CN101684021A - Technique for treating sewage of aeration biofilter having function of reinforced deodorization - Google Patents
Technique for treating sewage of aeration biofilter having function of reinforced deodorization Download PDFInfo
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- CN101684021A CN101684021A CN200810198779A CN200810198779A CN101684021A CN 101684021 A CN101684021 A CN 101684021A CN 200810198779 A CN200810198779 A CN 200810198779A CN 200810198779 A CN200810198779 A CN 200810198779A CN 101684021 A CN101684021 A CN 101684021A
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- 239000010865 sewage Substances 0.000 title claims abstract description 56
- 238000000034 method Methods 0.000 title claims abstract description 28
- 238000005273 aeration Methods 0.000 title claims abstract description 23
- 238000004332 deodorization Methods 0.000 title claims abstract description 22
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 20
- 239000000945 filler Substances 0.000 claims abstract description 20
- 230000001877 deodorizing effect Effects 0.000 claims abstract description 13
- 229910052742 iron Inorganic materials 0.000 claims abstract description 10
- 241000894006 Bacteria Species 0.000 claims abstract description 5
- 230000008859 change Effects 0.000 claims abstract description 3
- 239000007789 gas Substances 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 17
- 244000005700 microbiome Species 0.000 claims description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 11
- 239000002245 particle Substances 0.000 claims description 10
- 239000011362 coarse particle Substances 0.000 claims description 8
- 230000000813 microbial effect Effects 0.000 claims description 8
- QMQXDJATSGGYDR-UHFFFAOYSA-N methylidyneiron Chemical compound [C].[Fe] QMQXDJATSGGYDR-UHFFFAOYSA-N 0.000 claims description 7
- 239000000919 ceramic Substances 0.000 claims description 6
- 238000012856 packing Methods 0.000 claims description 6
- 238000012545 processing Methods 0.000 claims description 6
- 230000004060 metabolic process Effects 0.000 claims description 4
- 239000010802 sludge Substances 0.000 claims description 4
- 239000000126 substance Substances 0.000 claims description 4
- 239000002699 waste material Substances 0.000 claims description 4
- 230000009471 action Effects 0.000 claims description 3
- 239000000470 constituent Substances 0.000 claims description 3
- 230000009615 deamination Effects 0.000 claims description 3
- 238000006481 deamination reaction Methods 0.000 claims description 3
- 230000003247 decreasing effect Effects 0.000 claims description 3
- 238000006477 desulfuration reaction Methods 0.000 claims description 3
- 230000023556 desulfurization Effects 0.000 claims description 3
- 230000000694 effects Effects 0.000 claims description 3
- 238000012544 monitoring process Methods 0.000 claims description 3
- 230000035764 nutrition Effects 0.000 claims description 3
- 235000016709 nutrition Nutrition 0.000 claims description 3
- 230000002787 reinforcement Effects 0.000 claims description 3
- 230000000630 rising effect Effects 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 239000002131 composite material Substances 0.000 abstract 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract 1
- 229910052799 carbon Inorganic materials 0.000 abstract 1
- 230000002349 favourable effect Effects 0.000 abstract 1
- 239000008187 granular material Substances 0.000 abstract 1
- 239000002689 soil Substances 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 238000012423 maintenance Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000003344 environmental pollutant Substances 0.000 description 3
- 239000003205 fragrance Substances 0.000 description 3
- 231100000719 pollutant Toxicity 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000015556 catabolic process Effects 0.000 description 2
- 238000006731 degradation reaction Methods 0.000 description 2
- 238000013461 design Methods 0.000 description 2
- 230000007246 mechanism Effects 0.000 description 2
- 239000010841 municipal wastewater Substances 0.000 description 2
- 230000003647 oxidation Effects 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 239000002912 waste gas Substances 0.000 description 2
- 239000002028 Biomass Substances 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 241000233866 Fungi Species 0.000 description 1
- 244000046052 Phaseolus vulgaris Species 0.000 description 1
- 235000010627 Phaseolus vulgaris Nutrition 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000001651 autotrophic effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000000706 filtrate Substances 0.000 description 1
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 238000000386 microscopy Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000005416 organic matter Substances 0.000 description 1
- 239000003415 peat Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000005070 sampling Methods 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000001117 sulphuric acid Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A50/00—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
- Y02A50/20—Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/10—Biological treatment of water, waste water, or sewage
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- Treating Waste Gases (AREA)
Abstract
The invention sets up a novel technique for treating sewage of an aeration biofilter having the function of reinforced deodorization. The technique combines sewage treatment and deodorization treatment, under the prerequisite of up-to-standard discharge, and adopts a composite filler to replace the ceramsite filler of the aeration biofilter; after domestication, the aeration biofilter can have thefunction of bio-deodorization while treating sewage. The technique is implemented by filling the composite filler which is composed of ceramsite, coarse granule active carbon and iron scrap with thevolume ratio being 1:0.2:0.15 into the aeration biofilter; adopting reek to be treated to replace air to be as the aeration gas source of the aeration biofilter; and after domestication, generating high efficient deodorizing bacteria groups such as desulfurated and deaminized bacteria and the like, so as to realize treating sewage and deodorizing stink gas simultaneously in the aeration biofilter.The invention does not change the equipment parameters of the original sewage treatment system and is favorable for upgrading and modifying civil sewage and industrial sewage plants.
Description
Affiliated technical field
The present invention has set up a kind of new technique for treating sewage of aeration biofilter with function of reinforced deodorization, will treat the aeration source of the gas of de-odorised foul smell as BAF, adopts this technology to carry out the biological deodorization of foul smell in normal processing sewage.Belong to environmental pollution improvement and prevention and control field.
Background technology
Along with improving constantly of wastewater treatment in China rate, in processes such as sewage disposal, sludge treatment, the odor pollution that a large amount of foul gass of generation cause is serious day by day.The gaseous constituent complexity of odorant pollutant mainly comprises: hydrogen sulfide, ammonia, amine etc.In the past, industrial sewage was handled or municipal wastewater is handled the qualified discharge of often only paying attention to sewage, and odorant pollutant is not effectively administered.People's Environmental awareness is progressively strengthened in recent years, and the odor pollution control problem in the sewage treatment process needs to be resolved hurrily.
The treatment process of foul gas mainly is divided into two big classes: (1) physico-chemical process: as direct burning method, catalyst oxidation method, soda acid ablution, absorption method, ion method etc.; (2) biological deodorizing method: bio-trickling filter method, soil deodorization method etc.At present, the biological deodorizing technology is applied extensively owing to the advantage of aspects such as running maintenance and enthusiasm.
The biological deodorizing method is to utilize autotrophic type and heterotroph microorganism under aerobic condition repugnant substance to be carried out oxygenolysis, and microorganism is decomposed into CO with the pollutent in the waste gas
2, H
2O and other inorganic salts, thus waste gas is purified.The mechanism of the soil deodorization method in the biological deodorizing is the water-soluble foul smell class in the foul gas, removed by the moisture absorption in the soil, but not the dissolubility foul smell then earlier by after the soil particle absorption again by microbiological degradation in the soil.The characteristics of soil deodorization method are that maintenance cost is low, but are unsuitable for rainfall, area that snowfall is big.The bio-trickling filter method is to utilize in the pond on the filler microorganism of apposition growth that odorant pollutant is decomposed, and the sewage of spray appropriate amount makes filler relative humidity remain on 80~95% above filler, and provides nutrition for microorganism.Filler requires adhering to of suitable microorganism and grows, and big specific surface area is arranged, and keeps higher microbial biomass, and is ageing-resistant etc.Filler commonly used has: bark, medium-soft plastics, fibering peat etc.
Summary of the invention
At present, Sewage treatment systems and the deodorizing treatment system in the Sewage Plant is separate system.The present invention seeks to by having set up a kind of new technique for treating sewage of aeration biofilter with function of reinforced deodorization Sewage treatment systems and deodorizing treatment system to be united two into one, relatively have following characteristics with conventional deodorization process: (1) has saved the floor space of conventional deodoration system; (2) reduced the investment of deodoration system; (3) reduced the workload of Sewage Plant running maintenance.Under the prerequisite that does not influence normal operation of sewage treatment facility and qualified discharge, make aerating biological filter sewage processing system have the function of biological deodorization simultaneously.
The mechanism of solution of the present invention is: (1) adopts compounded mix to substitute the ceramics filling of conventional BAF; (particle diameter is 1.0~1.5mm) to compounded mix, (particle diameter>1.0mm) form with waste iron filing is adding in 1: 0.2: 0.15 according to volume ratio to the coarse particles gac by haydite.Wherein at the bottom of packing layer filling haydite, the coarse particles gac and the iron filings that recharge above the haydite and mix.Utilize the removal effect of the interior electrolytic action reinforcement of iron carbon to organism in the sewage and repugnant substance, the iron filings in iron carbon filler district are to the S in the sewage
2-Have stronger crown_interception (2) by cultivating domestication, make BAF sewage disposal deodorization device produce high-efficiency desulfurization deamination bacterium, make BAF H
2S, NH
3Deng having bigger metabolism and removal capacity.Foul smell is cut into small bubbles by aeration head during with filler and fully contacts with sewage, makes the gas-liquid mass transfer of foul gas composition more complete.Water-soluble H
2S, NH
3Deng contacting with microorganism on the filler with in the sewage, adsorbed by Institute of Micro-biology, the metabolism by microorganism obtains oxidation or degraded then.Wherein sulphur is that thing is oxidized into sulphur and sulfuric acid, NH
3Be degraded into nitrogen by nitrated-denitrification.
