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CN101787598B - A kind of phase change thermoregulation blended yarn and its production process - Google Patents

A kind of phase change thermoregulation blended yarn and its production process Download PDF

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CN101787598B
CN101787598B CN 201010128288 CN201010128288A CN101787598B CN 101787598 B CN101787598 B CN 101787598B CN 201010128288 CN201010128288 CN 201010128288 CN 201010128288 A CN201010128288 A CN 201010128288A CN 101787598 B CN101787598 B CN 101787598B
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fiber
fibers
speed
wool
temperature
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CN101787598A (en
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陈慰来
张声诚
高营
于斌
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Zhejiang Sunjazz Clothing Co ltd
Zhejiang Sunjazz Fashion Co ltd
Zhejiang University of Technology ZJUT
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Zhejiang Sunjazz Fashion Co ltd
Zhejiang University of Technology ZJUT
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Abstract

本发明公开了一种相变调温混纺纱及其生产工艺,该混纺纱其组分中包括outlast纤维和棉纤维,所述的outlast纤维重量比例为10%~50%,棉纤维重量比例为50%。该混纺纱的生产工艺依次包括以下步骤:散毛染色,和毛,开松,清花成卷,梳棉,一道并条,二道并条,三道并条,粗纱,细纱和络筒。本发明通过与其它纤维混合纺纱,可以改善单纯相变调温纤维成纱难度大的问题、提高织物的服用性能,同时又可以降低成本,提高产品的附加值。

Figure 201010128288

The invention discloses a phase-change temperature-regulating blended yarn and a production process thereof. The blended yarn includes outlast fibers and cotton fibers in its components, and the weight ratio of the outlast fibers is 10% to 50%, and the weight ratio of the cotton fibers is The ratio is 50%. The production process of the blended yarn includes the following steps in sequence: dyeing of loose wool, kneading, opening, blowing into rolls, carding, one-stage drawing, two-stage drawing, three-stage drawing, roving, spun yarn and winding . The invention can improve the problem of high difficulty in yarn formation of pure phase-change temperature-regulating fibers by mixing and spinning with other fibers, improve the wearing performance of fabrics, and at the same time reduce costs and increase the added value of products.

Figure 201010128288

Description

一种相变调温混纺纱及其生产工艺A kind of phase change thermoregulation blended yarn and its production process

技术领域 technical field

本发明涉及一种混纺纱线及其生产方法,具体是一种具有调温功能的相变调温混纺纱及其生产工艺,属纺织生产技术领域。The invention relates to a blended yarn and a production method thereof, in particular to a phase-change temperature-regulating blended yarn with a temperature-regulating function and a production process thereof, belonging to the technical field of textile production.

背景技术 Background technique

相变材料PCM(phase change materials)是一种利用物质相态转变进行储能和放能的化学材料。20世纪30年代以来,特别是受80年代能源危机的影响,相变储热(LTES)的基础理论和应用技术研究在欧美发达国家(如美国、英国、加拿大、日本、德国等)迅速崛起并得到不断发展。材料科学、太阳能、航天技术和工程热物理等领域的相互渗透与科技的迅猛发展为相变储热研究和应用创造了条件,而相变材料在纺织服装领域的应用,特别是在具有调温功能纺织品方面的应用也越来越广泛,对这方面的研究也越来越深入。目前,相变调温织物大量应用于户外服装、内衣裤、毛衣、衬衣、帽子、手套和床上用品等。Phase change material PCM (phase change materials) is a chemical material that uses the phase transition of matter to store and release energy. Since the 1930s, especially affected by the energy crisis in the 1980s, the basic theory and applied technology research of phase change heat storage (LTES) has risen rapidly in developed countries in Europe and the United States (such as the United States, Britain, Canada, Japan, Germany, etc.) be continuously developed. The mutual penetration and rapid development of science and technology in the fields of material science, solar energy, aerospace technology and engineering thermophysics have created conditions for the research and application of phase change heat storage, and the application of phase change materials in the field of textiles and clothing, especially in the field of temperature regulation The application of functional textiles is also becoming more and more extensive, and the research in this area is also getting more and more in-depth. At present, phase-change temperature-regulating fabrics are widely used in outdoor clothing, underwear, sweaters, shirts, hats, gloves and bedding.

20世纪70年代初,Hansen.R.H将CO2之类的气体先溶解到各种溶剂中,利用特殊方法将中空部分密封,使纤维中空部分的CO2等气体发生气-液(固)相转变,以此达到保温的目的。但仅适用于气温较低的情形,而且在织物加工的过程中气体很容易从纤维中逸出,使织物失去调温功能。In the early 1970s, Hansen.R.H dissolved gases such as CO2 into various solvents, and sealed the hollow part with a special method, so that the gas such as CO2 in the hollow part of the fiber undergoes a gas-liquid (solid) phase transition to This achieves the purpose of heat preservation. However, it is only suitable for low temperature conditions, and the gas is easy to escape from the fibers during the fabric processing, so that the fabric loses its temperature regulating function.

20世纪80年代初期,美国农业部南方实验室的Vigo等人将带有结晶水的无机盐类(硫酸钠、氯化钙、氯化锶等)填充到中空纤维的中空部分,利用相变水合盐在室温下发生的熔融和结晶来达到吸热和放热的目的,从而调节温度。但是中空纤维内部的无机盐在开始时具有吸放热功能,但反复升降温后,无机盐便失去结晶水从纤维中析出。后来,Vigo等人还将常温可结晶的聚乙二醇封人中空纤维内部,这种纤维经过150次加热和冷却循环后,仍具有吸放热功能。但由于中空纤维的直径较粗,很难避免纤维表面沾有聚乙二醇,所以产业化的推广价值也很小。In the early 1980s, Vigo and others from the Southern Laboratory of the United States Department of Agriculture filled the hollow part of the hollow fiber with inorganic salts (sodium sulfate, calcium chloride, strontium chloride, etc.) The melting and crystallization of salt at room temperature achieves the purpose of endothermic and exothermic, thereby regulating the temperature. However, the inorganic salt inside the hollow fiber has heat-absorbing and exothermic functions at the beginning, but after repeated heating and cooling, the inorganic salt loses crystal water and precipitates from the fiber. Later, Vigo et al. also sealed polyethylene glycol which can be crystallized at room temperature inside the hollow fiber. After 150 heating and cooling cycles, this fiber still has the function of absorbing and releasing heat. However, due to the relatively thick diameter of the hollow fiber, it is difficult to avoid polyethylene glycol on the surface of the fiber, so the promotion value of industrialization is also very small.

