CN101734764B - Water dispenser with sterilizing function and sterilizing method thereof - Google Patents
Water dispenser with sterilizing function and sterilizing method thereof Download PDFInfo
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- CN101734764B CN101734764B CN2008102260421A CN200810226042A CN101734764B CN 101734764 B CN101734764 B CN 101734764B CN 2008102260421 A CN2008102260421 A CN 2008102260421A CN 200810226042 A CN200810226042 A CN 200810226042A CN 101734764 B CN101734764 B CN 101734764B
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- sterilizing function
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Abstract
The invention relates to a water dispenser with the sterilizing function and a sterilizing method thereof. The water dispenser comprises a smart mouth connected with a barreled water outlet by inserting and a waterfall holder buckled with the smart mouth. An electrolytic component is arranged in the waterfall holder and is connected with a controllable power source by a lead penetrating through the waterfall holder. The sterilizing method is as follows: the water in the water dispenser is the barreled pure water or barreled mineral water sold in the market; water flows into the waterfall holder through the smart mouth, the controllable power source is switched on to electrify the electrolytic component to carry out electrolysis for 30min-2h, and then the controllable power source is switched off, thus finishing sterilization in the waterfall holder of the water dispenser and in the barrel on the water dispenser. The invention can realize powerful and continuous sterilization at any time, has no toxic or side effect, is safe and sanitary and can adjust the pH value of the original barreled pure water from weak acidity to weak basicity.
Description
Technical field
The present invention relates to a kind of water dispenser and method for disinfection thereof with sterilizing function.
Background technology
As everyone knows, the air that the negative pressure that produces after the bottled water water outlet on the water dispenser will lean on non-sterile to handle replenishes, and entrained air bacterium and dust enters water dispenser, causes " secondary pollution ", also can in water dispenser, form the clammy bacterial film of one deck simultaneously, jeopardize safe drinking water.Discover that the bacterium in the water dispenser mainly contains Acinetobacter baumannii, clostridium, coliform, mould, yeast, Pseudomonas aeruginosa etc., must kill for this reason, prevent the growth of pipeline and tank bacterium the bacterium that grows in the pipeline of water dispenser and the tank.
Generally one of purpose of carrying out water treatment is the pathogenic bacterium of killing in the water, and makes the bacteria content standard up to specification in the water.Water treatment method commonly used is chlorine disinfectant, disinfection by ultraviolet light and ozonization.
Chlorine disinfectant is mainly used in the tap water sterilization.
The principle of disinfection by ultraviolet light be the pathogenic micro-organism absorbing wavelength behind the ultraviolet energy between 200nm~275nm, its genetic material (nucleic acid) is undergone mutation and is caused no longer fissiparity of cell, reaches the purpose of disinfection.But one of its shortcoming is that ultraviolet ray is difficult to reach ideal effect because of the penetrativity in water is limited; The 2nd,, uv sterilisation can not be kept sterilisation effect as chlorine disinfection method.And what generally adopt in bottled water and the water dispenser is uv sterilisation.
The principle of ozonization is that redox reaction takes place in water ozone, produce extremely strong antozone (O) and the hydroxyl (OH) of oxidation capacity, organic substance, bacterium and microorganism in the moment water of decomposition, have the oxidation sterilizing ability stronger than chlorine disinfection method, but the improper bromate that might produce carcinogenic danger of ozonation process brings hidden danger to water safety.Also often adopt ozonization in bottled water and the water dispenser.
Another purpose of water treatment is the objectionable impurities of removing in the water, and what it adopted is electrochemical water treating method.Electrochemical water treating method is based on electrochemical ultimate principle, utilize electrode reaction and correlated process thereof, by direct and indirect comprehensive actions such as redox, pollutions such as organism, heavy metal, nitrate, colloid and particle, bacterium, colourity, stink in the water all there is good removal effect.Sewage work often adopts this method to dispose of sewage.Electrochemical sterilization is the oxidizing substance (H that utilizes electrolytic process to produce
2O
2, O
3Hydroxyl radical free radical etc.) to the lethal effect of bacterium, the electrical breakdown effect of electric field cell membrane, electric osmose and electrophoretic action, the adsorption and oxidation performance of electrode pair cell and effect of electric current pair cell or the like comprehensive action of pair cell metabolic function, reach potent germ-resistant purpose jointly.Especially electrochemical lasting bactericidal potency shows than ozone and the stronger sterilizing ability of ultraviolet ray.Another advantage that electrochemical sterilization contrasts other method for disinfection is nontoxic pair of effect, can not cause secondary pollution.
Summary of the invention
Technical problem to be solved by this invention provides a kind of water dispenser with sterilizing function, and it can realize potent sterilization constantly at any time, and has no side effect safety and sanitation.
Another technical problem to be solved by this invention provides a kind of method for disinfection with water dispenser of sterilizing function.
For solving the problems of the technologies described above, the present invention adopts following technical proposals: a kind of water dispenser with sterilizing function, comprise clever mouth of pegging graft and the drowning seat that fastens with clever mouth with the bottled water water outlet, be provided with electrolysis unit in described drowning seat, this electrolysis unit is connected with controllable electric power by the lead that penetrates the seat that falls into water.
Described electrolysis unit is the titanium plate of a pair of surface-coated inert metal, or the titanium plate of a pair of surface-coated inert metal and be arranged at high temperature resistant ionic membrane between the two titanium plates.Chemical reaction does not take place in the titanium plate electrode of described surface-coated inert metal under general power on condition.
Described controllable electric power is the dc pulse generator or the potentiostat of variable frequency control.
The spacing of described ionic membrane and two titanium plates all is 4-10mm.
The dc pulse generator peak level scope of described variable frequency control is the 30-200 volt, and peak currents range is the 5-80 milliampere; The voltage range of described potentiostat is the 5-30 volt, and range of current is the 10-100 milliampere.
A kind of method for disinfection with water dispenser of sterilizing function is:
Water source on the water dispenser is selected commercially available drummed pure water or commercially available barreled mineral water for use, allowing water pass through clever mouth flows in the seat that falls into water, open controllable electric power, electrolysis unit is switched on, the peak voltage ranges of controllable electric power is that 30-200 volt, peak currents range are that 5-80 milliampere or voltage are that 5-30 volt, range of current are the 10-100 milliamperes, be 30 minutes-2 hours conduction time, closes controllable electric power, finishes in the drowning seat of a water dispenser and the sterilization process in the barreled bucket on the water dispenser.The user can repeat above-mentioned method for disinfection as required at any time, to realize continuing sterilization.
The present invention is applied to the electro-chemical water handling principle sterilization of water dispenser, the oxidizing substance that utilizes the electrolytic process generation is to the lethal effect of bacterium, the electrical breakdown effect of electric field cell membrane, electric osmose and electrophoretic action, the adsorption and oxidation performance of electrode pair cell and effect of electric current pair cell or the like comprehensive action of pair cell metabolic function, reach the potent germ-resistant purpose that continues jointly, and have no side effect safety and sanitation.The water dispenser of band sterilizing function of the present invention and method for disinfection thereof except having good sterilization effect, also bring an additional benefit, promptly the pH value of former drummed pure water can be adjusted to pH value by slant acidity and be weakly alkaline, and it is healthy more to meet drinking-water.
Description of drawings
Fig. 1 is a structural representation of the present invention.
Fig. 2 is the embodiment of the invention 2 structural representations.
Fig. 3 is the embodiment of the invention 3 structural representations.
Embodiment
Referring to shown in Figure 1, a kind of water dispenser with sterilizing function, comprise clever mouth 1 of pegging graft with the bottled water water outlet and the drowning seat 2 that fastens with clever mouth 1, be provided with electrolysis unit 3 in described drowning seat 2, this electrolysis unit 3 is connected with controllable electric power 4 by the lead that penetrates the seat 2 that falls into water.
The titanium plate 31 that described electrolysis unit 3 is a pair of surface-coated inert metals, described controllable electric power 4 are dc pulse generators of variable frequency control.
The dc pulse generator peak level of described variable frequency control is 150 volts, and electric current is 10 milliamperes.
