CN101643912B - Aluminum product cleaning agent and production method thereof - Google Patents
Aluminum product cleaning agent and production method thereof Download PDFInfo
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- CN101643912B CN101643912B CN2009100442627A CN200910044262A CN101643912B CN 101643912 B CN101643912 B CN 101643912B CN 2009100442627 A CN2009100442627 A CN 2009100442627A CN 200910044262 A CN200910044262 A CN 200910044262A CN 101643912 B CN101643912 B CN 101643912B
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- aluminum
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- deionized water
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- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 title claims abstract description 31
- 229910052782 aluminium Inorganic materials 0.000 title claims abstract description 31
- 239000012459 cleaning agent Substances 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 23
- 239000000463 material Substances 0.000 claims abstract description 19
- 238000003756 stirring Methods 0.000 claims abstract description 18
- 239000004115 Sodium Silicate Substances 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 16
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 16
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 16
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims abstract description 16
- 229910052911 sodium silicate Inorganic materials 0.000 claims abstract description 16
- PMYUVOOOQDGQNW-UHFFFAOYSA-N hexasodium;trioxido(trioxidosilyloxy)silane Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-][Si]([O-])([O-])O[Si]([O-])([O-])[O-] PMYUVOOOQDGQNW-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 15
- 238000001914 filtration Methods 0.000 claims abstract description 6
- 239000013078 crystal Substances 0.000 claims abstract description 4
- 239000002994 raw material Substances 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 abstract description 10
- 239000011521 glass Substances 0.000 abstract description 4
- 238000005303 weighing Methods 0.000 abstract 1
- 241000519995 Stachys sylvatica Species 0.000 description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- CUDYYMUUJHLCGZ-UHFFFAOYSA-N 2-(2-methoxypropoxy)propan-1-ol Chemical compound COC(C)COC(C)CO CUDYYMUUJHLCGZ-UHFFFAOYSA-N 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 239000013530 defoamer Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 238000002791 soaking Methods 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- -1 sodium alkylsulfonate Chemical class 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- RYCLIXPGLDDLTM-UHFFFAOYSA-J tetrapotassium;phosphonato phosphate Chemical compound [K+].[K+].[K+].[K+].[O-]P([O-])(=O)OP([O-])([O-])=O RYCLIXPGLDDLTM-UHFFFAOYSA-J 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
- 238000004065 wastewater treatment Methods 0.000 description 1
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 description 1
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- Detergent Compositions (AREA)
- Cleaning And De-Greasing Of Metallic Materials By Chemical Methods (AREA)
Abstract
Description
技术领域technical field
本发明涉及新材料加工领域，特别是一种用于洗涤铝制品表面和铝容器的铝材清洗剂及其生产方法。The invention relates to the field of new material processing, in particular to an aluminum cleaning agent for cleaning the surface of aluminum products and aluminum containers and a production method thereof.
背景技术Background technique
铝材的表面经过阳极氧化、吸附着色后，其美丽的表面色彩可保持较长时间，而且耐氧化、耐腐蚀。但是，铝材在生产过程中，会受到各种设备的污染，产生白斑、霉斑以及油污等污渍，这些污渍必须在进行表面处理之前进行彻底清洗。目前市面流行的铝材清洗剂配方：非离子型表面活性剂：5.0、烷基磺酸钠：3.0、无水硅酸钠：3.0、焦磷酸钾：3.0、二丙甘醇甲醚：5.0和水：81.0，这是一种含磷清洗剂，其废水排放后，会污染环境水体，使其繁衍大量的藻类。中国专利(申请号为200710056524.2)公开了一种“铝材专用清洗剂”，其组分及重量配比分别为：无机酸15-45％，有机酸3-8％，表面活性剂5-12％，渗透剂8-15％，有机溶剂10-20％，水25-35％，其中的无机酸是磷酸与硫酸的混合物；该清洗剂虽然可在常温下通过浸泡的方式迅速清洗铝材表面，有效去除铝材表面白斑、霉斑、油污及硬脂酸锌等杂物，永久去除铝材表面的白斑、霉斑，但该清洗剂仍然属于含磷清洗剂，而且其酸性较强，使用后的废水处理较为困难。After the surface of aluminum is anodized, adsorbed and colored, its beautiful surface color can be maintained for a long time, and it is resistant to oxidation and corrosion. However, during the production process of aluminum, it will be polluted by various equipment, resulting in stains such as white spots, mildew spots, and oil stains. These stains must be thoroughly cleaned before surface treatment. The currently popular aluminum cleaning agent formula in the market: non-ionic surfactant: 5.0, sodium alkylsulfonate: 3.0, anhydrous sodium silicate: 3.0, potassium pyrophosphate: 3.0, dipropylene glycol methyl ether: 5.0 and Water: 81.0, this is a phosphorus-containing cleaning agent. After its wastewater is discharged, it will pollute the environmental water body and cause a large number of algae to multiply. Chinese patent (application number 200710056524.2) discloses a "special cleaning agent for aluminum materials", its components and weight ratio are: 15-45% of inorganic acid, 3-8% of organic acid, 5-12% of surfactant %, penetrating agent 8-15%, organic solvent 10-20%, water 25-35%, the inorganic acid is a mixture of phosphoric acid and sulfuric acid; although this cleaning agent can quickly clean the surface of aluminum materials by soaking at room temperature , effectively remove white spots, mildew spots, oil stains and zinc stearate and other sundries on the surface of aluminum materials, permanently remove white spots and mildew spots on the surface of aluminum materials, but this cleaning agent is still a phosphorus-containing cleaning agent, and its acidity is strong, use The subsequent wastewater treatment is more difficult.
发明内容Contents of the invention
针对现有技术存在的不足，本发明所要解决的技术问题是提供一种生产成本较低、对环境没有影响、且其后续使用能够节省大量清洗用水的铝材清洗剂及其生产方法。Aiming at the deficiencies in the prior art, the technical problem to be solved by the present invention is to provide an aluminum material cleaning agent with low production cost, no impact on the environment, and its subsequent use can save a lot of cleaning water and its production method.
本发明所采取的技术方案是发明一种铝材清洗剂：是由下列原料按重量份额配制而成：The technical scheme adopted in the present invention is to invent a kind of cleaning agent for aluminum material: it is formulated by weight ratio from the following raw materials:
速溶无水硅酸钠：10-15份Instant anhydrous sodium silicate: 10-15 parts
碳酸钠：10-15份Sodium carbonate: 10-15 parts
非离子型表面活性剂：600-800份Nonionic surfactant: 600-800 parts
层状结晶二硅酸钠：150-200份Layered crystalline sodium disilicate: 150-200 parts
去离子水：18000-19000份。Deionized water: 18000-19000 parts.
其优化的方案一：是由下列原料按重量份额配制而成：Its optimized scheme one: it is prepared by the weight ratio of the following raw materials:
速溶无水硅酸钠：10份 Instant anhydrous sodium silicate: 10 parts
碳酸钠：15份Sodium carbonate: 15 parts
非离子型表面活性剂：800份Nonionic surfactant: 800 parts
层状结晶二硅酸钠：150份Layered crystalline sodium disilicate: 150 parts
去离子水：18000份。Deionized water: 18000 parts.
其优化的方案二：是由下列原料按重量份额配制而成：Its optimized scheme two: be prepared by following raw material by weight ratio:
速溶无水硅酸钠：15份 Instant anhydrous sodium silicate: 15 parts
碳酸钠：10份Sodium carbonate: 10 parts
非离子型表面活性剂：600份Nonionic surfactant: 600 parts
层状结晶二硅酸钠：200份Layered crystalline sodium disilicate: 200 parts
去离子水：19000份。Deionized water: 19000 parts.
其优化的方案三：是由下列原料按重量份额配制而成：Its optimized scheme three: it is prepared from the following raw materials by weight:
速溶无水硅酸钠：12份 Instant anhydrous sodium silicate: 12 parts
碳酸钠：12份Sodium carbonate: 12 parts
非离子型表面活性剂：700份Nonionic surfactant: 700 parts
层状结晶二硅酸钠：180份Layered crystalline sodium disilicate: 180 parts
去离子水：18500份。Deionized water: 18500 parts.
去离子水的电导率在2us以下。The conductivity of deionized water is below 2us.
其铝材清洗剂的生产方法为：称取配方量的去离子水，搅拌状态下加入速溶无水硅酸钠、碳酸钠、层状结晶二硅酸钠，充分分散溶解约20-30min，静置1-3小时，过滤后，将溶液搅拌并加入非离子表面活性剂，搅拌均匀即可。The production method of the cleaning agent for aluminum materials is as follows: Weigh the deionized water of the formula amount, add instant anhydrous sodium silicate, sodium carbonate, and layered crystal disilicate sodium disilicate under stirring state, fully disperse and dissolve for about 20-30min, and statically Set aside for 1-3 hours, after filtering, stir the solution and add non-ionic surfactant, stir evenly.
本发明的铝材清洗剂，由于采用无磷配方，因而，对环境不会产生影响；同时，在使用时无需添加消泡剂，故客户使用时能够节省大量的清洗水，从而降低使用成本。此外，在配方中，水的比例占了绝大多数，因此，其生产成本很低。The aluminum material cleaning agent of the present invention adopts a phosphorus-free formula, so it has no impact on the environment; at the same time, it does not need to add a defoamer during use, so customers can save a lot of cleaning water when using it, thereby reducing the use cost. In addition, in the formula, the proportion of water accounts for the vast majority, so its production cost is very low.
具体实施方式Detailed ways
实施例一：称取18000克去离子水，搅拌状态下加入10克速溶无水硅酸钠、10克碳酸钠、150克层状结晶二硅酸钠，充分分散溶解约20-30min，静置1-3小时，过滤后，将溶液搅拌并加入800克非离子表面活性剂，搅拌均匀即为本发明的铝材清洗剂。Embodiment 1: Weigh 18,000 grams of deionized water, add 10 grams of instant anhydrous sodium silicate, 10 grams of sodium carbonate, and 150 grams of layered crystalline sodium disilicate under stirring, fully disperse and dissolve for about 20-30 minutes, and let stand After 1-3 hours, after filtering, stir the solution and add 800 grams of nonionic surfactant, and stir evenly to obtain the aluminum material cleaning agent of the present invention.
实施例二：称取19000克去离子水，搅拌状态下加入15克速溶无水硅酸钠、15克碳酸钠、200克层状结晶二硅酸钠，充分分散溶解约20-30min，静置1-3小时，过滤后，将溶液搅拌并加入600克非离子表面活性剂，搅拌均匀即为本发明的铝材清洗剂。Embodiment 2: Weigh 19,000 grams of deionized water, add 15 grams of instant anhydrous sodium silicate, 15 grams of sodium carbonate, and 200 grams of layered crystalline sodium disilicate under stirring, fully disperse and dissolve for about 20-30 minutes, and let it stand After 1-3 hours, after filtering, stir the solution and add 600 grams of nonionic surfactant, and stir evenly to obtain the aluminum material cleaning agent of the present invention.
实施例三：称取18500克去离子水，搅拌状态下加入12克速溶无水硅酸钠、12克碳酸钠、180克层状结晶二硅酸钠，充分分散溶解约20-30min，静置1-3小时，过滤后，将溶液搅拌并加入700克非离子表面活性剂，搅拌均匀即为本发明的铝材清洗剂。Embodiment 3: Weigh 18,500 grams of deionized water, add 12 grams of instant anhydrous sodium silicate, 12 grams of sodium carbonate, and 180 grams of layered crystalline sodium disilicate under stirring, fully disperse and dissolve for about 20-30 minutes, and let it stand After 1-3 hours, after filtering, stir the solution and add 700 grams of nonionic surfactant, and stir evenly to obtain the aluminum material cleaning agent of the present invention.
本发明的铝材清洗剂适用于洗涤铝制品表面和铝容器，也可用于玻璃和精密五金的清洗，特别适用于软材质玻璃的清洗。The aluminum material cleaning agent of the invention is suitable for cleaning the surface of aluminum products and aluminum containers, and can also be used for cleaning glass and precision hardware, and is especially suitable for cleaning soft glass.
Claims (5)
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2009100442627A CN101643912B (en) | 2009-09-01 | 2009-09-01 | Aluminum product cleaning agent and production method thereof |
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| CN2009100442627A CN101643912B (en) | 2009-09-01 | 2009-09-01 | Aluminum product cleaning agent and production method thereof |
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| CN101643912B true CN101643912B (en) | 2010-11-17 |
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Families Citing this family (7)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106635440A (en) * | 2016-12-19 | 2017-05-10 | 青岛古高生物科技有限公司 | Cleaning liquid of blood coagulation analysis instrument |
| CN108330008A (en) * | 2018-04-10 | 2018-07-27 | 苏州锐耐洁电子科技新材料有限公司 | A kind of plastics injection mould cleaning agent |
| CN109652227A (en) * | 2018-12-25 | 2019-04-19 | 广东富行洗涤剂科技有限公司 | Neutral cleaners and preparation method after a kind of anodic oxidation of aluminiun materials |
| CN112442429A (en) * | 2020-11-13 | 2021-03-05 | 苏州德韬科技有限公司 | Industrial cleaning agent and preparation method thereof |
| CN114570689B (en) * | 2022-03-23 | 2023-06-27 | 安徽鑫发铝业有限公司 | Production method of high-precision new energy vehicle body aluminum profile |
| CN115505935B (en) * | 2022-10-27 | 2023-11-24 | 祁阳宏泰铝业有限公司 | Cleaning process before surface treatment of aluminum alloy profile |
| CN115613045B (en) * | 2022-11-03 | 2025-01-07 | 纳峰真空镀膜（上海）有限公司 | Cleaning agent capable of improving chromatic aberration and preparation method and application thereof |
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