CN101708883B - A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water - Google Patents
A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water Download PDFInfo
- Publication number
- CN101708883B CN101708883B CN200910073449XA CN200910073449A CN101708883B CN 101708883 B CN101708883 B CN 101708883B CN 200910073449X A CN200910073449X A CN 200910073449XA CN 200910073449 A CN200910073449 A CN 200910073449A CN 101708883 B CN101708883 B CN 101708883B
- Authority
- CN
- China
- Prior art keywords
- water
- halogenated organic
- light
- organic matters
- potassium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 128
- 238000005695 dehalogenation reaction Methods 0.000 title claims abstract description 67
- 150000001875 compounds Chemical class 0.000 title claims abstract description 61
- 238000000034 method Methods 0.000 title claims abstract description 58
- 239000005416 organic matter Substances 0.000 title claims description 12
- 239000003795 chemical substances by application Substances 0.000 title claims 9
- 230000008878 coupling Effects 0.000 title description 11
- 238000010168 coupling process Methods 0.000 title description 11
- 238000005859 coupling reaction Methods 0.000 title description 11
- 239000003814 drug Substances 0.000 claims abstract 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 18
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 18
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 18
- -1 halogenated aromatic carboxylic acids Chemical class 0.000 claims description 16
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims description 14
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 claims description 14
- 229910052753 mercury Inorganic materials 0.000 claims description 14
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 13
- NBBJYMSMWIIQGU-UHFFFAOYSA-N Propionic aldehyde Chemical compound CCC=O NBBJYMSMWIIQGU-UHFFFAOYSA-N 0.000 claims description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 12
- 238000005273 aeration Methods 0.000 claims description 11
- WTDHULULXKLSOZ-UHFFFAOYSA-N Hydroxylamine hydrochloride Chemical compound Cl.ON WTDHULULXKLSOZ-UHFFFAOYSA-N 0.000 claims description 10
- 229910052736 halogen Inorganic materials 0.000 claims description 10
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims description 9
- 150000002367 halogens Chemical class 0.000 claims description 9
- GEHJYWRUCIMESM-UHFFFAOYSA-L sodium sulfite Chemical compound [Na+].[Na+].[O-]S([O-])=O GEHJYWRUCIMESM-UHFFFAOYSA-L 0.000 claims description 9
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 8
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 7
- 239000011591 potassium Substances 0.000 claims description 7
- 229910052700 potassium Inorganic materials 0.000 claims description 7
- 229910002651 NO3 Inorganic materials 0.000 claims description 6
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 claims description 6
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N butyric aldehyde Natural products CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 claims description 6
- IRXRGVFLQOSHOH-UHFFFAOYSA-L dipotassium;oxalate Chemical compound [K+].[K+].[O-]C(=O)C([O-])=O IRXRGVFLQOSHOH-UHFFFAOYSA-L 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 5
- DPLVEEXVKBWGHE-UHFFFAOYSA-N potassium sulfide Chemical compound [S-2].[K+].[K+] DPLVEEXVKBWGHE-UHFFFAOYSA-N 0.000 claims description 5
- 229920001174 Diethylhydroxylamine Polymers 0.000 claims description 4
- LSNNMFCWUKXFEE-UHFFFAOYSA-N Sulfurous acid Chemical compound OS(O)=O LSNNMFCWUKXFEE-UHFFFAOYSA-N 0.000 claims description 4
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 4
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 claims description 4
- NMCUIPGRVMDVDB-UHFFFAOYSA-L iron dichloride Chemical compound Cl[Fe]Cl NMCUIPGRVMDVDB-UHFFFAOYSA-L 0.000 claims description 4
- SQQMAOCOWKFBNP-UHFFFAOYSA-L manganese(II) sulfate Chemical compound [Mn+2].[O-]S([O-])(=O)=O SQQMAOCOWKFBNP-UHFFFAOYSA-L 0.000 claims description 4
- 239000012286 potassium permanganate Substances 0.000 claims description 4
- UMPKMCDVBZFQOK-UHFFFAOYSA-N potassium;iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[K+].[Fe+3] UMPKMCDVBZFQOK-UHFFFAOYSA-N 0.000 claims description 4
- JVBXVOWTABLYPX-UHFFFAOYSA-L sodium dithionite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])=O JVBXVOWTABLYPX-UHFFFAOYSA-L 0.000 claims description 4
- 235000011121 sodium hydroxide Nutrition 0.000 claims description 4
- 229910000497 Amalgam Inorganic materials 0.000 claims description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 claims description 3
- 235000010265 sodium sulphite Nutrition 0.000 claims description 3
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 claims description 2
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 2
- 229910052724 xenon Inorganic materials 0.000 claims description 2
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 claims description 2
- QIGBRXMKCJKVMJ-UHFFFAOYSA-N Hydroquinone Chemical compound OC1=CC=C(O)C=C1 QIGBRXMKCJKVMJ-UHFFFAOYSA-N 0.000 claims 2
- 239000002131 composite material Substances 0.000 claims 2
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Chemical compound O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 claims 2
- XXMBEHIWODXDTR-UHFFFAOYSA-N 1,2-diaminoethanol Chemical compound NCC(N)O XXMBEHIWODXDTR-UHFFFAOYSA-N 0.000 claims 1
- 229910021578 Iron(III) chloride Inorganic materials 0.000 claims 1
- FVCOIAYSJZGECG-UHFFFAOYSA-N diethylhydroxylamine Chemical compound CCN(O)CC FVCOIAYSJZGECG-UHFFFAOYSA-N 0.000 claims 1
- 229960002089 ferrous chloride Drugs 0.000 claims 1
- 239000003864 humus Substances 0.000 claims 1
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims 1
- 229940099596 manganese sulfate Drugs 0.000 claims 1
- 239000011702 manganese sulphate Substances 0.000 claims 1
- 235000007079 manganese sulphate Nutrition 0.000 claims 1
- CRPBAQAXWCOQOC-UHFFFAOYSA-L manganese(2+);dichlorate Chemical compound [Mn+2].[O-]Cl(=O)=O.[O-]Cl(=O)=O CRPBAQAXWCOQOC-UHFFFAOYSA-L 0.000 claims 1
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims 1
- 150000007524 organic acids Chemical class 0.000 claims 1
- 235000005985 organic acids Nutrition 0.000 claims 1
- 150000002989 phenols Chemical class 0.000 claims 1
- 239000001103 potassium chloride Substances 0.000 claims 1
- 235000011164 potassium chloride Nutrition 0.000 claims 1
- 230000003647 oxidation Effects 0.000 abstract description 14
- 238000007254 oxidation reaction Methods 0.000 abstract description 14
- 238000003756 stirring Methods 0.000 abstract description 8
- 230000005855 radiation Effects 0.000 abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 6
- 238000001179 sorption measurement Methods 0.000 abstract description 6
- 239000003054 catalyst Substances 0.000 abstract description 4
- 230000008569 process Effects 0.000 abstract description 4
- 229910052723 transition metal Inorganic materials 0.000 abstract description 4
- 150000003624 transition metals Chemical class 0.000 abstract description 4
- 238000013461 design Methods 0.000 abstract description 3
- 230000001737 promoting effect Effects 0.000 abstract 2
- 230000004888 barrier function Effects 0.000 abstract 1
- 238000010531 catalytic reduction reaction Methods 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 230000003287 optical effect Effects 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 230000000694 effects Effects 0.000 description 28
- 239000002253 acid Substances 0.000 description 21
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 14
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 14
- 230000015556 catabolic process Effects 0.000 description 14
- 238000006731 degradation reaction Methods 0.000 description 14
- 239000007789 gas Substances 0.000 description 14
- 125000005843 halogen group Chemical group 0.000 description 14
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 13
- 229960001701 chloroform Drugs 0.000 description 13
- IZUPBVBPLAPZRR-UHFFFAOYSA-N pentachlorophenol Chemical compound OC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl IZUPBVBPLAPZRR-UHFFFAOYSA-N 0.000 description 13
- 230000009471 action Effects 0.000 description 11
- 238000005516 engineering process Methods 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 10
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 9
- 229910052760 oxygen Inorganic materials 0.000 description 9
- 239000001301 oxygen Substances 0.000 description 9
- 150000003254 radicals Chemical class 0.000 description 9
- 229910052757 nitrogen Inorganic materials 0.000 description 8
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 8
- 239000000463 material Substances 0.000 description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N monobenzene Natural products C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 7
- 238000006722 reduction reaction Methods 0.000 description 7
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- 230000009467 reduction Effects 0.000 description 6
- 239000011734 sodium Substances 0.000 description 6
- 229910052708 sodium Inorganic materials 0.000 description 6
- FVAUCKIRQBBSSJ-UHFFFAOYSA-M sodium iodide Chemical compound [Na+].[I-] FVAUCKIRQBBSSJ-UHFFFAOYSA-M 0.000 description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Substances [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 description 6
- 230000003197 catalytic effect Effects 0.000 description 5
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 239000002689 soil Substances 0.000 description 5
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 4
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 4
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 4
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 4
- OAKJQQAXSVQMHS-UHFFFAOYSA-N Hydrazine Chemical compound NN OAKJQQAXSVQMHS-UHFFFAOYSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 4
- DTQVDTLACAAQTR-UHFFFAOYSA-N Trifluoroacetic acid Chemical compound OC(=O)C(F)(F)F DTQVDTLACAAQTR-UHFFFAOYSA-N 0.000 description 4
- QARVLSVVCXYDNA-UHFFFAOYSA-N bromobenzene Chemical compound BrC1=CC=CC=C1 QARVLSVVCXYDNA-UHFFFAOYSA-N 0.000 description 4
- 229910052799 carbon Inorganic materials 0.000 description 4
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical class OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 description 4
- FGRVOLIFQGXPCT-UHFFFAOYSA-L dipotassium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [K+].[K+].[O-]S([O-])(=O)=S FGRVOLIFQGXPCT-UHFFFAOYSA-L 0.000 description 4
- 238000009472 formulation Methods 0.000 description 4
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 4
- 235000006408 oxalic acid Nutrition 0.000 description 4
- SCVFZCLFOSHCOH-UHFFFAOYSA-M potassium acetate Chemical compound [K+].CC([O-])=O SCVFZCLFOSHCOH-UHFFFAOYSA-M 0.000 description 4
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 4
- 235000019394 potassium persulphate Nutrition 0.000 description 4
- 229910000160 potassium phosphate Inorganic materials 0.000 description 4
- 229940093916 potassium phosphate Drugs 0.000 description 4
- 235000011009 potassium phosphates Nutrition 0.000 description 4
- 238000012545 processing Methods 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- 231100000419 toxicity Toxicity 0.000 description 4
- 230000001988 toxicity Effects 0.000 description 4
- 230000007704 transition Effects 0.000 description 4
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 3
- HLHNOIAOWQFNGW-UHFFFAOYSA-N 3-bromo-4-hydroxybenzonitrile Chemical compound OC1=CC=C(C#N)C=C1Br HLHNOIAOWQFNGW-UHFFFAOYSA-N 0.000 description 3
- XRHGYUZYPHTUJZ-UHFFFAOYSA-N 4-chlorobenzoic acid Chemical compound OC(=O)C1=CC=C(Cl)C=C1 XRHGYUZYPHTUJZ-UHFFFAOYSA-N 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- NOMICGATVHRDNY-UHFFFAOYSA-N [Mn].Cl(=O)(=O)O Chemical compound [Mn].Cl(=O)(=O)O NOMICGATVHRDNY-UHFFFAOYSA-N 0.000 description 3
- 238000009303 advanced oxidation process reaction Methods 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- ZUOUZKKEUPVFJK-UHFFFAOYSA-N diphenyl Chemical group C1=CC=CC=C1C1=CC=CC=C1 ZUOUZKKEUPVFJK-UHFFFAOYSA-N 0.000 description 3
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical class C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 3
- 230000005518 electrochemistry Effects 0.000 description 3
- 239000003673 groundwater Substances 0.000 description 3
- 230000008595 infiltration Effects 0.000 description 3
- 238000001764 infiltration Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- WPBNNNQJVZRUHP-UHFFFAOYSA-L manganese(2+);methyl n-[[2-(methoxycarbonylcarbamothioylamino)phenyl]carbamothioyl]carbamate;n-[2-(sulfidocarbothioylamino)ethyl]carbamodithioate Chemical compound [Mn+2].[S-]C(=S)NCCNC([S-])=S.COC(=O)NC(=S)NC1=CC=CC=C1NC(=S)NC(=O)OC WPBNNNQJVZRUHP-UHFFFAOYSA-L 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000008929 regeneration Effects 0.000 description 3
- 238000011069 regeneration method Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 238000012546 transfer Methods 0.000 description 3
- QPFMBZIOSGYJDE-UHFFFAOYSA-N 1,1,2,2-tetrachloroethane Chemical compound ClC(Cl)C(Cl)Cl QPFMBZIOSGYJDE-UHFFFAOYSA-N 0.000 description 2
- VGVRPFIJEJYOFN-UHFFFAOYSA-N 2,3,4,6-tetrachlorophenol Chemical class OC1=C(Cl)C=C(Cl)C(Cl)=C1Cl VGVRPFIJEJYOFN-UHFFFAOYSA-N 0.000 description 2
- LCPVQAHEFVXVKT-UHFFFAOYSA-N 2-(2,4-difluorophenoxy)pyridin-3-amine Chemical compound NC1=CC=CN=C1OC1=CC=C(F)C=C1F LCPVQAHEFVXVKT-UHFFFAOYSA-N 0.000 description 2
- XZXYQEHISUMZAT-UHFFFAOYSA-N 2-[(2-hydroxy-5-methylphenyl)methyl]-4-methylphenol Chemical compound CC1=CC=C(O)C(CC=2C(=CC=C(C)C=2)O)=C1 XZXYQEHISUMZAT-UHFFFAOYSA-N 0.000 description 2
- JYLNVJYYQQXNEK-UHFFFAOYSA-N 3-amino-2-(4-chlorophenyl)-1-propanesulfonic acid Chemical compound OS(=O)(=O)CC(CN)C1=CC=C(Cl)C=C1 JYLNVJYYQQXNEK-UHFFFAOYSA-N 0.000 description 2
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 2
- OQVYMXCRDHDTTH-UHFFFAOYSA-N 4-(diethoxyphosphorylmethyl)-2-[4-(diethoxyphosphorylmethyl)pyridin-2-yl]pyridine Chemical compound CCOP(=O)(OCC)CC1=CC=NC(C=2N=CC=C(CP(=O)(OCC)OCC)C=2)=C1 OQVYMXCRDHDTTH-UHFFFAOYSA-N 0.000 description 2
- CZGCEKJOLUNIFY-UHFFFAOYSA-N 4-Chloronitrobenzene Chemical compound [O-][N+](=O)C1=CC=C(Cl)C=C1 CZGCEKJOLUNIFY-UHFFFAOYSA-N 0.000 description 2
- 239000004160 Ammonium persulphate Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-DUZGATOHSA-N D-isoascorbic acid Chemical compound OC[C@@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-DUZGATOHSA-N 0.000 description 2
- PQUCIEFHOVEZAU-UHFFFAOYSA-N Diammonium sulfite Chemical compound [NH4+].[NH4+].[O-]S([O-])=O PQUCIEFHOVEZAU-UHFFFAOYSA-N 0.000 description 2
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 2
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 2
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004159 Potassium persulphate Substances 0.000 description 2
- JCSRLZBFDUWIPN-UHFFFAOYSA-L S(=O)([O-])S(=O)[O-].[Na+].[Li+] Chemical compound S(=O)([O-])S(=O)[O-].[Na+].[Li+] JCSRLZBFDUWIPN-UHFFFAOYSA-L 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- VMHLLURERBWHNL-UHFFFAOYSA-M Sodium acetate Chemical compound [Na+].CC([O-])=O VMHLLURERBWHNL-UHFFFAOYSA-M 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 2
- JDZJVWAHZYIHFA-UHFFFAOYSA-N [Br].C1(=CC=CC=C1)O Chemical compound [Br].C1(=CC=CC=C1)O JDZJVWAHZYIHFA-UHFFFAOYSA-N 0.000 description 2
- YCINVKSCIBUTNF-UHFFFAOYSA-N [Mn].N(=O)O Chemical compound [Mn].N(=O)O YCINVKSCIBUTNF-UHFFFAOYSA-N 0.000 description 2
- DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 2
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 2
- 229940107816 ammonium iodide Drugs 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- 235000019395 ammonium persulphate Nutrition 0.000 description 2
- UYJXRRSPUVSSMN-UHFFFAOYSA-P ammonium sulfide Chemical compound [NH4+].[NH4+].[S-2] UYJXRRSPUVSSMN-UHFFFAOYSA-P 0.000 description 2
- XYXNTHIYBIDHGM-UHFFFAOYSA-N ammonium thiosulfate Chemical compound [NH4+].[NH4+].[O-]S([O-])(=O)=S XYXNTHIYBIDHGM-UHFFFAOYSA-N 0.000 description 2
- 229910052786 argon Inorganic materials 0.000 description 2
- UAZDIGCOBKKMPU-UHFFFAOYSA-O azanium;azide Chemical compound [NH4+].[N-]=[N+]=[N-] UAZDIGCOBKKMPU-UHFFFAOYSA-O 0.000 description 2
- GZUXJHMPEANEGY-UHFFFAOYSA-N bromomethane Chemical compound BrC GZUXJHMPEANEGY-UHFFFAOYSA-N 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- GBAOBIBJACZTNA-UHFFFAOYSA-L calcium sulfite Chemical compound [Ca+2].[O-]S([O-])=O GBAOBIBJACZTNA-UHFFFAOYSA-L 0.000 description 2
- 235000010261 calcium sulphite Nutrition 0.000 description 2
- FAYYUXPSKDFLEC-UHFFFAOYSA-L calcium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane Chemical compound [Ca+2].[O-]S([O-])(=O)=S FAYYUXPSKDFLEC-UHFFFAOYSA-L 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 238000006298 dechlorination reaction Methods 0.000 description 2
- 229910003460 diamond Inorganic materials 0.000 description 2
- 239000010432 diamond Substances 0.000 description 2
- JXTHNDFMNIQAHM-UHFFFAOYSA-N dichloroacetic acid Chemical compound OC(=O)C(Cl)Cl JXTHNDFMNIQAHM-UHFFFAOYSA-N 0.000 description 2
- BBLSYMNDKUHQAG-UHFFFAOYSA-L dilithium;sulfite Chemical compound [Li+].[Li+].[O-]S([O-])=O BBLSYMNDKUHQAG-UHFFFAOYSA-L 0.000 description 2
- ZPWVASYFFYYZEW-UHFFFAOYSA-L dipotassium hydrogen phosphate Chemical compound [K+].[K+].OP([O-])([O-])=O ZPWVASYFFYYZEW-UHFFFAOYSA-L 0.000 description 2
- BNBLBRISEAQIHU-UHFFFAOYSA-N disodium dioxido(dioxo)manganese Chemical compound [Na+].[Na+].[O-][Mn]([O-])(=O)=O BNBLBRISEAQIHU-UHFFFAOYSA-N 0.000 description 2
- BNIILDVGGAEEIG-UHFFFAOYSA-L disodium hydrogen phosphate Chemical compound [Na+].[Na+].OP([O-])([O-])=O BNIILDVGGAEEIG-UHFFFAOYSA-L 0.000 description 2
- 229910000397 disodium phosphate Inorganic materials 0.000 description 2
- 235000019800 disodium phosphate Nutrition 0.000 description 2
- PCAXGMRPPOMODZ-UHFFFAOYSA-N disulfurous acid, diammonium salt Chemical compound [NH4+].[NH4+].[O-]S(=O)S([O-])(=O)=O PCAXGMRPPOMODZ-UHFFFAOYSA-N 0.000 description 2
- 239000000598 endocrine disruptor Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 239000003344 environmental pollutant Substances 0.000 description 2
- VEPSWGHMGZQCIN-UHFFFAOYSA-H ferric oxalate Chemical compound [Fe+3].[Fe+3].[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O.[O-]C(=O)C([O-])=O VEPSWGHMGZQCIN-UHFFFAOYSA-H 0.000 description 2
- 239000011790 ferrous sulphate Substances 0.000 description 2
- 235000003891 ferrous sulphate Nutrition 0.000 description 2
- 235000019253 formic acid Nutrition 0.000 description 2
- CKAPSXZOOQJIBF-UHFFFAOYSA-N hexachlorobenzene Chemical compound ClC1=C(Cl)C(Cl)=C(Cl)C(Cl)=C1Cl CKAPSXZOOQJIBF-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- WQYVRQLZKVEZGA-UHFFFAOYSA-N hypochlorite Chemical compound Cl[O-] WQYVRQLZKVEZGA-UHFFFAOYSA-N 0.000 description 2
- 238000007654 immersion Methods 0.000 description 2
- 239000013067 intermediate product Substances 0.000 description 2
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 2
- LDHBWEYLDHLIBQ-UHFFFAOYSA-M iron(3+);oxygen(2-);hydroxide;hydrate Chemical compound O.[OH-].[O-2].[Fe+3] LDHBWEYLDHLIBQ-UHFFFAOYSA-M 0.000 description 2
- 229910000359 iron(II) sulfate Inorganic materials 0.000 description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 description 2
- GKLAGQWSCNXXKN-UHFFFAOYSA-N iron;nitrous acid Chemical compound [Fe].ON=O GKLAGQWSCNXXKN-UHFFFAOYSA-N 0.000 description 2
- 229910052744 lithium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- BLQJIBCZHWBKSL-UHFFFAOYSA-L magnesium iodide Chemical compound [Mg+2].[I-].[I-] BLQJIBCZHWBKSL-UHFFFAOYSA-L 0.000 description 2
- 229910001641 magnesium iodide Inorganic materials 0.000 description 2
- CQDMJJVHDPDPHO-UHFFFAOYSA-L magnesium;dioxido-oxo-sulfanylidene-$l^{6}-sulfane;hexahydrate Chemical compound O.O.O.O.O.O.[Mg+2].[O-]S([O-])(=O)=S CQDMJJVHDPDPHO-UHFFFAOYSA-L 0.000 description 2
- JESHZQPNPCJVNG-UHFFFAOYSA-L magnesium;sulfite Chemical compound [Mg+2].[O-]S([O-])=O JESHZQPNPCJVNG-UHFFFAOYSA-L 0.000 description 2
- LEEZVNHXYZTEDQ-UHFFFAOYSA-N manganese perchloric acid Chemical compound [Mn].Cl(=O)(=O)(=O)O LEEZVNHXYZTEDQ-UHFFFAOYSA-N 0.000 description 2
- CNFDGXZLMLFIJV-UHFFFAOYSA-L manganese(II) chloride tetrahydrate Chemical compound O.O.O.O.[Cl-].[Cl-].[Mn+2] CNFDGXZLMLFIJV-UHFFFAOYSA-L 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 229940045641 monobasic sodium phosphate Drugs 0.000 description 2
- 229940039748 oxalate Drugs 0.000 description 2
- YFSUTJLHUFNCNZ-UHFFFAOYSA-N perfluorooctane-1-sulfonic acid Chemical compound OS(=O)(=O)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F YFSUTJLHUFNCNZ-UHFFFAOYSA-N 0.000 description 2
- 239000002957 persistent organic pollutant Substances 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 238000001782 photodegradation Methods 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 231100000719 pollutant Toxicity 0.000 description 2
- 235000011056 potassium acetate Nutrition 0.000 description 2
- TZLVRPLSVNESQC-UHFFFAOYSA-N potassium azide Chemical compound [K+].[N-]=[N+]=[N-] TZLVRPLSVNESQC-UHFFFAOYSA-N 0.000 description 2
- WFIZEGIEIOHZCP-UHFFFAOYSA-M potassium formate Chemical compound [K+].[O-]C=O WFIZEGIEIOHZCP-UHFFFAOYSA-M 0.000 description 2
- ZOCLAPYLSUCOGI-UHFFFAOYSA-M potassium hydrosulfide Chemical compound [SH-].[K+] ZOCLAPYLSUCOGI-UHFFFAOYSA-M 0.000 description 2
- 235000007715 potassium iodide Nutrition 0.000 description 2
- 229960004839 potassium iodide Drugs 0.000 description 2
- RWPGFSMJFRPDDP-UHFFFAOYSA-L potassium metabisulfite Chemical compound [K+].[K+].[O-]S(=O)S([O-])(=O)=O RWPGFSMJFRPDDP-UHFFFAOYSA-L 0.000 description 2
- 235000010263 potassium metabisulphite Nutrition 0.000 description 2
- KAQHZJVQFBJKCK-UHFFFAOYSA-L potassium pyrosulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OS([O-])(=O)=O KAQHZJVQFBJKCK-UHFFFAOYSA-L 0.000 description 2
- BHZRJJOHZFYXTO-UHFFFAOYSA-L potassium sulfite Chemical compound [K+].[K+].[O-]S([O-])=O BHZRJJOHZFYXTO-UHFFFAOYSA-L 0.000 description 2
- 235000019252 potassium sulphite Nutrition 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000010865 sewage Substances 0.000 description 2
- 239000001632 sodium acetate Substances 0.000 description 2
- 235000017281 sodium acetate Nutrition 0.000 description 2
- AJPJDKMHJJGVTQ-UHFFFAOYSA-M sodium dihydrogen phosphate Chemical compound [Na+].OP(O)([O-])=O AJPJDKMHJJGVTQ-UHFFFAOYSA-M 0.000 description 2
- HRZFUMHJMZEROT-UHFFFAOYSA-L sodium disulfite Chemical compound [Na+].[Na+].[O-]S(=O)S([O-])(=O)=O HRZFUMHJMZEROT-UHFFFAOYSA-L 0.000 description 2
- HLBBKKJFGFRGMU-UHFFFAOYSA-M sodium formate Chemical compound [Na+].[O-]C=O HLBBKKJFGFRGMU-UHFFFAOYSA-M 0.000 description 2
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 2
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 2
- 235000009518 sodium iodide Nutrition 0.000 description 2
- 235000010262 sodium metabisulphite Nutrition 0.000 description 2
- ZNCPFRVNHGOPAG-UHFFFAOYSA-L sodium oxalate Chemical compound [Na+].[Na+].[O-]C(=O)C([O-])=O ZNCPFRVNHGOPAG-UHFFFAOYSA-L 0.000 description 2
- 229940039790 sodium oxalate Drugs 0.000 description 2
- 239000001488 sodium phosphate Substances 0.000 description 2
- JXAZAUKOWVKTLO-UHFFFAOYSA-L sodium pyrosulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OS([O-])(=O)=O JXAZAUKOWVKTLO-UHFFFAOYSA-L 0.000 description 2
- PODWXQQNRWNDGD-UHFFFAOYSA-L sodium thiosulfate pentahydrate Chemical compound O.O.O.O.O.[Na+].[Na+].[O-]S([S-])(=O)=O PODWXQQNRWNDGD-UHFFFAOYSA-L 0.000 description 2
- 239000008399 tap water Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 2
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 2
- 229910000406 trisodium phosphate Inorganic materials 0.000 description 2
- 235000019801 trisodium phosphate Nutrition 0.000 description 2
- HGBOYTHUEUWSSQ-UHFFFAOYSA-N valeric aldehyde Natural products CCCCC=O HGBOYTHUEUWSSQ-UHFFFAOYSA-N 0.000 description 2
- WSLDOOZREJYCGB-UHFFFAOYSA-N 1,2-Dichloroethane Chemical compound ClCCCl WSLDOOZREJYCGB-UHFFFAOYSA-N 0.000 description 1
- QIONYIKHPASLHO-UHFFFAOYSA-N 2,2,2-tribromoacetic acid Chemical class OC(=O)C(Br)(Br)Br QIONYIKHPASLHO-UHFFFAOYSA-N 0.000 description 1
- 239000003315 2-(4-chlorophenoxy)-2-methylpropanoic acid Substances 0.000 description 1
- SZIFAVKTNFCBPC-UHFFFAOYSA-N 2-chloroethanol Chemical compound OCCCl SZIFAVKTNFCBPC-UHFFFAOYSA-N 0.000 description 1
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 1
- JGZVUTYDEVUNMK-UHFFFAOYSA-N 5-carboxy-2',7'-dichlorofluorescein Chemical compound C12=CC(Cl)=C(O)C=C2OC2=CC(O)=C(Cl)C=C2C21OC(=O)C1=CC(C(=O)O)=CC=C21 JGZVUTYDEVUNMK-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- GCCLXWPKLQNVIT-UHFFFAOYSA-N BrC(C(=O)O)Br.[Cl] Chemical compound BrC(C(=O)O)Br.[Cl] GCCLXWPKLQNVIT-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- 208000031320 Teratogenesis Diseases 0.000 description 1
- 229910010413 TiO 2 Inorganic materials 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 230000001133 acceleration Effects 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000003570 air Substances 0.000 description 1
- 230000005260 alpha ray Effects 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical class OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 230000005250 beta ray Effects 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- 239000012267 brine Substances 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 125000001246 bromo group Chemical group Br* 0.000 description 1
- RDHPKYGYEGBMSE-UHFFFAOYSA-N bromoethane Chemical compound CCBr RDHPKYGYEGBMSE-UHFFFAOYSA-N 0.000 description 1
- JMSRBKPMLUGHCR-UHFFFAOYSA-N bromohydrin Chemical compound BrC[C]1CO1 JMSRBKPMLUGHCR-UHFFFAOYSA-N 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 230000000711 cancerogenic effect Effects 0.000 description 1
- 229910002091 carbon monoxide Inorganic materials 0.000 description 1
- ABDBNWQRPYOPDF-UHFFFAOYSA-N carbonofluoridic acid Chemical compound OC(F)=O ABDBNWQRPYOPDF-UHFFFAOYSA-N 0.000 description 1
- 231100000315 carcinogenic Toxicity 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- WIIZWVCIJKGZOK-RKDXNWHRSA-N chloramphenicol Chemical compound ClC(Cl)C(=O)N[C@H](CO)[C@H](O)C1=CC=C([N+]([O-])=O)C=C1 WIIZWVCIJKGZOK-RKDXNWHRSA-N 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- KYKAJFCTULSVSH-UHFFFAOYSA-N chloro(fluoro)methane Chemical compound F[C]Cl KYKAJFCTULSVSH-UHFFFAOYSA-N 0.000 description 1
- FOCAUTSVDIKZOP-UHFFFAOYSA-N chloroacetic acid Chemical compound OC(=O)CCl FOCAUTSVDIKZOP-UHFFFAOYSA-N 0.000 description 1
- TXCGAZHTZHNUAI-UHFFFAOYSA-N clofibric acid Chemical compound OC(=O)C(C)(C)OC1=CC=C(Cl)C=C1 TXCGAZHTZHNUAI-UHFFFAOYSA-N 0.000 description 1
- 229950008441 clofibric acid Drugs 0.000 description 1
- 230000001112 coagulating effect Effects 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000356 contaminant Substances 0.000 description 1
- 238000006392 deoxygenation reaction Methods 0.000 description 1
- 238000001784 detoxification Methods 0.000 description 1
- 229960005215 dichloroacetic acid Drugs 0.000 description 1
- DCOPUUMXTXDBNB-UHFFFAOYSA-N diclofenac Chemical compound OC(=O)CC1=CC=CC=C1NC1=C(Cl)C=CC=C1Cl DCOPUUMXTXDBNB-UHFFFAOYSA-N 0.000 description 1
- 229960001259 diclofenac Drugs 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000007337 electrophilic addition reaction Methods 0.000 description 1
- 238000007336 electrophilic substitution reaction Methods 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- UHCBBWUQDAVSMS-UHFFFAOYSA-N fluoroethane Chemical compound CCF UHCBBWUQDAVSMS-UHFFFAOYSA-N 0.000 description 1
- 125000000524 functional group Chemical group 0.000 description 1
- 238000005911 haloform reaction Methods 0.000 description 1
- 150000003944 halohydrins Chemical class 0.000 description 1
- 229910052734 helium Inorganic materials 0.000 description 1
- 239000001307 helium Substances 0.000 description 1
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000001939 inductive effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 229910052740 iodine Inorganic materials 0.000 description 1
- 239000011630 iodine Substances 0.000 description 1
- 125000002346 iodo group Chemical group I* 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 238000005374 membrane filtration Methods 0.000 description 1
- 229940102396 methyl bromide Drugs 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 231100000219 mutagenic Toxicity 0.000 description 1
- 230000003505 mutagenic effect Effects 0.000 description 1
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 description 1
- LQNUZADURLCDLV-UHFFFAOYSA-N nitrobenzene Chemical compound [O-][N+](=O)C1=CC=CC=C1 LQNUZADURLCDLV-UHFFFAOYSA-N 0.000 description 1
- 239000001272 nitrous oxide Substances 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 231100000956 nontoxicity Toxicity 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- 239000012476 oxidizable substance Substances 0.000 description 1
- 229940049547 paraxin Drugs 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 239000003504 photosensitizing agent Substances 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 238000007747 plating Methods 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 125000005575 polycyclic aromatic hydrocarbon group Chemical group 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 239000010970 precious metal Substances 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 230000001172 regenerating effect Effects 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000013535 sea water Substances 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 238000007086 side reaction Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 description 1
- 239000002594 sorbent Substances 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000001954 sterilising effect Effects 0.000 description 1
- 238000004659 sterilization and disinfection Methods 0.000 description 1
- 150000004763 sulfides Chemical class 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
- 230000002588 toxic effect Effects 0.000 description 1
- 239000003053 toxin Substances 0.000 description 1
- 231100000765 toxin Toxicity 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Images
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/30—Wastewater or sewage treatment systems using renewable energies
- Y02W10/37—Wastewater or sewage treatment systems using renewable energies using solar energy
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Physical Water Treatments (AREA)
Abstract
The invention provides a light promoting dehalogenation compound medicament/light combined method for removing halogenated organic matters in water, which relates to a method for removing halogenated organic matters in water. The invention overcomes various defects existing in the process of removing halogenated organic matters in water by using the current gas stripping method, activated carbon adsorption method, electrochemical removing method, advanced oxidation method, transition metal catalytic reduction method, vacuum ultraviolet technique or permeable reactive barrier technique. The method of the invention comprises the following steps: adding the light promoting dehalogenation compound medicament into the water containing halogenated organic matters for stirring, and then, carrying out optical radiation. The method of the invention does not need multi-stage removal, does not need expensive oxidants and catalysts, does not generate secondary pollution, does not need expensive vacuum ultraviolet light sources and high-energy radiation sources, can utilize common and cheap ultraviolet pop light sources or even expanding to visible light sources, improves the utilization efficiency of the light energy, can quickly remove the halogenated organic matters, can conveniently design a reactor, meets the requirements of various water bodies, is convenient in management, and can ensure the safety of the water quality.
Description
Technical field
The present invention relates to a kind of method of removing halogenated organic matters in the water.
Background technology
Halogenated organic matters is meant that 1 of linking to each other with C in the structure in the organism or a plurality of H by the organism that halogen replaces, comprise fluoro, chloro, bromo and iodo organism etc.Common halogenated organic matters has: trifluoroacetic acid, perfluoro octyl sulfonic acid, methylene dichloride, trichloromethane, tetracol phenixin, ethylene dichloride, tetrachloroethane, chloroethanol, Monochloro Acetic Acid, dichloro acetic acid, trichoroacetic acid(TCA), chlorobenzene, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, paraxin, diclofenac, clofibric acid, chlorophenol, Chlorodracylic acid, parachloronitrobenzene, methyl bromide, bromic ether, bromohydrin, tribromoacetic acid, one chlorine dibromoacetic acid, bromobenzene, bromine phenol, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers, iodine alkane, iodohydrin, Schering AG) etc.
It is toxic and natural, ecological is had a pollutent of significant damage to organism that halogenated organic matters is generally considered to be, wherein some halogenated organic matters is confirmed to be teratogenesis, carcinogenic, mutagenic three and causes material, and some is endocrine disrupter (EDCs) and environmental persistence organism (POPs).
Most in the world rivers and lake water have been subjected to the pollution in various degree of halogenated organic matters; Also in various degree the existence that detects halogenated organic matters, particularly offshore area of each big midocean, the part sea pollution is serious; The part underground water of China, the U.S., Canada, Japan and a lot of European countries also has been subjected to the pollution of halogenated organic matters.Because the groundwater environment condition is more special, halogenated organic matters enters body of groundwater and just is difficult to remove.Typical pollutent is as trieline, zellon, Perchlorobenzene, polychlorobiphenyl, halogen acetic acid etc. in the underground water.Show according to environmental surveys widely both at home and abroad, in the wildlife body of occurring in nature in various degree the accumulation that has detected halogenated organic matters also residual, as Perchlorobenzene; Because most of halogenated organic matters has certain volatility, human also being exposed in the environment of halogenated organic matters is as tap water, food, air etc.In indivedual areas, also detected corresponding organism in the human body, as chlorobenzene.
Therefore be necessary very much halogenated organic matters is removed.And conventional treatment process is not fully up to expectations to the removal effect of halogenated organic matters.Through various countries scientist effort for many years, developed the methods of taking out halogenated organic matters in a lot of gradually, removed method, advanced oxidation processes, transition metal-catalyzed reduction method, vacuum ultraviolet (VUV) and high-energy radiation is sent out and reactive infiltration wall technology etc. as gas formulation, active carbon adsorption, electrochemistry.Though the whole bag of tricks can both carry out to a certain degree removal to halogenated organic matters, the whole bag of tricks all has certain drawback, and some method cost is too high and can't large-scale application.
The gas formulation, be wallop when aqueous solution vapour pressure surpasses external pressure when utilizing water vapour by water layer and liquid constantly in bubble the effect of evaporation diffusion make the water treatment procedure that volatile dissolved matter matter is constantly separated in the water from water, be a kind of diffusion process of physics.Its shortcoming is: can only remove some volatile organic matters, deliquescent halogenated organic matters such as trichoroacetic acid(TCA) are not then had removal effect; Secondly, it is lower that this method is removed efficiency ratio for the halogenated organic matters of high density, in order to reach good clearance, needs multistage gas processing, the cost height; In addition, the secondary pollution gas of this method generation also needs further processing.
Active carbon adsorption, be to utilize the duct of gac distribution and huge specific surface area to come absorb polluted matter, it can well remove in the water hydrophobic organic compound of the overwhelming majority, as chlorobenzene etc., but does not remove substantially for the hydrophilic organics hydrophilicity people halogen acetic acid in the water, halohydrin etc.; Next is for the organic matter removal poor effect of the high density in the water; Similar with the gas formulation, active carbon adsorption also produces secondary pollution, need further handle gac; Gac needs regular regeneration to change, and costs an arm and a leg; Water quality water conservancy condition is bigger to its adsorption effect influence, and capacity of resisting impact load is not good, and operation cost is higher.
Electrochemistry is removed method, is to utilize polarization of electrode to produce living radical, the method for the pollutent in direct or indirect oxidation/reductive water.At present this method mainly obtains certain effect in the laboratory, but the obstacle of this method maximum be also do not have at present a kind of can negative electrode and anode can both stable existence electrode materials, and this kind material require has good antifouling property.Noble metal electrode, as the platinum material, at present usefulness is many, but these precious metal materials can catalytic electrolysis water, and therefore waste electric energy greatly also is easy in addition be polluted by some chemical substances or intermediate product, and has influence on degradation efficiency.The diamond of surface plating boron is used to do electrode at present, and has under lab also obtained certain effect, and still this material is had relatively high expectations to the effect functional group of diamond surface, and costs an arm and a leg.Large-scale practical application does not have actual operation parameter, lacks the relevant information of stable aspect.
Advanced oxidation processes is to utilize the very strong material of some oxidisability such as ozone, hydrogen peroxide etc., produces the hydroxyl radical free radical HO of strong oxidizing property, the deoxidation pollutent.This method is fine to some conventional readily oxidizable substances such as removal effects such as phenol, oil of mirbane, even can reach mineralising.But organism is after halogen replaces, because the electrophilic inductive effect of halogen, cloud density reduces in the molecular structure, and is therefore more difficult by the HO attack, and speed of reaction reduces.Some halogenated organic matters is as tribromoacetic acid, trichoroacetic acid(TCA), with second order rate constant＜10 of HO
6M
-1s
-1, therefore, be difficult to they be removed fully with the mode of advanced oxidation.Though the introducing of catalyzer can accelerated reaction, efficient is still not high, moreover adds catalyzer and increase cost, can affect to water quality yet.Recently, ultrasonic technique research many, because the effect of ultransonic cavatition and acceleration mass transfer, the ultrasonic associating with advanced oxidation uses with removing the pollutent effect than independent advanced oxidation efficient height, also useful ultrasonic and advanced oxidation coupling removal perfluorocarboxylic acid and perfluoro octyl sulfonic acid, but efficient is still lower, and relatively power consumption, has increased use cost.
Transition metal-catalyzed reduction method is meant and utilizes the special catalytic performance catalysis H of transition metal (as Pd etc.)
2Replace the halogen on the halogenated organic matters,, and then reach the purpose of reductive dehalogenation as chlorine.This method can be studied the chlorine that is used for removing trieline, zellon etc. in the laboratory, and when the transition-metal catalyst of capacity was arranged in the system, removal effect can reach level preferably.But this method has also just obtained certain effect at present in the laboratory, does not also come into operation, and actual operational circumstances and running cost are still waiting further investigation; But from breadboard running condition, transition-metal catalyst is subjected to the pollution of organism easily in this method, needs frequent regeneration backwash; In addition, sulfocompound in the system, as vitriol etc., can produce sulfide under this reduction system and action of microorganisms, this sulfide can make poisoning of catalyst, and then reduces its catalytic activity, therefore catalyzer needs frequent regenerating with hypochlorite solutions, keeping corresponding catalytic activity, therefore operate cumbersome, poor stability.
The vacuum ultraviolet (VUV) method is the ultraviolet ray excited water molecules that utilizes high-octane short wavelength, produces multiple free radical, comprises HO, e
Aq -, H etc., oxidation/go back parent pollutant.If the vacuum ultraviolet (VUV) method produces short wavelength ultraviolets such as 172nm with electrodeless ultraviolet lamp, the cost of lamp can be very high; And the part of low pressure mercury lamp generation short wavelength ultraviolet seldom, general＜6%, therefore relatively power consumption; In addition, the penetrativity of short wavelength ultraviolet in water is very weak, and be general＜1cm, therefore greatly reduces service efficiency, limited it and be extensive use of; If add catalyzer, then the catalytic capability of catalyzer, recovery and regeneration etc. all are a series of problems that must solve.High-energy radiation and vacuum ultraviolet (VUV) method principle are approaching, but cost all than higher, it needs source of radiation, costs an arm and a leg; And radsafe has limited its use in tap water; Remove the existing application of sewage with it, but cost is too high, management is inconvenient.
Reactive infiltration wall technology is the technology that the polluted-water that utilizes the permeability wall to pass through carries out scrubbing, is a kind of original place treatment technology, is mainly used in phreatic reparation.This method is used to phreatic reparation at present, utilizes Zero-valent Iron to remove halogenated organic matters in the underground water as this technology.This method can effectively be removed organism such as vinylchlorid, but only produces effect in the shallow-layer waterbearing stratum, has therefore limited its use.
Therefore, be necessary very much to research and develop a kind of can be effectively, economical, convenient and can broad spectrum ground removal water in the water technology of halogenated organic matters, this technology not only can be used in the household drinking water, also can be used in city water factory and the sewage work, can also be used in face of land rivers water, lake water and the phreatic reparation of overall situation, even can be used in brine disposal and the reparation.
Summary of the invention
The present invention seeks to adopt gas formulation, active carbon adsorption, electrochemistry to remove the various drawbacks that halogenated organic matters exists in method, advanced oxidation processes, transition metal-catalyzed reduction method, vacuum ultraviolet (VUV) or the reactive infiltration wall technology removal water, and the method for halogenated organic matters in the water is removed in the short dehalogenation compound of a kind of light that provides/light coupling in order to solve.
Light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is by S-WAT, lithium sulfite, potassium sulfite, magnesium sulfite, calcium sulfite, ammonium sulphite, sulfurous acid, Sodium Pyrosulfite, the pyrosulphite lithium, potassium pyrosulfite, pyrosulphite magnesium, pyrosulphite calcium, ammonium pyrosulfite, V-Brite B, the SODIUM HYDROSULPHITE lithium, potassium hyposulfite, magnesium hyposulfite, calcium hyposulfite, ammonium hyposulfite, potassiumiodide, sodium iodide, magnesium iodide, ammonium iodide, sodium hydroxide, potassium hydroxide, Potassium Persulphate, Sodium Persulfate, ammonium persulphate, potassium peroxydisulfate, sodium peroxydisulfate, sodium pyrosulfate, potassium pyrosulfate, permonosulphuric acid potassium, permonosulphuric acid sodium, the permonosulphuric acid ammonium, sulfurous gas, hydrogen sulfide, clorox, potassium permanganate, sodium permanganate, potassium ferrate, Na2Fe04, potassium manganate, sodium manganate, Manganse Dioxide, Manganous chloride tetrahydrate, manganous sulfate, manganous nitrate, nitrous acid manganese, chloric acid manganese, sodiumazide, potassium azide, ammonium azide, perchloric acid manganese, sodium-chlor, Repone K, hydrogen peroxide, formic acid, sodium formiate, potassium formiate, acetate, sodium acetate, potassium acetate, oxalic acid, sodium oxalate, potassium oxalate, potassium ferric oxalate, the oxalic acid ferrisodium, ironic oxalate, Ferrox, ferrous sulfate, ferric sulfate, iron nitrate, nitrous acid iron, Iron nitrate, nitrous acid is ferrous, iron protochloride, iron(ic) chloride, dipotassium hydrogen phosphate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, potassiumphosphate, potassiumphosphate sodium, phosphoric acid, tetra-sodium, potassium pyrophosphate, trisodium phosphate, Zero-valent Iron, zeroth order manganese, Sulfothiorine, Potassium Thiosulphate, sodium sulphite, potassium sulphide, ammonium sulfide, Sodium sulfhydrate, potassium bisulfide, sulphur hydrogenation ammonium, methyl alcohol, ethanol, propyl alcohol, butanols, formaldehyde, acetaldehyde, propionic aldehyde, acetone, butyraldehyde, butanone, hydrazine, N, the N-diethyl hydroxylamine, carbohydrazide, the amido thanomin, saccharosonic acid, nitrogen four substituted benzene diamines, oxammonium hydrochloride, pyrocatechol, Resorcinol, Resorcinol, in the soil ulmin one or more are composited; The dosage of the short dehalogenation compound of light be molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water than 0.5～10: 1 adds.
Principle of the present invention is: the short dehalogenation compound of light is added to and contains in the organic water of halo, under illumination, produces a series of middle free radical, as e then
Aq -, HO, H, SO
4 -, SO
2 -, SO
3 -, SO
5 -, O
2 -, HO
2, NO
2, NO, CO
2, CO
3 -, S
-, N
3, NH
2, (SCN)
2 -, (CH
3)
2COH, (CH
3)
2CO
-, CH
2OH, organic free radical R, Fe
2+,
These free radicals can with the halogenated organic matters generation rapid reaction in the water.HO and SO
4 -It all is the free radical of strong oxidizing property, can pass through mode and partial organic substances reactions such as electrophilic substitution, electrophilic addition and transfer transport, and speed of reaction is generally very big, the compound of some electron riches particularly, as common halogenated organic matters chlorobenzene, parachloronitrobenzene, chlorophenol etc., they and HO or SO
4 -Secondary rate constant all near or much larger than 10
9M
-1s
-1Therefore, can both be fallen the mechanism of Here it is advanced oxidation very soon by the very strong free-radical oxidn of these electronegativity; But advanced oxidation is dehalogenation fully many times, such as HO and SO
4 -The oxidation chlorobenzene is just to be easy to generate some micromolecular chloroparaffins, and the toxicity of these intermediate products might be bigger than parent pollutent; In addition, as the halogenated organic matters of some relative inertness, as halogenated organic matters such as fluoroethane, trichloromethane, trichoroacetic acid(TCA), tribromoacetic acids, they and some oxidative free radical HO and SO
4 -Speed of reaction is very little, general＜10
6M
-1s
-1, therefore, be difficult to they be removed fully by advanced oxidation.At this moment, the free radical such as the e that need some reductibilities
Aq -, H, SO
3 -Wait and removed.The sub-e of power and water particularly
Aq -, the speed of reaction of it and halogenated organic matters is very big, as e
Aq -Can reach 3 * 10 with the rate constant of haloform reaction
10M
-1s
-1, with the reaction rate constant of trichoroacetic acid(TCA) near rate of diffusion, 8.5 * 10
9M
-1s
-1, and the mechanism of action is simple, is the dehalogenation reaction directly takes place, and therefore seldom has by product to produce, and power and water is with 1,1, and following reaction takes place in the 2-Freon 113:
e
aq -+ClCF
2CCl
2F——·CF
2CCl
2F+CClF
2CClF+Cl
-
In addition, some halogenated organic matters in the water also can with reductive free radical H, SO
3 -Also the dehalogenation reaction more fast can take place, be 1.4 * 10 as the secondary rate constant with chlorobenzene
9M
-1s
-1, with the secondary rate constant of 2-chlorophenol be 1.5 * 10
9M
-1s
-1, therefore can remove the halogenated organic matters in the water.
Light of the present invention is urged the method that halogenated organic matters in the water is removed in dehalogenation compound/light coupling, does not need multistage removal; Do not need expensive oxygenant and catalyzer; Do not need to be easy to generate the sorbent materials such as gac of secondary pollution; Do not need expensive vacuum ultraviolet light source and high-energy radiation source; Can utilize the ultraviolet POP light source of common, inexpensive, even be extended to visible light, improve the utilising efficiency of luminous energy; Can remove the halogenated organic matters in the water fast; Can be used for the reparation of surface water river lake water and seawater; Can be used for the halogenated organic matters reparation of shallow ground water and deep phreatic water; Can be that miniaturization family or unit use, the structures formula of perhaps large-scale industry, water factory, underground water, ocean or restoration of the ecosystem be used; Reactor design easily satisfies the needs of various different water bodys, comes into operation as early as possible; Operation is economical, and convenient management can ensure water quality safety.
The present invention is to methylene dichloride, trichloromethane, tetracol phenixin, Chlorodracylic acid, 4-chlorophenol, 2, a series of representational halogenated organic matters such as 4-two chlorophenols, Pentachlorophenol, trifluoroacetic acid, trichoroacetic acid(TCA), tribromoacetic acid, chlorobenzene, polychlorobiphenyl, 4-bromine phenol, bromobenzene, Polybrominated biphenyl, Poly Brominated Diphenyl Ethers all have good effect of removing.With advanced oxidation (ozone O
3, UV/H
2O
2Deng), vacuum ultraviolet (VUV) method, transition metal-catalyzed reduction, electrochemical process etc. compare, and the advantage on obvious speed and the efficient is arranged; And the use of this technology and pollutent starting point concentration are irrelevant; When the present invention was applied to water treatment, the background of water quality (comprising inorganic zwitterion, soil ulmin, bacteria total amount etc.) was little to the removal effectiveness affects of system; The turbidity of water body, colourity have certain influence for photoreactor, but can give full play to the removal efficient of this technology by the appropriate design reactor; Compare with vacuum ultraviolet (VUV) and high-energy radiation method, the present invention only needs conventional ultraviolet lamp to get final product that (wavelength＜400nm), common low-pressure mercury ultraviolet lamp, middle pressure mercury ultraviolet lamp, high-pressure mercury ultraviolet lamp, amalgam ultraviolet lamp, halogen lamp promptly satisfy working conditions; Under visible light, use, need to add photosensitizers or catalyzer; If will improve removal efficient, can pass through to increase the throwing amount of light intensity and the short dehalogenation compound of increase light with realization; Present technique is used for removing the water halogenated organic matters, dehalogenation fully, and convenient follow-up further processing (as chlorobenzene etc.), perhaps dehalogenation detoxification fully (as trichoroacetic acid(TCA) etc.); The present invention is used for the halogenated organic matters that water treatment not only can be removed water, also can remove the nitro substituent, can also reach sterilization effects, can not produce secondary pollution, can the bigger product of toxigenicity, can ensure water quality safety, and can obviously not change the mouthfeel of water quality.
The present invention can be used for conventional water body, dissolved oxygen in the water, pH value, basicity and organic indicator etc. are not required, can select different modes with pollutant type according to different water body features, also can implement staging treating: when oxygen in water is higher, can take to improve the oxidation efficiency of system, also can increase dissolved oxygen in addition, improve oxidation efficiency by the mode that in system, blasts air or oxygen; When oxygen in water concentration is low, then help the reduction reaction process of system, also can keep reducing environment, and improve the removal efficient that halogenated organic matters is removed in reduction by in system, feeding nitrogen, hydrogen or rare gas element such as argon gas etc.
Description of drawings
Fig. 1 is a surplus ratio graphic representation of removing halogenated organic matters p-CBA in the water in the embodiment five, wherein is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters p-CBA in the water, and ■ is the surplus ratio curve of halogenated organic matters p-CBA during the short dehalogenation compound of light/light combined action goes down to dewater; Remove halogenated organic matters DCP in the water in Fig. 2 embodiment six, the surplus ratio graphic representation of PCP and BP, wherein is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters DCP in the water, △ is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters BP in the water, zero is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters PCP in the water, ■ light urge dehalogenation compound/light combined action go down to dewater in the surplus ratio curve of halogenated organic matters DCP, ▲ light urge dehalogenation compound/light combined action go down to dewater in the surplus ratio curve of halogenated organic matters BP, ● light urge dehalogenation compound/light combined action go down to dewater surplus ratio curve of middle halogenated organic matters PCP; Fig. 3 is a surplus ratio graphic representation of removing halogenated organic matters trichloromethane in the water in the embodiment seven, wherein is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters trichloromethane in the water, ■ is the surplus ratio curve of halogenated organic matters trichloromethane during ultraviolet and hydrogen peroxide effect go down to dewater
Light urge dehalogenation compound/light combined action go down to dewater in the surplus ratio curve of halogenated organic matters trichloromethane; Fig. 4 is a surplus ratio graphic representation of removing halogenated organic matters trichoroacetic acid(TCA) in the water in the embodiment eight, wherein is the surplus ratio curve that independent uv irradiation is removed halogenated organic matters trichoroacetic acid(TCA) in the water, and ■ is the surplus ratio curve of halogenated organic matters trichoroacetic acid(TCA) during the short dehalogenation compound of light/light combined action goes down to dewater.
Embodiment
Technical solution of the present invention is not limited to following cited embodiment, also comprises the arbitrary combination between each embodiment.
Embodiment one: present embodiment light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and is carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is by S-WAT, lithium sulfite, potassium sulfite, magnesium sulfite, calcium sulfite, ammonium sulphite, sulfurous acid, Sodium Pyrosulfite, the pyrosulphite lithium, potassium pyrosulfite, pyrosulphite magnesium, pyrosulphite calcium, ammonium pyrosulfite, V-Brite B, the SODIUM HYDROSULPHITE lithium, potassium hyposulfite, magnesium hyposulfite, calcium hyposulfite, ammonium hyposulfite, potassiumiodide, sodium iodide, magnesium iodide, ammonium iodide, sodium hydroxide, potassium hydroxide, Potassium Persulphate, Sodium Persulfate, ammonium persulphate, potassium peroxydisulfate, sodium peroxydisulfate, sodium pyrosulfate, potassium pyrosulfate, permonosulphuric acid potassium, permonosulphuric acid sodium, the permonosulphuric acid ammonium, sulfurous gas, hydrogen sulfide, clorox, potassium permanganate, sodium permanganate, potassium ferrate, Na2Fe04, potassium manganate, sodium manganate, Manganse Dioxide, Manganous chloride tetrahydrate, manganous sulfate, manganous nitrate, nitrous acid manganese, chloric acid manganese, sodiumazide, potassium azide, ammonium azide, perchloric acid manganese, sodium-chlor, Repone K, hydrogen peroxide, formic acid, sodium formiate, potassium formiate, acetate, sodium acetate, potassium acetate, oxalic acid, sodium oxalate, potassium oxalate, potassium ferric oxalate, the oxalic acid ferrisodium, ironic oxalate, Ferrox, ferrous sulfate, ferric sulfate, iron nitrate, nitrous acid iron, Iron nitrate, nitrous acid is ferrous, iron protochloride, iron(ic) chloride, dipotassium hydrogen phosphate, Sodium phosphate dibasic, SODIUM PHOSPHATE, MONOBASIC, potassium primary phosphate, potassiumphosphate, potassiumphosphate sodium, phosphoric acid, tetra-sodium, potassium pyrophosphate, trisodium phosphate, Zero-valent Iron, zeroth order manganese, Sulfothiorine, Potassium Thiosulphate, sodium sulphite, potassium sulphide, ammonium sulfide, Sodium sulfhydrate, potassium bisulfide, sulphur hydrogenation ammonium, methyl alcohol, ethanol, propyl alcohol, butanols, formaldehyde, acetaldehyde, propionic aldehyde, acetone, butyraldehyde, butanone, hydrazine, N, the N-diethyl hydroxylamine, carbohydrazide, the amido thanomin, saccharosonic acid, nitrogen four substituted benzene diamines, oxammonium hydrochloride, pyrocatechol, Resorcinol, Resorcinol, in the soil ulmin one or more are composited; The dosage of the short dehalogenation compound of light be molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water than 0.5～10: 1 adds.
The state of Zero-valent Iron and zeroth order manganese is Powdered, granular, thread, netted or coating in the short dehalogenation compound of present embodiment light.
When the short dehalogenation compound of light is by several being composited in the present embodiment, mix by the arbitrary volume ratio.
In the present embodiment the short dehalogenation compound of light by solution add, pressed powder adds or employing equipment adds.
The dosage of present embodiment medium ultraviolet photoirradiation: uv dosage is big more, and deaerating effect is good more, but need carry out safety precaution, in order to avoid excessive uv irradiation is hurted sb.'s feelings.
The intensity of present embodiment medium ultraviolet photoirradiation will keep stable, need regularly clean or replace ultraviolet source to keep the requirement of uv dosage.
The turbidity that present embodiment contains the organic water of halo is not higher than 0.5NTU.
Present embodiment can improve the efficient of removing halogenated organic matters in the water by aeration in water body; Mainly be because: 1, aeration can the raising system in the rate of mass transfer of each species; 2, aeration can the participation system react the accelerated reaction process; 3, can shield some emulative side reactions by aeration, improve processing efficiency.
Halogenated organic matters in the present embodiment water body is through after the dehalogenation, except halide-ions can not pollute, the organism thing of mineralising not after may some dehalogenation, in general toxicity is less or nontoxicity for this partial organic substances, as the acetate that generates after the trichoroacetic acid(TCA) dechlorination; Another part has certain toxicity, and as the benzene that generates after the chlorobenzene dechlorination, but toxicity is little more a lot of than chlorobenzene.For these organism, generally their polarity, solubleness all can reduce, and therefore are easy to be removed by the mode of routine.In addition, the photoirradiation of high dosage also has good photolysis for these organism, can remove preferably, as polycyclic aromatic hydrocarbons, algae toxin etc.
The short dehalogenation compound of light can adopt coagulating sedimentation or membrane filtration to remove if any residue in the present embodiment.
In the present embodiment the short dehalogenation compound of light can and catalyzer (TiO
2, Lin Wusuanyan) unite use, improve degradation efficiency.
Embodiment two: what present embodiment and embodiment one were different is that photoirradiation adopts ultraviolet source, visible light source or energetic ray light source, and light source is ozone free low pressure mercury lamp, medium pressure mercury lamp, high voltage mercury lamp, amalgam ultraviolet lamp, halogen lamp, xenon lamp, blackout, vacuum UV lamp, X ray, alpha-ray, β ray or gamma-rays.Other is identical with embodiment one.
Visible light comprises sunlight and simulated sunlight in the present embodiment.
Light source need be equipped with suitable electrical control equipment and power supply in the present embodiment.
The power of present embodiment medium ultraviolet UV photoirradiation can be selected arbitrarily, need decide (system oxygen concn, deoxygenation speed and running cost) according to system's actual needs.
Present embodiment medium ultraviolet UV photoirradiation adopts immersion or surface irradiation formula; Adopt immersion, then the ultraviolet source outer wall needs nested silica tube to be protected.
Embodiment three: present embodiment and embodiment two are different is to add the short dehalogenation compound of light and stir in containing the organic water of halo, photoirradiation then, and carry out aeration simultaneously, promptly finish and remove halogenated organic matters in the water.Other is identical with embodiment two.
The gas that aeration is selected for use in the present embodiment can be: air, oxygen, nitrogen, helium, argon gas, sulfurous gas, ozone, nitrous oxide, need rationally select source of the gas for use at different target contaminants and system.
Embodiment four: present embodiment and embodiment three are different is to contain that nitrate, nitrite content are lower than 20mg/L in the organic water of halo, and turbidity is less than 1NTU.Other is identical with embodiment three.
Embodiment five: present embodiment light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and is carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is composited by S-WAT, sodium hydroxide, manganous sulfate, Zero-valent Iron, oxammonium hydrochloride, Resorcinol and soil ulmin; The dosage of the short dehalogenation compound of light is that the molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water added than 2: 1.
In containing the organic water of halo, carry out aeration in the present embodiment.Halogenated organic matters is the Chlorodracylic acid (p-CBA) of 10 μ M in the present embodiment; Ultraviolet source is the ozone free low pressure mercury lamp, emission predominant wavelength 253.7nm, power 10w, surface light intensity 12mW/cm
2
The halogenated organic matters removal effect is seen Fig. 1 in the present embodiment, and as can be known, p-CBA degradation speed under independent ultraviolet condition is low; P-CBA degradation speed under the short dehalogenation compound of light/light combined action greatly improves, and 1.5min is that degradation rate reaches 50%, almost completely degraded behind the 5min, and effect is obvious; If improve UV intensity, effect can be more obvious, and degradation time also can obviously shorten.
Present embodiment can be used as the degrade reference of situation of halogenated aromatic carboxylic-acid substance in the water.
Embodiment six: present embodiment light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and is carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is composited by potassium hydroxide, potassium permanganate, hydrogen peroxide, iron protochloride, methyl alcohol, propionic aldehyde, carbohydrazide, oxammonium hydrochloride, Resorcinol; The dosage of the short dehalogenation compound of light is that the molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water added than 1.2: 1.
In containing the organic water of halo, carry out aeration in the present embodiment, adopt nitrogen.Halogenated organic matters is 2 of 5 μ M in the present embodiment, the Pentachlorophenol (PCP) of 4-two chlorophenols (DCP), 1mg/L and the bromine phenol (BP) of 10 μ M; Ultraviolet source is the ozone free low pressure mercury lamp, emission predominant wavelength 253.7nm, power 10w, surface light intensity 12mW/cm
2
The halogenated organic matters removal effect is seen Fig. 2 in the present embodiment, and as can be known, DCP, PCP and BP degradation speed under independent ultraviolet condition is low; DCP, PCP and BP degradation speed under the short dehalogenation compound of light/light combined action greatly improves, and degradation rate reaches about 90% during 7min, just is removed fully behind the 10min, and effect is obvious.
Present embodiment can be used as the reference of halo phenols degraded situation in the water.
Embodiment seven: present embodiment light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and is carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is composited by sulfurous acid, V-Brite B, potassium ferrate, chloric acid manganese, potassium oxalate, Iron nitrate, zeroth order manganese, potassium sulphide, propionic aldehyde, Resorcinol, soil ulmin; The dosage of the short dehalogenation compound of light is that the molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water added than 1.5: 1.
In containing the organic water of halo, carry out aeration in the present embodiment, adopt nitrogen or oxygen.Halogenated organic matters is the trichloromethane of 10 μ M in the present embodiment; Ultraviolet source is the ozone free low pressure mercury lamp, emission predominant wavelength 253.7nm, power 10w, surface light intensity 12mW/cm
2
The halogenated organic matters removal effect is seen Fig. 3 in the present embodiment, and as can be known, trichloromethane under the ultraviolet condition photodegradation is not taking place substantially separately; Trichloromethane is under the hydrogen peroxide effect of ultraviolet and 1mM, and the degradation rate of trichloromethane is 33% behind the 15min; Trichloromethane degradation speed under the short dehalogenation compound of light/light combined action greatly improves, and 10min can remove the trichloromethane in the water substantially fully, and effect is fairly obvious.
Present embodiment can be used as the reference of halogenated alkane degraded situation in the water.
Embodiment eight: present embodiment light is urged the method for halogenated organic matters in dehalogenation compound/light coupling removal water and is carried out in the following manner: add short dehalogenation compound of light and stirring in containing the organic water of halo, photoirradiation is promptly finished and is removed halogenated organic matters in the water then; Wherein the short dehalogenation compound of light is by potassium hydroxide, Manganse Dioxide, manganous nitrate, Repone K, potassium oxalate, iron(ic) chloride, phosphoric acid, potassium sulphide, methyl alcohol, N, and N-diethyl hydroxylamine, amido thanomin, oxammonium hydrochloride are composited; The dosage of the short dehalogenation compound of light is that the molar equivalent according to halogenated organic matters in the short dehalogenation compound of light and the water added than 1.8: 1.
In containing the organic water of halo, carry out aeration in the present embodiment, adopt nitrogen or oxygen.Halogenated organic matters is a trichoroacetic acid(TCA) in the present embodiment; Ultraviolet source is the ozone free low pressure mercury lamp, emission predominant wavelength 253.7nm, power 10w, surface light intensity 12mW/cm
2
The halogenated organic matters removal effect is seen Fig. 4 in the present embodiment, and as can be known, trichoroacetic acid(TCA) under the ultraviolet condition photodegradation is not taking place substantially separately; Trichoroacetic acid(TCA) degradation speed under the short dehalogenation compound of light/light combined action greatly improves, and the trichoroacetic acid(TCA) degradation rate reaches 66% during 10min, and the 15min degradation rate can reach 86%, and effect is fairly obvious.
Present embodiment can be used as the reference of halogen organic acid class degraded situation in the water.
Claims (4)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910073449XA CN101708883B (en) | 2009-12-18 | 2009-12-18 | A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910073449XA CN101708883B (en) | 2009-12-18 | 2009-12-18 | A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101708883A CN101708883A (en) | 2010-05-19 |
| CN101708883B true CN101708883B (en) | 2011-08-03 |
Family
ID=42401695
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910073449XA Expired - Fee Related CN101708883B (en) | 2009-12-18 | 2009-12-18 | A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101708883B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017202029A1 (en) * | 2016-05-26 | 2017-11-30 | 哈尔滨工业大学深圳研究生院 | Method and system for measuring content of dissolved organic halogens in water |
| CN107986386A (en) * | 2017-12-11 | 2018-05-04 | 江苏开放大学 | One kind uses UV/Na2SO3The method of photo-reduction degraded 2,4,6- tribromophenols |
Families Citing this family (29)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102139949A (en) * | 2011-02-16 | 2011-08-03 | 哈尔滨工业大学 | Method for removing trace pollutants in water by intensified PMS (phosphate monoester starch) composite technology |
| RU2466939C1 (en) * | 2011-06-17 | 2012-11-20 | Федеральное государственное бюджетное учреждение науки Институт органической химии Н.Д. Зелинского Российской академии наук (ИОХ РАН) | Reagent for purification of water and soil from chloro-organic compounds and method of its obtaining |
| CN102381740A (en) * | 2011-11-02 | 2012-03-21 | 哈尔滨工业大学 | Method for removing nitrogenous disinfection byproducts in water on basis of persulfate/light combination |
| NL2008263C2 (en) * | 2012-02-08 | 2013-08-14 | Arcadis Nederland B V | Degrading halogenated organic compounds. |
| CN102642959A (en) * | 2012-05-07 | 2012-08-22 | 哈尔滨工程大学 | Method for removing arsenic in water through combination of oxidization composite chemical and light |
| CN102642951B (en) * | 2012-05-07 | 2013-08-28 | 哈尔滨工程大学 | Method combining oxidizing composite reagent and activated carbon to remove arsenic in water |
| CN103058321A (en) * | 2013-01-21 | 2013-04-24 | 武汉大学 | Photochemical method of intensively degrading organic matters |
| CN103787448A (en) * | 2014-02-20 | 2014-05-14 | 南京大学 | Denitrification method combining denitrification agent and ultraviolet light |
| CN103964559A (en) * | 2014-05-20 | 2014-08-06 | 南京大学 | Photosensitive agent and method for synchronously removing nitrate, nitrite and chlorine disinfection side products out of drinking water |
| CN104140137A (en) * | 2014-08-20 | 2014-11-12 | 云南大学 | Method for removing EDCs (endocrine disrupting chemicals) from water body by ultraviolet or visible light source in combination with alkaline substances |
| CN107739723A (en) * | 2014-10-10 | 2018-02-27 | 苏州市环境科学研究所 | Nutrient solution used in organochlorine pollutant purification method |
| CN106517572A (en) * | 2016-10-17 | 2017-03-22 | 南京大学 | High-grade oxidation method for removing artificial sweetening agent in sewage based on sulfate radical |
| CN107973461A (en) * | 2017-12-11 | 2018-05-01 | 江苏开放大学 | A kind of UV/Na of 4- bromines phenol2SO3Photo-reduction biodegrading process |
| CN108558090A (en) * | 2018-05-25 | 2018-09-21 | 北京林业大学 | A kind of staged wastewater disinfection method and device |
| CN109019760A (en) * | 2018-07-03 | 2018-12-18 | 江苏开放大学（江苏城市职业学院） | A method of utilizing effective UV/sodium sulfite photo-reduction system degradation 2,4- dibromophenol |
| CN108911025A (en) * | 2018-07-20 | 2018-11-30 | 中山大学 | A kind of method for treating water removing micropollutants |
| CN109081471A (en) * | 2018-09-11 | 2018-12-25 | 四川长虹格润环保科技股份有限公司 | Efficiently repair the method for Pollution of Volatile Alkyl Halides water body |
| CN109772873A (en) * | 2018-10-30 | 2019-05-21 | 华南师范大学 | A composition for remediating organic-contaminated soil or groundwater and its remediation method |
| CN109607734A (en) * | 2018-12-31 | 2019-04-12 | 南京格洛特环境工程股份有限公司 | A kind of low-temperature denitration medicament and preparation method thereof |
| CN110028127A (en) * | 2019-04-03 | 2019-07-19 | 广西大学 | The method for controlling mariculture disinfection by-products |
| US11548800B2 (en) | 2019-04-26 | 2023-01-10 | Geyser Remediation LLC | Water purification apparatus and method |
| CN110372048B (en) * | 2019-06-21 | 2022-04-22 | 深圳市慧创源环保科技有限公司 | Method for removing organic matters in water |
| CN110272111A (en) * | 2019-07-31 | 2019-09-24 | 郑州恒博环境科技股份有限公司 | A kind of oxidant and preparation method thereof removing high-salt wastewater COD organic matter |
| CN111285454B (en) * | 2020-03-27 | 2022-06-10 | 中国科学院生态环境研究中心 | Water treatment method for reducing and degrading halogenated organic matters by using copper activated thiourea dioxide |
| CN112897780A (en) * | 2021-03-08 | 2021-06-04 | 沈阳大学 | Method for advanced reductive degradation of azo dye by using ultraviolet/semi-dry desulfurized fly ash |
| CN113003817A (en) * | 2021-03-25 | 2021-06-22 | 沈阳大学 | Method for removing halogenated organic matters by using high-grade reduction system based on semi-dry flue gas desulfurization ash |
| CN113105041A (en) * | 2021-04-06 | 2021-07-13 | 中南民族大学 | Method for degrading dehalogenated halogenated phenol pollutants by enhanced ultraviolet light |
| CN113292151A (en) * | 2021-05-24 | 2021-08-24 | 浙江工业大学 | Application of sodium azide in degradation of organic matters and method for treating organic wastewater by ozone |
| CN113321367B (en) * | 2021-08-04 | 2021-11-30 | 清大国华环境集团股份有限公司 | Pretreatment recycling method for halogen-containing waste |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040968A (en) * | 1988-09-06 | 1990-04-04 | 厦门大学 | A kind of method of photocatalysis treatment of waste water |
| CN1611454A (en) * | 2003-10-27 | 2005-05-04 | 中国科学院化学研究所 | Method for photo-oxidative flocculating treatment of organic pollutant waster water |
| CN1636893A (en) * | 2004-12-01 | 2005-07-13 | 南京大学 | Combined effluent treating process of photooxidizing Fenton's reaction, flocculation and microbial degradation |
-
2009
- 2009-12-18 CN CN200910073449XA patent/CN101708883B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1040968A (en) * | 1988-09-06 | 1990-04-04 | 厦门大学 | A kind of method of photocatalysis treatment of waste water |
| CN1611454A (en) * | 2003-10-27 | 2005-05-04 | 中国科学院化学研究所 | Method for photo-oxidative flocculating treatment of organic pollutant waster water |
| CN1636893A (en) * | 2004-12-01 | 2005-07-13 | 南京大学 | Combined effluent treating process of photooxidizing Fenton's reaction, flocculation and microbial degradation |
Non-Patent Citations (1)
| Title |
|---|
| JP特开平11-90460A 1999.04.06 |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2017202029A1 (en) * | 2016-05-26 | 2017-11-30 | 哈尔滨工业大学深圳研究生院 | Method and system for measuring content of dissolved organic halogens in water |
| CN107986386A (en) * | 2017-12-11 | 2018-05-04 | 江苏开放大学 | One kind uses UV/Na2SO3The method of photo-reduction degraded 2,4,6- tribromophenols |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101708883A (en) | 2010-05-19 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101708883B (en) | A method for photocatalyzed dehalogenation compound agent/light coupling to remove halogenated organic matter in water | |
| Wang et al. | Different activation methods in sulfate radical-based oxidation for organic pollutants degradation: Catalytic mechanism and toxicity assessment of degradation intermediates | |
| Mishra et al. | A review on advanced oxidation processes for effective water treatment | |
| Trojanowicz et al. | Advanced oxidation/reduction processes treatment for aqueous perfluorooctanoate (PFOA) and perfluorooctanesulfonate (PFOS)–a review of recent advances | |
| Ahmadi et al. | Degradation of organic pollutants by photoelectro-peroxone/ZVI process: Synergistic, kinetic and feasibility studies | |
| Rayaroth et al. | Advanced oxidation processes for the removal of mono and polycyclic aromatic hydrocarbons–A review | |
| Dolatabadi et al. | Electro-Fenton approach in oxidative degradation of dimethyl phthalate-The treatment of aqueous leachate from landfills | |
| Kataria et al. | Current progress in treatment technologies for plastic waste (bisphenol A) in aquatic environment: Occurrence, toxicity and remediation mechanisms | |
| Espana et al. | Treatment technologies for aqueous perfluorooctanesulfonate (PFOS) and perfluorooctanoate (PFOA): A critical review with an emphasis on field testing | |
| Mustapha et al. | A critical review on geosmin and 2-methylisoborneol in water: sources, effects, detection, and removal techniques | |
| Mojiri et al. | Occurrence of per-and polyfluoroalkyl substances in aquatic environments and their removal by advanced oxidation processes | |
| Khuntia et al. | Removal of ammonia from water by ozone microbubbles | |
| Sirés et al. | Electrochemical advanced oxidation processes: today and tomorrow. A review | |
| Gosavi et al. | A general review on various treatment methods for textile wastewater | |
| Nunes et al. | An overview on surfactants as pollutants of concern: Occurrence, impacts and persulfate-based remediation technologies | |
| Kim et al. | Revisiting the oxidizing capacity of the periodate–H2O2 mixture: identification of the primary oxidants and their formation mechanisms | |
| Qanbarzadeh et al. | Impacts of reactor configuration, degradation mechanisms, and water matrices on perfluorocarboxylic acid treatment efficiency by the UV/Bi3O (OH)(PO4) 2 photocatalytic process | |
| Wang et al. | Hazardous waste treatment technologies | |
| Girón-Navarro et al. | Evaluation and comparison of advanced oxidation processes for the degradation of 2, 4-dichlorophenoxyacetic acid (2, 4-D): a review | |
| Oliveira et al. | Removal and sensing of emerging pollutants released from (micro) plastic degradation: Strategies based on boron-doped diamond electrodes | |
| Motamedi et al. | A critical review of water contamination by polybrominated diphenyl ethers (PBDE) and main degradation techniques | |
| El Kateb et al. | Ferrate (VI) pre-treatment and subsequent electrochemical advanced oxidation processes: Recycling iron for enhancing oxidation of organic pollutants | |
| Mohammadi et al. | Oxidation of phenol from synthetic wastewater by a novel advance oxidation process: microwave-assisted periodate | |
| Das et al. | Ozone-based oxidation processes for the removal of pharmaceutical products from wastewater | |
| Zhang et al. | Unraveling the role of iodide in periodate-based water decontamination: accelerated selective oxidation and formation of iodinated products |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C17 | Cessation of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20110803 Termination date: 20121218 |