A kind of method for disinfection with water dispenser of sterilizing function is:
Water source on the water dispenser is commercially available drummed pure water, allowing water pass through clever mouth 1 flows in the seat 2 that falls into water, open the dc pulse generator of variable frequency control, titanium plate 31 energisings to a pair of surface-coated inert metal, the crest voltage of the dc pulse generator of variable frequency control is that 150 volts, electric current are 10 milliamperes, be 1 hour conduction time, closes the dc pulse generator of variable frequency control, finishes in the drowning seat of water dispenser and the sterilization process in the barreled bucket on the water dispenser.
Bacterial count contrast experiment in water dispenser and the bottled water before and after the electrolytic sterilizing:
Bacterium mark-on to 5.0 * 10 in commercially available drummed pure water
5Individual/ml, to fetch water from the water dispenser dewatering outlet after 1 hour according to the method electrolysis of embodiment 1, bacteria tested adds up to 8.
Of particular note, for drummed pure water, its specific conductivity of national Specification should be less than 10 μ S/cm.According to general thinking, during very little and even 0 μ S/cm, electrolyzer can't be worked when electrical conductivity of water.And in fact, when inter-electrode voltage reached certain value, the molecular linkage of water was opened, H
2O → H
++ OH
-, electrical conductivity of water risen gradually and conduct electricity.Repeatedly practise proof, even specific conductivity is zero drummed pure water, when adding DC electrode voltage (specifically become greater than certain value because of the battery lead plate spacing, in this example, the two-plate spacing is 80mm, middle no film, voltage is greater than 30 volts) more than, can measure Faradaic current from zero extremely tens of milliamperes slow increase.
Referring to shown in Figure 2, a kind of water dispenser with sterilizing function, comprise clever mouth 1 of pegging graft with the bottled water water outlet and the drowning seat 2 that fastens with clever mouth 1, be provided with electrolysis unit 3 in described drowning seat 2, this electrolysis unit 3 is connected with controllable electric power 4 by the lead that penetrates the seat 2 that falls into water.
The titanium plate 31 that described electrolysis unit 3 is a pair of surface-coated inert metals and be arranged at high temperature resistant (80 degrees centigrade) ionic membrane 32 between the two titanium plates 31, described two titanium plates 31 and ionic membrane 32 therebetween vertically are arranged in the seat 2 that falls into water, and described controllable electric power 4 is dc pulse generators of variable frequency control.
The spacing of described ionic membrane 32 and two titanium plates 31 all is 5mm.
The dc pulse generator peak level of described variable frequency control is 175 volts, and electric current is 80 milliamperes.
A kind of method for disinfection with water dispenser of sterilizing function is:
Water source on the water dispenser is commercially available drummed pure water, allowing water pass through clever mouth 1 flows in the seat 2 that falls into water, open the dc pulse generator of variable frequency control, to 31 energisings of two titanium plates, the crest voltage of the dc pulse generator of variable frequency control is that 175 volts, electric current are 80 milliamperes, be 1 hour conduction time, closes the dc pulse generator of variable frequency control, finishes in the drowning seat of water dispenser and the sterilization process in the barreled bucket on the water dispenser.
Bacterial count contrast experiment in water dispenser and the bottled water before and after the electrolytic sterilizing:
Experimental prototype send environment center, Nanjing measuring station to detect, and source water is commercially available drummed pure water.Analyze foundation: the mensuration of total plate count in " water and effluent monitoring analytical procedure " the 4th edition water.Bacterium mark-on to 1.3 * 10 in commercially available drummed pure water
5Individual/ml, to fetch water from water dispenser after 1 hour according to the method electrolysis of embodiment 2, bacteria tested adds up to 28, sterilization rate 99.98%.(examining report of enclosing)
Annotate: in the examining report of enclosing with application, the 1# machine be this experimental prototype, and the 2# machine is the self-control ozonizer sterilization model machine than testing of opposing.
Referring to shown in Figure 3, a kind of water dispenser with sterilizing function, comprise clever mouth 1 of pegging graft with the bottled water water outlet and the drowning seat 2 that fastens with clever mouth 1, be provided with electrolysis unit 3 in described drowning seat 2, this electrolysis unit 3 is connected with controllable electric power 4 by the lead that penetrates the seat 2 that falls into water.
