CN101775153B - Barium-zinc liquid stabilizer, preparation method and application thereof - Google Patents
Barium-zinc liquid stabilizer, preparation method and application thereof Download PDFInfo
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- CN101775153B CN101775153B CN2010101040690A CN201010104069A CN101775153B CN 101775153 B CN101775153 B CN 101775153B CN 2010101040690 A CN2010101040690 A CN 2010101040690A CN 201010104069 A CN201010104069 A CN 201010104069A CN 101775153 B CN101775153 B CN 101775153B
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- 239000003381 stabilizer Substances 0.000 title claims description 52
- 239000007788 liquid Substances 0.000 title claims description 32
- SHLNMHIRQGRGOL-UHFFFAOYSA-N barium zinc Chemical compound [Zn].[Ba] SHLNMHIRQGRGOL-UHFFFAOYSA-N 0.000 title claims description 22
- 238000002360 preparation method Methods 0.000 title claims description 10
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims description 22
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 claims description 19
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 claims description 13
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 claims description 13
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 claims description 13
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 claims description 13
- 239000005642 Oleic acid Substances 0.000 claims description 13
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 claims description 13
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 claims description 13
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 claims description 11
- OEOIWYCWCDBOPA-UHFFFAOYSA-N 6-methyl-heptanoic acid Chemical compound CC(C)CCCCC(O)=O OEOIWYCWCDBOPA-UHFFFAOYSA-N 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 11
- 238000001556 precipitation Methods 0.000 claims description 11
- 238000003756 stirring Methods 0.000 claims description 11
- 239000011787 zinc oxide Substances 0.000 claims description 11
- 238000010792 warming Methods 0.000 claims description 10
- QFKJCKFAYFUXRQ-UHFFFAOYSA-N barium;hydrate Chemical compound O.[Ba] QFKJCKFAYFUXRQ-UHFFFAOYSA-N 0.000 claims description 9
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 8
- 238000000605 extraction Methods 0.000 claims description 7
- 238000006243 chemical reaction Methods 0.000 claims description 6
- 239000012467 final product Substances 0.000 claims description 6
- 230000004044 response Effects 0.000 claims description 5
- 238000009413 insulation Methods 0.000 claims description 2
- 239000000047 product Substances 0.000 description 14
- -1 metals ion Chemical class 0.000 description 9
- 150000003839 salts Chemical class 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 150000007524 organic acids Chemical class 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000000344 soap Substances 0.000 description 5
- 229910052801 chlorine Inorganic materials 0.000 description 4
- 239000002131 composite material Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 239000002585 base Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 235000014113 dietary fatty acids Nutrition 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000000194 fatty acid Substances 0.000 description 3
- 229930195729 fatty acid Natural products 0.000 description 3
- 239000003446 ligand Substances 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 229910052725 zinc Inorganic materials 0.000 description 3
- 239000011701 zinc Substances 0.000 description 3
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- 238000007259 addition reaction Methods 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 229910052788 barium Inorganic materials 0.000 description 2
- DSAJWYNOEDNPEQ-UHFFFAOYSA-N barium atom Chemical compound [Ba] DSAJWYNOEDNPEQ-UHFFFAOYSA-N 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 125000001309 chloro group Chemical group Cl* 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 230000008676 import Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000006467 substitution reaction Methods 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 2
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- OSDWBNJEKMUWAV-UHFFFAOYSA-N Allyl chloride Chemical group ClCC=C OSDWBNJEKMUWAV-UHFFFAOYSA-N 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- FECYWCXKWXPHPP-UHFFFAOYSA-N [Ca][Zn][Ba] Chemical compound [Ca][Zn][Ba] FECYWCXKWXPHPP-UHFFFAOYSA-N 0.000 description 1
- XVYHFPMIBWTTLH-UHFFFAOYSA-N [Zn].[Mg].[Ca] Chemical compound [Zn].[Mg].[Ca] XVYHFPMIBWTTLH-UHFFFAOYSA-N 0.000 description 1
- 230000009471 action Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- MGFRKBRDZIMZGO-UHFFFAOYSA-N barium cadmium Chemical compound [Cd].[Ba] MGFRKBRDZIMZGO-UHFFFAOYSA-N 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 125000003262 carboxylic acid ester group Chemical group [H]C([H])([*:2])OC(=O)C([H])([H])[*:1] 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 150000001993 dienes Chemical class 0.000 description 1
