[go: up one dir, main page]

CN101683685A - A production technology of micro-alloyed wide and thick continuous casting slab - Google Patents

A production technology of micro-alloyed wide and thick continuous casting slab Download PDF

Info

Publication number
CN101683685A
CN101683685A CN200810013468A CN200810013468A CN101683685A CN 101683685 A CN101683685 A CN 101683685A CN 200810013468 A CN200810013468 A CN 200810013468A CN 200810013468 A CN200810013468 A CN 200810013468A CN 101683685 A CN101683685 A CN 101683685A
Authority
CN
China
Prior art keywords
production technology
thick
slab
wide
control
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN200810013468A
Other languages
Chinese (zh)
Other versions
CN101683685B (en
Inventor
张晓军
徐向阳
秦海山
仉勇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Angang Steel Co Ltd
Original Assignee
Angang Steel Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Angang Steel Co Ltd filed Critical Angang Steel Co Ltd
Priority to CN2008100134689A priority Critical patent/CN101683685B/en
Publication of CN101683685A publication Critical patent/CN101683685A/en
Application granted granted Critical
Publication of CN101683685B publication Critical patent/CN101683685B/en
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Landscapes

  • Continuous Casting (AREA)

Abstract

本发明提供一种微合金化宽厚连铸板坯生产技术,针对微合金化钢种,控制Als和P、S含量,采取较大电流电磁搅拌,控制中包过热度和结晶器锥度,增大窄面冷却水量,增加足辊数量,采用较高拉速以及实行弱冷工艺,生产宽厚断面铸坯。从而提高钢种的纯净度,控制铸坯的中心偏析,提高钢的热塑性,使等轴晶比率提高25%以上,鼓肚减少50%~80%,铸坯内部缺陷大幅度减少,轧后钢板探伤合格率提高六至十个百分点,各种表面裂纹基本消除,铸坯表面质量合格率达到99.4%。同时相应提高连铸产量,为连续化大批量生产中高碳微合金化高强度宽厚规格连铸板坯提供了成功经验,具有较高的推广应用价值。The invention provides a micro-alloyed wide-thick continuous casting slab production technology, aiming at micro-alloyed steel grades, controlling the content of Als, P and S, adopting relatively large current electromagnetic stirring, controlling the superheat of the tundish and the taper of the crystallizer, increasing the Increase the amount of cooling water on the narrow side, increase the number of foot rolls, adopt a higher casting speed and implement a weak cooling process to produce cast slabs with wide and thick sections. Thereby improving the purity of the steel, controlling the central segregation of the slab, improving the thermoplasticity of the steel, increasing the ratio of equiaxed grains by more than 25%, reducing the belly by 50% to 80%, and greatly reducing the internal defects of the slab. The qualified rate of flaw detection is increased by 6 to 10 percentage points, various surface cracks are basically eliminated, and the qualified rate of casting slab surface quality reaches 99.4%. At the same time, the continuous casting output is correspondingly increased, which provides successful experience for the continuous mass production of medium-high carbon micro-alloyed high-strength wide-thick continuous casting slabs, and has high promotion and application value.

Description

一种微合金化宽厚连铸板坯生产技术 A production technology of micro-alloyed wide and thick continuous casting slab

技术领域 technical field

本发明属于炼钢连铸技术领域,尤其涉及一种采用中高碳微合金化处理钢种生产宽厚连铸板坯的技术方法。The invention belongs to the technical field of steelmaking and continuous casting, and in particular relates to a technical method for producing wide and thick continuous casting slabs by adopting medium-high carbon micro-alloying treatment steel grades.

背景技术 Background technique

近年来,大规格的Nb、V、Ti微合金化高性能的低合金宽厚板材的市场需求不断增长,尤其是欧洲市场的需求量更为巨大。因此,国内各大钢铁企业竞相增上连铸宽厚板坯生产线,有条件的厂家亦争先恐后地生产这种微合金化高性能的低合金宽厚板坯。然而,在生产过程中发现,这些一直以生产普碳钢厚板坯为主的钢铁联合企业,一旦将钢种改为低合金的宽厚板坯,要想生产出内外质量合格和较高成坯率的Nb、V、Ti微合金化宽厚板坯,尚存在着很多亟待解决的问题。In recent years, the market demand for large-scale Nb, V, Ti micro-alloyed high-performance low-alloy wide-thick plates has been increasing, especially in the European market. Therefore, major domestic iron and steel enterprises are competing to add continuous casting wide-thick slab production lines, and qualified manufacturers are also scrambling to produce this kind of micro-alloyed high-performance low-alloy wide-thick slab. However, during the production process, it was discovered that these iron and steel complexes that have been mainly producing thick slabs of ordinary carbon steel, once the steel type is changed to low-alloy wide and thick slabs, if they want to produce slabs with qualified internal and external quality and high yield There are still many problems to be solved urgently in wide and thick slabs microalloyed with Nb, V and Ti.

其中,最为突出的问题是生产的微合金化宽厚板坯的质量合格率过低,致使铸坯的生产成本过高。除了部分铸坯内部存在内裂纹,造成轧后钢板探伤不合格以外,最严重的是铸坯表面质量不过关,存在大量的各种表面裂纹,如角裂、表面横裂纹等,从而造成铸坯表面质量不合格。严重的因表面裂纹报废,轻则必须进行清理或扒皮,增加了机械或火焰清理的工作量,加大了费用支出。另外,还存在着铸坯侧面鼓肚过大的问题,一般鼓肚都在10~15mm,这也是造成铸坯产生内裂纹(三角区裂纹、角部裂纹等)的原因之一。Among them, the most prominent problem is that the quality pass rate of the produced microalloyed wide and thick slab is too low, which leads to the high production cost of the cast slab. In addition to the internal cracks in some slabs, which caused the unqualified flaw detection of the steel plate after rolling, the most serious problem is that the surface quality of the slab is not up to standard, and there are a large number of various surface cracks, such as corner cracks, surface transverse cracks, etc., resulting in The surface quality is substandard. If it is serious, it will be scrapped due to surface cracks, and if it is light, it must be cleaned or peeled off, which increases the workload of mechanical or flame cleaning and increases the expense. In addition, there is also the problem of excessive bulging on the side of the slab. Generally, the bulging is 10-15mm, which is also one of the reasons for the internal cracks (triangle cracks, corner cracks, etc.) in the slab.

研究证明,之所以产生各种裂纹,其主要原因是由于在微合金化处理的过程中加入的合金元素造成的。在微合金化处理当中除加入一定量的Nb、V、Ti合金外,还普遍要求钢中的Mn含量达到1.3~1.9%,提高Mn含量和加入Nb、V、Ti合金的主要目的均在于提高铸坯以至于轧材的强度,满足低合金高强度的要求。然而在强度提高的同时,亦使铸坯的热塑性相应降低。铸坯在连铸过程中需经过连续的弯曲矫直变形,对于热塑性和韧性较好的低碳钢尚可,而对于经过微合金化处理的含碳量较高的中高碳钢来说,势必在弯曲矫直的过程中使表面铸壳被拉裂,或者在冷却过程中由于应力作用而形成裂纹。Studies have shown that the main reason for the occurrence of various cracks is the alloying elements added during the microalloying process. In addition to adding a certain amount of Nb, V, and Ti alloys in the microalloying treatment, it is generally required that the Mn content in the steel reaches 1.3-1.9%. The main purpose of increasing the Mn content and adding Nb, V, and Ti alloys is to improve The strength of the cast slab and even the rolled material meets the requirements of low alloy and high strength. However, while the strength is increased, the thermoplasticity of the slab is also reduced accordingly. The casting slab needs to undergo continuous bending and straightening deformation during the continuous casting process, which is acceptable for low-carbon steel with good thermoplasticity and toughness, but for medium-high carbon steel with high carbon content after micro-alloying treatment, it is bound to be During the bending and straightening process, the surface cast shell is cracked, or cracks are formed due to stress during the cooling process.

经检索,未发现有关同类产品生产技术的报道以及微合金化宽厚规格连铸板坯生产的相关资料记载。After searching, no reports on the production technology of similar products and relevant data records on the production of microalloyed wide and thick continuous casting slabs were found.

发明内容 Contents of the invention

本发明的目的就是针对上述问题及产生的原因,采取控制冶炼成分与控制连铸工艺、改进连铸设备相结合的办法,从而实现连续大批量生产合格的中高碳微合金化高强度宽厚规格连铸板坯。The purpose of the present invention is to solve the above problems and the causes, and adopt the method of combining the control of smelting components with the control of continuous casting process and the improvement of continuous casting equipment, so as to realize the continuous mass production of qualified medium-high carbon micro-alloyed high-strength wide-thick specification continuous castings. cast slab.

为此,本发明所提供的技术解决方案是:For this reason, the technical solution provided by the present invention is:

一种微合金化宽厚连铸板坯生产技术,采取控制冶炼成分与控制连铸工艺、改进设备相结合的措施,生产280~310×1800~2000mm宽厚断面铸坯。其具体工艺及控制方法为:A micro-alloyed wide-thick continuous casting slab production technology adopts the measures of controlling the smelting composition, controlling the continuous casting process, and improving equipment to produce 280-310×1800-2000mm wide-thick section casting slabs. Its specific process and control method are:

1、采用Nb、V、Ti微合金化钢种,控制Als≤0.008%。1. Use Nb, V, Ti micro-alloyed steels, and control Als≤0.008%.

2、控制钢中P<0.015%,S<0.005%。2. P<0.015% and S<0.005% in the control steel.

3、采用铸坯凝固末端较大电流的电磁搅拌方案,使二次冷却段双电磁搅拌电流均达到1000~1200A。3. The electromagnetic stirring scheme with a large current at the solidification end of the slab is adopted, so that the double electromagnetic stirring current in the secondary cooling section can reach 1000-1200A.

4、控制中包过热度为10~20℃。4. Control the superheat of the tundish at 10-20°C.

5、控制结晶器锥度,控制范围为9.3~9.8;5. Control the taper of the crystallizer, and the control range is 9.3 to 9.8;

6、铸坯窄面冷却水比正常量增大10~15%,控制范围为9~10Nm3/h;6. The cooling water on the narrow side of the slab is increased by 10-15% compared with the normal amount, and the control range is 9-10Nm 3 /h;

7、增加结晶器足辊,采用5~6对足辊生产;7. Increase crystallizer foot rolls and use 5 to 6 pairs of foot rolls for production;

8、采用较高拉坯速度,拉速控制在0.9~1.1m/min范围内;8. Higher casting speed is adopted, and the casting speed is controlled within the range of 0.9-1.1m/min;

9、实行弱冷工艺,冷却强度控制在0.75~0.9Nm3/t。9. The weak cooling process is implemented, and the cooling intensity is controlled at 0.75-0.9Nm 3 /t.

优先推荐的连铸工艺参数为:The preferred continuous casting process parameters are:

双电子搅拌电流均为1000A。The double electron stirring current is 1000A.

中包过热度控制在15℃。The superheat of the tundish is controlled at 15°C.

铸坯窄面冷却水比正常冷却水量增大10%。The cooling water on the narrow side of the slab is increased by 10% compared with the normal cooling water.

拉坯速度控制在1.0m/min。The casting speed is controlled at 1.0m/min.

冷却强度控制在0.80Nm3/t。The cooling intensity is controlled at 0.80Nm 3 /t.

结晶器锥度为9.5。The crystallizer taper is 9.5.

结晶器足辊由3对增加到5对。Crystallizer foot rolls increased from 3 pairs to 5 pairs.

由于采取上述措施,本发明取得了如下有益效果:Owing to taking above-mentioned measures, the present invention has obtained following beneficial effect:

一是提高了钢种的纯净度和铸坯的内在质量,有效地控制铸坯的中心偏析,提高钢在弯曲矫直时的热塑性,使偏析达到B0.5以下,等轴晶比率提高25%以上。二是极大地减少了鼓肚数量和规格,使产生的鼓肚明显减少,其大小由原来的10~15mm,缩小到0~5mm。三是轧后钢板内部缺陷减少,探伤合格率提高,平均探伤合格率平均提高六到十个百分点。四是各种表面裂纹基本消除,铸坯表面质量合格率由50%提高到99.4%。同时,由于采用比平时生产其他钢种铸坯更高的拉坯速度,因此其连铸产量亦得到相应提高。从而为高效优质连续化大批量生产中高碳微合金化高强度宽厚规格连铸板坯提供了成功经验,具有较高的推广应用价值。One is to improve the purity of the steel and the internal quality of the slab, effectively control the central segregation of the slab, improve the thermoplasticity of the steel during bending and straightening, make the segregation below B0.5, and increase the ratio of equiaxed grains by 25%. above. The second is to greatly reduce the number and specifications of the bulging belly, so that the produced bulging belly is significantly reduced, and its size is reduced from the original 10-15mm to 0-5mm. The third is that the internal defects of the rolled steel plate are reduced, the pass rate of flaw detection is increased, and the average pass rate of flaw detection is increased by an average of six to ten percentage points. Fourth, various surface cracks are basically eliminated, and the pass rate of the surface quality of the slab is increased from 50% to 99.4%. At the same time, due to the use of a higher casting speed than usual for other steel types, the continuous casting output has also been increased accordingly. Thus, it provides successful experience for high-efficiency, high-quality, continuous mass production of medium-high carbon micro-alloyed high-strength wide-thick specification continuous casting slabs, and has high promotion and application value.

