CN101634184A - Large-sized ultra-thin stoneware-quality tiles and preparation method thereof - Google Patents
Large-sized ultra-thin stoneware-quality tiles and preparation method thereof Download PDFInfo
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- CN101634184A CN101634184A CN200910039857A CN200910039857A CN101634184A CN 101634184 A CN101634184 A CN 101634184A CN 200910039857 A CN200910039857 A CN 200910039857A CN 200910039857 A CN200910039857 A CN 200910039857A CN 101634184 A CN101634184 A CN 101634184A
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- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 239000000835 fiber Substances 0.000 claims abstract description 25
- 239000000919 ceramic Substances 0.000 claims abstract description 12
- 239000002994 raw material Substances 0.000 claims abstract description 9
- 238000003825 pressing Methods 0.000 claims abstract description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000010304 firing Methods 0.000 claims description 13
- 239000002557 mineral fiber Substances 0.000 claims description 12
- 239000000758 substrate Substances 0.000 claims description 12
- 239000002002 slurry Substances 0.000 claims description 9
- 238000000498 ball milling Methods 0.000 claims description 7
- 238000000034 method Methods 0.000 claims description 7
- 239000000843 powder Substances 0.000 claims description 6
- 239000010456 wollastonite Substances 0.000 claims description 6
- 229910052882 wollastonite Inorganic materials 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 5
- 238000005516 engineering process Methods 0.000 claims description 5
- 229910004298 SiO 2 Inorganic materials 0.000 claims description 4
- 229910010413 TiO 2 Inorganic materials 0.000 claims description 4
- 239000003623 enhancer Substances 0.000 claims description 4
- 238000007639 printing Methods 0.000 claims description 4
- 150000001875 compounds Chemical class 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 2
- INJRKJPEYSAMPD-UHFFFAOYSA-N aluminum;silicic acid;hydrate Chemical compound O.[Al].[Al].O[Si](O)(O)O INJRKJPEYSAMPD-UHFFFAOYSA-N 0.000 claims description 2
- 239000010443 kyanite Substances 0.000 claims description 2
- 229910052850 kyanite Inorganic materials 0.000 claims description 2
- 239000000320 mechanical mixture Substances 0.000 claims description 2
- 238000012856 packing Methods 0.000 claims description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 9
- 239000012744 reinforcing agent Substances 0.000 abstract description 7
- 239000000463 material Substances 0.000 abstract description 6
- 239000000203 mixture Substances 0.000 abstract description 4
- 229910052681 coesite Inorganic materials 0.000 abstract description 3
- 229910052906 cristobalite Inorganic materials 0.000 abstract description 3
- 238000005034 decoration Methods 0.000 abstract description 3
- 239000000377 silicon dioxide Substances 0.000 abstract description 3
- 235000012239 silicon dioxide Nutrition 0.000 abstract description 3
- 229910052682 stishovite Inorganic materials 0.000 abstract description 3
- 229910052905 tridymite Inorganic materials 0.000 abstract description 3
- 230000007613 environmental effect Effects 0.000 abstract description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 238000005265 energy consumption Methods 0.000 abstract 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 239000002689 soil Substances 0.000 description 6
- 239000004575 stone Substances 0.000 description 6
- 238000010521 absorption reaction Methods 0.000 description 4
- 239000004372 Polyvinyl alcohol Substances 0.000 description 3
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 3
- 239000011449 brick Substances 0.000 description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 description 3
- 238000000748 compression moulding Methods 0.000 description 3
- 235000013312 flour Nutrition 0.000 description 3
- 229920002451 polyvinyl alcohol Polymers 0.000 description 3
- 239000004576 sand Substances 0.000 description 3
- 239000011734 sodium Substances 0.000 description 3
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 3
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 3
- 239000002699 waste material Substances 0.000 description 3
- 229920002472 Starch Polymers 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 238000000465 moulding Methods 0.000 description 2
- 238000010020 roller printing Methods 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000011467 thin brick Substances 0.000 description 2
- 206010013786 Dry skin Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 235000013339 cereals Nutrition 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000001254 oxidized starch Substances 0.000 description 1
- 235000013808 oxidized starch Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 235000019422 polyvinyl alcohol Nutrition 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000001488 sodium phosphate Substances 0.000 description 1
- 229910000162 sodium phosphate Inorganic materials 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000013638 trimer Substances 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Landscapes
- Glass Compositions (AREA)
- Finishing Walls (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The invention relates to large-sized ultra-thin stoneware-quality tiles and a preparation method thereof, and the utilized raw materials comprise the following components according to percentage by weight: 55-68% of SiO2, 14-28% of Al2O3, 0.5-1.8% of Fe2O3, 0.2-1.5% of TiO2, 1-12% of CaO, 0.3-1% of MgO and 2-5% of K2O+Na2O. The ultra-thin stoneware-quality tile products prepared by the composition of the invention adopt dry pressing forming, the forming thickness is 3-6mm, and the specification of the finished product can reach (900-1000)mm*(1800-2000)mm. 5-30% of fiber reinforcing agent is introduced into a green body, so as to ensure that the ultra-thin stoneware-quality tile has enough strength and toughness. The invention greatly lightens the weight of ceramic tiles per area, realizes the purposes of saving energy, and lowering energy consumption better and belongs to environmental protection building decoration materials.
