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CN101830611A - System and method for treating sewage containing high-proportion industrial waste water - Google Patents

System and method for treating sewage containing high-proportion industrial waste water Download PDF

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Publication number
CN101830611A
CN101830611A CN 201010214423 CN201010214423A CN101830611A CN 101830611 A CN101830611 A CN 101830611A CN 201010214423 CN201010214423 CN 201010214423 CN 201010214423 A CN201010214423 A CN 201010214423A CN 101830611 A CN101830611 A CN 101830611A
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CN
China
Prior art keywords
sewage
pond
aerobe
hydrolysis
waste water
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Pending
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CN 201010214423
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Chinese (zh)
Inventor
李玉庆
聂英进
张轶凡
马劲
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TIANJIN CAPITAL ENVIRONMENTAL PROTECTION GROUP CO Ltd
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TIANJIN CAPITAL ENVIRONMENTAL PROTECTION GROUP CO Ltd
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Priority to CN 201010214423 priority Critical patent/CN101830611A/en
Publication of CN101830611A publication Critical patent/CN101830611A/en
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Abstract

The invention discloses a system and a method for treating sewage containing high-proportion industrial waste water. The sewage processing system comprises an anaerobic hydrolyzing and acidifying system and an aerobic biological treatment system; and the sewage is firstly treated by the anaerobic hydrolyzing and acidifying system and then treated by the aerobic biological treatment system, wherein the anaerobic hydrolyzing and acidifying system is used for improving the biochemical performance of the sewage, and reducing the processing load of the subsequent aerobic biological treatment system. In the invention, the sewage treating method comprises the following steps of: carrying out the first sedimentation in a first sedimentation basin; carrying out the anaerobic hydrolyzing and acidifying treatment in a hydrolyzing and acidifying basin; carrying out the aerobe treatment in an aerobe oxidizing basin; and carrying out the solid-liquid separation in a second sedimentation basin. The invention improves the treatment efficiency of the sewage containing high-proportion industrial waste water and modifies the environment of the sewage treatment plants.

Description

A kind of Sewage treatment systems and method that contains high-proportion industrial waste water
Technical field
The present invention relates to environment protection and technical field of waste water processing, especially relate to a kind of Sewage treatment systems and method that contains high-proportion industrial waste water.
Background technology
The trade effluent proportion that sanitary sewage is mixed with in the municipal sewage plant is higher, and to have many be the waste water of difficult for biological degradation, causes the water outlet can not stably reaching standard.
Reactor for hydrolysis and acidification belongs to the technology category of up flow anaerobic sludge blanket reactor, sewage enters reactor by reactor bottom, pass through Sludge Bed, organic particle material during a large amount of microorganisms will be intake and colloidalmaterial are held back rapidly and are adsorbed, this is the rapid reaction of a physical process, and general needs several seconds to tens seconds time to finish.The material that is retained down is adsorbed on the surface of hydrolyzing sludge, the metabolism that is decomposed slowly, and it is greater than hydraulic detention time at intrasystem sludge retention time.Under the effect of a large amount of hydrolytic bacterias, insoluble organism is broken down into dissolved matter, simultaneously under the synergy of acid-producing bacteria with macromolecular substance, be difficult to biodegradable material and be converted into and be easy to biodegradable small-molecule substance, again be discharged in the waste water, under higher hydraulic load, flow out system with water.Because the generation time of hydrolysis and acid formers is shorter, often in minute and hour, therefore, this degradation process is rapidly.In this process, though the clearance of solvability COD, BOD5 is very low from the surface, but because particulate organic matter generation hydrolysis has increased the concentration of dissolved organic matter in the system, therefore, it is very high that the clearance of solvability COD, BOD5 is actually, the part of removing is present in waste water and the mud with CH4, CO2 and these three kinds of forms of thalline increment, and particularly the solubleness of CH4 and CO2 also is appreciable in low concentration wastewater.As seen from the above, hydrolysis reactor integrates precipitation, absorption, biofloculation and biological degradation function.The removal of organism in hydrolysis reaction bath comprised physics, chemistry and biochemical combined reaction process.This has essential difference with the preliminary sedimentation tank that has only the physical sedimentation function.Therefore, hydrolysis reaction is a kind of novel sewage treatment process.Much more the acidication treatment process of waste water has research at home and abroad as the Biological Pretreatment technology and uses.It can improve the sewage biochemical property, reduces the subsequent biological treatment load.
Therefore, how in conjunction with prior art, the design high efficiency, low cost is handled sink drainage and the method that contains high-proportion industrial waste water, is the target of technician's concern always.
Summary of the invention
In view of this, the object of the present invention is to provide a kind of Sewage treatment systems and method that contains high-proportion industrial waste water, improve the sewage treating efficiency that contains high-proportion industrial waste water, improve the environment of sewage work.
For achieving the above object, the present invention by the following technical solutions: Sewage treatment systems of the present invention comprises anaerobic hydrolysis-acidification system and aerobic biological treatment system; Sewage is handled through the aerobe treatment system then through the anaerobic hydrolysis-acidification system handles earlier; Wherein, the anaerobic hydrolysis-acidification system is used to improve the sewage biochemical property, reduces follow-up aerobe treatment system processing load.
Further, Sewage treatment systems of the present invention also comprises a heavy pond, second pond, the modified groove of excess sludge, described anaerobic hydrolysis-acidification system one is built-in with the hydrolysis acidification pool of biologic packing material, described aerobe system is an aerobe oxidation pond, and this aerobe oxidation pond is by aerobic contact oxidation system and aerobic activated sludge system be combined into; Sewage inlet links to each other with a heavy pond, one sinking pool effluent mouth connects hydrolysis acidification pool, the hydrolysis acidification pool water outlet links to each other with the aerobe oxidation pond, aerobe oxidation pond water outlet links to each other with second pond, system's water outlet and mud relief outlet are set on the second pond, and the mud relief outlet connects the modified groove of excess sludge.
Sewage water treatment method of the present invention comprises following treatment step: a heavy pond primary deposition; Hydrolysis acidification pool carries out anaerobic hydrolysis-acidification to be handled; The aerobe oxidation pond carries out aerobe to be handled; Second pond carries out solid-liquid separation.
Further sewage water treatment method of the present invention comprises following treatment step: sewage enters the heavy pond of hydraulic detention time 1.5~2h successively, the hydrolysis acidification pool of hydraulic detention time 10~12h, the aerobe oxidation pond of hydraulic detention time 7.0~9.0h and the second pond of hydraulic detention time 2.5~3.5h are discharged or reuse at last; Residual sludge reflux flow and flooding velocity are than 50%-100%, and aerobe oxidation pond internal reflux amount compares 100%-200% with flooding velocity.
The invention has the beneficial effects as follows: 1) anaerobic hydrolysis-acidification and aerobic biological treatment process are effectively made up, the anaerobic hydrolysis-acidification means are placed on the technical process head end, have guaranteed that high-proportion industrial waste water can reach strict emission control standards after processing; Remove in the time of anaerobic hydrolysis-acidification the virulent pollutent of aerobe, guarantee the steady running of aerobic process and the working cost of reduction aerobic process system; 2) the anaerobic hydrolysis-acidification process has effectively been removed the influence of hardly degraded organic substance to effluent quality, also handle the denitrogenation dephosphorizing process high-quality carbon source is provided for the back aerobe, reduced the dosage of denitrogenation dephosphorizing process additional carbon, effectively reduce the Sewage Plant working cost, guaranteed the up to standard of outlet water organic substance and nitrogen phosphorus; 3) hydrolytic process can adapt to the existence of suspended particle preferably, this part material of degrading preferably simultaneously, thus reduced sludge quantity, reduced the VSS of mud.Hydrolysis acidification pool does not generally need heating, and it is few to produce surplus sludge volume, can make the rapid hydrolysis of solid particulate at normal temperatures, realizes sewage, mud primary treatment; 4) the reactor for hydrolysis and acidification water inlet does not need the strictly anaerobic condition, comprises the compound with oxygenizement, as nitric nitrogen, nitrite nitrogen etc.Reaction is controlled at acidication during the stage, and in many cases, acidization is also incomplete.So water outlet does not have the unpleasant odor that anaerobically fermenting has, and has improved the environment of sewage work.
