CN1014911B - Active carbon anode for electrolyting al - Google Patents
Active carbon anode for electrolyting alInfo
- Publication number
- CN1014911B CN1014911B CN88100103.1A CN88100103A CN1014911B CN 1014911 B CN1014911 B CN 1014911B CN 88100103 A CN88100103 A CN 88100103A CN 1014911 B CN1014911 B CN 1014911B
- Authority
- CN
- China
- Prior art keywords
- carbon anode
- anode
- electrolyting
- active carbon
- aluminium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract description 14
- 229910052799 carbon Inorganic materials 0.000 title abstract description 14
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 claims abstract description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 11
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 11
- 239000004411 aluminium Substances 0.000 claims abstract description 9
- 238000005868 electrolysis reaction Methods 0.000 claims abstract description 6
- 239000000571 coke Substances 0.000 claims abstract description 3
- 239000010405 anode material Substances 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 claims 1
- 229910052808 lithium carbonate Inorganic materials 0.000 abstract description 2
- 239000010426 asphalt Substances 0.000 abstract 1
- 239000003792 electrolyte Substances 0.000 abstract 1
- 238000000034 method Methods 0.000 description 4
- -1 sodium aluminum fluoride Chemical compound 0.000 description 3
- 239000003610 charcoal Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000009257 reactivity Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 239000003575 carbonaceous material Substances 0.000 description 1
- 230000003197 catalytic effect Effects 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000005242 forging Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25C—PROCESSES FOR THE ELECTROLYTIC PRODUCTION, RECOVERY OR REFINING OF METALS; APPARATUS THEREFOR
- C25C3/00—Electrolytic production, recovery or refining of metals by electrolysis of melts
- C25C3/06—Electrolytic production, recovery or refining of metals by electrolysis of melts of aluminium
- C25C3/08—Cell construction, e.g. bottoms, walls, cathodes
- C25C3/12—Anodes
- C25C3/125—Anodes based on carbon
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Electrolytic Production Of Metals (AREA)
- Battery Electrode And Active Subsutance (AREA)
Abstract
The present invention relates to an anode used for preparing aluminium by electrolysis, which is formed by mixing and nipping 0.4 to 1.5% of lithium carbonate, asphalt and coke. The present invention is characterized in that compared with the existing carbon anode, the overvoltage of the anode can be reduced by 150 to 200mV, so that 300 to 600 degrees of power can be saved in preparing per ton of aluminium. In addition, the electric conductivity of electrolyte can be enhanced.
Description
The invention belongs to the technical field of electrolytic production of aluminum.
Present aluminum electrolysis process be that aluminum oxide is carried out electrolysis and produces aluminium in sodium aluminum fluoride solution, and the anode that is adopted is a carbon anode.Because the oxonium ion delay of response of carbon anode and discharge in electrolytic process, the superpotential that causes carbon anode accounts for 9～14% of bath voltage up to 400～600mV.Therefore, existing technology is more because of the electric energy that adopts carbon anode to waste, thereby manages to reduce the key that the anodic superpotential is a head it off.
In view of the foregoing the objective of the invention is to change existing carbon anode composition, a kind of active carbon anode for electrolyting Al material that can reduce anodic overvoltage is provided.
A kind of used for aluminium electrolysis gac anode material provided by the invention is for achieving the above object made by the carbonaceous material that contains 0.4～1.5% Quilonum Retard.Be specially 0.4～1.5% Quilonum Retard is joined in the pitch of fusing, mix and pinch into charcoal and stick with paste with forging the back coke again after stirring, Quilonum Retard can be evenly distributed in the surperficial and inner of carbon anode like this.The carbon anode of this lithium carbonate containing has higher chemical reactivity in electrolytic process, can impel the chemical reaction velocity between charcoal and oxonium ion to accelerate, thereby can reduce the anodic superpotential.Thereby the content of Quilonum Retard will be in above-mentioned scope value, if the content of Quilonum Retard is lower than 0.4%, then its catalytic effect is not obvious; If the content of Quilonum Retard is higher than 1.5%, though have certain chemical reactivity, the manufacturing cost of electrode improves, the ratio resistance of electrode also increases thereupon because of the increase of its content is facilitated.
Used for aluminium electrolysis gac anode provided by the invention is compared with existing pure carbon anode, can make anodic overvoltage reduce by 150～200mV, bath voltage than original minimizing 25～5%, can save electric energy 300～600 degree thereby produce aluminium per ton.With the exception of this, because contained Quilonum Retard is dissolved in electrolytic process in the ionogen in the gac anode, can make electrolytical temperature reduce, improve electrolytical electric conductivity.
One of embodiments of the invention:
Add 0.4% Quilonum Retard in the self-baking carbon anode, anodic overvoltage is produced aluminium per ton and can be saved about 400 degree of electric energy than the original 150mV that reduces.
Two of embodiments of the invention:
Add 1.5% Quilonum Retard in the self-baking carbon anode, anodic overvoltage is produced aluminium per ton and can be saved about 600 degree of electric energy than the original 200mV that reduces.
Claims (1)
1, a kind of used for aluminium electrolysis gac anode material is mainly formed by coke with as the pitch of binding agent, it is characterized in that wherein also containing equably 0.4～1.5% the Quilonum Retard that accounts for total material weight.
Priority Applications (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN88100103.1A CN1014911B (en) | 1988-01-06 | 1988-01-06 | Active carbon anode for electrolyting al |
| US07/292,383 US4885073A (en) | 1988-01-06 | 1988-12-30 | Activated carbon anode including lithium |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN88100103.1A CN1014911B (en) | 1988-01-06 | 1988-01-06 | Active carbon anode for electrolyting al |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1034027A CN1034027A (en) | 1989-07-19 |
| CN1014911B true CN1014911B (en) | 1991-11-27 |
Family
ID=4831176
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN88100103.1A Expired CN1014911B (en) | 1988-01-06 | 1988-01-06 | Active carbon anode for electrolyting al |
Country Status (2)
| Country | Link |
|---|---|
| US (1) | US4885073A (en) |
| CN (1) | CN1014911B (en) |
Families Citing this family (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5310476A (en) | 1992-04-01 | 1994-05-10 | Moltech Invent S.A. | Application of refractory protective coatings, particularly on the surface of electrolytic cell components |
| US5651874A (en) | 1993-05-28 | 1997-07-29 | Moltech Invent S.A. | Method for production of aluminum utilizing protected carbon-containing components |
| US6001236A (en) | 1992-04-01 | 1999-12-14 | Moltech Invent S.A. | Application of refractory borides to protect carbon-containing components of aluminium production cells |
| US5397450A (en) * | 1993-03-22 | 1995-03-14 | Moltech Invent S.A. | Carbon-based bodies in particular for use in aluminium production cells |
| AU688098B2 (en) | 1994-09-08 | 1998-03-05 | Moltech Invent S.A. | Aluminium electrowinning cell with improved carbon cathode blocks |
| US5753163A (en) | 1995-08-28 | 1998-05-19 | Moltech. Invent S.A. | Production of bodies of refractory borides |
| BR9900252A (en) | 1999-02-02 | 2000-08-29 | Companhia Brasileira Carbureto | Stainless steel container for forming self-baking electrodes for use in electric reduction blast furnaces |
| BR9900253A (en) | 1999-02-02 | 2000-08-29 | Companhia Brasileira Carbureto | Aluminum and stainless steel container forming self-cooking electrodes for use in electric reduction furnaces |
| US7141149B2 (en) * | 2004-06-22 | 2006-11-28 | Cii Carbon Llc | Electrodes useful for molten salt electrolysis of aluminum oxide to aluminum |
| CN112853401A (en) * | 2020-12-30 | 2021-05-28 | 江苏苏菱铝用阳极有限公司 | Prebaked anode for inhibiting active alkali metal in anode |
| CN116444273A (en) * | 2022-01-10 | 2023-07-18 | 山东圣泉新材料股份有限公司 | Resin carbon anode green body and preparation method thereof, green body intermediate and preparation method thereof, carbon anode and preparation method thereof |
| CN115142093B (en) * | 2022-07-14 | 2024-01-30 | 湖南大学 | Prebaked anode antioxidant, preparation method and application thereof |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4011374A (en) * | 1975-12-02 | 1977-03-08 | The United States Of America As Represented By The United States Energy Research And Development Administration | Porous carbonaceous electrode structure and method for secondary electrochemical cell |
-
1988
- 1988-01-06 CN CN88100103.1A patent/CN1014911B/en not_active Expired
- 1988-12-30 US US07/292,383 patent/US4885073A/en not_active Expired - Fee Related
Also Published As
| Publication number | Publication date |
|---|---|
| CN1034027A (en) | 1989-07-19 |
| US4885073A (en) | 1989-12-05 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |