CN101797200A - Absorbent article with anti-mosquito agent and preparation method thereof - Google Patents
Absorbent article with anti-mosquito agent and preparation method thereof Download PDFInfo
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技术领域:Technical field:
本发明涉及一种日常用吸收用品,属日常用品技术领域,具体地说,尤其指一种一次性具有防蚊虫剂的吸收用品及制备方法。The invention relates to an absorbent article for daily use, which belongs to the technical field of daily articles, in particular to a disposable absorbent article with an anti-mosquito agent and a preparation method thereof.
背景技术:Background technique:
随着生活水平的提高,人们对一次性吸收物品的需求不再仅仅满足于简单的吸尿功能,需求开始呈现多功能化。尿布从简陋的第一代发展到第六代,产品在功能上日趋多样化,各个厂家也致力于尿布产品的多样化设计:弹性腰围、弹性大耳朵等适合大腰身弹性功能设计,表皮护理及杀菌的芦荟、抗菌表层材料功能性设计,透气性强的高透气底膜等透湿性设计,尿湿显示等功能性提示设计。诸多各种设计,呈现出未来一次性尿布的设计必然呈现更多的功能化。With the improvement of living standards, people's demand for disposable absorbent articles is no longer satisfied with the simple urine absorption function, and the demand has begun to show multi-functionality. Diapers have developed from the humble first generation to the sixth generation. The functions of products are becoming more and more diversified. Various manufacturers are also committed to diversifying the design of diaper products: elastic waist, elastic big ears and other elastic functional designs suitable for large waists, skin care and Functional design of sterilizing aloe vera and antibacterial surface material, moisture permeability design such as highly breathable and highly breathable bottom film, and functional reminder design such as urine wetness display. Many various designs show that the design of disposable diapers in the future will inevitably show more functionalization.
蚊子等吸血动物除直接叮刺吸血、骚扰祥和的工作、生活气氛外,还会传染多种严重疾病,如痢疾、登革热、流行性乙型脑炎、淋巴丝虫病、黄热病、马脑炎等,严重危害人类健康。据统计,每年超过100万人死于蚊传染病。防治蚊传疾病的传播是全球广泛关注的重要公共卫生问题,降低蚊传疾病发病率,减轻蚊传疾病负担已列入《联合国千年发展目标》。Mosquitoes and other blood-sucking animals, in addition to directly biting and sucking blood, disturbing the peaceful work and living atmosphere, can also infect many serious diseases, such as dysentery, dengue fever, Japanese encephalitis, lymphatic filariasis, yellow fever, equine encephalitis, etc. Inflammation, etc., seriously endanger human health. According to statistics, more than 1 million people die from mosquito-borne diseases every year. Prevention and control of the spread of mosquito-borne diseases is an important public health issue of global concern. Reducing the incidence of mosquito-borne diseases and reducing the burden of mosquito-borne diseases has been included in the United Nations Millennium Development Goals.
目前应用比较成熟的防蚊虫方法主要用两种。第一种方法就是对环境中的蚊子进行驱避或杀灭的方法,这种方法使用简便,经济实惠,但是效果并不持久,需要经常使用。并且蚊香或杀虫气雾剂所释放出的烟雾或药剂会对人体产生一定的伤害,因此不适合经常使用。第二种方法就是对经常与人体接触的纺织品进行加工整理,使之具有耐久的防蚊虫效果。这种方法操作简单,使用方便,技术工艺成熟,经过长时间的生产时间,证明具有良好的防蚊虫效果,并且耐多次水洗,对人体无毒、无害。At present, the more mature anti-mosquito methods are mainly used in two ways. The first method is to repel or kill mosquitoes in the environment. This method is easy to use and economical, but the effect is not long-lasting and needs to be used frequently. And the smog or medicine released by mosquito coils or insecticidal aerosols will cause certain damage to the human body, so it is not suitable for regular use. The second method is to process the textiles that are often in contact with the human body to make it have a durable anti-mosquito effect. This method is simple to operate, convenient to use, and has mature technology. After a long production time, it has been proved to have a good anti-mosquito effect, and it is resistant to multiple washings, and it is non-toxic and harmless to the human body.
具有驱避效能和杀蚊效能的化合物有许多种,但效果差异较大,理想的驱避剂和杀虫剂具有高效、快速、对人体无害、对皮肤无刺激、无难闻气味、性质稳定、价格低廉、使用方便等优点。There are many kinds of compounds with repellent and mosquito-killing effects, but the effects are quite different. Ideal repellents and insecticides are highly efficient, fast, harmless to human body, non-irritating to the skin, and have no unpleasant smell. Stability, low price, easy to use and so on.
驱避剂本身并无杀虫作用,一般认为其驱蚊的机理是因为驱避蚊剂具有蚊虫所厌恶的气味,使其不愿在含有驱避剂的地方停歇而逃之夭夭,利于预防蚊虫的叮咬和侵袭。另外一种观点认为,驱避作用很有可能是因为驱蚊化合物的分子阻塞可蚊子感觉器官毛状物的小孔,使蚊子失去了对人体散发出的热气和湿气的跟踪能力,从而不能正确地找到目的物所致。The repellent itself has no insecticidal effect. It is generally believed that its mechanism of repelling mosquitoes is because the repellent has an odor that mosquitoes hate, making them unwilling to stop and run away in places containing repellent, which is beneficial to prevent mosquito bites and invasion. Another point of view is that the repellent effect is probably due to the fact that the molecules of the mosquito repellent compound block the small holes in the hairs of the mosquito's sensory organs, so that the mosquito loses the ability to track the heat and moisture emitted by the human body, so it cannot Correctly find the target object.
常用的驱避剂是对孟烷-3,8-二醇,该物质为微黄色蜡状物,难溶于水,易溶于有机溶剂。此外,孟烯二醇、4-萜丙醇、2,5-二甲苯-2,5 己二醇、孟烷醇类化合物、苯羧酸酯化合物、苯酸胺化合物等也可用作生产防蚊虫驱避剂。The commonly used repellent is p-mentane-3,8-diol, which is a light yellow waxy substance, hardly soluble in water, but easily soluble in organic solvents. In addition, menthenediol, 4-terpene propanol, 2,5-xylene-2,5 hexanediol, menthanol compounds, benzene carboxylate compounds, benzoic acid amine compounds, etc. Mosquito repellant.
杀虫剂主要通过触杀、熏蒸作用杀灭害虫。虽然杀虫剂的种类很多,但在目前用于杀灭蚊蝇等昆虫的卫生杀虫剂中,拟除虫菊酯最受推崇。拟除虫菊酯是近四十年才迅速发展起来的一类化合物。它是模拟天然除虫菊素的化学结构,人工合成的一类新型卫生杀虫剂。它具有快速击倒、杀虫谱广、药效高等特点,对昆虫具有驱避作用,对人体毒性低,易生物降解,在生物降解后不产生有毒残留物,另外,拟除虫菊酯的理化性质也比较理想,适合制成各种类型制剂。拟除虫菊酯化合物中最适宜用于织物或纤维材料防蚊虫的是胺菊酯,纯胺菊酯为白色晶体,不溶于水,溶于有机溶剂,对昆虫的击倒作用极快,常温下贮存三年品质不变。Pesticides mainly kill pests through contact and fumigation. Although there are many kinds of insecticides, among the hygienic insecticides currently used to kill insects such as mosquitoes and flies, pyrethroids are the most respected. Pyrethroids are a class of compounds that have developed rapidly in the past forty years. It is a new type of hygienic insecticide that simulates the chemical structure of natural pyrethrins and is artificially synthesized. It has the characteristics of fast knockdown, wide insecticidal spectrum, high efficacy, etc., has repellent effect on insects, low toxicity to human body, easy biodegradation, no toxic residues after biodegradation, in addition, the physical and chemical properties of pyrethroids It is also ideal and suitable for making various types of preparations. Among pyrethroid compounds, tetramethrin is most suitable for fabric or fiber materials to prevent mosquitoes. Pure tetramethrin is a white crystal, insoluble in water, soluble in organic solvents, and has a very fast knockdown effect on insects. Store at room temperature The quality remains the same for three years.
CN101187158公开了一种防蚊整理剂与制备方法及采用所述防蚊虫整理剂制备的防蚊虫织物,其中防蚊虫整理剂采用含糊精类化合物、驱蚊剂、表面活性剂、缓冲剂、催化剂、交联剂组成,通过将驱蚊剂包合在糊精类化合物的空腔中,然后用咪唑类树脂作为交联剂,再加入适当的其他添加剂便可制得整理剂。将防蚊整理剂的水溶液经浸轧-预烘-焙烘工艺,通过化学交联方法可将防蚊整理剂整理到布料中,得到防蚊织物。为进一步提高织物具有安全、防蚊效果持久、穿着舒适性强等优点,可广泛用于制作各种具有防蚊功效的织品,具有很好的社会价值与经济效益。CN101187158 discloses an anti-mosquito finishing agent and its preparation method and the anti-mosquito fabric prepared by using the anti-mosquito finishing agent, wherein the anti-mosquito finishing agent is made of compounds containing dextrin, mosquito repellent, surfactant, buffer, catalyst, The composition of the cross-linking agent is that the finishing agent can be prepared by encapsulating the mosquito repellent in the cavity of the dextrin compound, then using the imidazole resin as the cross-linking agent, and adding other appropriate additives. The aqueous solution of the anti-mosquito finishing agent is subjected to a padding-pre-baking-baking process, and the anti-mosquito finishing agent can be finished into the cloth through a chemical cross-linking method to obtain the anti-mosquito fabric. In order to further improve the advantages of safety, long-lasting anti-mosquito effect, and strong wearing comfort, the fabric can be widely used to make various anti-mosquito fabrics, and has good social value and economic benefits.
CN1033736A公开了一种具有驱蚊功能的网织物,该网织物可用于室内、野外供个人防蚊、蠓的驱蚊网式织物。他主要将棉纱网放在药物溶液中浸渍。其药物成分由驱避剂、增效剂、高分子保护剂、丙酮和乙醇所组成。该网织物可制成帽子、手套、袜子、汗背心、门帘及罩单等,其每次有效时间达4个月左右,可适当的清洗、日晒,对人体不构成危害。CN1033736A discloses a net fabric with mosquito repelling function, which can be used as a mosquito repelling net fabric for personal mosquito and midge prevention indoors and outdoors. He basically dipped cotton gauze in a solution of the drug. Its medicinal ingredients are composed of repellent, synergist, macromolecule protective agent, acetone and ethanol. The net fabric can be made into hats, gloves, socks, vests, door curtains and cover sheets, etc., and its effective time is about 4 months each time. It can be properly washed and exposed to the sun without causing harm to the human body.
CN1468983A公开了一种具有避蚊功能的聚丙烯纤维,该聚丙烯纤维通过聚丙烯树脂与驱蚊剂均匀混合后熔融造粒再经熔融纺丝得到,纤维中均匀地含有驱蚊剂,纤维中的驱蚊剂含量控制为1.0~3.0%,驱蚊剂取自邻苯二甲酸二甲酯、三氯杀虫酯或甲醚菊酯中的一种化合物或两种以上化合物的混合物,纤维可以是单丝线密度为1.0~4.0dtex的预取向丝POY,或进一步加工成为单丝线密度为0.5~3.0dtex的牵伸丝DT或弹力丝DTY,或者是线密度为1.0~4.0dtex的短纤维,与现有技术相比,本发明的优点是驱蚊剂均匀地存在于纤维中而不是仅仅附着于表面,耐水洗性能明显提高。CN1468983A discloses a polypropylene fiber with mosquito repellent function. The polypropylene fiber is obtained by uniformly mixing polypropylene resin and mosquito repellant, melting and granulating, and then melt spinning. The fiber uniformly contains mosquito repellent, and the fiber contains The content of mosquito repellent is controlled at 1.0 to 3.0%, and the mosquito repellent is derived from one compound or a mixture of two or more compounds in dimethyl phthalate, triclosulphate or methothrin, and the fiber can be It is pre-oriented yarn POY with a linear density of 1.0-4.0dtex, or further processed into drawn yarn DT or elastic yarn DTY with a linear density of 0.5-3.0dtex, or short fibers with a linear density of 1.0-4.0dtex, Compared with the prior art, the invention has the advantages that the mosquito repellent is evenly present in the fiber instead of just adhering to the surface, and the washing resistance is obviously improved.
CN1267494A公开了一种驱蚊驱虫蚊帐及其生产方法。蚊帐上附着有一层包括邻苯二甲酸二甲酯与驱蚊胺的混合反应物。生产方法为首先将包括邻苯二甲酸二甲酯与驱蚊胺的化工原料混合,混合后的反应物与水按重量比50%的比例进行配比,制成溶液;将溶液加温至60-100℃;将蚊帐放入溶液中进行浸液搅拌;用白乳胶与聚乙烯醇制成胶黏剂,将浸液处理后的蚊帐放入脱粘剂内搅拌,进行覆盖胶粘,最后干燥处理。CN1267494A discloses a mosquito-repelling and insect-repelling mosquito net and a production method thereof. A layer of mixed reactants including dimethyl phthalate and DEET is attached to the mosquito net. The production method is as follows: firstly, chemical raw materials including dimethyl phthalate and insect repellent are mixed, and the reactants after mixing are mixed with water at a ratio of 50% by weight to make a solution; the solution is heated to 60 -100°C; put the mosquito net into the solution for immersion and stirring; use white latex and polyvinyl alcohol to make an adhesive, put the immersion treated mosquito net into the debonding agent and stir, cover and glue, and finally dry deal with.
各纸尿裤厂家致力于新型功能化吸收物品的研发,但目前为止未发现有驱蚊虫的吸收物品。驱蚊虫功能也是尿布需求多功能化的一种发展趋势。Various diaper manufacturers are committed to the research and development of new functional absorbent articles, but so far no absorbent articles that repel mosquitoes have been found. The mosquito repellent function is also a development trend of multi-functional demand for diapers.
发明内容:Invention content:
本发明的目的旨在克服上述现有技术中的不足之处,而提供一种结构简单,制造成本低,具有防蚊虫剂功能的吸收物品及制备方法。所述的吸收物品对蚊子、白蛉、蜱、恙螨等吸血昆虫都具有理想的驱避作用,可有效防止蚊虫叮咬。The purpose of the present invention is to overcome the disadvantages of the above-mentioned prior art, and to provide an absorbent article with simple structure, low manufacturing cost, and the function of mosquito repellent and its preparation method. The absorbent article has an ideal repelling effect on mosquitoes, sandflies, ticks, chiggers and other blood-sucking insects, and can effectively prevent mosquito bites.
为了达到上述目的,本发明采用如下技术方案:In order to achieve the above object, the present invention adopts following technical scheme:
(一)一种防蚊剂,其包括下述重量份的组分:(1) a mosquito repellent, which comprises the following components by weight:
2%~15%香精油,5%~15%驱蚊剂,1%~5%杀虫剂,5%~10%缓释剂,乙醇40~60%,去离子水适量。2% to 15% essential oil, 5% to 15% mosquito repellent, 1% to 5% insecticide, 5% to 10% slow release agent, 40 to 60% ethanol, and appropriate amount of deionized water.
所述的香精油是一种香精油是天然植物香料最主要的商品形态之,是以香料植物的花卉、根、叶、茎、枝、木、皮、籽或分泌物为原料,经蒸馏、干馏、萃取、压榨等工艺提取的具有香味的精油物质。如优选薄荷油、香叶天竺葵油、山仓子油、樟脑油、香矛草油、薰衣草油中的一种或几种的组合。The essential oil is a kind of essential oil, which is one of the most important commercial forms of natural plant spices. It is made from flowers, roots, leaves, stems, branches, wood, bark, seeds or secretions of spice plants. After distillation, Fragrant essential oils extracted by dry distillation, extraction, pressing and other processes. For example, one or more combinations of peppermint oil, geranium oil, bark oil, camphor oil, lemongrass oil, and lavender oil are preferred.
所述的薄荷油是一种无色或淡黄色的澄清液体。有特殊的清凉香气,味初辛、后凉,存放日久,色渐变深。与乙醇、氯仿或乙醚能任意混合,相对密度应为0.888~0.908,折光率为1.456~1.466,薄荷油可消除恶心、紧张和紧张性头痛;可退热,还可祛除蚊虫。Described peppermint oil is a kind of colorless or pale yellow clear liquid. It has a special cool aroma, tastes pungent at the beginning, cools later, and the color gradually becomes darker after being stored for a long time. It can be arbitrarily mixed with ethanol, chloroform or ether, the relative density should be 0.888-0.908, and the refractive index should be 1.456-1.466. Peppermint oil can eliminate nausea, tension and tension headaches; it can reduce fever and mosquitoes.
所述的香叶天竺葵油的主要成分为香叶醇、香茅醇、芳樟醇(沉香醇)和苯乙醇等,可作玫瑰油的代用品,用以调制香精,作食品、香皂和牙膏等的添加剂。香叶天竺葵油可抗疲劳和精神创伤,也可祛蚊。The main components of the geranium oil are geraniol, citronellol, linalool (linalool) and phenylethyl alcohol, etc., which can be used as a substitute for rose oil, used to prepare essence, and used as food, scented soap and toothpaste and other additives. Geranium oil fights fatigue and trauma, and also repels mosquitoes.
所述的山苍子油是一种浅黄色至黄色澄清液体,主要由樟科植物山苍子树的果实经蒸汽蒸馏而得得率约为3%~6%左右。主要成分是柠檬醛,含量约达70%-80%。其它成分包括甲基庚烯酮,香茅醛,蒎烯,苎烯,香叶醇,松油醇,乙酸香叶酯等;具有清鲜香甜的果香,有酸柠檬样气息,不及柠檬草油香气好,强烈而不持久;相对密度:0.882~0.905;沸点:232℃;折射率:1.4810~1.4880;旋光度:+5~+35(20℃);闪点:130°F。The litsea cubeba oil is a light yellow to yellow clear liquid, which is mainly obtained by steam distillation of the fruit of the lauraceae plant litsea cubeba, with a yield of about 3% to 6%. The main component is citral, the content is about 70%-80%. Other ingredients include methylheptenone, citronellal, pinene, limonene, geraniol, terpineol, geranyl acetate, etc.; it has a fresh and sweet fruity aroma, with a sour lemon-like smell, not as good as lemongrass The oil has good aroma, strong but not persistent; Relative density: 0.882~0.905; Boiling point: 232°C; Refractive index: 1.4810~1.4880; Optical rotation: +5~+35 (20°C); Flash point: 130°F.
所述的樟脑油是一种无色或淡黄色至红棕色的油状液体,具有强烈的樟脑气味,与乙醇和乙醚任意混溶,相对密度0.875~0.900,折光率(20℃)1.465~1.481,旋光度(20℃)+9°~+24°,樟脑油的特殊清香,除能防虫驱蚊外,还具有愈合伤口、除臭等功能,用途十分广泛。The camphor oil is a colorless or light yellow to reddish-brown oily liquid with a strong camphor smell, is freely miscible with ethanol and ether, has a relative density of 0.875-0.900, and a refractive index (20° C.) of 1.465-1.481. Optical rotation (20°C) +9°~+24°, the special fragrance of camphor oil, in addition to repelling insects and mosquitoes, also has the functions of healing wounds, deodorization, etc., and has a wide range of uses.
所述的香茅草油为苍黄色至苍棕黄色澄清液体。香茅油相对密度0.880~0.895,折射率1.466~1.473。主要成分为香茅醛、香叶醇、香茅醇、柠檬醛、香茅烯等。香矛草油具有强烈的青草香气,被广泛用来添加在香水、肥皂、乳液、亮光剂、清洁剂和除臭剂、化妆品之中,另外它也为某些中国菜增添诱人的香味。The citronella oil is pale yellow to pale brown clear liquid. The relative density of citronella oil is 0.880-0.895, and the refractive index is 1.466-1.473. The main ingredients are citronellal, geraniol, citronellol, citral, citronellene, etc. Lemongrass oil has a strong grassy aroma and is widely used in perfumes, soaps, lotions, lighteners, cleansers and deodorants, cosmetics, and it also adds an attractive aroma to certain Chinese dishes.
所述的薰衣草油的主要成分是乙酸芳樟酯,这个化合物对人来说是起镇静作用的。性质温和,气味芳香,静心、助睡眠,可降低高血压,安抚心悸。促进细胞再生,祛斑、杀菌、消炎、止痒,对皮炎、粉刺、疱疹、脚气有良好的消炎杀菌效果。The main component of described lavender oil is linalyl acetate, and this compound has a sedative effect on people. It is mild in nature, fragrant in smell, calms the mind, helps sleep, reduces high blood pressure, and calms heart palpitations. Promote cell regeneration, remove freckles, sterilize, reduce inflammation, relieve itching, and have good anti-inflammatory and bactericidal effects on dermatitis, acne, herpes, and beriberi.
所述的驱蚊剂优选N,N-二乙基间甲苯甲酰胺(DEET)、苯酸苄酯、邻苯二甲酸二甲酯中的一种或几种的组合。The mosquito repellent is preferably one or a combination of N,N-diethyl-m-toluamide (DEET), benzyl benzoate, and dimethyl phthalate.
所述的N,N-二乙基间甲苯甲酰胺(DEET)是淡黄色液体,有淡的柑桔清香气味,它的沸点是111℃(1mmHg),蒸气密度6.7(vs air),密度0.998g/mLat 20℃,蒸气压<1.3Pa/25℃,折射率n20/D1.523,闪点>230°F。等张比容(90.2K)为475.1,极化率(0.510-24cm3)为23.28,表面张力(3.0dyne/cm)为35.9。由于其独特的分子结构、形状和体积,能阻塞蚊子的感觉器官使之无法找到寄主,从而发挥驱避作用。Described N, N-diethyl m-toluamide (DEET) is light yellow liquid, has light citrus fragrance smell, and its boiling point is 111 ℃ (1mmHg), vapor density 6.7 (vs air), density 0.998 g/mLat 20°C, vapor pressure <1.3Pa/25°C, refractive index n 20 / D 1.523, flash point >230°F. The isotonic specific volume (90.2K) is 475.1, the polarizability (0.510-24cm 3 ) is 23.28, and the surface tension (3.0dyne/cm) is 35.9. Due to its unique molecular structure, shape and volume, it can block the mosquito's sensory organs so that it cannot find the host, thus playing a repellent role.
所述的苯酸苄酯是一种无色粘稠液体。存在于秘鲁香脂、妥卢香脂和衣兰油等中。有微弱的愉快香气。不溶于水和甘油,溶于乙醇、乙醚和氯仿。用作麝香的溶剂和香精的定香剂、樟脑的代用品(在赛璐珞中),也用于配制百日咳药、气喘药等。由苯(甲)酸甲酯与过量的苄醇经酯交换,或由苯(甲)酸钠与苄基氯作用而制得。Described benzyl benzoate is a kind of colorless viscous liquid. Exist in Peru balsam, Tolu balsam and ylang-ylang oil. Has a faint pleasant aroma. Insoluble in water and glycerin, soluble in ethanol, ether and chloroform. It is used as a solvent for musk and as a fixative for essence, as a substitute for camphor (in celluloid), and for the preparation of pertussis and asthma medicines. From benzoic acid methyl ester and excess benzyl alcohol by transesterification, or from benzoic acid sodium and benzyl chloride role in the system.
所述的邻苯二甲酸二甲酯是一种无色透明微黄色油状液体,稍有芳香味,沸点为283.7℃。能与乙醇、乙醚等一般有机溶剂混溶,不溶于水和石油醚。可用作驱蚊油(原油)、聚氟乙烯涂料、过氧化甲乙酮以及滴滴涕的溶剂。The dimethyl phthalate is a colorless, transparent, yellowish oily liquid with a slight aroma and a boiling point of 283.7°C. It can be miscible with general organic solvents such as ethanol and ether, but insoluble in water and petroleum ether. It can be used as a solvent for mosquito repellent oil (crude oil), polyvinyl fluoride paint, methyl ethyl ketone peroxide and DDT.
所述的杀虫剂主要通过触杀、熏蒸作用杀灭害虫。虽然杀虫剂的种类很多,但在目前用于杀灭蚊蝇等昆虫的卫生杀虫剂中,拟除虫菊酯最受推崇。拟除虫菊酯化合物中最适宜用于织物或纤维材料防蚊虫整理的是胺菊酯。The insecticide mainly kills pests through contact killing and fumigation. Although there are many kinds of insecticides, among the hygienic insecticides currently used to kill insects such as mosquitoes and flies, pyrethroids are the most respected. Among pyrethroid compounds, tetramethrin is the most suitable for mosquito repellent finishing of fabrics or fiber materials.
胺菊酯是拟除虫菊酯类杀虫剂,胺菊酯纯品为白色结晶,具有除虫菊样的气味。为黄色膏状物或凝固体,比重(20℃)1.108,沸点185~190℃(0.1mmHg),熔点60~80℃,闪点200℃以上,蒸汽压(20℃)4.7*10-6Pa,水中溶解度(30℃)仅4.6mg/kg。溶于丙酮、苯和二甲苯。在弱酸性条件下稳定。胺菊酯在50℃下储存6个月,不失去生物活性。Tetramethrin is a pyrethroid insecticide, and its pure product is white crystal with a pyrethrum-like odor. It is a yellow paste or solidified solid, specific gravity (20°C) 1.108, boiling point 185-190°C (0.1mmHg), melting point 60-80°C, flash point above 200°C, vapor pressure (20°C) 4.7*10-6Pa, The solubility in water (30°C) is only 4.6mg/kg. Soluble in acetone, benzene and xylene. Stable under weakly acidic conditions. Tetramethrin does not lose its biological activity when stored at 50°C for 6 months.
胺菊酯为世界卫生组织推荐用于公共卫生的主要杀虫剂之一。可用于各种场合的公共卫生害虫如蚊、蝇、蟑螂、臭虫、跳蚤、虱、蠓虫、飞蛾、蜘蛛、香烟甲虫、谷象虫、蚜虫、蚊、黄蜂、蟋蟀等的扑灭和驱避。单独使用效果不明显,应和其它杀虫力强的卫生杀虫剂混配使用。Tetramethrin is one of the main insecticides recommended by the World Health Organization for public health. It can be used for extermination and repelling of public health pests such as mosquitoes, flies, cockroaches, bedbugs, fleas, lice, midges, moths, spiders, cigarette beetles, grain weevils, aphids, mosquitoes, wasps, crickets, etc. . The effect of using alone is not obvious, and it should be mixed with other hygienic insecticides with strong insecticidal power.
所述的缓释剂是一种醇溶性的高分子材料,优选聚乙烯醇、丙烯酸酯中的一种或两种的组合。The sustained-release agent is an alcohol-soluble polymer material, preferably one or a combination of polyvinyl alcohol and acrylate.
聚乙烯醇(简称PVA)外观为白色粉末,是一种用途相当广泛的水溶性高分子聚合物,性能介于塑料和橡胶之间,它的用途可分为纤维和非纤维两大用途。Polyvinyl alcohol (PVA for short) is a white powder in appearance. It is a water-soluble polymer with a wide range of uses. Its performance is between plastics and rubber. Its use can be divided into two major uses: fiber and non-fiber.
丙烯酸酯的聚合物,结构为R为甲基等有机基团,R不同就得到一系列的聚丙烯酸酯,且性质也不相同。聚丙烯酸甲酯在室温下无粘性、强韧、略有弹性、硬度中等。聚丙烯酸乙酯较甲酯更柔软,且耐伸长率约为聚丙烯酸甲酯的2.5倍。聚丙烯酸酯易溶于丙酮、乙酸乙酯、二氯乙烷等溶剂,不易溶于水。由于高分子链的柔顺性,其玻璃化温度较低,并随R的含碳量而异。此类高分子能形成光泽好的耐水薄膜,粘合牢固,不易剥落,在室温下柔韧而有弹性。The polymer of acrylate has the structure that R is an organic group such as a methyl group, and a series of polyacrylates can be obtained with different R, and the properties are also different. Polymethylacrylate is non-tacky, strong, slightly elastic, and medium hardness at room temperature. Polyethyl acrylate is softer than methyl ester, and its elongation resistance is about 2.5 times that of polymethyl acrylate. Polyacrylate is easily soluble in solvents such as acetone, ethyl acetate, and dichloroethane, but not easily soluble in water. Due to the flexibility of the polymer chain, its glass transition temperature is low and varies with the carbon content of R. This type of polymer can form a water-resistant film with good gloss, strong adhesion, not easy to peel off, flexible and elastic at room temperature.
(二)薄膜或无纺布的驱蚊虫整理(2) Mosquito repellent finishing of film or non-woven fabric
按配比将缓释剂溶于乙醇中,加入驱蚊剂、杀虫剂搅拌混合,再加入香精油,加入适量去离子水调节粘度。薄膜或无纺布材料经驱蚊整理剂辊涂、烘干等工艺制得具有驱蚊虫功能的不透液底层。Dissolve the sustained-release agent in ethanol according to the proportion, add mosquito repellent and insecticide, stir and mix, then add essential oil, and add appropriate amount of deionized water to adjust the viscosity. A liquid-impermeable bottom layer with the function of repelling mosquitoes is prepared by rolling coating and drying the mosquito repellent finishing agent on the film or non-woven material.
(三)具有防蚊虫剂功能的一次性吸收物品的制备(3) Preparation of disposable absorbent articles with anti-mosquito function
一次性吸收用品,包括透液性顶层、不透液性底层以及设于顶层和底层之间的吸收芯组成。所述的透液性顶层为热轧、热风、亲水性纺粘、打孔热风、打孔亲水性纺粘无纺布,该层材料要求能迅速吸收尿液,克重为20~35g/m2,其渗入时间1.5~3.5s。所述的吸收芯为吸收性聚合物与绒毛浆的混合芯体,吸收性聚合物占芯体的比例为15~65%。其中绒毛浆克重为600~800g/m2,含水率为2~10%,硬度为1000~1300Kpa;粉碎能量为100~120Kj/Kg。所述吸收性聚合物其尿液吸收倍率为45~65g/g;尿液保液量为25~40g/g;尿液吸收速度25~70s;尿液0.3psi加压下吸收倍率为5~40g/g。吸收芯3的包裹层2为卫生纸或无纺布,其中卫生纸为原生木浆经湿法造纸工艺制备的,原生木浆结构上大量的纤维素羟基的存在,卫生纸有非常好的亲水性及疏导液体的能力;其克重为15~35g/m2,湿强度为0.6~2.5N/15mm;包裹层用无纺布为热风、热轧或亲水纺粘无纺布,其克重为10~25g/m2,渗入时间为1.5~3.5s。所述的不渗性底层为上述经驱蚊虫整理的薄膜和无纺布的复合底膜,驱蚊虫整理剂涂布在底膜外侧和底膜无纺布内侧。所述的薄膜为不透气的流延膜或透气性的流延膜,不透气的流延膜为12~30gsm,拉断力为横向1.5~5.0N/25mm、纵向6.0~10.0N/25mm;透气性的流延膜为12~35gsm,透气量为1800~3500g/24h/m2(正杯法),拉断力为横向1.5~4.0N/25mm、纵向5.0~10.0N/25mm,延伸率为横向200~400%、纵向100~250%,撕裂强度为横向10~20N/mm。所述的纺粘无纺布为PP长纤热轧布,克重为10~20gsm,拉断力为纵向15~30N/25mm、横向5~15N/25mm。所述的各层之间靠热熔胶粘接,各层之间的热熔胶喷胶量为1.0~3.0g/m2。Disposable absorbent articles consist of a liquid-permeable topsheet, a liquid-impermeable backsheet, and an absorbent core disposed between the topsheet and the backsheet. The liquid-permeable top layer is hot-rolled, hot air, hydrophilic spunbond, perforated hot air, perforated hydrophilic spunbond non-woven fabric, and the material of this layer is required to be able to quickly absorb urine, with a gram weight of 20-35g /m2, the penetration time is 1.5-3.5s. The absorbent core is a mixed core of absorbent polymer and fluff pulp, and the ratio of absorbent polymer to the core is 15-65%. The fluff pulp has a grammage of 600-800g/m2, a moisture content of 2-10%, a hardness of 1000-1300Kpa, and a crushing energy of 100-120Kj/Kg. The absorbent polymer has a urine absorption rate of 45-65g/g; a urine retention capacity of 25-40g/g; a urine absorption rate of 25-70s; and a urine absorption rate of 5-60s under 0.3psi pressure. 40g/g. The wrapping layer 2 of the absorbent core 3 is toilet paper or non-woven fabric, wherein the toilet paper is prepared from virgin wood pulp through a wet papermaking process. There are a large number of cellulose hydroxyl groups in the structure of the virgin wood pulp, and the toilet paper has very good hydrophilicity and The ability of dredging liquid; its grammage is 15-35g/m2, and its wet strength is 0.6-2.5N/15mm; ~25g/m2, penetration time is 1.5~3.5s. The impermeable bottom layer is a composite bottom film of the above-mentioned mosquito-repellent-finished film and non-woven fabric, and the mosquito-repellent finishing agent is coated on the outside of the bottom film and the inside of the non-woven fabric on the bottom film. The film is an air-tight cast film or an air-permeable cast film, the air-tight cast film is 12-30gsm, and the tensile force is 1.5-5.0N/25mm in the transverse direction and 6.0-10.0N/25mm in the longitudinal direction; The air-permeable casting film is 12-35gsm, the air permeability is 1800-3500g/24h/m2 (positive cup method), the breaking force is 1.5-4.0N/25mm in the transverse direction, 5.0-10.0N/25mm in the longitudinal direction, and the elongation is The transverse direction is 200-400%, the longitudinal direction is 100-250%, and the tear strength is 10-20 N/mm in the transverse direction. The spun-bonded non-woven fabric is PP long-fiber hot-rolled fabric, the grammage is 10-20gsm, and the breaking force is 15-30N/25mm in the longitudinal direction and 5-15N/25mm in the transverse direction. The layers are bonded by hot-melt adhesive, and the amount of hot-melt adhesive sprayed between the layers is 1.0-3.0 g/m2.
附图说明:Description of drawings:
附图1为本发明示意图Accompanying drawing 1 is schematic diagram of the present invention
附图2为使用本发明测试效果图Accompanying drawing 2 is to use the test effect figure of the present invention
具体实施方式:Detailed ways:
实施方式1:Implementation mode 1:
防蚊虫剂配方:Mosquito Repellent Formula:
组分 Wt.%Component Wt.%
薄荷油 5%
香叶天竺葵油 3%Geranium oil 3%
N,N-二乙基间甲苯甲酰胺(DEET) 2.5%N, N-diethyl-m-toluamide (DEET) 2.5%
苯酸苄酯 8%Benzyl benzoate 8%
胺菊酯 3%Tetramethrin 3%
聚乙烯醇(PVA) 10%Polyvinyl alcohol (PVA) 10%
乙醇 50%Ethanol 50%
去离子水 18.5%Deionized water 18.5%
具有防蚊虫功能无纺布的制备:Preparation of non-woven fabric with anti-mosquito function:
按配比将聚乙烯醇溶于乙醇中,加入驱避剂、杀虫剂搅拌混合,再加入香精油,加入适量去离子水调节粘度。薄膜或无纺布材料经经驱蚊整理剂辊涂、烘干等工艺制得具有驱蚊虫功能的不透液底层。上油率为0.5%,烘干温度为150℃,线速度为80m/min。Dissolve polyvinyl alcohol in ethanol according to the proportion, add repellent and insecticide, stir and mix, then add essential oil, add appropriate amount of deionized water to adjust viscosity. A liquid-impermeable bottom layer with the function of repelling mosquitoes is obtained by rolling coating and drying the mosquito repellent finishing agent on the film or non-woven material. The oiling rate is 0.5%, the drying temperature is 150°C, and the line speed is 80m/min.
具有驱蚊虫功能尿布的制备:Preparation of diaper with mosquito repellent function:
见附图1,本发明一次性吸收用品包括透液性顶层1、不透液性底层4以及设于顶层1和底层4之间的吸收芯3组成。所述的渗透性顶层1为20g/m2热风无纺布,该层材料要求能迅速吸收尿液,渗入时间1.5~3.5s。所述的吸收芯3为吸收性聚合物与绒毛浆的混合芯体,吸收性聚合物占芯体的比例为40%。其中绒毛浆克重700g/m2,含水率为8%。所述吸收性聚合物其尿液吸收倍率为60g/g;尿液保液量为35g/g;尿液吸收速度30s;尿液0.3psi加压下吸收倍率为10g/g。吸收芯3的包裹层2为18g/m2卫生纸。所述的不渗性底层4为上述具有防蚊虫功能的无纺布制备无纺布合成的复合底膜5,温致变色剂涂布在无纺布内侧。所述的薄膜为20gsm透气膜,透气量为1800~2600g/24h/m2(正杯法)。所述的纺粘无纺布为PP长纤热轧布,克重为15gsm。所述的各层之间靠热熔胶粘接,各层之间的热熔胶喷胶量为2.5g/m2。Referring to accompanying drawing 1, the disposable absorbent article of the present invention comprises a liquid-permeable top layer 1, a liquid-impermeable bottom layer 4 and an absorbent core 3 disposed between the top layer 1 and the bottom layer 4. The permeable top layer 1 is a 20g/m 2 air-through non-woven fabric, and the material of this layer is required to absorb urine quickly, and the penetration time is 1.5-3.5s. The absorbent core 3 is a mixed core of absorbent polymer and fluff pulp, and the ratio of absorbent polymer to the core is 40%. The fluff pulp has a grammage of 700g/m 2 and a moisture content of 8%. The absorbent polymer has a urine absorption rate of 60g/g; a urine retention capacity of 35g/g; a urine absorption rate of 30s; and a urine absorption rate of 10g/g under 0.3psi pressure. The wrapping layer 2 of the absorbent core 3 is 18 g/m 2 toilet paper. The impermeable bottom layer 4 is a
表1:实施方式1驱避蚊虫效果Table 1: Mosquito repellent effect of Embodiment 1
实施方式2:Implementation mode 2:
防蚊虫整理剂配方:Formula of anti-mosquito finishing agent:
组分 Wt.%Component Wt.%
薄荷油 7%Peppermint Oil 7%
香茅草油 2.5%Lemongrass Oil 2.5%
N,N-二乙基间甲苯甲酰胺(DEET) 8%N, N-diethyl-m-toluamide (DEET) 8%
胺菊酯 4.5%Tetramethrin 4.5%
聚乙烯醇(PVA) 10%Polyvinyl alcohol (PVA) 10%
乙醇 50%Ethanol 50%
去离子水 18%Deionized water 18%
具有驱蚊虫功能无纺布的制备:Preparation of non-woven fabric with mosquito repellent function:
按配比将聚乙烯醇溶于乙醇中,加入驱避剂、杀虫剂搅拌混合,再加入香精油,加入适量去离子水调节粘度。薄膜或无纺布材料经经驱蚊整理剂辊涂、烘干等工艺制得具有驱蚊虫功能的不透液底层。上油率为0.5%,烘干温度为150℃,线速度为80m/min。Dissolve polyvinyl alcohol in ethanol according to the proportion, add repellent and insecticide, stir and mix, then add essential oil, add appropriate amount of deionized water to adjust viscosity. A liquid-impermeable bottom layer with the function of repelling mosquitoes is obtained by rolling coating and drying the mosquito repellent finishing agent on the film or non-woven material. The oiling rate is 0.5%, the drying temperature is 150°C, and the line speed is 80m/min.
具有驱蚊虫功能尿布的制备与前述相同。The preparation of the diaper with mosquito repelling function is the same as above.
表2:实施方式2驱避蚊虫效果Table 2: Mosquito repellent effect of Embodiment 2
从以上各实施例可以看出,本发明所述的具有防蚊功能的一次性吸收物品,对蚊虫具有很好的驱避作用,可保证穿着者2m范围内驱蚊组分的挥发浓度达到驱避蚊虫的作用,该驱蚊虫剂对人体无副作用,保证穿着者整晚不受蚊虫干扰。It can be seen from the above examples that the disposable absorbent article with anti-mosquito function according to the present invention has a good repelling effect on mosquitoes, and can ensure that the volatile concentration of the mosquito repellent components within 2m of the wearer reaches the level of repellent. The effect of repelling mosquitoes, the mosquito repellent has no side effects on the human body, ensuring that the wearer will not be disturbed by mosquitoes all night.
(四)蚊虫驱避率与杀虫率测试(4) Mosquito repellent rate and insecticidal rate test
蚊虫驱避率的测试采用空气流动法,如附图2所示。将50只蚊子放入用板隔开、下面联通的玻璃箱22和23,裁剪一小块经驱避剂整理的尿布试样放入玻璃瓶25中,然后启动流水泵12,于是空气经填充活性炭的容器13,一部分经由玻璃瓶25流入玻璃箱22,其余部分则由玻璃瓶26进入玻璃箱23,这两部分空气均由玻璃管11排出箱外。空气流量可控制在3.5L/min,此时玻璃瓶25中的试样因蒸发而被空气铗入玻璃箱22。如果有驱避活性,玻璃箱22中的蚊子应向玻璃箱23逃去,分别记下通气前后玻璃箱22和23中的蚊子的个数,即可比较试样的驱避活性。The test of mosquito repellent rate adopts air flow method, as shown in Figure 2. Put 50 mosquitoes into the
杀虫率的测试采用三角瓶接触法,每次实验重复3次。将经驱蚊整理的一次性吸收物品置于三角瓶中,放入15-20只蚊子,开始计时,并数被击倒的蚊子数,接触30min后,将蚊子移置干燥器中恢复30min,统计蚊子死亡和回复活动能力的百分比。The insecticidal rate was tested using the Erlenmeyer flask contact method, and each experiment was repeated 3 times. Put the disposable absorbent articles that have been repelled into a triangular flask, put 15-20 mosquitoes, start timing, and count the number of knocked down mosquitoes. After 30 minutes of contact, place the mosquitoes in a desiccator to recover for 30 minutes. The percentage of mosquitoes that died and regained mobility was counted.
(五)蚊虫驱避率的活体模拟测试(5) In vivo simulation test of mosquito repellent rate
模拟测试,将经驱蚊剂整理的吸收物品,穿着在人身上,其他部位裸露,测试12小时内人体周围的蚊虫数及被蚊子叮咬的次数。In the simulation test, the absorbent article treated with mosquito repellent is worn on the human body, and other parts are exposed, and the number of mosquitoes around the human body and the number of mosquito bites are tested within 12 hours.
当然,以上所述技术方案只是本发明的较佳实例而已,并非来限制本发明实施范围,故凡依本发明申请专利范围所述的构造、特征及原理所做的等效变化或修饰,均包括于本发明申请专利范围内。Of course, the technical solutions described above are only preferred examples of the present invention, and are not intended to limit the implementation scope of the present invention, so all equivalent changes or modifications made according to the structure, features and principles described in the patent scope of the present invention are all Included in the patent scope of the present invention.
图号说明:Description of figure number:
1-透气性顶层 2-包裹层 3-吸收芯 4-不透液性底层 5-驱蚊虫整理剂 21-隔板 22、23-分成两室的玻璃箱 24-试样 25、26-玻璃瓶7-10 玻璃管 11-带支管的玻璃管 12-流水泵 13-充填活性炭的容器 14-流量计 15-流量调节阀1-breathable top layer 2-wrapping layer 3-absorbent core 4-liquid impermeable bottom layer 5-mosquito repellent finishing agent 21-
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