CN1014525B - Water-based cold rolling lubricating antirust liquid - Google Patents
Water-based cold rolling lubricating antirust liquidInfo
- Publication number
- CN1014525B CN1014525B CN 88108338 CN88108338A CN1014525B CN 1014525 B CN1014525 B CN 1014525B CN 88108338 CN88108338 CN 88108338 CN 88108338 A CN88108338 A CN 88108338A CN 1014525 B CN1014525 B CN 1014525B
- Authority
- CN
- China
- Prior art keywords
- water
- rolling
- antirust liquid
- lubricating
- based cold
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 21
- 230000001050 lubricating effect Effects 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 title claims abstract description 17
- 238000005097 cold rolling Methods 0.000 title claims abstract description 14
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 claims description 15
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 7
- 239000004359 castor oil Substances 0.000 claims description 7
- 235000019438 castor oil Nutrition 0.000 claims description 7
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 7
- 239000003109 Disodium ethylene diamine tetraacetate Substances 0.000 claims description 5
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 claims description 5
- 229910021538 borax Inorganic materials 0.000 claims description 5
- 235000019301 disodium ethylene diamine tetraacetate Nutrition 0.000 claims description 5
- UQGFMSUEHSUPRD-UHFFFAOYSA-N disodium;3,7-dioxido-2,4,6,8,9-pentaoxa-1,3,5,7-tetraborabicyclo[3.3.1]nonane Chemical compound [Na+].[Na+].O1B([O-])OB2OB([O-])OB1O2 UQGFMSUEHSUPRD-UHFFFAOYSA-N 0.000 claims description 5
- 229910000029 sodium carbonate Inorganic materials 0.000 claims description 5
- 235000017550 sodium carbonate Nutrition 0.000 claims description 5
- 239000004328 sodium tetraborate Substances 0.000 claims description 5
- 235000010339 sodium tetraborate Nutrition 0.000 claims description 5
- 239000000178 monomer Substances 0.000 claims description 4
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000000314 lubricant Substances 0.000 claims description 2
- 239000000203 mixture Substances 0.000 claims description 2
- 238000002360 preparation method Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract description 5
- 229910000831 Steel Inorganic materials 0.000 abstract description 4
- 239000003921 oil Substances 0.000 abstract description 4
- 239000010731 rolling oil Substances 0.000 abstract description 4
- 238000005096 rolling process Methods 0.000 abstract description 4
- 239000010959 steel Substances 0.000 abstract description 4
- 238000004519 manufacturing process Methods 0.000 abstract 2
- 238000000034 method Methods 0.000 abstract 2
- 230000002035 prolonged effect Effects 0.000 abstract 2
- 238000006243 chemical reaction Methods 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 230000006866 deterioration Effects 0.000 abstract 1
- 238000005553 drilling Methods 0.000 abstract 1
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 230000008901 benefit Effects 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 3
- 230000000694 effects Effects 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
Landscapes
- Lubricants (AREA)
Abstract
The water-based cold rolling lubricating antirust liquid is mainly applied to the steel rolling industry, and also can be applied to drilling machine tools, grinding machines and other industries with high requirements on cooling and lubricating properties. The method can be changed chemically at normal pressure and high temperature, the process flow is simple, feasible and easy to operate, all chemical reactions can be completed within 8-10 hours, and the production supporting equipment is simple and easy to purchase. The technical key of the water-based cold-rolling lubricating antirust liquid is that under the condition of meeting the same technical indexes, the service cycle is prolonged, the capital is saved, the yield of a finished product is increased, the oil is replaced by water, the defects of oil mildew and odor and deterioration are overcome, the service base is short, the manufacturing cost is high, the working environment is polluted and the like, one ton of water-based cold-rolling lubricating antirust liquid can replace 10-15 tons of rolling oil, the capital is saved by about 2 ten thousand yuan, and the water-based cold-rolling lubricating antirust liquid has the characteristics of good cooling performance, lubricating performance and antirust performance, and the service life is prolonged by 4-.
Description
Water based lubricating and antirust liquid for cold-rolling
The invention belongs to the improvement of steel rolling cooling and lubricating rust protection liquid.
Before the present invention made, used cooling and lubricating rust protection liquid in the steel rolling industry adopted emulsion or ROLLING OIL more.Emulsion because of life cycle weak point, unstable properties, pollution is arranged.ROLLING OIL is cost height, consumes energy and pollution is also arranged again, thereby bring very big inconvenience for the steel rolling industry, purpose of the present invention just is to make a kind of life cycle length, stable performance, pollution-free and cost is low, and effect is better than the cooling and lubricating rust protection liquid of said two products.
Main points of the present invention are, hydrated barta and castor oil acid are reacted under 110～130 ℃ of conditions and are formed the rust-preventive agent monomer, potassium hydroxide and castor oil acid are reacted under 80～95 ℃ of conditions and are formed the lubricant monomer, then with sodium tetraborate, disodium ethylene diamine tetraacetate, soda ash, water drop in the reactor and react under 80～95 ℃ of conditions, make water based lubricating and antirust liquid for cold-rolling.Wherein each composition charge ratio (parts by weight) is a sodium hydroxide 3～5, potassium hydroxide 30～35, sodium tetraborate 60～65, castor oil acid 200～210, soda ash 13～18, disodium ethylene diamine tetraacetate 0.3～0.7, water 693.7～666.3, thus water based lubricating and antirust liquid for cold-rolling made.
The advantage of this product is with water for oil, save energy, 1 ton of water based lubricating and antirust liquid for cold-rolling can replace 10～15 tons of oil base ROLLING OIL, life cycle is 4～8 times of emulsions, pollution-free, nontoxic, produce that support equipment is simple, easy to operate, appropriation of labour power is few, easily-learned easily mastered, product cost be low, has good social benefit and economic benefit.
Claims (2)
1, a kind of water based lubricating and antirust liquid for cold-rolling is characterized in that its proportioning (parts by weight) is as follows:
Hydrated barta 3～5
Potassium hydroxide 30～35
Sodium tetraborate 60～65
Soda ash 13～18
Disodium ethylene diamine tetraacetate 0.3～0.7
Castor oil acid 200～210
Water 693.7～666.3
2, a kind of preparation method of water based lubricating and antirust liquid for cold-rolling, base is characterised in that hydrated barta and castor oil acid are reacted and forms the rust-preventive agent monomer under 110～130 ℃ of conditions, potassium hydroxide and castor oil acid are reacted under 80～95 ℃ of conditions and are formed the lubricant monomer, then with sodium tetraborate, disodium ethylene diamine tetraacetate, soda ash water drops in the reactor and reacts under 80～90 ℃ of conditions, makes water based lubricating and antirust liquid for cold-rolling.Wherein each composition charge ratio (parts by weight) is hydrated barta 3～5, potassium hydroxide 30～35, sodium tetraborate 60～65, castor oil acid 200～210, soda ash 13～18, disodium ethylene diamine tetraacetate 0.3～0.7, water 693.7～666.3, thus water based lubricating and antirust liquid for cold-rolling made.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88108338 CN1014525B (en) | 1988-12-08 | 1988-12-08 | Water-based cold rolling lubricating antirust liquid |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 88108338 CN1014525B (en) | 1988-12-08 | 1988-12-08 | Water-based cold rolling lubricating antirust liquid |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1042375A CN1042375A (en) | 1990-05-23 |
| CN1014525B true CN1014525B (en) | 1991-10-30 |
Family
ID=4835040
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 88108338 Expired CN1014525B (en) | 1988-12-08 | 1988-12-08 | Water-based cold rolling lubricating antirust liquid |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1014525B (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5486316A (en) * | 1987-06-01 | 1996-01-23 | Henkel Corporation | Aqueous lubricant and surface conditioner for formed metal surfaces |
| TW296990B (en) * | 1994-03-25 | 1997-02-01 | Nissin Seiko Kk | |
| CN1036527C (en) * | 1994-08-26 | 1997-11-26 | 巢剑崙 | Concentrated transmission liquid for coal mine hydraulic supporting |
| CN103642288B (en) * | 2013-11-28 | 2016-03-30 | 阜阳安固锅炉压力容器制造有限公司 | A kind of Environment-friendlywater-soluble water-soluble rust protection liquid and preparation method thereof |
-
1988
- 1988-12-08 CN CN 88108338 patent/CN1014525B/en not_active Expired
Also Published As
| Publication number | Publication date |
|---|---|
| CN1042375A (en) | 1990-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C13 | Decision | ||
| GR02 | Examined patent application | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |