CN101701123A - Preparation method of vitrified colorful stone lacquer - Google Patents
Preparation method of vitrified colorful stone lacquer Download PDFInfo
- Publication number
- CN101701123A CN101701123A CN200910073165A CN200910073165A CN101701123A CN 101701123 A CN101701123 A CN 101701123A CN 200910073165 A CN200910073165 A CN 200910073165A CN 200910073165 A CN200910073165 A CN 200910073165A CN 101701123 A CN101701123 A CN 101701123A
- Authority
- CN
- China
- Prior art keywords
- preparation
- stone lacquer
- vitrified
- mixed solution
- colored stone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004575 stone Substances 0.000 title claims abstract description 25
- 239000004922 lacquer Substances 0.000 title claims abstract description 21
- 238000002360 preparation method Methods 0.000 title claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 18
- 238000003756 stirring Methods 0.000 claims abstract description 17
- 239000000839 emulsion Substances 0.000 claims abstract description 11
- 239000000919 ceramic Substances 0.000 claims abstract description 9
- 238000002156 mixing Methods 0.000 claims abstract description 9
- 239000000049 pigment Substances 0.000 claims abstract description 7
- 239000011324 bead Substances 0.000 claims abstract description 6
- 239000011521 glass Substances 0.000 claims description 24
- 239000011259 mixed solution Substances 0.000 claims description 18
- 239000000463 material Substances 0.000 claims description 10
- 239000012466 permeate Substances 0.000 claims description 10
- 239000000203 mixture Substances 0.000 claims description 8
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 239000001913 cellulose Substances 0.000 claims description 5
- 229920002678 cellulose Polymers 0.000 claims description 5
- 239000012467 final product Substances 0.000 claims description 5
- 230000003712 anti-aging effect Effects 0.000 claims description 4
- 230000008719 thickening Effects 0.000 claims description 4
- 229920000191 poly(N-vinyl pyrrolidone) Polymers 0.000 claims description 3
- 239000003223 protective agent Substances 0.000 claims description 2
- 239000011248 coating agent Substances 0.000 abstract description 7
- 238000000576 coating method Methods 0.000 abstract description 7
- 239000000428 dust Substances 0.000 abstract description 7
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract description 3
- 238000005562 fading Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011325 microbead Substances 0.000 abstract 2
- NJVOHKFLBKQLIZ-UHFFFAOYSA-N (2-ethenylphenyl) prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1C=C NJVOHKFLBKQLIZ-UHFFFAOYSA-N 0.000 abstract 1
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 230000003796 beauty Effects 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000003973 paint Substances 0.000 abstract 1
- 230000035515 penetration Effects 0.000 abstract 1
- 238000005245 sintering Methods 0.000 abstract 1
- 238000005507 spraying Methods 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 5
- 239000011707 mineral Substances 0.000 description 5
- 239000002966 varnish Substances 0.000 description 5
- 238000010276 construction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000032683 aging Effects 0.000 description 2
- 230000007797 corrosion Effects 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- 239000011435 rock Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000005282 brightening Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000009500 colour coating Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 230000008595 infiltration Effects 0.000 description 1
- 238000001764 infiltration Methods 0.000 description 1
- 239000004579 marble Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 230000009967 tasteless effect Effects 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
Landscapes
- Glass Compositions (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a preparation method of vitrified colorful stone lacquer, relating to coating. The method solves the problems that: existing stone lacquer has serious dust absorption and fading obscission, particularly contains more carbonate stone which can perform chemical reaction in air and then is dissolved when meeting water, thereby causing color change, crude true stone lacquer spraying surface, easy dust adhesion and uneasy dust elimination. The method of the invention comprises the following steps: firstly, mixing vitrified micro beads with inorganic ceramic pigment, and sintering into colorful micro beads under high temperature condition; secondly, mixing and stirring penetration agent and antiager by weight percent and then preparing into opacifying mixed liquor, mixing the mixed liquor and thickener emulsion until mutual solubility, and then evenly stirring with styrene-acrylate emulsion; and thirdly, evenly mixing 50-80% of vitrified beads and 20-50% of mixed liquid by weight percent to obtain vitrified stone paint. The invention has the advantages of true stone lacquer such as naturalness, primitive simplicity, dazzling beauty, fresh and elegance, cleanness and environment protection, light weight and wear resistance, various colors and permanent color.
Description
Technical field
The present invention relates to the preparation of coating.Relate in particular to the preparation method of glass color coating material.
Background technology
Existing material of construction is to develop and develop along with real estate and living standards of the people improve, exterior coating is of a great variety, people pursue the theory of environment-friendly natural, expedite the emergence of out a lot of novel decorative coating, the true mineral varnish that the nineties is risen, because the thick and heavy nature of its texture is subjected to pursuing of people, and the trend of replacement marble-ceramic tile is arranged greatly, because of it is that the natural crystal pulverizing processes, look that effect is fine, but after using 1～2 year, dust is serious and have the obscission of fading to take place, natural rock is impure many, especially contain stone material, chemical reaction, CaCO can take place in air by more carbonate
3+ H
2O+CO
2=Ca (HCO
3)
2, Ca (HCO
3)
2Meeting water can dissolve, and this is the major cause that causes color to change, and true in addition mineral varnish sprayed surface is coarse, and is not ageing-resistant, and not environmental protection adheres to the dust and the problem of easy-clear not easily.
Summary of the invention
The present invention is that the natural crystal pulverizing processes in order to solve existing mineral varnish because of it, look that effect is fine, but after using 1～2 year, dust is serious and have the obscission of fading to take place, natural rock is impure many, especially contain stone material, chemical reaction, CaCO can take place in air by more carbonate
3+ H
2O+CO
2=Ca (HCO
3)
2, Ca (HCO
3)
2Meeting water can dissolve, this is the major cause that causes color to change, true in addition mineral varnish sprayed surface is coarse, not ageing-resistant, not environmental protection, adhere to the dust and the problem of easy-clear not easily, and a kind of preparation method of glass colored stone lacquer is provided, and the concrete technical scheme that addresses this problem is as follows:
The preparation method's of a kind of glass colored stone lacquer of the present invention step is as follows:
Step 1, glass bead and inorganic ceramic pigment are mixed by weight 6.5～7.5: 1～2.5, put into electrical heater and under 550～850 ℃ of conditions, be fired into vitrified color balls;
Step 2, by weight percentage permeate agent (permeate agent employing peregal) be 0.2～1% and antiaging agent be 0.1～0.5% mix to stir and to make the milkiness mixed solution, mixed solution again with by weight percentage high-quality thickening material (Mierocrystalline cellulose) be 8～11% emulsions mix dissolve each other after, be that acrylic tackifier stirs and gets final product with surplus again;
Step 3, vitrified color balls and mixed solution that step 1 and step 2 are obtained, vitrified color balls is 50～80% by weight percentage, mixed solution is 20～50% to stir after mixing and promptly make glass colored stone lacquer of the present invention.
The color exterior coating of glass of the present invention, the color microballon of glass adds permeate agent, tinting material adopts inorganic ceramic pigment, oxidation and corrosion, the high-temperature firing clinkering together, can not with airborne any substance reaction; The effect of permeate agent is to promote the infiltration of tackiness agent and coating for wall surface to merge, and has effectively improved cohesive strength, and antiaging agent can prevent tackiness agent by the corrosion of acid, alkali, oxygen obnoxious flavour, and can reach 30 years the work-ing life that acrylic acid or the like strengthens tackiness agent; It also has natural, simple and unsophisticated, dazzlingly beautiful, the pure and fresh elegance, solid thick and heavy of true mineral varnish, and clean environment firendly, light weight are wear-resisting, significantly reduced the load-bearing on heat-preserving wall surface, also have simultaneously firm durable, glittering and translucent, color is various, the durable advantage more than 30 years of color.The present invention compares with marble with ceramic tile; easy construction is quick; time saving and energy saving, coating is firmly hard after solidifying, and can clean at any time; stupalith is fully tasteless nontoxic; after the high temperature vitreous, sealing of hole cover in addition is so surface-brightening is level and smooth; do not soak, do not glue ash, clean light, improved the quality and the class of material of construction.Now authentication detects in the national chemical building material of process test center.
Embodiment
Embodiment one: the preparation method's of the glass colored stone lacquer of present embodiment step is as follows:
Step 1, glass bead and inorganic ceramic pigment are mixed by weight 6.5～7.5: 1～2.5, put into electrical heater and under 550～850 ℃ of conditions, be fired into vitrified color balls;
Step 2, by weight percentage permeate agent (permeate agent employing peregal) be 0.2～1% and antiaging agent be 0.1～0.5% mix to stir and to make the milkiness mixed solution, mixed solution again with by weight percentage high-quality thickening material (Mierocrystalline cellulose) be 8～11% emulsions mix dissolve each other after, be that stir gets final product acrylic tackifier (acrylic tackifier adopt pure third or benzene emulsion) with surplus again;
Step 3, vitrified color balls and mixed solution that step 1 and step 2 are obtained, vitrified color balls is 50～80% by weight percentage, mixed solution is 20～50% to stir after mixing and promptly make glass colored stone lacquer of the present invention.
Embodiment two: present embodiment is glass bead in the step 1 is mixed by weight 7: 2 with inorganic ceramic pigment with the difference of embodiment one, puts into electrical heater and be fired into vitrified color balls under 700 ℃ of conditions.
Embodiment three: present embodiment and the difference of embodiment one be in the step 2 by weight percentage permeate agent be 0.5% and protective agent be 0.3% to mix to stir and make the milkiness mixed solution, mixed solution again with the high-quality Mierocrystalline cellulose be 10% emulsion mix dissolve each other after, be that pure-acrylic emulsion stirs and gets final product with surplus again.
Embodiment four: present embodiment and the difference of embodiment one are in the step 3 by weight percentage that vitrified color balls is 65%, mixed solution is 35% to stir after mixing and promptly make glass colored stone lacquer of the present invention.
Claims (7)
1. the preparation method of glass colored stone lacquer is characterized in that this preparation method's step is as follows:
Step 1, glass bead and inorganic ceramic pigment are mixed by weight 6.5～7.5: 1～2.5, put into electrical heater and under 550～850 ℃ of conditions, be fired into vitrified color balls;
Step 2, by weight percentage permeate agent be 0.2～1% and antiaging agent be 0.1～0.5% mix to stir and to make the milkiness mixed solution, mixed solution again with by weight percentage high-quality thickening material be 8～11% emulsions mix dissolve each other after, be that acrylic tackifier stirs and gets final product with surplus again;
Step 3, vitrified color balls and mixed solution that step 1 and step 2 are obtained, vitrified color balls is 50～80% by weight percentage, mixed solution is 20～50% to stir after mixing and promptly make glass colored stone lacquer of the present invention.
2. the preparation method of a kind of glass colored stone lacquer according to claim 1 is characterized in that permeate agent adopts peregal.
3. the preparation method of a kind of glass colored stone lacquer according to claim 1 is characterized in that thickening material selects Mierocrystalline cellulose for use.
4. the preparation method of a kind of glass colored stone lacquer according to claim 1 is characterized in that acrylic tackifier adopts pure third or benzene emulsion.
5. the preparation method of a kind of glass colored stone lacquer according to claim 1 is characterized in that glass bead in the step 1 is mixed by weight 7: 2 with inorganic ceramic pigment, puts into electrical heater and be fired into vitrified color balls under 700 ℃ of conditions.
6. the preparation method of a kind of glass colored stone lacquer according to claim 1, it is characterized in that in the step 2 by weight percentage permeate agent be 0.5% and protective agent be 0.3% to mix to stir and make the milkiness mixed solution, mixed solution again with Mierocrystalline cellulose be 10% emulsion mix dissolve each other after, be that pure-acrylic emulsion stirs and gets final product with surplus again.
7. the preparation method of a kind of glass colored stone lacquer according to claim 1 is characterized in that in the step 3 by weight percentage that vitrified color balls is 65%, mixed solution is 35% to stir after mixing and promptly make glass colored stone lacquer of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910073165A CN101701123A (en) | 2009-11-10 | 2009-11-10 | Preparation method of vitrified colorful stone lacquer |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910073165A CN101701123A (en) | 2009-11-10 | 2009-11-10 | Preparation method of vitrified colorful stone lacquer |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101701123A true CN101701123A (en) | 2010-05-05 |
Family
ID=42156051
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910073165A Pending CN101701123A (en) | 2009-11-10 | 2009-11-10 | Preparation method of vitrified colorful stone lacquer |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101701123A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102180620A (en) * | 2011-01-28 | 2011-09-14 | 牛智勇 | A kind of preparation technology of vitrified stone paint |
| CN103030335A (en) * | 2012-12-27 | 2013-04-10 | 北京天维宝辰化学产品有限公司 | Colored rock paint and preparation method thereof |
| CN111117319A (en) * | 2019-11-22 | 2020-05-08 | 石家庄泰图建材有限公司 | Glass color paint and preparation method thereof |
-
2009
- 2009-11-10 CN CN200910073165A patent/CN101701123A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102180620A (en) * | 2011-01-28 | 2011-09-14 | 牛智勇 | A kind of preparation technology of vitrified stone paint |
| CN102180620B (en) * | 2011-01-28 | 2012-10-10 | 牛智勇 | Preparation process of vitrified stone paint |
| CN103030335A (en) * | 2012-12-27 | 2013-04-10 | 北京天维宝辰化学产品有限公司 | Colored rock paint and preparation method thereof |
| CN103030335B (en) * | 2012-12-27 | 2015-02-18 | 北京天维宝辰化学产品有限公司 | Colored rock paint and preparation method thereof |
| CN111117319A (en) * | 2019-11-22 | 2020-05-08 | 石家庄泰图建材有限公司 | Glass color paint and preparation method thereof |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20100505 |