CN101802236A - High-strength steel sheet for can manufacturing and process for manufaturing the sheet - Google Patents
High-strength steel sheet for can manufacturing and process for manufaturing the sheet Download PDFInfo
- Publication number
- CN101802236A CN101802236A CN200880106279A CN200880106279A CN101802236A CN 101802236 A CN101802236 A CN 101802236A CN 200880106279 A CN200880106279 A CN 200880106279A CN 200880106279 A CN200880106279 A CN 200880106279A CN 101802236 A CN101802236 A CN 101802236A
- Authority
- CN
- China
- Prior art keywords
- steel sheet
- martensite
- strength
- strength steel
- ferrite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/06—Ferrous alloys, e.g. steel alloys containing aluminium
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D1/00—General methods or devices for heat treatment, e.g. annealing, hardening, quenching or tempering
- C21D1/18—Hardening; Quenching with or without subsequent tempering
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0226—Hot rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0221—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the working steps
- C21D8/0236—Cold rolling
-
- C—CHEMISTRY; METALLURGY
- C21—METALLURGY OF IRON
- C21D—MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
- C21D8/00—Modifying the physical properties by deformation combined with, or followed by, heat treatment
- C21D8/02—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips
- C21D8/0247—Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of plates or strips characterised by the heat treatment
- C21D8/0273—Final recrystallisation annealing
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/001—Ferrous alloys, e.g. steel alloys containing N
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/02—Ferrous alloys, e.g. steel alloys containing silicon
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/04—Ferrous alloys, e.g. steel alloys containing manganese
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/48—Ferrous alloys, e.g. steel alloys containing chromium with nickel with niobium or tantalum
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/50—Ferrous alloys, e.g. steel alloys containing chromium with nickel with titanium or zirconium
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C38/00—Ferrous alloys, e.g. steel alloys
- C22C38/18—Ferrous alloys, e.g. steel alloys containing chromium
- C22C38/40—Ferrous alloys, e.g. steel alloys containing chromium with nickel
- C22C38/54—Ferrous alloys, e.g. steel alloys containing chromium with nickel with boron
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Thermal Sciences (AREA)
- Crystallography & Structural Chemistry (AREA)
- Heat Treatment Of Sheet Steel (AREA)
- Metal Rolling (AREA)
Abstract
本发明提供了可通过ASTM的规定、并且可兼顾强度和延性的加工性优良的制罐用高强度薄钢板,制品板厚t为0.1~0.5mm的制罐用高强度薄钢板的特征在于:具有如下钢组成:以质量%计含有C:0.04~0.13%、Si:大于0.01%且为0.03%以下、Mn:0.1~0.6%、P:0.02%以下、S:0.03%以下、Al:0.01~0.2%、N:0.001~0.02%,余量由Fe及不可避免的杂质构成;且钢组织是以铁素体为主体的铁素体与马氏体的复合组织,将马氏体分率规定为5%以上、且低于30%,马氏体粒径d(μm)和制品板厚t(mm)满足下式<A>,30T硬度为60以上。1.0<(1-EXP(-t×3.0))×4/d 式<A>。
The present invention provides a high-strength steel sheet for can making that can pass the regulations of ASTM and has excellent workability in both strength and ductility. The high-strength steel sheet for can making with a product thickness t of 0.1 to 0.5 mm is characterized by: It has the following steel composition: C: 0.04 to 0.13% by mass %, Si: more than 0.01% to 0.03%, Mn: 0.1 to 0.6%, P: 0.02% or less, S: 0.03% or less, Al: 0.01 ~0.2%, N: 0.001~0.02%, the balance is composed of Fe and unavoidable impurities; and the steel structure is a composite structure of ferrite and martensite with ferrite as the main body, and the martensite fraction It is defined as 5% or more and less than 30%, the martensite grain size d (μm) and the product plate thickness t (mm) satisfy the following formula <A>, and the 30T hardness is 60 or more. 1.0<(1-EXP(-t×3.0))×4/d Formula <A>.
Description
技术领域technical field
本发明涉及作为食品罐及饮料罐的原材料使用的制罐用高强度薄钢板及其制造方法。这里所谓的高强度薄钢板,指的是抗拉强度为590MPa以上的薄钢板。The present invention relates to a high-strength thin steel sheet for can making used as a raw material for food cans and beverage cans and a method for producing the same. Here, the high-strength thin steel sheet refers to a thin steel sheet with a tensile strength of 590 MPa or more.
背景技术Background technique
作为制罐用钢板,一般使用制品板厚t为0.1~0.5mm的冷压薄钢板。作为制罐用钢板,强度越高越能减薄制品板厚t,因而要求尽量高的强度。As steel sheets for can making, cold-rolled thin steel sheets having a product sheet thickness t of 0.1 to 0.5 mm are generally used. As a steel plate for can making, the higher the strength, the thinner the plate thickness t of the product, and therefore, as high a strength as possible is required.
因此,以往一般是采用2次冷轧法制造制罐用高强度薄钢板。这种方法例如如日本特公昭38-8563号公报及日本特开平8-5039号公报中所述,是在1次冷轧后对钢板进行退火,然后再进行第2次的冷轧将硬度调整到规定值的方法。除此以外,还提出了对含有粗大晶粒的软质热轧板进行冷轧的方法等。Therefore, in the past, high-strength thin steel sheets for cans were generally produced by the secondary cold rolling method. This method, for example, as described in Japanese Patent Publication No. 38-8563 and Japanese Patent Application Publication No. 8-5039, is to anneal the steel plate after the first cold rolling, and then carry out the second cold rolling to adjust the hardness. method to a specified value. In addition, a method of cold-rolling a soft hot-rolled sheet containing coarse crystal grains, etc. have also been proposed.
可是,利用这些以往技术制造的制罐用高强度薄钢板具有加工性非常低的缺陷,在制罐工序中容易发生成形不良。特别是在最终工序为冷轧的情况下,由于成品由延性低的冷轧组织形成,因此上述倾向更明显。此外还提出了冷轧后进行消除应力退火的方法,但由于不会使钢板再结晶,因此同样延性还是低。However, the high-strength thin steel sheets for can-making produced by these conventional techniques have a defect that the workability is very low, and forming defects tend to occur in the can-making process. In particular, when the final step is cold rolling, the above-mentioned tendency is more pronounced because the finished product is formed of a cold-rolled structure with low ductility. In addition, a method of performing stress relief annealing after cold rolling has been proposed, but the ductility is also low because the steel sheet is not recrystallized.
因此,这些制罐用高强度薄钢板在以弯曲加工为主体、不太要求延性时能够使用,但在要求大的延性时不能使用。再有,近年来,由于罐用原材料急速向薄壁化发展,因此有钢板的延性越发降低的倾向,存在不能与食品罐及饮料罐的设计变化相对应的问题。这样,对于制罐用钢板有强度和延性的要求。Therefore, these high-strength thin steel sheets for can making can be used when bending is the main part and ductility is not very required, but they cannot be used when high ductility is required. In addition, in recent years, due to rapid thinning of can materials, the ductility of steel sheets tends to decrease, and there is a problem that it cannot cope with changes in the design of food and beverage cans. In this way, strength and ductility are required for steel sheets for can making.
再者,对于汽车用钢板也有强度和延性的要求,在该技术领域中,如日本特开2004-285366号公报中所述,提出了通过形成延性优良的铁素体相和硬质的析出相的2相(DP)组织来兼顾延性和强度的方案。可是,与汽车用钢板不同,对于食品罐及饮料罐的钢板,从对人体的无害性的观点出发,ASTM严格限制了合金成分,因此不能将汽车用钢板的制法应用于制罐用高强度薄钢板。例如,在日本特开2004-285366号公报的发明中,通过含有1.5~3.5%的Mn使晶粒微细化,但在ASTM中将Mn的上限规定为0.6%,因而上述Mn的范围是不标准的。Furthermore, steel sheets for automobiles are also required for strength and ductility. In this technical field, as described in JP-A-2004-285366, it has been proposed to form a ferrite phase with excellent ductility and a hard precipitated phase. The 2-phase (DP) organization is a solution that takes into account both ductility and strength. However, unlike steel sheets for automobiles, for steel sheets for food cans and beverage cans, ASTM strictly limits the alloy composition from the viewpoint of harmlessness to the human body, so the manufacturing method of steel sheets for automobiles cannot be applied to high-grade steel sheets for cans. Strength thin steel plate. For example, in the invention of Japanese Unexamined Patent Application Publication No. 2004-285366, crystal grains are refined by containing 1.5 to 3.5% of Mn, but the upper limit of Mn is specified as 0.6% in ASTM, so the range of Mn mentioned above is not standard. of.
此外,如果将制品板厚t减薄为0.1~0.5mm,则无法获得在汽车用钢板中体现的的延伸改善。认为这是因为,在极薄材料中因板厚薄而容易发生马氏体与铁素体界面的应力集中。而且如果为了能够通过ASTM而降低合金成分,则马氏体的粒径增大。因这些理由,不可能将汽车用钢板的DP技术应用于制罐用高强度薄钢板,无法兼顾强度和延性。In addition, if the product sheet thickness t is reduced to 0.1 to 0.5 mm, the elongation improvement shown in the steel sheet for automobiles cannot be obtained. This is considered to be because, in an extremely thin material, stress concentration at the interface between martensite and ferrite tends to occur due to the thin plate thickness. Furthermore, if the alloy composition is reduced in order to pass ASTM, the grain size of martensite increases. For these reasons, it is impossible to apply the DP technology of steel sheets for automobiles to high-strength thin steel sheets for can making, and it is impossible to achieve both strength and ductility.
发明内容Contents of the invention
因此,本发明的目的是解决上述以往的问题点,提供一种可通过ASTM的规定、并可兼顾强度和延性的加工性优良的制罐用高强度薄钢板。再者,ASTM的罐用钢板的合金成分的规定上限值如下。Therefore, an object of the present invention is to solve the above-mentioned conventional problems and provide a high-strength steel sheet for can making that can pass the ASTM regulations and has both strength and ductility and excellent workability. In addition, the prescribed upper limit value of the alloy composition of the steel plate for cans of ASTM is as follows.
C:0.13%、Mn:0.60%、P:0.020%、S:0.03%、Si:0.020%、Cu:0.60%、Ni:0.15%、Cr:0.10%、Mo:0.05%、Al:0.20%、其它:0.02%。但是,在是Al镇静钢时容许Si:0.03%。C: 0.13%, Mn: 0.60%, P: 0.020%, S: 0.03%, Si: 0.020%, Cu: 0.60%, Ni: 0.15%, Cr: 0.10%, Mo: 0.05%, Al: 0.20%, Other: 0.02%. However, Si: 0.03% is allowed in the case of Al-killed steel.
为解决上述问题而完成的本发明的第1发明是制品板厚t为0.1~0.5mm的制罐用高强度薄钢板,其特征在于:The first invention of the present invention made to solve the above-mentioned problems is a high-strength thin steel plate for can making with a product plate thickness t of 0.1 to 0.5 mm, characterized in that:
所述制罐用高强度薄钢板具有如下钢组成:以质量%计含有C:0.04~0.13%、Si:大于0.01%且为0.03%以下、Mn:0.1~0.6%、P:0.02%以下、S:0.03%以下、Al:0.01~0.2%、N:0.001~0.02%,余量由Fe及不可避免的杂质构成;The high-strength thin steel sheet for can-making has a steel composition as follows: C: 0.04 to 0.13%, Si: more than 0.01% to 0.03%, Mn: 0.1 to 0.6%, P: 0.02% or less, S: 0.03% or less, Al: 0.01-0.2%, N: 0.001-0.02%, the balance is composed of Fe and unavoidable impurities;
钢组织是以铁素体为主体的铁素体与马氏体的复合组织;The steel structure is a composite structure of ferrite and martensite with ferrite as the main body;
将马氏体分率规定在5%以上、且低于30%;The martensite fraction shall be above 5% and below 30%;
马氏体粒径d(μm)和制品板厚t(mm)满足下式<A>;Martensite particle size d (μm) and product plate thickness t (mm) satisfy the following formula <A>;
30T硬度为60以上。30T hardness is above 60.
1.0<(1-EXP(-t×3.0))×4/d 式(A)1.0<(1-EXP(-t×3.0))×4/d Formula (A)
此外,本发明的第2发明是制品板厚t为0.1~0.5mm的制罐用高强度薄钢板,其特征在于:Furthermore, the second invention of the present invention is a high-strength thin steel sheet for can making with a product sheet thickness t of 0.1 to 0.5 mm, characterized in that:
所述制罐用高强度薄钢板具有如下钢组成:以质量%计含有C:0.04~0.13%、Si:大于0.01%且为0.03%以下、Mn:0.1~0.6%、P:0.02%以下、S:0.03%以下、Al:0.01~0.2%、N:0.001~0.02%,余量由Fe及不可避免的杂质构成;The high-strength thin steel sheet for can-making has a steel composition as follows: C: 0.04 to 0.13%, Si: more than 0.01% to 0.03%, Mn: 0.1 to 0.6%, P: 0.02% or less, S: 0.03% or less, Al: 0.01-0.2%, N: 0.001-0.02%, the balance is composed of Fe and unavoidable impurities;
钢组织是以铁素体为主体的铁素体与马氏体的复合组织;The steel structure is a composite structure of ferrite and martensite with ferrite as the main body;
将马氏体分率规定为5%以上、且低于30%;The martensite fraction is specified as more than 5% and less than 30%;
马氏体粒径d(单位μm)、制品板厚t(mm)和马氏体硬度(Hv)满足下式<B>,30T硬度为60以上。Martensite particle size d (unit μm), product plate thickness t (mm) and martensite hardness (Hv) satisfy the following formula <B>, and the 30T hardness is 60 or more.
1.0<{(1-EXP(-t×3.0))×2400/Hv}/d 式<B>1.0<{(1-EXP(-t×3.0))×2400/Hv}/d Formula<B>
此外,本发明的第3发明是在第1或第2发明的钢组成中,以质量%计进一步含有Mo:0.05%以下、Ni:0.15%以下、Cr:0.10%以下、V:0.02%以下、B:0.02%以下、Nb:0.02%以下、Ti:0.02%以下中的1种或2种以上,从而能够提高淬火性。In addition, the third invention of the present invention is that in the steel composition of the first or second invention, Mo: 0.05% or less, Ni: 0.15% or less, Cr: 0.10% or less, V: 0.02% or less are further contained in mass % , B: 0.02% or less, Nb: 0.02% or less, Ti: 0.02% or less one or two or more can improve hardenability.
此外,本发明的第4发明是第1~第3发明中任一项所述的制罐用高强度薄钢板的制造方法,其特征在于:在精加工温度Ar3以上进行热精轧,然后在750℃以下的温度下进行了卷取后,以80%以上的冷轧率进行冷轧,在退火工序中,在Ar1以上且870℃以下的温度下保温3分钟以下后,将750℃至400℃的温度区以100℃/秒以上的冷却速度冷却到300℃以下。Furthermore, a fourth invention of the present invention is the method for producing a high-strength steel sheet for can making according to any one of the first to third inventions, characterized in that hot finish rolling is performed at a finishing temperature Ar of 3 or higher, and then After coiling at a temperature of 750°C or less, cold rolling is performed at a cold rolling ratio of 80 % or more. The temperature zone up to 400°C is cooled to below 300°C at a cooling rate of above 100°C/sec.
再者,本发明的第5发明优选的是在第4发明中,热精轧的精加工温度为Ar3以上且920℃以下,其后的冷却工序中的从850℃到600℃的平均冷却速度为20℃/秒以上,将卷取温度规定为550℃以下。Furthermore, in the fifth invention of the present invention, in the fourth invention, it is preferable that the finishing temperature of the hot finish rolling is not less than Ar 3 and not more than 920°C, and the average cooling from 850°C to 600°C in the subsequent cooling step is preferably The speed is 20°C/sec or more, and the coiling temperature is set to be 550°C or less.
根据本发明的第1~第2发明,通过与制品板厚t对应地控制马氏体粒径d,从而能够得到可通过ASTM的规定、并兼顾了强度和延性的制罐用高强度薄钢板。再者,第2发明考虑了制品板厚t和马氏体硬度Hv而控制马氏体粒径d,从而能够以更高的水平兼顾强度和延性。According to the first to second inventions of the present invention, by controlling the martensite grain size d in accordance with the thickness t of the product, it is possible to obtain a high-strength steel sheet for can making that satisfies ASTM regulations and has both strength and ductility . Furthermore, in the second invention, the martensite grain size d is controlled in consideration of the product plate thickness t and the martensite hardness Hv, thereby achieving both strength and ductility at a higher level.
此外,根据本发明的第3发明,通过添加促进马氏体析出的合金元素,能够改善淬火性,通过添加可补充强度不足的合金元素能够提高强度。再者,罐可被再循环再利用,但在第3发明的合金成分中,不含在再循环工序中成为障碍的元素(难以除去的元素)。In addition, according to the third aspect of the present invention, hardenability can be improved by adding alloy elements that promote martensite precipitation, and strength can be improved by adding alloy elements that can supplement insufficient strength. In addition, the can can be recycled and reused, but the alloy composition of the third invention does not contain elements (elements that are difficult to remove) that become obstacles in the recycling process.
此外,根据本发明的第4、第5发明,能够在不将冷轧重复2次的情况下,高效率地制造按本发明的第1~第3发明所述地控制了马氏体粒径d的制罐用高强度薄钢板。In addition, according to the fourth and fifth inventions of the present invention, it is possible to efficiently produce steel sheets with martensite particle diameters controlled as described in the first to third inventions of the present invention without repeating cold rolling twice. d's high-strength thin steel plate for canning.
附图说明Description of drawings
图1是对于延伸率的良否按板厚和马氏体粒径整理而得到的图。Fig. 1 is a graph showing whether elongation is good or bad according to plate thickness and martensite grain size.
图2是对延伸率的良否按马氏体的超微小维氏硬度和马氏体粒径整理而得到的图。Fig. 2 is a graph showing whether the elongation is good or not according to the ultra-fine Vickers hardness of martensite and the grain size of martensite.
具体实施方式Detailed ways
本发明的制罐用高强度薄钢板具有如下钢组成:以质量%计含有C:0.04~0.13%、Si:大于0.01%且为0.03%以下、Mn:0.1~0.6%、P:0.02%以下、S:0.03%以下、A1:0.01~0.2%、N:0.001~0.02%,余量由Fe及不可避免的杂质构成,因而首先对各成分的数值的限定理由进行说明。The high-strength thin steel sheet for can making according to the present invention has a steel composition containing, by mass %, C: 0.04 to 0.13%, Si: more than 0.01% to 0.03%, Mn: 0.1 to 0.6%, and P: 0.02% or less , S: 0.03% or less, A1: 0.01 to 0.2%, N: 0.001 to 0.02%, and the balance is composed of Fe and unavoidable impurities. Therefore, the reason for limiting the numerical values of each component will be described first.
C:0.04~0.13%C: 0.04 to 0.13%
关于C,为了确保罐用钢板所必要的强度,将其规定为0.04%以上。可是如果超过0.13%,则不能通过ASTM,因此将C限定在0.04~0.13%的范围。更优选根据作为目的的钢板强度水平来限定,但如果C量增多,则有得到的马氏体的强度提高的倾向,因此为了高平衡地兼顾延伸率和强度,优选C量为0.04%以上、且低于0.07%。Regarding C, in order to secure the strength required for steel sheets for cans, it is specified to be 0.04% or more. However, if it exceeds 0.13%, ASTM cannot be passed, so C is limited to the range of 0.04 to 0.13%. It is more preferable to limit according to the target steel sheet strength level, but if the amount of C increases, the strength of the obtained martensite tends to increase, so in order to achieve a high balance between elongation and strength, the amount of C is preferably 0.04% or more. And less than 0.07%.
Si:大于0.01%且为0.03%以下Si: more than 0.01% and less than 0.03%
Si是使热轧及冷轧中的变形阻力增加的元素,为了确保强度需要含有超过0.01%的量,更优选为0.015%以上。将其上限规定为ASTM规定的0.03%。Si is an element that increases deformation resistance during hot rolling and cold rolling, and needs to be contained in an amount exceeding 0.01% in order to secure strength, and more preferably 0.015% or more. Its upper limit is specified at 0.03% specified by ASTM.
Mn:0.1~0.6%Mn: 0.1-0.6%
Mn是防止S造成的热裂纹、抑制热轧板的强度增加、并提高冷轧钢板的强度、且使晶粒微细化的有用的元素,需要至少含有0.1%。通过使Mn含有0.1%以上,即使在卷取温度下的保温或从卷取温度缓冷程度的热过程中也容易在比较短的时间内发生马氏体相变。将其上限规定为ASTM规定的0.60%。更优选根据作为目的的强度水平进行规定,但由于Mn是固溶强化元素,因此有因添加量增大而提高强度的倾向,因此为了兼顾延伸率和强度,优选为0.1%以上、且低于0.5%。Mn is an element useful for preventing hot cracks caused by S, suppressing an increase in strength of a hot-rolled steel sheet, increasing the strength of a cold-rolled steel sheet, and refining crystal grains, and it needs to be contained at least 0.1%. By containing 0.1% or more of Mn, martensitic transformation easily occurs in a relatively short period of time even during heat retention at the coiling temperature or slow cooling from the coiling temperature. Its upper limit is specified at 0.60% as specified by ASTM. It is more preferable to specify according to the intended strength level, but since Mn is a solid-solution strengthening element, it tends to increase the strength by increasing the amount of addition, so in order to balance elongation and strength, it is preferably 0.1% or more and less than 0.1%. 0.5%.
P:0.02%以下P: less than 0.02%
P是使钢板延性降低的元素,此外P在钢中偏析的倾向强,导致起因于偏析的脆化。因此,优选尽量降低P,在本发明将其上限规定为0.02%。该上限与ASTM规定的值一致。P is an element that lowers the ductility of a steel sheet, and P tends to segregate strongly in steel, causing embrittlement due to segregation. Therefore, it is preferable to reduce P as much as possible, and the upper limit thereof is made 0.02% in the present invention. This upper limit is consistent with the value specified by ASTM.
S:0.03%以下S: 0.03% or less
S在钢中作为夹杂物存在,使钢板延性降低,进而使耐蚀性劣化,因此优选尽量降低其含量,在本发明将其上限规定为0.03%。该上限与ASTM规定的值一致。S exists as inclusions in steel, which lowers the ductility of the steel sheet and further deteriorates the corrosion resistance. Therefore, it is preferable to reduce its content as much as possible, and the upper limit is set at 0.03% in the present invention. This upper limit is consistent with the value specified by ASTM.
A1:0.01~0.2%A1: 0.01 to 0.2%
Al是作为脱氧剂发挥作用、提高钢的清洁度、并具有使组织微细化的作用的有用的元素。为了得到这样的效果,优选含有0.01%以上。此外,将其上限规定为ASTM规定的0.2%。Al is a useful element that functions as a deoxidizer, improves the cleanliness of steel, and has a function of making the structure finer. In order to obtain such an effect, it is preferable to contain 0.01% or more. In addition, the upper limit thereof is specified as 0.2% specified by ASTM.
N:0.001~0.02%N: 0.001~0.02%
N是具有通过固溶强化、应变时效硬化来提高钢板强度(屈服强度及抗拉强度)的作用的元素,为了得到这样的效果,需要含有0.001%以上。此外,如果含有超过0.02%,则导致板坯裂纹或钢板内部缺陷的增加,因此是不优选的。N is an element that has the effect of increasing the strength (yield strength and tensile strength) of the steel sheet through solid solution strengthening and strain age hardening, and in order to obtain such effects, it needs to be contained in an amount of 0.001% or more. Moreover, if it contains more than 0.02%, it will cause cracks in a slab and an increase in the internal defect of a steel plate, so it is unpreferable.
在本发明中,在上述基本的钢组成中,可以以质量%计进一步含有Mo:0.05%以下、Ni:0.15%以下、Cr:0.10%以下、V:0.02%以下、B:0.02%以下中的1种或2种以上。这些元素都是用于提高钢板的淬火性的成分,对于提高强度是有效的,但其上限根据ASTM如上所述地进行限制。这些成分的添加不是必须的,但在作为目的的强度高的情况下,最好适宜地添加。过剩的添加会抑制铁素体而涉及到延性降低,因此从这方面考虑上述范围是适当的。In the present invention, in the above-mentioned basic steel composition, Mo: 0.05% or less, Ni: 0.15% or less, Cr: 0.10% or less, V: 0.02% or less, B: 0.02% or less may be further contained in mass %. 1 or more than 2 types. These elements are components for improving the hardenability of the steel sheet and are effective for increasing the strength, but the upper limit thereof is limited by ASTM as described above. Addition of these components is not essential, but it is preferable to add them appropriately when the intended strength is high. Excessive addition suppresses ferrite and leads to a decrease in ductility, so it is appropriate to consider the above range from this point of view.
此外,在本发明中在上述基本的钢组成中,可以以质量%计进一步含有Nb:0.02%以下、Ti:0.02%以下中的1种或2种。它们都是析出强化元素,对于谋求提高强度是有效的。这些成分的上限值也根据ASTM如上所述地进行限制。用于提高上述退火性的成分和析出强化成分可以单独使用,也可以并用。In addition, in the present invention, one or two of Nb: 0.02% or less and Ti: 0.02% or less may be further contained in the above-mentioned basic steel composition in mass %. These are all precipitation strengthening elements, and are effective for improving strength. The upper limits of these components are also limited according to ASTM as described above. The components for improving the above-mentioned annealing properties and the precipitation strengthening components may be used alone or in combination.
本发明的制罐用高强度薄钢板具有上述钢组成,制品板厚t为0.1~0.5mm。在制品板厚t低于0.1mm时,难以用现行的技术进行制罐,超过0.5mm的板厚超出薄钢板的概念,因此将制品板厚t规定为0.1~0.5mm。更优选制品板厚t为0.1~0.3mm的范围。The high-strength thin steel plate for can making according to the present invention has the above-mentioned steel composition, and the product plate thickness t is 0.1 to 0.5 mm. When the product plate thickness t is less than 0.1 mm, it is difficult to make cans with the current technology, and the plate thickness exceeding 0.5 mm exceeds the concept of a thin steel plate, so the product plate thickness t is specified as 0.1 to 0.5 mm. More preferably, the product plate thickness t is in the range of 0.1 to 0.3 mm.
本发明的制罐用高强度薄钢板的钢组织为以铁素体为主体的铁素体与马氏体的复合组织。铁素体对于提高钢板加工性是必需的相,因而将其规定为主相。另一方面,为了提高钢板强度,马氏体在本发明中是必需的相,通过形成这些铁素体与马氏体的2相组织,可兼顾延性和强度。The steel structure of the high-strength thin steel sheet for can making according to the present invention is a composite structure of ferrite and martensite mainly composed of ferrite. Since ferrite is an essential phase for improving the workability of steel sheets, it is defined as the main phase. On the other hand, in order to increase the strength of the steel sheet, martensite is an essential phase in the present invention, and by forming a two-phase structure of these ferrite and martensite, both ductility and strength can be achieved.
再者,优选马氏体分率(马氏体在组织中所占的面积率)为5%以上且低于30%。因为如果马氏体低于5%,则强度不足,如果超过30%,则铁素体分率相对降低,使加工性下降。Furthermore, the martensite fraction (area ratio of martensite in the structure) is preferably 5% or more and less than 30%. This is because if the martensite is less than 5%, the strength will be insufficient, and if it exceeds 30%, the ferrite fraction will decrease relatively, and the workability will decrease.
在本发明的制罐用高强度薄钢板中,根据与制品板厚t(mm)的关系控制马氏体粒径d(μm),在第1发明中满足下式<A>。In the high-strength thin steel sheet for can making of the present invention, the martensite grain size d (μm) is controlled in relation to the product plate thickness t (mm), and the following formula <A> is satisfied in the first invention.
1.0<(1-EXP(-t×3.0))×4/d 式<A>1.0<(1-EXP(-t×3.0))×4/d Formula<A>
关于后述的实施例1的表2、表3(续表2),图1中横轴为板厚、纵轴为马氏体粒径,延伸率在5%以上的为合格,用○表示,低于5%的为不合格,用×表示,上述式<A>是通过自然对数对合格与不合格的界线进行近似而得到的。也就是说,如果制品板厚t接近0.1mm,则马氏体粒径d的上限接近1μm,如果制品板厚t接近0.3mm,则马氏体粒径d的上限接近2.5μm。之所以如此根据制品板厚t规定马氏体粒径d的上限,是因为与制品板厚t相比,如果硬质的马氏体粒径d增大,则加工性下降。Regarding Table 2 and Table 3 (continued from Table 2) of Example 1 described later, in Fig. 1, the abscissa represents the plate thickness, and the ordinate represents the martensite grain size, and those with an elongation of 5% or more are qualified, and are indicated by ○ , less than 5% is unqualified, represented by ×, the above formula <A> is obtained by approximating the boundary between qualified and unqualified by natural logarithm. That is, when the product thickness t is close to 0.1 mm, the upper limit of the martensite grain size d is close to 1 μm, and when the product thickness t is close to 0.3 mm, the upper limit of the martensite grain size d is close to 2.5 μm. The reason why the upper limit of the martensite grain size d is defined according to the product plate thickness t is that, if the hard martensite grain size d is larger than the product plate thickness t, the workability decreases.
此外,在第2发明中,设定为满足将上述<A>式的4/d置换为2400/Hv的式子整体除以马氏体粒径d(μm)而得出的下式<B>。In addition, in the second invention, it is set to satisfy the following formula <B obtained by substituting 4/d of the above formula <A> with 2400/Hv and dividing the whole formula by the martensite grain size d (μm). >.
1.0<{(1-EXP(-t×3.0))×2400/Hv}/d 式<B>1.0<{(1-EXP(-t×3.0))×2400/Hv}/d Formula<B>
关于后述的实施例2的表4、表5(续表4),图2中在制品板厚t(mm)=0.22mm时,横轴为马氏体的超微小维氏硬度、纵轴为马氏体粒径,将延伸率在5%以上的规定为合格,用○表示,将低于5%规定为不合格,用×表示,上述式<B>通过自然对数来近似于合格与不合格的界线。Regarding Table 4 and Table 5 (continued Table 4) of Example 2 described later, when the product plate thickness t (mm)=0.22mm in Fig. 2, the horizontal axis is the ultra-micro Vickers hardness of martensite, The axis is the martensite grain size, and the elongation rate of more than 5% is defined as qualified, and it is indicated by ○, and less than 5% is defined as unqualified, and it is indicated by ×. The above formula <B> is approximated by natural logarithm Pass and fail boundaries.
这里Hv是马氏体超微小维氏硬度,是测定方法采用例如岛津制作所制的HMV-1AD并根据组织将测定载荷规定为10g以下进行测定而得到的硬度。如果超微小维氏硬度Hv大于300,则马氏体粒径d的上限小于上式规定的值。Here, Hv is a martensitic ultra-fine Vickers hardness, and is a hardness obtained by measuring, for example, HMV-1AD manufactured by Shimadzu Corporation, and setting a measurement load to 10 g or less according to the structure. If the ultrafine Vickers hardness Hv is greater than 300, the upper limit of the martensite grain size d is smaller than the value specified by the above formula.
基于JISZ2245的30T对30T硬度进行评价,如果30T硬度低于60,则在用于罐的本体部时强度不足,因此60以上是必要的,可通过后述的100℃/秒以上的冷却速度及冷却到300℃以下的冷却来实现。上限没有特别的限定,但是,目前的通过急速冷却能达到的30T硬度的上限为90左右,将其看作是上限。再者,从延伸率和强度的平衡考虑,更优选为65~85。The hardness of 30T is evaluated based on 30T of JISZ2245. If the hardness of 30T is lower than 60, the strength is insufficient when used in the body of the tank. Therefore, 60 or more is necessary, and the cooling rate of 100°C/s or more described later and the Cooling to below 300°C is achieved. The upper limit is not particularly limited, but the current upper limit of the hardness of 30T that can be achieved by rapid cooling is about 90, which is regarded as the upper limit. Furthermore, it is more preferably 65-85 from the balance of elongation and strength.
以下对本发明的制罐用高强度薄钢板的制造方法进行说明。The method for producing the high-strength steel sheet for can making according to the present invention will be described below.
本发明的制罐用高强度薄钢板基本上是经热轧、卷取、冷轧、退火、急速冷却的工序而制造的,通过尽量在低温下进行热轧使热轧板的晶粒直径减小,通过以80%以上的高冷轧率对其进行冷轧使晶粒直径减小,通过在退火工序中产生奥氏体相变、并适当地控制急速冷却速度,从而使微细的马氏体产生。The high-strength thin steel sheet for can making of the present invention is basically manufactured through the processes of hot rolling, coiling, cold rolling, annealing, and rapid cooling. Small, by cold-rolling it at a high cold-rolling rate of 80% or more to reduce the grain size, by producing austenite transformation in the annealing process, and properly controlling the rapid cooling rate, so that the fine Martensite body produced.
首先,将热精轧的精加工温度规定为Ar3以上进行热轧。为了将冷轧钢板的粒径微细化,使热轧板的晶粒微细化是有效的,因此优选尽量降低热轧温度,优选规定为920℃以下。可是,如果热轧温度为Ar3以下,则因成为在铁素体-奥氏体的2相区的轧制而在热轧板表层产生粗大晶粒,在其后的工序中不能进行马氏体粒径d的微细化,因而优选将热精轧温度规定为Ar3以上、且920℃以下。First, hot rolling is performed by setting the finishing temperature of hot finish rolling to Ar 3 or higher. In order to refine the grain size of the cold-rolled steel sheet, it is effective to refine the crystal grains of the hot-rolled sheet. Therefore, it is preferable to lower the hot-rolling temperature as much as possible, and it is preferably set to 920° C. or lower. However, if the hot-rolling temperature is below Ar 3 , coarse grains will be formed on the surface of the hot-rolled sheet due to rolling in the ferrite-austenite two-phase region, and martensite cannot be performed in the subsequent process. Therefore, it is preferable to set the hot finish rolling temperature to Ar 3 or higher and 920° C. or lower.
对该热轧钢板进行冷却、卷取,但冷却工序中的从850℃到600℃的平均冷却速度优选为20℃/秒以上。这是因为,为了使热轧钢板的晶体的粒径细化,从850℃到600℃的冷却速度是重要的。如果该温度区的平均冷却速度低于20℃/秒则粒径增大,因而其后不能进行微细化。卷取温度为750℃以下、优选为550℃以下。因为如果卷取温度高于此温度,则在热轧阶段形成铁素体和珠光体的层状组织,损害均匀性,因此即使其后进行冷轧或退火,加工性也下降。The hot-rolled steel sheet is cooled and coiled, but the average cooling rate from 850°C to 600°C in the cooling step is preferably 20°C/sec or more. This is because the cooling rate from 850° C. to 600° C. is important in order to refine the crystal grain size of the hot-rolled steel sheet. If the average cooling rate in this temperature range is lower than 20° C./sec, the particle diameter will increase, and subsequent miniaturization cannot be performed. The coiling temperature is 750°C or lower, preferably 550°C or lower. If the coiling temperature is higher than this temperature, a lamellar structure of ferrite and pearlite is formed in the hot rolling stage, impairing the uniformity, and thus workability is lowered even if cold rolling or annealing is performed thereafter.
卷取得到的钢板接着经过冷轧加工成0.1~0.5mm范围内的所希望的板厚,但在本发明中重要的是将该冷轧中的冷轧率规定为80%以上的高值。如果该冷轧率低于80%,则退火时的铁素体粒径增大,不能使马氏体细化到规定的细度。另外,在冷轧机的性能上,难以将冷轧率规定为95%以上,因而将冷轧率规定为80~95%的范围内、优选为83~93%。The steel sheet obtained from the coil is then cold-rolled to a desired thickness in the range of 0.1 to 0.5 mm. However, it is important in the present invention to set the cold-rolling ratio in the cold-rolling to a high value of 80% or more. If the cold rolling ratio is less than 80%, the ferrite grain size increases during annealing, and martensite cannot be refined to a predetermined fineness. In addition, in view of the performance of the cold rolling mill, it is difficult to regulate the cold rolling ratio to be 95% or more, so the cold rolling ratio is made within the range of 80 to 95%, preferably 83 to 93%.
以下的退火和急速冷却对于得到铁素体和马氏体的复合组织是重要的工序。在退火工序中,在Ar1以上、且870℃以下的温度下将冷轧钢板保温3分钟以下。如果保温温度为Ar1以下,则在退火工序中不发生奥氏体相变,因此即使进行急速冷却也不能产生马氏体。可是,如果保温温度为870℃以上,则退火时的再结晶过度地进行,铁素体成为粗晶粒,不能使马氏体达到规定尺寸以下。再者,将保温时间规定为3分钟以下是为了抑制再结晶的进行。The following annealing and rapid cooling are important steps for obtaining a composite structure of ferrite and martensite. In the annealing step, the cold-rolled steel sheet is kept at a temperature of Ar 1 or more and 870° C. or less for 3 minutes or less. If the holding temperature is below Ar 1 , austenite transformation does not occur in the annealing step, so martensite cannot be generated even if rapid cooling is performed. However, if the holding temperature is 870° C. or higher, recrystallization during annealing proceeds excessively, ferrite becomes coarse-grained, and martensite cannot be reduced to a predetermined size or less. Furthermore, the reason for setting the holding time to 3 minutes or less is to suppress the progress of recrystallization.
在最后的急速冷却工序中,通过将750℃至400℃的温度区的冷却速度规定为100℃/秒以上、并且冷却到300℃以下,在铁素体中析出微细的马氏体。如果冷却速度低于此速度则无法形成马氏体。此外,将以100℃/秒以上的冷却速度进行冷却的温度范围规定为750℃至400℃,是为了最有效地使马氏体析出,如果急速冷却开始温度低于750℃,则因铁素体的生长进展而难以进行马氏体的微细化。此外,如果不急速冷却到至少400℃,则因不能生成马氏体而使强度不足。只要如此冷却到300℃以下,就能得到结晶结构稳定的、铁素体中分散有微细的马氏体晶粒的本发明的制罐用高强度薄钢板。再者,400℃以下的温度区的冷却速度是任意的。In the final rapid cooling step, fine martensite is precipitated in ferrite by controlling the cooling rate in the temperature range from 750°C to 400°C to 100°C/sec or more and cooling to 300°C or less. If the cooling rate is lower than this rate, martensite cannot be formed. In addition, the temperature range for cooling at a cooling rate of 100°C/s or more is specified as 750°C to 400°C in order to precipitate martensite most effectively. If the rapid cooling start temperature is lower than 750°C, the ferrite It is difficult to refine the martensite because of the progress of the growth of the martensite. In addition, if it is not rapidly cooled to at least 400°C, the strength is insufficient because martensite cannot be formed. As long as it is cooled to 300° C. or lower in this way, the high-strength steel sheet for can making of the present invention having a stable crystal structure and fine martensite grains dispersed in ferrite can be obtained. In addition, the cooling rate in the temperature range of 400 degrees C or less is arbitrary.
如此制造的制罐用高强度薄钢板具备第1、第2发明中记载的马氏体粒径d,能够兼顾强度和延性。而且合金成分满足ASTM,能够作为食品罐及饮料罐的原材料而放心使用。以下示出本发明的实施例。The high-strength steel sheet for can manufacturing thus produced has the martensite grain size d described in the first and second inventions, and can achieve both strength and ductility. Moreover, the alloy composition meets ASTM, so it can be safely used as a raw material for food cans and beverage cans. Examples of the present invention are shown below.
实施例Example
(实施例1)(Example 1)
将具有表1中所示成分的钢熔炼,对于在表2、表3(续表2)中所示的制造条件下制造的钢板A1~S1,对马氏体的状态、式<A>的左边的计算结果、30T硬度、延伸率进行了评价。Melting the steel having the composition shown in Table 1, for the steel plates A1 to S1 manufactured under the manufacturing conditions shown in Table 2 and Table 3 (continued from Table 2), the state of martensite, formula <A> The calculation results on the left, 30T hardness, and elongation were evaluated.
这里,关于马氏体的状态,通过LePera(レペラ一)蚀刻对马氏体进行鉴定,用1000倍的光学显微镜,以0.2μm×0.2μm的视野至少对100个视野实施了画像解析,求出马氏体分率(马氏体在组织中所占的面积率)。此外关于马氏体粒径,通过同样的测定算出当量圆直径,并将其平均化。Here, regarding the state of martensite, the martensite was identified by LePera (レペラ-) etching, and image analysis was carried out on at least 100 fields of view with a field of view of 0.2 μm × 0.2 μm with a 1000-magnification optical microscope to obtain Martensite fraction (the area ratio of martensite in the structure). In addition, regarding the martensite grain size, the circle-equivalent diameter was calculated by the same measurement and averaged.
关于硬度,基于JISZ2245的30T进行评价。如果30T硬度低于60,则如上所述在用于罐的本体部时强度不足,因此将60以上规定为合格。关于延伸率,按照JISZ2241的JIS5号片进行材质试验,如上所述将延伸率为5%以上的规定为合格,将低于5%的规定为不合格。About hardness, it evaluated based on 30T of JISZ2245. If the 30T hardness is less than 60, the strength is insufficient when used for the main body of a can as described above, so 60 or more is defined as acceptable. Regarding the elongation, a material test was performed in accordance with JIS No. 5 sheet of JIS Z2241, and as described above, those with an elongation of 5% or more were defined as acceptable, and those with an elongation of less than 5% were defined as unacceptable.
从表2、表3(续表2)可知:在成分及热轧~冷轧、退火中满足规定条件、且满足式<A>的钢,其马氏体粒径小,可确保延伸率。From Table 2 and Table 3 (continued from Table 2), it can be seen that the steel that satisfies the specified conditions in composition, hot rolling to cold rolling, and annealing, and satisfies the formula <A> has a small martensite grain size and can ensure elongation.
(实施例2)(Example 2)
在表4、表5(续表4)中所示的制造条件下将具有表1中所示成分的钢制成钢板A21~Q22,对该钢板的马氏体状态、式<B>的左边的计算结果、马氏体超微小维氏硬度、30T硬度、延伸率进行了评价。Under the manufacturing conditions shown in Table 4 and Table 5 (continued from Table 4), the steel having the composition shown in Table 1 was made into steel plates A21 to Q22, and the martensitic state of the steel plate, the left side of formula <B> The calculation results, martensite ultra-fine Vickers hardness, 30T hardness, and elongation were evaluated.
再者,各种评价方法基于与实施例1同样的方法及基准进行实施,关于马氏体超微小维氏硬度,采用岛津制作所制的HMV-1AD,以测定载荷为0.1gf进行了测定。In addition, various evaluation methods were carried out based on the same method and standard as in Example 1. Regarding the ultra-micro Vickers hardness of martensite, HMV-1AD manufactured by Shimadzu Corporation was used, and the measurement load was 0.1gf. Determination.
从表4、表5(续表4)可知:在热轧~冷轧、退火中满足规定条件、且满足式<B>的钢,其马氏体粒径小、能够确保延伸率。From Table 4 and Table 5 (continued from Table 4), it can be seen that the steel which satisfies the specified conditions in hot rolling to cold rolling and annealing and satisfies the formula <B> has a small martensite grain size and can ensure elongation.
根据本发明,能够提供可通过ASTM的规定、并且可兼顾强度和延性的加工性优良的制罐用高强度薄钢板。According to the present invention, it is possible to provide a high-strength steel sheet for can making that can pass the ASTM regulations and has both strength and ductility and excellent formability.
Claims (5)
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2007-233629 | 2007-09-10 | ||
JP2007233629 | 2007-09-10 | ||
PCT/JP2008/066616 WO2009035120A1 (en) | 2007-09-10 | 2008-09-09 | High-strength steel sheet for can manufacturing and process for manufaturing the sheet |
Publications (2)
Publication Number | Publication Date |
---|---|
CN101802236A true CN101802236A (en) | 2010-08-11 |
CN101802236B CN101802236B (en) | 2012-05-30 |
Family
ID=40452126
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN2008801062794A Active CN101802236B (en) | 2007-09-10 | 2008-09-09 | High-strength steel sheet for can manufacturing and process for manufaturing the sheet |
Country Status (4)
Country | Link |
---|---|
JP (1) | JP4235247B1 (en) |
KR (1) | KR101159824B1 (en) |
CN (1) | CN101802236B (en) |
WO (1) | WO2009035120A1 (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104334460A (en) * | 2012-06-06 | 2015-02-04 | 杰富意钢铁株式会社 | Three-piece can and method for producing same |
TWI560280B (en) * | 2014-10-17 | 2016-12-01 | Nippon Steel & Sumitomo Metal Corp | Steel sheet for drawn-can and producing method thereof |
CN106282809A (en) * | 2016-08-31 | 2017-01-04 | 广西盛隆冶金有限公司 | The storage tank manufacture method of nickeliferous chromium steel |
TWI588271B (en) * | 2014-11-12 | 2017-06-21 | Jfe Steel Corp | Steel plate for can and method for producing steel plate for can |
US11913087B2 (en) | 2017-10-31 | 2024-02-27 | Jfe Steel Corporation | High-strength steel sheet and method for producing same |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5794004B2 (en) * | 2011-07-12 | 2015-10-14 | Jfeスチール株式会社 | Steel sheet for high strength can excellent in flange workability and manufacturing method thereof |
DE102011056847B4 (en) * | 2011-12-22 | 2014-04-10 | Thyssenkrupp Rasselstein Gmbh | Steel sheet for use as a packaging steel and process for the production of a packaging steel |
DE102011056846B4 (en) * | 2011-12-22 | 2014-05-28 | Thyssenkrupp Rasselstein Gmbh | Method for producing a tear-open lid and use of a steel sheet provided with a protective layer for producing a tear-open lid |
JP5974999B2 (en) * | 2013-08-30 | 2016-08-23 | Jfeスチール株式会社 | Steel plate for high strength can |
BR112018017156A2 (en) | 2016-02-29 | 2018-12-26 | Jfe Steel Corporation | steel sheet for cans and method of making it |
JP7131596B2 (en) * | 2019-12-04 | 2022-09-06 | Jfeスチール株式会社 | Steel plate for high-strength cans and method for manufacturing the same |
CN115176042B (en) | 2020-02-21 | 2023-10-20 | 杰富意钢铁株式会社 | Steel sheet and method for manufacturing steel sheet |
JP7585896B2 (en) | 2020-03-26 | 2024-11-19 | Jfeスチール株式会社 | Steel sheet for cans and its manufacturing method |
WO2025047755A1 (en) * | 2023-08-31 | 2025-03-06 | Jfeスチール株式会社 | Steel sheet and method for manufacturing same |
WO2025047754A1 (en) * | 2023-08-31 | 2025-03-06 | Jfeスチール株式会社 | Steel sheet and method for manufacturing same |
Family Cites Families (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5938336A (en) * | 1982-08-26 | 1984-03-02 | Kawasaki Steel Corp | Production of ultra thin steel sheet for can having high yield strength and drawability |
JPH04337049A (en) * | 1991-05-13 | 1992-11-25 | Kawasaki Steel Corp | Cold rolled steel sheet for can manufacturing having high strength and superior workability and its production |
JPH05247669A (en) * | 1992-03-06 | 1993-09-24 | Toyo Kohan Co Ltd | Manufacture of high strength steel sheet for thinned and deep-drawn can |
JP3248389B2 (en) * | 1995-04-27 | 2002-01-21 | 日本鋼管株式会社 | Ultra-thin steel sheet for welded cans with excellent neck formability |
JP4268521B2 (en) * | 2001-10-04 | 2009-05-27 | 新日本製鐵株式会社 | Steel plate for container and method for producing the same |
JP3887235B2 (en) | 2002-01-11 | 2007-02-28 | 新日本製鐵株式会社 | High-strength steel sheet, high-strength hot-dip galvanized steel sheet, high-strength galvannealed steel sheet excellent in stretch flangeability and impact resistance, and manufacturing method thereof |
JP4085826B2 (en) | 2003-01-30 | 2008-05-14 | Jfeスチール株式会社 | Duplex high-strength steel sheet excellent in elongation and stretch flangeability and method for producing the same |
-
2008
- 2008-08-28 JP JP2008219140A patent/JP4235247B1/en active Active
- 2008-09-09 KR KR1020107001822A patent/KR101159824B1/en active Active
- 2008-09-09 CN CN2008801062794A patent/CN101802236B/en active Active
- 2008-09-09 WO PCT/JP2008/066616 patent/WO2009035120A1/en active Application Filing
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104334460A (en) * | 2012-06-06 | 2015-02-04 | 杰富意钢铁株式会社 | Three-piece can and method for producing same |
TWI560280B (en) * | 2014-10-17 | 2016-12-01 | Nippon Steel & Sumitomo Metal Corp | Steel sheet for drawn-can and producing method thereof |
TWI588271B (en) * | 2014-11-12 | 2017-06-21 | Jfe Steel Corp | Steel plate for can and method for producing steel plate for can |
CN107109556A (en) * | 2014-11-12 | 2017-08-29 | 杰富意钢铁株式会社 | The manufacture method of steel plate for tanks and steel plate for tanks |
CN107109556B (en) * | 2014-11-12 | 2019-01-11 | 杰富意钢铁株式会社 | The manufacturing method of steel plate for tanks and steel plate for tanks |
US10837076B2 (en) | 2014-11-12 | 2020-11-17 | Jfe Steel Corporation | Steel sheet for cans and method for manufacturing steel sheet for cans |
CN106282809A (en) * | 2016-08-31 | 2017-01-04 | 广西盛隆冶金有限公司 | The storage tank manufacture method of nickeliferous chromium steel |
US11913087B2 (en) | 2017-10-31 | 2024-02-27 | Jfe Steel Corporation | High-strength steel sheet and method for producing same |
Also Published As
Publication number | Publication date |
---|---|
JP4235247B1 (en) | 2009-03-11 |
CN101802236B (en) | 2012-05-30 |
KR101159824B1 (en) | 2012-06-26 |
WO2009035120A1 (en) | 2009-03-19 |
KR20100029132A (en) | 2010-03-15 |
JP2009084687A (en) | 2009-04-23 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN101802236B (en) | High-strength steel sheet for can manufacturing and process for manufaturing the sheet | |
JP5135868B2 (en) | Steel plate for can and manufacturing method thereof | |
TWI441928B (en) | High strength galvanized steel sheet having excellent uniform elongation and zinc coatability and method for manufacturing the same | |
JP4811528B2 (en) | High-strength cold-rolled steel sheet and manufacturing method thereof | |
TWI390053B (en) | Method for manufacturing steel sheet for high strength container | |
JP4834733B2 (en) | A method for producing a high-strength bake-hardening cold-rolled steel sheet, hot-dip plated steel sheet, and cold-rolled steel sheet having excellent aging resistance. | |
WO2001098552A1 (en) | Thin steel sheet and method for production thereof | |
CN107208206A (en) | High-strength hot-dip zinc-coated steel sheet and its manufacture method | |
WO2012002566A1 (en) | High-strength steel sheet with excellent processability and process for producing same | |
TWI750033B (en) | Steel plate and its manufacturing method | |
CN110088331B (en) | Hot-rolled steel sheet for electric resistance welded steel pipe having excellent weldability and method for producing same | |
CN107429360A (en) | The manufacture method of steel plate for tanks and steel plate for tanks | |
JP7482231B2 (en) | Low carbon, low cost, ultra-high strength multi-phase steel sheet/strip and manufacturing method thereof | |
WO2005103316A1 (en) | Steel sheet for can and method for production thereof | |
JP4943244B2 (en) | Steel sheet for ultra-thin containers | |
EP0659890A2 (en) | Method of manufacturing small planar anisotropic high-strength thin can steel plate | |
JP5031751B2 (en) | Manufacturing method of high-strength cold-rolled steel sheet, hot-dipped steel sheet and cold-rolled steel sheet with excellent bake hardenability | |
JP4779737B2 (en) | Manufacturing method of steel sheet for ultra thin can and steel sheet for ultra thin can | |
JP2023507810A (en) | Tin-plated base plate for processing and method for producing the same | |
CN113950536B (en) | Steel sheet for can and method for producing same | |
KR20150073005A (en) | Austenitic galvanized steel sheet having excellent resistance crack of welding point and method for manufacturing the same | |
CN116368253A (en) | High-strength steel sheet excellent in heat stability and method for producing same | |
JPH11222647A (en) | Original sheet for surface-treated steel sheet with excellent aging resistance and low ear incidence rate, and method for producing the same | |
JP3369658B2 (en) | High-strength and high-workability steel sheet for cans with excellent bake hardenability, aging resistance and non-earring properties, and method for producing the same | |
EP4455346A1 (en) | High strength and high formability steel sheet having excellent spot weldability, and method for manufacturing same |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
ASS | Succession or assignment of patent right |
Owner name: NIPPON STEEL + SUMITOMO METAL CORPORATION Free format text: FORMER OWNER: SHIN NIPPON STEEL LTD. Effective date: 20130326 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TR01 | Transfer of patent right |
Effective date of registration: 20130326 Address after: Tokyo, Japan Patentee after: Nippon Steel Corporation Address before: Tokyo, Japan Patentee before: Nippon Steel Corporation |
|
CP01 | Change in the name or title of a patent holder | ||
CP01 | Change in the name or title of a patent holder |
Address after: Tokyo, Japan Patentee after: Nippon Iron & Steel Corporation Address before: Tokyo, Japan Patentee before: Nippon Steel Corporation |