CN101484570A - Beverage comprising insoluble gas - Google Patents
Beverage comprising insoluble gas Download PDFInfo
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- CN101484570A CN101484570A CNA2007800249525A CN200780024952A CN101484570A CN 101484570 A CN101484570 A CN 101484570A CN A2007800249525 A CNA2007800249525 A CN A2007800249525A CN 200780024952 A CN200780024952 A CN 200780024952A CN 101484570 A CN101484570 A CN 101484570A
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- Prior art keywords
- beverage
- gas
- insoluble gas
- beer
- insoluble
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- 235000013361 beverage Nutrition 0.000 title claims abstract description 93
- 239000007789 gas Substances 0.000 claims description 89
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 33
- 235000013405 beer Nutrition 0.000 claims description 31
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 claims description 24
- 229910052757 nitrogen Inorganic materials 0.000 claims description 17
- ATUOYWHBWRKTHZ-UHFFFAOYSA-N Propane Chemical compound CCC ATUOYWHBWRKTHZ-UHFFFAOYSA-N 0.000 claims description 16
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims description 16
- 229910052760 oxygen Inorganic materials 0.000 claims description 15
- 229910052786 argon Inorganic materials 0.000 claims description 12
- 239000001307 helium Substances 0.000 claims description 12
- 229910052734 helium Inorganic materials 0.000 claims description 12
- 239000001257 hydrogen Substances 0.000 claims description 12
- 229910052739 hydrogen Inorganic materials 0.000 claims description 12
- SWQJXJOGLNCZEY-UHFFFAOYSA-N helium atom Chemical compound [He] SWQJXJOGLNCZEY-UHFFFAOYSA-N 0.000 claims description 11
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 10
- 239000001301 oxygen Substances 0.000 claims description 10
- -1 cyclic hydrocar-bons Chemical class 0.000 claims description 9
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical compound CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 claims description 8
- 229930195733 hydrocarbon Natural products 0.000 claims description 8
- 229910052743 krypton Inorganic materials 0.000 claims description 8
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 claims description 8
- 229910052754 neon Inorganic materials 0.000 claims description 8
- GKAOGPIIYCISHV-UHFFFAOYSA-N neon atom Chemical compound [Ne] GKAOGPIIYCISHV-UHFFFAOYSA-N 0.000 claims description 8
- 239000001294 propane Substances 0.000 claims description 8
- 235000014214 soft drink Nutrition 0.000 claims description 8
- 230000006872 improvement Effects 0.000 claims description 5
- 230000006353 environmental stress Effects 0.000 claims description 3
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims 2
- 235000019659 mouth feeling Nutrition 0.000 abstract description 7
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 30
- 239000006260 foam Substances 0.000 description 25
- 235000011089 carbon dioxide Nutrition 0.000 description 20
- 239000007788 liquid Substances 0.000 description 15
- 238000000034 method Methods 0.000 description 14
- GQPLMRYTRLFLPF-UHFFFAOYSA-N Nitrous Oxide Chemical compound [O-][N+]#N GQPLMRYTRLFLPF-UHFFFAOYSA-N 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 10
- 230000035622 drinking Effects 0.000 description 6
- 150000002431 hydrogen Chemical class 0.000 description 6
- 239000001272 nitrous oxide Substances 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 5
- 235000019640 taste Nutrition 0.000 description 5
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 4
- 238000000855 fermentation Methods 0.000 description 4
- 230000004151 fermentation Effects 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 239000000047 product Substances 0.000 description 4
- 239000011435 rock Substances 0.000 description 4
- 239000002253 acid Substances 0.000 description 3
- 229910002092 carbon dioxide Inorganic materials 0.000 description 3
- 239000001569 carbon dioxide Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 235000019605 sweet taste sensations Nutrition 0.000 description 3
- 235000020017 wheat beer Nutrition 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- IOVCWXUNBOPUCH-UHFFFAOYSA-N Nitrous acid Chemical compound ON=O IOVCWXUNBOPUCH-UHFFFAOYSA-N 0.000 description 2
- 239000000443 aerosol Substances 0.000 description 2
- 235000015107 ale Nutrition 0.000 description 2
- 235000019998 barley wine Nutrition 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 235000015095 lager Nutrition 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 102000004169 proteins and genes Human genes 0.000 description 2
- 108090000623 proteins and genes Proteins 0.000 description 2
- 235000012976 tarts Nutrition 0.000 description 2
- 239000011800 void material Substances 0.000 description 2
- 235000014101 wine Nutrition 0.000 description 2
- FFRBMBIXVSCUFS-UHFFFAOYSA-N 2,4-dinitro-1-naphthol Chemical compound C1=CC=C2C(O)=C([N+]([O-])=O)C=C([N+]([O-])=O)C2=C1 FFRBMBIXVSCUFS-UHFFFAOYSA-N 0.000 description 1
- PAWQVTBBRAZDMG-UHFFFAOYSA-N 2-(3-bromo-2-fluorophenyl)acetic acid Chemical compound OC(=O)CC1=CC=CC(Br)=C1F PAWQVTBBRAZDMG-UHFFFAOYSA-N 0.000 description 1
- 241000894006 Bacteria Species 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- 241001539473 Euphoria Species 0.000 description 1
- 206010015535 Euphoric mood Diseases 0.000 description 1
- 241000209219 Hordeum Species 0.000 description 1
- 235000007340 Hordeum vulgare Nutrition 0.000 description 1
- GXCLVBGFBYZDAG-UHFFFAOYSA-N N-[2-(1H-indol-3-yl)ethyl]-N-methylprop-2-en-1-amine Chemical compound CN(CCC1=CNC2=C1C=CC=C2)CC=C GXCLVBGFBYZDAG-UHFFFAOYSA-N 0.000 description 1
- WTYPILSVGOSWBQ-UHFFFAOYSA-N N=N=O Chemical group N=N=O WTYPILSVGOSWBQ-UHFFFAOYSA-N 0.000 description 1
- 206010028813 Nausea Diseases 0.000 description 1
- 208000003251 Pruritus Diseases 0.000 description 1
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 1
- 244000098338 Triticum aestivum Species 0.000 description 1
- 235000009754 Vitis X bourquina Nutrition 0.000 description 1
- 235000012333 Vitis X labruscana Nutrition 0.000 description 1
- 240000006365 Vitis vinifera Species 0.000 description 1
- 235000014787 Vitis vinifera Nutrition 0.000 description 1
- 235000013334 alcoholic beverage Nutrition 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000019658 bitter taste Nutrition 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 235000014171 carbonated beverage Nutrition 0.000 description 1
- JYYOBHFYCIDXHH-UHFFFAOYSA-N carbonic acid;hydrate Chemical compound O.OC(O)=O JYYOBHFYCIDXHH-UHFFFAOYSA-N 0.000 description 1
- 235000019993 champagne Nutrition 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- RBNWAMSGVWEHFP-UHFFFAOYSA-N cis-p-Menthan-1,8-diol Natural products CC(C)(O)C1CCC(C)(O)CC1 RBNWAMSGVWEHFP-UHFFFAOYSA-N 0.000 description 1
- 238000002288 cocrystallisation Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000007423 decrease Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 238000004821 distillation Methods 0.000 description 1
- 235000020026 dunkelweizenbier Nutrition 0.000 description 1
- 125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
- 238000004880 explosion Methods 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- 210000004907 gland Anatomy 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 239000005431 greenhouse gas Substances 0.000 description 1
- 150000002371 helium Chemical class 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 230000009545 invasion Effects 0.000 description 1
- 230000007803 itching Effects 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000033001 locomotion Effects 0.000 description 1
- 230000005389 magnetism Effects 0.000 description 1
- 235000021577 malt beverage Nutrition 0.000 description 1
- VUZPPFZMUPKLLV-UHFFFAOYSA-N methane;hydrate Chemical compound C.O VUZPPFZMUPKLLV-UHFFFAOYSA-N 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000008693 nausea Effects 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen(.) Chemical compound [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- 210000000056 organ Anatomy 0.000 description 1
- 229930006948 p-menthane-3,8-diol Natural products 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 238000012797 qualification Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000000630 rising effect Effects 0.000 description 1
- 230000001835 salubrious effect Effects 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 230000035807 sensation Effects 0.000 description 1
- 235000019615 sensations Nutrition 0.000 description 1
- 210000000697 sensory organ Anatomy 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 229950010257 terpin Drugs 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000009423 ventilation Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C11/00—Fermentation processes for beer
- C12C11/11—Post fermentation treatments, e.g. carbonation, or concentration
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/40—Effervescence-generating compositions
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES, NOT OTHERWISE PROVIDED FOR; PREPARATION OR TREATMENT THEREOF
- A23L2/00—Non-alcoholic beverages; Dry compositions or concentrates therefor; Preparation or treatment thereof
- A23L2/52—Adding ingredients
- A23L2/54—Mixing with gases
-
- C—CHEMISTRY; METALLURGY
- C12—BIOCHEMISTRY; BEER; SPIRITS; WINE; VINEGAR; MICROBIOLOGY; ENZYMOLOGY; MUTATION OR GENETIC ENGINEERING
- C12C—BEER; PREPARATION OF BEER BY FERMENTATION; PREPARATION OF MALT FOR MAKING BEER; PREPARATION OF HOPS FOR MAKING BEER
- C12C5/00—Other raw materials for the preparation of beer
- C12C5/02—Additives for beer
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Organic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Bioinformatics & Cheminformatics (AREA)
- Genetics & Genomics (AREA)
- Biochemistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Nutrition Science (AREA)
- Polymers & Plastics (AREA)
- Non-Alcoholic Beverages (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
Abstract
The present invention relates to the use of insoluble gas in beverage to improve head characteristics and to pro not vide a more pleasant and smooth mouth feeling experience perceived by the drinker.
