CN101618618B - Antiskid glass - Google Patents
Antiskid glass Download PDFInfo
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- CN101618618B CN101618618B CN200910101018XA CN200910101018A CN101618618B CN 101618618 B CN101618618 B CN 101618618B CN 200910101018X A CN200910101018X A CN 200910101018XA CN 200910101018 A CN200910101018 A CN 200910101018A CN 101618618 B CN101618618 B CN 101618618B
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- glass
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- antiskid
- anti slip
- glaze
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- 239000011521 glass Substances 0.000 title claims abstract description 44
- 239000005357 flat glass Substances 0.000 claims abstract description 33
- 239000004576 sand Substances 0.000 claims abstract description 25
- 238000005245 sintering Methods 0.000 claims abstract description 20
- 239000002994 raw material Substances 0.000 claims abstract description 15
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 claims description 20
- 229910003460 diamond Inorganic materials 0.000 claims description 17
- 239000010432 diamond Substances 0.000 claims description 17
- 239000000428 dust Substances 0.000 claims description 17
- 230000003213 activating effect Effects 0.000 claims description 14
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 12
- 150000005846 sugar alcohols Polymers 0.000 claims description 10
- QAZLUNIWYYOJPC-UHFFFAOYSA-M sulfenamide Chemical compound [Cl-].COC1=C(C)C=[N+]2C3=NC4=CC=C(OC)C=C4N3SCC2=C1C QAZLUNIWYYOJPC-UHFFFAOYSA-M 0.000 claims description 10
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 9
- 238000005496 tempering Methods 0.000 abstract description 5
- 239000000463 material Substances 0.000 abstract description 3
- 230000005855 radiation Effects 0.000 abstract description 2
- 239000013543 active substance Substances 0.000 abstract 3
- 239000003344 environmental pollutant Substances 0.000 abstract 1
- 231100000719 pollutant Toxicity 0.000 abstract 1
- 239000010410 layer Substances 0.000 description 20
- 230000000694 effects Effects 0.000 description 8
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000011229 interlayer Substances 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000007639 printing Methods 0.000 description 4
- 238000007650 screen-printing Methods 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- HLGLVCYQUDXULU-UHFFFAOYSA-N NS[S+]1C(C=CC=C2)=C2N=C1 Chemical compound NS[S+]1C(C=CC=C2)=C2N=C1 HLGLVCYQUDXULU-UHFFFAOYSA-N 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 238000000137 annealing Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000005336 safety glass Substances 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- 230000004927 fusion Effects 0.000 description 2
- 239000005315 stained glass Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000000853 adhesive Substances 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 238000007667 floating Methods 0.000 description 1
- 238000009408 flooring Methods 0.000 description 1
- 239000008240 homogeneous mixture Substances 0.000 description 1
- 239000005340 laminated glass Substances 0.000 description 1
- 230000002045 lasting effect Effects 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 239000011368 organic material Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 238000009877 rendering Methods 0.000 description 1
- 238000005488 sandblasting Methods 0.000 description 1
- RBNWAMSGVWEHFP-UHFFFAOYSA-N trans-p-Menthane-1,8-diol Chemical compound CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
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- Surface Treatment Of Glass (AREA)
Abstract
The invention discloses antiskid glass which comprises flat glass. An antiskid layer is formed on the surface of the flat glass in a sintering way, and is made of the following raw materials by weight percent: 50 percent to 80 percent of base glaze, 15 percent to 40 percent of sands, 0.15 permillage to 5 percent of active agent and 0.1 permillage to 6 percent of accelerator. In the technical scheme, the raw materials are reformed, the active agent and the accelerator with certain amount are added, and the materials, the active agent and the accelerator are uniformly mixed to be arranged on the flat glass by silk screen so as to form a firm and durable antiskid layer through tempering high-temperature sintering. The antiskid layer is completely combined with the glass, therefore, the antiskid glass is durable and difficult to fall off, has long service lift and no pollutant radiation, and cannot generate any hurt to a human, and is green and healthy. Compared with the prior antiskid glass, the invention has more excellent performance, better wear resistance and longer service life, efficiently puts an end to existence of sand holes and micropores, and improves the quality of a product.
Description
Technical field
The invention belongs to glass processing and manufacturing field, be specifically related to a kind of anti slip glass.
Background technology
For a long time, people use wooden perhaps pottery as flooring material, though practical still deficiency attractive in appearance, the two is neither transparent, can't form the rendering effect of mutual friendship brightness with light, and skidproof effect is had a greatly reduced quality after getting wet in addition.Improving constantly of Along with people's living standard strengthens the interest of practicality product attractive in appearance again day by day.Antiskid glass floor arises at the historic moment, and begins to come into public place of entertainment, hotel, market even huge numbers of families.But mostly early stage anti slip glass is pattern glass, ice glass, sand blasting glass, etching glass, fusion cast glass etc.But one of which light transmission difference or light distortion are serious, and its two skidproof effect is very unobvious, after especially getting wet, are prone to cause the pedestrian to fall, and bring inconvenience and hidden danger to people.So people have researched and developed novel anti slip glass, it had both had superior non-skid property, when getting wet, also can obviously not reduce its skidproof effect, and simultaneously its permeability is good, light distortion is little, elegant in appearance, received people's favor deeply.
Present common anti slip glass; Mostly be that the anti-skidding glaze of sintering one deck is formed on the plate glass face; Like publication number is that the patent documentation of CN101289282A discloses a kind of anti slip glass and manufacturing approach thereof; This anti slip glass comprises that a plate glass and one deck contain the skid resistant course of glaze and sand grains, and the two sintering forms, and wherein diamond dust adopts and directly sheds or process with the mode that glaze directly mixes.Be prone to like this cause the sand grains skewness at glass surface, adhesive bond power is not enough, has micropore between sand grains and glaze and exists, and has quality problems such as more sand holes, pin hole, influences service life, skidproof effect.
And for example publication number is that the patent documentation of CN2908663Y discloses a kind of antiskid glass floor, and the skid resistant course that is sintered in this surface of plate glass by a plate glass and one is formed, and this skid resistant course is that mixed uniformly glass glaze and diamond dust constitute.Also include surfactant in the homogeneous mixture of this glass glaze and diamond dust, according to the explanation of this patent documentation: add surfactant, have good adhesive property after making diamond dust and glaze mixing, and diamond dust is adsorbed among the glaze well.This shows; Here mainly be to utilize surfactant to increase the surface tension of glaze, behind silk-screen, the diamond dust and the glaze that are positioned on the screen printing glaze layer outer surface have bigger bond area like this; Thereby the bonding force that improves between the two avoids diamond dust to come off; But, only adding the surface tension that above-mentioned surfactant increases glaze, the diamond dust that can cause like this being arranged in glaze is not easy the floating outer surface of going up the screen printing glaze layer more; Cause the diamond dust distributive law of glaze layer outer surface to reduce, thereby cause the wearability of the skid resistant course behind the sintering, coefficient of friction to reduce.And such scheme does not have substantive help for quality problems such as eliminating sand holes, pin hole yet.
Summary of the invention
In order to solve above-mentioned technical problem; The purpose of this invention is to provide a kind of anti slip glass, on existing anti slip glass basis, the skid resistant course raw material is transformed; Make the existence that its performance is more superior, wearability better, is effectively stopped sand holes, micropore, longer service life.
In order to reach above-mentioned purpose, the technical scheme below the present invention has adopted:
A kind of anti slip glass; Comprise plate glass; Said surface of plate glass sintering is formed with skid resistant course, and said skid resistant course is to be made by following raw material, and this raw material according to percentage by weight is: basic glaze 50%～80%, sand grains 15%～40%, activating agent 1.5 ‰～5% and promoter 1 ‰～6%.
Wherein, basic glaze is the carrier of fusion and bonding other compositions, and said basic glaze is a high temperature ink, promptly can tolerate the oiliness or the water color ink of 150 ℃～750 ℃ of high temperature, in addition, also can select the varnish that contains ethyl cellulose, terpinol, alkyd resins for use.