Other advantages of the present invention, target and feature will be set forth to a certain extent in the following description, and to a certain extent, based on being conspicuous to those skilled in the art, perhaps can obtain instruction from the practice of the present invention to investigating hereinafter.Target of the present invention and other advantages can realize and obtain by specifically noted structure in following specification sheets and the accompanying drawing.
Description of drawings
Fig. 1 contains the process flow sheet of the Sewage treatment systems and the method for high-proportion industrial waste water for the present invention.
Embodiment
Below in conjunction with drawings and Examples the present invention is further described.
As shown in drawings, adopt when method and system processing of the present invention is high to contain the sewage of ratio trade effluent, sewage enters the heavy pond 2 of hydraulic detention time 1.5~2h successively by sewage inlet 1, the hydrolysis acidification pool 3 of hydraulic detention time 10~12h, the aerobe oxidation pond 4 of hydraulic detention time 7.0~9.0h and the second pond 5 of hydraulic detention time 2.5~3.5h are discharged or reuse at last; Residual sludge reflux flow and flooding velocity are than 50%-100%, and aerobe oxidation pond internal reflux amount compares 100%-200% with flooding velocity.In the hydrolysis acidification pool 3 that is built-in with biologic packing material, hardly degraded organic substance after hydrolysis acidification pool 3 is handled, hardly degraded organic substance and will reduce greatly to follow-up biological treatment hazardous contaminant content; The water outlet of hydrolysis acidification pool 3 enters aerobe oxidation pond 4 biodegrades, in aerobe oxidation pond 4, organism is degraded to carbonic acid gas and water, and phosphorus is effectively removed in the water, and organonitrogen and ammonia nitrogen carry out carrying out final biological removal behind the efficient oxidation; Water outlet is carried out solid-liquid separation through second pond 5, and treated water up to standard is discharged through system's water outlet 6, and mud enters the modified groove 7 of excess sludge.
Embodiment 1, and the water-quality guideline at sewage inlet 1 place is COD 〉=1000mg/L, BOD5 〉=300mg/L, TP 〉=15mg/L, NH3-N 〉=150mg/L.Sewage enters a heavy pond 2(hydraulic detention time 2.0h), the organic and inorganic pollutant of precipitation larger particles.The waste water that discharge in one heavy pond 2 enters hydrolysis acidification pool 3(hydraulic detention time 10.0h) in carry out anaerobic hydrolysis-acidification.Hydrolysis acidification pool 3 effusive waste water behind acidication enter aerobe oxidation pond 4(hydraulic detention time 8.5h), be degraded to carbonic acid gas and water at this organism, phosphorus is effectively removed in the water, and organonitrogen and ammonia nitrogen carry out carrying out final biological removal behind the efficient oxidation.The water that aerobe oxidation pond 4 is discharged enters second pond 5, carries out solid-liquid separation, and the water-quality guideline that system's water outlet 6 of second pond 5 is discharged reaches COD≤60mg/L, BOD5≤20mg/L, PO43--P≤1mg/L, NH3-N≤5mg/L.In the present embodiment, residual sludge reflux flow and flooding velocity be than 75%, and aerobe oxidation pond internal reflux amount and flooding velocity are than 150%.
Embodiment 2, and the water-quality guideline at sewage inlet 1 place is: COD 〉=800mg/L, BOD5 〉=200mg/L, TP 〉=12mg/L, NH3-N 〉=110mg/L.Sewage enters a heavy pond 2(hydraulic detention time 2.0h), the organic and inorganic pollutant of precipitation larger particles.Then, a heavy pond 2 waste water of discharging enters hydrolysis acidification pool 3(hydraulic detention time 11.0h) in carry out anaerobic hydrolysis-acidification.Hydrolysis acidification pool 3 effusive waste water behind acidication enter aerobe oxidation pond 4(hydraulic detention time 8h), be degraded to carbonic acid gas and water at this organism, phosphorus is effectively removed in the water, and organonitrogen and ammonia nitrogen carry out carrying out final biological removal behind the efficient oxidation.4 water outlets of aerobe oxidation pond enter second pond 5, carry out solid-liquid separation, and the effluent quality index at system's water outlet 6 places of second pond 5 reaches COD≤60mg/L, BOD5≤20mg/L, PO43--P≤1mg/L, NH3-N≤8mg/L.In the present embodiment, residual sludge reflux flow and flooding velocity be than 100%, and aerobe oxidation pond internal reflux amount and flooding velocity are than 150%.
Embodiment 3, and the water-quality guideline at sewage inlet 1 place is: COD 〉=1200mg/L, BOD5 〉=250mg/L, TP 〉=10mg/L, NH3-N 〉=130mg/L.Sewage enters a heavy pond 2(hydraulic detention time 2.0h), the organic and inorganic pollutant of precipitation larger particles.Then, a heavy pond 2 waste water of discharging enters hydrolysis acidification pool 3(hydraulic detention time 11.0h) in carry out anaerobic hydrolysis-acidification.Hydrolysis acidification pool 3 effusive waste water behind acidication enter aerobe oxidation pond 4(hydraulic detention time 9h), be degraded to carbonic acid gas and water at this organism, phosphorus is effectively removed in the water, and organonitrogen and ammonia nitrogen carry out carrying out final biological removal behind the efficient oxidation.4 water outlets of aerobe oxidation pond enter second pond 5, carry out solid-liquid separation, and the water-quality guideline at system's water outlet 6 places of second pond 5 reaches: COD≤60mg/L, BOD5≤20mg/L, PO43--P≤1mg/L, NH3-N≤5mg/L.In the present embodiment, residual sludge reflux flow and flooding velocity be than 100%, and aerobe oxidation pond internal reflux amount and flooding velocity are than 150%.
Explanation is at last, above embodiment is only unrestricted in order to technical scheme of the present invention to be described, other modifications that those of ordinary skills make technical scheme of the present invention or be equal to replacement, only otherwise break away from the spirit and scope of technical solution of the present invention, all should be encompassed in the middle of the claim scope of the present invention.

