, obtain condensed water;
(4) condensed water is collected---the condensed water after step (3) is handled, if aqueous water directly pumps into water tank through water pump; If solid water adopts the medium that thaws that condensed water is melted to behind the aqueous water earlier, pump into water tank through water pump again.
2. according to the said process for preparing water that utilizes diffusion barrier enriched air By steam of claim 1, it is characterized in that used sweep gas derives from dehumidified air in the step (3), the mass fraction that its use amount accounts for dehumidified air is 10~30%.
3. according to the said process for preparing water that utilizes diffusion barrier enriched air By steam of claim 1, it is characterized in that the medium that thaws in the step (4) is the pretreated compressed air of process step (1).
4. according to the said process for preparing water that utilizes diffusion barrier enriched air By steam of claim 3; It is characterized in that; In step (3), after the steam cooling medium cools off the high humility sweep gas, as the secondary cooling medium; Once more the auxilliary system water removal of impurities air of handling through the air filter removal of impurities is cooled off, to obtain liquid or solid water; Simultaneously, auxilliary system water removal of impurities air is carried out cooled secondary cooling medium,, carry out the cooling of dehumidified air in the step (3) once more as the compressed air cooling medium.
5. water generator that utilizes diffusion barrier enriched air By steam; It is characterized in that; Comprise air master water generator; This air master water generator comprises main system water air pretreatment unit, film dehumidifying assembly, sweep gas pressure-reducing valve, dehumidified air forecooler, dehumidified air decompressor, sweep gas forecooler, main water-producing apparatus and water tank; Said main system water air pretreatment unit comprises the main system water air filter and main system water air compressor that is linked in sequence, and the air inlet and the outside air of said main system water air filter are connected, and the high pressure admission mouth of said film dehumidifying assembly is connected with the gas outlet of main system water air compressor; The cold side channel entrance of the high pressure gas outlet of film dehumidifying assembly, hot-side channel, dehumidified air decompressor and the main water-producing apparatus of dehumidified air forecooler then is linked in sequence successively; Simultaneously, the hot-side channel and the water tank of the gas outlet of sweep gas pressure-reducing valve, the low-pressure admission side of film dehumidifying assembly, the hot-side channel of sweep gas forecooler, main water-producing apparatus are linked in sequence successively, and the air inlet of sweep gas pressure-reducing valve is communicated with the sweep gas carrier pipe; In addition, the cold side passage of dehumidified air forecooler and sweep gas forecooler all has the cooling medium circulation.
6. according to the said water generator that utilizes diffusion barrier enriched air By steam of claim 5; It is characterized in that; Said main system water air compressor is communicated with main water-producing apparatus hot-side channel; And being connected between main system water air compressor and the main water-producing apparatus hot-side channel is equipped with main water-producing apparatus defrost valve on the pipeline, and main simultaneously system water air compressor and film dehumidify and being connected between the high pressure admission mouth of assembly be connected with stop valve on the pipeline.
7. according to claim 5 or the 6 said water generators that utilize diffusion barrier enriched air By steam; It is characterized in that; Comprise that also air assists water generator; The auxilliary water generator of this air comprises auxilliary system water air air-introduced machine, auxilliary system water air filter and auxilliary water-producing apparatus, and said auxilliary system water air air-introduced machine and outside air are connected, and auxilliary system water air air-introduced machine, auxilliary system water air filter, auxilliary water-producing apparatus hot-side channel and water tank are linked in sequence successively; Simultaneously, the cold side channel outlet of main water-producing apparatus is connected with the cold side feeder connection of auxilliary water-producing apparatus.
8. according to the said water generator that utilizes diffusion barrier enriched air By steam of claim 7; It is characterized in that; Said auxilliary water-producing apparatus hot-side channel is communicated with main system water air compressor, and auxilliary water-producing apparatus hot-side channel is equipped with auxilliary water-producing apparatus defrost valve being connected between the water air compressor with main the system on the pipeline.
9. according to the said water generator that utilizes diffusion barrier enriched air By steam of claim 7; It is characterized in that; Also be connected with the dehumidified air cooler between said dehumidified air forecooler and the dehumidified air decompressor; The hot-side channel of said dehumidified air cooler is connected with the hot-side channel outlet and the air expander air inlet of dehumidified air forecooler respectively, and the cold side channel entrance of dehumidified air cooler then is connected with the cold side channel outlet of auxilliary water-producing apparatus.
10. according to the said water generator that utilizes diffusion barrier enriched air By steam of claim 5, it is characterized in that said sweep gas carrier pipe is connected with the high pressure gas outlet of film dehumidifying assembly.
CN2010101757538A 2010-05-18 2010-05-18 Water generating method by utilizing separating membrane to enrich air water vapor and device thereof Expired - Fee Related CN101851946B (en)

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