Description
Technical field
The present invention relates to the application of insoluble gas in beverage such as beer or soft drink for example.
Background technology
Meeting is blistered, send the bubble drink that emits that fizzs is common known carbonated beverages in the past.Term herein " carbonating " is meant that carbonic acid gas is dissolved in this beverage.Generally speaking, these beverage main components are water, and a part of carbonic acid gas and water reaction and form carbonic acid, and remaining carbonic acid gas is then stayed in the physical solution.Carbonic acid gas often will be by pressurized package, not equal environmental stress (101, pack under condition 335Pa), even it is also not all right to pack under quite low temperature such as for example 0 ℃ of grade.
When the human consumer unpacked, the pressure in the headspace of this packing can fade to suddenly and be not enough to carbonic acid gas is remained in the solution, so carbonic acid gas begins to escape.But, this is to spend a slow process of tens of minutes, so will experience the distinctive mouthfeel of sending out puckery, itching during the thin liquid layer in the lower jaw of drinking person around the carbonic acid gas bubble effusion tongue in mouth.Carbonic acid can bring remarkable strong impulse tart flavour.Disruptive carbonic acid gas bubble can produce the aerosol mist when breaking, the attention that it causes the olfactory organ in the nose has produced smell thus.
May be this just " salubrious sense ", made people intoxicated for it in several thousand.The water of natural bubbling and the fermentation as beer and champagne emit bubble drink always very popular.But, carbonic acid gas can be brought into play more function: particularly for beer, expectation is supplied with the good quality froth beverage usually, and the quality of beverage reaches such degree usually, still keeps a little carbonic acid gas when drinking end.
This air foam is to be produced by the carbonic acid gas bubble that rises, and the carbonic acid gas bubble then must be certain flaw that comes from the glass drinking glasses, perhaps comes from the particle that is suspended in this liquid.These bubbles rise to surperficial speed will be faster than the speed according to the Stokes'theorem anticipation, this is because thereby they expand because of the cause of hydrostatic drops when rising and because cause air bubble growth/increase/diffusion because of the bubble that diffuses into surrounding liquid.When they washed the surface open, they were carried into one deck liquid on the vault (dome) on top.If bubble rises enough soon, a bubble will be pressed on other bubbles of one deck, so formed air foam liquid (broth).At first, this air foam liquid is by forming with the spherical bubbles of the slime layer that has occupied void volume.If glass cylinder is tilted, as following beverage, air foam will be kept horizontal plane.Be because this part void volume of liquid is followed poiseuille (Poiseuilles) equation like this.But soon, liquid-flow, bubble will begin contact, and these bubbles have the multiaspect platelets, have extremely thin liquid layer between the platelets.Very fast, all bubbles all will become polyhedron.The most possible polyhedron that occurs, promptly non-Euler's polyhedron is made of hexagon and pentagon.Air foam so far becomes solid-state, and the motion of liquid between the face of multiaspect platelets so far controlled by capillary flow.
Air foam liquid is except having aesthetic magnetism; also play the effect of the reduction taste of protection beer; for example, can protect α-different humolonic acid or aldehydes in soft drink or the terpin alcohols invasion and attack that avoid be subjected to oxygen in atmosphere of beer full taste in distributing.For this reason, lucky coincidence is, carbonic acid gas is heavily more about 50% than ambient atmosphere, this makes it can rest on the top of air foam liquid and protects air foam to become dry to be avoided its as the saturated cover of water vapor.
The life-span of air foam can be with viscosity and incipient bubble size and different, does not wait to several hours from several seconds.For the beverage of a lot of types, all wish to prolong this life-span.A kind of mode that prolongs the air foam life-span is the amount that increases institute's carbon dioxide dissolved simply.Henry's law is to a certain extent applicable to such beverage.
The foam that has more viscosity can produce by adding various polymkeric substance, or by instructing fermentation in the mode that produces these polymkeric substance.These polymkeric substance are polysaccharide normally.Also known interpolation six hydrogen α-different humolonic acid can produce highly stable air foam.
Another mode that prolongs the air foam life-span is also to dissolve another soluble gas, for example nitrous oxide (N in beverage except carbonic acid gas
2O), this has increased the total amount of gas dissolved.
US 2002/0197364 discloses the method that a kind of production is contained in the flowing product in jar or bottle or other suitable containers.This method comprises the step of one or more gases in nitrogen, carbonic acid gas and the nitrous oxide being injected liquid product.
WO 00/23357 has described a kind of by rocking the method for improving the characteristic of foaming that is contained in the nitrogenize flowing product in jar, bottle or other suitable containers.In addition, the document discloses a kind of method, it is characterized in that, flowing product is charged into jar or bottle or other suitable containers before, during or afterwards, with nitrous oxide with optionally nitrogen and/or carbonic acid gas inject this flowing product.
In addition, for many years, in worldwide, nitrogen has been used for the barley broth of nitrogenize to obtain butyraceous air foam.But, obtain believable creamy head in order to utilize nitrogen, some measure is necessary.
Guinness (Guinness) and Caffries use so-called dingus technology, and wherein, the plastics " dingus " that are full of nitrogen have aperture, produce a large amount of small bubbles when pressure descends, thereby produce creamy head.
The another kind of method that produces creamy head in nitrogenized beer is to use the so-called SURGER that is sold by Guinness, and it is by the ultrasonic creamy head that produces.
It is known using argon gas and hydrogen in beverage, but its purpose is not in order to improve head characteristics.
GB1408995 discloses and has a kind ofly for example dissolved for example method of rare gas elementes such as nitrogen, argon gas and hydrogen in the beverages such as beer, grape wine and soft drink, this method comprises: remove air from container, rare gas element is introduced this container, this container of then beverage being packed into makes that the air pressure in this container is 5~90psig (pound/square inch).The purpose of this method is to improve taste and anti-deterioration.
Yet, exist such difficult problem all the time in the bubbling field of beverage: beverage is had continue permanent air foam and don't cause negative impact can for the taste of beverage.Another difficult problem is, a kind of bubble drink that emits is provided, and wherein, institute's one or more gases of dissolved can provide joyful mouthfeel when drinking person is drunk this beverage.
Although this area has now been known a large amount of bubble drinks that emits, but still there is such demand that is not satisfied: promptly, provide a kind of improvement beverage that more joyful mouth feeling experience can be provided when drinking person is drunk this beverage.Also there is such demand: provide a kind of beverage that can when toppling over, produce more stable air foam.Also there is such demand in addition: a kind of improvement beverage with above-mentioned character is provided, and when obtaining these character, can significantly increase the manufacturing cost of beverage.
Summary of the invention
The present invention relates to insoluble gas is used to improve head characteristics and provides pleasant more and the purposes of pure and mild mouth feeling experience in beverage.
This effect can realize by dissolving one or more following insoluble gas: cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, nitrogen, hydrogen, neon and/or helium, prerequisite is that nitrogen is not independent use when using as described insoluble gas.Preferably, described beverage also comprises one or more soluble gas, for example N in this beverage
2O and CO
2
Therefore, in first aspect, the invention provides the purposes that insoluble gas is used to improve the head characteristics of beverage, prerequisite is that nitrogen is not the insoluble gas of unique use.
In a preferred implementation, provide the described insoluble gas of the solubleness of use under room temperature environment pressure less than 1.0g/l.
In another preferred embodiment, provide the described insoluble gas that uses to be selected from cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, hydrogen, neon and helium.
In the 3rd preferred implementation, the described purposes of insoluble gas in beverage is provided, the consumption of described insoluble gas is extremely about 2g/l of about 0.1g/l, is preferably about 0.3g/l to about 1g/l.
In another preferred embodiment, described beverage is beer or soft drink.
In a further preferred embodiment, provide N
2The consumption of O is extremely about 15g/l of about 0.1g/l, is preferably about 1g/l to about 10g/l, is preferably about 4g/l especially to about 6g/l.
In another preferred embodiment, provide CO
2Consumption for about 0.1g/l to about 15g/l, be preferably extremely about 10g/l of about 1g/l, be preferably extremely about 6g/l of about 4g/l especially.
In another preferred implementation, further provide use N
2
In second aspect, the invention provides the beverage of head characteristics with improvement, this beverage comprises N
2O and insoluble gas, prerequisite are N
2Be not included in the unique insoluble gas in this beverage.
In a preferred implementation, the described beverage that comprises described insoluble gas is provided, the solubleness of described insoluble gas under room temperature environment pressure is less than 1.0g/l.
Second preferred embodiment in, provide to comprise the beverage that is selected from following insoluble gas: cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, hydrogen, neon and helium.
In the 3rd preferred implementation, described beverage is beer or soft drink.
