CN101781613B - Acid soaping agent - Google Patents
Acid soaping agent Download PDFInfo
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- CN101781613B CN101781613B CN2009100955242A CN200910095524A CN101781613B CN 101781613 B CN101781613 B CN 101781613B CN 2009100955242 A CN2009100955242 A CN 2009100955242A CN 200910095524 A CN200910095524 A CN 200910095524A CN 101781613 B CN101781613 B CN 101781613B
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- acid
- agent
- soaping
- monomer
- cloth
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- 239000003795 chemical substances by application Substances 0.000 title claims abstract description 29
- 239000002253 acid Substances 0.000 title claims abstract description 18
- 238000006116 polymerization reaction Methods 0.000 claims abstract description 26
- 239000000178 monomer Substances 0.000 claims abstract description 22
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims abstract description 8
- 229920000642 polymer Polymers 0.000 claims abstract description 8
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 claims abstract description 7
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 claims abstract description 5
- 239000004094 surface-active agent Substances 0.000 claims abstract description 4
- 239000000203 mixture Substances 0.000 claims description 9
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 claims description 8
- 238000009991 scouring Methods 0.000 claims description 8
- 239000013543 active substance Substances 0.000 claims description 5
- 150000001408 amides Chemical class 0.000 claims description 5
- 239000004160 Ammonium persulphate Substances 0.000 claims description 4
- 239000004159 Potassium persulphate Substances 0.000 claims description 4
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 claims description 4
- 235000019395 ammonium persulphate Nutrition 0.000 claims description 4
- 235000019864 coconut oil Nutrition 0.000 claims description 4
- 239000003240 coconut oil Substances 0.000 claims description 4
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 4
- 239000001530 fumaric acid Substances 0.000 claims description 4
- 239000003999 initiator Substances 0.000 claims description 4
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 claims description 4
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 claims description 4
- 235000019394 potassium persulphate Nutrition 0.000 claims description 4
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 claims description 3
- -1 alcohol ether carboxylate Chemical class 0.000 claims description 3
- 238000007334 copolymerization reaction Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- VVWRJUBEIPHGQF-UHFFFAOYSA-N propan-2-yl n-propan-2-yloxycarbonyliminocarbamate Chemical compound CC(C)OC(=O)N=NC(=O)OC(C)C VVWRJUBEIPHGQF-UHFFFAOYSA-N 0.000 claims description 3
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 3
- AYAUBWSUZRFVQO-UHFFFAOYSA-N 2-[2-(4-phenyl-5-sulfanylidene-1h-1,2,4-triazol-3-yl)ethyl]benzo[de]isoquinoline-1,3-dione Chemical compound O=C1C(C=23)=CC=CC3=CC=CC=2C(=O)N1CCC1=NNC(=S)N1C1=CC=CC=C1 AYAUBWSUZRFVQO-UHFFFAOYSA-N 0.000 claims description 2
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims description 2
- 150000001875 compounds Chemical class 0.000 claims description 2
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 2
- 239000004744 fabric Substances 0.000 abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 13
- 238000004043 dyeing Methods 0.000 abstract description 7
- 239000002131 composite material Substances 0.000 abstract description 6
- 239000006185 dispersion Substances 0.000 abstract description 6
- 230000000694 effects Effects 0.000 abstract description 6
- 238000000034 method Methods 0.000 abstract description 4
- 238000006386 neutralization reaction Methods 0.000 abstract description 4
- 238000010186 staining Methods 0.000 abstract description 4
- 239000000839 emulsion Substances 0.000 abstract description 3
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002191 fatty alcohols Chemical class 0.000 abstract description 2
- 239000000126 substance Substances 0.000 abstract description 2
- 230000009920 chelation Effects 0.000 abstract 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 abstract 1
- 239000011976 maleic acid Substances 0.000 abstract 1
- 230000007935 neutral effect Effects 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 10
- 238000003756 stirring Methods 0.000 description 10
- 238000006243 chemical reaction Methods 0.000 description 8
- 239000000344 soap Substances 0.000 description 8
- 238000005406 washing Methods 0.000 description 8
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 238000009835 boiling Methods 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- 238000001816 cooling Methods 0.000 description 5
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 238000009413 insulation Methods 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 238000010792 warming Methods 0.000 description 5
- 239000011259 mixed solution Substances 0.000 description 4
- 238000007599 discharging Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 239000003643 water by type Substances 0.000 description 3
- 239000003513 alkali Substances 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 239000012530 fluid Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 238000004045 reactive dyeing Methods 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 1
- OZAIFHULBGXAKX-VAWYXSNFSA-N AIBN Substances N#CC(C)(C)\N=N\C(C)(C)C#N OZAIFHULBGXAKX-VAWYXSNFSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 241000322338 Loeseliastrum Species 0.000 description 1
- 101710194948 Protein phosphatase PhpP Proteins 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 238000010504 bond cleavage reaction Methods 0.000 description 1
- 230000003139 buffering effect Effects 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000008233 hard water Substances 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000006210 lotion Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000003472 neutralizing effect Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
Landscapes
- Coloring (AREA)
Abstract
The invention discloses an addition agent acid soaping agent for dyeing. Although the conventional soaping agent composite has good soaping function, but cannot neutralize the alkaline substances which are remained on the cloth, and the cloth is washed by water for multiple times until the pH value of the cloth is close to neutral, the cloth can be used, so a great amount of water resource is wasted. Fatty alcohol polyethenoxy ether is firstly reacted with acrylic acid or maleic acid to generate a polymerization monomer with surface activity, then under the existence of the evocating agent, the polymerization monomer is polymerized with hydrophilic monomer to generate a macromolecular polymer having dispersion chelation performance, and the macromolecular polymer is compounded with the surface active agent to obtain the acid soaping agent. The prepared acid soaping agent integrates the neutralization process and the soaping process after the dyeing of the active dye, so the process flow is greatly shortened, the water is saved, the energy is saved, the emulsion dispersion chelation performance is excellent, the loose color on the texture can be easy to wash, and the staining prevention performance is excellent.
Description
Technical field
The present invention relates to the used additives of printing and dyeing, specifically a kind of acid scouring agent.
Background technology
Because the dyeing of reactive dyestuffs is ripe, chromatogram is complete, particularly development in recent years the double-active radical dye of a series of high colour-fast rates, thereby it is used more and more widely.But because reactive dyestuffs hydrolysis can take place last when dying set, hydrolised dye is adsorbed on the colour fastness that can have a strong impact on dyeing product on the fiber, thereby must carry out water after the reactive dyeing and soap.The main purpose of soaping is exactly in order to remove the hydrolised dye that attaches on fiber, not set dyestuff and other impurity.
The kind of soaping agent is a lot of in the market, according to the mechanism difference of soaping, can soaping agent commonly used be divided into surfactant-based (like industrial soap powder), chelating class (like poly organic phospho acid salt), chelating dispersion type (like a polyacrylate).Usually soap with the basic soap lotion, cloth cover pH value is 10-11 in the bath, is alkalescence; Reactive dyestuffs are prone to take place scission of link when high temperature is soaped; Therefore after the reactive dyestuffs alkali fixation, must after washing or the acid neutralization, making cloth cover pH value, could get into soap bath carrying out soap boiling near neutrality.Publication number is that the one Chinese patent application of CN1834216A discloses a kind of textile printing and dyeing with high-efficiency environment friendly soaping agent composition and method of making the same, with C
12Aliphatic alcohol polyethenoxy (9) ether, Oleum Cocois (acid) diglycollic amide, SAS SAS, reservehao S, tripoly phosphate sodium STPP and water etc. fully stir and form, and the pH of finished product is 6.0-8.0; Though above-mentioned compsn has the function of well soaping, can not in the residual alkaline matter of cloth cover, need cloth cover pH value the time could be used near neutrality through repeatedly washing, wasted great lot of water resources.
Summary of the invention
Technical problem to be solved by this invention is to overcome the defective that above-mentioned prior art exists; A kind of the have washing and the acid scouring agent of stable pH value effect are provided, and it is in order to the pH value that buffering is soaped and bathed, and making that cloth cover pH value remains on 6-8 in the bath of soaping; To reduce by one washing step with in the weak acid and operation; Alleviate the pressure of WWT, water saving guarantees that simultaneously each item fastness of dyeing product meets the requirements.
