CN101805095B - Leachate Treatment and Reuse Method of Garbage Transfer Station - Google Patents
Leachate Treatment and Reuse Method of Garbage Transfer Station Download PDFInfo
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- 238000012546 transfer Methods 0.000 title claims abstract description 19
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- 239000012528 membrane Substances 0.000 claims abstract description 23
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 claims abstract description 13
- 244000005700 microbiome Species 0.000 claims abstract description 12
- 238000006731 degradation reaction Methods 0.000 claims abstract description 10
- 239000005416 organic matter Substances 0.000 claims abstract description 9
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- 239000007788 liquid Substances 0.000 claims description 10
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 9
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- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
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- BFNBIHQBYMNNAN-UHFFFAOYSA-N ammonium sulfate Chemical compound N.N.OS(O)(=O)=O BFNBIHQBYMNNAN-UHFFFAOYSA-N 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
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Abstract
本发明涉及一种垃圾中转站渗滤液处理与回用方法。它是通过厌氧去除大部分有机污染物,通过电催化氧化提高渗滤液可生化性,在好氧MBR反应器通过膜对微生物的截留作用强化生化过程,完成主要污染物的生物降解,保证出水水质。包括以下方法:(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(2)经过厌氧消化之后进入一级MBR进行好氧反应;(3)一级MBR出水流入电催化氧化塔进行电催化氧化;(4)提高可生化性之后,进入二级MBR进行好氧生化反应,完成有机物和氨氮的降解。
The invention relates to a treatment and reuse method for leachate in a garbage transfer station. It removes most of the organic pollutants through anaerobic, improves the biodegradability of the leachate through electrocatalytic oxidation, and strengthens the biochemical process through the interception of microorganisms by the membrane in the aerobic MBR reactor, completes the biodegradation of the main pollutants, and ensures the effluent water quality. Including the following methods: (1) The leachate produced by garbage compression enters the water storage well and is lifted into the regulating tank by the lift pump; (2) After anaerobic digestion, it enters the first-level MBR for aerobic reaction; (3) The first-level MBR effluent flows into the The electrocatalytic oxidation tower performs electrocatalytic oxidation; (4) After improving the biodegradability, it enters the secondary MBR for aerobic biochemical reaction to complete the degradation of organic matter and ammonia nitrogen.
Description
技术领域 technical field
本发明涉及一种垃圾中转站渗滤液处理与回用方法。The invention relates to a method for treating and reusing leachate in a garbage transfer station.
背景技术 Background technique
CN200910111323.7公开了“一种垃圾渗滤液零排放回用处理方法”,它的目的是利用物化、生化、膜过滤联用技术,提供一种垃圾渗滤液零排放回用处理方法。该发明申请的技术方案是:将垃圾渗滤液原液送入原水调节池,出水经膜混凝反应器去除悬浮固体和杂质,膜混凝反应器的反冲洗出水回流至原水调节池,排出的废水进入膜接触反应器,形成副产品硫酸铵溶液;膜接触反应器出水进入升流式厌氧生物反应器,进行厌氧生化处理,将升流式厌氧生物反应器的出水送入膜生物反应器进行好氧生化处理;将膜生物反应器的出水送入连续膜过滤系统进行过滤,将连续膜过滤系统的浓缩液和反冲洗水回流至原水调节池;将连续膜过滤系统的出水送入反渗透系统,将反渗透系统的浓缩液经锅炉氧化喷烧去除,反渗透系统的出水即为可回用的纯水。其不足之处是:反渗透系统的使用,增加设备的维护难度,投资成本高,而产生的浓缩液也增加后续处理的工作量。氨氮和有机物的去处一大部分靠物理化学方法分离而非生物方法,加药量大,增加了运行成本。CN200910111323.7 discloses "a treatment method for zero discharge and reuse of landfill leachate", which aims to provide a treatment method for zero discharge and reuse of landfill leachate by using combined technologies of physicochemical, biochemical and membrane filtration. The technical solution of this invention application is: send the stock solution of landfill leachate into the raw water adjustment tank, remove the suspended solids and impurities from the effluent through the membrane coagulation reactor, return the backwash effluent from the membrane coagulation reactor to the raw water adjustment tank, and discharge the waste water Enter the membrane contact reactor to form a by-product ammonium sulfate solution; the effluent from the membrane contact reactor enters the upflow anaerobic bioreactor for anaerobic biochemical treatment, and the effluent from the upflow anaerobic bioreactor is sent to the membrane bioreactor Carry out aerobic biochemical treatment; send the effluent of the membrane bioreactor to the continuous membrane filtration system for filtration, return the concentrate and backwash water of the continuous membrane filtration system to the raw water adjustment tank; send the effluent of the continuous membrane filtration system to the reverse Osmosis system, the concentrated solution of the reverse osmosis system is oxidized and burned by the boiler to remove it, and the effluent of the reverse osmosis system is pure water that can be reused. Its disadvantages are: the use of reverse osmosis system increases the difficulty of equipment maintenance, high investment cost, and the concentrated solution produced also increases the workload of subsequent treatment. Most of the removal of ammonia nitrogen and organic matter is separated by physical and chemical methods rather than biological methods, and the amount of dosing is large, which increases the operating cost.
发明内容 Contents of the invention
本发明要解决的技术问题是提供一种通过厌氧去除大部分有机污染物,通过电催化氧化提高渗滤液可生化性,在好氧MBR反应器通过膜对微生物的截留作用强化生化过程,完成主要污染物的生物降解,保证出水水质,适合于垃圾中转站渗滤液的分散处理及就地回用的垃圾中转站渗滤液处理与回用方法。The technical problem to be solved in the present invention is to provide a method to remove most of the organic pollutants through anaerobic, improve the biodegradability of the leachate through electrocatalytic oxidation, and strengthen the biochemical process through the interception of the membrane to microorganisms in the aerobic MBR reactor. The biodegradation of the main pollutants ensures the quality of the effluent, which is suitable for the dispersive treatment and on-site reuse of the leachate in the garbage transfer station.
为了解决上述技术问题,本发明提出的技术方案是:In order to solve the problems of the technologies described above, the technical solution proposed by the present invention is:
所述垃圾中转站渗滤液处理与回用方法,其特殊之处在于,所述方法包括:The leachate treatment and reuse method of the garbage transfer station is special in that the method includes:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应;(2) After anaerobic digestion, enter the first-level MBR for aerobic reaction;
(3)一级MBR出水流入电催化氧化塔进行电催化氧化;(3) The effluent of the primary MBR flows into the electrocatalytic oxidation tower for electrocatalytic oxidation;
(4)提高可生化性之后,进入二级MBR进行好氧生化反应;(4) After improving biodegradability, enter the secondary MBR for aerobic biochemical reactions;
其中:in:
所述方法(2)的厌氧工艺可采用厌氧反应器;厌氧反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of the method (2) can adopt an anaerobic reactor; the start-up and domestication of the anaerobic reactor are carried out simultaneously, and the water inflow is small at the initial stage of start-up, and then the water inflow gradually increases until reaching the reactor design progress. water volume.
所述方法(3)一级MBR、方法(4)二级MBR均为内环流式膜生物反应器,反应器内设有中空纤维膜组件,通过膜组件对微生物进行截留,截留的微生物对有机污染物和氨氮进行生化降解;反应器的液位通过自动液位控制器与进水泵的联动来调节,由风机提供空气并通过微孔曝气器进行曝气,由自动程序控制器控制出水泵的开和停,出水泵采用间歇抽吸运行,抽吸频率可调,并定时反冲。The first-level MBR of the method (3) and the second-level MBR of the method (4) are all internal circulation membrane bioreactors, and a hollow fiber membrane module is provided in the reactor, and the microorganisms are intercepted by the membrane modules, and the intercepted microorganisms are harmful to the organic matter. Pollutants and ammonia nitrogen are biochemically degraded; the liquid level of the reactor is adjusted by the linkage between the automatic liquid level controller and the water inlet pump, the air is provided by the fan and aerated by the microporous aerator, and the water outlet pump is controlled by the automatic program controller The water outlet pump adopts intermittent suction operation, the suction frequency is adjustable, and the recoil is timed.
所述方法(3)的电催化氧化塔为改良的电芬顿Fenton反应装置,方法为将废铁屑与活性炭或焦炭按照公知比例和结构填充到电催化氧化塔内,并在填料的内两侧设置阴阳电极板,在电极板施加12~24V直流电压静电场,激发芬顿Fenton反应,同时曝气并投加工业用双氧水,形成微电解与芬顿反应的协同效应。The electrocatalytic oxidation tower of the method (3) is an improved electric Fenton reaction device, and the method is to fill the electrocatalytic oxidation tower with scrap iron scraps and activated carbon or coke according to the known ratio and structure, and fill the two sides of the filler with the electrocatalytic oxidation tower. The positive and negative electrode plates are installed on the side, and a 12-24V DC voltage electrostatic field is applied to the electrode plates to stimulate the Fenton reaction. At the same time, it is aerated and processed with industrial hydrogen peroxide to form a synergistic effect between micro-electrolysis and Fenton reaction.
所述厌氧反应器选用上流式厌氧污泥床反应器(UASB)、厌氧反应器(EGSB)、水解酸化池的一种。The anaerobic reactor is selected from one of an upflow anaerobic sludge bed reactor (UASB), an anaerobic reactor (EGSB), and a hydrolytic acidification tank.
本发明提出的第二个技术方案是:The second technical scheme that the present invention proposes is:
所述垃圾中转站渗滤液处理与回用方法,其特殊之处在于,所述方法包括:The leachate treatment and reuse method of the garbage transfer station is special in that the method includes:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应;(2) After anaerobic digestion, enter the first-level MBR for aerobic reaction;
(3)一级MBR出水流入电催化氧化塔进行电催化氧化,完成有机物和氨氮的降解;其中:(3) The effluent from the primary MBR flows into the electrocatalytic oxidation tower for electrocatalytic oxidation to complete the degradation of organic matter and ammonia nitrogen; where:
所述方法(2)的厌氧工艺可采用厌氧反应器;厌氧反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of the method (2) can adopt an anaerobic reactor; the start-up and domestication of the anaerobic reactor are carried out simultaneously, and the water inflow is small at the initial stage of start-up, and then the water inflow gradually increases until reaching the reactor design progress. water volume.
所述厌氧反应器选用上流式厌氧污泥床反应器(UASB)、厌氧反应器(EGSB)、水解酸化池的一种。The anaerobic reactor is selected from one of an upflow anaerobic sludge bed reactor (UASB), an anaerobic reactor (EGSB), and a hydrolytic acidification tank.
所述方法(3)一级MBR为内环流式膜生物反应器,反应器内设有中空纤维膜组件,通过膜组件对微生物进行截留,截留的微生物对有机污染物和氨氮进行生化降解;反应器的液位通过自动液位控制器与进水泵的联动来调节,由风机提供空气并通过微孔曝气器进行曝气,由自动程序控制器控制出水泵的开和停,出水泵采用间歇抽吸运行,抽吸频率可调,并定时反冲。The method (3) the first-level MBR is an internal circulation membrane bioreactor, and a hollow fiber membrane module is arranged in the reactor, and the microorganisms are intercepted by the membrane modules, and the intercepted microorganisms biochemically degrade organic pollutants and ammonia nitrogen; The liquid level of the device is adjusted through the linkage between the automatic liquid level controller and the water inlet pump. The air is provided by the fan and aerated through the microporous aerator. The automatic program controller controls the start and stop of the water outlet pump. The water outlet pump adopts intermittent Suction operation with adjustable suction frequency and timed recoil.
所述方法(3)的电催化氧化塔为改良的电芬顿Fenton反应装置,方法为将废铁屑与活性炭或焦炭按照公知比例和结构填充到电催化氧化塔内,并在填料的内两侧设置阴阳电极板,在电极板施加12~24V直流电压静电场,激发芬顿Fenton反应,同时曝气并投加工业用双氧水,形成微电解与芬顿反应的协同效应。The electrocatalytic oxidation tower of the method (3) is an improved electric Fenton reaction device, and the method is to fill the electrocatalytic oxidation tower with scrap iron scraps and activated carbon or coke according to the known ratio and structure, and fill the two sides of the filler with the electrocatalytic oxidation tower. The positive and negative electrode plates are installed on the side, and a 12-24V DC voltage electrostatic field is applied to the electrode plates to stimulate the Fenton reaction. At the same time, it is aerated and processed with industrial hydrogen peroxide to form a synergistic effect between micro-electrolysis and Fenton reaction.
本发明提出的第三个技术方案是:The third technical scheme that the present invention proposes is:
所述垃圾中转站渗滤液处理与回用方法,其特殊之处在于,所述方法包括:The leachate treatment and reuse method of the garbage transfer station is special in that the method includes:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应;(2) After anaerobic digestion, enter the first-level MBR for aerobic reaction;
其中:in:
所述方法(2)的厌氧工艺可采用厌氧反应器;厌氧反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of the method (2) can adopt an anaerobic reactor; the start-up and domestication of the anaerobic reactor are carried out simultaneously, and the water inflow is small at the initial stage of start-up, and then the water inflow gradually increases until reaching the reactor design progress. water volume.
所述厌氧反应器选用上流式厌氧污泥床反应器(UASB)、厌氧反应器(EGSB)、水解酸化池的一种。The anaerobic reactor is selected from one of an upflow anaerobic sludge bed reactor (UASB), an anaerobic reactor (EGSB), and a hydrolytic acidification tank.
与现有技术相比,本发明的有益效果是;Compared with the prior art, the beneficial effects of the present invention are;
(1)通过“厌氧-MBRI-电催化氧化-MBRII”组合工艺处理后的出水平均COD≤30mg/L,NH3-N≤2mg/L,水质可以达到杂用水水质标准(见水质监测结果表);通过“厌氧-MBRI-电催化氧化”组合工艺处理后的出水平均COD≤60mg/L,NH3-N≤2mg/L,水质可以达到GB18918-2002一级排放标准,保证了出水水质,具体降解过程请参阅图1、图2所示。(1) After the combined process of "anaerobic-MBRI-electrocatalytic oxidation-MBRII", the effluent average COD≤30mg/L, NH 3 -N≤2mg/L, and the water quality can reach the water quality standard for miscellaneous water (see water quality monitoring results Table); after the combined process of "anaerobic-MBRI-electrocatalytic oxidation", the effluent average COD≤60mg/L, NH 3 -N≤2mg/L, and the water quality can reach the first-level discharge standard of GB18918-2002, ensuring that the effluent Water quality, please refer to Figure 1 and Figure 2 for the specific degradation process.
(2)该处理与回用方法具有高效提高可生化性、稳定降解COD、氮、磷等主要污染物,工艺简单,占地小,成本低的技术优势。(2) The treatment and recycling method has the technical advantages of efficiently improving biodegradability, stably degrading major pollutants such as COD, nitrogen, and phosphorus, simple process, small footprint, and low cost.
(3)该处理与回用方法将“厌氧-MBRI-电催化氧化-MBR II”组合为一体式污水处理装置,用于垃圾中转站渗滤液的有效降解并给出了厌氧反应、电催化氧化、好氧MBR反应器的运行条件及结构特征。(3) The treatment and reuse method combines "anaerobic-MBRI-electrocatalytic oxidation-MBR II" into an integrated sewage treatment device, which is used for the effective degradation of leachate in the garbage transfer station and provides anaerobic reaction, electrocatalytic oxidation The operating conditions and structural characteristics of catalytic oxidation and aerobic MBR reactors.
附图说明 Description of drawings
图1是本发明COD降解过程示意图。Fig. 1 is a schematic diagram of the COD degradation process of the present invention.
图2是本发明氨氮降解过程示意图。Fig. 2 is a schematic diagram of the degradation process of ammonia nitrogen in the present invention.
具体实施方式 Detailed ways
下面将结合实施例对本发明作进一步详述:The present invention will be described in further detail below in conjunction with embodiment:
【实施例1】【Example 1】
用于城市垃圾中转站渗滤液处理与回用方法,包括以下方法:The leachate treatment and reuse methods used in urban waste transfer stations include the following methods:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应;(2) After anaerobic digestion, enter the first-level MBR for aerobic reaction;
(3)一级MBR出水流入电催化氧化塔进行电催化氧化;(3) The effluent of the primary MBR flows into the electrocatalytic oxidation tower for electrocatalytic oxidation;
(4)提高可生化性之后,进入二级MBR进行好氧生化反应,完成有机物和氨氮的降解。(4) After improving the biodegradability, enter the secondary MBR for aerobic biochemical reaction to complete the degradation of organic matter and ammonia nitrogen.
垃圾中转站渗滤液经该组合工艺处理后出水平均COD≤30mg/L,NH3-N≤2mg/L,水质可以达到杂用水水质标准(见水质监测结果表)。After the leachate of the garbage transfer station is treated by this combination process, the average COD ≤ 30mg/L, NH 3 -N ≤ 2mg/L, and the water quality can meet the water quality standard for miscellaneous water (see the water quality monitoring results table).
其中:in:
所述方法(2)的厌氧工艺采用上流式厌氧污泥床反应器UASB、厌氧反应器EGSB、水解酸化等厌氧反应器;反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of described method (2) adopts anaerobic reactors such as upflow anaerobic sludge bed reactor UASB, anaerobic reactor EGSB, hydrolytic acidification; The amount of water is small, and then the amount of water inflow gradually increases until it reaches the design water amount of the reactor.
所述方法(3)一级MBR、方法(4)二级MBR均为内环流式膜生物反应器,反应器内设有中空纤维膜组件,通过膜组件对微生物进行截留,截留的微生物对有机污染物和氨氮进行生化降解;反应器的液位通过自动液位控制器与进水泵的联动来调节,由风机提供空气并通过微孔曝气器进行曝气,由自动程序控制器控制出水泵的开和停,出水泵采用间歇抽吸运行,抽吸频率可调,并定时反冲。The first-level MBR of the method (3) and the second-level MBR of the method (4) are all internal circulation membrane bioreactors, and a hollow fiber membrane module is provided in the reactor, and the microorganisms are intercepted by the membrane modules, and the intercepted microorganisms are harmful to the organic matter. Pollutants and ammonia nitrogen are biochemically degraded; the liquid level of the reactor is adjusted by the linkage between the automatic liquid level controller and the water inlet pump, the air is provided by the fan and aerated by the microporous aerator, and the water outlet pump is controlled by the automatic program controller The water outlet pump adopts intermittent suction operation, the suction frequency is adjustable, and the recoil is timed.
所述方法(3)的电催化氧化塔为改良的电芬顿Fenton反应装置,方法为将废铁屑与活性炭或焦炭按照公知比例和结构填充到电催化氧化塔内,并在填料的内两侧设置阴阳电极板,在电极板施加12~24V直流电压静电场,激发芬顿Fenton反应,同时曝气并投加工业用双氧水,形成微电解与芬顿反应的协同效应。The electrocatalytic oxidation tower of the method (3) is an improved electric Fenton reaction device, and the method is to fill the electrocatalytic oxidation tower with scrap iron scraps and activated carbon or coke according to the known ratio and structure, and fill the two sides of the filler with the electrocatalytic oxidation tower. The positive and negative electrode plates are installed on the side, and a 12-24V DC voltage electrostatic field is applied to the electrode plates to stimulate the Fenton reaction. At the same time, it is aerated and processed with industrial hydrogen peroxide to form a synergistic effect between micro-electrolysis and Fenton reaction.
【实施例2】[Example 2]
用于城市垃圾中转站渗滤液处理与回用方法,包括以下方法:The leachate treatment and reuse methods used in urban waste transfer stations include the following methods:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应;(2) After anaerobic digestion, enter the first-level MBR for aerobic reaction;
(3)一级MBR出水流入电催化氧化塔进行电催化氧化,完成有机物和氨氮的降解。(3) The effluent of the primary MBR flows into the electrocatalytic oxidation tower for electrocatalytic oxidation to complete the degradation of organic matter and ammonia nitrogen.
垃圾中转站渗滤液经该组合工艺处理后的出水平均COD≤60mg/L,NH3-N≤2mg/L,水质可以达到GB18918-2002一级排放标准。After the leachate of the garbage transfer station is treated by this combination process, the average COD ≤ 60mg/L, NH 3 -N ≤ 2mg/L, and the water quality can meet the first-level discharge standard of GB18918-2002.
