CN101768499B - Lipid type antirust oil with gaseous phase antirust function - Google Patents
Lipid type antirust oil with gaseous phase antirust function Download PDFInfo
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- CN101768499B CN101768499B CN 201010100937 CN201010100937A CN101768499B CN 101768499 B CN101768499 B CN 101768499B CN 201010100937 CN201010100937 CN 201010100937 CN 201010100937 A CN201010100937 A CN 201010100937A CN 101768499 B CN101768499 B CN 101768499B
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- antirust
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- Preventing Corrosion Or Incrustation Of Metals (AREA)
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Abstract
The invention discloses a lipid type antirust oil with gaseous phase antirust function; the composition of the lipid type antirust oil in weight percent is as follows: 70-90% of base lipid, 4-15% of antirust agent, 1-5% of gaseous phase antirust agent and 5-10% of oil film modifying agent; the inventive antirust oil has long protection period, sun and rain exposure resistance, non-leakage at high temperature, non-cracking at low temperature, transparent and soft oil film, good paintability, and easy removal, and is mainly applied for antirusting for various metalwares, precise instruments, mechanical equipments, metal rotation sequence of workshops in machining industry, etc.
Description
Technical field
The invention belongs to chemical field, especially a kind of grease type rust preventing oil with gaseous phase antirust function.
Background technology
Along with China's mechanical processing industry develop, import and export the increasing of equipment rapidly, antirust grease plays very important effect in machinofacture, transportation, storage and normal operation.Metallic substance and the mechanical means overwhelming majority be take iron as main, and the cast iron in the ferrous metal, carbon steel and low alloy steel etc. gets rusty easily especially, and the non-ferrous metals such as copper, magnesium also are easy to corrosive chameleon.Surface oxidisation can make the performance of metal products and mechanical means and commodity value be subject to very big infringement, even can cause significant trouble and make equipment scrapping.
China's mechanical processing industry often uses butter for a long time, machinery oil, and Vaseline, the grease that this class such as paraffin does not possess special-purpose antirust technology performance is used as metal rust preventing, and this series products the oil film drying shrinkage can occur after use, and sclerosis is difficult for the problems such as removal.In the situation that more abominable being difficult to of environment for use has rust-proof effect.Chinese patent CN1385507A discloses a kind of rust-resistant cream, the product produced in conventional processes mixes calcium grease, lithium saponify, sodium-base grease, butter and gasoline or diesel oil, although this type of rust-resistant cream is easily produced, but do not add rust-preventive agent, rustless property is not good.Chinese patent CN101381650A discloses a kind of long-acting rust-proof grease, although product has good rustless property, the adipose membrane performance is general, and has used the barium mahogany sulfonate composition, makes product have certain toxicity.Chinese patent CN1102855A discloses a kind of metal rust-proof grease, although product has improved the adipose membrane performance, uses formaldehyde as sanitas, and contaminate environment is toxic.
Summary of the invention
The object of the invention is to, provide a kind of and added adipose membrane properties-correcting agent and with the grease type rust preventing oil of gaseous phase antirust function.
The present invention is achieved through the following technical solutions.
A kind of grease type rust preventing oil with gaseous phase antirust function, its component and weight percent thereof are:
Basic grease 70～90%
Rust-preventive agent 4～15%
Vapor phase inhibitor 1～5%
Adipose membrane properties-correcting agent 5～10%.
Described basic grease is selected from Vaseline or machinery oil, perhaps the mixture between them.Vaseline is medical grade Vaseline.Machinery oil is the 22# machinery oil.
Described rust-preventive agent is selected from the mixture of a kind of in the rust-preventive agent such as petroleum sodium sulfonate, calcium mahogany sulfonate, barium mahogany sulfonate, sorbitol monooleate, lanolin magnesium soap, naphthenic soap, N-oleoyl propylhomoserin stearylamine salt, benzotriazole, methyl benzotriazazole or four kinds.Be preferably calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole.
Described calcium mahogany sulfonate be rust-preventive agent be again detergent-dispersant additive, rust-proof effect is similar to barium mahogany sulfonate, and nontoxic, has in the good acid and performance and certain characteristic of solubilizing.
Described sorbitol monooleate has good moisture-resistant pattern of fever.
Described N-oleoyl propylhomoserin stearylamine salt has the tensio-active agent of multiple group, not only has a good moisture-resistant hot, and good resistance to salt(spray)fog and sour neutrality are arranged.
The benzotriazole that the present invention selects has good inhibition antirust function to non-ferrous metals such as copper.
Described vapor phase inhibitor is stearylamine or 124 Triazole Tributylamine, the perhaps mixture between them.
Described stearylamine has with the 124 Triazole Tributylamine and contacts antirust and gaseous phase antirust function, can play antirust and gaseous phase antirust function to various metals.
Described adipose membrane properties-correcting agent is stearic acid or resol, perhaps the mixture between them.Stearic acid makes oil film have good application property.
Described resol had both made oil film have good hydrophobicity, and made oil film have good compactness.
Preparation method of the present invention: proportionally basic grease is joined in the reactor, be warmed up to 70 ℃, add adipose membrane properties-correcting agent, stirred 15 minutes, keep 70 ℃ and add successively rust-preventive agent, stirred 30 minutes; To be cooled to 60 ℃, add vapor phase inhibitor, restir got final product in 1 hour.
The present invention has advantages of: anti-Japanese solarization drenches with rain, and high temperature does not run off, and low temperature does not ftracture, and oil film is transparent, soft, and coating is good, easily removes; Added vapor phase inhibitor; make grease type rust preventing oil have certain volatile inhibition concurrently; unique VCI technology; can volatilize at normal temperatures the inhibition particle with rust inhibition; because the vapour-phase inhibitor particle volatility of this technology is higher, as long as its steam-energy gets at and reaches the metallic surface metal is protected.
Embodiment
The preparation of the grease type rust preventing oil of embodiment 1～4 band gaseous phase antirust function of the present invention joins Vaseline and 22# machinery oil in the reactor according to the ratio of table 1, be warmed up to 70 ℃, add stearic acid, resol, stirred 15 minutes, keep 70 ℃, add successively calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole, stirred 30 minutes; To be cooled to 60 ℃, add 124 Triazole fourth triamine and stearylamine, restir got final product in 1 hour.
The composition of table 1 grease type rust preventing oil of the present invention and schedule of proportion thereof.
| The 22# machinery oil | 15 | 11 | 8 | 10 |
| Calcium mahogany sulfonate | 2 | 2 | 1 | 1 |
| Sorbitol monooleate | 2 | 3 | 3 | 2 |
| N-oleoyl propylhomoserin stearylamine salt | 2 | 2.5 | 3 | 1.5 |
| Benzotriazole | 0.4 | 0.6 | 0.8 | 1 |
| 124 Triazole fourth triamine | 1.0 | 0.8 | 0.6 | 0.4 |
| Stearylamine | 0.7 | 1.0 | 1.3 | 1.5 |
| Stearic acid | 2 | 3 | 4 | 5 |
| Resol | 4.9 | 2.1 | 2.3 | 2.6 |
Embodiment 5 grease type rust preventing oil performance index of the present invention detect
According to the test method shown in the table 2, embodiment 3 prepared grease type rust preventing oils are detected, detected result sees Table 2
The performance test results table of table 2 grease type rust preventing oil of the present invention
| Project | Quality index | Test method | Test-results |
| Melt drop temperature ℃ is not less than | 55 | GB/T 8026 | 57 |
| Flash-point ℃ is not less than | 175 | GB/T 3536 | 181 |
| Sludge number, ml is not more than | 0.05 | SH/T 0215 | 0.04 |
| Abradability | Without scar | SH/T 0215 | Without scar |
| Flow down a little, ℃ be not less than | 40 | SH/T 0082 | 43 |
By table 2 data as seen, grease type rust preventing oil of the present invention not only satisfies the technical indicator of L-RK grease type rust preventing oil, and has excellent volatile inhibition, makes the metal that can't apply slushing oil also can obtain corrosion protection.
Embodiment 6 grease type rust preventing oil rustless property simultaneous tests of the present invention
In order to verify that grease type rust preventing oil of the present invention has excellent gaseous phase antirust function, according to SH/T 0660 test method, selected commercially available blue star board LX-85 rust preventing grease, shell Bang Lite board 903 rust preventing greases,, shell Bang Lite board 663 rust preventing greases carry out volatile rust prevention performance simultaneous test.Contrast and experiment sees Table 3
Table 3 volatile rust prevention performance comparative test result table
| The simultaneous test product | Grease type rust preventing oil of the present invention | Blue star board LX-85 rust preventing grease | Shell Bang Lite board 903 rust preventing greases | Shell Bang Lite board 663 rust preventing greases |
| Volatile inhibition SH/T 0660 | Non-corroding | Corrosion is arranged | Corrosion is arranged | Corrosion is arranged |
Can find out grease type rust preventing oil of the present invention from table 2, table 3 data, adipose membrane is transparent, and softness has good workability, sun-resistant drenching with rain, and have excellent volatile inhibition, make the metal that can't apply slushing oil also can obtain corrosion protection.Be particluarly suitable for height damp and hot, long-term antirust use under the severe environment such as high salt fog.
Claims (2)
1. grease type rust preventing oil with gaseous phase antirust function is characterized in that its component and weight percent thereof are:
Described rust-preventive agent is the mixture of calcium mahogany sulfonate, sorbitol monooleate, N-oleoyl propylhomoserin stearylamine salt and benzotriazole;
Described vapor phase inhibitor is the mixture of stearylamine and 124 Triazole Tributylamine;
Described adipose membrane properties-correcting agent is the mixture of stearic acid and resol.
2. grease type rust preventing oil according to claim 1 is characterized in that described basic grease is Vaseline or machinery oil, or the mixture between them.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010100937 CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010100937 CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101768499A CN101768499A (en) | 2010-07-07 |
| CN101768499B true CN101768499B (en) | 2013-01-30 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 201010100937 Expired - Fee Related CN101768499B (en) | 2010-01-25 | 2010-01-25 | Lipid type antirust oil with gaseous phase antirust function |
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2010
- 2010-01-25 CN CN 201010100937 patent/CN101768499B/en not_active Expired - Fee Related
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