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CN101582454B - Double-bit U-shaped memory structure and manufacturing method thereof - Google Patents

Double-bit U-shaped memory structure and manufacturing method thereof Download PDF

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CN101582454B
CN101582454B CN2008101002032A CN200810100203A CN101582454B CN 101582454 B CN101582454 B CN 101582454B CN 2008101002032 A CN2008101002032 A CN 2008101002032A CN 200810100203 A CN200810100203 A CN 200810100203A CN 101582454 B CN101582454 B CN 101582454B
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dielectric layer
floating gate
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CN101582454A (en
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廖伟明
王哲麒
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Nanya Technology Corp
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Abstract

The invention discloses a double-bit U-shaped memory structure and a manufacturing method thereof. The memory disclosed by the invention is structurally characterized in that the bottom of the floating gate is U-shaped and is embedded in the substrate. The memory structure of the invention comprises a substrate; the control grid is arranged on the surface of the substrate; the floating grid is arranged on two sides of the control grid, wherein the floating grid is provided with a U-shaped bottom which is embedded in the substrate; a first dielectric layer between the control gate and the substrate; a second dielectric layer between the U-shaped bottom of the floating gate and the substrate; a third dielectric layer between the control gate and the floating gate; the local doping area is arranged in the U-shaped floating gate channel right below the floating gate; and a source/drain doped region disposed in the substrate at one side of the floating gate.

Description

双位U型存储器结构及其制作方法 Double-bit U-shaped memory structure and manufacturing method thereof

技术领域technical field

本发明涉及一种存储器的结构及其制作方法,特别涉及一种具有U型底部的浮动栅极的双位存储器元件结构及其制作方法。The invention relates to a memory structure and a manufacturing method thereof, in particular to a double-bit memory element structure with a U-shaped bottom floating gate and a manufacturing method thereof.

背景技术Background technique

快闪存储器具有不挥发以及可重复抹除读写的特性,加上传输快速,所以应用层面非常广泛,使得近来许多可携式产品都采用快闪存储器,在许多的信息、通讯及消费性电子产品中都已将其当成必要元件。为了提供轻巧及高品质的电子元件产品,提升快闪存储器的元件集成度与品质便成为信息产业发展的重点。Flash memory has the characteristics of non-volatility, reerasable read-write, and fast transmission, so it has a wide range of applications, making many portable products use flash memory recently. It is used in many information, communication and consumer electronics. It has been considered as a necessary component in the product. In order to provide lightweight and high-quality electronic component products, improving the component integration and quality of flash memory has become the focus of the development of the information industry.

请参阅图1,图1为已知双位快闪存储器单元的结构示意图。如图1所示,已知快闪存储器单元包含基底10、控制栅极12设于基底10上、两浮动栅极14a、14b分别设于控制栅极12的两侧、介电层16设于控制栅极12与基底10之间以及浮动栅极14a、14b与基底10之间、介电层18设于控制栅极12与浮动栅极14a、14b之间、源极/漏极掺杂区20位于浮动栅极14a、14b一侧的基底内、口袋型掺杂区22邻接源极/漏极掺杂区20,以及浮动栅极沟道24。Please refer to FIG. 1 , which is a schematic structural diagram of a known dual-bit flash memory cell. As shown in FIG. 1 , a known flash memory cell includes a substrate 10, a control gate 12 disposed on the substrate 10, two floating gates 14a, 14b respectively disposed on both sides of the control gate 12, and a dielectric layer 16 disposed on the substrate 10. Between the control gate 12 and the substrate 10 and between the floating gates 14a, 14b and the substrate 10, the dielectric layer 18 is arranged between the control gate 12 and the floating gates 14a, 14b, and the source/drain doped regions 20 is located in the substrate on one side of the floating gates 14a, 14b, the pocket doped region 22 adjoins the source/drain doped region 20, and the floating gate channel 24.

上述已知快闪存储器的结构,具有形成在控制栅极12两侧壁上的浮动栅极14a、14b,可储存双位数据。随着元件设计的尺寸不断缩小,浮动栅极沟道不断缩短,然而浮动栅极沟道的长度,对于快闪存储器的效能有很大的影响。一般而言,浮动栅极沟道越长,快闪存储器的效能越佳。缩小元件尺寸虽然可以提升集成度,但却会造成快闪存储器的浮动栅极沟道变短,造成元件效能下降,此外,也会使得工艺宽裕度降低。The structure of the above-mentioned known flash memory has floating gates 14a, 14b formed on both side walls of the control gate 12, and can store double-bit data. As the size of the device design keeps shrinking, the floating gate channel keeps shortening. However, the length of the floating gate channel has a great influence on the performance of the flash memory. In general, the longer the floating gate channel, the better the performance of the flash memory. Although reducing the device size can increase the integration level, it will shorten the floating gate channel of the flash memory, resulting in a decrease in device performance. In addition, it will also reduce the process margin.

再者,已知快闪存储器中其口袋型掺杂区是在注入之后利用加热工艺使得掺杂剂横向扩散后形成,由于口袋型掺杂区邻接源极/漏极掺杂区,使得口袋型掺杂区易受到源极/漏极掺杂区的影响,造成工艺控制的问题。因此,发展出新的存储器结构及工艺,并提升快闪存储器的效能以及改善工艺控制问题是目前半导体业界努力的方向。Furthermore, in the known flash memory, the pocket-type doped region is formed after the dopant is laterally diffused by a heating process after implantation. Since the pocket-type doped region is adjacent to the source/drain doped region, the pocket-type doped region Doped regions are susceptible to source/drain doped regions, causing process control issues. Therefore, developing a new memory structure and process, improving the performance of the flash memory and improving the process control are the current efforts of the semiconductor industry.

发明内容Contents of the invention

有鉴于此,本发明提供一种存储器结构及其制作方法,利用设置在基底中的U形浮动栅极底部,可以在元件缩小的同时增加浮动栅极沟道的长度,提升快闪存储器的效能,并且在浮动栅极正下方设置局部掺杂区取代已知技术的口袋型掺杂区,可以有效避免上述工艺控制的问题。此外,本发明的存储器结构可以提升栅极诱发的漏极漏电流(GIDL)的现象,增加快闪存储器写入速度。In view of this, the present invention provides a memory structure and its manufacturing method. By using the bottom of the U-shaped floating gate arranged in the substrate, the length of the floating gate channel can be increased while the element is shrunk, and the performance of the flash memory can be improved. , and disposing a local doped region directly under the floating gate instead of the pocket-type doped region in the known technology can effectively avoid the above-mentioned problem of process control. In addition, the memory structure of the present invention can improve the gate-induced drain leakage (GIDL) phenomenon and increase the writing speed of the flash memory.

根据本发明的优选实施例,本发明一种存储器元件结构包含:基底、控制栅极,设于该基底表面、浮动栅极,设于该控制栅极的两侧,其中该浮动栅极具有U形底部陷入于该基底中、第一介电层,介于该控制栅极与该基底之间、第二介电层,介于该浮动栅极的该U形底部与该基底之间、第三介电层,介于该控制栅极与该浮动栅极之间、局部掺杂区,设于该浮动栅极正下方的U形浮动栅极沟道、以及源极/漏极掺杂区,设于该浮动栅极的一侧的该基底中。According to a preferred embodiment of the present invention, a structure of a memory element in the present invention includes: a substrate, a control gate disposed on the surface of the substrate, and a floating gate disposed on both sides of the control gate, wherein the floating gate has U shaped bottom embedded in the substrate, a first dielectric layer between the control gate and the substrate, a second dielectric layer between the U-shaped bottom of the floating gate and the substrate, a second dielectric layer between the U-shaped bottom of the floating gate and the substrate, Three dielectric layers between the control gate and the floating gate, a local doped region, a U-shaped floating gate channel directly below the floating gate, and a source/drain doped region , set in the substrate on one side of the floating gate.