Wherein, sand grains mainly plays anti-skidding effect, and said sand grains is preferably diamond dust or white fused alumina, and diamond dust hard wear resistant, lasting stability, fire-resistant heat resistance are good, even if under the situation that has water to exist, can be as other floors yet tangible reduction non-skid property; White fused alumina has above-mentioned performance equally, and with respect to diamond dust, when printing, white fused alumina is distributed in the glaze laminar surface more easily, thereby makes anti slip glass have better non-skid property.
Wherein, impel sand grains to distribute, increase the density of sand grains, thereby improve the non-skid property of the skid resistant course of sintering formation at glaze layer outer surface to the outer surface of screen printing glaze layer thereby activating agent mainly act as the surface tension that reduces glaze.As preferably; Above-mentioned activating agent is the mixture of neopelex and polyalcohol; Wherein, the weight ratio of said neopelex and polyalcohol is 2: 3, so under the same conditions with respect to the glaze that does not add activating agent; The glaze that contains above-mentioned activating agent is behind silk-screen, and the distributive law of screen printing glaze laminar surface diamond dust or white fused alumina can obviously improve more than 40%.
Wherein, mainly acting as of promoter improves the adhesive property between each material in the skid resistant course, impel between aggregate and liquid phase combine tightr, the appearance of stopping sand holes, pin hole.As preferably, above-mentioned promoter is the mixture of sulfenamide and resorcinol, and said sulfenamide and resorcinol weight ratio are 3: 4.The use of above-mentioned promoter; Can effectively make inorganic aggregates (diamond dust or white fused alumina) and organic material (basic glaze) zero-gap bond, behind sintering, the two forms whole; Diamond dust or white fused alumina can not come off, thereby the skid resistant course that sintering forms has good anti-skidding and wear-resisting effect.
For the sand grains that guarantees the skid resistant course outer surface is evenly distributed, said raw material mixes the back silk-screen and forms said skid resistant course through sintering again at surface of plate glass.The half tone order number of above-mentioned raw materials silk-screen is 60～150 orders.
For the ease of being evenly distributed on the skid resistant course outer surface and having good skidproof effect, the granularity of above-mentioned sand grains is 60～150 orders.
The present invention transforms raw material owing to adopted above technical scheme, adds the activating agent and the promoter of doses; Mix the back silk-screen on plate glass; Again through the tempering high temperature sintering, thereby form the skid resistant course of strong, durable, what skid resistant course and glass were complete combines; Durable is difficult to come off; Long service life, the contamination-free radiation; Human body is not caused any harm green health.With respect to existing anti slip glass, the existence that performance of the present invention is more superior, wearability better, is effectively stopped sand holes, micropore has improved product quality, longer service life.
Description of drawings
Fig. 1 is the structural representation of the embodiment of the invention 1.
Fig. 2 is the structural representation of the embodiment of the invention 2.
The specific embodiment
Do a detailed explanation below in conjunction with the accompanying drawing specific embodiments of the invention.
Embodiment 1:
A kind of anti slip glass as shown in Figure 1 comprises that thickness is the plate glass 1 of 15mm, and said plate glass 1 surperficial sintering is formed with and is the skid resistant course 2 that graininess distributes.
The manufacture process of present embodiment is following:
According to percentage by weight be: basic glaze 53.85%, sand grains 40%, activating agent 1.5 ‰ and promoter 6%.Said basic glaze is a high temperature ink; Said sand grains is a diamond dust, and granularity is 100～150 orders; Said activating agent is the mixture of neopelex and polyalcohol (present embodiment is selected different basic hexahydroxylic alcohols for use), and the weight ratio of said neopelex and polyalcohol is 2: 3; Said promoter is the mixture of sulfenamide (present embodiment selects 2 for use, 1-benzothiazole sulfenamide) and resorcinol, and said sulfenamide and resorcinol weight ratio are 3: 4; With above-mentioned raw materials in proportion after the mixing and stirring silk-screen form the glaze layer on plate glass 1 surface, the glaze layer thickness of printing is between 0.75mm～2mm, the half tone order number of silk-screen is 100 orders; Treat after the glaze layer drying above-mentioned plate glass to be sent into annealing furnace high temperature tempering; Temperature is 560 ℃～630 ℃; Thereby the glaze layer sintering on above-mentioned plate glass 1 surface forms above-mentioned skid resistant course 2, and plate glass 1 forms safety glass, and stress is between 95Mpa～200Mpa.
