CN101597529A - Methane bio-desulfurization device - Google Patents
Methane bio-desulfurization device Download PDFInfo
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- CN101597529A CN101597529A CNA2009101622608A CN200910162260A CN101597529A CN 101597529 A CN101597529 A CN 101597529A CN A2009101622608 A CNA2009101622608 A CN A2009101622608A CN 200910162260 A CN200910162260 A CN 200910162260A CN 101597529 A CN101597529 A CN 101597529A
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- Prior art keywords
- thionizer
- pump
- outlet
- regeneration tank
- liquid
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 238000006477 desulfuration reaction Methods 0.000 title claims abstract description 23
- 239000007788 liquid Substances 0.000 claims abstract description 63
- 238000010521 absorption reaction Methods 0.000 claims abstract description 38
- 230000008929 regeneration Effects 0.000 claims abstract description 35
- 238000011069 regeneration method Methods 0.000 claims abstract description 35
- 238000012856 packing Methods 0.000 claims abstract description 24
- 239000012530 fluid Substances 0.000 claims abstract description 18
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 13
- 239000001301 oxygen Substances 0.000 claims abstract description 13
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims abstract description 11
- 238000005273 aeration Methods 0.000 claims abstract description 11
- 239000013049 sediment Substances 0.000 claims abstract description 4
- 239000010865 sewage Substances 0.000 claims abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 29
- 239000000945 filler Substances 0.000 claims description 10
- 239000013505 freshwater Substances 0.000 claims description 6
- 230000023556 desulfurization Effects 0.000 claims description 5
- 230000008676 import Effects 0.000 claims description 4
- 238000000034 method Methods 0.000 description 10
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 229910000037 hydrogen sulfide Inorganic materials 0.000 description 8
- 239000007789 gas Substances 0.000 description 7
- 238000006243 chemical reaction Methods 0.000 description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N iron oxide Inorganic materials [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 3
- 230000000050 nutritive effect Effects 0.000 description 3
- NDLPOXTZKUMGOV-UHFFFAOYSA-N oxo(oxoferriooxy)iron hydrate Chemical compound O.O=[Fe]O[Fe]=O NDLPOXTZKUMGOV-UHFFFAOYSA-N 0.000 description 3
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000011941 Tilia x europaea Nutrition 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- 239000004571 lime Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000005587 bubbling Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000003009 desulfurizing effect Effects 0.000 description 1
- 230000029087 digestion Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010992 reflux Methods 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000004062 sedimentation Methods 0.000 description 1
- 230000035939 shock Effects 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 230000019086 sulfide ion homeostasis Effects 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000005200 wet scrubbing Methods 0.000 description 1
- 230000003245 working effect Effects 0.000 description 1
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- Gas Separation By Absorption (AREA)
Abstract
The invention discloses a kind of methane bio-desulfurization device, comprise thionizer, in described thionizer, be provided with packing layer, be provided with the biogas inlet mouth in the bottom of packing layer, sewage draining exit and liquid outlet, above described packing layer, be provided with air outlet and fluid inlet, it is characterized in that: comprise that also absorption liquid that a regeneration tank and one discharge described thionizer liquid outlet squeezes into the pump of regeneration tank, the regeneration tank bottom has inlet mouth and inlet pipe to ventilate with the absorption liquid in regeneration tank, carry out the dissolved oxygen content of aeration and control absorption liquid, described regeneration tank liquid outlet also is communicated with a subsider, so that the elemental sulfur in the absorption liquid is by settlement separate, subsider top has purified liquor outlet to communicate with a lean solution groove, the liquid outlet of lean solution groove is communicated with the fluid inlet of described thionizer by absorbing liquid pump and circulating line, and the sediment discharge outlet is arranged at the subsider bottom.This desulfurizer long, safety running period, and sweetening effectiveness is good.
Description
Technical field
The invention belongs to the energy---the biogas field specifically is a kind of methane bio-desulfurization device.
Background technology
Usually also has hydrogen sulfide in the biogas that anaerobic digestion produces; hydrogen sulfide is under wet heat condition; metallic conduit, gas storage holder and gas equipment had very high corrodibility; during the biogas burning; hydrogen sulfide can change into sulfurous gas or sulphur trioxide; not only pollute the environment, but also can etching apparatus.So biogas must be removed hydrogen sulfide wherein before use.
Existing sulfur method has dry desulfurization, and its method is in the dry type desulfurizing tower, by sweetening agent ferric oxide and hydrogen sulfide generation chemical reaction, removes the hydrogen sulfide in the biogas, but ferric oxide meeting inefficacy after using repeatedly, a large amount of ferric oxide waste materials can cause secondary pollution.Wet desulphurization method, its method are in the wet scrubbing tower, by the hydrogen sulfide in the alkaline liquid absorption biogas.The first step is to adopt the NaOH solution washing biogas of pH=12.5, and the clearance of hydrogen sulfide is about 80%; Second step, NaC10 and the NaOH solution washing of employing pH=9.5, the clearances of handling postcure hydrogen through two steps reach more than 99%.But alkali lye is very fast crystallization in working cycle, stops up water pump, pipeline etc.
The patent No. is 200710067269.1, the Chinese patent literature that name is called " methane bio-desulfurization device " discloses a kind of thionizer, be in thionizer, to place the mesh-like filler, the nutritive medium section of filler below is communicated with reflux pump and transfer lime with the nozzle of filler top at the bottom of the tower, and biogas and air intlet are that the same mouth of pipe is positioned on the tower wall of filler lower position.This desulfurizer is simple in structure, but there are the following problems: 1, the air of this device and biogas enter in the thionizer from same inlet, and biogas at first directly contacts with air, because biogas is inflammable gas, thereby there is great potential safety hazard, is easy to take place burning and blast; 2, in the process of desulfurization, oxygen one biogas and stream are through packing layer, it is dissolved with a process in absorption liquid, although therefore oxygen contains bright easy control in oxygen-supplying amount and the Ta Nei gas, the bad control of dissolved oxygen content, dissolved oxygen content is too much, then can produce the extremely strong sulfuric acid of corrodibility, equipment is damaged, and if dissolved oxygen content is very few, then have a strong impact on sweetening effectiveness; 3, in the process of reaction, the elemental sulfur that produces in thionizer stops up packing layer easily, thereby result of use and work-ing life are affected greatly.Nutritive medium section restricted volume, and be subjected to top spray and under the influence of absorption liquid, the elemental sulfur in this nutritive medium section is difficult for settlement separate come out, and has influenced sweetening effectiveness.
Summary of the invention
At the problem that prior art exists, the object of the present invention is to provide that a kind of sweetening effectiveness is good to the easier control of dissolved oxygen, safe and reliable methane bio-desulfurization device.
The technical solution used in the present invention is: a kind of methane bio-desulfurization device, comprise thionizer, in described thionizer, be provided with packing layer, be provided with the biogas inlet mouth in the bottom of packing layer, sewage draining exit and liquid outlet, above described packing layer, be provided with air outlet and fluid inlet, it is characterized in that: comprise that also absorption liquid that a regeneration tank and one discharge described thionizer liquid outlet squeezes into the pump of regeneration tank, the regeneration tank bottom has inlet mouth and inlet pipe to ventilate with the absorption liquid in regeneration tank, carry out the dissolved oxygen content of aeration and control absorption liquid, described regeneration tank liquid outlet also is communicated with a subsider, so that the elemental sulfur in the absorption liquid is by settlement separate, subsider top has purified liquor outlet to communicate with a lean solution groove, the liquid outlet of lean solution groove is communicated with the fluid inlet of described thionizer by absorbing liquid pump and circulating line, and the sediment discharge outlet is arranged at the subsider bottom.
In described thionizer, between packing layer and biogas air outlet, also be provided with scum dredger, bring the mist that produces into methane outlet pipe and gas equipment with the air-flow of avoiding rising.
Owing to have salt that elemental sulfur or crystallization separate out or other impurity in process of production along with on filler, cause porosity to reduce and the packing pressure drop increase, thereby influence runs well, can also have a clear water water-in in described thionizer filler top position, also comprise a clear water jar, a fresh water pump is connected on the clear water water-in and the connecting pipe between the clear water jar of thionizer, utilizes clear water that packing layer is cleaned.
For guaranteeing that clear water evenly is sprayed on the packing layer, in institute's thionizer, can also be provided with nozzle or skimmer and communicate with described clear water water-in.
Fresh water pump and absorb liquid pump and can be pump independently, but more satisfactory is that described fresh water pump and described absorption liquid pump are same pump, its import is communicated with lean solution groove and Rinsing Area respectively by threeway and valve, and its outlet is communicated with by the pipeline that threeway and the valve and the fluid inlet of thionizer are connected with the clear water water-in respectively.Because normal sweetening process and cleaning process can not carried out simultaneously, can reduce the investment of a pump like this.
All under meter can be installed on the pipeline of described pump discharge threeway and thionizer fluid inlet and clear water water-in, with convenient control absorption liquid internal circulating load and clear water flow.
Can also comprise a rich solution groove, liquid outlet at the bottom of the described desulfurization Tata communicates with the rich solution groove by pipeline, described inlet from the pump of absorption liquid to regeneration tank that make communicates with this rich solution groove, also have a liquid-inlet pipe and rich solution groove to pass to mutually and replenish absorption liquid or mend clear water, this rich solution groove prevents to find time in the thionizer and avoids the mercury vapour erosion except that having certain shock absorption like this, also is convenient to replenish in needs absorption liquid or clear water.
In the vertex position automatic blow off valve valve air relief can also be installed on the connecting pipe between described rich solution groove and the thionizer, to keep the thionizer internal pressure and to prevent the mercury vapour erosion.
Inlet pipe lowest part at described thionizer biogas inlet mouth can be equipped with trap, separates before entering thionizer and discharges with the lime set that biogas is contained.
On the connecting tube of the fluid inlet of described regeneration tank and inlet mouth, under meter is installed all, with dominant discharge.For the occasion that does not have compressed air gas source directly to adopt, can also on the pipeline of inlet mouth, air pump be installed, to satisfy the aeration needs.
This methane-desulfurizing device of the present invention has following characteristics:
(1) increases an independently regeneration tank, and regeneration tank has the inlet mouth bubbling air, make that the aeration of absorption liquid is independently to carry out in the regeneration tank, can control the elemental sulfur major part like this is to produce in the regeneration tank, subsider that can be by the back is settlement separate, and elemental sulfur is produced obstruction filler problem when avoiding in tower aeration in packing layer.
(2) aeration in the regeneration tank independently again, the stable easily and accurately control of the dissolved oxygen content of air flow and absorption liquid.
(3) volume of regeneration tank can carry out design and installation as required easily, is not subjected to the height and the diameter restrictions of thionizer.
(4) excess air used of aeration and biogas are isolated, and have avoided excessive oxygen and biogas directly to mix and have contacted the unsafe factor that brings.
Description of drawings
Fig. 1 is the schema of methane-desulfurizing device of the present invention.
Embodiment
Below by specific embodiment the present invention is described in further detail.
As shown in Figure 1, it is a preferred embodiment of methane bio-desulfurization device of the present invention, desulfurizer comprises a thionizer 1, in thionizer 1, be provided with packing layer 11, be provided with biogas inlet mouth, sewage draining exit and liquid outlet in the bottom of packing layer, above packing layer 11, be provided with air outlet and fluid inlet.In thionizer 1, between packing layer 11 and biogas air outlet, also be provided with scum dredger 12.
Comprise that also absorption liquid that a regeneration tank 5 and one discharge the thionizer liquid outlet squeezes into the pump 3 of regeneration tank, and rich solution groove 2.
Liquid outlet at the bottom of thionizer 1 tower communicates with rich solution groove 2 by pipeline, also has a liquid-inlet pipe and rich solution groove to pass to mutually on the rich solution groove 2 and replenishes absorption liquid or mend clear water.In the vertex position automatic blow off valve valve air relief 21 is installed also on the connecting pipe between rich solution groove 2 and the thionizer 1.
The inlet of making the pump 3 of absorption liquid communicates with rich solution groove 2, and the outlet conduit of pump 3 is connected the import of regeneration tank 5.Regeneration tank 5 bottoms have inlet mouth and inlet pipe to ventilate with the absorption liquid in regeneration tank, carry out the dissolved oxygen content of aeration and control absorption liquid, on the connecting tube of the fluid inlet of regeneration tank 5 and inlet mouth, under meter is installed all, and the air pump 4 that air feed is used also is installed on the pipeline of inlet mouth.
The liquid outlet of regeneration tank 5 is communicated with a subsider 6, so that the elemental sulfur in the absorption liquid is by settlement separate, the sediment discharge outlet is arranged at the subsider bottom.Subsider 6 tops have purified liquor outlet to communicate with a lean solution groove 7, and the liquid outlet of lean solution groove 7 is communicated with the fluid inlet of thionizer 1 by absorbing liquid pump 8 and circulating line.
Also have a clear water water-in in thionizer 1 filler 11 top positions, comprise that also 9, one pumps 8 of a clear water jar are connected on the clear water water-in and the connecting pipe between the clear water jar of thionizer.Also being provided with nozzle or skimmer 13 in institute's thionizer 1 communicates with the clear water water-in.
The import of pump 8 is communicated with lean solution groove 7 and Rinsing Area 9 respectively by threeway and valve, and its outlet is communicated with by the pipeline that threeway and the valve and the fluid inlet of thionizer 1 are connected with the clear water water-in respectively.On the fluid inlet of pump 8 outlet threeways and thionizer 1 and the pipeline of clear water water-in under meter is installed all.
