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CN101409332B - Sealed battery - Google Patents

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Publication number
CN101409332B
CN101409332B CN2008102127707A CN200810212770A CN101409332B CN 101409332 B CN101409332 B CN 101409332B CN 2008102127707 A CN2008102127707 A CN 2008102127707A CN 200810212770 A CN200810212770 A CN 200810212770A CN 101409332 B CN101409332 B CN 101409332B
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China
Prior art keywords
mentioned
injection port
hole
liquid injection
axial region
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Expired - Fee Related
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CN2008102127707A
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CN101409332A (en
Inventor
山本真由美
藤原义久
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Maxell Ltd
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Hitachi Maxell Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/317Re-sealable arrangements
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/147Lids or covers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/10Primary casings; Jackets or wrappings
    • H01M50/183Sealing members
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M50/00Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
    • H01M50/30Arrangements for facilitating escape of gases
    • H01M50/308Detachable arrangements, e.g. detachable vent plugs or plug systems
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Filling, Topping-Up Batteries (AREA)
  • Sealing Battery Cases Or Jackets (AREA)

Abstract

The present invention relates to sealed batteries, object to remove the fluctuation of the jogged state resulting from the dimensional tolerances of a liquid injection port (17) and a seal bolt (18) and to realize the sealability improvement of the liquid injection port (17) performed by the seal bolt (18). In this invention, the spreading and deformation of the shaft section(25) of the seal bolt (18) is performed by pressing an operation pin (29) in a function hole (30), so that the external circumstance surface of the shaft section (25) is pressed on the internal circumstance surface of a filling hole (19). Thus, the sealing-joining performance of the entire circumference scope between the external circumstance surface of the shaft section (25) and the internal circumstance surface of the filling hole (19) can be improved, so as to improve the sealability between the shaft section (25) of the seal bolt (18) and the filling hole (19) of the liquid injection port (17).

Description

密封电池 sealed battery

技术领域technical field

本发明涉及具有堵住电池盒的开口上面的盖、设在盖上的电解液注入用的注液口以及安装在该注液口的密封栓的密封电池,涉及实现提高由密封栓得到的注液口的密封特性的技术。The present invention relates to a sealed battery with a cover that blocks the opening of the battery case, a liquid injection port provided on the cover for injecting electrolyte solution, and a sealing plug installed in the liquid injection port, and relates to the realization of improving the injection rate obtained by the sealing plug. The technology of the sealing characteristics of the liquid port.

背景技术Background technique

在涉及本发明的密封电池中,将注液口形成为具有凹部的带阶梯状,在该注液口安装了具有头部的密封栓之后,通过焊接该头部的外周边缘和凹部的周边部从而封住注液口,而同样的封口构造例如在专利文献1(日本特开2006-40690号公报)中也能够看到。In the sealed battery related to the present invention, the liquid injection port is formed in a stepped shape with a concave portion, and after the sealing plug having a head is attached to the liquid injection port, the outer peripheral edge of the head and the peripheral portion of the concave portion are welded. Thus, the liquid injection port is sealed, and a similar sealing structure can also be seen in, for example, Patent Document 1 (Japanese Patent Application Laid-Open No. 2006-40690).

在该专利文献1中,在堵住电池盒的开口上面的盖上以上下贯通状形成注入孔,在该注入孔的周围形成具有向上的承受面的圆状的凹部,并作为注液口。另外,密封栓具备:从上方插入注入孔的轴部、和在轴部的上端伸出地形成且由凹部的承受面来承受的圆形的头部。而且,在凹部内安装了密封栓之后,通过对头部的外周边缘和凹部的周边部照射激光使其熔化,从而用密封栓封住注液口。In this patent document 1, an injection hole is formed vertically through the cover that closes the upper surface of the opening of the battery case, and a circular recess with an upward receiving surface is formed around the injection hole as a liquid injection port. In addition, the sealing plug includes a shaft portion inserted into the injection hole from above, and a circular head portion protruding from the upper end of the shaft portion and received by the receiving surface of the concave portion. Then, after the sealing plug is installed in the concave portion, the outer peripheral edge of the head portion and the peripheral portion of the concave portion are irradiated with laser to melt them, thereby sealing the liquid injection port with the sealing plug.