Description
Technical field:
The present invention relates to technical field of construction and decoration materials, particularly a kind of large-sized ultra-thin stoneware-quality tiles and preparation method thereof.
Background technology:
Generally along with the increase of product specification, the thickness of Ceramic Tiles also constantly increases.The raw material that the unit area Ceramic Tiles is consumed is also many more, has increased the weight of the carrying of building.Ultra-thin brick economizes in raw materials, and cuts down the consumption of energy, and has become the ceramic industry developing tendency in future.Standard GB/T 4100.4-1999 dry-pressing Ceramic Tiles the 4th part Shi matter brick water absorption rate need be controlled between 6%＜E≤10%.Ultra-thin stoneware-quality tiles has guaranteed the intensity and the pliability of product owing to added relatively large fiber-like reinforcing agent, make product specification meet or exceed 900 * 1800mm, and moulding thickness only is 3～6mm.This large-sized ultra-thin stoneware-quality tiles high resilience and pliability preferably resolve the fragility problem of Imitation Rock Porcelain Tiles.Simultaneously it also has the unexistent characteristics such as big, thin, light of other common size ceramic product.After glaze is decorated, have imitative stone material or wallpaper decoration effect, can be used as the facing plate and replace wallpaper, hard board, stone material etc.
Summary of the invention:
The objective of the invention is to overcome the deficiencies in the prior art part, a kind of big specification Shi matter brick of ultra-thin environmental protection is provided.This ultra-thin brick adhibit quality is good, the intensity height, and good straightness degree, high resilience and pliability, the abrasion resistance height, antifouling property is good, fire-proof high-temperature resistant, long service life and "dead" pollution.This product can alleviate the load-bearing of building, has fabulous ornamental again.
The present invention adopts following technical scheme to realize above-mentioned purpose:
A kind of large-sized ultra-thin stoneware-quality tiles and preparation method thereof adopts dry-pressing formed technology to introduce 5～30% fiber enhancers in base substrate, the main chemical compound of base substrate: SiO
255～68%, Al
2O
314～28%, Fe
2O
30.5～1.8%, TiO
20.2～1.5%, CaO 1～12%, MgO 0.3～1%, K
2O+Na
2O 2～5%.
Fiber enhancer of the present invention can be mineral fibers such as acicular wollastonite, basalt mineral fiber etc., also can be synthesize ceramic fiber such as alumina silicate fibre, alumina fibre, kyanite fiber and other manmade inorganic fibre etc.Can adopt the one or more combination in mineral fibers or the synthesize ceramic fiber in the prescription.3～6 microns of average fibre diameters, draw ratio 10～60, and have certain hydrophily, dispersiveness will be got well in mud.
A kind of large-sized ultra-thin stoneware-quality tiles, described preparation method's processing step comprises: selected raw material, and---------------------old---combined filament slurry in the pulp storage tank is shaped batching---drying---glazing printing ornament---roller kilns once-firing---pick---edging---classification---packing warehouse-in in spray-on process powder process in deironing in grinding slurrying to stack old, homogenizing.Described preparation method's processing step press forming stage is adopted dry method compression moulding, and molding thickness is 3～6mm, and product specification can meet or exceed 900 * 1800mm.Also can first biscuiting after the drying kiln drying is dry again the glazing printing ornament carry out glaze firing, i.e. twice firing.Require in the ball-milling technology blank ball milling to 10000-hole sieve is tailed over 0.8%～1.0%; Roller kilns once-firing temperature is 1140 ℃～1160 ℃.Twice firing biscuiting temperature is 1130 ℃～1150 ℃, 1080 ℃～1100 ℃ of temperature of glaze firing.Fibre stuff needs independentization slurry to carry out mechanical mixture with common slurry again.
Be that the base substrate of 1050mm * 2060mm * (3～6) mm has enough intensity simultaneously, reduce damaged in order to guarantee to enter specification before the calcining kiln.Needing to add the base substrate reinforcing agent cooperates the clay of more high adhesion stress to increase the intensity of green compact.The base substrate reinforcing agent can be the one or more combination of polyvinyl alcohol, sodium carboxymethylcellulose or oxidized starch.
The present invention adopts the beneficial effect that can reach after the technique scheme to be:
Introduce intensity and toughness that relatively large ceramic fibre improves finished bricks.Have the unexistent characteristics such as big, thin, light of other common size ceramic product.Mode by serigraphy or roller printing after the glazing obtains required pattern, clear-cut texture, and pattern is true to nature naturally, can be used as the substitute of wallpaper, hard board, stone material etc.
The specific embodiment:
Embodiment one:
The bed material essential element is (percentage by weight) according to chemical composition: SiO
266.8%, Al
2O
318.8%, Fe
2O
30.8%, TiO
20.4%, CaO 8.0%, and MgO 0.7%, K
2O+Na
2O 4.5%.Various raw materials (expression by weight percentage) content is: acicular wollastonite 18%, and flag soil 10%, middle temperature sand 20%, high temperature stone flour 18% reclaims waste material 8%, mixed soil 26%.Add base substrate reinforcing agent polyvinyl alcohol 0.1%, sodium carboxymethylcellulose 0.1%.Used acicular wollastonite short fiber is that a kind of diameter is 5 μ m, and draw ratio is 15～18 natural mineral fiber, its SiO2 content 〉=51, CaO content 〉=45.Acicular wollastonite adopts 14 tons of little ball mills to change slurry separately, and other raw material is prepared burden into 40 tons of ball mill ball millings by forklift, adds the water that accounts for total siccative weight 43% and 0.2% water reducing agent sodium phosphate trimer simultaneously to improve grinding efficiency.It is 0.8～1.0% that the ball milling fineness is controlled at tailing over of 10000-hole sieve.Mix the acicular wollastonite slurry after mud sieves through deironing in pulp storage tank, mixing speed is 12 rev/mins, and mixing time is 24 hours.Cross 40 mesh sieve powders by spraying, make the powder of water content 5～7%.Powder particle slyness, good fluidity, bulk density is big.Grain composition is: greater than 30 orders 6～10%; 30～60 orders 〉=70; 60～80 orders≤12; Less than 80 orders≤5.With the compression moulding after old 24 hours of this powder, the moulding specification is 1050mm * 2060mm * 4mm.Through 180 ℃ of temperature dryings, base substrate moisture is controlled at below 0.4%.The dry tenacity of base substrate reaches 1.8Mpa like this, and can stand the operation of glaze line and drench glaze, the processing of subsequent handlings such as roller printing, and do not break.Wherein drenching the glaze amount is 900 grams, and glaze slip proportion is 1.5, through 1145 ℃ of high temperature once-firings.After testing, its water absorption rate is 8.5%, fracture strength 400N.
Embodiment two:
Introduce basalt mineral fiber, various raw materials (expression by weight percentage) content is: basalt mineral fiber 22%, and flag soil 10%, middle temperature sand 20%, high temperature stone flour 14% reclaims waste material 8%, mixed soil 26%.Add base substrate reinforcing agent polyvinyl alcohol 0.08%, converted starch 0.12%.Used basalt mineral fiber is that a kind of diameter is 4 μ m, and draw ratio is 30 natural mineral fiber.Its main chemical compound is SiO
250%Al
2O
320%CaO+MgO 28%.Basalt mineral fiber adopts 14 tons of little ball mills to change slurry separately, and surplus stock is prepared burden into 40 tons of ball mill ball millings by forklift, and other step just adopts firing process twice with embodiment one.Adopt 1140 ℃ of high temperature biscuitings earlier, glaze volume and glaze proportion are constant, 1085 ℃ of temperature of glaze firing.After testing, its water absorption rate is 7.5%, fracture strength 450N.
Embodiment three:
Introduce manmade inorganic fibre, various raw materials (expression by weight percentage) content is: manmade inorganic fibre 22%, and flag soil 10%, middle temperature sand 20%, high temperature stone flour 8% reclaims waste material 14%, mixed soil 26%.Add base substrate reinforcing agent converted starch 0.2%, sodium carboxymethylcellulose 0.08%.Used manmade inorganic fibre is that a kind of diameter is 3 μ m, and draw ratio is 30 fiber, its SiO2 48.7%, Al
2O
337.7%, Fe
2O
31.2%, TiO
21.3%, CaO 5.5%, and MgO 0.8%, K
2O 3.3%, Na
2O 0.3%.Other step is with embodiment one.After testing, its water absorption rate is 9.5%, fracture strength 430N.
Claims (4)
1. large-sized ultra-thin stoneware-quality tiles and preparation method thereof,---------------------old---combined filament slurry in the pulp storage tank is shaped batching---drying---glazing printing ornament---roller kilns once-firing---pick---edging---classification---packing warehouse-in in spray-on process powder process in deironing in grinding slurrying to stack old, homogenizing to comprise the steps: selected raw material, it is characterized in that: adopt dry-pressing formed technology in base substrate, to introduce 5～30% fiber enhancers, the main chemical compound of base substrate: SiO
255～68%, Al
2O
314～28%, Fe
2O
30.5～1.8%, TiO
20.2～1.5%, CaO 1～12%, MgO 0.3～1%, K
2O+Na
2O2～5%.
2. a kind of large-sized ultra-thin stoneware-quality tiles according to claim 1, it is characterized in that: described fiber enhancer is mineral fibers such as acicular wollastonite, basalt mineral fiber, or synthesize ceramic fiber such as alumina silicate fibre, alumina fibre, kyanite fiber and other manmade inorganic fibre; Adopt the one or more combination in mineral fibers or the synthesize ceramic fiber in the prescription; 3～6 microns of average fibre diameters, draw ratio 10～60, and possess hydrophilic property, dispersiveness will be got well in mud.
3. a kind of large-sized ultra-thin stoneware-quality tiles according to claim 1 is characterized in that: the ultra-thin stoneware-quality tiles formed product thickness of preparation is 3～6mm, and product specification reaches 900～1000mm * 1800～2000mm.
4. the preparation method of large-sized ultra-thin stoneware-quality tiles according to claim 1, it is characterized in that: can also first biscuiting after the drying kiln drying is dry again the glazing printing ornament carry out glaze firing, be twice firing, require in the ball-milling technology blank ball milling to 10000-hole sieve is tailed over 0.8%～1.0%; Roller kilns once-firing temperature is 1140 ℃～1160 ℃.Twice firing biscuiting temperature is 1130 ℃～1150 ℃, 1080 ℃～1100 ℃ of temperature of glaze firing.Fibre stuff needs independentization slurry to carry out mechanical mixture with common slurry again.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910039857A CN101634184A (en) | 2009-05-31 | 2009-05-31 | Large-sized ultra-thin stoneware-quality tiles and preparation method thereof |
| CN 201010122755 CN101898892B (en) | 2009-05-31 | 2010-03-02 | Stoneware sheet and preparation method thereof |
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|---|---|---|---|
| CN200910039857A CN101634184A (en) | 2009-05-31 | 2009-05-31 | Large-sized ultra-thin stoneware-quality tiles and preparation method thereof |
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| Publication Number | Publication Date |
|---|---|
| CN101634184A true CN101634184A (en) | 2010-01-27 |
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|---|---|---|---|
| CN200910039857A Pending CN101634184A (en) | 2009-05-31 | 2009-05-31 | Large-sized ultra-thin stoneware-quality tiles and preparation method thereof |
| CN 201010122755 Active CN101898892B (en) | 2009-05-31 | 2010-03-02 | Stoneware sheet and preparation method thereof |
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| CN 201010122755 Active CN101898892B (en) | 2009-05-31 | 2010-03-02 | Stoneware sheet and preparation method thereof |
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| CN101898892A (en) * | 2009-05-31 | 2010-12-01 | 广东蒙娜丽莎陶瓷有限公司 | Stoneware sheet and preparation method thereof |
| CN102795846A (en) * | 2012-08-16 | 2012-11-28 | 广东宏陶陶瓷有限公司 | Formula of thin micro-powder polished tile |
| CN104326733A (en) * | 2014-10-16 | 2015-02-04 | 佛山市禾才科技服务有限公司 | High strength ceramic thin plate and preparation method thereof |
| CN105712702A (en) * | 2015-09-18 | 2016-06-29 | 安庆惠嘉新型建材有限公司 | Process for producing tiles in walls |
| CN106747375A (en) * | 2016-12-21 | 2017-05-31 | 蒙娜丽莎集团股份有限公司 | ZrO2Short fiber reinforced Ceramic Tiles and preparation method thereof |
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-
2010
- 2010-03-02 CN CN 201010122755 patent/CN101898892B/en active Active
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| CN113443893B (en) * | 2021-09-01 | 2021-12-07 | 新明珠集团股份有限公司 | Ceramic body, ceramic plate and preparation method thereof |
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| CN117886619A (en) * | 2024-03-15 | 2024-04-16 | 蒙娜丽莎集团股份有限公司 | High-strength dry-process powder-making mud-free ceramic blank and preparation method thereof |
| CN117886619B (en) * | 2024-03-15 | 2024-06-11 | 蒙娜丽莎集团股份有限公司 | High-strength dry-process powder-making mud-free ceramic blank and preparation method thereof |
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| CN101898892B (en) | 2013-11-06 |
| CN101898892A (en) | 2010-12-01 |
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