CN101797851B - Special card sheet for laser printer and preparation method thereof - Google Patents
Special card sheet for laser printer and preparation method thereof Download PDFInfo
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- CN101797851B CN101797851B CN 201010125222 CN201010125222A CN101797851B CN 101797851 B CN101797851 B CN 101797851B CN 201010125222 CN201010125222 CN 201010125222 CN 201010125222 A CN201010125222 A CN 201010125222A CN 101797851 B CN101797851 B CN 101797851B
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- 238000002360 preparation method Methods 0.000 title abstract description 35
- 238000000576 coating method Methods 0.000 claims abstract description 42
- 239000011248 coating agent Substances 0.000 claims abstract description 38
- 239000000853 adhesive Substances 0.000 claims abstract description 17
- 230000001070 adhesive effect Effects 0.000 claims abstract description 17
- 239000001023 inorganic pigment Substances 0.000 claims abstract description 16
- 239000000843 powder Substances 0.000 claims description 52
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 claims description 22
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 239000000080 wetting agent Substances 0.000 claims description 11
- 239000002270 dispersing agent Substances 0.000 claims description 10
- 239000004094 surface-active agent Substances 0.000 claims description 7
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 6
- 239000012752 auxiliary agent Substances 0.000 claims description 6
- 229920000877 Melamine resin Polymers 0.000 claims description 5
- 229910001593 boehmite Inorganic materials 0.000 claims description 5
- FAHBNUUHRFUEAI-UHFFFAOYSA-M hydroxidooxidoaluminium Chemical group O[Al]=O FAHBNUUHRFUEAI-UHFFFAOYSA-M 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 4
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 3
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 229920000180 alkyd Polymers 0.000 claims description 3
- 239000001913 cellulose Substances 0.000 claims description 3
- 235000010980 cellulose Nutrition 0.000 claims description 3
- 229920002301 cellulose acetate Polymers 0.000 claims description 3
- 239000011737 fluorine Substances 0.000 claims description 3
- 229910052731 fluorine Inorganic materials 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 150000007522 mineralic acids Chemical class 0.000 claims description 3
- 150000007524 organic acids Chemical group 0.000 claims description 3
- 239000011092 plastic-coated paper Substances 0.000 claims description 3
- 229920002689 polyvinyl acetate Polymers 0.000 claims description 3
- 239000011118 polyvinyl acetate Substances 0.000 claims description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 3
- 239000000377 silicon dioxide Substances 0.000 claims description 3
- 239000007788 liquid Substances 0.000 abstract description 2
- 238000007765 extrusion coating Methods 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 48
- 239000010410 layer Substances 0.000 description 46
- 238000003756 stirring Methods 0.000 description 29
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 25
- 238000004519 manufacturing process Methods 0.000 description 20
- 239000012530 fluid Substances 0.000 description 19
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 18
- 239000011230 binding agent Substances 0.000 description 18
- 239000000049 pigment Substances 0.000 description 18
- 239000002002 slurry Substances 0.000 description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
- 239000008367 deionised water Substances 0.000 description 12
- 229910021641 deionized water Inorganic materials 0.000 description 12
- 229910001220 stainless steel Inorganic materials 0.000 description 12
- 239000010935 stainless steel Substances 0.000 description 12
- 239000000463 material Substances 0.000 description 8
- 238000004078 waterproofing Methods 0.000 description 7
- 239000010882 bottom ash Substances 0.000 description 6
- 238000001035 drying Methods 0.000 description 6
- 238000010792 warming Methods 0.000 description 6
- 244000025254 Cannabis sativa Species 0.000 description 5
- 239000012790 adhesive layer Substances 0.000 description 5
- 230000003068 static effect Effects 0.000 description 5
- IAGCDJZAYOZMCS-UHFFFAOYSA-N 2-hydroxypropanoic acid;titanium Chemical compound [Ti].CC(O)C(O)=O IAGCDJZAYOZMCS-UHFFFAOYSA-N 0.000 description 4
- 238000013019 agitation Methods 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000003384 imaging method Methods 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- 230000000903 blocking effect Effects 0.000 description 2
- 238000001125 extrusion Methods 0.000 description 2
- 239000004640 Melamine resin Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000003618 dip coating Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 238000007648 laser printing Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 238000007639 printing Methods 0.000 description 1
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Abstract
The invention relates to a special card sheet for a laser printer and a preparation method thereof. The special card sheet for the laser printer consists of a film base and a toner receiving layer, wherein the toner receiving layer is coated at the upper surface of the film base, the toner receiving layer is technically characterized by comprising an inorganic pigment and an adhesive according to the weight ratio of 1:1-15:1, and the coating amount of the toner receiving layer is 5-25 g/m<2> based on dry weight. In the preparation method, coating liquid of the toner receiving layer is firstly prepared and then is coated at the upper surface of the film base by using an extrusion coating mode. The invention has reasonable design and adopts the laser printer to directly print and form an image on the card sheet, greatly shortens the card-making time, reduces the card-making cost, enhances the card-making precision, improves the water-proofness, the wear resistance and the service life of the card and can be widely used for making various cards on site and making various personalized cards.
Description
Technical field
The invention belongs to fabrication sheet material field, especially a kind of special card sheet for laser printer and preparation method thereof.
Background technology
Along with the arriving of information age, the application of various information-recording materials is more and more, and the card card is widely used as typical case's representative of information recording carrier.At present, the making of personalized card card (as: PVC colour portrait card card is as employee's card, student's identity card, admission card for entrance examination, temporary residency card, driver's license etc.) mainly adopts traditional ink-jet printing material to make, because its manufacturing card and becomes card to have problems such as water proofing property difference, be very limited the service life that one-tenth blocks always.People constantly seek simply, accreditation mode efficiently adapts to quick and various information environment, the requirement of on-the-spot accreditation, personalized accreditation is more and more.Therefore characteristics such as print speed is fast because laser printing technology has, printing writing quality height, noise are little, are done also to gradually adopt laser printer to carry out fabrication in the card blocking.
A kind of manufacture craft of utilizing laser printing-laminated personal colour card is disclosed in Chinese patent file CN1304837A (open day is 2001.07.25), this manufacturing card utilizes laser printer to improve the definition of fabrication, but this patent is when carrying out fabrication, at first need to use laser printer to print, add wadding, be equipped with moulding through multiple film lamination towards blocking again, its manufacture craft is very complicated, the fabrication time is longer, can not adapt to the needs of on-the-spot accreditation.
Summary of the invention
The objective of the invention is to overcome the deficiencies in the prior art, a kind of special card sheet for laser printer and preparation method thereof is provided, this special card sheet for laser printer has that water proofing property is strong, the characteristics of long service life, its preparation method have technology simply, characteristics fast.
The present invention solves its technical problem and takes following technical scheme to realize:
A kind of special card sheet for laser printer, constitute by sheet base and ink powder receiving layer, this ink powder receiving layer is coated on the upper surface of sheet base, this ink powder receiving layer comprises inorganic pigment, adhesive and auxiliary agent, this auxiliary agent is wherein one or more the combination of curing agent, dispersant, wetting agent, the weight ratio of inorganic pigment and adhesive is 1: 1～15: 1, and the coating weight of this ink powder receiving layer is counted 5～25g/m with dry weight
2, described curing agent is a melamine.
And described inorganic pigment is boehmite, silica or brium carbonate; Described adhesive is polyvinyl butyral resin, alkyd resins, gelatin, polyvinylpyrrolidone, cellulose or polyvinyl acetate.
And the weight ratio of described curing agent and adhesive is 1: 10; Described dispersant is organic acid, inorganic acid or calgon, and the weight ratio of this dispersant and inorganic pigment is 1: 100～1: 30; Described wetting agent is silicon-type surfactant or fluorine surfactant, and the weight ratio of this wetting agent and ink powder receiving layer is 1: 1000.
And described base is PET, ABS, PC, plastic-coated paper or synthetic paper.
And the thickness of described base is 10 microns～1500 microns.
Advantage of the present invention and good effect are:
1, this special card sheet for laser printer is made of sheet base and the ink powder receiving layer that is coated on its upper surface thereof, this ink powder receiving layer is mixed with by inorganic pigment and adhesive and forms, use laser printer directly on this special card sheet, to be printed as picture, performances such as its water proofing property, wearability and service life are significantly better than the every performance that adopts open product, can be widely used in the field fabrication and the various personalized accreditation of various card cards, its manufacture craft is simple, improved the fabrication precision significantly, shorten the fabrication time, reduced the fabrication cost.
2, the ink powder receiving layer of this special card sheet for laser printer is mixed with by inorganic pigment and adhesive and forms, and adopt the extrusion coated mode that ink powder receiving layer coating fluid is coated on the upper surface of sheet base, its preparation method have technology simply, characteristics fast.
3, the sheet base of this special card sheet for laser printer adopts the various cards of present making to block widely used material, has excellent mechanical strength and weatherability, can use for a long time under exacting terms.
4, the present invention is reasonable in design, use laser printer directly on assertive evidence card material, to print and form picture, shortened the fabrication time significantly, reduced the fabrication cost, improved the fabrication precision, improve water proofing property, wearability and the service life of card card, can be widely used in the field fabrication and the various personalized accreditation of various card cards.
The specific embodiment
Below in conjunction with example the present invention is described further.
A kind of special card sheet for laser printer, be made of sheet base and ink powder receiving layer, this sheet base is PET, ABS, PC, plastic-coated paper or synthetic paper, is preferably PET white tablets base, the thickness of sheet base is 10 microns～1500 microns, and preferred thickness is 100 microns～1000 microns.This ink powder receiving layer comprises inorganic pigment and adhesive, and the weight ratio of inorganic pigment and adhesive is 1: 1～15: 1, and this ink powder receiving layer is coated on the upper surface of sheet base, and the coating weight of ink powder receiving layer is counted 5～25g/m with dry weight
2, be preferably 10～14g/m
2Inorganic pigment in the ink powder receiving layer can be selected boehmite, silica or brium carbonate etc. for use, is preferably boehmite, for example the boehmite of Tianjin Bo Yuan nanosecond science and technology Co., Ltd production; Adhesive in the ink powder receiving layer can be selected for use water-soluble or the water miscible adhesive of part, for example polyvinyl butyral resin (PVB), alkyd resins, gelatin, polyvinylpyrrolidone, cellulose or polyvinyl acetate, be preferably polyvinyl butyral resin (PVB), the molecular weight of this polyvinyl butyral resin is 3000～50000.
Also contain auxiliary agent in the ink powder receiving layer, this auxiliary agent is wherein one or more the combination of curing agent, dispersant, wetting agent.The adding curing agent can increase the water resistance of ink powder receiving layer, adds the suitable performance of coating that wetting agent can strengthen the ink powder receiving layer.This curing agent can be selected ethanol, isopropyl alcohol, acetone, melamine, lactic acid titanium or melamine resin etc. for use, is preferably melamine, and the weight ratio of this curing agent and adhesive is 1: 10.Dispersant can be selected organic acid, inorganic acid or calgon for use, is preferably acetic acid or calgon, and the weight ratio of this dispersant and inorganic pigment is 1: 100～1: 30.Wetting agent is silicon-type surfactant or fluorine surfactant, is preferably the silicon-type surfactant, and as Bi Ke chemistry BYK-347, the weight ratio of this wetting agent and ink powder receiving layer is 1: 1000.
A kind of preparation method of special card sheet for laser printer comprises the steps:
(1) preparation binder solution: with weight ratio is 1: 2 deionized water and ethanol, joins in the stainless steel cask, stirs, drop into adhesive then, continue to stir 1 hour, begin to be warming up to 40 ℃ and kept 1 hour, reduce to room temperature then, make binder solution;
(2) preparation pigment slurry: it is in 1: 3 the deionized water and alcohol mixeding liquid that inorganic pigment and dispersant are joined weight ratio, stirs, pre-dispersed and shear and disperse, and makes pigment slurry;
(3) preparation ink powder receiving layer coating fluid: binder solution and pigment slurry are mixed, add curing agent and wetting agent and make ink powder receiving layer coating fluid;
(4) ink powder receiving layer coating fluid is coated on the upper surface of sheet base, its coating method can adopt any coating method, promptly obtains special card sheet for laser printer after the drying.Coating method can be coating methods such as traditional dip-coating, roller coat, air knife, scraper, extruding, adopts the extrusion coated mode can guarantee the flatness and the glossiness of coating better.
Below by some specific embodiments this preparation method is described.
Embodiment 1
The sheet base is selected PET white tablets base for use, and each component of the ink powder receiving layer that is coated with on its surface and the parts by weight of each component are as follows:
The preparation process of special card sheet for laser printer is as follows:
1, preparation binder solution: claim 15.9 parts deionized water and 31.8 parts ethanol, join in the stainless steel cask, stir, under stirring state, 5.3 parts PVB is dropped into wherein then, continue to stir 1 hour, begin to be warming up to 40 ℃ and kept 1 hour, reduce to room temperature, obtain PVB solution (binder solution);
2, preparation pigment slurry: by the ethanol (15.9 parts) of prescription with balance of deionized water (5.3 parts) and surplus, join in the stainless steel cask, add 0.053 part of acetic acid, stir, add 5.3 parts of boehmites, continue to stir pre-dispersed 1 hour, use high speed shear disperser (BNE-100X of Shanghai prestige space company) to disperse again 2 hours, make pigment slurry;
3, preparation ink powder receiving layer coating fluid: PVB solution (binder solution) and pigment slurry are mixed, add 0.53 part of lactic acid titanium and 0.01 part of BYK-347, stir, static froth breaking makes ink powder receiving layer coating fluid;
4, use coating device that ink powder receiving layer coating fluid is applied on the adhesive-layer of PC white tablets base, the coating dry measure is 25g/m
2After under 50 ℃ of temperature dry 20 minutes, promptly get special card sheet for laser printer, survey its results of property as shown in Table 1.
Embodiment 2
The sheet base is selected PET white tablets base for use, and each component of the ink powder receiving layer that is coated with on its surface and the parts by weight of each component are as follows:
The preparation process of special card sheet for laser printer is as follows:
1, preparation binder solution: claim 15.9 parts deionized water and 31.8 parts ethanol, join in the stainless steel cask, stir, under agitation 5.3 parts PVB is dropped into wherein then, continue to stir 1 hour, begin to be warming up to 40 ℃ and kept 1 hour, reduce to room temperature, obtain PVB solution (binder solution);
2, preparation pigment slurry: by the ethanol (238.5 parts) of prescription with balance of deionized water (79.5 parts) and surplus, join in the stainless steel cask, add 1.6 parts of acetic acid, stir, add 79.5 parts of boehmites, continue to stir pre-dispersed 1 hour, use high speed shear disperser (BNE-100X of Shanghai prestige space company) to disperse again 2 hours, make pigment slurry;
3, preparation ink powder receiving layer coating fluid: PVB solution (binder solution) and pigment slurry are mixed, add 0.085 part of BYK-347 of 0.53 part of lactic acid titanium, stir, static froth breaking makes ink powder receiving layer coating fluid;
4, use coating device that ink powder receiving layer coating fluid is applied on the adhesive-layer of PC white tablets base, the coating dry measure is 25g/m
2After under 50 ℃ of temperature dry 20 minutes, promptly get special card sheet for laser printer, survey its results of property as shown in Table 1.
Embodiment 3
The sheet base is selected PET white tablets base for use, and each component of the ink powder receiving layer that is coated with on its surface and the parts by weight of each component are as follows:
The preparation process of special card sheet for laser printer is as follows:
1, preparation binder solution: claim 15.9 parts deionized water and 31.8 parts ethanol, join in the stainless steel cask, stir, under agitation 5.3 parts PVB is dropped into wherein then, continue to stir 1 hour, begin to be warming up to 40 ℃ and kept 1 hour, reduce to room temperature, obtain PVB solution (binder solution);
2, preparation pigment slurry: by the ethanol (15.9 parts) of prescription with balance of deionized water (5.3 parts) and surplus, join in the stainless steel cask, add 0.18 part of acetic acid, stir, add 5.3 parts of boehmites, continue to stir pre-dispersed 1 hour, use high speed shear disperser (BNE-100X of Shanghai prestige space company) to disperse again 2 hours, make pigment slurry;
3, preparation ink powder receiving layer coating fluid: PVB solution (binder solution) and pigment slurry are mixed, add 0.01 part of BYK-347 of 0.53 part of lactic acid titanium, stir, static froth breaking makes ink powder receiving layer coating fluid;
4, use coating device that ink powder receiving layer coating fluid is applied on the adhesive-layer of PC white tablets base, the coating dry measure is 10g/m
2After under 50 ℃ of temperature dry 20 minutes, promptly get special card sheet for laser printer, survey its results of property as shown in Table 1.
Embodiment 4
The sheet base is selected PET white tablets base for use, and each component of the ink powder receiving layer that is coated with on its surface and the parts by weight of each component are as follows:
The preparation process of special card sheet for laser printer is as follows:
1, preparation binder solution: claim 3.6 parts deionized water and 7.2 parts ethanol, join in the stainless steel cask, stir, under agitation 1.2 parts PVB is dropped into wherein then, continue to stir 1.5 hours, begin to be warming up to 40 ℃, kept 2 hours, reduce to room temperature, obtain PVB solution (binder solution);
2, preparation pigment slurry: by the ethanol (36.0 parts) of prescription with balance of deionized water (12.0 parts) and surplus, join in the stainless steel cask, add 0.3 part of acetic acid, stir, add 12.0 parts of boehmites, continue to stir pre-dispersed 2 hours, use high speed shear disperser (BNE-100X of Shanghai prestige space company) to disperse again 2 hours, make pigment slurry;
3, preparation ink powder receiving layer coating fluid: PVB solution (binder solution) and pigment slurry are mixed, add 0.12 part of melmac and 0.013 part of BYK-347, stir, static froth breaking makes ink powder receiving layer coating fluid;
4, use coating device that ink powder receiving layer coating fluid is applied on the adhesive-layer of PET white tablets base, the coating dry measure is 15g/m
2After under 50 ℃ of temperature dry 20 minutes, promptly get special card sheet for laser printer, survey its results of property as shown in Table 1.
Embodiment 5
The sheet base is selected PET white tablets base for use, and each component of the ink powder receiving layer that is coated with on its surface and the parts by weight of each component are as follows:
The preparation process of special card sheet for laser printer is as follows:
1, preparation binder solution: claim 3.6 parts deionized water and 7.2 parts ethanol, join in the stainless steel cask, stir, under agitation 1.2 parts PVB is dropped into wherein then, continue to stir 1.5 hours, begin to be warming up to 40 ℃, kept 2 hours, reduce to room temperature, obtain PVB solution (binder solution);
2, preparation pigment slurry: by the ethanol (36.0 parts) of prescription with balance of deionized water (12.0 parts) and surplus, join in the stainless steel cask, add 0.3 part of acetic acid, stir, add 12.0 parts of brium carbonates, continue to stir pre-dispersed 2 hours, use high speed shear disperser (BNE-100X of Shanghai prestige space company) to disperse again 2 hours, make pigment slurry;
3, preparation ink powder receiving layer coating fluid: PVB solution (binder solution) and pigment slurry are mixed, add 0.12 part of melmac and 0.013 part of BYK-347, stir, static froth breaking makes ink powder receiving layer coating fluid;
4, use coating device that ink powder receiving layer coating fluid is applied on the adhesive-layer of PET white tablets base, the coating dry measure is 15g/m
2After under 50 ℃ of temperature dry 20 minutes, promptly get special card sheet for laser printer, survey its results of property as shown in Table 1.
Comparative example
This comparative example is the used sheet material of ink-jet printer, and this sheet material adopts PVC white tablets base, and at its surface coating ink powder receiving layer, this ink powder receiving layer comprises two-layer up and down, and the component of upper strata and lower floor and the parts by weight of each component are as follows:
Its preparation process:
Preparation ink powder receiving layer is applied to it on PET white film with the excellent spreader of silk, and the coating dry measure is carried out by the embodiment requirement; Behind the heat drying, obtain unified recording materials, be die-cut into the standard scale, survey its performance as shown in Table 1 with the standard card punch machine.
Table one
| Imaging | Bottom ash | Drying time | Water proofing property | Service life | |
| Embodiment 1 | B | A | 0 second | A | A |
| Embodiment 2 | A | C | 0 second | A | A |
| Embodiment 3 | A | B | 0 second | A | A |
| Embodiment 4 | A | A | 0 second | A | A |
| Embodiment 5 | B | B | 0 second | A | B |
| Comparative example | C | B | 0 second | C | C |
Test and the evaluation to the foregoing description now describes:
1, imaging:
Utilize the OKI5880 laser printer that yellow, magenta, cyan, these four kinds of colors of black are tested.
A: clear
B: ink powder shifts
C: ink powder shifts serious
Drying time:
Under the condition of environment temperature (23 ± 2) ℃, relative humidity (55 ± 10) %, on the test specimen page, print test chart drying time.By 1.5cm * 1.5cm color lump that 100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% black (K) four look China inks are formed by stacking, print above-mentioned color lump with the OKI5880 laser printer.After print media goes out machine, put the clean scraps of paper successively according to the time that each color lump is demarcated, on the scraps of paper, add ballast (weight is the piece of stainless steel of 2.5cm * 2.5cm * 8mm, and the weight of each bloom is identical) then.Treat that weight is pressed in the scraps of paper after last 3 minute, take off and observe its pollution condition.The pairing shortest time of the free of contamination scraps of paper is the drying time of this medium.
2, water proofing property:
After using the OKI5880 laser printer to print 2cm * 2cm 100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% black (K) four look color lumps, under tap, washed 30 minutes, dab with have gentle hands and smear, observe the surface and become dirty situation with circulating water.
A: the surface is without any change
B: the surface is slight to become dirty
C: the surface becomes dirty
3, bottom ash:
Use the OKI5880 laser printer to print 21cm * 297cm 100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% black (K) four look color lumps, compare with unprinted special card sheet for laser printer then, observe the bottom ash situation.
A: the surface does not have bottom ash
B: the slight bottom ash in surface
C: bottom ash is serious
4, service life:
After using the OKI5880 laser printer to print 100% green grass or young crops (C), 100% product (M), 100% Huang (Y), 100% black (K) color lump, make green grass or young crops, product, Huang, black four colour standard scales by standard card clipping technique, use the constant temperature and humidity ageing oven, test 60 ℃, relative humidity 90%, the one-tenth card performance after 96 hours.
As seen through the above analysis, performances such as water proofing property of the present invention, imaging, service life are significantly better than every performance of open product, can be widely used in the field fabrication and the various personalized accreditation of various card cards, can obtain having do soon, the card card of Gao Guang, waterproof, characteristic such as wear-resisting.
It is emphasized that; embodiment of the present invention is illustrative; rather than it is determinate; therefore the present invention is not limited to the embodiment described in the specific embodiment; every other embodiments that drawn by those skilled in the art's technical scheme according to the present invention belong to the scope of protection of the invention equally.
Claims (5)
1. special card sheet for laser printer, constitute by sheet base and ink powder receiving layer, this ink powder receiving layer is coated on the upper surface of sheet base, this ink powder receiving layer comprises inorganic pigment, adhesive and auxiliary agent, this auxiliary agent is wherein one or more the combination of curing agent, dispersant, wetting agent, the weight ratio of inorganic pigment and adhesive is 1: 1～15: 1, and the coating weight of this ink powder receiving layer is counted 5～25g/m with dry weight
2, it is characterized in that: described curing agent is a melamine.
2. special card sheet for laser printer according to claim 1 is characterized in that: described inorganic pigment is boehmite, silica or brium carbonate; Described adhesive is polyvinyl butyral resin, alkyd resins, gelatin, polyvinylpyrrolidone, cellulose or polyvinyl acetate.
3. special card sheet for laser printer according to claim 1 is characterized in that: the weight ratio of described curing agent and adhesive is 1: 10; Described dispersant is organic acid, inorganic acid or calgon, and the weight ratio of this dispersant and inorganic pigment is 1: 100～1: 30; Described wetting agent is silicon-type surfactant or fluorine surfactant, and the weight ratio of this wetting agent and ink powder receiving layer is 1: 1000.
4. special card sheet for laser printer according to claim 1 is characterized in that: described base is PET, ABS, PC, plastic-coated paper or synthetic paper.
5. according to claim 1 or 4 described special card sheet for laser printer, it is characterized in that: the thickness of described base is 10 microns～1500 microns.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010125222 CN101797851B (en) | 2010-03-16 | 2010-03-16 | Special card sheet for laser printer and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010125222 CN101797851B (en) | 2010-03-16 | 2010-03-16 | Special card sheet for laser printer and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN101797851A CN101797851A (en) | 2010-08-11 |
| CN101797851B true CN101797851B (en) | 2011-08-03 |
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|---|---|---|---|---|
| CN102218953B (en) * | 2011-05-13 | 2013-10-16 | 潍坊恒彩数码影像材料有限公司 | Laser printing film and preparation method thereof |
| CN102501675A (en) * | 2011-10-14 | 2012-06-20 | 江苏格美高科技发展有限公司 | Matte polypropylene inkjet photo paper suitable for ECO-solvent ink |
| CN102632739A (en) * | 2012-04-27 | 2012-08-15 | 张保平 | Non-silver digitalized laser-printing medical image film |
| CN102922893B (en) * | 2012-10-30 | 2015-02-18 | 江苏格美高科技发展有限公司 | Medical laser color printing and imaging PET (Polyester) film and preparation method thereof |
| CN108589401A (en) * | 2018-04-08 | 2018-09-28 | 温州创佳影像材料有限公司 | A kind of waterproof fluorescence Alhue paper and its production technology |
| CN108611917A (en) * | 2018-04-08 | 2018-10-02 | 温州创佳影像材料有限公司 | A kind of non-watertight bloom digital photo paper and its production technology being applicable in cold and hot mounting film |
Family Cites Families (4)
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| CN1027582C (en) * | 1993-03-20 | 1995-02-08 | 北京化工学院 | laser printing offset printing plate and preparation method thereof |
| CN1105936A (en) * | 1994-05-09 | 1995-08-02 | 北京捷印精细化工技术公司 | Light printing laser offset plate and its production method |
| DE19847033A1 (en) * | 1998-10-13 | 2000-04-20 | Agfa Gevaert Ag | Negative working, radiation-sensitive mixture for the production of a recordable material with heat or infrared laser |
| US8147198B2 (en) * | 2006-02-24 | 2012-04-03 | Bell Helicopter Textron Inc. | Helicopter rotor yoke and method of making same |
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