In another preferred embodiment, provide and comprised N
2The described beverage of O, this N
2The content of O is extremely about 15g/l of about 0.1g/l, is preferably about 1g/l to about 10g/l, is preferably about 4g/l especially to about 6g/l.
In further preferred embodiment, the described beverage that comprises described insoluble gas is provided, the content of described insoluble gas is extremely about 2g/l of about 0.1g/l, is preferably about 0.3g/l to about 1g/l.
In another preferred embodiment, provide and also comprised CO
2Described beverage, this CO
2Content for about 0.1g/l to about 15g/l, be preferably extremely about 10g/l of about 1g/l, be preferably extremely about 6g/l of about 4g/l especially.
In another preferred implementation, provide also to comprise N
2Described beverage.
Embodiment
An object of the present invention is completely or partially to solve the above-mentioned needs that are not met.More particularly, an object of the present invention is to provide a kind of beverage, this beverage can be given the mouth feeling experience that the human consumer improves when being drunk by the human consumer.Another object of the present invention provides and has the beverage that continues air foam more of a specified duration.And, the present invention also aims to provide beverage, and the production of this beverage that is provided is unlike the traditional beverages difficulty with above-mentioned character, production cost is also unlike the traditional beverages height.
It is obvious that above-mentioned purpose and many other purposes, advantage and feature will become by following description, it can for example beer or soft drink be realized by the beverage of technical scheme of the present invention by comprising insoluble gas, prerequisite is that nitrogen is not the insoluble gas of unique use.Preferably, described beverage also comprises soluble gas, for example N
2O and CO
2
Preferably, described beverage comprises one or more following insoluble gas: cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, nitrogen, hydrogen, neon and/or helium, prerequisite is that nitrogen is not independent use when using as described insoluble gas.More preferably, described beverage also comprises one or more soluble gas, for example N
2O and CO
2
Preferably, described beverage is a beer.But, the present invention is not limited to beer.On the contrary, the invention provides insoluble gas and for example N
2The purposes of some other gas such as O in beer and non-beer beverage, described non-beer beverage for example have mineral water, add flavor alcoholic beverage (FlavouredAlcoholic Beverages), with malt beverage (malt drinks) etc.Preferably, can be with N
2O is used for the beverage of particular type, wherein, and N
2O particularly advantageous part is to have aforesaid unique benefit to quality of head and sweet taste.The beverage of these types comprises top fermentation beer and bottom fermented beer etc.Specifically, included beer type is Wit (Belgian wheat beer) type, Weizen (wheat beer) type, Dunkel-weizen (black wheat beer) type or Ale (ale) type, for example Paleblond (light golden yellow), Brown (brown beer), Bitter IPA (bitter taste IPA) or barley wine (Barley wines) and strong.Sedimentary fermentation type beer comprise the low lager beer (lager) of the U.S., vienna type beer,
With red beer or typical Munich types beer, black Munich and bock (Bock), and last Baltic Sea baud (Baltic Porter) type.In all cases, insoluble gas and the N that preferably is dissolved in beverage
2O can provide mouthfeel pure and mild, pleasant, and the stable air foam of pleasant is provided.
Preferably, described beverage comprises the described insoluble gas of about 0.01g/l to about 5g/l.More preferably, described beverage comprises the described insoluble gas of about 0.1g/l to about 2g/l.More preferably, described beverage comprises the described insoluble gas of about 0.3g/l to about 1g/l.
In addition, described beverage preferably comprises the N of about 0.1g/l to about 15g/l
2O.More preferably, described beverage comprises the N of about 1g/l to about 10g/l
2O.More preferably, described beverage comprises the N of about 4g/l to about 6g/l
2O.
In addition, described beverage preferably comprises the CO of about 0.1g/l to about 15g/l
2More preferably, described beverage comprises the CO of about 1g/l to about 10g/l
2More preferably, described beverage comprises the CO of about 4g/l to about 6g/l
2
In fact, bubble is more little, and the air foam that is produced continues of a specified duration more.Yet, existing physically the limit in such carbon dioxide/water system, forming how little bubble, this physics limit depends on surface tension.Specifically, if imaginary bubble less than 2 * (wherein P is with newton/m to (surface tension of this liquid)/P
2The pressure that this bubble institute of expression " sees "), it will break, and is reuptaked in the liquid.Therefore, surface tension is more little, and bubble is more little.
According to surface chemistry as can be known, high surface tension and high-dissolvability match.This is because the molecule with high-dissolvability is difficult for the surface of being ostracised.
By adding a spot of CO of ratio
2Have more insoluble gas, this gas will cause the littler bubble of spontaneous formation when equilibrium pressure reduces suddenly.
The inventor finds, in common soda pop, the incipient bubble diameter is about 40 microns, but the amount by adding 0.3g/l to 1g/l have more insoluble gas, the size of seed gas bubble will be dwindled 3 orders of magnitude, and the quantity of seed gas bubble then increases with the similar order of magnitude.
The inventor finds, produces littler bubble by dissolving insoluble gas in beverage, can provide more stable and continue air foam more of a specified duration, and can not influence the taste of this beverage.In fact, the above-mentioned beverage that is dissolved with insoluble gas provides and has had more viscosity, better to eat creamy head, thereby can constitute the mouth feeling experience of pleasant on the whole and the sense organ that drinking person is experienced energetically.
Therefore, according to the present invention, this discovery provides a technical scheme, and this technical scheme can solve a described difficult problem,, improves the head characteristics emit bubble drink and mouth feeling experience and not remarkably influenced cost that is.
Based on this discovery,, several insoluble gas can be used to provide the beverage of head characteristics with described improvement according to the present invention.
Insoluble gas of the present invention be solubleness under room temperature environment pressure less than the gas of 1.0g/l, preferably this solubleness is more preferably less than 0.1g/l less than 0.5g/l.
Insoluble gas of the present invention is selected from the group by following gas composition: cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, nitrogen, hydrogen, neon and helium.From left to right, insoluble increase successively.
Argon gas obtains with liquid state or pressurized gas form easily.Because it can extract by atmosphere (accounting for 0.9% in atmosphere) distillation, therefore very sufficient, be inertia, in environment, have fabulous inertia, nontoxic (because it does not form compound) and safety.
Oxygen is easy to get, and since very sufficient, so quite cheap; It accounts for 20.9% in atmosphere, can extract by distilling as argon gas.
Hydrogen can use under away from the consumption of limits of explosion and concentration, equally also can think safe.
Helium also is a kind of available gas that is applicable to this application.
The inventor also finds, in beverage with insoluble gas and N
2O is used in combination and can strengthens head characteristics and mouth feeling experience, and does not need to adopt other measures of the relevant nitrogen of mentioning in the background technology.Nitrous oxide not only helps to form better butteriness, stablize good to eat air foam, but also makes beverage have the sweet taste of pleasant.
But, improve the method for air foam of beverage also more than these.Carbonic acid gas is three atom linear molecules, because its symmetric O=C=O, it does not have moment of dipole, and is therefore soluble in water on physics.Yet carbonic acid gas can react with water, and forms carbonic acid, therefore only can partly be dissolved into physical solution.Can reduce the pH value of beverage by adding stronger acid, be reversed thereby impel carbonic acid to form molecular balance.But very fast, tart flavour will cause dislike.Someone may expect using other gas, for example HFC and various HCFC.Even the ethene that has unique apple aroma also can be used for for example Sucus Mali pumilae drink originally.But these gases all are greenhouse gases, and can cause nausea and floaty euphoria.Yet they now have been widely used for conditioning unit, refrigerator and aerosol canister.
On the contrary, as mentioned above, the invention provides the independent use of one or more insoluble gas or with being used in combination of nitrous oxide and/or carbonic acid gas, wherein, described insoluble gas is selected from cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, nitrogen, hydrogen, neon and helium, prerequisite is that nitrogen is not independent use when using as described insoluble gas.
Nitrous oxide is a linear molecule, but asymmetric.Its structure is N=N=O.This electronic structure only can be explained by using orbit theory.It has high moment of dipole, and the mechanism of being followed when it is water-soluble is very different with the mechanism of carbonic acid gas.But in addition, N
2O and CO
2Between have many similaritys: both have fusing point much at one, belong to the isomorphism, can have similar boiling point (N with any ratio cocrystallization
2O and CO
2Be respectively-89 ℃ and-79 ℃), they can keep liquid under room temperature and about 80 bar pressures, and they all have 44 molecular weight, and they have similar solubleness in water.According to J.Chem.Eng.Data (nineteen ninety-five, the 40th phase, 627-629 page or leaf), their henry 's law constant and diffusion constants in 303K to 333K scope differ in 5%.This is unexpected, because both dissolution mechanisms are so different, one is by chemical reaction, and another is by pure physics mode.With regard to nitrous acid, it does not form by water-soluble, but must just can make through some twists and turns.At occurring in nature, N
2O can be formed by some bacterium.Aspect artificial, its manufacturing is by ammonium nitrate being heated to 190 ℃, and is perhaps according to Ullmann, adopts and utilizes the novel method of the direct reaction between nitrous acid and the ammonia to make.According to Gmelin (Gai Molin), it absorbs heat, but different with acetylene, allow its blast be unusual difficulty, only can use the high strength detonator and only can at high temperature carry out.
Embodiment/preferred implementation
Below experiment is used to explain the present invention, but must not be considered as the qualification to scope of the present invention.
In experiment, in the time of 5 ℃, from the fresh Carlsberg pilsner (Pilsner) of 50 liters of barreleds, go 17 liters, rock this bucket then, left standstill 2 hours, and ventilation enters in the atmosphere so that air foam is calmed down, and then rock this bucket, and leave standstill, ventilating enters in the atmosphere.After rocking for six times, the content of this barrel is " deflation " fully.Use water trap to keep aseptic constantly.This bucket places 5 ℃ to refrigerate always.
Then, should bucket and helium tank and N
2The O gas cylinder connects.The reducing valve of these two gas cylinders all is controlled at 3 crust, rocks beer, and with this bucket sealing.
Second day, with this helium/N
2O/CO
2Mixture ventilates and enters atmosphere, and repeats this program.After 4 days, helium and N
2Gageable decline will can not take place in the pressure of O after spending the night.
Carried out further pressure adjustment at ensuing one day, after 3 days, pressure will remain unchanged at 3 Ba Chu.
Then this beer is refrigerated, and under aseptic condition, putting the 33cl bottle of wine on the filling machine of laboratory to pack into general from gland.After one week, pour beer into test glasses usually.The beer of gained has butyraceous air foam and pure sweet taste, and imperceptible " sensation of pricking " by carbon dioxide generating.
In a manner described the beer degassing can be caused some proteinic sex change usually, it is generally acknowledged that these protein help to form air foam.Although do not want to be bound by theory, it is believed that this is caused possible CO by rocking beer
2In this process, also played vital role.These denatured protein are rendered as tectum with having characteristic in phase microscope.When using said procedure, this phenomenon will not occur, and only contain CO
2The contrast bucket that rocks of process after one day tectum appears then.
Although foregoing invention has obtained describing, it will be readily apparent to one skilled in the art that some modification also can be expected under the condition that does not deviate from the following defined invention of claim aspect inventive embodiments.
Claims (16)
1. insoluble gas is used to improve the purposes of the head characteristics of beverage, and prerequisite is that nitrogen is not the insoluble gas of unique use.
2. purposes according to claim 1, wherein, the solubleness of described insoluble gas under room temperature and environmental stress is less than 1.0g/l.
3. purposes according to claim 1 and 2, wherein, described insoluble gas is selected from cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, hydrogen, neon and helium.
4. according to each described purposes in the aforementioned claim, wherein, the amount of the described insoluble gas that described beverage comprises is extremely about 2g/l of about 0.1g/l, is preferably about 0.3g/l to about 1g/l.
5. according to each described purposes in the aforementioned claim, wherein, described beverage is beer or soft drink.
6. according to each described purposes in the aforementioned claim, it also comprises use N
2O, this N
2The consumption of O is extremely about 15g/l of about 0.1g/l, is preferably about 1g/l to about 10g/l, is preferably about 4g/l especially to about 6g/l.
7. according to each described purposes in the aforementioned claim, it also comprises use CO
2, this CO
2Consumption for about 0.1g/l to about 15g/l, be preferably extremely about 10g/l of about 1g/l, be preferably about 4 especially
G/l is to about 6g/l.
8. according to each described purposes in the aforementioned claim, it also comprises use N
2
9. the beverage that has the head characteristics of improvement, described beverage comprises N
2O and insoluble gas, prerequisite are N
2Be not included in the unique insoluble gas in this beverage.
10. beverage according to claim 9, wherein, the solubleness of described insoluble gas under room temperature and environmental stress is less than 1.0g/l.
11. according to claim 9 or 10 described beverages, wherein, described insoluble gas is selected from cyclic hydrocar-bons, krypton gas, propane, ethane, methane, argon gas, oxygen, hydrogen, neon and helium.
12. according to each described beverage in the claim 9 to 11, described beverage is beer or soft drink.
13. according to each described beverage in the claim 9 to 12, wherein, the N that described beverage comprises
2The content of O is extremely about 15g/l of about 0.1g/l, is preferably about 1g/l to about 10g/l, is preferably about 4g/l especially to about 6g/l.
14. according to each described beverage in the claim 9 to 13, wherein, the content of the described insoluble gas that described beverage comprises is extremely about 2g/l of about 0.1g/l, is preferably about 0.3g/l to about 1g/l.
15. according to each described beverage in the claim 9 to 14, described beverage also comprises CO
2, CO
2Content for about 0.1g/l to about 15g/l, be preferably extremely about 10g/l of about 1g/l, be preferably extremely about 6g/l of about 4g/l especially.
16. according to each described beverage in the claim 9 to 15, described beverage also comprises N
2
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DKPA200600880 | 2006-06-30 |
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CN101484570A true CN101484570A (en) | 2009-07-15 |
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CNA2007800249525A Pending CN101484570A (en) | 2006-06-30 | 2007-07-02 | Beverage comprising insoluble gas |
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EP (1) | EP2038398A2 (en) |
CN (1) | CN101484570A (en) |
EA (1) | EA200970073A1 (en) |
WO (1) | WO2008000271A2 (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
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CN106085689A (en) * | 2015-09-28 | 2016-11-09 | 上海金苇子生物技术有限公司 | A kind of beverage and preparation method thereof |
CN106465832A (en) * | 2015-08-18 | 2017-03-01 | 光腾光电股份有限公司 | Antioxidant functional drink |
Families Citing this family (12)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2010066772A1 (en) | 2008-12-09 | 2010-06-17 | Carlsberg Breweries A/S | A system and method for providing a self cooling container |
EP2196752A1 (en) | 2008-12-09 | 2010-06-16 | Carlsberg Breweries A/S | A self cooling container |
EP2397796A1 (en) | 2010-06-15 | 2011-12-21 | Carlsberg Breweries A/S | A self cooling container and a cooling device |
WO2011157735A2 (en) | 2010-06-15 | 2011-12-22 | Carlsberg Breweries A/S | A self cooling container and a cooling device |
EA028905B1 (en) | 2011-05-26 | 2018-01-31 | Карлсберг Брюириз А/С | Beer, beer container, container assembly, beer treatment method and plant |
JP5730227B2 (en) * | 2012-03-05 | 2015-06-03 | サッポロビール株式会社 | Sparkling beverage product and method relating thereto |
EP2695560A1 (en) | 2012-08-10 | 2014-02-12 | Carlsberg Breweries A/S | A cooling device including coated reactants |
WO2014166867A1 (en) | 2013-04-08 | 2014-10-16 | Carlsberg Breweries A/S | A system for externally cooling a beverage holder and a method of externally cooling a beverage holder |
US9745187B2 (en) | 2015-05-05 | 2017-08-29 | Fizzics Group Llc | Carbonated fluid dispenser with ultrasonic foaming mechanism |
US9895667B2 (en) | 2015-05-05 | 2018-02-20 | Fizzics Group Llc | Carbonated fluid dispenser with ultrasonic foaming mechanism |
BE1024348B1 (en) * | 2016-07-01 | 2018-02-05 | Duvel Moortgat Nv | Device for pouring beer with a high carbon dioxide content |
US20190335789A1 (en) * | 2018-05-04 | 2019-11-07 | Michael Dray | Packaged beverages, and a process and device for introducing gases into packaged beverages |
Family Cites Families (6)
Publication number | Priority date | Publication date | Assignee | Title |
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GB8430014D0 (en) * | 1984-11-28 | 1985-01-09 | Bass Plc | Beer &c |
US20020197364A1 (en) * | 1997-07-10 | 2002-12-26 | Shyong Pan Christopher Chia | Producing liquid products contained in cans, bottles and other suitable containers |
EP0994809A1 (en) * | 1997-07-10 | 2000-04-26 | Amcor Packaging (Australia) Pty, Ltd | Producing liquid products contained in cans, bottles and other suitable containers |
CA2347802A1 (en) * | 1998-10-19 | 2000-04-27 | Christopher Chia Shyong Pan | Method of improving froth on beverage dispensed from a container |
EP1034703B1 (en) * | 1999-03-08 | 2003-06-18 | Societe Des Produits Nestle S.A. | Assembly containing a container and a ready-to-drink beverage |
GB0013822D0 (en) * | 2000-06-07 | 2000-07-26 | Better Brands N I Limited | A drink product |
-
2007
- 2007-07-02 CN CNA2007800249525A patent/CN101484570A/en active Pending
- 2007-07-02 EA EA200970073A patent/EA200970073A1/en unknown
- 2007-07-02 EP EP07764456A patent/EP2038398A2/en not_active Withdrawn
- 2007-07-02 WO PCT/DK2007/000326 patent/WO2008000271A2/en active Application Filing
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN106465832A (en) * | 2015-08-18 | 2017-03-01 | 光腾光电股份有限公司 | Antioxidant functional drink |
CN106085689A (en) * | 2015-09-28 | 2016-11-09 | 上海金苇子生物技术有限公司 | A kind of beverage and preparation method thereof |
Also Published As
Publication number | Publication date |
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WO2008000271A3 (en) | 2008-02-14 |
EA200970073A1 (en) | 2009-06-30 |
WO2008000271A2 (en) | 2008-01-03 |
EP2038398A2 (en) | 2009-03-25 |
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