CN101555428A - Adhesive - Google Patents
Adhesive Download PDFInfo
- Publication number
- CN101555428A CN101555428A CNA2009101359716A CN200910135971A CN101555428A CN 101555428 A CN101555428 A CN 101555428A CN A2009101359716 A CNA2009101359716 A CN A2009101359716A CN 200910135971 A CN200910135971 A CN 200910135971A CN 101555428 A CN101555428 A CN 101555428A
- Authority
- CN
- China
- Prior art keywords
- portions
- coke
- parts
- binding agent
- adhesive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000853 adhesive Substances 0.000 title abstract 4
- 230000001070 adhesive effect Effects 0.000 title abstract 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims abstract description 21
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000002994 raw material Substances 0.000 claims abstract description 10
- 229920001353 Dextrin Polymers 0.000 claims abstract description 7
- 239000004375 Dextrin Substances 0.000 claims abstract description 7
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims abstract description 7
- 239000010426 asphalt Substances 0.000 claims abstract description 7
- 239000011280 coal tar Substances 0.000 claims abstract description 7
- 235000019425 dextrin Nutrition 0.000 claims abstract description 7
- 239000011734 sodium Substances 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 7
- 239000011230 binding agent Substances 0.000 claims description 20
- 239000002253 acid Substances 0.000 claims description 6
- 229920002678 cellulose Polymers 0.000 claims description 6
- 239000011285 coke tar Substances 0.000 claims description 6
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 claims description 6
- 150000003951 lactams Chemical class 0.000 claims description 6
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 claims description 6
- 229920002554 vinyl polymer Polymers 0.000 claims description 6
- 239000000440 bentonite Substances 0.000 claims description 4
- 229910000278 bentonite Inorganic materials 0.000 claims description 4
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 4
- 239000001913 cellulose Substances 0.000 claims description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 claims description 4
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 239000000571 coke Substances 0.000 abstract description 38
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 abstract description 16
- 239000000126 substance Substances 0.000 abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 abstract description 10
- 239000003245 coal Substances 0.000 abstract description 7
- 229910052799 carbon Inorganic materials 0.000 abstract description 6
- 238000000465 moulding Methods 0.000 abstract description 6
- -1 polyethylene Polymers 0.000 abstract description 6
- 239000005997 Calcium carbide Substances 0.000 abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 5
- 229910052782 aluminium Inorganic materials 0.000 abstract description 5
- 239000003337 fertilizer Substances 0.000 abstract description 5
- 229910052742 iron Inorganic materials 0.000 abstract description 5
- 238000005272 metallurgy Methods 0.000 abstract description 5
- CLZWAWBPWVRRGI-UHFFFAOYSA-N tert-butyl 2-[2-[2-[2-[bis[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]amino]-5-bromophenoxy]ethoxy]-4-methyl-n-[2-[(2-methylpropan-2-yl)oxy]-2-oxoethyl]anilino]acetate Chemical compound CC1=CC=C(N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)C(OCCOC=2C(=CC=C(Br)C=2)N(CC(=O)OC(C)(C)C)CC(=O)OC(C)(C)C)=C1 CLZWAWBPWVRRGI-UHFFFAOYSA-N 0.000 abstract description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 abstract description 4
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 abstract description 4
- 239000000654 additive Substances 0.000 abstract description 4
- 239000011777 magnesium Substances 0.000 abstract description 4
- 229910052749 magnesium Inorganic materials 0.000 abstract description 4
- 239000011574 phosphorus Substances 0.000 abstract description 4
- 229910052698 phosphorus Inorganic materials 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 2
- 239000004698 Polyethylene Substances 0.000 abstract 1
- 229920013820 alkyl cellulose Polymers 0.000 abstract 1
- 150000001408 amides Chemical class 0.000 abstract 1
- 125000004181 carboxyalkyl group Chemical group 0.000 abstract 1
- 230000007797 corrosion Effects 0.000 abstract 1
- 238000005260 corrosion Methods 0.000 abstract 1
- YRIUSKIDOIARQF-UHFFFAOYSA-N dodecyl benzenesulfonate Chemical compound CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 YRIUSKIDOIARQF-UHFFFAOYSA-N 0.000 abstract 1
- 229940071161 dodecylbenzenesulfonate Drugs 0.000 abstract 1
- 229920000573 polyethylene Polymers 0.000 abstract 1
- 239000011273 tar residue Substances 0.000 abstract 1
- 238000004519 manufacturing process Methods 0.000 description 10
- 235000010980 cellulose Nutrition 0.000 description 5
- 239000004411 aluminium Substances 0.000 description 4
- 230000000996 additive effect Effects 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 238000004939 coking Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 238000005453 pelletization Methods 0.000 description 2
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- 239000004566 building material Substances 0.000 description 1
- 238000005266 casting Methods 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000003034 coal gas Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000011194 food seasoning agent Nutrition 0.000 description 1
- 238000013467 fragmentation Methods 0.000 description 1
- 238000006062 fragmentation reaction Methods 0.000 description 1
- 239000000446 fuel Substances 0.000 description 1
- 238000002309 gasification Methods 0.000 description 1
- 238000005469 granulation Methods 0.000 description 1
- 230000003179 granulation Effects 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E50/00—Technologies for the production of fuel of non-fossil origin
- Y02E50/30—Fuel from waste, e.g. synthetic alcohol or diesel
Landscapes
- Manufacture And Refinement Of Metals (AREA)
- Solid Fuels And Fuel-Associated Substances (AREA)
- Fertilizers (AREA)
Abstract
The invention discloses an adhesive, which is prepared by the following raw materials in weight ratio: 10 portions to 15 portions of asphalt powder, 10 portions to 16 portions of coal tar, 14 portions to 17 portions of tar residue, 0.1 portion of MF4, 0.1 portion of NO, 1.2 portions to 2.5 portions corrosion sodium, 0.3 portion of dodecyl benzene sulfonate, 0.5 portion of polyethylene amide, 1 portion to 1.5 portions of carboxy alkyl cellulose, 2 portions of sodium hydroxide and 1 portion of dextrin. The adhesive solves the problem of difficult molding of coke powder. The formed coke produced by the adhesive, after being dried, has coal strength of 70 kilograms to 90 kilograms per ball, does not disperse at high temperature of 1,300 DEG C, has less fixed carbon reduction amount, does not contain chemical components such as magnesium, phosphorus, aluminum, iron, and the like in additives, and has good chemical activity. The formed coke produced can be applicable to the industries such as metallurgy, chemical fertilizer, calcium carbide, and the like for replacing part of the coke.
Description
Technical field
The present invention relates to a kind of production formed coke, metallurgical coke or gasification formed coke binding agent.
Background technology
As everyone knows, current China coke price goes up to more than 1000 yuan, and some areas are especially up to 1500 yuan/ton.And the coke powder of the annual coke fragmentation of China is more than 5,000 ten thousand tons, and a large amount of coke powders can only be made low-grade fuel and handle, and price has only about 150 yuan.
Coke is the important raw and processed materials of metallurgy, machinery, chemical industry, building materials industry.The raw material of producing coke is the high-quality coking coal.Formed coke is a raw material with coke or the undersized granulated slag of coal then, produces the metallurgical coke or the foundry coke that meet national standard.Expanded the application of feed coal.Especially broken (smokelessly) coal, the broken coke less than 3mm is the raw material of making formed coke, reduced cost.Formed coke per ton can be saved coke fund 300-500 unit.Build the industrial production line of a year handling 40,000 tons of coke powders, armamentarium is invested about 1,300,000 yuan.Found the factory then, just can make a profit more than 500 ten thousand yuan then.So, utilize coke powder production to be suitable for the formed coke that industry instead of part coke such as metallurgy, chemical industry chemical fertilizer, calcium carbide are used, be that China's existing market potentiality are big, good in economic efficiency investment project.
But, in the formed coke production process, exist the problem of the extremely difficult moulding of coke powder, thereby produce with binding agent most important.
Summary of the invention
The technical issues that need to address of the present invention just are to overcome the problem of the extremely difficult moulding of coke powder that exists in the existing formed coke production process, a kind of binding agent is provided, it has solved the problem of the extremely difficult moulding of coke powder, utilize binding agent of the present invention can go out the product formed coke, 70 kilograms of-90 kilograms/single balls of dry back cold strength, not powder does not loose when 1300 ℃ of high temperature, fixed carbon reduction amount is few, do not contain Chemical Composition such as magnesium, phosphorus, aluminium, iron in the additive, chemically reactive is good, and the formed coke of production can be suitable for industry instead of part coke such as metallurgy, chemical industry chemical fertilizer, calcium carbide and use.
For addressing the above problem, the present invention adopts following technical scheme:
A kind of binding agent of the present invention, described binding agent is prepared from by following raw materials in weight portion:
Asphalt powder 10-15 part; Coal tar 10-16 part; Coke tar refuse 14-17 part; 0.1 part of MF4; 0.1 part of NO; Corrosive acid sodium 1.2-2.5 part; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; The first class that contracts Mierocrystalline cellulose 1-1.5 part; 2 parts in sodium hydroxide; 1 part in dextrin.
When being used to make coking coal, the raw material of binding agent of the present invention also comprises following parts by weight of component:
Bentonite 1-2 part; Aluminium sesquioxide 1-3 part; Lime carbonate 0.5-2 part.
Binding agent of the present invention has solved the problem of the extremely difficult moulding of coke powder, utilize binding agent of the present invention can produce formed coke, moulded coal etc., 70 kilograms of-90 kilograms/single balls of cold strength behind the formed coke product drying, not powder does not loose when 1300 ℃ of high temperature, fixed carbon reduction amount is few, do not contain Chemical Composition such as magnesium, phosphorus, aluminium, iron in the additive, chemically reactive is good.Can be suitable for industry instead of part coke such as metallurgy, chemical industry chemical fertilizer, calcium carbide uses.Use the collocation of coke enterprise to use by domestic ironmaking, casting, chemical fertilizer gas-making etc., all reached good result.While also provides practicable method for the moulding and the granulation of multiple diffusing shape powders such as smelting, chemical enterprise such as manganese ore powder, chromite ore fine, iron content dirt material.The formed coke that utilizes formed coke tackiness agent of the present invention to produce can guarantee the thermostability of formed coke, and the fixed carbon of the formed coke that do not descend again can play tangible energy-saving and emission-reduction, increase the effect of benefit.
Advantage of the present invention has: 1, easy to use: the big coke powder of water content be need not oven dry, directly in proportion coke powder, binding agent are mixed promptly plasticly, one ton of binding agent can be produced 20 tons of coke powder pelletizings; 2, excellent performance: once shaped, ratio of briquetting is up to 95-98%, do not loose in 2 meters high whereabouts of wet bulb, seasoning or oven dry all can, 100 kilograms/ball of dry back intensity, high temperature resistant 1000 ℃ of not powder that do not loose, do not contain Chemical Composition such as magnesium, phosphorus, aluminium, iron in the additive, chemically reactive is good, and fixed carbon reduction amount is little; 3, of many uses: as to utilize coke, refinery coke, blue carbon residual powder to be processed into pelletizing and to be suitable for small blast furnace ironmaking, advantages such as industry instead of part coke application such as furnace refractory, chemical industry coal gas raw material, calcium carbide raw materials for production.
Embodiment
Embodiment 1
Press row weight part proportioning feedstock production binding agent:
15 parts of asphalt powders; 10 parts in coal tar; 17 parts of coke tar refuse; MF40.1 part; 0.1 part of NO; 1.2 parts in corrosive acid sodium; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; 1.5 parts of the first class that contracts Mierocrystalline celluloses; 2 parts in sodium hydroxide; 1 part in dextrin.
Embodiment 2
Press row weight part proportioning feedstock production binding agent:
10 parts of asphalt powders; 16 parts in coal tar; 14 parts of coke tar refuse; 0.1 part of MF4; 0.1 part of NO; 2.5 parts in corrosive acid sodium; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; 1 part of the first class that contracts Mierocrystalline cellulose; 2 parts in sodium hydroxide; 1 part in dextrin.
Embodiment 3
Press row weight part proportioning feedstock production binding agent:
15 parts of asphalt powders; 10 parts in coal tar; 17 parts of coke tar refuse; 1 part of bentonite; 0.1 part of MF4; 0.1 part of NO; 1.2 parts in corrosive acid sodium; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; 1.5 parts of the first class that contracts Mierocrystalline celluloses; 2 parts in sodium hydroxide; 1 part in dextrin; 3 parts of aluminium sesquioxides; 0.5 part in lime carbonate.
Embodiment 4
Press row weight part proportioning feedstock production binding agent:
10 parts of asphalt powders; 16 parts in coal tar; 14 parts of coke tar refuse; 2 parts of bentonite; 0.1 part of MF4; 0.1 part of NO; 2.5 parts in corrosive acid sodium; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; 1 part of the first class that contracts Mierocrystalline cellulose; 2 parts in sodium hydroxide; 1 part in dextrin; 1 part of aluminium sesquioxide; 2 parts in lime carbonate.
It should be noted that at last: above embodiment only in order to the explanation the present invention and and unrestricted technical scheme described in the invention; Therefore, although this specification sheets has been described in detail the present invention with reference to each above-mentioned embodiment,, those of ordinary skill in the art should be appreciated that still and can make amendment or be equal to replacement the present invention; And all do not break away from the technical scheme and the improvement thereof of the spirit and scope of the present invention, all should be encompassed in the claim scope of the present invention.
Claims (2)
1, a kind of binding agent is characterized in that described binding agent is prepared from by following raw materials in weight portion:
Asphalt powder 10-15 part; Coal tar 10-16 part; Coke tar refuse 14-17 part; MF40.1 part; 0.1 part of NO; Corrosive acid sodium 1.2-2.5 part; 0.3 part of Sodium dodecylbenzene sulfonate; 0.5 part of polyvinyl lactam; The first class that contracts Mierocrystalline cellulose 1-1.5 part; 2 parts in sodium hydroxide; 1 part in dextrin.
2, binding agent as claimed in claim 1 is characterized in that the raw material of described binding agent also comprises following parts by weight of component:
Bentonite 1-2 part; Aluminium sesquioxide 1-3 part; Lime carbonate 0.5-2 part.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2009101359716A CN101555428A (en) | 2009-05-07 | 2009-05-07 | Adhesive |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNA2009101359716A CN101555428A (en) | 2009-05-07 | 2009-05-07 | Adhesive |
Publications (1)
Publication Number | Publication Date |
---|---|
CN101555428A true CN101555428A (en) | 2009-10-14 |
Family
ID=41173715
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNA2009101359716A Pending CN101555428A (en) | 2009-05-07 | 2009-05-07 | Adhesive |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN101555428A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101812341A (en) * | 2010-04-21 | 2010-08-25 | 姜文平 | Mechanical-coke and formed-coke quick-volatilizing high-strength adhesive |
CN105778963A (en) * | 2016-04-27 | 2016-07-20 | 神雾环保技术股份有限公司 | Compound adhesive and application thereof in cold-state molding of semicoke and quick lime |
CN107418644A (en) * | 2017-06-02 | 2017-12-01 | 太原理工大学 | A kind of briquette binder preparation method and application |
CN108239561A (en) * | 2018-01-25 | 2018-07-03 | 姜文平 | A kind of reduction wind dry type coal adhesive and production technology |
CN115926768A (en) * | 2021-08-24 | 2023-04-07 | 中国石油化工股份有限公司 | A kind of oil-soluble viscosity reducer composition and its preparation method and application |
-
2009
- 2009-05-07 CN CNA2009101359716A patent/CN101555428A/en active Pending
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101812341A (en) * | 2010-04-21 | 2010-08-25 | 姜文平 | Mechanical-coke and formed-coke quick-volatilizing high-strength adhesive |
CN105778963A (en) * | 2016-04-27 | 2016-07-20 | 神雾环保技术股份有限公司 | Compound adhesive and application thereof in cold-state molding of semicoke and quick lime |
CN107418644A (en) * | 2017-06-02 | 2017-12-01 | 太原理工大学 | A kind of briquette binder preparation method and application |
CN107418644B (en) * | 2017-06-02 | 2019-11-01 | 太原理工大学 | Application of a Briquette Binder |
CN108239561A (en) * | 2018-01-25 | 2018-07-03 | 姜文平 | A kind of reduction wind dry type coal adhesive and production technology |
CN115926768A (en) * | 2021-08-24 | 2023-04-07 | 中国石油化工股份有限公司 | A kind of oil-soluble viscosity reducer composition and its preparation method and application |
CN115926768B (en) * | 2021-08-24 | 2023-11-10 | 中国石油化工股份有限公司 | Oil-soluble viscosity reducer composition and preparation method and application thereof |
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C06 | Publication | ||
PB01 | Publication | ||
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Application publication date: 20091014 |