Inlet pipe lowest part at thionizer 1 biogas inlet mouth is equipped with trap 20.
Weakly alkaline absorption liquid descends from packing layer 11 tops spray, and biogas enters in the thionizer 1 from the filler bottom, makes progress when passing through packing layer and the absorption liquid counter current contact, H wherein
2S is dissolved in the weakly alkaline absorption liquid and carries out following reaction:
Absorption liquid enters rich solution groove 2 from the tower bottom liquid outlet of thionizer 1, and is driven in the regeneration tank 5 through pump 3, and inflate in regeneration tank 5 by air pump 4 and carry out aeration, following reaction, take place in control absorption liquid dissolved oxygen content in regeneration tank:
Absorption liquid overflow behind the aeration is advanced subsider 6 through sedimentation, makes most of elemental sulfur be deposited to bottom land to be discharged from recovery, and lean solution groove 7 is gone in the clear liquid overflow, squeezes into the thionizer circulation desulfurization through pump 8 and handles.
When needs clean thionizer, close communicating valve between pump 8 and the lean solution groove 7 and the communicating valve between pump discharge and thionizer 1 fluid inlet, open pump 8 after opening the communicating valve between pump 8 and the Rinsing Area 9, and the valve of opening on the pump 8 outlet fresh water pipelines cleans to scum dredger 12 and packing layer 11.
Claims (10)
1, a kind of methane bio-desulfurization device, comprise thionizer, in described thionizer, be provided with packing layer, be provided with the biogas inlet mouth in the bottom of packing layer, sewage draining exit and liquid outlet, above described packing layer, be provided with air outlet and fluid inlet, it is characterized in that: comprise that also absorption liquid that a regeneration tank and one discharge described thionizer liquid outlet squeezes into the pump of regeneration tank, the regeneration tank bottom has inlet mouth and inlet pipe to ventilate with the absorption liquid in regeneration tank, carry out the dissolved oxygen content of aeration and control absorption liquid, described regeneration tank liquid outlet also is communicated with a subsider, so that the elemental sulfur in the absorption liquid is by settlement separate, subsider top has purified liquor outlet to communicate with a lean solution groove, the liquid outlet of lean solution groove is communicated with the fluid inlet of described thionizer by absorbing liquid pump and circulating line, and the sediment discharge outlet is arranged at the subsider bottom.
2, methane bio-desulfurization device according to claim 1 is characterized in that: also be provided with scum dredger in described thionizer between packing layer and biogas air outlet.
3, methane bio-desulfurization device according to claim 1 and 2, it is characterized in that: also have a clear water water-in in described thionizer filler top position, also comprise a clear water jar, a fresh water pump is connected on the clear water water-in and the connecting pipe between the clear water jar of thionizer.
4, methane bio-desulfurization device according to claim 3 is characterized in that: also be provided with nozzle or skimmer and communicate with described clear water water-in in institute's thionizer.
5, methane bio-desulfurization device according to claim 3, it is characterized in that: described fresh water pump and described absorption liquid pump are same pump, its import is communicated with lean solution groove and Rinsing Area respectively by threeway and valve, and its outlet is communicated with by the pipeline that threeway and the valve and the fluid inlet of thionizer are connected with the clear water water-in respectively.
6, methane bio-desulfurization device as claimed in claim 5 is characterized in that: on the pipeline of described pump discharge threeway and thionizer fluid inlet and clear water water-in under meter is installed all.
7, methane bio-desulfurization device according to claim 1 and 2, it is characterized in that: also comprise a rich solution groove, liquid outlet at the bottom of the described desulfurization Tata communicates with the rich solution groove by pipeline, described inlet from the pump of absorption liquid to regeneration tank that make communicates with this rich solution groove, also has a liquid-inlet pipe and rich solution groove to pass to mutually and replenishes absorption liquid or mend clear water.
8, methane bio-desulfurization device as claimed in claim 7 is characterized in that: in the vertex position automatic blow off valve valve air relief is installed also on the connecting pipe between described rich solution groove and the thionizer.
9, methane bio-desulfurization device as claimed in claim 1 or 2 is characterized in that: the inlet pipe lowest part at described thionizer biogas inlet mouth is equipped with trap.
10, methane bio-desulfurization device as claimed in claim 1 or 2 is characterized in that: on the connecting tube of the fluid inlet of described regeneration tank and inlet mouth under meter is installed all, and on the pipeline of inlet mouth air pump is installed also.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910162260A CN101597529B (en) | 2009-07-31 | 2009-07-31 | Methane bio-desulfurization device |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN200910162260A CN101597529B (en) | 2009-07-31 | 2009-07-31 | Methane bio-desulfurization device |
Publications (2)
| Publication Number | Publication Date |
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| CN101597529A true CN101597529A (en) | 2009-12-09 |
| CN101597529B CN101597529B (en) | 2012-09-05 |
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| CN200910162260A Active CN101597529B (en) | 2009-07-31 | 2009-07-31 | Methane bio-desulfurization device |
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102120134A (en) * | 2010-12-31 | 2011-07-13 | 哈尔滨工业大学 | Electrochemical treatment device and method for removing hydrogen sulfide in methane |
| CN101732985B (en) * | 2010-01-29 | 2013-01-23 | 北京合力清源科技有限公司 | Methane-desulfurizing device |
| CN102994181A (en) * | 2012-10-10 | 2013-03-27 | 贵州泰然环境科技有限责任公司 | Process for wet desulfurization of biogas |
| CN103071378A (en) * | 2013-01-11 | 2013-05-01 | 中国科学院广州能源研究所 | Two-stage biological desulfuration device of marsh gas |
| CN105505495A (en) * | 2014-09-23 | 2016-04-20 | 中国石油化工股份有限公司 | Skid-mounted microorganism desulfurization and sulphur recovery apparatus |
| CN106381183A (en) * | 2016-11-30 | 2017-02-08 | 唐山绿源环保科技有限公司 | Biological desulfurization device and desulfurization process for biogas |
| CN108097021A (en) * | 2017-12-25 | 2018-06-01 | 宜宾丝丽雅股份有限公司 | TRS purification process |
| CN114684969A (en) * | 2022-04-07 | 2022-07-01 | 四川迅升油气工程技术有限公司 | Skid-mounted desulfurization device and method for high-sulfur-content sewage treatment |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005053820A1 (en) * | 2003-12-03 | 2005-06-16 | Stefan Ermich | Desulfurization of gases for gaseous fuels treatment or odour control |
| CN1689995A (en) * | 2004-04-28 | 2005-11-02 | 北京城市排水集团有限责任公司 | Digestion tank desulfurization method |
| CN2870960Y (en) * | 2006-01-18 | 2007-02-21 | 北京合百意生态能源科技开发有限公司 | Marsh-gas desulfurizer |
| CN201168561Y (en) * | 2008-03-25 | 2008-12-24 | 北京城市排水集团有限责任公司 | Digester biogas desulfurization device in sewage treatment plant |
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2009
- 2009-07-31 CN CN200910162260A patent/CN101597529B/en active Active
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101732985B (en) * | 2010-01-29 | 2013-01-23 | 北京合力清源科技有限公司 | Methane-desulfurizing device |
| CN102120134A (en) * | 2010-12-31 | 2011-07-13 | 哈尔滨工业大学 | Electrochemical treatment device and method for removing hydrogen sulfide in methane |
| CN102994181A (en) * | 2012-10-10 | 2013-03-27 | 贵州泰然环境科技有限责任公司 | Process for wet desulfurization of biogas |
| CN103071378A (en) * | 2013-01-11 | 2013-05-01 | 中国科学院广州能源研究所 | Two-stage biological desulfuration device of marsh gas |
| CN103071378B (en) * | 2013-01-11 | 2015-07-01 | 中国科学院广州能源研究所 | Two-stage biological desulfuration device of marsh gas |
| CN105505495A (en) * | 2014-09-23 | 2016-04-20 | 中国石油化工股份有限公司 | Skid-mounted microorganism desulfurization and sulphur recovery apparatus |
| CN106381183A (en) * | 2016-11-30 | 2017-02-08 | 唐山绿源环保科技有限公司 | Biological desulfurization device and desulfurization process for biogas |
| CN108097021A (en) * | 2017-12-25 | 2018-06-01 | 宜宾丝丽雅股份有限公司 | TRS purification process |
| CN114684969A (en) * | 2022-04-07 | 2022-07-01 | 四川迅升油气工程技术有限公司 | Skid-mounted desulfurization device and method for high-sulfur-content sewage treatment |
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| CN101597529B (en) | 2012-09-05 |
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Address after: 100043 Shijingshan District Yinhe South Street, No. 2, No. 2, international building, royal purple, No. 820, No. Patentee after: Beijing Ying and Rui environmental Polytron Technologies Inc Address before: 100097 East Haidian District Jin Yuan Residence Internazionale East Beijing Road, No. 69 9E Patentee before: Beijing Yingherui Environmental Engineering Co., Ltd. |
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