The technical solution adopted for the present invention to solve the technical problems is: at first compounded mix is loaded in the BAF; (particle diameter is 1.0~1.5mm) to compounded mix, (particle diameter>1.0mm) form with waste iron filing is adding in 1: 0.2: 0.15 according to volume ratio to the coarse particles gac by haydite.Wherein at the bottom of packing layer filling haydite, the coarse particles gac and the iron filings that recharge above the haydite and mix.Then pending sewage is inserted the water inlet pipe of BAF.To treat the aeration source of the gas of de-odorised foul smell again, insert the inlet pipe of BAF by blower fan as BAF.Make pending sewage and foul gas pass through the ceramics filling district and the iron carbon filler district of BAF successively.On the one hand, microorganism utilizes the oxygen in the foul smell that the organism in the sewage is degraded, and carries out denitrogenation dephosphorizing, makes the effluent quality of BAF realize qualified discharge.On the other hand, after taming the deodorizing floras such as high-efficiency desulfurization deamination bacterium in the filler with the NH in the foul smell
3And H
2Foul smell compositions such as S are effectively removed by metabolism, and the foul gas decreasing ratio is reached more than 90%.
Beneficial effect of the present invention:
1. having set up a kind of new technique for treating sewage of aeration biofilter with function of reinforced deodorization unites two into one Sewage treatment systems and deodorizing treatment system, need not increase the floor space of original BAF, save the floor space and the investment of conventional odor removal.
2. reduced the running maintenance workload of conventional odor removal, the shortcoming of having avoided conventional deodorizing biological filter to stop up easily.
3. the present invention is suitable for the upgrading of the deodoration system of municipal wastewater processing and industrial sewage processing, remarkable in economical benefits.
4. the present invention does not change the processing parameter and the sewage disposal device parameter of original Sewage treatment systems.
Description of drawings
The present invention is further described below in conjunction with accompanying drawing.
Fig. 1 is the device longitudinal section structural map of the BAF of the present invention with function of reinforced deodorization.1. water inlet pipes among the figure, 2. inlet pipe, 3. gas blower, 4. ceramics filling district, 5. iron carbon mixed fillers district, 6. thief hole, 7. rising pipe, 8. air outlet, 9. effluent weir, 10. blow-down pipe.
Specific implementation method
1) filling of compounded mix: (particle diameter is 1.0~1.5mm) to compounded mix, (particle diameter>1.0mm) form with waste iron filing is adding in 1: 0.2: 0.15 according to volume ratio to the coarse particles gac by haydite.Wherein at the bottom of packing layer filling haydite, the coarse particles gac and the iron filings that recharge above the haydite and mix.Must sieve filler filler cleaning and particle diameter on request before the filling, guarantee the even of packing material size as far as possible.
2) domestication of deodorization microorganism.At first with the excess sludge of municipal sewage plant and sewage mixed by 1: 5, pump into then in the water inlet pipe 1 (as shown in Figure 1) of aeration biological filter device, circulation for some time, make filler 4 surfaces in the BAF generate certain thickness microbial film.Pending foul gas is fed in the inlet pipe 2 of BAF with blower fan 3 then, constantly feed fresh sanitary sewage simultaneously, provide nutrition to the microorganism on the microbial film.By regularly monitoring effluent quality respectively and give vent to anger middle NH at rising pipe 6 and air outlet 7
3And H
2Foul smell constituent concentrations such as S.When the effluent quality qualified discharge, foul gas deodorization rate reaches 90% when above, and domestication is finished.
3) in the domestication process, can be by the effluent quality of thief hole 5 sampling analyses monitoring different heights place packing layer.
4) after domestication is finished, insert BAF respectively by the water yield and the tolerance that design, the employing foul smell carries out aeration after replacing air by the blower fan pressurization, and beginning normally moves.Sewage carries out denitrogenation dephosphorizing and organic matter degradation, the NH in the foul smell in BAF
3And H
2In foul smell compositions such as S and the sewage with filler on microorganism fully contact and effectively removed, in the water outlet qualified discharge, the foul gas decreasing ratio is reached more than 90%.
Exemplifying embodiment:
At first active sludge is imported the BAF reactor, adopt and advance the sanitary sewage mode continuously, keep the flooding velocity of design, adopt the foul gas replaces air as the aeration source of the gas, after about 20-30 days cultivation domestication, can on filtrate, observe very thin one deck microbial film.The microscopy result shows and adheres in a large number as microorganisms such as thread fungus, beans shape worms on the microbial film, indicates that microbial film cultivates maturation.
After biofilm and domestication are finished, regularly water inlet, water outlet and the air inlet of BAF, the concentration of giving vent to anger are monitored.The sanitary sewage influent quality actual measurement of this example is as follows:
H in the water inlet volumetric loading of BAF and foul smell
2The concentration of S is respectively at 0.3~1.6KgCOD/ (m
3.d) and 0.8~2.3mg/m
3Between when changing, the water outlet and the middle COD that gives vent to anger
CrAnd H
2S is respectively less than 50mg/l and 0.04mg/m
3, satisfy the requirement of qualified discharge.
Claims (4)
1. the present invention has set up a kind of new technique for treating sewage of aeration biofilter with function of reinforced deodorization, Sewage treatment systems and deodorizing treatment system are united two into one, adopt compounded mix to substitute the ceramics filling of conventional BAF, utilize the removal effect of the interior electrolytic action reinforcement of iron carbon to organism in the sewage and repugnant substance, to treat that the de-odorised foul gas replaces the source of the gas of air as aeration, makes pending sewage and foul gas pass through the ceramics filling district and the iron carbon filler district of BAF successively.On the one hand, microorganism utilizes the oxygen in the foul smell that the organism in the sewage is degraded, and carries out denitrogenation dephosphorizing, makes the effluent quality of BAF realize qualified discharge.On the other hand, after taming the deodorizing floras such as high-efficiency desulfurization deamination bacterium in the filler with the NH in the foul smell
3And H
2Foul smell compositions such as S are effectively removed by metabolism, under the prerequisite of water outlet qualified discharge, the foul gas decreasing ratio are reached more than 90%.
2. employing compounded mix according to claim 1 substitutes the ceramics filling of conventional BAF; utilize the removal effect of the interior electrolytic action reinforcement of iron carbon to organism in the sewage and repugnant substance; (particle diameter is 1.0~1.5mm) to compounded mix, (particle diameter>1.0mm) form with waste iron filing is adding in 1: 0.2: 0.15 according to volume ratio to the coarse particles gac by haydite.Wherein at the bottom of packing layer filling haydite, the coarse particles gac and the iron filings that recharge above the haydite and mix.
3. a kind of technique for treating sewage of aeration biofilter with function of reinforced deodorization according to claim 1 is characterized in that: adopt and treat that the de-odorised foul gas replaces the source of the gas of air as aeration.This deodour method does not change the processing parameter and the sewage disposal device parameter of original Sewage treatment systems.
4. the microorganism that is used for sewage disposal and foul smell deodorization obtains by cultivating domestication.At first the mixed that the excess sludge and the sewage of municipal sewage plant are pressed 1: 5 pumps in the water inlet pipe of aeration biological filter device then, circulation for some time, makes the filling surface in the BAF generate certain thickness microbial film.Pending foul gas is fed in the inlet pipe of BAF with blower fan then, constantly feed fresh sanitary sewage simultaneously, provide nutrition to the microorganism on the microbial film.By regularly monitoring effluent quality respectively and give vent to anger middle NH at rising pipe and air outlet
3And H
2Foul smell constituent concentrations such as S.When the effluent quality qualified discharge, foul gas deodorization rate reaches 90% when above, and domestication is finished.The normal operation of beginning.
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Cited By (23)
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CN101891299A (en) * | 2010-07-05 | 2010-11-24 | 上海凡清环境工程有限公司 | Deodorizing method and system |
CN102161527A (en) * | 2010-12-22 | 2011-08-24 | 兰州交通大学 | Sponge iron-AT (Attapulgite)-PVF (Polyvinyl Fluoride) composite filler and application thereof on water treatment |
CN102295327A (en) * | 2011-07-19 | 2011-12-28 | 山东京鲁水务集团有限公司 | Electrolytic equipment for high-recovery-rate reverse-osmosis system |
CN102849844A (en) * | 2012-10-10 | 2013-01-02 | 南京大学 | Coupling bioreactor and method for simultaneously purifying malodorous gas and waste water by using same |
CN102863081A (en) * | 2011-07-08 | 2013-01-09 | 李鸿惠 | Three-dimensional ecological deodorization dephosphorization denitrification method as well as device and application |
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2008
- 2008-09-26 CN CN200810198779A patent/CN101684021A/en active Pending
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CN101891299A (en) * | 2010-07-05 | 2010-11-24 | 上海凡清环境工程有限公司 | Deodorizing method and system |
CN102161527A (en) * | 2010-12-22 | 2011-08-24 | 兰州交通大学 | Sponge iron-AT (Attapulgite)-PVF (Polyvinyl Fluoride) composite filler and application thereof on water treatment |
CN102863081B (en) * | 2011-07-08 | 2014-10-29 | 深圳地大水务工程有限公司 | Three-dimensional ecological deodorization dephosphorization denitrification method as well as device and application |
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