CN101442977B - Hair conditioning composition comprising polysaccharide polymer and aminosilicone - Google Patents
Hair conditioning composition comprising polysaccharide polymer and aminosilicone Download PDFInfo
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- CN101442977B CN101442977B CN200780000603.XA CN200780000603A CN101442977B CN 101442977 B CN101442977 B CN 101442977B CN 200780000603 A CN200780000603 A CN 200780000603A CN 101442977 B CN101442977 B CN 101442977B
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- 239000000203 mixture Substances 0.000 title claims abstract description 109
- 229920000642 polymer Polymers 0.000 title claims abstract description 36
- 229920013822 aminosilicone Polymers 0.000 title claims abstract description 27
- 150000004676 glycans Chemical class 0.000 title claims abstract description 24
- 229920001282 polysaccharide Polymers 0.000 title claims abstract description 24
- 239000005017 polysaccharide Substances 0.000 title claims abstract description 24
- 230000003750 conditioning effect Effects 0.000 title abstract description 22
- 150000001875 compounds Chemical class 0.000 claims abstract description 37
- 239000003093 cationic surfactant Substances 0.000 claims abstract description 33
- -1 methylol, ethoxy, hydroxypropyl Chemical group 0.000 claims description 56
- 230000003741 hair volume Effects 0.000 claims description 21
- 229920002907 Guar gum Polymers 0.000 claims description 17
- 239000000665 guar gum Substances 0.000 claims description 17
- 235000010417 guar gum Nutrition 0.000 claims description 17
- 229960002154 guar gum Drugs 0.000 claims description 17
- 229940116364 hard fat Drugs 0.000 claims description 17
- 239000008365 aqueous carrier Substances 0.000 claims description 8
- 239000001257 hydrogen Substances 0.000 claims description 8
- 229910052739 hydrogen Inorganic materials 0.000 claims description 8
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 8
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 claims description 8
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 6
- 229920006318 anionic polymer Polymers 0.000 claims description 5
- 239000003945 anionic surfactant Substances 0.000 claims description 5
- 238000002844 melting Methods 0.000 abstract description 8
- 125000002091 cationic group Chemical group 0.000 abstract description 7
- 230000008018 melting Effects 0.000 abstract description 7
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- 125000003696 stearoyl group Chemical group O=C([*])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 4
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- 230000003301 hydrolyzing effect Effects 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 229920013818 hydroxypropyl guar gum Polymers 0.000 description 1
- ZCTXEAQXZGPWFG-UHFFFAOYSA-N imidurea Chemical compound O=C1NC(=O)N(CO)C1NC(=O)NCNC(=O)NC1C(=O)NC(=O)N1CO ZCTXEAQXZGPWFG-UHFFFAOYSA-N 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000001630 malic acid Substances 0.000 description 1
- 235000011090 malic acid Nutrition 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000011929 mousse Nutrition 0.000 description 1
- AFFLGGQVNFXPEV-UHFFFAOYSA-N n-decene Natural products CCCCCCCCC=C AFFLGGQVNFXPEV-UHFFFAOYSA-N 0.000 description 1
- 238000006386 neutralization reaction Methods 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 239000000346 nonvolatile oil Substances 0.000 description 1
- 235000015097 nutrients Nutrition 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 229940049964 oleate Drugs 0.000 description 1
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N papa-hydroxy-benzoic acid Natural products OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- WVDDGKGOMKODPV-ZQBYOMGUSA-N phenyl(114C)methanol Chemical compound O[14CH2]C1=CC=CC=C1 WVDDGKGOMKODPV-ZQBYOMGUSA-N 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 239000000419 plant extract Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 235000011056 potassium acetate Nutrition 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 150000003139 primary aliphatic amines Chemical class 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 1
- FGVVTMRZYROCTH-UHFFFAOYSA-N pyridine-2-thiol N-oxide Chemical compound [O-][N+]1=CC=CC=C1S FGVVTMRZYROCTH-UHFFFAOYSA-N 0.000 description 1
- 229960002026 pyrithione Drugs 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229960004889 salicylic acid Drugs 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 1
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/89—Polysiloxanes
- A61K8/896—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate
- A61K8/898—Polysiloxanes containing atoms other than silicon, carbon, oxygen and hydrogen, e.g. dimethicone copolyol phosphate containing nitrogen, e.g. amodimethicone, trimethyl silyl amodimethicone or dimethicone propyl PG-betaine
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
- A61K8/342—Alcohols having more than seven atoms in an unbroken chain
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
- A61K8/41—Amines
- A61K8/416—Quaternary ammonium compounds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/73—Polysaccharides
- A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/12—Preparations containing hair conditioners
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5422—Polymers characterized by specific structures/properties characterized by the charge nonionic
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
- A61K2800/54—Polymers characterized by specific structures/properties
- A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
- A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic
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- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Dermatology (AREA)
- Emergency Medicine (AREA)
- Cosmetics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Disclosed is a hair conditioning composition comprising: a cationic or nonionic polysaccharide polymer; an aminosilicone; a cationic surfactant; and a high melting point fatty compound. The composition of the present invention can provide hair volume-up benefit and ease-to-rinse feel, while providing improved conditioning benefits. The present invention also relates to a use of the above composition for hair volume-up.
Description
Invention field
The present invention relates to a kind of hair care composition, described compositions comprises: cation or nonionic polysaccharide polymer; Amino silicone; Cationic surfactant; And hard fat compounds of group.Compositions of the present invention can provide hair volume to increase beneficial effect and be easy to and rinse sense, and the conditioning beneficial effect of improvement is provided simultaneously.
Background of invention
Develop the whole bag of tricks and come conditioning hair.A kind of common method of nursing one's health beneficial effect that provides is to use conditioner, as cationic surfactant and polymer, hard fat compounds of group, low melting point oil, silicone compounds and their mixture.These conditioners of known great majority provide various conditioning beneficial effects.
The hair care composition that comprises above-mentioned conditioner can provide the conditioning beneficial effect, send out flexibility and wetness sensation as doing, yet this also can force down hair.The hair that forces down presents the outward appearance that the hair overall volume reduces.For the consumer that the expectation hair volume increases, as have the consumer of very thin hair, the effect that hair forces down is worthless.Term used herein " hair volume increase " is not equal to the hair that disperses.The hair that disperses static content due to increases, and shows generally the only volume increase of very a small amount of hair, and is worthless.On the other hand, hair volume increase used herein relates to the increase of hair overall volume.Consumer expectation with very thin hair realizes that hair volume increases, and also can control simultaneously worthless hair and disperse.Therefore, need to provide hair volume to increase beneficial effect and the hair care composition of nursing one's health beneficial effect can be provided simultaneously.
Also need to provide the hair care composition that is easy to rinse sense and the beneficial effect of maintenance conditioning simultaneously of improvement, especially when forming the gel-type vehicle that is consisted of by cationic surfactant and hard fat compounds of group.The hair care composition that comprises gel-type vehicle can be during rinsing hair, or even provide smooth feeling after rinsing hair.For example, be easy to rinse sense for beginning to rinse the smooth feeling that weakens fast after hair and/or the clean feel of increase.The clean feel of the above-mentioned smooth feeling that weakens and/or increase is to make consumer stop rinsing the signal of hair care composition.The hair that tends to select the consumer of above-mentioned signal to be processed by hair care composition with large water gaging continual rinsing is until they experience described signal.Yet above-mentioned flushing behavior can't provide conditioner more to deposit on hair, thereby can't provide more conditioning beneficial effect to doing to send out.Therefore, still need to be after beginning to rinse hair more Quick for above-mentioned signal, and can keep the hair care composition that the capacity conditioner deposited and/or can keep nursing one's health beneficial effect simultaneously on hair.
Japanese patent laid-open 2004-143093 discloses a kind of hair care composition, and described compositions comprises: the condensation polyhydric alcohol that has 4Pas to 100Pas viscosity in the time of 25 ℃; Have 30 ℃ to the oiliness improver of 55 ℃ of fusing points; Has amino siloxanes or derivatives thereof; Has the accrete non-ionic surface active agent of polyoxyalkylene; And saturated aliphatic alcohol, it is said that described compositions can provide sufficient moistening and soft effect to damaged hair, and fabulous sensation can be provided simultaneously, as the gluing sense that reduces, the naturally not thick and heavy sense of reduction, better finger combing sense and flexibility.Japanese patent laid-open 2004-143093 also discloses a kind of hair care composition in embodiment 21, described compositions comprises: the hydroxypropyl melon ear; 16-18 mixed alcohols; The stearyl trimethyl ammonium chloride; The amino modified siloxanes that is provided by Dow Coming Toray with trade name SM8704C.
Yet find, this still is not easy to obtain to provide hair volume to increase beneficial effect and is easy to rinse sense also can provide simultaneously the hair care composition of the conditioning beneficial effect of improvement.
Described based on preamble, still needing to provide hair volume to increase beneficial effect and being easy to rinse sense also can provide the hair care composition of the conditioning beneficial effect of improvement simultaneously.
Can provide all advantages of the present invention and beneficial effect without any prior art.
Summary of the invention
The present invention relates to a kind of hair care composition, said composition comprises by weight:
(a) approximately 0.05% to approximately 10% cation or nonionic polysaccharide polymer, described polysaccharide polymer has approximately 1,000,000 or higher molecular weight, wherein said polysaccharide polymer is selected from cellulose, guar gum, Cortex cinnamomi japonici (Ramulus Cinnamomi) glue, starch and their derivant;
(b) approximately 0.1% to about 10% amino silicone, described amino silicone has following chemical formula structure:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl; A is 1 to 3 integer; N is 1 to 2,000 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L, wherein q is 2 to 8 integer, and L is selected from following group :-N (R
2) CH
2-CH
2-N (R
2)
2-N (R
2)
2-N (R
2)
3A
--N (R
2) CH
2-CH
2-NR
2H
2A
-Wherein R2 is hydrogen, phenyl, benzyl or saturated hydrocarbyl; A
-Be the halogen ion;
(c) by weight of the composition approximately 0.1% to about 10% cationic surfactant;
(d) by weight of the composition approximately 0.1% to about 20% hard fat compounds of group; With
(e) aqueous carrier.
Care composition of the present invention can provide hair volume to increase beneficial effect and be easy to and rinse sense, and the conditioning beneficial effect of improvement can be provided simultaneously.
The invention still further relates to the hair care composition for increasing hair volume, wherein said hair care composition comprises by weight:
(a) approximately 0.05% to approximately 10% cation or nonionic polysaccharide polymer, described polysaccharide polymer has approximately 1,000,000 or higher molecular weight, wherein said polysaccharide polymer is selected from cellulose, guar gum, Cortex cinnamomi japonici (Ramulus Cinnamomi) glue, starch and their derivant;
(b) by weight of the composition approximately 0.1% to about 10% cationic surfactant;
(c) by weight of the composition approximately 0.1% to about 20% hard fat compounds of group; With
(d) aqueous carrier;
And wherein said hair care composition preferably also comprises: approximately 0.1% to about 10% amino silicone, and described amino silicone has following chemical formula structure:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl; A is 1 to 3 integer; N is 1 to 2,000 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L, wherein q is 2 to 8 integer, and L is selected from following group :-N (R
2) CH
2-CH
2-N (R
2)
2-N (R
2)
2-N (R
2)
3A
--N (R
2) CH
2-CH
2-NR
2H
2A
-R wherein
2Be hydrogen, phenyl, benzyl or saturated alkyl; A
-Be the halogen ion.
By reading following description and appending claims, can understand better these and other feature, aspect and advantage of the present invention.
Detailed Description Of The Invention
Although this description by particularly point out and clearly claimed claims of the present invention draw a conclusion, it is believed that by following explanation and will understand better the present invention.
In this article, " comprise " and refer to add other step of not affecting final result and other composition.This term comprise term " by ... form " and " basically by ... composition ".
Except as otherwise noted, all percentage ratio, umber and ratio are all in the gross weight of the present composition.All weight that relate to listed composition are all in its activity substance content, and therefore do not comprise carrier or the by-product that may be included in the commercially available material.
Term used herein " mixture " will comprise the simple combination of material and make up issuable any compound by them.
Compositions
It is believed that, by having approximately 1,000,000 or more the polysaccharide polymer of high molecular and the amino silicone with specific chemical formula use together with other required component, care composition of the present invention can provide hair volume to increase beneficial effect and be easy to and rinse sense, and the conditioning beneficial effect of improvement is provided simultaneously.
Preferably, when the gel-type vehicle that comprises cationic surfactant and/or formed by cationic surfactant and hard fat compounds of group, for avoiding with cationic surfactant, worthless reciprocal action occuring and/or for stable gel substrate, compositions of the present invention is substantially free of anion surfactant and anionic polymer.In the present invention, " being substantially free of anion surfactant and anionic polymer " refers to that described compositions comprises 1% or still less, preferred 0.5% or still less altogether, more preferably totally 0% anion surfactant and anionic polymer.
Polysaccharide polymer
Compositions of the present invention comprises polysaccharide polymer.According to rheological behavior, the content of described polymer in described compositions is approximately 0.05% to approximately 10% by weight, is preferably approximately 0.08% to approximately 5%, more preferably approximately 0.1% to approximately 1%.
For avoiding with cationic surfactant, worthless reciprocal action occuring, the polymer that can be used for this paper is cation or non-ionic.Consider to be easy to rinse sense, the polymer that can be used for this paper is preferably non-ionic.
Increase beneficial effect according to rheological behavior and hair volume, the polymer that can be used for this paper is that molecular weight is approximately 1,000,000 or higher, preferred 1,500,000 or higher, more preferably 2,000,000 or higher those.According to water solubility, described molecular weight mostly is approximately 5,000,000 usually most, preferably to approximately 4,000,000.
The polymer that can be used for this paper is water miscible.In the present invention, " water-soluble polymer " refers to that described polymer has the water greater than 0.1g/100g in the time of 25 ℃, preferred 0.3g/100g water, the more preferably dissolubility of 0.5g/100g water.
The polymer that can be used for this paper is to be selected from those of cellulose, guar gum, Cortex cinnamomi japonici (Ramulus Cinnamomi) glue (cassia gum), starch and their derivants.Above-mentioned polymer comprises, for example, cellulose and derivant thereof, as the cellulose ether of cellulose ether (comprising hydroxyethyl-cellulose and hydroxypropyl cellulose), hydrophobically modified (as the cetyl hydroxyethyl-cellulose, for example, it is provided by Hercules with trade name Polysurf 67), the cationic cellulose of quaternized cellulose and hydrophobically modified; The guar gum polymer comprises cationic guar gum polymer and nonionic guar gum polymer, as guar gum 2-hydroxypropyl ether (for example, it is provided by Rhodia with trade name Jaguar HP-105); And Cortex cinnamomi japonici (Ramulus Cinnamomi) glue and cation Cortex cinnamomi japonici (Ramulus Cinnamomi) glue.
The nonionic guar gum derivant
In described compositions, increase beneficial effect according to hair volume, above preferably using the nonionic guar gum derivant in multiple polymers.The said derivative that can be used for this paper is with C1-C6 hydroxyalkyl or alkyl-modified and have a guar gum of 8 to 30 fat of carbon atom chains (as alkyl or the alkenyl of straight or branched).It is believed that with other polymer such as cellulosic those main chains and compare, the guar gum main chain that volume is larger can provide thicker polymeric layer on hair, and can provide hair volume to increase beneficial effect.Also it is believed that the above-mentioned substituent group that is connected on the guar gum main chain by having, described guar gum derivatives can provide thicker polymeric layer on hair, and provides hair volume to increase beneficial effect.In superincumbent substituent group, preferred C1-C6 hydroxyalkyl more preferably selects those that free following groups forms: methylol, ethoxy, hydroxypropyl and hydroxyl butyl, and more preferably hydroxypropyl.It is believed that with cationic substituent and compare, the nonionic substituent group can be sent better being easy to and be rinsed sense.The hydroxyalkylation degree corresponding with the alkylene oxide molecular number that is consumed by contained free hydroxyl functions number on guar gum is preferably in 0.2 to 1.2 scope, and more preferably in 0.4 to 1.2 scope.The commercial examples of highly preferred nonionic guar gum derivant comprises, for example, take trade name Jaguar HP-105 available from the molecular weight of Rhodia as approximately 2,500,000, the hydroxyalkylation degree is about 0.6 hydroxypropyl guar gum.
Amino silicone
Compositions of the present invention comprises amino silicone.The amino silicone that can be used for this paper is to meet those of general formula (I) structure:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl, preferable methyl; A is 1 to 3 integer, preferred 1; N is 1 to approximately 2,000, and is preferred approximately 100 to 2,000, more preferably 300 to 1,800 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L, wherein q is 2 to 8 integer, and L is selected from following group :-N (R
2) CH
2-CH
2-N (R
2)
2-N (R
2)
2-N (R
2)
3A
--N (R
2) CH
2-CH
2-NR
2H
2A
-R wherein
2Hydrogen, phenyl, benzyl or saturated alkyl, preferred approximately C
1To about C
20Alkyl; A
-Be the halogen ion.L is preferably-N (CH
3)
2Or-NH
2
It is believed that when being used for the present composition, the amino silicone with formula hereinabove structure is compared with other siloxanes can increase at hair volume, be easy to rinse between sense and conditioning beneficial effect suitable balance is provided.Above-mentioned other siloxanes is for example there is no amino substituent siloxanes and grafting amino silicone.Consumption with amino silicone of formula hereinabove structure is approximately 0.1% to approximately 10% by weight of the composition, is preferably approximately 0.1% to approximately 7%, more preferably approximately 0.2% to approximately 5%.
A kind of highly preferred amino silicone is to meet those of chemical formula (I) structure, and a=1 wherein, q=3, G=methyl, n are preferably approximately 1400 to approximately 1700, more preferably approximately 1600; And L is-N (CH
3)
2Or-NH
2, more preferably-NH
2Another kind of highly preferred amino silicone is to meet those of chemical formula (I) structure, and a=1 wherein, q=3, G=methyl, n are preferably approximately 400 to approximately 800, more preferably approximately 500 to approximately 600; And L is-N (CH
3)
2Or-NH
2, more preferably-NH
2Above-mentioned highly preferred amino silicone can be called as the terminal amino group siloxanes, because the one or both ends of described siloxane chain are by the nitrogen-containing group end-blocking.
When being incorporated into above-mentioned amino silicone in described compositions, described amino silicone can with have more low viscous solvent.Above-mentioned solvent for example comprises polarity or nonpolar, volatility or nonvolatile oil.Above-mentioned oil comprises for example silicone oil, hydrocarbon and ester.In above-mentioned multi-solvents, be preferably selected from those that are formed by following material: nonpolar volatile hydrocarbon, volatile cyclic silicones, non-volatile linear siloxanes and their mixture.The non-volatile linear siloxanes that can be used for this paper is that viscosity is approximately 1 to about 20,000 centistokes in the time of 25 ℃, and is preferred approximately 20 to those of about 10,000 centistokes.In preferred solvent, highly preferred nonpolar volatile hydrocarbon, especially nonpolar volatility isoparaffin, this is can reduce the viscosity of amino silicone due to it, and the hair care beneficial effect of improvement is provided, and for example reduces friction on dried sending out.It is preferred approximately 1 that said mixture has, and 000mPas is to approximately 100,000mPas, and more preferably from about 5,000mPas is to approximately 50, the viscosity of 000mPas.
Cationic surfactant system
Compositions of the present invention comprises cationic surfactant system.Described cationic surfactant system can be the mixture of a kind of cationic surfactant or two or more cationic surfactants.According to the balance that is easy to rinse between sense, rheological behavior and moistening conditioning beneficial effect, the content of described cationic surfactant system in described compositions is approximately 0.1% to approximately 10% by weight, be preferably approximately 0.5% to approximately 8%, more preferably approximately 1% to approximately 5%, also more preferably approximately 1.4% to approximately 4%.
The multiple cationic surfactant that comprises monoalkyl chain and dialkyl group chain cationic surfactant can be used in compositions of the present invention.Wherein, for suitable gel-type vehicle and moistening conditioning beneficial effect, preferred monoalkyl chain cationic surfactant are provided.For the moistening conditioning beneficial effect of balance is provided, described monoalkyl cationic surfactant is to have those of a long alkyl chain, and described long alkyl chain has 12 to 22 carbon atoms, preferred 16 to 22 carbon atoms, more preferably C18-22 alkyl.Other group that is connected with nitrogen is independently selected to have 1 to the alkyl of about 4 carbon atoms or has at most approximately alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryls of 4 carbon atoms.Above-mentioned monoalkyl cationic surfactant comprises for example monoalkyl quaternary ammonium salt and monoalkylamine.The monoalkyl quaternary ammonium salt comprises those that for example have non-functionalised alkyl long-chain.Monoalkylamine comprises for example monoalkyl amidoamines and salt thereof.
The long-chain monoalkyl quaternary ammonium salt that can be used for this paper is to have those of chemical formula (II) structure:
R wherein
75, R
76, R
77And R
78In one be selected from the alkyl with 12 to 30 carbon atoms or have at most approximately aryl, alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryls of 30 carbon atoms; R
75, R
76, R
77And R
78In all the other groups be independently selected from and have 1 to the alkyl of about 4 carbon atoms or have at most approximately alkoxyl, polyoxyalkylenes, alkyl amido, hydroxyalkyl, aryl or the alkylaryls of 4 carbon atoms; And X
-Be into salt anionic, as be selected from halogen (as chloride ion, bromide ion), acetate, citrate, lactate, glycolate, phosphate radical, nitrate anion, sulfonate radical, sulfate radical, alkyl sulfate and alkyl sulfonic acid foundation those.Except carbon atom and hydrogen atom, alkyl group also can comprise ether, ester and/or ester bond and other group such as amino.Than the alkyl of long-chain, as have approximately 12 carbon atoms or more those, can be saturated or unsaturated.Preferably, R
75, R
76, R
77And R
78In one be selected from and have 12 to 30 carbon atoms, more preferably 16 to 22 carbon atoms, also more preferably 18 to 22 carbon atoms, the even more preferably alkyl of 22 carbon atoms; R
75, R
76, R
77And R
78In all the other groups be independently selected from CH
3, C
2H
5, C
2H
4OH and their mixture; And the group that X selects free following groups to form: Cl, Br, CH
3OSO
3, C
2H
5OSO
3, and their mixture.
The example of preferred long-chain monoalkyl quaternary cationics comprises: the docosyl leptodactyline; The stearyl leptodactyline; The cetyl leptodactyline; With the hydrogenated tallow alkyl leptodactyline.Wherein, highly preferred docosyl leptodactyline and stearyl leptodactyline.
Monoalkylamine is the applicable cationic surfactant of doing also.Primary aliphatic amine, secondary fatty amine and uncle's fatty amine are available.Especially available is uncle's amidoamines, and this uncle's amidoamines has approximately 12 to the about alkyl of 22 carbon atoms.exemplary uncle's amidoamines comprises: the amino diemethylamine of stearoyl, the amino propyl group diethylamide of stearoyl, the amino ethyl diethylamide of stearoyl, the amino ethyl dimethyl amine of stearoyl, palmityl aminopropyl dimethyl amine, palmityl aminopropyl diethylamide, palmityl amino-ethyl diethylamide, palmityl amino-ethyl dimethyl amine, docosane acylamino-propyl-dimethyl amine, docosane acylamino-propyl group diethylamide, docosane acylamino-ethyl diethylamide, docosane acylamino-ethyl dimethyl amine, eicosane acylamino-propyl-dimethyl amine, eicosane acylamino-propyl group diethylamide, eicosane acylamino-ethyl diethylamide, eicosane acylamino-ethyl dimethyl amine, diethylamino ethyl stearmide.In the present invention, available amine is disclosed in the people's such as Nachtigal United States Patent (USP) 4,275,055.These amine also can be united use with acid, as λ-glutamic acid, lactic acid, hydrochloric acid, malic acid, succinic acid, acetic acid, fumaric acid, tartaric acid, citric acid, λ-glutamic acid hydrochloride, maleic acid and their mixture; More preferably λ-glutamic acid, lactic acid, citric acid.Preferably with the neutralization of any one part in these acid, wherein amine is approximately 1: 0.3 to approximately 1: 2 with the mol ratio of acid to amine herein, more preferably approximately 1: 0.4 to approximately 1: 1.
Although preferred monoalkyl chain cationic surfactant also can use separately other cationic surfactant such as dialkyl group chain cationic surfactant, or be used in combination with monoalkyl chain cationic surfactant.Above-mentioned dialkyl group chain cationic surfactant comprises for example dialkyl group (14-18) alkyl dimethyl ammonium chloride, two tallow alkyl alkyl dimethyl ammonium chlorides, dihydro tallow alkyl alkyl dimethyl ammonium chloride, VARISOFT TA100 and Varisoft 432PPG.
The hard fat compound
Can be used for hard fat compounds of group of the present invention and have 25 ℃ or higher fusing point, and the group of the freely following material composition of choosing: aliphatic alcohol, fatty acid, fatty alcohol derivative, derivative of fatty acid and their mixture.It should be appreciated by those skilled in the art that the compound that is disclosed on this description in this part belongs to more than one classification sometimes, for example some fatty alcohol derivative also can be classified as derivative of fatty acid.But the class of appointment is not intended to specific compound is limited, but for the ease of classification and name.In addition, it will be understood by those skilled in the art that according to the number of two keys and the length and location of position and side chain to have required certain some compound of carbon number purpose and may have fusing point lower than 25 ℃.This low-melting compound will be not included in this part.The limiting examples of high melting compound is found in " International Cosmetic IngredientDictionary ", the 5th edition, 1993; " CTFA Cosmetic Ingredient Handbook ", second edition, 1992.
In multiple hard fat compounds of group, preferred fat alcohol is used for the present composition.The aliphatic alcohol that can be used for this paper is to have approximately 14 to about 30 carbon atoms, and is preferred approximately 16 to those of about 22 carbon atoms.These aliphatic alcohol are saturated, and can be straight chain alcohol or branched-chain alcoho.Preferably aliphatic alcohol comprises, for example, and spermol, stearyl alcohol, docosanol and their mixture.
Be preferably the hard fat compounds of group of highly purified single compound.Highly be preferably the freely single compound of the pure fat alcohol of the group of pure spermol, stearyl alcohol and docosanol composition of choosing." pure " herein refers to that the purity of compound is at least about 90%, is preferably at least about 95%.When the present composition rinsed in consumer, these high-purity single compounds provided good eccysis from hair.
For the conditioning beneficial effect of improvement is provided, as the wetness sensation on smooth feeling, flexibility and dried sending out during using to wet, the content of described hard fat compounds of group in described compositions is approximately 0.1% to approximately 20% by weight of the composition, be preferably approximately 1% to approximately 15%, more preferably approximately 1.5% to approximately 8%.
Gel-type vehicle
Compositions of the present invention comprises gel-type vehicle.Described gel-type vehicle comprises cationic surfactant, hard fat compounds of group and aqueous carrier.
Described gel-type vehicle is suitable for providing multiple conditioning beneficial effect, as providing smooth feeling during being administered to wet sending out, and provides flexibility and moist feeling doing to send out.For above-mentioned gel-type vehicle is provided, the cationic surfactant and the hard fat compounds of group that comprise certain content, so that the weight rate of cationic surfactant and hard fat compounds of group is at preferred approximately 1: 1 to approximately 1: 10, more preferably from about in the scope of 1: 1 to approximately 1: 6.
Aqueous carrier
Care composition of the present invention comprises aqueous carrier.According to selecting content and the kind of described carrier with the compatibility of other component and required other characteristic of product.
Can be used for the aqueous solution that carrier of the present invention comprises water and the pure and mild polyhydric alcohol of low alkyl group.Being applicable to lower alkyl alcohol of the present invention is the monohydric alcohol with 1 to 6 carbon atom, more preferably ethanol and isopropyl alcohol.Can be used for polyhydric alcohol of the present invention and comprise propylene glycol, hexanediol, glycerol and propylene glycol.
Preferably, this aqueous carrier is water basically.The preferred deionized water that uses.The characteristic required according to product also can be used the water of the natural origin that comprises mineral cation.Compositions of the present invention contains approximately 20% to approximately 95% usually, and is preferred approximately 30% to approximately 99%, and more preferably from about 80% to about 95% water.
Annexing ingredient
Compositions of the present invention can comprise other annexing ingredient, described annexing ingredient can the characteristic required according to end product be selected by those skilled in the art, and it is suitable for making said composition attractive in appearance or aestheticly more can accept, and perhaps provides additional use beneficial effect for them.The independent consumption of above-mentioned other annexing ingredient is generally approximately 0.001% to approximately 10% by weight of the composition, is preferably at most approximately 5%.
Various other annexing ingredients can be formulated in compositions of the present invention.These components comprise: other conditioner, as with trade name Peptein 2000 available from the hydrolytic collagen of Hormel, with trade name Emix-d available from the vitamin E of Eisai, available from the pantothenylol of Roche, DL-Pantyl Ethyl Ether, hydrolysis of keratin, protein, plant extract and nutrient substance available from Roche; Antiseptic is as benzylalcohol, methyl parahydroxybenzoate, propyl p-hydroxybenzoate and imidazolidinyl urea; PH adjusting agent is as citric acid, sodium citrate, succinic acid, phosphoric acid, sodium hydroxide, sodium carbonate; Salt is generally for example potassium acetate and sodium chloride; Stain is as any FD﹠amp; C or D﹠amp; The C dyestuff; Spice; And sequestering agent, as disodiumedetate; Ultraviolet and infrared shielding and absorbent are as ethylhexyl salicylate; And the dandruff agent, as OMADINE and salicylic acid.
Additional silicone compounds
Except above lower those that describe of title " amino silicone ", compositions of the present invention also can comprise additional silicone compounds.The silicone compounds content that this paper adds is preferably approximately 0.1% to approximately 10% by weight of the composition, and more preferably approximately 0.1% to approximately 5%.
As independent compound, as the blend of at least two kinds of silicone compounds or mixture or as blend or the mixture of at least a silicone compounds and at least a solvent, the silicone compounds that can be used for this paper has preferred approximately 1 under 25 ℃, 000 to approximately 2, the sticking degree of accounting for of 000,000mPas.
Described on July 20th, 1970 method of testing CTM0004 of Dow Corning company, can measure viscosity by using glass capillary tube viscometer.Suitable organosilicon liquid comprises poly-alkylsiloxane, poly-aryl siloxanes, polyoxyethylene alkyl aryl radical siloxane, polyether siloxane copolymer, amino siloxanes, quaternized siloxanes and their mixture that replaces.Also can use other non-volatile siloxane compound with conditioning characteristic.
For example, above-mentioned poly-alkylsiloxane can be buied with the mixture with more low viscous silicone compounds.The said mixture that can be used for this paper for example comprises that the viscosity available from GE Toshiba is 18,000, the polydimethylsiloxane of 000mPas and viscosity are the blend of the polydimethylsiloxane of 200mPas, and be 18 available from the viscosity of GE Toshiba, the polydimethylsiloxane of 000,000mPas and the blend of cyclopentasiloxane.
Low melting point oil
Can be used for low melting point oil of the present invention and be fusing point less than those of 25 ℃.Can be used for the group that the freely following material of low melting point grease separation of the present invention forms: have 10 to the about hydrocarbon of 40 carbon atoms; Have approximately 10 to approximately unsaturated fatty alcohol such as the oleyl alcohol of 30 carbon atoms; Have approximately 10 to the about unsaturated fatty acid of 30 carbon atoms; Derivative of fatty acid; Fatty alcohol derivative; Ester oil such as pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil and glyceride oil; Poly ﹠ Alpha ,-olefin oil; And their mixture.The group that the freely following material of the preferred low melting point grease separation of the present invention forms: ester oil such as pentaerythritol ester oil, trihydroxy methyl ester oil, citric acid ester oil and glyceride oil; Poly ﹠ Alpha ,-olefin oil; And their mixture.
The pentaerythritol ester oil that the present invention is particularly useful and trihydroxy methyl ester oil comprise pentaerythritol tetraoctyl stearate, tetramethylolmethane four oleates, trimethylolpropane tris isostearate, trimethylolpropane tris oleate and their mixture.Especially the citric acid ester oil that can be used for herein comprises the different cetyl ester of citric acid three, citric acid three iso stearyl esters and citric acid trioctylphosphine dodecyl ester.Especially the glyceride oil that can be used for herein comprises glycerol three isostearates, triolein and linolein.The poly ﹠ Alpha ,-olefin oil that this paper is particularly useful comprises following several all available from the poly decene of Exxon MobilCo.: commodity are called PURESYN 6, and number-average molecular weight is approximately 500; Commodity are called PURESYN100, and number-average molecular weight is approximately 3000; And commodity PURESYN300 by name, number-average molecular weight is approximately 6000.
Cationic conditioning polymer
The cationic conditioning polymer that can be used for this paper is that mean molecule quantity is at least about 5,000, typical case approximately 10,000, preferred approximately 100,000 to approximately 200 ten thousand those.The cationic conditioning polymer that can be used for this paper is not above at the lower described polymer of title " polysaccharide polymer ".
Suitable cationic polymer comprises the vinyl monomer that for example has cationic amine or quaternary ammonium functional group and the copolymer of water solublity spacer monomers, and described water solublity spacer monomers is acrylamide, Methacrylamide, alkyl and dialkyl group acrylamide, alkyl and dialkyl methyl acrylamide, alkyl acrylate, alkyl methacrylate, vinyl caprolactone and vinyl pyrrolidone for example.Other suitable spacer monomers comprises vinyl acetate, vinyl alcohol (being made by the polyvinyl acetate hydrolysis), maleic anhydride, propylene glycol and ethylene glycol.
Product form
Care composition of the present invention can be rinse-off products or leave product form, and can be formulated as the multiple product form, includes but not limited to cream, gel, emulsion, mousse and spray.
Care composition of the present invention is particularly useful for the washing-off type conditioner.Above-mentioned composition preferably follows these steps to use:
(i) after the hair washing, the care composition of coating effective dose is with conditioning hair on hair; With
(ii) then clean described hair.
Preferred use compositions of the present invention is to increase hair volume.When being used for increasing the product of hair volume, the said goods preferably has at least a and hair volume increase beneficial effect is described accordingly.Foregoing description comprises, for example, " volume increase ", " shearing volume ", " plentiful ", " hair is plentiful ", " a large amount of hair ", " denser hair ", " hair that does not force down ", " fluffy ", " slimmer and more graceful hair ", " flexible ", " merrily and lightheartedly " and " from the root of hair perk ".
Embodiment
Following examples have further described and have proved the embodiment in the scope of the invention.These embodiment that give are only illustrative, and are unintelligible for being limitation of the present invention, because can carry out many changes in the case of without departing from the spirit and scope of protection of the present invention.Unless hereinafter explanation in addition, applicable composition is all identified with chemical name or CTFA name herein.
The component definition
*1 polysaccharide polymer-1: melon ear hydroxypropyl polymer, molecular weight are approximately 2,500,000, and substitution value is 0.6, with trade name Jaguar HP-105 available from Rhodia.
*2 polysaccharide polymers-2: Rhaball Gum CG-M 8M, molecular weight are 2,200,000, and charge density is 0.6, with trade name Jaguar C17 available from Rhodia.
*3 polysaccharide polymers-3: Rhaball Gum CG-M 8M, molecular weight are 1,200,000, and charge density is 0.7, with trade name Jaguar Excel available from Rhodia.
*4 polysaccharide polymers-4: hydroxypropyl melon ear, molecular weight are Isosorbide-5-Nitrae 00,000, and substitution value is 0.4, with trade name N-Hance HP-40 available from Aqualon/Hercules.
*5 amino silicones-1: the terminal amino group siloxanes, it is available from GE, and viscosity is approximately 10,000mPas, and have following chemical formula structure:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is methyl; A is integer 1; N is 400 to about 600 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L structure, wherein q is integer 3, and L is-NH
2
Preparation method
Can by any conventional method well known in the art, prepare the care composition in " embodiment 1 " as implied above to " embodiment 8 ".They can followingly suitably prepare:
Under agitation, polymeric material is added to the water, and is heated to approximately 80 ℃.Approximately under 80 ℃, under agitation cationic surfactant and hard fat compounds of group are joined in mixture.Described mixture is cooled to approximately 55 ℃.Under agitation, amino silicone and annexing ingredient (if comprising) are joined in mixture as spice and antiseptic.Then make the cooling room temperature of described mixture.
Embodiment 1 to 8 is the present invention of being particularly useful for rinsing purposes care compositions of taking care of hair.Embodiment open by aforementioned " embodiment 1 " to " embodiment 8 " and representative has many advantages.For example, they can provide hair volume to increase beneficial effect and be easy to and rinse sense, and the conditioning beneficial effect of improvement also can be provided simultaneously.
Size disclosed herein and numerical value should not be understood to be strictly limited to described exact numerical values recited.On the contrary, except as otherwise noted, each above-mentioned size is intended to represent described value and near the function equivalent scope of this value.For example, disclosed size " 40mm " is intended to expression " approximately 40mm ".The relevant portion of all documents of quoting in detailed Description Of The Invention is incorporated herein by reference.It is to its approval as prior art of the present invention that the quoting of any document not can be regarded as.In this written document record, when any implication of same term in any implication of term or definition and the document that is incorporated herein by reference or define when conflicting, will be as the criterion with term implication or the definition of appointment in this written document record.
Although illustrated and described the present invention with specific embodiments, it will be apparent to those skilled in the art that many other variations and modifications may be made in the case of without departing from the spirit and scope of protection of the present invention.Therefore, comprise at additional claims all such changes and modifications that belong in the scope of the invention consciously.
Claims (2)
1. hair care composition, described compositions comprises by weight:
(a) 0.05% to 10% nonionic polysaccharide polymer, described polysaccharide polymer has 1,500,000 to 5,000,000 molecular weight, wherein said nonionic polysaccharide polymer are selected from by being selected from the group modified nonionic guar gum of methylol, ethoxy, hydroxypropyl and hydroxyl butyl;
(b) 0.1% to 10% amino silicone, described amino silicone has following formula:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl; A is 1; N is 300 to 1,800 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L, wherein q is 2 to 8 integer, and L is-N (CH
3)
2Or-NH
2
(c) 0.1% to 10% cationic surfactant by weight of the composition;
(d) 0.1% to 20% hard fat compounds of group by weight of the composition; With
(e) aqueous carrier,
And wherein said compositions does not contain anion surfactant and anionic polymer.
2. for increasing the purposes of the hair care composition of hair volume, wherein said hair care composition comprises by weight:
(a) 0.05% to 10% nonionic polysaccharide polymer, described polysaccharide polymer has 1,500,000 to 5,000,000 molecular weight, wherein said nonionic polysaccharide polymer are selected from by being selected from the group modified nonionic guar gum of methylol, ethoxy, hydroxypropyl and hydroxyl butyl;
(b) 0.1% to 10% amino silicone, described amino silicone has following formula:
(R
1)
aG
3-a-Si-(-OSiG
2)
n-O-SiG
3-a(R
1)
a
Wherein G is hydrogen, phenyl, hydroxyl or C
1-C
8Alkyl; A is 1; N is 300 to 1,800 number; R
1For meeting general formula C
qH
2qThe univalent perssad of L, wherein q is 2 to 8 integer, and L is-N (CH
3)
2Or-NH
2
(c) 0.1% to 10% cationic surfactant by weight of the composition;
(d) 0.1% to 20% hard fat compounds of group by weight of the composition; With
(e) aqueous carrier,
And wherein said compositions does not contain anion surfactant and anionic polymer.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/IB2007/052531 WO2009004404A1 (en) | 2007-06-29 | 2007-06-29 | Hair conditioning composition comprising polysaccharide polymer and aminosilicone |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101442977A CN101442977A (en) | 2009-05-27 |
| CN101442977B true CN101442977B (en) | 2013-05-15 |
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|---|---|---|---|
| CN200780000603.XA Active CN101442977B (en) | 2007-06-29 | 2007-06-29 | Hair conditioning composition comprising polysaccharide polymer and aminosilicone |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN101442977B (en) |
| BR (1) | BRPI0702868A2 (en) |
| CA (1) | CA2611244C (en) |
| MX (1) | MX2007015815A (en) |
| WO (1) | WO2009004404A1 (en) |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CA2728212A1 (en) * | 2008-06-25 | 2009-12-30 | The Procter & Gamble Company | Hair conditioning composition containing a salt of behenyl aidopropyl diemethylamine and l-glutamic acid |
| BR112016001826B1 (en) * | 2013-08-01 | 2019-12-03 | Oreal | composition comprising an aminosilicone, a cationic surfactant, an associative polymer and a thickening agent |
| CN115505293B (en) * | 2022-09-26 | 2023-04-25 | 三晃树脂（佛山）有限公司 | Polyurethane for shoe material printing ink and preparation method thereof |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20070010408A1 (en) * | 2005-07-07 | 2007-01-11 | The Procter & Gamble Company | Conditioning compositions comprising coacervate and gel matrix |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0413416A3 (en) * | 1989-06-21 | 1991-09-04 | Colgate-Palmolive Company | Fiber conditioning compositions containing an aminosilicone |
| US4997641A (en) * | 1990-04-09 | 1991-03-05 | Colgate-Palmolive Company | Hair conditioning shampoo containing C6 -C10 alkyl sulfate or alkyl alkoxy sulfate |
| AU2002301803B2 (en) * | 2001-11-08 | 2004-09-09 | L'oreal | Cosmetic compositions containing an aminosilicone and a conditioner, and uses thereof |
| CA2484974C (en) * | 2002-06-04 | 2011-08-02 | The Procter & Gamble Company | Conditioning shampoo containing aminosilicone |
| ES2308254T3 (en) * | 2003-09-24 | 2008-12-01 | THE PROCTER & GAMBLE COMPANY | CONDITIONING COMPOSITION THAT AMINOSILICONA INCLUDES. |
| CN101039721A (en) * | 2004-10-13 | 2007-09-19 | 宝洁公司 | Hair conditioning composition comprising an alkyl diquaternized ammonium salt cationic surfactant |
| WO2006137004A2 (en) * | 2005-06-21 | 2006-12-28 | The Procter & Gamble Company | Hair conditioning composition comprising gel matrix and high molecular weight water-soluble cationic polymer |
-
2007
- 2007-06-29 MX MX2007015815A patent/MX2007015815A/en active IP Right Grant
- 2007-06-29 CN CN200780000603.XA patent/CN101442977B/en active Active
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| US20070010408A1 (en) * | 2005-07-07 | 2007-01-11 | The Procter & Gamble Company | Conditioning compositions comprising coacervate and gel matrix |
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| Publication number | Publication date |
|---|---|
| BRPI0702868A2 (en) | 2011-03-15 |
| CN101442977A (en) | 2009-05-27 |
| CA2611244C (en) | 2011-11-15 |
| WO2009004404A1 (en) | 2009-01-08 |
| CA2611244A1 (en) | 2008-12-29 |
| MX2007015815A (en) | 2009-02-23 |
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