CN101798185A - Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof - Google Patents
Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof Download PDFInfo
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- CN101798185A CN101798185A CN 201010147285 CN201010147285A CN101798185A CN 101798185 A CN101798185 A CN 101798185A CN 201010147285 CN201010147285 CN 201010147285 CN 201010147285 A CN201010147285 A CN 201010147285A CN 101798185 A CN101798185 A CN 101798185A
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- glass
- glue
- laminated safety
- shellproof
- substrate
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- 239000003292 glue Substances 0.000 claims abstract description 49
- 239000000758 substrate Substances 0.000 claims abstract description 49
- 239000005336 safety glass Substances 0.000 claims abstract description 40
- 239000000853 adhesive Substances 0.000 claims abstract description 33
- 230000001070 adhesive effect Effects 0.000 claims abstract description 33
- 239000003063 flame retardant Substances 0.000 claims abstract description 26
- 239000011229 interlayer Substances 0.000 claims description 39
- 239000010410 layer Substances 0.000 claims description 31
- 239000003795 chemical substances by application Substances 0.000 claims description 25
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- 206010041662 Splinter Diseases 0.000 claims description 18
- 238000009413 insulation Methods 0.000 claims description 16
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- Joining Of Glass To Other Materials (AREA)
Abstract
The invention respectively discloses bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as and compound glass thereof, which respectively comprise laminated safety glass, bullet-resistent glue and/or fire-retardant glue and an outer-layer glass substrate, wherein the outer-layer glass substrate is bonded on the surface of the laminated safety glass by the bullet-resisting glue and/or the fire-retardant glue; and the laminated safety glass comprises two inner-layer glass substrates and an organic laminated adhesive material which is arranged between the two inner-layer glass substrates. The bullet-resistant glass and the fireproof glass not only can resist bullets and fire, but also can absorb ultraviolet rays, near infrared rays and strong dazzling light to insulate heat, prevent freeze, resist bright light, strong heat, the penetration of harmful radiant rays for human bodies, and the like, can prevent rain pulverization, snow adhesion and self-pulverization of glass under strong shock waves, realize self protection, and the like.
Description
Technical field
The invention belongs to the glass technology field, more particularly, the present invention relates to have splinter-proof glass, flame resistant glass and compound glass thereof heat insulation, radiation proof function.
Background technology
Existing laminated safety glass, for example be used for the interlayer security window glass of laminated safety glass that automobile keeps out the wind and Highrise buildings and interlayer furniture glass etc., though transmittance height, but all can not play heat insulation, shellproof, fp effect, can not prevent that rain and dew atomizing and ice and snow adhere to, can not absorb the ultraviolet ray of dazzling light and 200～380nm, let alone absorb the near infrared ray of 780～1500nm.Because existing laminated safety glass is to adopt following Recipe technology preparation: (1) polyvinyl butyral film method: polyvinyl butyral acetal is cut into required sheet base, it is clipped in the layer glass by heat-conglutinating machine heating and pressurizing makes, this method is very high to the requirement of film, promptly require film not scratch and fault, thickness is very even, material cost is very high, and facility investment is huge.(2) thermopolymerization encapsulating method: the prepolymer of making is poured in the middle of the layer glass of sealing the limit, heats up gradually in process furnace, it is heating and curing, the production cycle of this method reaches 24～36 hours, and temperature requirement is at 80～100 ℃, and cost is also quite high.(3) Photocurable adhesive method: adopting methyl methacrylate (MMA) is major ingredient, methyl acrylate (MA) and butyl acrylate (BA) are auxiliary material, dibutyl phthalate (DBP) and dimethyl phthalate (DOP) are softening agent, Diisopropyl azodicarboxylate (ABN) is an initiator, add in the reactor, react prepolymerization at a certain temperature, stopped reaction when transformation efficiency reaches 15% left and right sides, and adding tackifier vinylformic acid, light trigger benzoin isobutyl ether and linking agent, through the high-speed stirring mixing Photocurable adhesive, in the middle of the glass through pouring into two-layer edge sealing after the vacuum outgas, can solidify voluntarily after 4～8 hours in irradiation under sunlight or the light (UV-light).There is following shortcoming in the laminated safety glass that adopts the Photocurable adhesive method to produce: (1) is aging easily, and bonding strength is not high, and long the inefficacy easily of time and separating comes off, and causes the accident.(2) the tackiness agent variation of temperature that can not conform is bigger to the glass cementation intensity effect, and long used Plasticizer DBP of time one and DOP can hardening, easily embrittlement.(3) after laminated safety glass is subjected to impact grinding, the retention rate of fragment has only about 60%, and is dangerous.(4) can not prevent the rain and dew atomizing, can not prevent that ice and snow adheres to.(5) can not absorb the ultraviolet ray of 200～380nm and the near infrared light of 780～1500nm.(6) thickness of glass is generally 6mm+6mm～10mm+10mm, and weight is big, the cost height, but the laminated safety glass cost of producing than preceding two kinds of methods is low slightly.
Summary of the invention
The object of the present invention is to provide a kind of splinter-proof glass heat insulation, radiation proof function that has, a kind of flame resistant glass with heat insulation, radiation proof function and a kind ofly have a shellproof fireproof composite glass heat insulation, radiation proof function.Glass provided by the present invention not only can play shellproof and/or the fp effect; and can absorb ultraviolet ray, near infrared ray and strong dazzling light; play heat insulation, antifreeze, as to prevent high light, heat-flash and harmful radiation (as laser wave, r ray, x ray and neutron ray) effect such as see through; can also prevent that rain and dew atomizings and ice and snow adhere to, prevent functions such as the broken broken and realization autoprotection of glass self under the intense impact ripple.
The objective of the invention is to be achieved through the following technical solutions:
A kind of have a splinter-proof glass heat insulation, radiation proof function, comprise laminated safety glass, shellproof glue and glass outer substrate, on the surface of described laminated safety glass, described laminated safety glass comprises two inner layer glass substrates and places organic interlayer adhesive material between the inner layer glass substrate described glass outer substrate by described shellproof glue bond.
A kind of have a flame resistant glass heat insulation, radiation proof function, comprise laminated safety glass, fire retardant glue and glass outer substrate, described glass outer substrate is bonded in by described fire retardant glue on the surface of described laminated safety glass, and described laminated safety glass comprises two inner layer glass substrates and places organic interlayer adhesive material between the inner layer glass substrate.
A kind of have a shellproof fireproof composite glass heat insulation, radiation proof function, comprise laminated safety glass, shellproof glue, middle level glass substrate, fire retardant glue and glass outer substrate, on a surface of described laminated safety glass, described glass outer substrate is bonded on another surface of described middle level glass substrate described middle level glass substrate by described fire retardant glue by described shellproof glue bond; Described laminated safety glass is by two inner layer glass substrates and place the organic interlayer adhesive material between the inner layer glass substrate to form.
A kind of have a shellproof fireproof composite glass heat insulation, radiation proof function, comprise laminated safety glass, shellproof glue, fire retardant glue and glass outer substrate, wherein, on a surface of described laminated safety glass, the second glass outer substrate is bonded on another surface of described laminated safety glass the first glass outer substrate by described fire retardant glue by described shellproof glue bond; Described laminated safety glass comprises two inner layer glass substrates and places organic interlayer adhesive material between the inner layer glass substrate.
In the above-described technical scheme of the present invention, PVB (PolyVinyl Butyral polyvinyl butyral acetal) or EVA (Ethylene Vinyl Acetate polyvinyl acetic acid salt) glue-line can also be set on the surface of described splinter-proof glass, flame resistant glass and shellproof fireproof composite glass, and by this PVB or the bonding again upper glass substrate of EVA glue-line.In addition, can also add 0.05%～0.15% Potassium ethanoate or vinyl silicane coupling agent in the glued membrane of PVB or EVA glue.
In the above-described technical scheme of the present invention, the thickness of glass substrate is 2mm～5mm; The filling thickness of organic interlayer adhesive material is 0.5mm～3mm; The filling thickness of shellproof glue is 3mm～8mm; The filling thickness of fire retardant glue is 2mm～4mm; The filling thickness of PVB or EVA glue is 0.38mm～1.5mm.
In the above-described technical scheme of the present invention, described organic interlayer adhesive material comprises following component by weight percentage:
Major ingredient 60.0%～70.0%; Properties-correcting agent 10.0%～15.0%; Modification agent 3.0%～5.0%;
Linking agent 0.1%～1.5%; Coupling agent 0.5%～1.5%; Thickening material 1.0%～3.0%;
Light trigger 0.5%～2.5%; Catalyzer 1.0%～5.0%; Impact modifier 3.0%～5.0%;
Excipient 0.5%～2.0%; UV-IR optical protective material 0.5%～5%.
Wherein, in the described organic interlayer adhesive material, major ingredient is a methyl methacrylate; Properties-correcting agent is selected from one or more the mixing in methacrylic acid, n-BMA, the n-butyl acrylate; Modification agent is selected from one or both the mixing in Propylene glycol monoacrylate and the Rocryl 410; Linking agent is selected from one or both the mixing in glycidyl methacrylate and the allyl methacrylate(AMA); Coupling agent is selected from one or both the mixing among coupling agent ND-27 and the ND-30; Thickening material is selected from one or both the mixing in hydroxyethyl methylacrylate and the lauryl; Light trigger is selected from one or more the mixing in benzophenone, benzil and the Benzoin ethyl ether; Catalyzer is selected from one or more the mixing in Viscoat 295,1,6 hexanediol diacrylate and the pentaerythritol triacrylate; Impact modifier is selected from one or both the mixing in bisphenol fluorene and the fluorenes; Excipient is a cyclohexyl methacrylate; The UV-IR optical protective material is Organometallic complexes (divalent, 4 valencys, 6 valency coordinations), and dicyclopentadieny iron by 30% and 30% the curing ethylene type metallic nickel complex compound that contains pyranoid ring polymethine cyanine dyes and 40% are prepared from through the extraction underpressure distillation.
In the above-described technical scheme of the present invention, described shellproof glue comprises following component by weight percentage:
N-BMA 65.0%～70.0%; Fluorenes 10.0%～12.0%;
Butyl acrylate 8.0%～10.0%; Vinylsiloxane coupling agent 3.0%～5.0%;
Vinyl acetate 2.0%～3.0%; Plug fen formyl three oxygen two ethyl acetoacetic acid ethyl ester lithiums 1.0%～2.0%;
Methacrylic acid gadolinium 0.5%～1.0%; Sulfonation dioctyl succinate sodium salt 0.5%～1.0%;
Methyl ethyl diketone samarium 1.0%～1.5%; Light curing agent 1.0%～1.5%;
Chemical cross-linking agent 0.3%～0.5%.
Wherein, in the described shellproof glue, light curing agent is selected from one or more the mixing in trimethylolpropane allyl ether, methacrylic acid hexafluoro butyl ester, benzil, the acyl ether of resting in peace; Chemical cross-linking agent is selected from one or more the mixing in diallyl adipate, allyl methacrylate(AMA), the dimethacrylate triethyleneglycol ester.
In the above-described technical scheme of the present invention, described fire retardant glue comprises following component by weight percentage:
Bromine ethene 25.0%～30.0%; Halogen polyphosphate 18.0%～20.0%;
Methyl methacrylate 10.0%～15.0%; Ammonium polyphosphate 10.0%～12.0%;
Vinyl neopentylglycol diacrylate 10.0%～12.0%; Vinylformic acid tribromophenyl 8.0%～10.0%;
Tricresyl phosphate (β-chloroethyl) ester 5.0%～8.0%; Triallyl phosphate 5.0%～8.0%.
Glass substrate of the present invention can be selected silicate glass, float glass, white glass or toughened glass etc. for use.
Splinter-proof glass of the present invention, flame resistant glass and shellproof fireproof composite glass all can be used as the windshield glass and the window glass of various vehicles, aircraft, steamer etc., also can be used as the window glass of various buildings and various display protections etc.
Splinter-proof glass of the present invention, flame resistant glass and shellproof fireproof composite glass have following beneficial effect with respect to prior art:
(1) can absorb the ultraviolet ray of 200～380nm fully, prevent that ultraviolet radiation from causing damage to the DNA in the human body cell, prevent the generation of diseases such as skin carcinoma, cataract, visual deterioration, and prevent the aging of human body skin, various material and installations and facilities;
(2) can absorb the near infrared ray of 780～1500nm, it is interior or indoor to prevent that near infrared ray from entering automobile, play heat insulation and every the effect of light, can make room temp reduce by 5 ℃～8 ℃ effectively, prevent near infrared ray injury optic nerve simultaneously, protect human eye vision, alleviate eye strain, the accident that prevents takes place;
(3) can effectively dissipate strong dazzling light in the visible light, its radiating capacity that dissipates makes the high light line become soft and not dazzling light, makes vision free and relaxed;
(4) can prevent the rain and dew atomizing effectively, this is because the organic interlayer adhesive material can produce another kind of radiating capacity after having absorbed near infrared heat, make glass table body temperature degree raise and its ambient temperature decline, thereby reduced the temperature head between glass and the ambient air, prevent small dewdrop from glass surface, condensing effectively and cause fuzzyly, influence sight line;
(5) have explosion prevention function, hardness height, wear-resisting wiping, good impact resistance have certain unit elongation, the energy when can heat absorbing glass broken, when shock strength up to 40Kg/m
2The time, even the glass fragmentation, the glass fragment retention rate can not come off up to more than 98%;
(6) behind the interpolation shellproof glue of the present invention, not only can be in case the shooting bullet of various pistol, rifle, tommy gun and logotype machine gun can also prevent that radiating such as r ray, x ray, neutron ray and laser wave from seeing through;
(7) after the interpolation fire retardant glue of the present invention, can play the effect of good heat-insulating, fire-preventing, when extraneous surface combustion temperature reaches more than 800 ℃, the temperature of internal surface is less than 140 ℃, glass outer is not broken quick-fried, its radiation coefficient is 0.01, and promptly the inner face air themperature can be protected personnel safety effectively between 60 ℃～70 ℃;
(8) can in-50 ℃ to 150 ℃ temperature range, use, and in light weight.
Laminated safety glass of the present invention had both had the performance of unorganic glass, had the performance of synthetic glass again.Experiment shows, its total light transmittance is 55%～85%, to the ultraviolet specific absorption of 200～380nm 〉=99.9%, is 35%～75% to the transmitance of 400～750nm visible light, to the near infrared specific absorption of 800～1500nm 〉=99.9%, control solar radiation rate (Ts) is 10%～15%.By the shellproof glue of surface coated, fire retardant glue at this laminated safety glass, the glass outer substrate of fitting again, can make have heat insulation, the splinter-proof glass of radiation proof function, flame resistant glass.Splinter-proof glass of the present invention, flame resistant glass have satisfied the desired every index of present technique fully, having captured countries in the world is the difficult problem of the power-saving technology of representative to reduce cooling load, and manufacturing process is simple, cost is low, has the extremely wide world and domestic market.
Description of drawings
Fig. 1 is the structural representation of the embodiment of the invention one described laminated safety glass;
Fig. 2 is the visible light transmissivity graphic representation of laminated safety glass of the present invention, and wherein, solid line is represented maximum visible light transmissivity, and dotted line is represented minimum visible light transmissivity;
Fig. 3 is the structural representation of the embodiment of the invention two described splinter-proof glasses;
Fig. 4 is the structural representation of the embodiment of the invention three described flame resistant glasses;
Fig. 5 is the structural representation of the embodiment of the invention four described shellproof fireproof composite glass.
Embodiment
Embodiment one: the preparation of laminated safety glass
Take by weighing each component of organic interlayer adhesive material according to following weight percent:
Major ingredient 60.0%～70.0%; Properties-correcting agent 10.0%～15.0%; Modification agent 3.0%～5.0%;
Linking agent 0.1%～1.5%; Coupling agent 0.5%～1.5%; Thickening material 1.0%～3.0%;
Light trigger 0.5%～2.5%; Catalyzer 1.0%～5.0%; Impact modifier 3.0%～5.0%;
Excipient 0.5%～2.0%; UV-IR optical protective material 0.5%～5%.
Wherein, major ingredient is a methyl methacrylate; Properties-correcting agent is selected from one or more the mixing in methacrylic acid, n-BMA, the n-butyl acrylate; Modification agent is selected from one or both the mixing in Propylene glycol monoacrylate and the Rocryl 410; Linking agent is selected from one or both the mixing in glycidyl methacrylate and the allyl methacrylate(AMA); Coupling agent is selected from one or both the mixing among coupling agent ND-27 and the ND-30; Thickening material is selected from one or both the mixing in hydroxyethyl methylacrylate and the lauryl; Light trigger is selected from one or more the mixing in benzophenone, benzil and the Benzoin ethyl ether; Catalyzer is selected from one or more the mixing in Viscoat 295,1,6 hexanediol diacrylate and the pentaerythritol triacrylate; Impact modifier is selected from one or both the mixing in bisphenol fluorene and the fluorenes; Excipient is a cyclohexyl methacrylate; The UV-IR optical protective material is Organometallic complexes (divalent, 4 valencys, 6 valency coordinations), and dicyclopentadieny iron by 30% and 30% the curing ethylene type metallic nickel complex compound that contains pyranoid ring polymethine cyanine dyes and 40% are prepared from through the extraction underpressure distillation.
The silicate glass that to get two thickness be 2mm～5mm is cleaned, oven dry; Seal with flexible PVC sebific duct or adhesive tape around silicate glass then and make framedly, reserve the material filling mouth, the distance between two silicate glasses is controlled at 0.5mm～3mm.
Take by weighing each component of described organic interlayer adhesive material by weight percentage, carry out prepolymerization slurrying, earlier major ingredient is mixed with light trigger, add properties-correcting agent and modification agent when being warming up to 50 ℃, 55 ℃ add coupling agent, 60 ℃ add linking agent and impact modifier, 65 ℃ add thickening materials, and 70 ℃ add excipient and catalyzer, are warming up to 80 ℃ and kept 3～5 minutes, cool off rapidly when being warming up to 89 ℃ naturally, add the UV-IR optical protective material when being cooled to 80 ℃.After continuing to be cooled to room temperature, with pre-polymerization slurry metering from the material filling mouth pour into framed in, solidifying under UV-light or the sunlight 60～150 minutes or in 40 ℃～60 ℃ water railway carriage or compartment or drying room, solidifying 3～4 hours; Under 100～120 ℃, carried out the broken fire of high temperature place subsequently 60～90 minutes, and carry out stepped annelaing and handle (80 ℃～60 ℃); Be cooled to normal temperature and promptly make laminated safety glass of the present invention.As shown in Figure 1, prepared laminated safety glass is by two silicate glasses 1,3, and places the organic interlayer adhesive material layer 2 between two silicate glasses 1,3 to form.
Experiment shows, the total light transmittance of prepared laminated safety glass is 55%～85%, to the ultraviolet specific absorption of 200～380nm 〉=99.9%, transmitance to 400～700nm visible light was 35%～75% (as shown in Figure 2), to the near infrared specific absorption of 800～1500nm 〉=99.9%, control solar radiation rate (Ts) is 10%～15%, can make summer indoor or vehicle interior temperature reduces by 5 ℃～8 ℃, and room temp is raise 3 ℃～4 ℃.Prepared laminated safety glass has the surface hardness of inorganic silicon glass, and resistance to impact shock is 5～8 times of simple glass, has explosion-proof performance, and the glass fragment retention rate is up to more than 98%, and function such as has anti-rain and dew atomizing and prevent that ice and snow adheres to.
Embodiment two: the preparation of splinter-proof glass
The silicate glass that to get three thickness be 2mm～5mm is cleaned, oven dry; Framed according to embodiment one described method making, wherein, from inside to outside, first interlayer is an organic interlayer adhesive material layer, and its filling thickness is controlled at 0.5mm～3mm; Second interlayer is shellproof glue-line, and its filling thickness is controlled at 3mm～8mm.
Prepare organic interlayer adhesive material pre-polymerization slurry according to embodiment one described method.
Take by weighing each component of shellproof glue according to following weight percent, carry out prepolymerization slurrying:
N-BMA 65.0%～70.0%; Fluorenes 10.0%～12.0%;
Butyl acrylate 8.0%～10.0%; Vinylsiloxane coupling agent 3.0%～5.0%;
Vinyl acetate 2.0%～3.0%; Plug fen formyl three oxygen two ethyl acetoacetic acid ethyl ester lithiums 1.0%～2.0%;
Methacrylic acid gadolinium 0.5%～1.0%; Sulfonation dioctyl succinate sodium salt 0.5%～1.0%;
Methyl ethyl diketone samarium 1.0%～1.5%; Light curing agent 1.0%～1.5%;
Chemical cross-linking agent 0.3%～0.5%.
Wherein, light curing agent is selected from one or more the mixing in trimethylolpropane allyl ether, methacrylic acid hexafluoro butyl ester, benzil, the acyl ether of resting in peace; Chemical cross-linking agent is selected from one or more the mixing in diallyl adipate, allyl methacrylate(AMA), the dimethacrylate triethyleneglycol ester.
Respectively with the organic interlayer adhesive material that makes and the metering of shellproof glue pre-polymerization slurry from the material filling mouth pour into framed in, handle according to embodiment one described method, promptly make splinter-proof glass of the present invention.As shown in Figure 3, prepared splinter-proof glass places the organic interlayer adhesive material layer 2 between the internal layer silicate glass 1,3, shellproof glue-line 4 by two internal layer silicate glasses 1,3, outer silicate glass 5, PVB or EVA glue-line 8 and outer silicate glass 9 are formed.
Embodiment three: the preparation of flame resistant glass
Silicate glass that to get two thickness be 2mm～5mm and the caesium potassic glass of a slice 3mm～5mm are cleaned, oven dry; Framed according to embodiment one described method making, wherein, the caesium potassic glass is arranged on outermost layer; From inside to outside, first interlayer is an organic interlayer adhesive material layer, and its filling thickness is controlled at 0.5mm～3mm; Second interlayer is fire-retardant glue-line, and its filling thickness is controlled at 2mm～4mm.
Prepare organic interlayer adhesive material pre-polymerization slurry according to embodiment one described method.
Take by weighing each component of fire retardant glue according to following weight percent, carry out prepolymerization slurrying:
Bromine ethene 25.0%～30.0%; Halogen polyphosphate 18.0%～20.0%;
Methyl methacrylate 10.0%～15.0%; Ammonium polyphosphate 10.0%～12.0%;
Vinyl neopentylglycol diacrylate 10.0%～12.0%; Vinylformic acid tribromophenyl 8.0%～10.0%;
Tricresyl phosphate (β-chloroethyl) ester 5.0%～8.0%; Triallyl phosphate 5.0%～8.0%.
Respectively with the organic interlayer adhesive material that makes and the metering of fire retardant glue pre-polymerization slurry from the material filling mouth pour into framed in, handle according to embodiment one described method, promptly make flame resistant glass of the present invention.As shown in Figure 4, prepared flame resistant glass places the organic interlayer adhesive material layer 2 between the internal layer silicate glass 1,3 by two internal layer silicate glasses 1,3, and fire-retardant glue-line 6 and outer caesium potassic glass 7 are formed.
Embodiment four: the preparation of shellproof fireproof composite glass
Silicate glass that to get four thickness be 2mm～5mm and the caesium potassic glass of a slice 3mm～5mm are cleaned, oven dry; Framed according to embodiment one described method making, wherein, arranging of glass substrate is followed successively by from inside to outside: two silicate glasses, a slice caesium potassic glass and two silicate glasses; And from inside to outside, first interlayer is an organic interlayer adhesive material layer, and its filling thickness is controlled at 0.5mm～3mm; Second interlayer is shellproof glue-line, and its filling thickness is controlled at 3mm～8mm; The 3rd interlayer is fire-retardant glue-line, and its filling thickness is controlled at 2mm～4mm; The 4th interlayer is PVB or EVA glue-line, and its filling thickness is controlled at 0.38mm～1.5mm.
Get an amount of PVB or EVA glue, and to add weight percent in this glued membrane be 0.05%～0.15% Potassium ethanoate or vinyl silicane coupling agent; And prepare organic interlayer adhesive material pre-polymerization slurry according to embodiment one described method; Prepare shellproof glue pre-polymerization slurry according to embodiment two described methods; And prepare fire retardant glue pre-polymerization slurry according to embodiment three described methods.
Respectively with the organic interlayer adhesive material that makes, shellproof glue and fire retardant glue pre-polymerization slurry and PVB or the metering of EVA glue from the material filling mouth pour into framed in, handle according to embodiment one described method, promptly make shellproof fireproof composite glass of the present invention.As shown in Figure 5, prepared shellproof fireproof composite glass is by two internal layer silicate glasses 1,3, place the organic interlayer adhesive material layer 2 between the internal layer silicate glass 1,3, shellproof glue-line 4, middle level silicate glass 5, fire-retardant glue-line 6, middle level caesium potassic glass 7, PVB or EVA glue-line 8 and outer silicate glass 9 are formed.
Claims (10)
1. one kind has splinter-proof glass heat insulation, radiation proof function, it is characterized in that, comprise laminated safety glass, shellproof glue and glass outer substrate, described glass outer substrate passes through described shellproof glue bond on the surface of described laminated safety glass, described laminated safety glass comprises two inner layer glass substrates and places organic interlayer adhesive material between the inner layer glass substrate that described organic interlayer adhesive material comprises following component by weight percentage:
Major ingredient 60.0%～70.0%; Properties-correcting agent 10.0%～15.0%; Modification agent 3.0%～5.0%;
Linking agent 0.1%～1.5%; Coupling agent 0.5%～1.5%; Thickening material 1.0%～3.0%;
Light trigger 0.5%～2.5%; Catalyzer 1.0%～5.0%; Impact modifier 3.0%～5.0%;
Excipient 0.5%～2.0%; UV-IR optical protective material 0.5%～5%.
2. splinter-proof glass according to claim 1 is characterized in that: described shellproof glue comprises following component by weight percentage:
N-BMA 65.0%～70.0%; Fluorenes 10.0%～12.0%;
Butyl acrylate 8.0%～10.0%; Vinylsiloxane coupling agent 3.0%～5.0%;
Vinyl acetate 2.0%～3.0%; Plug fen formyl three oxygen two ethyl acetoacetic acid ethyl ester lithiums 1.0%～2.0%;
Methacrylic acid gadolinium 0.5%～1.0%; Sulfonation dioctyl succinate sodium salt 0.5%～1.0%;
Methyl ethyl diketone samarium 1.0%～1.5%; Light curing agent 1.0%～1.5%;
Chemical cross-linking agent 0.3%～0.5%.
3. splinter-proof glass according to claim 1 is characterized in that: also be provided with PVB or EVA glue-line on the surface of described splinter-proof glass, and by this PVB or the bonding again upper glass substrate of EVA glue-line.
4. according to the described splinter-proof glass of arbitrary claim in the claim 1 to 3, it is characterized in that: the thickness of described glass substrate is 2mm～5mm; The filling thickness of described organic interlayer adhesive material is 0.5mm～3mm; The filling thickness of described shellproof glue is 3mm～8mm.
5. one kind has flame resistant glass heat insulation, radiation proof function, it is characterized in that, comprise laminated safety glass, fire retardant glue and glass outer substrate, described glass outer substrate is bonded on the surface of described laminated safety glass by described fire retardant glue, described laminated safety glass comprises two inner layer glass substrates and places organic interlayer adhesive material between the inner layer glass substrate that described fire retardant glue comprises following component by weight percentage:
Bromine ethene 25.0%～30.0%; Halogen polyphosphate 18.0%～20.0%;
Methyl methacrylate 10.0%～15.0%; Ammonium polyphosphate 10.0%～12.0%;
Vinyl neopentylglycol diacrylate 10.0%～12.0%; Vinylformic acid tribromophenyl 8.0%～10.0%;
Tricresyl phosphate (β-chloroethyl) ester 5.0%～8.0%; Triallyl phosphate 5.0%～8.0%.
6. flame resistant glass according to claim 5, it is characterized in that: described UV-IR optical protective material is an Organometallic complexes, and dicyclopentadieny iron by 30% and 30% the curing ethylene type metallic nickel complex compound that contains pyranoid ring polymethine cyanine dyes and 40% are prepared from through the extraction underpressure distillation.
7. flame resistant glass according to claim 5 is characterized in that: also be provided with PVB or EVA glue-line on the surface of described flame resistant glass, and by this PVB or the bonding again upper glass substrate of EVA glue-line.
8. according to the described flame resistant glass of arbitrary claim in the claim 5 to 7, it is characterized in that: the thickness of described glass substrate is 2mm～5mm; The filling thickness of described organic interlayer adhesive material is 0.5mm～3mm; The filling thickness of described fire retardant glue is 2mm～4mm.
9. one kind has shellproof fireproof composite glass heat insulation, radiation proof function, it is characterized in that, comprise laminated safety glass, shellproof glue, middle level glass substrate, fire retardant glue and glass outer substrate, on a surface of described laminated safety glass, described glass outer substrate is bonded on another surface of described middle level glass substrate described middle level glass substrate by described fire retardant glue by described shellproof glue bond; Described laminated safety glass is by two inner layer glass substrates and place the organic interlayer adhesive material between the inner layer glass substrate to form.
10. shellproof fireproof composite glass according to claim 9 is characterized in that: also be provided with PVB or EVA glue-line on the surface of described shellproof fireproof composite glass, and by this PVB or the bonding again upper glass substrate of EVA glue-line.
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010147285 CN101798185A (en) | 2010-03-02 | 2010-03-22 | Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof |
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| CN201010119002.4 | 2010-03-02 | ||
| CN 201010147285 CN101798185A (en) | 2010-03-02 | 2010-03-22 | Bullet-resistant glass and fireproof glass for insulating heat and resisting radiation, as well as compound glass thereof |
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| CN101798185A true CN101798185A (en) | 2010-08-11 |
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Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104185549A (en) * | 2012-02-22 | 2014-12-03 | 西格艾国际有限公司 | Fire resistant glazing unit |
| CN105131872A (en) * | 2015-09-07 | 2015-12-09 | 中国建筑材料科学研究总院 | Fireproof liquid of composite fireproof glass and preparation method thereof and composite fireproof glass |
| CN106466951A (en) * | 2016-09-30 | 2017-03-01 | 扬州大学 | Anti- neutron irradiation vacuum double glazing |
| CN106746758A (en) * | 2016-11-23 | 2017-05-31 | 扬州大学 | A kind of water-cooled doubling containing gadolinium neutron shield glass |
| CN109927356A (en) * | 2019-03-21 | 2019-06-25 | 黄涛 | Heat-insulating radiation-resistant laminated glass film and its production technology |
| CN110466219A (en) * | 2019-08-07 | 2019-11-19 | 聚优新材料科技（上海）有限公司 | It is a kind of with anti-radiation, shellproof multifunctional glass |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2281268Y (en) * | 1997-03-11 | 1998-05-13 | 国家建筑材料工业局秦皇岛玻璃工业研究设计院 | Safeguard fire resistant alarming glass |
| CN2285772Y (en) * | 1997-05-10 | 1998-07-08 | 深圳市斯伟思科技实业有限公司 | Special bulletproof glass |
| CN1239710A (en) * | 1998-06-20 | 1999-12-29 | 王辑五 | Low temperature polymerization process and equipment for preparing glue specially for sandwiched glass |
| CN1594171A (en) * | 2004-06-30 | 2005-03-16 | 姚明强 | Process for preparing sandwich glass |
| CN1796102A (en) * | 2004-12-21 | 2006-07-05 | 郝长岭 | Composite safe energy saving glass |
-
2010
- 2010-03-22 CN CN 201010147285 patent/CN101798185A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2281268Y (en) * | 1997-03-11 | 1998-05-13 | 国家建筑材料工业局秦皇岛玻璃工业研究设计院 | Safeguard fire resistant alarming glass |
| CN2285772Y (en) * | 1997-05-10 | 1998-07-08 | 深圳市斯伟思科技实业有限公司 | Special bulletproof glass |
| CN1239710A (en) * | 1998-06-20 | 1999-12-29 | 王辑五 | Low temperature polymerization process and equipment for preparing glue specially for sandwiched glass |
| CN1594171A (en) * | 2004-06-30 | 2005-03-16 | 姚明强 | Process for preparing sandwich glass |
| CN1796102A (en) * | 2004-12-21 | 2006-07-05 | 郝长岭 | Composite safe energy saving glass |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104185549A (en) * | 2012-02-22 | 2014-12-03 | 西格艾国际有限公司 | Fire resistant glazing unit |
| CN105131872A (en) * | 2015-09-07 | 2015-12-09 | 中国建筑材料科学研究总院 | Fireproof liquid of composite fireproof glass and preparation method thereof and composite fireproof glass |
| CN106466951A (en) * | 2016-09-30 | 2017-03-01 | 扬州大学 | Anti- neutron irradiation vacuum double glazing |
| CN106466951B (en) * | 2016-09-30 | 2019-03-05 | 扬州大学 | Anti- neutron irradiation vacuum double glazing |
| CN106746758A (en) * | 2016-11-23 | 2017-05-31 | 扬州大学 | A kind of water-cooled doubling containing gadolinium neutron shield glass |
| CN106746758B (en) * | 2016-11-23 | 2019-04-09 | 扬州大学 | A water-cooled gadolinium-containing sandwich neutron shielding glass |
| CN109927356A (en) * | 2019-03-21 | 2019-06-25 | 黄涛 | Heat-insulating radiation-resistant laminated glass film and its production technology |
| CN110466219A (en) * | 2019-08-07 | 2019-11-19 | 聚优新材料科技（上海）有限公司 | It is a kind of with anti-radiation, shellproof multifunctional glass |
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