具体实施方式Detailed ways

下面以生产规格为300×1950mm连铸坯为例,对本发明作以具体说明。Taking the continuous casting slab whose production specification is 300×1950 mm as an example, the present invention will be described in detail below.

本发明的特点是标本兼治,采取控制冶炼成分与控制连铸工艺、改进连铸设备相结合,生产出合格的中高碳微合金化高强度宽厚断面铸坯。其具体工艺参数及控制过程为:The present invention is characterized by treating both symptoms and root causes, combining control of smelting components with control of continuous casting process and improvement of continuous casting equipment to produce qualified medium-high-carbon micro-alloyed high-strength wide-thick section billets. Its specific process parameters and control process are:

对300×1950mm宽厚断面的铸坯,在冶炼过程中进行Nb、V、Ti微合金化处理,严格控制Als≤0.005%,降低钢中的AlN含量,以降低铸坯表面产生裂纹的几率。For slabs with a wide and thick section of 300×1950mm, Nb, V, and Ti microalloying treatments are carried out during the smelting process, and Als≤0.005% is strictly controlled to reduce the AlN content in the steel to reduce the probability of cracks on the surface of the slab.

减少钢中有害元素含量,控制P<0.015%,S<0.005%,以便有效地防止铸坯的中心偏析和内部裂纹。Reduce the content of harmful elements in steel, control P<0.015%, S<0.005%, so as to effectively prevent the central segregation and internal cracks of the slab.

采用铸坯凝固末端较大电流的电磁搅拌方案,二次冷却段双电磁搅拌电流均达到1000A,提高铸坯内在质量。The electromagnetic stirring scheme with a large current at the end of the solidification of the slab is adopted, and the double electromagnetic stirring current in the secondary cooling section reaches 1000A, which improves the internal quality of the slab.

控制中包过热度为15℃,增加铸坯内部等轴晶的比率。Control the superheat of the tundish to 15°C, and increase the ratio of equiaxed grains inside the slab.

控制结晶器锥度为9.5;窄面冷却水比正常量增大10%,控制在9.3Nm3/h;以控制和减小鼓肚。Control the taper of the crystallizer to 9.5; increase the cooling water on the narrow side by 10% compared with the normal amount, and control it at 9.3Nm 3 /h; to control and reduce the belly.

以增加结晶器足辊的办法进一步控制鼓肚和内部裂纹,将足辊增加到5对,有效防止轧后钢板内裂,提高钢板探伤合格率。The bulge and internal cracks are further controlled by increasing the foot rolls of the crystallizer, and the number of foot rolls is increased to 5 pairs, which can effectively prevent internal cracking of the steel plate after rolling and improve the qualified rate of steel plate flaw detection.

采用较高拉坯速度,拉速控制在1.0m/min;实行弱冷工艺,冷却强度控制在0.8Nm3/t,从而可控制铸坯表面产生横裂纹和角裂。High casting speed is adopted, and the casting speed is controlled at 1.0m/min; the weak cooling process is implemented, and the cooling intensity is controlled at 0.8Nm 3 /t, so that the transverse cracks and corner cracks on the surface of the casting billet can be controlled.

按照上述工艺方法对冶炼和连铸生产进行控制和组织,即可高效优质地生产出中高碳微合金化宽厚断面的合格连铸板坯。By controlling and organizing smelting and continuous casting production according to the above-mentioned process method, qualified continuous casting slabs with medium-high carbon microalloying wide and thick sections can be produced efficiently and with high quality.

Claims (8)

1, a kind of production technology of microalloying wide and thick continous casting slab is characterized in that, takes to control and smelts composition and the measure of controlling continuous casting process, improving equipment and combine, and produces the generous section casting blank of 280~310 * 1800~2000mm; Its concrete technology and control method are:
1), adopts Nb, V, Ti microalloying steel grade, control Als≤0.008%;
2), control P<0.015% in the steel, S<0.005%;
3), adopt the electromagnetic agitation scheme of the big electric current of casting blank solidification end, make the two electromagnetic agitation electric currents of secondary cooling section all reach 1000~1200A;
4), the bag degree of superheat is 10~20 ℃ in the control;
5), crystallization control device tapering, control range is 9.3~9.8;
6), strand leptoprosopy cooling water increases 10~15% than normal amount, control range is 9~10Nm 3/ h;
7), increase crystallizer foot roll, adopt 5~6 pairs of sufficient roller productions;
8), adopt higher casting speed, pulling rate to be controlled in 0.9~1.1m/min scope;
9), carry out weak cold technology, intensity of cooling is controlled at 0.75~0.9Nm 3/ t.
2, the thick strand production technology of microalloying according to claim 1 is characterized in that, described pair of electromagnetic agitation electric current is 1000A.
3, the thick strand production technology of microalloying according to claim 1 is characterized in that, the middle bag degree of superheat is controlled at 15 ℃.
4, the thick strand production technology of microalloying according to claim 1 is characterized in that, strand leptoprosopy cooling water increases 10% than normal amount.
5, the thick strand production technology of microalloying according to claim 1 is characterized in that described casting speed is controlled at 1.0m/min.
6, the thick strand production technology of microalloying according to claim 1 is characterized in that described intensity of cooling is controlled at 0.8Nm 3/ t.
7, the thick strand production technology of microalloying according to claim 1 is characterized in that, described crystallizer foot roll is 5 pairs.
8, the thick strand production technology of microalloying according to claim 1 is characterized in that, described conical degree of crystallizer is 9.5.
CN2008100134689A 2008-09-28 2008-09-28 Production method of microalloyed wide and thick continuous casting slab Expired - Fee Related CN101683685B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN2008100134689A CN101683685B (en) 2008-09-28 2008-09-28 Production method of microalloyed wide and thick continuous casting slab

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN2008100134689A CN101683685B (en) 2008-09-28 2008-09-28 Production method of microalloyed wide and thick continuous casting slab

Publications (2)

Publication Number Publication Date
CN101683685A true CN101683685A (en) 2010-03-31
CN101683685B CN101683685B (en) 2011-04-13

Family

ID=42047179

Family Applications (1)

Application Number Title Priority Date Filing Date
CN2008100134689A Expired - Fee Related CN101683685B (en) 2008-09-28 2008-09-28 Production method of microalloyed wide and thick continuous casting slab

Country Status (1)

Country Link
CN (1) CN101683685B (en)

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101967597A (en) * 2010-10-10 2011-02-09 舞阳钢铁有限责任公司 Method for producing high-thickness Z-direction steel plate
CN102310178A (en) * 2011-07-08 2012-01-11 南阳汉冶特钢有限公司 Method for solving center segregation of casting blank
CN102399929A (en) * 2010-09-08 2012-04-04 鞍钢股份有限公司 A Method for Reducing Surface Cracks of Aluminum Deoxidized High Carbon Steel Slab
CN102409221A (en) * 2011-12-02 2012-04-11 武汉钢铁(集团)公司 Method for controlling edge crack of peritectic steel containing niobium or boron
CN104057047A (en) * 2014-06-17 2014-09-24 首钢总公司 Sectioned foot roller for preventing narrow surface of extra-thick plate blank from bulging
CN104399929A (en) * 2014-11-28 2015-03-11 首钢总公司 Method for reducing longitudinal division of weather-proof steel continuously cast slab
CN105499528A (en) * 2015-10-23 2016-04-20 首钢总公司 Continuous casting method of high-carbon steel plate blank
CN113857449A (en) * 2021-09-14 2021-12-31 湖南华菱涟源钢铁有限公司 Preparation method of oriented silicon steel casting blank and casting blank system
CN115608936A (en) * 2022-10-24 2023-01-17 攀钢集团攀枝花钢铁研究院有限公司 A high-efficiency electromagnetic stirring control method for large-section rectangular billet continuous casting

Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102399929A (en) * 2010-09-08 2012-04-04 鞍钢股份有限公司 A Method for Reducing Surface Cracks of Aluminum Deoxidized High Carbon Steel Slab
CN102399929B (en) * 2010-09-08 2013-07-31 鞍钢股份有限公司 Method for reducing surface cracks of aluminum-deoxidized high-carbon steel casting blank
CN101967597A (en) * 2010-10-10 2011-02-09 舞阳钢铁有限责任公司 Method for producing high-thickness Z-direction steel plate
CN101967597B (en) * 2010-10-10 2012-08-29 舞阳钢铁有限责任公司 Method for producing high-thickness Z-direction steel plate
CN102310178A (en) * 2011-07-08 2012-01-11 南阳汉冶特钢有限公司 Method for solving center segregation of casting blank
CN102409221A (en) * 2011-12-02 2012-04-11 武汉钢铁(集团)公司 Method for controlling edge crack of peritectic steel containing niobium or boron
CN104057047A (en) * 2014-06-17 2014-09-24 首钢总公司 Sectioned foot roller for preventing narrow surface of extra-thick plate blank from bulging
CN104057047B (en) * 2014-06-17 2016-08-03 首钢总公司 A kind of merogenesis foot roller preventing extra-thick plate blank leptoprosopy bulge
CN104399929A (en) * 2014-11-28 2015-03-11 首钢总公司 Method for reducing longitudinal division of weather-proof steel continuously cast slab
CN105499528A (en) * 2015-10-23 2016-04-20 首钢总公司 Continuous casting method of high-carbon steel plate blank
CN105499528B (en) * 2015-10-23 2018-06-26 首钢集团有限公司 A kind of high-carbon steel slab continuous cast method
CN113857449A (en) * 2021-09-14 2021-12-31 湖南华菱涟源钢铁有限公司 Preparation method of oriented silicon steel casting blank and casting blank system
CN113857449B (en) * 2021-09-14 2023-10-10 湖南华菱涟源钢铁有限公司 Preparation method of oriented silicon steel casting blank and casting blank system
CN115608936A (en) * 2022-10-24 2023-01-17 攀钢集团攀枝花钢铁研究院有限公司 A high-efficiency electromagnetic stirring control method for large-section rectangular billet continuous casting

Also Published As

Publication number Publication date
CN101683685B (en) 2011-04-13

Similar Documents

Publication Publication Date Title
CN101683685A (en) A production technology of micro-alloyed wide and thick continuous casting slab
EP3851216B1 (en) Method for producing ultra-thin hot-rolled strip steel
CN100503864C (en) A method for producing ultra-fine grain steel plates by continuous casting and rolling of medium and thin slabs
EP3859042A1 (en) High-strength high-toughness non-quenched and tempered round steel and preparation method
CN102423795B (en) Continuous casting method for high manganese steel
CN106825478B (en) Control method for corner cracks of boron-containing steel plate blank
CN100542715C (en) Continuous Casting Method of 450mm×360mm Medium Carbon Manganese Steel Bloom
WO2021128590A1 (en) 600 mpa-grade steel bar for reinforced concrete and preparation method therefor
CN103924030B (en) Smelting method of ultra-low oxygen pure steel
JP2024514967A (en) Highly efficient welded steel for bridges and its manufacturing method
CN103320691B (en) Manufacturing method for Q345 series coil plates
CN102703815A (en) 600 MPa-grade hot-rolled dual-phase steel and preparation method thereof
CN101549353A (en) A method for producing low-alloy large-size square steel by continuous casting and rolling
CN111014603B (en) Double-roller casting-rolling production method of boron-added steel
CN105803152B (en) The center porosity control method of 30CrMo circular pipe blank steel strands
CN104745940A (en) A kind of anti-corrosion hot-rolled ribbed steel bar and its production process
CN114293093A (en) A kind of 600MPa grade vanadium-titanium microalloyed hot-rolled steel bar and production method thereof
CN106917050B (en) A kind of continuous cast method of anti-corrosion spiral
CN105779869B (en) The method of 30Mn circular pipe blank steel Inner Quality of Billet control
CN107881289A (en) A kind of method for improving steel high-temp plastic
CN109332619B (en) YQ450NQR 1B-shaped steel bloom shell quality control method
CN117226059A (en) Reduction control method for improving macro-segregation and semi-macro-segregation of high-carbon low-alloy steel
CN115740378A (en) Preparation method of austenitic stainless steel 0Cr19Ni10 continuous casting round billet for bearing part
CN108467995B (en) Electric Furnace Continuous Casting Production of BG65Mn Steel for Ball Mill Grinding Rod and Its Preparation Method
EP4144460B1 (en) Cooling and reduction method for improving quality of casting slab

Legal Events

Date Code Title Description
C06 Publication
PB01 Publication
C10 Entry into substantive examination
SE01 Entry into force of request for substantive examination
C14 Grant of patent or utility model
GR01 Patent grant
CF01 Termination of patent right due to non-payment of annual fee
CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20110413

Termination date: 20200928