Embodiment 2:
A kind of anti slip glass as shown in Figure 2 comprises that thickness is the two-layer plate glass 1 of 10mm, thereby is that the PVB intermediate layer forms laminated glass between the two-layer plate glass 1, and the plate glass 1 surperficial sintering on said upper strata is formed with and is the skid resistant course 2 that graininess distributes.
The manufacture process of present embodiment is following:
According to percentage by weight be: basic glaze 79.9%, sand grains 15%, activating agent 5% and promoter 1 ‰.Said basic glaze is a high temperature ink; Said sand grains is a white fused alumina, and granularity is 60～100 orders; Said activating agent is the mixture of neopelex and polyalcohol (present embodiment is selected different basic hexahydroxylic alcohols for use), and the weight ratio of said neopelex and polyalcohol is 2: 3; Said promoter is the mixture of sulfenamide (present embodiment selects 2 for use, 1-benzothiazole sulfenamide) and resorcinol, and said sulfenamide and resorcinol weight ratio are 3: 4; With above-mentioned raw materials in proportion after the mixing and stirring silk-screen form the glaze layer on plate glass 1 surface, the glaze layer thickness of printing is between 0.75mm～2mm, the half tone order number of silk-screen is 60 orders; Treat after the glaze layer drying above-mentioned plate glass to be sent into annealing furnace high temperature tempering, temperature is 650 ℃～720 ℃, thereby forms above-mentioned skid resistant course 2 at the glaze layer sintering on above-mentioned plate glass 1 surface, and this plate glass 1 forms safety glass; There are the plate glass of skid resistant course and other transparent or coloured glass to carry out the product that the interlayer processing makes present embodiment above-mentioned sintering again.The interlayer anti slip glass of present embodiment can be used as antiskid glass floor and uses.
Embodiment 3:
A kind of anti slip glass, product structure is identical with embodiment 2, and the manufacture process of present embodiment is following:
According to percentage by weight be: basic glaze 65%, sand grains 28%, activating agent 3% and promoter 4%.Said basic glaze is a high temperature ink; Said sand grains is a white fused alumina, and granularity is 60～100 orders; Said activating agent is the mixture of neopelex and polyalcohol (present embodiment is selected different basic hexahydroxylic alcohols for use), and the weight ratio of said neopelex and polyalcohol is 2: 3; Said promoter is the mixture of sulfenamide (present embodiment selects 2 for use, 1-benzothiazole sulfenamide) and resorcinol, and said sulfenamide and resorcinol weight ratio are 3: 4; With above-mentioned raw materials in proportion after the mixing and stirring silk-screen form the glaze layer on plate glass 1 surface, the glaze layer thickness of printing is between 0.75mm～2mm, the half tone order number of silk-screen is 60 orders; Treat after the glaze layer drying above-mentioned plate glass to be sent into annealing furnace high temperature tempering, temperature is 650 ℃～720 ℃, thereby forms above-mentioned skid resistant course 2 at the glaze layer sintering on above-mentioned plate glass 1 surface, and this plate glass 1 forms safety glass; There are the plate glass of skid resistant course and other transparent or coloured glass to carry out the product that the interlayer processing makes present embodiment above-mentioned sintering again.The interlayer anti slip glass of present embodiment can be used as antiskid glass floor and uses.
Claims (8)
1. anti slip glass; Comprise plate glass (1); The surperficial sintering of said plate glass (1) is formed with skid resistant course (2); It is characterized in that said skid resistant course (2) is to be made by following raw material, this raw material according to percentage by weight is: basic glaze 50%～80%, sand grains 15%～40%, activating agent 1.5 ‰～5% and promoter 1 ‰～6%; Wherein, said activating agent is the mixture of neopelex and polyalcohol, and said promoter is the mixture of sulfenamide and resorcinol.
2. a kind of anti slip glass according to claim 1 is characterized in that, said basic glaze is a high temperature ink.
3. a kind of anti slip glass according to claim 1 is characterized in that, said sand grains is diamond dust or white fused alumina.
4. a kind of anti slip glass according to claim 1 is characterized in that, the weight ratio of said neopelex and polyalcohol is 2: 3.
5. a kind of anti slip glass according to claim 1 is characterized in that, said sulfenamide and resorcinol weight ratio are 3: 4.
6. a kind of anti slip glass according to claim 1 is characterized in that, said raw material mixes the back silk-screen and forms said skid resistant course (2) through sintering again on plate glass (1) surface.
7. a kind of anti slip glass according to claim 6 is characterized in that, the half tone order number of said raw material silk-screen is 60～150 orders.
8. according to each described a kind of anti slip glass in the claim 1 to 7, it is characterized in that the granularity of said sand grains is 60～150 orders.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910101018XA CN101618618B (en) | 2009-07-30 | 2009-07-30 | Antiskid glass |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910101018XA CN101618618B (en) | 2009-07-30 | 2009-07-30 | Antiskid glass |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101618618A CN101618618A (en) | 2010-01-06 |
| CN101618618B true CN101618618B (en) | 2012-03-28 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN200910101018XA Expired - Fee Related CN101618618B (en) | 2009-07-30 | 2009-07-30 | Antiskid glass |
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| Country | Link |
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| CN (1) | CN101618618B (en) |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107640905B (en) * | 2017-03-29 | 2020-05-19 | 谢晓元 | Boron glass anti-skid particle blank and preparation process thereof, and anti-skid toughened glass and preparation process thereof |
| CN107201083B (en) * | 2017-05-25 | 2020-07-31 | 山东国瓷康立泰新材料科技有限公司 | A kind of inkjet anti-skid glass ink and preparation method thereof |
| CN107140851A (en) * | 2017-06-20 | 2017-09-08 | 江苏秀强玻璃工艺股份有限公司 | A kind of preparation method of the glass decoration panel with high temperature mirror material layer |
| CN108383393B (en) * | 2018-01-19 | 2019-08-09 | 维达力实业(深圳)有限公司 | Cover-plate glass and preparation method thereof |
| CN108275880A (en) * | 2018-01-23 | 2018-07-13 | 合肥利裕泰玻璃制品有限公司 | A kind of wear-resisting antiskid glass and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6167879B1 (en) * | 1995-05-18 | 2001-01-02 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | Process for producing non-slip floor covering |
| CN1476473A (en) * | 2000-11-28 | 2004-02-18 | Լ��ѷ | Anti-slip floor coating remover composition |
| CN2908663Y (en) * | 2005-04-11 | 2007-06-06 | 深圳市三鑫特种玻璃技术股份有限公司石岩生产中心 | Anti-slip glass floorings |
| CN101289282A (en) * | 2007-04-20 | 2008-10-22 | 信义玻璃工程（东莞）有限公司 | Anti-slip glass and manufacturing method thereof |
-
2009
- 2009-07-30 CN CN200910101018XA patent/CN101618618B/en not_active Expired - Fee Related
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US6167879B1 (en) * | 1995-05-18 | 2001-01-02 | Fraunhofer-Gesellschaft Zur Forderung Der Angewandten Forschung E.V. | Process for producing non-slip floor covering |
| CN1476473A (en) * | 2000-11-28 | 2004-02-18 | Լ��ѷ | Anti-slip floor coating remover composition |
| CN2908663Y (en) * | 2005-04-11 | 2007-06-06 | 深圳市三鑫特种玻璃技术股份有限公司石岩生产中心 | Anti-slip glass floorings |
| CN101289282A (en) * | 2007-04-20 | 2008-10-22 | 信义玻璃工程（东莞）有限公司 | Anti-slip glass and manufacturing method thereof |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2004-116211A 2004.04.15 |
| JP特开平11-270114A 1999.10.05 |
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| CN101618618A (en) | 2010-01-06 |
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