CN101810202B - Microbial weeding oil flowable concentrate for rice field - Google Patents
Microbial weeding oil flowable concentrate for rice field Download PDFInfo
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- CN101810202B CN101810202B CN 201010166724 CN201010166724A CN101810202B CN 101810202 B CN101810202 B CN 101810202B CN 201010166724 CN201010166724 CN 201010166724 CN 201010166724 A CN201010166724 A CN 201010166724A CN 101810202 B CN101810202 B CN 101810202B
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- 238000009333 weeding Methods 0.000 title claims abstract description 13
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- 235000009566 rice Nutrition 0.000 title abstract description 11
- 230000000813 microbial effect Effects 0.000 title abstract description 9
- 239000004546 suspension concentrate Substances 0.000 title abstract 3
- 240000007594 Oryza sativa Species 0.000 title description 6
- 241000223211 Curvularia lunata Species 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims abstract description 10
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- 239000000725 suspension Substances 0.000 claims abstract description 5
- 239000004480 active ingredient Substances 0.000 claims description 9
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- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 4
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 3
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- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 claims description 3
- 229930006000 Sucrose Natural products 0.000 claims description 3
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- 239000005995 Aluminium silicate Substances 0.000 claims description 2
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 2
- 235000019774 Rice Bran oil Nutrition 0.000 claims description 2
- 235000019486 Sunflower oil Nutrition 0.000 claims description 2
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- -1 atlapulgite Substances 0.000 claims description 2
- 239000000440 bentonite Substances 0.000 claims description 2
- 229910000278 bentonite Inorganic materials 0.000 claims description 2
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 2
- OSGAYBCDTDRGGQ-UHFFFAOYSA-L calcium sulfate Inorganic materials [Ca+2].[O-]S([O-])(=O)=O OSGAYBCDTDRGGQ-UHFFFAOYSA-L 0.000 claims description 2
- ZOMBKNNSYQHRCA-UHFFFAOYSA-J calcium sulfate hemihydrate Chemical compound O.[Ca+2].[Ca+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O ZOMBKNNSYQHRCA-UHFFFAOYSA-J 0.000 claims description 2
- 239000002283 diesel fuel Substances 0.000 claims description 2
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 2
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- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims description 2
- 239000002736 nonionic surfactant Substances 0.000 claims description 2
- 239000008165 rice bran oil Substances 0.000 claims description 2
- 239000008159 sesame oil Substances 0.000 claims description 2
- 235000011803 sesame oil Nutrition 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 239000002383 tung oil Substances 0.000 claims description 2
- 244000005700 microbiome Species 0.000 claims 7
- 239000000375 suspending agent Substances 0.000 claims 7
- 241001066679 bacterium B6 Species 0.000 claims 3
- 150000001450 anions Chemical class 0.000 claims 1
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- 239000000084 colloidal system Substances 0.000 claims 1
- 235000012343 cottonseed oil Nutrition 0.000 claims 1
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- 239000010721 machine oil Substances 0.000 claims 1
- 238000003801 milling Methods 0.000 claims 1
- 238000005498 polishing Methods 0.000 claims 1
- 229940088417 precipitated calcium carbonate Drugs 0.000 claims 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims 1
- 238000010008 shearing Methods 0.000 claims 1
- 239000002689 soil Substances 0.000 claims 1
- 241000192043 Echinochloa Species 0.000 abstract description 10
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- 239000000428 dust Substances 0.000 description 2
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- 235000010446 mineral oil Nutrition 0.000 description 2
- 238000004806 packaging method and process Methods 0.000 description 2
- 239000000575 pesticide Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000004260 weight control Methods 0.000 description 2
- 241000223208 Curvularia Species 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 239000005909 Kieselgur Substances 0.000 description 1
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- IGFHQQFPSIBGKE-UHFFFAOYSA-N Nonylphenol Natural products CCCCCCCCCC1=CC=C(O)C=C1 IGFHQQFPSIBGKE-UHFFFAOYSA-N 0.000 description 1
- 231100000674 Phytotoxicity Toxicity 0.000 description 1
- 241000607479 Yersinia pestis Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
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- 239000003905 agrochemical Substances 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000004071 biological effect Effects 0.000 description 1
- 229910000019 calcium carbonate Inorganic materials 0.000 description 1
- 229920005551 calcium lignosulfonate Polymers 0.000 description 1
- OOCMUZJPDXYRFD-UHFFFAOYSA-L calcium;2-dodecylbenzenesulfonate Chemical compound [Ca+2].CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O.CCCCCCCCCCCCC1=CC=CC=C1S([O-])(=O)=O OOCMUZJPDXYRFD-UHFFFAOYSA-L 0.000 description 1
- RYAGRZNBULDMBW-UHFFFAOYSA-L calcium;3-(2-hydroxy-3-methoxyphenyl)-2-[2-methoxy-4-(3-sulfonatopropyl)phenoxy]propane-1-sulfonate Chemical compound [Ca+2].COC1=CC=CC(CC(CS([O-])(=O)=O)OC=2C(=CC(CCCS([O-])(=O)=O)=CC=2)OC)=C1O RYAGRZNBULDMBW-UHFFFAOYSA-L 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
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- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
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- NVVZQXQBYZPMLJ-UHFFFAOYSA-N formaldehyde;naphthalene-1-sulfonic acid Chemical compound O=C.C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 NVVZQXQBYZPMLJ-UHFFFAOYSA-N 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
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- 239000000463 material Substances 0.000 description 1
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- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical compound CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
Description
技术领域 technical field
本发明涉及一种新型微生物除草剂,特别是一种真菌除草剂的油悬浮剂,属于农用化学品领域。The invention relates to a novel microbial herbicide, in particular to an oil suspension concentrate of a fungal herbicide, and belongs to the field of agricultural chemicals.
背景技术 Background technique
新月弯孢霉菌B6(保藏编号CGMCC No.2928)是新研究开发出的除草剂真菌,经过大量实验研究结果表明它对水稻田稗草具有较高的生物活性,用于水稻田除草具有防效高、对稻田的生态环境安全、没有残留毒性、不产生任何药害、增产幅度明显等特点。目前微生物农药使用的主要剂型是水剂和可湿性粉剂,水剂含活性成分较低,在包装、运输、使用过程中量较大,使用成本较高;可湿性粉剂虽然活性成分较高,但在加工,包装、使用过程中存在粉尘漂移问题,且在贮藏过程中活性成分受载体表面酸性或碱性影响而降解。油悬浮剂是由有效成分分散在油相介质中形成的高分散、稳定的悬浮体系。油悬浮剂与水剂和可湿性粉剂比较,前者对靶标作物有较强的渗透性和粘附性,因而具有增效作用,由于前者使用惰性矿物油和植物油,在贮藏过程中活性成分稳定。Curvularia crescens B6 (preservation number CGMCC No.2928) is a newly developed herbicide fungus. After a large number of experimental studies, it has shown that it has high biological activity against barnyardgrass in paddy fields, and it has anti-weeding properties when used in paddy fields. It has the characteristics of high efficiency, safety to the ecological environment of rice fields, no residual toxicity, no phytotoxicity, and obvious increase in yield. At present, the main dosage forms of microbial pesticides are water preparations and wettable powders. The water preparations contain low active ingredients, and the amount in the process of packaging, transportation, and use is large, and the cost of use is high; although the wettable powders have high active ingredients, they are more expensive. There are dust drift problems during processing, packaging, and use, and the active ingredient is degraded by the acidity or alkalinity of the carrier surface during storage. Oil suspension concentrate is a highly dispersed and stable suspension system formed by dispersing active ingredients in oil phase medium. Compared with water and wettable powders, oil suspension concentrates have stronger penetration and adhesion to target crops, so they have a synergistic effect. Since the former uses inert mineral oil and vegetable oil, the active ingredients are stable during storage.
发明内容 Contents of the invention
本发明的目的在于克服现有技术中的不足和缺陷,提供一种贮藏稳定性好稻田微生物除草油悬浮剂,使其能高效地防除稻田稗草,从而节省人力、物力、减少因大量使用化学农药对环境的污染和人体的危害,达到增产、增收的目的。The purpose of the present invention is to overcome the deficiencies and defects in the prior art, to provide a kind of paddy field microbial herbicide oil suspension concentrate with good storage stability, so that it can effectively control paddy field barnyard grass, thereby saving manpower and material resources, reducing the cost of using chemicals due to a large number of Pesticides pollute the environment and harm the human body to achieve the purpose of increasing production and income.
本发明是通过以下技术方案实现的,新月弯孢霉菌B6油悬浮剂是由新月弯孢霉菌、溶剂、表面活性剂、稳定剂、增稠剂等组成,各组分组成如下:The present invention is achieved through the following technical solutions, Curvularia lunata B6 oil suspension concentrate is made up of Curvularia lunata, solvent, surfactant, stabilizer, thickener etc., and each component is formed as follows:
有效成分 (0.1-10)×108个孢子/ml 表面活性剂 1-10%Active ingredient (0.1-10)× 108 spores/ml Surfactant 1-10%
稳定剂 1-10% 增稠剂 0.1-5%Stabilizer 1-10% Thickener 0.1-5%
溶剂 补齐至100%Solvent fill up to 100%
所述有效成分是新月弯孢霉(Curvularia lunata)B6,其保藏编号为CGMCC No.2928,其浓度为(0.1-10)×108个孢子/ml。The active ingredient is Curvularia lunata B6, its preservation number is CGMCC No.2928, and its concentration is (0.1-10)×10 8 spores/ml.
所述的溶剂包括植物油和矿物油,可以是花生油、大豆油、棕榈油、菜籽油、米糠油、葵花油、芝麻油、蓖麻油、桐油、柴油、机油、煤油中的一种或几种混合物。The solvent includes vegetable oil and mineral oil, which can be one or more mixtures of peanut oil, soybean oil, palm oil, rapeseed oil, rice bran oil, sunflower oil, sesame oil, castor oil, tung oil, diesel oil, motor oil, and kerosene .
所述表面活性剂包括阴离子、阳离子、非离子性表面活性剂中的一种或几种混合物。所述的增稠剂包括高岭土、膨润土、活性白土、海泡石、白碳黑、硅藻土、轻质碳酸钙、滑石粉、熟石膏、白垩土、陶土、蒙脱土、粘土中的一种或几种混合物。The surfactant includes one or more mixtures of anionic, cationic and nonionic surfactants. Described thickener comprises one of kaolin, bentonite, attapulgite, sepiolite, white carbon black, diatomaceous earth, light calcium carbonate, talcum powder, plaster of paris, chalk, clay, montmorillonite, clay species or a mixture of several.
所述稳定剂包括蔗糖、尿素、海藻酸、乙二醇、丙二醇、丙三醇中的一种或几种混合物。The stabilizer includes one or more mixtures of sucrose, urea, alginic acid, ethylene glycol, propylene glycol and glycerin.
本发明具有以下特点:The present invention has the following characteristics:
1.对水稻田稗草有较好的防效。1. It has good control effect on barnyardgrass in paddy fields.
2.对人畜无毒、对害虫天敌安全、不污染环境。2. Non-toxic to humans and animals, safe to natural enemies of pests, and does not pollute the environment.
3.在生产加工、使用过程中无粉尘漂移,运输、贮藏过程中没有结块、不吸潮现象。3. There is no dust drift in the process of production, processing and use, and there is no agglomeration or moisture absorption in the process of transportation and storage.
4.渗透性和粘附性强、抗蒸发、耐雨水冲刷、持效期长、耐贮藏、对作物安全、增产明显。4. Strong permeability and adhesion, anti-evaporation, rain-resistant, long-lasting, storage-resistant, safe for crops, and obvious increase in production.
经过室内和田间试验证明,本发明可用于水稻田中防除稗草,对水稻安全、杀草谱广,一次用药可以控制水稻整个生长期的稗草,用药方法为杂草一心一叶期至四叶期间兑水稀释200-1000倍均匀喷雾,本发明提供了一种优良芽后微生物除草剂新剂型品种,贮藏期内稳定,对环境友好、增产明显。Indoor and field tests have proved that the present invention can be used to control barnyardgrass in paddy fields, is safe for rice, has a wide herbicidal spectrum, and can control barnyardgrass in the whole growth period of rice with one application of medicine. During the period, it is diluted with water for 200-1000 times and sprayed evenly. The invention provides a new formulation variety of an excellent post-emergent microbial herbicide, which is stable during storage, friendly to the environment and significantly increases production.
具体实施方式 Detailed ways
结合本发明的具体内容提供以下实施例:The following embodiments are provided in conjunction with the specific content of the present invention:
实施例1.新月弯孢霉菌B6(Curvularia lunata)6×108个孢子/ml,十二烷基苯磺酸钙2g,壬基酚聚氧乙烯醚(n=20)6g,脲2g,白碳黑0.2g,脱臭煤油补齐至100ml,放入砂磨机中研磨5小时,使其平均粒径为4μm左右,即得100ml油悬浮剂产品,按照FAO相关标准,该制剂的冷、热贮藏稳定性合格,按50ml/亩剂量兑水30公斤于水稻移栽田稗草两叶一心时施药,30天后测得对稗草鲜重防除率为93.8%。Embodiment 1. Curvularia lunata mold B6 (Curvularia lunata) 6 × 10 spores/ml, calcium dodecylbenzenesulfonate 2g, nonylphenol polyoxyethylene ether (n=20) 6g, urea 2g, White carbon black 0.2g, make up to 100ml with deodorized kerosene, put it into a sand mill and grind for 5 hours, so that its average particle size is about 4 μm, and then 100ml of oil suspension product is obtained. According to the relevant standards of FAO, the cold, The thermal storage stability is qualified, and the dose of 50ml/mu is mixed with 30 kg of water when the two leaves of the barnyardgrass are applied in the rice transplanting field. After 30 days, the control rate of the fresh weight of the barnyardgrass is 93.8%.
实施例2.新月弯孢霉菌B6(Curvularia lunata)2×108个孢子/ml,木质素磺酸钙2g,蓖麻油聚氧乙烯醚(n=15)2g,海泡石5g,海藻酸1g,花生油补齐至100ml,放入球磨机中研磨4小时,使其平均粒径为4μm左右,即得100ml油悬浮剂产品,按照FAO相关标准,该制剂的冷、热贮藏稳定性合格,按150ml/亩剂量兑水30公斤于水稻抛秧田两叶一心时施药,30天后测得对杂草鲜重防除率为96.5%。Example 2. Curvularia lunata B6 (Curvularia lunata) 2 × 10 8 spores/ml, calcium lignosulfonate 2g, castor oil polyoxyethylene ether (n=15) 2g, sepiolite 5g, alginic acid 1g, filled with peanut oil to 100ml, put it into a ball mill and grind it for 4 hours, so that the average particle size is about 4μm, and then 100ml of oil suspension product is obtained. According to the relevant standards of FAO, the cold and hot storage stability of this preparation is qualified. 150ml/mu dosage mixed with 30kg of water was applied when two leaves were united in the paddy seedling throwing field, and the fresh weight control rate of weeds was 96.5% after 30 days.
实施例3.新月弯孢霉菌B6(Curvularia lunata)0.3×108个孢子/ml,萘磺酸甲醛缩合物的钠盐(NNO)3g,蓖麻油聚氧乙烯醚(n=15)5g,粘土1g,蔗糖1g,棕榈油齐至100ml,放入砂磨机中研磨3小时,使其平均粒径为4μm左右,即得100ml油悬浮剂产品,按照FAO相关标准,该制剂的冷、热贮藏稳定性合格,按750ml/亩剂量兑水30公斤于水稻秧田三叶期时施药,30天后测得对杂草鲜重防除率为91.6%。Example 3. Curvularia lunata B6 (Curvularia lunata) 0.3 × 108 spores/ml, sodium salt (NNO) 3g of naphthalenesulfonic acid formaldehyde condensate, castor oil polyoxyethylene ether (n=15) 5g, 1g of clay, 1g of sucrose, and 100ml of palm oil are put into a sand mill and ground for 3 hours, so that the average particle size is about 4μm, and 100ml of oil suspension product is obtained. According to the relevant standards of FAO, the cold and hot The storage stability is qualified, and the dosage of 750ml/mu is mixed with 30 kilograms of water in the rice seedling field at the three-leaf stage. After 30 days, the fresh weight control rate of weeds is 91.6%.
Claims (7)
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