For this reason; The present invention adopts following technical scheme: a kind of acid scouring agent, and it obtains through following preparation method: AEO and vinylformic acid or toxilic acid react, and generate to have surface-active polymerization single polymerization monomer; Then in the presence of initiator; This polymerization single polymerization monomer and hydrophilic monomer copolymerization generate has the high molecular polymer that disperses chelating ability, and this high molecular polymer and surfactant compound obtain acid scouring agent.Use fatty alcohol polyethenoxy ether class type tensio-active agent and vinylformic acid or toxilic acid reaction among the present invention with excellent dispersion and emulsion performance; Generation has surface-active polymerization single polymerization monomer; Make the final polymkeric substance that generates have more excellent dispersion properties; Superpolymer can be dispersed in dye molecule in the solution through adsorption well, thereby having prevented better that reactive dyestuffs from returning is stained with.The monomer of participating in copolymerization contains carboxyl, not only can in the residual alkaline matter of cloth cover, and have good chelating ability, the product stability in hard water can be good.The also composite emulsifying agent that has some to have special emulsion dispersion property in the product has good washing function to dyestuff in addition.
Above-mentioned hydrophilic monomer is any or the mixture more than two kinds in vinylformic acid, toxilic acid, maleic anhydride, fumaric acid, 2-acrylic amide-2-methyl propane sulfonic acid (AMPS), the acrylic amide
Above-mentioned initiator is any or the mixture more than two kinds in Potassium Persulphate, Sodium Persulfate, ammonium persulphate, Diisopropyl azodicarboxylate (AIBN), the BPO (BPO).
The above-mentioned polymerization single polymerization monomer and the mass ratio of hydrophilic monomer are 1-6: 1.
Above-mentioned tensio-active agent is any or the mixture more than two kinds in aliphatic amine polyoxyethylene ether, coconut oil diethanol amide, the alcohol ether carboxylate (AEC).
The above-mentioned high molecular polymer and the mass ratio of tensio-active agent are 1-6: 1.
The acid neutralization after the acid scouring agent of the present invention's preparation finishes reactive dyeing and the technology of soaping unite two into one; Shortened technical process greatly; Save water and energy, emulsification disperses chelating ability good, and well flush away sticks in the loose colour on the fabric; And anti-staining excellent performance, fabric washing fastness after treatment and anti-staining excellent property.
Below in conjunction with embodiment the present invention is further described.
Embodiment
Embodiment 1
Vinylformic acid 72 grams, the 470 gram addings of lauryl alcohol T 46155 (9) ether are equipped with in the 2000ml four-hole boiling flask of reflux condensing tube, start stirring, logical nitrogen; Be warming up to 135 ℃, between 135-140 ℃ insulation reaction 3.5-4.0 hour, cooling; Discharging synthesizes and has surface-active polymerization single polymerization monomer.
Embodiment 2
Get in polymerization single polymerization monomer 12 grams among the embodiment 1, maleic anhydride 2 grams, the deionized water 40 gram adding four-hole boiling flasks, stir logical nitrogen; Be warming up to 70 ℃, add 0.05 gram Potassium Persulphate, insulation reaction between 75-80 ℃; React after 30 minutes, the mixed solution of dropping 13 gram vinylformic acid, 3 gram AMPS, 0.07 gram Potassium Persulphate, 30 gram deionized waters compositions, the dropping time was controlled between 1.5-2.0 hour; Dropwise continued reaction 1 hour, cooling, discharging.It is composite with 17 gram aliphatic amine polyoxyethylene ethers (1815) to get sample 51 grams that make, and stirs, and makes soaping agent 1#.
Embodiment 3
Get in polymerization single polymerization monomer 10 grams among the embodiment 1, toxilic acid 10 grams, the deionized water 40 gram adding four-hole boiling flasks, stir logical nitrogen; Be warming up to 70 ℃, add Diisopropyl azodicarboxylate 0.06 gram, insulation reaction between 75-80 ℃; React after 30 minutes, the mixed solution of dropping 8 gram vinylformic acid, 2 gram AMPS, 0.07 gram ammonium persulphate, 30 gram deionized waters compositions, the dropping time was controlled between 1.5-2.0 hour; Dropwise continued reaction 30 minutes, cooling, discharging.It is composite with 8 gram coconut oil diethanol amides (6501) to get sample 48 grams that make, and stirs, and makes soaping agent 2#.
Embodiment 4
Get in polymerization single polymerization monomer 18 grams among the embodiment 1, maleic anhydride 6 grams, the deionized water 50 gram adding four-hole boiling flasks, stir logical nitrogen; Be warming up to 70 ℃, add BPO 0.08 gram, insulation between 75-80 ℃; React after 1 hour, the mixed solution that dropwise addition of acrylic acid 4 grams, AMPS 2 grams, 0.05 gram Sodium Persulfate, 20 gram deionized waters are formed, the dropping time was controlled between 1.0-1.5 hour; Dropwise continued reaction 30 minutes, cooling discharge.It is composite with 30 gram AEC to get sample 30 grams that make, and stirs, and makes soaping agent 3#.
Embodiment 5
Get in polymerization single polymerization monomer 15 grams among the embodiment 1, fumaric acid 7 grams, the deionized water 50 gram adding four-hole boiling flasks, stir logical nitrogen; Be warming up to 70 ℃, add 0.06 gram BPO, insulation between 75-80 ℃; React after 1 hour, drip the mixed solution that fumaric acid 3 restrains, vinylformic acid 5 restrains, ammonium persulphate 0.07 restrains, deionized water 20 grams are formed, the dropping time was controlled between 1.0-1.5 hour; Dropwise continued reaction 45 minutes, cooling discharge.Get the sample that makes 50 grams, composite with 10 gram coconut oil diethanol amides (6501), 5 gram aliphatic amine polyoxyethylene ethers (1815), stir, make soaping agent 4#.
For the effect that clearer explanation product of the present invention has, the sample among the embodiment 2 is carried out applicating evaluating, the result sees the following form 1, table 2.
Table 1: soaping agent 1# is to the neutralising capacity of alkali
| Soaping agent 1# consumption, g/l | 0 | ?0.4 | ?0.8 | ?1.2 | ?1.6 | ?2.0 |
| Neutralization back pH value | 10.74 | ?10.38 | ?10.03 | ?9.67 | ?9.08 | ?7.80 |
Annotate: soda ash content is 1g/l in the liquid of soaping.
Can be known by table 1 data: when residual soda ash was 1g/L in bathing when soaping, soaping agent 1# consumption was that 2.0g/L can neutralize working fluid pH between the 7-8, has good acid regulating power.
Table 2: soap effect and the anti-staining effect of soaping agent 1#
| The soaping agent consumption, g/l | 0.3 | ?0.5 | ?1.0 | ?1.5 | ?2.0 | ?2.5 |
| Colour fastness to washing, level | 3 | ?3 | ?3-4 | ?4 | ?4 | ?4 |
| The anti-effect (K/S value) of being stained with | 0.389 | ?0.385 | ?0.339 | ?0.352 | ?0.369 | ?0.382 |
Annotate: with the pH to 7 of soda ash adjusting working fluid, soap effect and the anti-effect of being stained with when estimating soaping agent 1# different amounts.
Technology: painting cloth (bright red) 7.5g+ calico 2.5g, bath raio: 1: 10, condition: 95 ℃ * 20min.
Can know by table 2, under neutrallty condition, when the soaping agent consumption reaches 1.5g/l, colour fastness to washing and the anti-effect excellence of being stained with.
The above only is preferred embodiment of the present invention, is not technical scheme of the present invention is done any pro forma restriction.Every foundation technical spirit of the present invention all falls in protection scope of the present invention any simple modification, equivalent variations and modification that above embodiment did.
Claims (1)
1. acid scouring agent; It obtains through following preparation method: AEO and vinylformic acid or toxilic acid react; Generation has surface-active polymerization single polymerization monomer, and in the presence of initiator, this polymerization single polymerization monomer and hydrophilic monomer copolymerization generate has the high molecular polymer that disperses chelating ability then; This high molecular polymer and surfactant compound obtain acid scouring agent;
Described hydrophilic monomer is any or the mixture more than two kinds in vinylformic acid, toxilic acid, maleic anhydride, fumaric acid, 2-acrylic amide-2-methyl propane sulfonic acid, the acrylic amide;
Described initiator is any or the mixture more than two kinds in Potassium Persulphate, Sodium Persulfate, ammonium persulphate, Diisopropyl azodicarboxylate, the BPO;
Described tensio-active agent is any or the mixture more than two kinds in aliphatic amine polyoxyethylene ether, coconut oil diethanol amide, the alcohol ether carboxylate;
The mass ratio of described polymerization single polymerization monomer and hydrophilic monomer is 1-6: 1, and the mass ratio of described high molecular polymer and tensio-active agent is 1-6: 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100955242A CN101781613B (en) | 2009-01-19 | 2009-01-19 | Acid soaping agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100955242A CN101781613B (en) | 2009-01-19 | 2009-01-19 | Acid soaping agent |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101781613A CN101781613A (en) | 2010-07-21 |
| CN101781613B true CN101781613B (en) | 2012-03-21 |
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| CN2009100955242A Active CN101781613B (en) | 2009-01-19 | 2009-01-19 | Acid soaping agent |
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| CN103388269B (en) * | 2010-10-18 | 2014-12-10 | 南通斯恩特纺织科技有限公司 | Preparation method of high-efficiency environmentally-friendly soaping agent of reactive dye |
| CN102454126B (en) * | 2010-10-18 | 2014-04-23 | 南通斯恩特纺织科技有限公司 | Efficient environment-friendly neutral soaping agent for reactive dye and preparation method for efficient environment-friendly neutral soaping agent |
| CN102864053B (en) * | 2012-10-25 | 2014-06-25 | 南京大地冷冻食品有限公司 | Preparation method of clean and environment-friendly type efficient printing and dyeing soaping agent |
| CN103233377B (en) * | 2013-04-13 | 2016-01-20 | 青岛金智高新技术有限公司 | Jeans prevent the preparation method returning staining agent |
| CN103305854B (en) * | 2013-05-22 | 2015-07-01 | 江苏飞拓界面工程科技有限公司 | Phosphating acid pickling fog inhibitor |
| CN103555460B (en) * | 2013-11-04 | 2015-05-27 | 张家港市德宝化工有限公司 | Reactive dye anti-staining soaping agent and preparation method thereof |
| CN104017124A (en) * | 2014-03-13 | 2014-09-03 | 南京工业大学 | Preparation method of macromolecular soaping agent containing 2-acrylamide-2-methylpropanesulfonic Acid (AMPS) |
| CN104611958B (en) * | 2015-01-16 | 2018-03-13 | 建德市白沙化工有限公司 | A kind of energy-saving environment friendly low temperature soaping agent and its synthetic method |
| CN105297496A (en) * | 2015-11-24 | 2016-02-03 | 惠州市泰和化工有限公司 | Acidic soaping softener |
| CN105419958B (en) * | 2015-12-14 | 2018-06-26 | 厦门大邦瑞达印染材料有限公司 | It is a kind of for the anti-staining soaping agent of acid dyes, preparation method and application |
| CN105802753A (en) * | 2016-04-12 | 2016-07-27 | 湖州吉昌丝绸有限公司 | Soaping agent applicable to wool fabric |
| CN106380543B (en) * | 2016-08-29 | 2018-12-18 | 上海东升新材料有限公司 | A kind of preparation method and products thereof of environment-friendly type soaping agent |
| CN106929178A (en) * | 2017-03-12 | 2017-07-07 | 石狮市华锐化工贸易有限公司 | A kind of acid scouring agent and preparation method thereof |
| CN111607993A (en) * | 2020-05-27 | 2020-09-01 | 山东黄河三角洲纺织科技研究院有限公司 | Printing double-sided printing-through process for cellulose fiber cation modified fabric |
| CN111549549A (en) * | 2020-05-27 | 2020-08-18 | 山东黄河三角洲纺织科技研究院有限公司 | Cationic modified printing washing anti-staining process for cellulose fiber fabric |
| CN112779794B (en) * | 2020-12-23 | 2023-03-10 | 太仓宝霓实业有限公司 | Soaping agent for polyester/cotton/ammonia fabric and preparation method thereof |
| CN112726236B (en) * | 2020-12-28 | 2022-06-17 | 绍兴海成化工有限公司 | Neutralization soaping agent |
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Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1814722A (en) * | 2006-01-16 | 2006-08-09 | 张宏格 | Liquid detergent viscosity-increasing agent |
| CN1834216A (en) * | 2005-09-29 | 2006-09-20 | 东莞市德能化工有限公司 | A kind of high-efficiency and environment-friendly soaping agent composition for textile printing and dyeing soaping and preparation method thereof |
-
2009
- 2009-01-19 CN CN2009100955242A patent/CN101781613B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1834216A (en) * | 2005-09-29 | 2006-09-20 | 东莞市德能化工有限公司 | A kind of high-efficiency and environment-friendly soaping agent composition for textile printing and dyeing soaping and preparation method thereof |
| CN1814722A (en) * | 2006-01-16 | 2006-08-09 | 张宏格 | Liquid detergent viscosity-increasing agent |
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| CN101781613A (en) | 2010-07-21 |
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