根据本发明的优选实施例,本发明的一方面提供一种快闪存储器元件的制作方法,包含有:提供基底,包含第一沟槽以及第二沟槽设于该基底中,然后,于该第一沟槽以及该第二沟槽的底部形成局部掺杂区,接着,形成第一介电层覆盖该第一沟槽的表面、该第二沟槽的表面以及该基底表面之后,形成第一导电层填满并覆盖该第一沟槽以及该第二沟槽,然后,形成第二介电层于该第一导电层两侧,接着,形成一开口于该第一沟槽以及该第二沟槽之间的该第一导电层内,最后,形成掺杂区于该第一沟槽以及该第二沟槽之间的该基底内。According to a preferred embodiment of the present invention, one aspect of the present invention provides a method for manufacturing a flash memory device, comprising: providing a substrate, including a first trench and a second trench disposed in the substrate, and then, on the substrate The first trench and the bottom of the second trench form a local doping region, and then, after forming a first dielectric layer to cover the surface of the first trench, the surface of the second trench and the surface of the substrate, a second trench is formed. A conductive layer fills and covers the first groove and the second groove, then, forms a second dielectric layer on both sides of the first conductive layer, and then forms an opening in the first groove and the second groove. In the first conductive layer between the two trenches, finally, a doped region is formed in the substrate between the first trench and the second trench.

附图说明Description of drawings

图1为已知双位快闪存储器单元的结构示意图。FIG. 1 is a schematic structural diagram of a known dual-bit flash memory cell.

图2至7绘示根据本发明优选实施例的存储器元件的制作方法示意图。2 to 7 are schematic diagrams illustrating a manufacturing method of a memory device according to a preferred embodiment of the present invention.

附图标记说明Explanation of reference signs

10基底            12控制栅极10 base 12 control grid

14浮动栅极        16、18介电层14 floating gate 16, 18 dielectric layer

20源极/漏极掺杂区    22口袋型掺杂区20 source/drain doped region 22 pocket doped region

24浮动栅极沟道       50基底24 Floating Gate Trench 50 Substrate

52介电层             54硬掩模层52 dielectric layer 54 hard mask layer

56沟槽               58局部掺杂区56 trenches 58 local doping regions

60区域               62介电层60 area 62 dielectric layer

64导电层             66凹槽64 conductive layers 66 grooves

68介电层             70导电层68 dielectric layer 70 conductive layer

72开口               74浮动栅极72 openings 74 floating gates

76源极/漏极掺杂区    80浮动栅极沟道76 source/drain doped regions 80 floating gate channel

57U型底部57U bottom

具体实施方式Detailed ways

图2至图7是根据本发明一优选实施例所绘示的存储器元件的制作方法示意图。如图2所示,首先提供基底50,其上覆有介电层52以及图案化的硬掩模层54,其中介电层52包含氧化硅,而硬掩模层54包含氮化硅。2 to 7 are schematic diagrams illustrating a manufacturing method of a memory device according to a preferred embodiment of the present invention. As shown in FIG. 2 , firstly, a substrate 50 is provided, which is overlaid with a dielectric layer 52 and a patterned hard mask layer 54 , wherein the dielectric layer 52 includes silicon oxide, and the hard mask layer 54 includes silicon nitride.

如图3所示,利用硬掩模层54作为掩模,在基底50中形成沟槽56,其中沟槽56具有U型底部57,接着于沟槽56的U型底部57周围的基底50内形成局部掺杂区58,接着利用掩模(图未示)去除位于区域60的硬掩模54以及介电层52,使得区域60的基底50被曝露出来。As shown in FIG. 3, using the hard mask layer 54 as a mask, a trench 56 is formed in the substrate 50, wherein the trench 56 has a U-shaped bottom 57, and then in the substrate 50 around the U-shaped bottom 57 of the trench 56. The local doping region 58 is formed, and then the hard mask 54 and the dielectric layer 52 in the region 60 are removed by using a mask (not shown), so that the substrate 50 in the region 60 is exposed.

如图4所示,于沟槽56的表面以及区域60的基底50的表面,形成介电层62,作为穿隧介电层。根据本发明的优选实施例,介电层62可以利用高温氧化法形成。然后,再形成导电层64,并使导电层64填满沟槽56。接着,利用研磨工艺使得导电层64的表面和硬掩模54的表面切齐。As shown in FIG. 4 , a dielectric layer 62 is formed on the surface of the trench 56 and the surface of the substrate 50 in the region 60 as a tunneling dielectric layer. According to a preferred embodiment of the present invention, the dielectric layer 62 can be formed by high temperature oxidation. Then, a conductive layer 64 is formed, and the conductive layer 64 fills the trench 56 . Next, a polishing process is used to align the surface of the conductive layer 64 with the surface of the hard mask 54 .

如图5所示,去除剩余的硬掩模54,形成凹槽66。然后,形成介电层68,使介电层68顺应地覆盖在导电层64以及凹槽66的表面。根据本发明的优选实施例,介电层68可以为氧化层-氮硅层-氧化层(ONO)介电层结构,其形成方式例如是先利用高温氧化法(high temperature oxidation,HTO)制作氧化层,再利用低压化学气相沉积法(LPCVD)制作氮硅层。As shown in FIG. 5 , the remaining hard mask 54 is removed, forming recesses 66 . Then, a dielectric layer 68 is formed, so that the dielectric layer 68 conformably covers the surface of the conductive layer 64 and the groove 66 . According to a preferred embodiment of the present invention, the dielectric layer 68 may be an oxide layer-silicon nitride layer-oxide layer (ONO) dielectric layer structure, and its formation method is, for example, first utilizing high temperature oxidation (high temperature oxidation, HTO) to make an oxide layer. layer, and then use low-pressure chemical vapor deposition (LPCVD) to make a nitrogen-silicon layer.

如图6所示,将部分的介电层68移除,仅留下位于凹槽66两侧的介电层68。根据本发明的另一优选实施例,位于凹槽66底部的介电层68亦可以保留,只需将位于导电层上方的介电层68移除即可。As shown in FIG. 6 , part of the dielectric layer 68 is removed, leaving only the dielectric layer 68 on both sides of the groove 66 . According to another preferred embodiment of the present invention, the dielectric layer 68 at the bottom of the groove 66 may also remain, and only the dielectric layer 68 above the conductive layer is removed.

如图7所示,于凹槽66内填入导电层70作为控制栅极,接着,使用前述用来去除位于区域60的硬掩模54的掩模(图未示),于导电层70中形成开口72,暴露出部分介电层62,以形成浮动栅极74。接着,利用离子注入于开口72的下方基底50中形成源极/漏极掺杂区76。在操作时,于浮动栅极74的U型底部周围会形成浮动栅极沟道80。至此,本发明的存储器元件即完成,之后可在后续的工艺中于开口72的两侧形成介电层,并去除开口72底部的介电层62,然后在于开口72内形成接触插塞。As shown in FIG. 7, a conductive layer 70 is filled in the groove 66 as a control gate, and then, using the aforementioned mask (not shown) for removing the hard mask 54 located in the region 60, in the conductive layer 70 An opening 72 is formed to expose a portion of the dielectric layer 62 to form a floating gate 74 . Next, source/drain doped regions 76 are formed in the substrate 50 below the opening 72 by ion implantation. In operation, floating gate channel 80 is formed around the bottom of the U-shape of floating gate 74 . So far, the memory device of the present invention is completed, and then a dielectric layer can be formed on both sides of the opening 72 in subsequent processes, and the dielectric layer 62 at the bottom of the opening 72 can be removed, and then contact plugs can be formed in the opening 72 .

图7所绘示的是根据本发明的优选实施例的存储器元件结构,本发明的存储器元件包含基底50、控制栅极70,设于基底50表面、浮动栅极74,设于控制栅极70的两侧,其中浮动栅极74具有U形底部57嵌入于基底50中、介电层52作为控制栅极介电层,介于控制栅极70与基底50之间,介电层62作为穿隧介电层,介于浮动栅极74的U形底部57与基底50之间、介电层68,介于控制栅极70与浮动栅极74之间、局部掺杂区58,设于浮动栅极74正下方的U形浮动栅极沟道80周围以及源极/漏极掺杂区76,设于浮动栅极74的一侧的基底50中。前述的介电层52可以是氧化硅以及氧化硅-氮化硅-氧化硅结构(ONO)所组成,例如,氧化硅作为下层,而氧化硅-氮化硅-氧化硅结构则覆盖在氧化硅上;或者亦可以仅由氧化硅所构成。What Fig. 7 depicts is the structure of the memory element according to the preferred embodiment of the present invention. The memory element of the present invention includes a substrate 50, a control gate 70 disposed on the surface of the substrate 50, and a floating gate 74 disposed on the control gate 70. The floating gate 74 has a U-shaped bottom 57 embedded in the substrate 50, the dielectric layer 52 is used as a control gate dielectric layer, between the control gate 70 and the substrate 50, and the dielectric layer 62 is used as a through-hole The tunnel dielectric layer is interposed between the U-shaped bottom 57 of the floating gate 74 and the substrate 50, the dielectric layer 68 is interposed between the control gate 70 and the floating gate 74, and the local doped region 58 is disposed on the floating gate. The U-shaped floating gate channel 80 directly below the gate 74 and the source/drain doped region 76 are disposed in the substrate 50 on one side of the floating gate 74 . The aforementioned dielectric layer 52 may be composed of silicon oxide and silicon oxide-silicon nitride-silicon oxide structure (ONO), for example, silicon oxide is used as the lower layer, while the silicon oxide-silicon nitride-silicon oxide structure is covered on the on; or may only be composed of silicon oxide.

根据本发明优选实施例,若源极/漏极掺杂区76中的掺杂剂为P型,例如硼,则局部掺杂区58中的掺杂剂则为N型,例如砷,其中局部掺杂区58中利用离子注入所形成,所使用的离子剂量约为5E13,离子能量约为50KeV。According to a preferred embodiment of the present invention, if the dopant in the source/drain doped region 76 is P-type, such as boron, then the dopant in the local doped region 58 is N-type, such as arsenic, wherein the local The doped region 58 is formed by ion implantation, the ion dose used is about 5E13, and the ion energy is about 50KeV.

本发明的局部掺杂区58的功用主要在于取代已知技术中的口袋型掺杂区,用来避免开关存储器的源极与漏极发生不正常的贯通现象并增加元件开关状态的阈值电压差,局部掺杂区58的优点在于工艺中不易受到源极/漏极掺杂区的影响,能够提供较佳的工艺控制。The function of the local doped region 58 of the present invention is mainly to replace the pocket-type doped region in the known technology, to avoid abnormal penetration between the source and drain of the switch memory and to increase the threshold voltage difference of the switching state of the element. The advantage of the local doped region 58 is that the process is not easily affected by the source/drain doped region, and better process control can be provided.

此外,本发明的浮动栅极74具有嵌入基底的U型底部57,相较于传统的存储器(请参阅图1)其浮动栅极沟道会随着元件集成度增加而缩短,本发明的浮动栅极74却能在极集度增加的同时亦提供更长的浮动栅极沟道80,并且能够增加栅极诱发的漏极漏电流现象(GIDL)提升写入效率,如此一来,存储器可以有更好的效能并且也能够提升工艺宽裕度。In addition, the floating gate 74 of the present invention has a U-shaped bottom 57 embedded in the substrate. Compared with the traditional memory (see FIG. 1 ), its floating gate channel will be shortened as the integration of components increases. The floating gate of the present invention The gate 74 can provide a longer floating gate channel 80 while increasing the pole concentration, and can increase the gate-induced drain leakage (GIDL) to improve the writing efficiency. In this way, the memory can It has better performance and can also improve the process margin.

以上所述仅为本发明的优选实施例,凡依本发明权利要求所做的均等变化与修饰,皆应属本发明的涵盖范围。The above descriptions are only preferred embodiments of the present invention, and all equivalent changes and modifications made according to the claims of the present invention shall fall within the scope of the present invention.

Claims (11)

1.一种存储器元件结构,包含:1. A memory element structure comprising: 基底;base; 控制栅极,设于该基底表面;a control grid disposed on the surface of the substrate; 浮动栅极,设于该控制栅极的两侧,其中该浮动栅极具有U形底部嵌入于该基底中;a floating gate, disposed on both sides of the control gate, wherein the floating gate has a U-shaped bottom embedded in the substrate; 第一介电层,介于该控制栅极与该基底之间;a first dielectric layer between the control gate and the substrate; 第二介电层,介于该浮动栅极的该U形底部与该基底之间;a second dielectric layer between the U-shaped bottom of the floating gate and the substrate; 第三介电层,介于该控制栅极与该浮动栅极之间;a third dielectric layer between the control gate and the floating gate; 局部掺杂区,设于该浮动栅极正下方的U形浮动栅极沟道的周围;以及a locally doped region disposed around the U-shaped floating gate channel directly below the floating gate; and 源极/漏极掺杂区,设于该浮动栅极的一侧的该基底中。The source/drain doped region is arranged in the substrate on one side of the floating gate. 2.如权利要求1所述的存储器结构,其中该第一介电层为氧化硅。2. The memory structure of claim 1, wherein the first dielectric layer is silicon oxide. 3.如权利要求1所述的存储器结构,其中该第一介电层由氧化硅以及氧化硅-氮化硅-氧化硅所组成。3. The memory structure of claim 1, wherein the first dielectric layer is composed of silicon oxide and silicon oxide-silicon nitride-silicon oxide. 4.如权利要求1所述的存储器结构,其中该第三介电层包含氧化硅-氮化硅-氧化硅。4. The memory structure of claim 1, wherein the third dielectric layer comprises silicon oxide-silicon nitride-silicon oxide. 5.如权利要求1所述的存储器结构,其中该源极/漏极掺杂区为P型时,该局部掺杂区为N型。5. The memory structure as claimed in claim 1, wherein when the source/drain doped region is P-type, the local doped region is N-type. 6.如权利要求1所述的存储器结构,其中介于该浮动栅极以及该基底之间的第二介电层为U形。6. The memory structure of claim 1, wherein the second dielectric layer between the floating gate and the substrate is U-shaped. 7.如权利要求1所述的存储器结构,其中该局部掺杂区的底部为U形。7. The memory structure of claim 1, wherein the bottom of the locally doped region is U-shaped. 8.一种存储器元件的制作方法,包含:8. A method of manufacturing a memory element, comprising: 提供基底,包含第一沟槽以及第二沟槽设于该基底中,其中该第一沟槽的底部为U型以及该第二沟槽的底部为U型;providing a substrate, including a first groove and a second groove disposed in the substrate, wherein the bottom of the first groove is U-shaped and the bottom of the second groove is U-shaped; 于该第一沟槽以及该第二沟槽的底部形成局部掺杂区;forming local doped regions at the bottom of the first trench and the second trench; 形成第一介电层覆盖该第一沟槽的表面、该第二沟槽的表面以及该基底表面;forming a first dielectric layer covering the surface of the first trench, the surface of the second trench and the surface of the substrate; 形成第一导电层填满并覆盖该第一沟槽以及该第二沟槽;forming a first conductive layer to fill and cover the first trench and the second trench; 形成第二介电层于该第一导电层两侧;forming a second dielectric layer on both sides of the first conductive layer; 形成一开口于该第一沟槽以及该第二沟槽之间的该第一导电层内;以及forming an opening in the first conductive layer between the first trench and the second trench; and 形成掺杂区于该第一沟槽以及该第二沟槽之间的该基底内。A doped region is formed in the substrate between the first trench and the second trench. 9.如权利要求8所述的存储器元件的制作方法,在形成该开口之后,于该开口内形成接触插塞。9. The manufacturing method of the memory device according to claim 8, after forming the opening, forming a contact plug in the opening. 10.如权利要求8所述的存储器元件的制作方法,其中该第二介电层包含氧化硅-氮化硅-氧化硅。10. The manufacturing method of the memory device as claimed in claim 8, wherein the second dielectric layer comprises silicon oxide-silicon nitride-silicon oxide. 11.如权利要求8所述的存储器元件的制作方法,其中该第二介电层于该导电层两侧定义出凹陷区域,该制作方法于形成该第二介电层之后与形成该开口之前,另包含有以下步骤:11. The manufacturing method of the memory device according to claim 8, wherein the second dielectric layer defines recessed regions on both sides of the conductive layer, and the manufacturing method is performed after forming the second dielectric layer and before forming the opening , which additionally includes the following steps: 于该凹陷区域填入第二导电层;以及filling the recessed area with a second conductive layer; and 研磨掉部分的该第二导电层、该第二介电层以暴露出该第一导电层。Parts of the second conductive layer and the second dielectric layer are ground to expose the first conductive layer.
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