其中:in:
所述方法(2)的厌氧工艺采用上流式厌氧污泥床反应器UASB、厌氧反应器EGSB、水解酸化等厌氧反应器;反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of described method (2) adopts anaerobic reactors such as upflow anaerobic sludge bed reactor UASB, anaerobic reactor EGSB, hydrolytic acidification; The amount of water is small, and then the amount of water inflow gradually increases until it reaches the design water amount of the reactor.
所述方法(3)一级MBR为内环流式膜生物反应器,反应器内设有中空纤维膜组件,通过膜组件对微生物进行截留,截留的微生物对有机污染物和氨氮进行生化降解;反应器的液位通过自动液位控制器与进水泵的联动来调节,由风机提供的空气通过微孔曝气器进行曝气,由自动程序控制器控制出水泵的开和停,出水泵采用间歇抽吸运行,抽吸频率可调,并定时反冲。The method (3) the first-level MBR is an internal circulation membrane bioreactor, and a hollow fiber membrane module is arranged in the reactor, and the microorganisms are intercepted by the membrane modules, and the intercepted microorganisms biochemically degrade organic pollutants and ammonia nitrogen; The liquid level of the device is adjusted through the linkage between the automatic liquid level controller and the water inlet pump. The air provided by the fan is aerated through the microporous aerator, and the automatic program controller controls the opening and stopping of the water outlet pump. The water outlet pump adopts intermittent Suction operation with adjustable suction frequency and timed recoil.
所述方法(3)的电催化氧化塔为改良的电芬顿Fenton反应装置,方法为将废铁屑与活性炭或焦炭按照公知比例和结构填充到电催化氧化塔内,并在填料的内两侧设置阴阳电极板,在电极板施加12~24V直流电压静电场,激发芬顿Fenton反应,同时曝气并投加工业用双氧水,形成微电解与芬顿反应的协同效应。The electrocatalytic oxidation tower of the method (3) is an improved electric Fenton reaction device, and the method is to fill the electrocatalytic oxidation tower with scrap iron scraps and activated carbon or coke according to the known ratio and structure, and fill the two sides of the filler with the electrocatalytic oxidation tower. The positive and negative electrode plates are installed on the side, and a 12-24V DC voltage electrostatic field is applied to the electrode plates to stimulate the Fenton reaction. At the same time, it is aerated and processed with industrial hydrogen peroxide to form a synergistic effect between micro-electrolysis and Fenton reaction.
【实施例3】[Example 3]
用于城市垃圾中转站渗滤液处理与回用方法,包括以下方法:The leachate treatment and reuse methods used in urban waste transfer stations include the following methods:
(1)垃圾压缩产生的渗滤液进入储水井,经提升泵提升进入调节池;(1) The leachate produced by garbage compression enters the water storage well, and is lifted into the regulating pool by the lift pump;
(2)经过厌氧消化之后进入一级MBR进行好氧反应,完成有机物和氨氮的降解。(2) After anaerobic digestion, enter the first-stage MBR for aerobic reaction to complete the degradation of organic matter and ammonia nitrogen.
垃圾中转站渗滤液经该组合工艺处理后出水水质COD≤150mg/L,NH3-N≤20mg/L,水质可以达到GB18918-2002三级排放标准。After the leachate of the garbage transfer station is treated by this combination process, the effluent water quality COD≤150mg/L, NH 3 -N≤20mg/L, and the water quality can reach the third-level discharge standard of GB18918-2002.
其中:in:
所述方法(2)的厌氧工艺采用上流式厌氧污泥床反应器UASB、厌氧反应器EGSB、水解酸化等厌氧反应器;反应器的启动和驯化是同时进行的,启动初期进水量较小,随后进水量逐渐增大,直至达到反应器设计进水量。The anaerobic process of described method (2) adopts anaerobic reactors such as upflow anaerobic sludge bed reactor UASB, anaerobic reactor EGSB, hydrolytic acidification; The amount of water is small, and then the amount of water inflow gradually increases until it reaches the design water amount of the reactor.
以上所述仅为本发明的较佳实施例,凡依本发明权利要求范围所做的均等变化与修饰,皆应属本发明权利要求的涵盖范围。The above descriptions are only preferred embodiments of the present invention, and all equivalent changes and modifications made according to the scope of the claims of the present invention shall fall within the scope of the claims of the present invention.
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