The titanium plate 31 that described electrolysis unit 3 is a pair of surface-coated inert metals and be arranged at high temperature resistant ionic membrane 32 between the two titanium plates 31, described two titanium plates 31 and 32 oblique seat 2 middle parts of falling into water that are arranged at of ionic membrane therebetween, described controllable electric power 4 is potentiostats.
The spacing of described ionic membrane and two titanium plates all is 5mm.
The level of described potentiostat is 30 volts, and range of current is 80 milliamperes.
A kind of method for disinfection with water dispenser of sterilizing function is:
Water source on the water dispenser is commercially available barreled mineral water, allowing water pass through clever mouth 1 flows in the seat 2 that falls into water, open potentiostat, to 31 energisings of two titanium plates, the voltage of potentiostat is that 30 volts, electric current are 80 milliamperes, be 1 hour conduction time, closes potentiostat, finishes in the drowning seat of water dispenser and the sterilization process in the barreled bucket on the water dispenser.
Bacterial count contrast experiment in water dispenser and the bottled water before and after the electrolytic sterilizing:
Source water is commercially available barreled mineral water.Bacterium mark-on to 9.8 * 10 in commercially available barreled mineral water
5Individual/ml, to fetch water from water dispenser after 1 hour according to the method electrolysis of embodiment 3, bacteria tested adds up to 7, sterilization rate 99.99%.In addition, get 10 glasss of water (every glass of about 180ml) continuously from the dewatering outlet, test pH value variation range is 8.4-7.6, the redox potential variation range be-247mv extremely-186mv.
For antibacterial, the sterilizing ability of the water dispenser of estimating band sterilizing function of the present invention under user's actual service conditions, adopt embodiment 2, the water dispenser model machine of band sterilizing function shown in Figure 2, carried out following simulation test:
Commercially available bottled water (for Beijing Tian Yuanshan board drummed pure water) being placed and (disconnects power supply) on the water dispenser that disinfection equipment is housed, after water outlet is emitted about 1L water whole device was left standstill 2 days, is 19000/mL in water outlet water receiving test total number of bacterial colony.Open electrolytic sterilizing then.Later on the same time water receiving of every day carries out same test, and in one day the repeatedly irregular water (the water intaking total amount of every day remains on about 2L) of getting random amount, so operation was carried out 7 days.Reject operate miss, bacterium colony group number average value is 25/mL.Test-results shows that disinfection equipment water dispenser of the present invention has reasonable lasting germicidal action really.
The foregoing description is except having good sterilization effect, and pH value transfers weakly alkaline to by the slant acidity of former bottled water, and redox potential is negative value, when discharging water continuously, with the fluctuation variation range minimum of embodiment 3.Simultaneously, the molecular grouping of water diminishes, and oil and infusion of tea are all shown good emulsifying power and solvency power.Water quality mouthfeel after electrolytic sterilizing is handled is better, does not all have any peculiar smell.
As mentioned above, a kind of water dispenser and method for disinfection thereof of the present invention with sterilizing function, be the electrochemistry sewage water treatment method to be migrated be applied to the sterilization of water dispenser on the way, described embodiment and figure, it is the present invention's implementation result preferably, be not to be confined to the present invention, a kind of water dispenser with sterilizing function, can also realize like this, comprise clever mouth of pegging graft and the drowning seat that fastens with clever mouth with the bottled water water outlet, the place is equipped with small-sized device for electrochemical water preparation at described drowning seat rising pipe, this installs an end and connects faucet and/or water dispenser heating courage, and described small-sized device for electrochemical water preparation is connected (accompanying drawing is not provided) by lead with controllable electric power.
In the electrolytic sterilizing process of reality of the present invention, the position factors that the kind of dc electrolysis voltage range and waveform, current density, PH, reaction times, electrode materials and shape, bottled water (pure water or mineral water), electrolysis unit have film or do not have film and place in water dispenser, all sterilization effect is influenced to some extent, and then can derive from the various contrive equipments of optimization at various application scenarios in of the present invention containing down, both can be applicable in the process for sterilizing of bottled water or bottled water production.
Claims (7)
1. water dispenser with sterilizing function, comprise clever mouth of pegging graft and the drowning seat that fastens with clever mouth with the bottled water water outlet, it is characterized in that: be provided with electrolysis unit in the described drowning seat, this electrolysis unit is connected with controllable electric power by the lead that penetrates the seat that falls into water.
2. a kind of water dispenser with sterilizing function according to claim 1 is characterized in that: described electrolysis unit is the titanium plate of a pair of surface-coated inert metal.
3. a kind of water dispenser with sterilizing function according to claim 1 is characterized in that: described electrolysis unit is the titanium plate of a pair of surface-coated inert metal and is arranged at high temperature resistant ionic membrane between the two titanium plates.
4. a kind of water dispenser with sterilizing function according to claim 1 is characterized in that: described controllable electric power is the dc pulse generator or the potentiostat of variable frequency control.
5. a kind of water dispenser with sterilizing function according to claim 3 is characterized in that: the spacing of described ionic membrane and two titanium plates all is 4-10mm.
6. a kind of water dispenser with sterilizing function according to claim 4 is characterized in that: the dc pulse generator peak level scope of described variable frequency control is the 30-200 volt, and range of current is the 5-80 milliampere; The level range of described potentiostat is the 5-30 volt, and range of current is the 10-100 milliampere.
7. as each described a kind of method for disinfection of claim 1 to 6 with water dispenser of sterilizing function, it is characterized in that: the water source on the water dispenser is selected commercially available drummed pure water or commercially available barreled mineral water for use, allowing water pass through clever mouth flows in the seat that falls into water, open controllable electric power, electrolysis unit is switched on, the crest voltage of controllable electric power is the 30-200 volt, range of current is that 5-80 milliampere or voltage are the 5-30 volts, range of current is the 10-100 milliampere, be 30 minutes-2 hours conduction time, close controllable electric power, finish in the drowning seat of water dispenser and the sterilization process in the barreled bucket on the water dispenser.
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CN2008102260421A CN101734764B (en) | 2008-11-04 | 2008-11-04 | Water dispenser with sterilizing function and sterilizing method thereof |
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CN101734764B true CN101734764B (en) | 2011-11-23 |
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CN103936109B (en) * | 2014-04-12 | 2016-08-17 | 大连双迪创新科技研究院有限公司 | Drinking-water Electrowinning device |
CN114604942B (en) * | 2022-01-19 | 2024-09-10 | 郭力 | Built-in purifier device that has electrode antibacterial subassembly |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN2339125Y (en) * | 1998-07-23 | 1999-09-22 | 赵莉生 | Disinfecting mouthpiece device for drinking device |
US5993618A (en) * | 1996-12-19 | 1999-11-30 | Dirk Schulze, Wolfgang Beyer Bonn | Device for generating oxygen or a mixture of ozone and oxygen |
CN2829579Y (en) * | 2005-09-30 | 2006-10-25 | 深圳新世纪饮水科技有限公司 | Multifunction activated water cooling/heating drinking machine |
CN201026114Y (en) * | 2006-09-14 | 2008-02-27 | 浙江大学 | Improved electrolytic functional water dispenser |
CN201313837Y (en) * | 2008-12-17 | 2009-09-23 | 肖志邦 | Water fountain with sterilization function |
-
2008
- 2008-11-04 CN CN2008102260421A patent/CN101734764B/en not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5993618A (en) * | 1996-12-19 | 1999-11-30 | Dirk Schulze, Wolfgang Beyer Bonn | Device for generating oxygen or a mixture of ozone and oxygen |
CN2339125Y (en) * | 1998-07-23 | 1999-09-22 | 赵莉生 | Disinfecting mouthpiece device for drinking device |
CN2829579Y (en) * | 2005-09-30 | 2006-10-25 | 深圳新世纪饮水科技有限公司 | Multifunction activated water cooling/heating drinking machine |
CN201026114Y (en) * | 2006-09-14 | 2008-02-27 | 浙江大学 | Improved electrolytic functional water dispenser |
CN201313837Y (en) * | 2008-12-17 | 2009-09-23 | 肖志邦 | Water fountain with sterilization function |
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