- 238000006073 displacement reaction Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- 150000002632 lipids Chemical class 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000011159 matrix material Substances 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 150000004291 polyenes Polymers 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 239000008247 solid mixture Substances 0.000 description 1
- 238000002910 structure generation Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 239000003017 thermal stabilizer Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Abstract
The invention relates to PVC heat stabilizer, in particular to heat stabilizer applied to decoration of PVC materials, a preparation method and application thereof. The barium-zinc liquid stabilizer is prepared from the following components in percentage by weight:, 20.0 to 35.0 percent of sodium iso-octoate, 10.0 to 15.5 percent of oleic acid, 8.5 to 12.8 percent of barium monohydrate, 1.0 to 5.0 percent of zinc oxide, 5.0 to 10.5 percent of diethylene glycolmonobutylether, 1.0 to 3.0 percent of antioxidant 1010, 1.0 to 4.5 percent of bisphenol A, 1.0 to 3.0 percent of beta-diketone, 5.0 to 10.5 percent of anti-separation agent, and 20.0 to 35.0 percent of DOP, wherein the total amount of components is 100 percent. The invention solves the problem that products have foreign smell based on raw materials, simplifies the production process by a one-step synthesis method, has more convenient operation, and has the effects that: firstly, the stabilizer saves energy consumption and reducing pollution; secondly, the stabilizer has high value advantage compared with international products with the same function and has better competitive force; and thirdly, the stabilizer belongs to green and environment-friendly product, and has strong vitality.
Description
Technical field
The present invention relates to a kind of PVC thermo-stabilizer, relate in particular to a kind of thermo-stabilizer that is applied to decoration of PVC materials.
Background technology
Thermo-stabilizer is one type can be prevented or reduce polymkeric substance and be heated in the use and degraded or crosslinked takes place in processing, the additive in elongate composite material work-ing life.Stablizer commonly used can be divided into salt base class, fatty acid soaps class, organo-tin compound, composite type heat stablizer and pure organic cpds class according to the staple classification.
1) alkali type thermal stabilizing agent: salt base class stablizer is meant and is combined with the inorganic of " alkali " and organic acid lead salt; This type stablizer has good thermotolerance, weathering resistance and electrical insulating property, and cost is low, and the transparency is poor; Certain toxicity is arranged, and consumption is generally 0.5%～5.0%.
2) fatty acid thermo-stabilizer: this type thermal stabilizing agent is meant the compound of being made up of fatty acid radical and metals ion, also claims metal soap thermal stabilizers, and its performance is relevant with the kind of acid group and metals ion, and general consumption is 0.1%～3.0%.
3) organic tin thermo-stabilizer: this type thermal stabilizing agent can form ligand with unstable chlorine atom in the SE molecule, and in ligand the carboxylic acid ester groups and the unsettled chlorine atomic substitutions of organotin.The characteristics of this type thermal stabilizing agent are that stability is high, good, the excellent heat resistance of the transparency, and weak point is that price is more expensive.
4) composite type heat stablizer: this type thermal stabilizing agent is the mixture that the liquid or solid mixture that is the basis with salt base class or metallic soap class and organotin are the basis, and wherein metallic salt has calcium-magnesium-zinc, barium-calcium-zinc, barium-zinc and barium-cadmium etc.; Organic acid such as organic lipid acid, naphthenic acid, oleic acid, phenylformic acid and Whitfield's ointment etc. commonly used.
5) organic cpds thermo-stabilizer: the main stabilizer that this type thermal stabilizing agent can use separately except that minority (mainly being nitrogenous organic cpds); Also comprise high boiling polyvalent alcohol and phosphorous acid ester; Phosphorous acid ester normal and metal(lic)stabilizer and usefulness; Can improve weathering resistance, the transparency of matrix material, improve the surface color of goods.
The mechanism of action of PVC thermo-stabilizer is following: in 1) absorbing and HCL, suppress its autocatalytic action.This type stablizer comprises lead salts, organic acid metal soap class, organo-tin compound, epoxy compounds, phenates and metal mercaptide salt etc.They can react with HCL, suppress the reaction that PVC takes off HCL.2) unsettled chlorallylene atom suppresses to take off PVC in the displacement PVC molecule.Combine with the unstable chlorine atom generation coordination of PVC molecule like organotin stabilizer, in ligand, organotin and unstable chlorine atomic substitutions.3) with polyene structure generation addition reaction, destroy the formation of big conjugated system, reduce painted.The salt of unsaturated acid or ester contain two keys, with conjugated double bond generation diene addition reaction in the PVC molecule, thereby destroy its conjugated structure, suppress variable color.
The composite type heat stablizer is because good performance and favorable environment protection can be Development Trend, and the existing PVC thermo-stabilizer that is used for top layer film in the car adopts raw material: phosphorous acid ester, 1010, dihydroxyphenyl propane, β--diketone, white oil, solvent oil, anti-precipitation agent, hydrated barta, zinc oxide, oleic acid, isocaprylic acid, triglycol, NP; Production technique comprises the steps: 1. hydrated barta, NP, triglycol, oleic acid etc. to be made 6# barium; 2. isocaprylic acid, oleic acid, zinc oxide, phosphorous acid ester, white oil etc. are made 4# zinc; 3. with 6# barium, 4# zinc and phosphorous acid ester, 1010, dihydroxyphenyl propane, β--diketone, white oil, solvent oil, anti-precipitation agent mix, and under 120 ℃ of temperature, stir to get final product in 1 hour.This product preparation process is complicated, and product has peculiar smell.
Summary of the invention
For the technological deficiency that the PVC thermo-stabilizer that solves top layer film in the above-mentioned car exists, first purpose of the present invention provides a kind of barium-zinc liquid stabilizer, and this stablizer solves the problem that product has peculiar smell, has the characteristics of safety and environmental protection.Another object of the present invention provides the preparation method of above-mentioned barium-zinc liquid stabilizer, and this method has been simplified production process, operates easier.
In order to realize first above-mentioned purpose, the technical scheme below the present invention has adopted:
A kind of barium-zinc liquid stabilizer, this liquid stabilisers is prepared by following component by weight percentage:
As preferably, this liquid stabilisers is prepared by following component by weight percentage:
Preferred as again, this liquid stabilisers is prepared by following component by weight percentage:
In order to realize second above-mentioned purpose, the preparation method of barium-zinc liquid stabilizer of the present invention, this method comprises the steps:
1. isocaprylic acid, oleic acid, barium monohydrate, zinc oxide and part Diethylene Glycol butyl ether are put into reaction kettle, stir and are warming up to 80～95 ℃, and insulation is to fully anti-;
2. question response is complete, after solution becomes is transparent, is warming up to 100～110 ℃, carries out vacuum hydro-extraction;
3. after the vacuum hydro-extraction, add antioxidant 1010, dihydroxyphenyl propane, β--diketone, anti-precipitation agent, DOP and remaining Diethylene Glycol butyl ether, stir under 115～125 ℃ of temperature and got final product in 0.5～2 hour.
As preferably, 1. above-mentioned steps is 1: 2～2: 3 with the mass ratio that 3. step adds the Diethylene Glycol butyl ether.
The present invention also discloses top layer PVC film in a kind of car in addition, and this PVC film adopts barium-zinc liquid stabilizer of the present invention.The usage quantity of barium-zinc liquid stabilizer of the present invention is identical with the usage quantity of existing liquid stabilisers.
The present invention is owing to having adopted above-mentioned technical scheme, and is compound with other auxiliary stabilizer again behind organic acid and MOX and oxyhydroxide effect generation metallic soap, forms one package stabilizer efficiently at last.Wherein, isocaprylic acid, oleic acid are organic acid, and barium monohydrate is an oxyhydroxide, and zinc oxide is MOX, and the Diethylene Glycol butyl ether is made thinner, 1010, dihydroxyphenyl propane is oxidation inhibitor, and β--diketone is an auxiliary stabilizer, and the effect of reduction " zinc burning " can be arranged.DOP makees solvent, and anti-precipitation agent is that market purchasing mainly is the blending that improves stablizer and resin, and minimizing is oozed out.
Product of the present invention is compared with existing like product, and the present invention solves the problem that product has peculiar smell from raw material, simultaneously, has simplified production process, and adopt in the past and divide step production method, be one-step synthesis now, operate easier.Product of the present invention is with respect to existing products, and effect of the present invention is obvious.Mainly show: the first, energy efficient has also reduced pollution.The second, we have very big price advantage with the product of congenerous is compared in the world, therefore also have more competitive power.The 3rd, also be the most outstanding a bit to the invention belongs to Green Product, have very strong vitality.
Embodiment
Following specific embodiments of the invention is done a detailed explanation.
Embodiment 1
A kind of barium-zinc liquid stabilizer, the raw materials by weight meter of this liquid stabilisers is made up of following component:
| Isocaprylic acid | 28.5％ | Oleic acid | 12.5％ |
| Barium monohydrate | 9.8％ | Zinc oxide | 4.2％ |
| The Diethylene Glycol butyl ether | 6.5％ | Antioxidant 1010 | 1.5％ |
| Dihydroxyphenyl propane | 3.5％ | β--diketone | 2.0％ |
| Anti-precipitation agent | 7.5％ | DOP | 24.0％。 |
The preparation method of above-mentioned barium-zinc liquid stabilizer, this method comprises the steps:
1. isocaprylic acid, oleic acid, barium monohydrate, zinc oxide and part Diethylene Glycol butyl ether are put into reaction kettle, stir and are warming up to 90 ℃, are incubated 2 hours to fully anti-;
2. question response is complete, after solution becomes is transparent, is warming up to 100 ℃, carries out vacuum hydro-extraction;
3. dewatering after about half a hour, add antioxidant 1010, dihydroxyphenyl propane, β--diketone, anti-precipitation agent, DOP and remaining Diethylene Glycol butyl ether, stirring got final product in 1 hour under 120 ℃ of temperature.
Wherein: 1. step is 1: 2 with the mass ratio that 3. step adds the Diethylene Glycol butyl ether.
Embodiment 2
A kind of barium-zinc liquid stabilizer, the raw materials by weight meter of this liquid stabilisers is made up of following component:
| Isocaprylic acid | 21.8％ | Oleic acid | 14.2％ |
| Barium monohydrate | 11.2％ | Zinc oxide | 3.5％ |
| The Diethylene Glycol butyl ether | 9.6％ | Antioxidant 1010 | 2.4％ |
| Dihydroxyphenyl propane | 1.8％ | β--diketone | 2.4％ |
| Anti-precipitation agent | 6.2％ | DOP | 26.9％。 |
The preparation method of above-mentioned barium-zinc liquid stabilizer, this method comprises the steps:
1. isocaprylic acid, oleic acid, barium monohydrate, zinc oxide and part Diethylene Glycol butyl ether are put into reaction kettle, stir and are warming up to 90 ℃, are incubated 2 hours to fully anti-;
2. question response is complete, after solution becomes is transparent, is warming up to 100 ℃, carries out vacuum hydro-extraction;
3. dewatering after about half a hour, add antioxidant 1010, dihydroxyphenyl propane, β--diketone, anti-precipitation agent, DOP and remaining Diethylene Glycol butyl ether, stirring got final product in 1 hour under 120 ℃ of temperature.
Wherein: 1. step is 2: 3 with the mass ratio that 3. step adds the Diethylene Glycol butyl ether.
Embodiment 3
A kind of barium-zinc liquid stabilizer, the raw materials by weight meter of this liquid stabilisers is made up of following component:
| Isocaprylic acid | 27.3％ | Oleic acid | 13.5％ |
| Barium monohydrate | 9.2％ | Zinc oxide | 2.3％ |
| The Diethylene Glycol butyl ether | 7.2％ | Antioxidant 1010 | 1.8％ |
| Dihydroxyphenyl propane | 2.4％ | β--diketone | 2.0％ |
| Anti-precipitation agent | 7.3％ | DOP | 27.0％； |
The preparation method of above-mentioned barium-zinc liquid stabilizer, this method comprises the steps:
1. isocaprylic acid, oleic acid, barium monohydrate, zinc oxide and part Diethylene Glycol butyl ether are put into reaction kettle, stir and are warming up to 90 ℃, are incubated 2 hours to fully anti-;
2. question response is complete, after solution becomes is transparent, is warming up to 100 ℃, carries out vacuum hydro-extraction;
3. dewatering after about half a hour, add antioxidant 1010, dihydroxyphenyl propane, β--diketone, anti-precipitation agent, DOP and remaining Diethylene Glycol butyl ether, stirring got final product in 1 hour under 120 ℃ of temperature.
Wherein: 1. step is 3: 5 with the mass ratio that 3. step adds the Diethylene Glycol butyl ether.
Test Example 1
The product that the embodiment of the invention 3 prepares and German bear board 801S barium-zinc liquid stabilizer stability contrast table such as table 1.
Table 1: stablizer stability contrast table
Can find out that through table 1 stability of the stablizer of the inventive method preparation is superior to the advanced like product of import.Moreover, be placed on frosted bottle splendid attire in 80 ℃ the baking oven and take out after 2 hours through testing stablizer of the present invention, tasteless.Compare with the 801S of German bear board, product flavor of the present invention is lighter, thereby we can say that the present invention not only can substitute the import like product, but also has remedied domestic blank market.
Claims (6)
1. barium-zinc liquid stabilizer is characterized in that this liquid stabilisers is prepared by following component by weight percentage:
The total amount of above-mentioned each component is 100%.
2. a kind of barium-zinc liquid stabilizer according to claim 1 is characterized in that this liquid stabilisers is prepared by following component by weight percentage:
The total amount of above-mentioned each component is 100%.
3. a kind of barium-zinc liquid stabilizer according to claim 1 is characterized in that this liquid stabilisers is prepared by following component by weight percentage:
The total amount of above-mentioned each component is 100%.
4. the preparation method like claim 1 or 2 or 3 described barium-zinc liquid stabilizers is characterized in that this method comprises the steps:
1. isocaprylic acid, oleic acid, barium monohydrate, zinc oxide and part Diethylene Glycol butyl ether are put into reaction kettle, stir and are warming up to 80～95 ℃, and insulation is to reacting completely;
2. question response is complete, after solution becomes is transparent, is warming up to 100～110 ℃, carries out vacuum hydro-extraction;
3. after the vacuum hydro-extraction, add antioxidant 1010, dihydroxyphenyl propane, β--diketone, anti-precipitation agent, DOP and remaining Diethylene Glycol butyl ether, stir under 115～125 ℃ of temperature and got final product in 0.5～2 hour.
5. the preparation method of barium-zinc liquid stabilizer according to claim 4 is characterized in that: 1. step is 1: 2～2: 3 with the mass ratio that 3. step adds the Diethylene Glycol butyl ether.
6. top layer PVC film in the car, it is characterized in that: this PVC film adopts like claim 1 or 2 or 3 described barium-zinc liquid stabilizers.
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| CN2010101040690A CN101775153B (en) | 2010-01-28 | 2010-01-28 | Barium-zinc liquid stabilizer, preparation method and application thereof |
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| CN2010101040690A CN101775153B (en) | 2010-01-28 | 2010-01-28 | Barium-zinc liquid stabilizer, preparation method and application thereof |
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| CN101775153B true CN101775153B (en) | 2012-01-04 |
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| CN102604263A (en) * | 2012-03-13 | 2012-07-25 | 德清县东来化学有限公司 | Potassium-zinc liquid stabilizer for PVC (polyvinyl chloride) wallpaper and preparation method of potassium-zinc liquid stabilizer |
| CN102604264A (en) * | 2012-03-13 | 2012-07-25 | 德清县东来化学有限公司 | Potassium-zinc liquid stabilizer for PVC (polyvinyl chloride) artificial leather and preparation method for same |
| CN103304847A (en) * | 2013-07-02 | 2013-09-18 | 上海浩缘环保材料有限公司 | Barium-zinc liquid stabilizer and preparation method thereof |
| CN103450589B (en) * | 2013-08-16 | 2016-08-10 | 泰山体育产业集团有限公司 | A kind of PVC liquid composite stabilizing agent and preparation method thereof |
| CN104910414A (en) * | 2015-06-18 | 2015-09-16 | 巢湖香枫塑胶助剂有限公司 | Preparation method of liquid barium-zinc composite heat stabilizer |
| CN106084538B (en) * | 2016-06-14 | 2018-10-30 | 浙江海普顿新材料股份有限公司 | A kind of liquid carboxylic metal salt and the preparation method and application thereof |
| CN107141643B (en) * | 2017-05-26 | 2019-06-07 | 南通艾德旺化工有限公司 | A kind of barium-zinc liquid heat stabilizer and preparation method thereof, application |
| CN109293988A (en) * | 2018-10-07 | 2019-02-01 | 德清县东来化学有限公司 | A kind of environment-friendly liquid barium zinc compound stabilizer and preparation method thereof |
| CN110066522A (en) * | 2019-04-25 | 2019-07-30 | 安徽华文塑胶科技有限公司 | Anti- precipitation liquid stabilizer of one kind and preparation method thereof |
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