Claims (4)

1. a Sewage treatment systems that contains high-proportion industrial waste water is characterized in that: comprise anaerobic hydrolysis-acidification system and aerobic biological treatment system; Sewage is handled through the aerobe treatment system then through the anaerobic hydrolysis-acidification system handles earlier; Wherein, the anaerobic hydrolysis-acidification system is used to improve the sewage biochemical property, reduces follow-up aerobe treatment system processing load.
2. the Sewage treatment systems that contains high-proportion industrial waste water according to claim 1, it is characterized in that: also comprise a heavy pond, second pond, the modified groove of excess sludge, described anaerobic hydrolysis-acidification system one is built-in with the hydrolysis acidification pool of biologic packing material, described aerobe system is an aerobe oxidation pond, and this aerobe oxidation pond is by aerobic contact oxidation system and aerobic activated sludge system be combined into; Sewage inlet links to each other with a heavy pond, one sinking pool effluent mouth connects hydrolysis acidification pool, the hydrolysis acidification pool water outlet links to each other with the aerobe oxidation pond, aerobe oxidation pond water outlet links to each other with second pond, system's water outlet and mud relief outlet are set on the second pond, and the mud relief outlet connects the modified groove of excess sludge.
3. the described treatment process that contains the Sewage treatment systems of high-proportion industrial waste water of claim 2 is characterized in that sewage is successively through comprising following treatment step: a heavy pond primary deposition; Hydrolysis acidification pool carries out anaerobic hydrolysis-acidification to be handled; The aerobe oxidation pond carries out aerobe to be handled; Second pond carries out solid-liquid separation.
4. the described treatment process that contains the Sewage treatment systems of high-proportion industrial waste water of claim 3, it is characterized in that sewage is successively through comprising following treatment step: sewage enters the heavy pond of hydraulic detention time 1.5~2h successively, the hydrolysis acidification pool of hydraulic detention time 10~12h, the aerobe oxidation pond of hydraulic detention time 7.0~9.0h and the second pond of hydraulic detention time 2.5~3.5h are discharged or reuse at last; Residual sludge reflux flow and flooding velocity are than 50%-100%, and aerobe oxidation pond internal reflux amount compares 100%-200% with flooding velocity.
CN 201010214423 2010-07-01 2010-07-01 System and method for treating sewage containing high-proportion industrial waste water Pending CN101830611A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107311298A (en) * 2017-07-14 2017-11-03 深圳华联伟创环保技术有限公司 A kind of sugaring modified active removes ammonia nitrogen sludge
CN107473513A (en) * 2017-09-04 2017-12-15 杭州宸祥环境工程有限公司 A kind of bamboo product waste water Fenton processing unit and method
CN111099783A (en) * 2018-10-26 2020-05-05 中国石油化工股份有限公司 Method for treating production wastewater containing organic amine molecular sieve catalyst
CN111115816A (en) * 2020-01-06 2020-05-08 广东电科院能源技术有限责任公司 Bioelectrochemical device and method for treating organic pollutants containing azobenzene

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CN1396125A (en) * 2001-07-12 2003-02-12 徐祥圣 Energy-saving burying-under-ground process for treating sewage in urban area
CN101391853A (en) * 2008-11-03 2009-03-25 山东邹平开元化工石材有限公司 Chemical wastewater recovery processing technique and apparatus
CN101607780A (en) * 2009-07-22 2009-12-23 顾利平 A kind of technology of handling tar product wastewater

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Publication number Priority date Publication date Assignee Title
CN1396125A (en) * 2001-07-12 2003-02-12 徐祥圣 Energy-saving burying-under-ground process for treating sewage in urban area
CN101391853A (en) * 2008-11-03 2009-03-25 山东邹平开元化工石材有限公司 Chemical wastewater recovery processing technique and apparatus
CN101607780A (en) * 2009-07-22 2009-12-23 顾利平 A kind of technology of handling tar product wastewater

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN107311298A (en) * 2017-07-14 2017-11-03 深圳华联伟创环保技术有限公司 A kind of sugaring modified active removes ammonia nitrogen sludge
CN107473513A (en) * 2017-09-04 2017-12-15 杭州宸祥环境工程有限公司 A kind of bamboo product waste water Fenton processing unit and method
CN111099783A (en) * 2018-10-26 2020-05-05 中国石油化工股份有限公司 Method for treating production wastewater containing organic amine molecular sieve catalyst
CN111099783B (en) * 2018-10-26 2023-01-13 中国石油化工股份有限公司 Method for treating production wastewater containing organic amine molecular sieve catalyst
CN111115816A (en) * 2020-01-06 2020-05-08 广东电科院能源技术有限责任公司 Bioelectrochemical device and method for treating organic pollutants containing azobenzene

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Open date: 20100915