上述封口构造的问题在于,由于注液口及密封栓的尺寸公差的问题,不能避免“间隙配合”或“过盈配合”等的嵌合状态发生变化,结果在注液口安装密封栓变得困难,或者产生焊接不良。即,注液口和密封栓是通过冲压加工而形成的微细部件,允许一定程度的部件尺寸的波动、即尺寸公差。因此,在注入孔的内径尺寸为包括尺寸公差的最小值、且轴部的外径尺寸为包括尺寸公差的最大值的场合,存在不能向注入孔内插入轴部的危险(过盈配合)。The problem with the above-mentioned sealing structure is that due to the dimensional tolerance of the liquid injection port and the sealing plug, it is impossible to avoid changes in the fitting state such as "clearance fit" or "interference fit", and as a result, it becomes difficult to install the sealing plug at the liquid injection port. Difficulty, or poor welding occurs. That is, the filling port and the sealing plug are minute parts formed by press working, and a certain degree of fluctuation in part size, that is, dimensional tolerance is allowed. Therefore, when the inner diameter of the injection hole is the minimum value including the dimensional tolerance and the outer diameter of the shaft is the maximum value including the dimensional tolerance, there is a risk that the shaft cannot be inserted into the injection hole (interference fit).

相反,在注入孔的内径尺寸为包括尺寸公差的最大值、且轴部的外径尺寸为包括尺寸公差的最小值的场合,在安装状态下存在密封栓在注液口的内部浮动的危险(间隙配合)。这样若在安装状态下密封栓浮动,则密封栓在凹部内偏心而产生轴偏移,结果在凹部与密封栓的接触部分或间隙部分产生焊接不良,存在产生漏液的危险。Conversely, when the inner diameter of the injection hole is the maximum value including the dimensional tolerance, and the outer diameter of the shaft is the minimum value including the dimensional tolerance, there is a risk of the seal plug floating inside the liquid injection port in the mounted state ( gap fit). In this way, if the sealing plug floats in the installed state, the sealing plug is eccentric in the recess to cause an axial shift. As a result, poor welding occurs at the contact portion or gap between the recess and the sealing plug, and there is a risk of liquid leakage.

发明内容Contents of the invention

本发明为解决如上所述的问题而提出,其目的在于消除由注液口及密封栓的尺寸公差引起的嵌合状态的波动,并实现提高由密封栓得到的注液口的密封性。The present invention is made to solve the above problems, and its purpose is to eliminate fluctuations in the fitting state caused by dimensional tolerances of the filling port and the sealing plug, and to improve the sealing performance of the filling port by the sealing plug.

涉及本发明的密封电池的特征在于,具有:堵住外装罐2的开口上面的盖5、设在上述盖5上的电解液注入用的注液口17以及安装在该注液口17的金属制的密封栓18。上述注液口17具有以上下贯通状形成于上述盖5的注入孔19、和具有形成于该注入孔19周围的朝上的承受面的圆状的凹部21。上述密封栓18具有从上方插入上述注入孔19的轴部25、和在该轴部25的上端伸出地形成且由上述凹部21的承受面20承受的圆形的头部26,在上述轴部25的轴心位置上凹入地形成具有上方开口的扩展变形用的操作孔30。而且,若从上方开口将操作销29压入上述操作孔30中使上述轴部25扩展变形,则成为该轴部25的外周面按压在上述注入孔19的内周面的贴紧状态,在该贴紧状态下,通过焊接上述头部26的外周边缘和上述凹部21的周边部从而封住上述注液口17。The sealed battery according to the present invention is characterized in that it has: a cover 5 for blocking the upper surface of the opening of the outer container 2, a liquid injection port 17 for injecting an electrolyte solution provided on the cover 5, and a metal material attached to the liquid injection port 17. Made sealing plug 18. The liquid injection port 17 has an injection hole 19 formed vertically through the cap 5 , and a circular recess 21 having an upward receiving surface formed around the injection hole 19 . The sealing plug 18 has a shaft portion 25 inserted into the injection hole 19 from above, and a circular head portion 26 protruding from the upper end of the shaft portion 25 and received by the receiving surface 20 of the concave portion 21. An operation hole 30 for expanding and deforming with an upper opening is recessed at the axial center position of the portion 25 . And, when the operation pin 29 is pressed into the operation hole 30 from the upper opening to expand and deform the shaft portion 25, the outer peripheral surface of the shaft portion 25 is pressed against the inner peripheral surface of the injection hole 19 in a tight state. In this close contact state, the liquid injection port 17 is sealed by welding the outer peripheral edge of the head portion 26 and the peripheral portion of the concave portion 21 .

可以采用在上述操作孔30的上端部形成有下窄锥状的被按压面33的方式。A form in which a downwardly tapered pressed surface 33 is formed at the upper end of the operation hole 30 may be employed.

包括尺寸公差的轴部25的最大外径尺寸D1设定为比包括尺寸公差的上述注入孔19的最小内径尺寸D2还小,包括尺寸公差的头部26的最大外径尺寸D3设定为比包括尺寸公差的上述凹部21的最小内径尺寸D4还小。The maximum outer diameter dimension D1 of the shaft portion 25 including the dimensional tolerance is set to be smaller than the minimum inner diameter dimension D2 of the injection hole 19 including the dimensional tolerance, and the maximum outer diameter dimension D3 of the head portion 26 including the dimensional tolerance is set to be smaller than The minimum inner diameter dimension D4 of the above-mentioned concave portion 21 including dimensional tolerances is also small.

本发明具有以下效果。The present invention has the following effects.

根据本发明的密封电池,通过将操作销29压入操作孔30中而使密封栓18的轴部25扩展变形,从而使轴部25的外周面按压在注入孔19的内周面上,能够使轴部25牢固地贴紧在该注入孔19上。由此,能够提高注入孔19的内周面与轴部25的外周面之间的密合性,且可实现密封栓18的轴部25与注液口17的注入孔19的密封性的提高,所以能切实防止从注液口17的漏液。According to the sealed battery of the present invention, by pressing the operation pin 29 into the operation hole 30, the shaft portion 25 of the sealing plug 18 is expanded and deformed, so that the outer peripheral surface of the shaft portion 25 is pressed against the inner peripheral surface of the injection hole 19. The shaft portion 25 is firmly attached to the injection hole 19 . Thus, the adhesiveness between the inner peripheral surface of the injection hole 19 and the outer peripheral surface of the shaft portion 25 can be improved, and the sealing performance between the shaft portion 25 of the sealing plug 18 and the injection hole 19 of the liquid injection port 17 can be improved. , Therefore, leakage from the liquid injection port 17 can be reliably prevented.

尤其是,通过使轴部25扩展变形而提高轴部25与注入孔19之间的密合性的方式,因此能够在吸收制作方面的密封栓18和注液口17的尺寸公差的同时切实地密封注液口17。换言之,根据本发明,在消除了由制作上的尺寸公差引起的轴部25与注液口19之间的嵌合状态的波动,能够通过轴部25切实地焊接固定注液口19,能得到无漏液的可靠性优良的密封电池的方面优良。In particular, by expanding and deforming the shaft portion 25 to improve the adhesion between the shaft portion 25 and the injection hole 19, it is possible to absorb the dimensional tolerances of the sealing plug 18 and the liquid injection port 17 on the production side while reliably Seal the filling port 17. In other words, according to the present invention, the fluctuation of the fitting state between the shaft portion 25 and the liquid injection port 19 caused by dimensional tolerances in production can be eliminated, and the liquid injection port 19 can be reliably welded and fixed by the shaft portion 25, and it is possible to obtain A sealed battery with excellent reliability without leakage is excellent.

若在操作孔30的上端部形成下窄锥状的被按压面33,则能够以该被按压面33作为导向面,在使操作销29切实地位于轴部25的轴心位置的同时,进行操作销29的压入操作。由此,能够使轴部25沿周向均匀地扩展变形,所以能够将密封栓18的轴部25的整个外周面均匀地接触在注液口17的注入孔19的内周面上。If the pressed surface 33 of lower narrow tapered shape is formed on the upper end portion of the operation hole 30, the pressed surface 33 can be used as a guide surface, and the operation pin 29 can be positioned at the axial center position of the shaft portion 25 reliably. Push-in operation of the operation pin 29. As a result, the shaft portion 25 can be expanded and deformed uniformly in the circumferential direction, so that the entire outer peripheral surface of the shaft portion 25 of the sealing plug 18 can be brought into uniform contact with the inner peripheral surface of the injection hole 19 of the liquid injection port 17 .

若包括尺寸公差的轴部25的最大外径尺寸D1设定为比包括尺寸公差的上述注入孔19的最小内径尺寸D2还小,则成为所谓的“过盈配合”状态,不存在密封栓18不能安装在注液口17的情况。因此,在将密封栓18切实地落入注液口17内而成为临时固定状态之后,进行由操作销29进行的扩展变形作业,接着进行焊接作业,从而能够用密封栓18切实地密封注液口17。在能够抑制由不能将密封栓18临时固定在注液口17上所引起的成品率的下降并实现生产率的提高的方面优良。If the maximum outer diameter D1 of the shaft portion 25 including dimensional tolerances is set to be smaller than the minimum inner diameter D2 of the above-mentioned injection hole 19 including dimensional tolerances, it becomes a so-called "interference fit" state, and the sealing plug 18 does not exist. It cannot be installed on the liquid injection port 17. Therefore, after the sealing plug 18 is reliably dropped into the liquid injection port 17 to be in a temporarily fixed state, the expansion and deformation operation by the operation pin 29 is performed, followed by the welding operation, so that the sealing plug 18 can be reliably sealed. Mouth 17. It is excellent in that it is possible to suppress a drop in yield due to the inability to temporarily fix the seal plug 18 to the liquid injection port 17 and to improve productivity.

附图说明Description of drawings

图1是本发明的密封电池的主要部分的纵剖视图。Fig. 1 is a longitudinal sectional view of main parts of the sealed battery of the present invention.

图2是本发明的密封电池的分解立体图。Fig. 2 is an exploded perspective view of the sealed battery of the present invention.

图3是用于说明本发明的密封电池的封口构造的图。Fig. 3 is a diagram for explaining the sealing structure of the sealed battery of the present invention.

图4是用于说明本发明的密封电池的封口顺序的图。Fig. 4 is a diagram for explaining the sealing procedure of the sealed battery of the present invention.

图5是用于说明本发明的密封电池的封口顺序的图。Fig. 5 is a diagram for explaining the sealing procedure of the sealed battery of the present invention.

图中:In the picture:

1-密封电池(干电池),2-外装罐,5-盖(封口板),17-注液口,18-密封栓,19-注入孔,20-承受面,21-凹部,25-轴部,26-头部,29-操作销,30-操作孔,33-被按压面。1-sealed battery (dry battery), 2-outer can, 5-cover (sealing plate), 17-injection port, 18-sealing plug, 19-injection hole, 20-receiving surface, 21-recess, 25-shaft , 26-head, 29-operation pin, 30-operation hole, 33-pressed surface.

具体实施方式Detailed ways

图1至图5表示将本发明的密封电池应用于构成电池部分的干电池的实施例。在图2中,素电池1以上面开口的扁平筒状的外装罐2作为基体,在其内部容纳电极体3和电解液,并将外装罐2的开口用塑料制的绝缘体4和金属制的封口板(盖)5密封而构成。外装罐2及封口板5的两端做成圆形。1 to 5 show an embodiment in which the sealed battery of the present invention is applied to a dry battery constituting a battery portion. In Fig. 2, the plain battery 1 uses a flat cylindrical outer can 2 with an open upper surface as a base, houses an electrode body 3 and an electrolyte solution inside, and uses a plastic insulator 4 and a metal insulator 4 for the opening of the outer can 2. The sealing plate (cover) 5 is configured to be sealed. The two ends of the exterior can 2 and the sealing plate 5 are made into circles.

电极体3在将以LiCoO2为活性物质的正极片、以石墨为活性物质的负极片、以及对这些两个片进行绝缘的隔离片层叠之后卷绕成螺旋状,再将整体以扁平状压扁而形成。从正极片和负极片分别向上引出导电片7、8。电解液是在混合了碳酸乙烯酯(EC)和碳酸甲乙酯(MEC)的溶剂中融解LiPF5而成。The electrode body 3 is wound in a spiral shape after stacking a positive electrode sheet with LiCoO2 as an active material, a negative electrode sheet with graphite as an active material, and a separator for insulating these two sheets, and then presses the whole in a flat shape. formed flat. The conductive sheets 7 and 8 are drawn upward from the positive electrode sheet and the negative electrode sheet respectively. The electrolyte is prepared by melting LiPF 5 in a solvent mixed with ethylene carbonate (EC) and methyl ethyl carbonate (MEC).

如图1所示,在封口板5的上面中央配置有负极端子9,正极端子10兼作封口板5或外装罐2。封口板5由以铝或铝合金作为原材料的冲压成型品构成,在其盘面中央,以内外贯通状设有使绝缘密封件11及负极端子9通过的圆形的端子安装孔。在封口板5的上面,在端子安装孔周围凹入形成托座。在封口板5的内面侧配置有绝缘板12,在绝缘板12的下侧配置有金属制的压板13。As shown in FIG. 1 , a negative terminal 9 is arranged at the center of the upper surface of the sealing plate 5 , and a positive terminal 10 also serves as the sealing plate 5 or the outer can 2 . The sealing plate 5 is composed of a stamped product made of aluminum or an aluminum alloy, and a circular terminal mounting hole through which the insulating seal 11 and the negative terminal 9 pass is provided in the center of the disk surface. On the upper surface of the sealing plate 5, a socket is formed by recessing around the terminal mounting hole. An insulating plate 12 is arranged on the inner side of the sealing plate 5 , and a metal pressure plate 13 is arranged on the lower side of the insulating plate 12 .

外装罐2由以铝、铝合金或不锈钢材料作为原材料的深拉深成型品构成,封口板5在嵌入外装罐2的开口内面的状态下通过激光焊接被固定。绝缘体4是有底盘状的塑料成型品,在底部以上下贯通状形成允许电极体的导电片7、8插入的切口15、15。The outer can 2 is made of a deep-drawn product made of aluminum, aluminum alloy, or stainless steel, and the sealing plate 5 is fixed by laser welding while being fitted into the inner surface of the opening of the outer can 2 . The insulator 4 is a chassis-shaped plastic molded product, and cutouts 15, 15 for allowing the conductive sheets 7, 8 of the electrode body to be inserted are formed on the bottom to penetrate up and down.

在图1中,在封口板5的左右方向的一端侧设有防爆用的开裂口(開裂ベント)16,在封口板5的另一端侧设有电解液注入用的注液口17。开裂口16在外装罐2的内压超过一定值时破裂而放出外装罐2内的气体。在电解液注入后,注液口17由密封栓18密封。In FIG. 1 , one end side of the sealing plate 5 in the left-right direction is provided with an explosion-proof opening (crack vent) 16 , and the other end side of the sealing plate 5 is provided with a liquid injection port 17 for injecting the electrolyte. The opening 16 ruptures when the internal pressure of the outer can 2 exceeds a certain value, and releases the gas in the outer can 2 . After the electrolyte is injected, the liquid injection port 17 is sealed by a sealing plug 18 .

如图3所示,注液口17形成为由以上下贯通状形成于封口板5的注入孔19和具有形成于该注入孔19周围的朝上的承受面20的圆状的凹部21构成的带阶梯状。注入孔19形成为在上下方向范围内内径尺寸均匀的直线状。同样地,凹部21形成为在上下方向范围内内径尺寸均匀的直线状。As shown in FIG. 3 , the liquid injection port 17 is formed by an injection hole 19 formed in the sealing plate 5 penetrating up and down and a circular concave portion 21 having an upward receiving surface 20 formed around the injection hole 19 . Stepped. The injection hole 19 is formed in a linear shape with a uniform inner diameter in the vertical direction. Likewise, the concave portion 21 is formed in a linear shape with a uniform inner diameter in the range in the vertical direction.

密封该注液口17的密封栓18是以铝等金属作为原材料的部件,并具备从上方插入到注入孔19中的轴部25和在该轴部25的上端伸出地形成且由凹部21的承受面20承受的圆形的头部26。通过在凹部21嵌合地承受头部,从而实现密封栓18对封口板5的向下的防脱。The sealing plug 18 that seals the liquid injection port 17 is made of metal such as aluminum, and has a shaft portion 25 inserted into the injection hole 19 from above, and a concave portion 21 protruding from the upper end of the shaft portion 25 . The circular head 26 received by the receiving surface 20 . The downward locking of the sealing plate 5 by the sealing plug 18 is achieved by fitting and receiving the head portion in the recessed portion 21 .