20世纪80年代中期,TRDC(triangle research & development company)公司将相变材料密封于微胶囊中,研制出具有吸放热功能的微胶囊。同一时期Vigo等人又将分子量为500-8000的聚乙二醇和DMDHEU等交联剂及催化剂一起混合后制成均匀水溶液,再将棉、涤棉和羊毛织物等在溶液中浸渍、轧榨、烘干、皂洗,得到增重50%左右的织物,测试发现该类织物在0-50℃范围内具有明显的吸放热效果。In the mid-1980s, TRDC (triangle research & development company) sealed phase-change materials in microcapsules and developed microcapsules with heat-absorbing and exothermic functions. During the same period, Vigo and others mixed polyethylene glycol with a molecular weight of 500-8000 and DMDHEU and other cross-linking agents and catalysts together to make a uniform aqueous solution, and then soaked cotton, polyester cotton and wool fabrics in the solution. After drying and soaping, a fabric with a weight gain of about 50% is obtained. Tests have found that this type of fabric has obvious heat absorption and release effects in the range of 0-50°C.

90年代初,日本酯公司采用纺丝法直接将低温相变物质如石蜡纺制在纤维内部,并在纤维表面进行环氧树脂处理,该纤维在升降温过程中,石蜡熔融吸热、结晶放热,使该纤维具有吸热、放热的效果。In the early 1990s, Nippon Ester Company directly spun low-temperature phase-change substances such as paraffin inside the fiber by spinning, and treated the fiber surface with epoxy resin. Heat, so that the fiber has the effect of heat absorption and heat release.

1993年美国TRDC公司通过将石蜡类碳氢化合物封人直径为1.0~10.0μm的微胶囊中,然后与聚合物溶液一起纺丝制得具有可逆蓄热特点的纤维,也有公司将相变微胶囊通过涂层的方式添加到织物表面,以此提高织物的保温性。In 1993, the TRDC company of the United States encapsulated paraffin hydrocarbons in microcapsules with a diameter of 1.0-10.0 μm, and then spun them together with polymer solutions to obtain fibers with reversible heat storage characteristics. Some companies also made phase-change microcapsules It is added to the surface of the fabric by coating to improve the thermal insulation of the fabric.

在海湾战争期间,美国TRDC公司研制具有长效降温功能的夹克(PECS)。研究人员通过将直径3~100μm的微小相变材料密封在各种口袋内固定在夹克上,得到了吸、放热量效果明显的调温服装。轻质的PECS服装可以使服装内温度保持在26℃达2-3h,加强型的PECS服装可以使服装内温度保持在26℃达3h。During the Gulf War, TRDC Corporation of the United States developed a jacket (PECS) with long-lasting cooling function. By sealing tiny phase-change materials with a diameter of 3-100 μm in various pockets and fixing them on jackets, the researchers obtained temperature-regulating clothing with obvious heat absorption and heat release effects. Lightweight PECS clothing can keep the temperature inside the clothing at 26°C for 2-3 hours, and reinforced PECS clothing can keep the temperature inside the clothing at 26°C for 3 hours.

1998年,美国TRDC公司将经过改性的微胶囊进行熔融法纺丝试验,制成了含有3%(重量)相变材料微胶囊的丙纶纤维,并对纤维进行了测试,结果表明该纤维具有温度调节能力。In 1998, the TRDC company of the United States carried out the melt spinning test of the modified microcapsules, and made polypropylene fibers containing 3% (weight) phase change material microcapsules, and tested the fibers, and the results showed that the fibers had Temperature regulation capability.

我国自20世纪90年代初开始蓄热调温纺织品的研究工作,天津工业大学功能纤维研究所自1993年开始从事蓄热调温纤维的研究开发工作,对以聚对苯二甲酸乙二酯一聚乙二醇嵌段共聚物、脂肪族聚酯、聚乙二醇和聚丁二醇为原料进行熔融复合纺丝制得具有温度调节功能的纤维进行了系列研究。天津工业大学材料化工学院马晓光副教授将相变材料聚乙二醇(PEG)以交联方式添加到织物上,对整理后的织物的蓄热调温性能进行了研究。Since the early 1990s in my country, the research work on thermal storage and temperature-regulating textiles has begun. The Functional Fiber Research Institute of Tianjin University of Technology has been engaged in the research and development of thermal storage and temperature-regulating fibers since 1993. For polyethylene terephthalate- Polyethylene glycol block copolymer, aliphatic polyester, polyethylene glycol and polytetramethylene glycol were used as raw materials for melt composite spinning to prepare fibers with temperature regulation function. Associate Professor Ma Xiaoguang from the School of Materials and Chemical Engineering of Tianjin University of Technology added the phase change material polyethylene glycol (PEG) to the fabric in a cross-linked manner, and studied the heat storage and temperature regulation performance of the finished fabric.

1997年,天津工业大学对熔融复合纺丝技术进行了深入研究,研制出了相变物质含量在16%以上,单丝线密度为5dtex的蓄热调温纤维。2000年,天津工业大学将一定量的调温微胶囊与粘合剂、消泡剂均匀混合,在纯棉及涤/棉织物上进行涂层整理,经测定其相变热可达40J/g,热阻值也从原来的0.207CLO提高到0.245CLO,但经整理后透气性下降,物理机械性能也受影响。天津工业大学张兴祥研制的熔纺纤维中相变材料微胶囊含量达到了20Wt%,经测试在38℃的气温下能保持服装内部温度低于30℃达25h,目前已试用于我军用飞行服和通风服等。In 1997, Tianjin Polytechnic University conducted in-depth research on melt composite spinning technology, and developed a thermal storage and temperature regulating fiber with a phase change substance content of more than 16% and a linear density of 5 dtex. In 2000, Tianjin Polytechnic University evenly mixed a certain amount of temperature-regulating microcapsules with adhesives and defoamers, and coated them on pure cotton and polyester/cotton fabrics. It was determined that the phase change heat can reach 40J/g , The thermal resistance value is also increased from the original 0.207CLO to 0.245CLO, but after finishing, the air permeability decreases, and the physical and mechanical properties are also affected. The content of phase change material microcapsules in the melt-spun fiber developed by Zhang Xingxiang of Tianjin University of Technology has reached 20Wt%, and it has been tested to keep the internal temperature of the clothing below 30°C for 25 hours at a temperature of 38°C. It has been tried in our military flight suits and Ventilation suits, etc.

2003年,清华大学张寅平等人研制的医用降温服,通过衣服上缝制多个用于装降温袋的口袋,且每个口袋都有封口。使用时将降温袋装入降温服的口袋里,利用相变潜热进行降温。In 2003, Zhang Yinping and others of Tsinghua University developed a medical cooling suit, which sewed multiple pockets for cooling bags on the clothes, and each pocket was sealed. When in use, put the cooling bag into the pocket of the cooling suit, and use the latent heat of phase change to cool down.

相变调温纤维既能纯纺,也能与棉、羊绒、桑蚕丝、维纶、涤纶等各类纤维混纺;既可以机织,也可以针织。目前,相变调温纤维采用大多采用两种纤维混纺为主,对三组分纤维混纺的研究较少。相变调温织物大多采用涂层和植入纤维体中的形式,然而涂层织物不耐水洗,易掉落,织物厚重闷热,手感粗硬,透气性差,不利于人体长时间穿着;又相变调温纤维是以腈纶为基体的Outlast纤维,其横截面较粗,比电阻较大,抱合力差,纺纱过程会出现静电现象,这些特性严重影响了纺纱加工的顺利进行。Phase-change temperature-regulating fibers can be purely spun or blended with various fibers such as cotton, cashmere, mulberry silk, vinylon, and polyester; they can be machine-woven or knitted. At present, most of the phase-change temperature-regulating fibers are blended with two kinds of fibers, and there are few studies on blended with three-component fibers. Most of the phase-change temperature-regulating fabrics are coated and implanted into the fiber body. However, the coated fabric is not washable and easy to fall off. The variable temperature fiber is Outlast fiber with acrylic fiber as the matrix. Its cross-section is thicker, its specific resistance is larger, its cohesion is poor, and static electricity will appear in the spinning process. These characteristics seriously affect the smooth progress of the spinning process.

发明内容 Contents of the invention

本发明所要解决的技术问题是克服现有技术中的不足而提供一种通过与其它纤维混合纺纱,可以改善单纯相变调温纤维成纱难度大的问题、提高织物的服用性能,同时又可以降低成本,提高产品附加值的相变调温混纺纱及其生产工艺。The technical problem to be solved by the present invention is to overcome the deficiencies in the prior art and provide a kind of blended spinning with other fibers, which can improve the difficult problem of simple phase change temperature-adjusting fiber yarn forming, improve the wearing performance of the fabric, and at the same time A phase-change temperature-adjusted blended yarn and a production process thereof that can reduce costs and increase product added value.

本发明解决上述技术问题采用的技术方案是:该相变调温混纺纱,其特征在于:其组分中包括outlast纤维和棉纤维,所述的outlast纤维重量比例为10%~50%,棉纤维重量比例为50%。The technical solution adopted by the present invention to solve the above-mentioned technical problems is: the phase-change temperature-adjusted blended yarn is characterized in that: its components include outlast fibers and cotton fibers, and the weight ratio of the outlast fibers is 10% to 50%. The cotton fiber weight ratio is 50%.

本发明所述的组分中还包括丝光羊毛或者吸湿排汗涤纶纤维,丝光羊毛重量比例10%~40%,吸湿排汗涤纶纤维重量比例为10%~40%。本发明采用纤维混纺的方式,采用的outlast纤维即相变调温纤维是以腈纶为基体的棉型纤维,基于内衣及毛织类产品的服用特性,选择棉、羊毛等天然纤维混纺,能充分提升调温纤维的特性,能有效控制调温纤维的转移规律。从可纺性来讲,选用三组分比二组分的实用性更大,也可以为其他类型的三组分纺纱作技术参考,采用吸湿排汗纤维主要考虑内衣产品吸湿及服用性能,最终的测试表明该组分纱线的调温及吸湿效果比较理想。The components of the present invention also include mercerized wool or moisture-absorbing and sweat-absorbing polyester fiber, the weight ratio of the mercerized wool is 10%-40%, and the weight ratio of moisture-absorbing and sweat-wicking polyester fiber is 10%-40%. The present invention adopts the mode of fiber blending, and the outlast fiber adopted, that is, the phase-change temperature-regulating fiber is a cotton-type fiber with acrylic fiber as the matrix. Based on the wearing characteristics of underwear and woolen products, natural fibers such as cotton and wool are selected for blending, which can fully Improving the characteristics of the temperature-regulating fiber can effectively control the transfer law of the temperature-regulating fiber. In terms of spinnability, it is more practical to choose three-component than two-component, and it can also be used as a technical reference for other types of three-component spinning. The use of moisture-absorbing and sweat-wicking fibers mainly considers the moisture absorption and wearability of underwear products. The final test shows that the temperature regulation and moisture absorption effect of the component yarn is ideal.

本发明解决上述技术问题的技术方案还是:一种相变调温混纺纱的生产工艺,依次包括以下步骤:散毛染色,和毛,开松,清花成卷,梳棉,一道并条,二道并条,三道并条,粗纱,细纱和络筒,其特点在于:所述的和毛过程中首先按所纺比例将各种纤维进行混合,在和毛机上进行人工喂人;其次用和毛机将纤维开松,根据纤维的回潮率添加水分;组分中若含有丝光羊毛则在定量的水中一边慢慢倒入和毛油,一边搅拌,进行乳化,和毛油用量为丝光羊毛重量的5-8‰,待乳化调匀后,再慢慢倒入抗静电剂边倒入边搅拌,使其达到均匀为止,抗静电剂用量为丝光羊毛的5-10‰;The technical solution of the present invention to solve the above-mentioned technical problems is still: a production process of phase-change temperature-adjusted blended yarn, which includes the following steps in turn: dyeing of loose wool, blending of wool, opening, cleaning into rolls, carding, and drawing together , two-way drawing, three-way drawing, roving, spun yarn and winding, which are characterized in that: in the kneading process, various fibers are first mixed according to the spinning ratio, and artificially fed on the knitting machine; Secondly, use the wool machine to loosen the fibers, and add water according to the moisture regain of the fibers; if the component contains mercerized wool, slowly pour the wool oil into a certain amount of water while stirring, and emulsify. The amount of wool oil is 5-8‰ of the weight of mercerized wool. After emulsification and mixing, slowly pour in the antistatic agent and stir while pouring in to make it uniform. The amount of antistatic agent is 5-10‰ of that of mercerized wool;

所述的开松以及清花成卷过程中,用尼龙布包裹棉卷,棉卷定量300g/m,棉卷定长30m,各部打手速度350-450r/min;In the process of opening and clearing the laps, wrap the laps with nylon cloth, the quantity of the laps is 300g/m, the length of the laps is 30m, and the beater speed of each part is 350-450r/min;

所述的梳棉过程中,采用化纤专用针布,生条定量16g/5m,道夫转速11r/min,锡林转速380r/min,刺辊转速1800r/min,锡林与盖板隔距为12mm、10mm、8mm、6mm和8mm;刺辊与锡林隔距12mm,锡林与道夫隔距5mm;In the carding process described above, special card clothing for chemical fibers is used, the raw sliver weight is 16g/5m, the doffer speed is 11r/min, the cylinder speed is 380r/min, the licker-in speed is 1800r/min, and the distance between the cylinder and the cover plate is 12mm , 10mm, 8mm, 6mm and 8mm; the distance between the licker-in roller and the cylinder is 12mm, and the distance between the cylinder and the doffer is 5mm;

所述的多道并条过程中,在保证正常牵伸的前提下,前、中、后罗拉上胶辊加压范围为200-300N,胶辊进行防静电处理,头道并条其后区牵伸倍数为1-3,第二道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-8,第三道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-9;In the above-mentioned multi-pass drawing process, under the premise of ensuring normal drafting, the pressure range of the front, middle and rear roller upper rubber rollers is 200-300N, and the rubber rollers are treated with anti-static treatment. The draft ratio is 1-3, the draft ratio of the second drawing frame is 2-4, the draft ratio of the front region is 5-8, and the draft ratio of the third drawing frame is 2-4. The draft ratio in the front area is 5-9;

所述的粗纱过程中前罗拉速度为180r/min,捻系数50,干定量2.25g/5m,前档皮辊加压340N,罗拉隔距22mm×35mm,后区牵伸10倍,车间温度25℃,相对湿度80%;In the roving process, the speed of the front roller is 180r/min, the twist coefficient is 50, the dry weight is 2.25g/5m, the pressure of the top roller of the front gear is 340N, the roller gauge is 22mm×35mm, the draft in the rear area is 10 times, and the workshop temperature is 25mm. ℃, relative humidity 80%;

所述的细纱过程中前档加压270N,细纱锭速6500r/min,罗拉隔距22mm×23mm,后区牵伸倍数1.35,前罗拉速度165r/min,车间温度25℃,相对湿度75%。本发明采用纤维混纺的方式,主要对相变调温混纺纱加工工艺等方面进行了研究。本发明采用的Outlast纤维是以腈纶为基体的棉型纤维,其横截面较粗,比电阻较大,抱合力差,纺纱过程易出现静电现象,纤维在分梳、牵伸等加工过程中存在微胶囊被挤压破裂的问题,这些特性严重影响了纺纱加工的顺利进行,易造成梳棉成条困难,纱条蓬松、并纱、粗纱、细纱时易缠罗拉、绕胶辊等问题。由于Outlast纤维密度小、纤维蓬松、单位质量体积较大,成纱难度大,纺纱细度有很大的局限性,尤其是纺细支数的纱难度特别大,因此各纺纱工序中定量要偏轻设计,定长偏小掌握,粗纱、细纱卷绕螺距和径向密度也要偏小掌握。混纺工艺参数、纤维转移规律及混纺比大小在很大程度上影响了织物的调温效果。本发明通过选择纤维品种、细度、长度及含量来使Outlast纤维趋于分布在纱线的表层。在Outlast纤维含量40%时可以显著分布在纱的表面,减少或增加其含量则又趋于内层转移。可以根据实际需要调整Outlast纤维含量,使微胶囊处于次表层,这样既保证了调温效果,又减少了微胶囊的破裂,一般以30%-40%比较合适。尽可能使Outlast纤维趋于分布在纱线的表层,尽可能减少微胶囊的破裂。改变了以往利用涂层工艺来使织物具有调温的方法,在一定程度上改善了织物的风格,将Outlast纤维与其他纤维混纺,改善了涂层织物手感粗硬,重演性差,不透气,不耐水洗,笨重闷热等缺点。同时也充分利用了其他纤维的优良特性,弥补了Outlast纤维成纱难的缺点。In the described spinning process, the front gear is pressurized at 270N, the spinning spindle speed is 6500r/min, the roller gauge is 22mm×23mm, the draft ratio in the rear area is 1.35, the front roller speed is 165r/min, the workshop temperature is 25°C, and the relative humidity is 75%. The invention adopts the mode of fiber blending, and mainly studies the processing technology of the phase change temperature-regulating blended yarn and the like. The Outlast fiber used in the present invention is a cotton-type fiber with acrylic fibers as the matrix. Its cross-section is relatively thick, its specific resistance is large, its cohesion is poor, and static electricity is prone to occur in the spinning process. There is the problem of microcapsules being squeezed and broken. These characteristics seriously affect the smooth progress of the spinning process, which may easily cause problems such as difficulty in carding and slivering, fluffy sliver, yarn doubling, roving, and easy winding of rollers and cots during spinning. . Due to the low density of Outlast fibers, fluffy fibers, and large volume per unit mass, it is difficult to form yarns, and the spinning fineness has great limitations, especially the difficulty of spinning fine-count yarns. Therefore, quantitative The design should be lighter, the fixed length should be controlled too small, and the winding pitch and radial density of roving and spun yarn should also be controlled too small. Blending process parameters, fiber transfer rules and blending ratio greatly affect the temperature adjustment effect of fabrics. In the present invention, Outlast fibers tend to be distributed on the surface layer of yarns by selecting fiber types, fineness, length and content. When the content of Outlast fiber is 40%, it can be significantly distributed on the surface of the yarn, and it tends to transfer to the inner layer when its content is reduced or increased. The content of Outlast fiber can be adjusted according to the actual needs, so that the microcapsules are in the subsurface layer, which not only ensures the temperature adjustment effect, but also reduces the rupture of the microcapsules. Generally, 30%-40% is more suitable. As far as possible, the Outlast fibers tend to be distributed on the surface of the yarn to minimize the breakage of the microcapsules. It has changed the previous method of using the coating process to make the fabric temperature-adjustable, and has improved the style of the fabric to a certain extent. Blending Outlast fiber with other fibers has improved the coated fabric to feel rough, poor repeatability, airtight, and non-toxic. Disadvantages such as washable, bulky and stuffy. At the same time, it also makes full use of the excellent properties of other fibers to make up for the shortcomings of Outlast fibers that are difficult to form into yarns.

本发明所述的散毛染色中对棉纤维的处理过程是:先将染液升温至70℃,加入活性染料,保温30分钟后,加入元明粉、纯碱,保温30分钟,冲洗干净后出缸;对Outlast纤维的处理过程是:先将染液升温至100℃,加入阳离子染料,保温30分钟后,用40℃~45℃水洗,冲洗干净后出缸。The treatment process of cotton fiber in the loose wool dyeing of the present invention is: first heat up the dye liquor to 70°C, add reactive dyes, keep warm for 30 minutes, add sodium sulfate and soda ash, keep warm for 30 minutes, rinse and remove Cylinder; the treatment process for Outlast fiber is: first heat the dye solution to 100°C, add cationic dyes, keep warm for 30 minutes, wash with water at 40°C to 45°C, rinse and then leave the vat.

本发明所述的络筒过程中槽筒速度控制在800r/min。络筒速度过快,容易增加混纺纱毛羽,所以在考虑产量的同时,要适当降低槽筒速度,利于控制毛羽。In the winding process of the present invention, the speed of the groove drum is controlled at 800r/min. If the winding speed is too fast, it is easy to increase the hairiness of the blended yarn, so while considering the output, it is necessary to properly reduce the speed of the drum to control the hairiness.

本发明与现有技术相比具有以下优点:通过与其它纤维混合纺纱,可以改善单纯相变调温纤维成纱难度大的问题、提高织物的服用性能,同时又可以降低成本,提高产品的附加值。相变调温纤维是一种具有双向调温的功能性纤维,其织物能够为人体提供较为舒适的服装内环境。调温类纺织品的生产方法有中空纤维填充法、织物涂层法和微胶囊法。中空法相变材料容易泄漏,而且纺、织、染加工难度大,涂层法织物闷热笨重、透气性差、手感粗硬。将相变微胶囊与纺丝液一起熔融纺丝可以解决上述两种方法出现的问题,并能在一定程度上改善织物的服用性能。Compared with the prior art, the present invention has the following advantages: by mixing spinning with other fibers, it can improve the difficult problem of simple phase-change temperature-adjusting fiber yarn formation, improve the wearing performance of the fabric, and at the same time reduce the cost and improve the quality of the product. added value. Phase-change temperature-regulating fiber is a functional fiber with two-way temperature regulation, and its fabric can provide a more comfortable clothing internal environment for the human body. The production methods of temperature-regulating textiles include hollow fiber filling method, fabric coating method and microencapsulation method. Hollow phase change materials are easy to leak, and spinning, weaving, and dyeing are difficult to process, while coating fabrics are stuffy and bulky, have poor air permeability, and feel rough. Melt-spinning the phase-change microcapsules together with the spinning solution can solve the problems of the above two methods and improve the wearability of the fabric to a certain extent.

本发明采用的是美国Outlast公司生产的腈纶型相变调温纤维,该纤维属于棉型有光纤维,横截面较粗,比电阻较大,易产生静电,纤维抱合力小,这些特性影响了产品的开发与应用。通过与其它纤维混合纺纱,可以改善单纯调温纤维成纱难度大的问题。通过选用合适的纤维混纺比和纺纱工艺纺制相变调温混纺纱,通过控制调温纤维含量来控制调温效果,同时又能改善成纱及服用性能,也可以适当控制成本。What the present invention adopts is the acrylic fiber type phase-change temperature-regulating fiber produced by U.S. Outlast Company, and this fiber belongs to cotton type glossy fiber, and cross section is thicker, and specific resistance is bigger, easily produces static electricity, and fiber cohesion force is little, and these characteristics have influenced Product development and application. By blending spinning with other fibers, it can improve the difficulty of simply adjusting the temperature of fibers into yarns. By selecting the appropriate fiber blending ratio and spinning process to spin the phase change temperature-regulating blended yarn, the temperature-regulating effect can be controlled by controlling the temperature-regulating fiber content, and at the same time, the yarn forming and wearing performance can be improved, and the cost can also be properly controlled.

附图说明 Description of drawings

图1为本发明生产工艺流程示意图。Fig. 1 is a schematic diagram of the production process of the present invention.

具体实施方式 Detailed ways

棉、丝光羊毛、Outlast纤维、吸湿排汗纤维混纺,各纤维原料结构性能差异大,为达到所要求的混纺纱品质,本发明采用半精梳毛纺系统进行纺制。其基本工艺模式为:前道为粗纺的和毛设备、棉纺的梳棉机和并条机,粗纺的粗纱机,棉纺的细纱机,后道为精纺的络筒、并线、倍捻设备。半精纺混纺纱具有精梳毛纺光洁度和粗疏毛纺的蓬松感。其工艺流程如下(括号内为使用的设备型号):Cotton, mercerized wool, Outlast fiber, and moisture-absorbing and sweat-wicking fiber are blended, and the structure and performance of each fiber raw material are greatly different. In order to achieve the required blended yarn quality, the present invention uses a semi-worsted wool spinning system for spinning. Its basic process mode is: woolen and woolen equipment in the front, carding frame and draw frame for cotton spinning, roving frame for wool spinning, spinning frame for cotton spinning, and winding, doubling and two-for-one twisting equipment for worsted spinning in the rear . Semi-worsted blends have the finish of worsted wool and the bulk of carded wool. The process flow is as follows (equipment models used are in brackets):

散毛染色→和毛(BC262)→开松(FA100)→清花成卷(A035C;FA046;A176E;A045B组合)→梳棉(A186H)→一道并条(FA304)→二道并条(FA304)→三道并条(FA304)→粗纱(A454E)→细纱(EJM128K)→络筒(意大利萨维奥ORION.M型)。Dyeing of loose wool → and wool (BC262) → loosening (FA100) → cleaning and coiling (A035C; FA046; A176E; A045B combination) → carding (A186H) → one-stage drawing (FA304) → two-stage drawing (FA304 )→three-way drawing (FA304)→roving (A454E)→spinning (EJM128K)→winding (Italy Savio ORION.M type).

结合原料的特性、企业生产成本及实际穿着使用情况,我们确定Outlast纤维最高比例为50%,具体的纤维混纺比如表1所示。Combining the characteristics of the raw materials, the production cost of the enterprise and the actual wearing and usage conditions, we determined that the maximum proportion of Outlast fibers is 50%. The specific fiber blending examples are shown in Table 1.

表1混纺纱纤维含量Table 1 Fiber content of blended yarn

Figure GSA00000060271300061
Figure GSA00000060271300061

具体工艺过程如下:The specific process is as follows:

(1)散毛染色(1) Scattered hair dyeing

棉纤维:染液升温至70℃,加入活性染料,保温30分钟后,加入元明粉、纯碱,保温30分钟,冲洗干净后出缸。Cotton fiber: heat up the dye solution to 70°C, add reactive dyes, keep warm for 30 minutes, then add sodium sulfate and soda ash, keep warm for 30 minutes, rinse and leave the vat.

Outlast纤维:染液升温至100℃,加入阳离子染料,保温30分钟后,用40℃~45℃水洗,冲洗干净后出缸。Outlast fiber: heat up the dye solution to 100°C, add cationic dyes, keep warm for 30 minutes, wash with water at 40°C to 45°C, rinse thoroughly and leave the vat.

丝光羊毛和吸湿排汗纤维涤纶用原白,没有染色。Mercerized wool and moisture-wicking fiber polyester in raw white, not dyed.

(2)和毛工序(2) Wool process

对于多组分纤维混和,在混和前需对各组分纤维进行预开松。由于Outlast纤维是以腈纶为载体,纺纱过程易出现静电现象,为改善其可纺性,必须在纺纱前对Outlast纤维进行充分预松加湿、加抗静电剂等预处理,为保证纺纱工序的顺利进行,和毛时还需加入一定的油水。For multi-component fiber blending, each component fiber needs to be pre-opened before blending. Since Outlast fiber is based on acrylic fibers, static electricity is prone to occur in the spinning process. In order to improve its spinnability, the Outlast fiber must be fully pre-loosened and humidified before spinning, and antistatic agents must be added to ensure the spinning process. For the smooth progress of the process, a certain amount of oil and water needs to be added when kneading.

和毛工序为:预开松→和毛→加油水。对于不同成分纤维原料,由于纤维结构性能及混入比例不同,加入油水的量也应不同。具体操作:首先,按所纺比例进行混合,在和毛机上进行人工喂人;其次,用和毛机将纤维开松,根据纤维的回潮率添加水分;然后,对含有羊毛成分比较多的纤维,在定量的水中一边慢慢倒入和毛油,一边搅拌,进行乳化,待乳化调匀后,再慢慢倒入抗静电剂边倒入边搅拌,使其达到均匀为止。和毛油用量一般相对纤维重量的5-8‰,抗静电剂用量一般相对纤维重量的5-10‰。The woolen process is: pre-opening → woolen → oiling water. For fiber raw materials with different components, the amount of oil and water added should also be different due to the difference in fiber structure performance and mixing ratio. Specific operation: First, mix according to the spinning ratio, and manually feed people on the knitting machine; secondly, use the knitting machine to loosen the fibers, and add water according to the moisture regain of the fibers; then, for the fibers containing more wool components , slowly pour the crude oil into the quantitative water while stirring, and emulsify. After the emulsification is mixed thoroughly, slowly pour in the antistatic agent and stir while pouring to make it uniform. The amount of crude oil and crude oil is generally 5-8‰ relative to the weight of the fiber, and the amount of antistatic agent is generally 5-10‰ relative to the weight of the fiber.

(3)开清棉工序(3) Opening and cleaning process

开清棉工序采用“短流程、多梳少打、慢速度、勤抓少抓、多混合”的工艺原则。以梳代打,减少纤维损伤,防止微胶囊破裂。此外,还需用尼龙布包裹棉卷,防止抗静电油剂挥发。主要工艺参数:棉卷定量300g/m,棉卷定长30m,同时适当降低各部打手速度,一般各部打手速度为350-450r/min。The opening and cleaning process adopts the process principle of "short process, more combing and less beating, slow speed, frequent grasping and less grasping, and more mixing". Use a comb instead of beating to reduce fiber damage and prevent microcapsules from breaking. In addition, it is necessary to wrap the cotton roll with nylon cloth to prevent the antistatic oil from volatilizing. Main process parameters: lap weight 300g/m, lap length 30m, at the same time reduce the beater speed of each part appropriately, generally the beater speed of each part is 350-450r/min.

(4)梳棉工序(4) Carding process

为了减少纤维损伤,梳棉采用“偏轻定量、慢速度、小张力、中隔距、轻加压”的工艺原则。定量太轻容易飘棉网、烂边、破洞,太重容易堵圈条盘;加压过重易使微胶囊破裂,过轻易堵喇叭口。另外,须采用化纤专用针布防止分梳过程中微胶囊破裂。主要工艺参数:生条定量16g/5m;道夫转速11r/min锡林转速380r/min;刺辊转速1800r/min锡林~盖板隔距12、10、8、6、8mm;刺辊与锡林隔距12mm;锡林与道夫隔距5mm。In order to reduce fiber damage, the carding adopts the process principle of "light weight, slow speed, small tension, medium gauge, and light pressure". If the weight is too light, it will easily float cotton net, rotten edges, and holes; if it is too heavy, it will easily block the coil; if the pressure is too heavy, it will easily break the microcapsules, and if it is too heavy, it will easily block the bell mouth. In addition, special card clothing for chemical fibers must be used to prevent microcapsules from breaking during the carding process. Main process parameters: raw sliver weight 16g/5m; doffer speed 11r/min; cylinder speed 380r/min; The distance between the forest and the doffer is 12mm; the distance between the cylinder and the doffer is 5mm.

(5)并条工序(5) Drawing process

为防止牵伸过程中微胶囊破裂,在保证正常牵伸的前提下,前、中、后罗拉上胶辊加压范围为200-300N,胶辊进行防静电处理,速度偏低掌握,以防止缠绕胶辊。为消除纤维弯钩、提高纤维伸直度,使纤维排列整齐,头道并条采用较大的后区牵伸倍数;为获得较好的条干均匀度,第二、第三道并条采用“后区牵伸倍数较小、前区牵伸较大”的工艺原则。一般头道并条其后区牵伸倍数为1-3,第二道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-8,第三道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-9;主要工艺参数见表2。In order to prevent the breakage of the microcapsules during the drafting process, under the premise of ensuring normal drafting, the pressure range of the upper rubber rollers of the front, middle and rear rollers is 200-300N. Winding rubber rollers. In order to eliminate fiber hooks, improve fiber straightness, and arrange fibers neatly, a larger drafting ratio in the rear area is used in the first draw; in order to obtain better evenness, the second and third draws use The process principle of "the draft ratio in the rear area is small, and the draft in the front area is large". Generally, the draft ratio of the first drawing frame is 1-3, the draft ratio of the second drawing frame is 2-4, the draft ratio of the front area is 5-8, and the draft ratio of the third drawing frame is 5-8. The draft ratio is 2-4, and the front zone draft ratio is 5-9; the main process parameters are shown in Table 2.

表2并条工序的工艺参数Table 2 Process parameters of drawing frame process

Figure GSA00000060271300081
Figure GSA00000060271300081

(6)粗纱工序(6) Roving process

Outlast纤维蓬松,体积密度小,纤维间抱合差,粗纱生产难度较大。为保证粗纱质量,应选用较大的捻系数、较小的锭速和后区牵伸倍数,粗纱轴向密度、径向密度设定偏小掌握。另外,为了避免微胶囊破裂,粗纱皮辊加压应选用最轻档。主要工艺参数:前罗拉速度180r/min,捻系数50,干定量2.25g/5m,前档皮辊加压340N,罗拉隔距22mm×35mm,后区牵伸10倍,车间温度25℃,相对湿度80%。Outlast fibers are fluffy, with low bulk density and poor cohesion between fibers, making roving production difficult. In order to ensure the quality of the roving, a larger twist coefficient, a smaller spindle speed and a draft multiple in the rear area should be selected, and the axial density and radial density of the roving should be set too small to control. In addition, in order to avoid microcapsule breakage, the lightest gear should be selected for the pressure of the roving top roller. Main process parameters: front roller speed 180r/min, twist coefficient 50, dry basis weight 2.25g/5m, front top roller pressure 340N, roller gauge 22mm×35mm, rear zone draft 10 times, workshop temperature 25℃, relative Humidity 80%.

(7)细纱工序(7) Spinning process

由于Outlast维蓬松,不易控制,为有效控制纤维,改善条干均匀度,除合理选配牵伸区工艺参数外,还要适当增加上下皮圈厚度及改用自动张力皮圈架{4}。主要工艺参数:前档加压270N,细纱锭速6500r/min,罗拉隔距22mm×23mm,后区牵伸倍数1.35,前罗拉速度165r/min,车间温度25℃,相对湿度75%。Because the Outlast dimension is fluffy and difficult to control, in order to effectively control the fibers and improve the evenness, in addition to reasonably selecting the process parameters of the drafting zone, the thickness of the upper and lower aprons should be appropriately increased and the automatic tension apron holder should be used {4}. Main process parameters: front pressure 270N, spinning spindle speed 6500r/min, roller gauge 22mm×23mm, rear draft ratio 1.35, front roller speed 165r/min, workshop temperature 25℃, relative humidity 75%.

(8)络筒工序(8) Winding process

采用意大利萨维奥ORION.M型自动络筒机,槽筒速度控制在800r/min,络筒速度过快,容易增加混纺纱毛羽,所以在考虑产量的同时,要适当降低槽筒速度,利于控制毛羽。Italian Savio ORION.M type automatic winding machine is adopted, and the speed of the grooved drum is controlled at 800r/min. If the winding speed is too fast, it is easy to increase the hairiness of the blended yarn. Therefore, while considering the output, the speed of the grooved drum should be appropriately reduced. Helps control hairiness.

虽然本发明已以实施例公开如上,但其并非用以限定本发明的保护范围,任何熟悉该项技术的技术人员,在不脱离本发明的构思和范围内所作的更动与润饰,均应属于本发明的保护范围。Although the present invention has been disclosed as above with the embodiments, it is not intended to limit the scope of protection of the present invention. Any changes and modifications made by those skilled in the art without departing from the concept and scope of the present invention shall be Belong to the protection scope of the present invention.

Claims (3)

1.一种相变调温混纺纱的生产工艺,依次包括以下步骤:散毛染色,和毛,开松,清花成卷,梳棉,一道并条,二道并条,三道并条,粗纱,细纱和络筒,其特征在于:所述的和毛过程中首先按outlast纤维重量比例为40%,棉纤维重量比例为50%,丝光羊毛重量比例10%将各种纤维进行混合,在和毛机上进行人工喂入,其次用和毛机将纤维开松,根据纤维的回潮率添加水分,在定量的水中一边慢慢倒入和毛油,一边搅拌进行乳化,和毛油用量为丝光羊毛重量的5-8‰,待乳化调匀后,再慢慢倒入抗静电剂边倒入边搅拌,使其达到均匀为止,抗静电剂用量为丝光羊毛的5-10‰; 1. A production process of phase-change temperature-adjusted blended yarn, which comprises the following steps in turn: loose wool dyeing, kneading, opening, cleaning into rolls, carding, one-step drawing, two-pass drawing, three-pass drawing Strip, roving, spun yarn and winding are characterized in that: in the described knitting process, various fibers are first mixed according to the outlast fiber weight ratio of 40%, the cotton fiber weight ratio of 50%, and the mercerized wool weight ratio of 10%. , artificial feeding on the wool machine, followed by opening the fiber with the wool machine, adding water according to the moisture regain of the fiber, slowly pouring the wool oil into the quantitative water, stirring while emulsifying, and the amount of crude oil It is 5-8‰ of the weight of mercerized wool. After emulsification and mixing, slowly pour in the antistatic agent and stir while pouring to make it uniform. The amount of antistatic agent is 5-10‰ of that of mercerized wool; 所述的开松以及清花成卷过程中,用尼龙布包裹棉卷,棉卷定量300g/m,棉卷定长30m,各部打手速度350-450 r/min; In the process of opening and clearing the laps, the laps are wrapped with nylon cloth, the mass of the laps is 300g/m, the length of the laps is 30m, and the beater speed of each part is 350-450 r/min; 所述的梳棉过程中,采用化纤专用针布,生条定量16g/5m,道夫转速11r/min,锡林转速380r/min,刺辊转速1800r/min,锡林与盖板隔距为12 mm、10 mm、8 mm、6 mm和8mm;刺辊与锡林隔距12mm,锡林与道夫隔距5mm; In the described carding process, the special card clothing for chemical fibers is adopted, the raw sliver basis weight is 16g/5m, the doffer speed is 11r/min, the cylinder speed is 380r/min, the licker-in speed is 1800r/min, and the cylinder and cover plate gauges are 12 mm, 10 mm, 8 mm, 6 mm and 8mm; the distance between the licker-in roller and the cylinder is 12mm, and the distance between the cylinder and the doffer is 5mm; 所述的多道并条过程中,前、中、后罗拉上胶辊加压范围为200-300N,胶辊进行防静电处理,头道并条其后区牵伸倍数为1-3,第二道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-8,第三道并条的后区牵伸倍数为2-4,前区牵伸倍数为5-9; In the multi-pass drawing process, the pressure range of the rubber rollers on the front, middle and rear rollers is 200-300N, and the rubber rollers are treated with anti-static treatment. The draft ratio of the rear zone of the second drawing frame is 2-4, the draft multiple of the front zone is 5-8, the draft multiple of the rear zone of the third drawing frame is 2-4, and the draft multiple of the front zone is 5-9 ; 所述的粗纱过程中前罗拉速度为180r/min,捻系数50,干定量2.25g/5m,前档皮辊加压340N,罗拉隔距22mm×35mm,后区牵伸10倍,车间温度25℃,相对湿度80%; In the roving process, the speed of the front roller is 180r/min, the twist coefficient is 50, the dry weight is 2.25g/5m, the pressure of the top roller of the front gear is 340N, the roller gauge is 22mm×35mm, the draft in the rear area is 10 times, and the workshop temperature is 25mm. ℃, relative humidity 80%; 所述的细纱过程中前档加压270N,细纱锭速6500r/min,罗拉隔距22mm×23mm,后区牵伸倍数1.35,前罗拉速度165r/min,车间温度25℃,相对湿度75%。 In the spinning process, the front gear is pressurized at 270N, the spinning spindle speed is 6500r/min, the roller gauge is 22mm×23mm, the rear draft ratio is 1.35, the front roller speed is 165r/min, the workshop temperature is 25°C, and the relative humidity is 75%. 2.根据权利要求1所述的相变调温混纺纱的生产工艺,其特征在于:所述的散毛染色中对棉纤维的处理过程是:先将染液升温至70℃,加入活性染料,保温30分钟后,加入元明粉、纯碱,保温30分钟,冲洗干净后出缸;对Outlast纤维的处理过程是:先将染液升温至100℃,加入阳离子染料,保温30分钟后,用40℃~45℃水洗,冲洗干净后出缸。 2. The production process of phase-change temperature-adjusted blended yarn according to claim 1, characterized in that: the cotton fiber treatment process in the loose wool dyeing is: firstly, the temperature of the dye solution is raised to 70°C, and the active Dye, heat preservation for 30 minutes, add sodium sulfate and soda ash, heat preservation for 30 minutes, rinse out and leave the tank; the treatment process for Outlast fiber is: first heat the dye solution to 100°C, add cationic dyes, heat preservation for 30 minutes, Wash it with water at 40°C to 45°C, rinse it and leave the vat. 3.根据权利要求1所述的相变调温混纺纱的生产工艺,其特征在于:所述的络筒过程中槽筒速度控制在800r/min。 3. The production process of phase-change temperature-adjusted blended yarn according to claim 1, characterized in that: the speed of the drum during the winding process is controlled at 800r/min.
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