轴部25具备:在上下方向上外径尺寸均匀的直线部27、和设在该直线部27的下端且随着朝向下方直径尺寸逐渐变小的下窄锥状的导向部28。直线部27的壁厚50为0.1mm以上,且从密封栓18的小径部31的底部到前端的壁厚为0.1mm以上。The shaft portion 25 includes a linear portion 27 with a uniform outer diameter in the vertical direction, and a lower tapered guide portion 28 provided at the lower end of the linear portion 27 and whose diameter gradually decreases downward. The thickness 50 of the linear portion 27 is 0.1 mm or more, and the thickness from the bottom to the tip of the small diameter portion 31 of the sealing plug 18 is 0.1 mm or more.

在轴部25的轴心位置凹下形成操作孔30,该操作孔30在从上方压入操作销29时使轴部25扩展变形。操作孔30包括:内径尺寸均匀的下方的小径部31、具有比该小径部31大的内径尺寸的大径部32、以及设在小径部31的上端且被操作销29按压的下窄锥状的被按压面33。在操作销29的下端,形成有下窄锥状的按压面34。An operation hole 30 is recessed at the axial center position of the shaft portion 25 , and the shaft portion 25 is expanded and deformed when the operation pin 29 is pushed in from above. The operation hole 30 includes: a lower small-diameter portion 31 with a uniform inner diameter, a large-diameter portion 32 having a larger inner diameter than the small-diameter portion 31 , and a narrow tapered lower portion provided on the upper end of the small-diameter portion 31 and pressed by the operating pin 29 . The pressed surface 33 of. At the lower end of the operation pin 29, a downward tapered pressing surface 34 is formed.

如图3所示,包括尺寸公差的轴部25的直线部27的最大外径尺寸D1设定为比包括尺寸公差的注入孔19的最小内径尺寸D2还小。而且,包括尺寸公差的头部的最大外径尺寸D3设定为比包括尺寸公差的凹部的最小内径尺寸D4还小。从而,在从上方将密封栓18落入了注液口17中时,轴部25及头部26不会卡在注液口17的注入孔19及凹部21,能够做成如图4所示的临时固定状态。As shown in FIG. 3 , the maximum outer diameter dimension D1 of the straight portion 27 of the shaft portion 25 including the dimensional tolerance is set smaller than the minimum inner diameter dimension D2 of the injection hole 19 including the dimensional tolerance. Furthermore, the maximum outer diameter dimension D3 of the head portion including the dimensional tolerance is set to be smaller than the minimum inner diameter dimension D4 of the concave portion including the dimensional tolerance. Therefore, when the sealing plug 18 is dropped into the liquid injection port 17 from above, the shaft portion 25 and the head portion 26 will not be stuck in the injection hole 19 and the concave portion 21 of the liquid injection port 17, and it can be made as shown in FIG. 4 . temporary fixation status.

接着,参照图4及图5对电解液注入后的注液口17的密封作业进行说明。首先,如图4所示,从注液口17的上方落入密封栓18而做成临时固定状态。如前面所述,由于注液口17及密封栓18满足D1<D2、D3<D4的关系,因此在轴部25的外周面与注入孔19的内周面之间以及头部26的外周面与凹部21的周侧面之间形成一点点间隙。而且,虽然反复说明,由于满足D1<D2、D3<D4的关系,因此在从上方将密封栓18落入了注液口17时,轴部25及头部26不会卡在注入孔19及凹部21上,能够顺利地做成如图4所示的临时固定状态。Next, the sealing operation of the liquid injection port 17 after the electrolytic solution is injected will be described with reference to FIGS. 4 and 5 . First, as shown in FIG. 4 , the sealing plug 18 is dropped from above the liquid injection port 17 to be temporarily fixed. As mentioned above, since the liquid injection port 17 and the sealing plug 18 satisfy the relationship of D1<D2, D3<D4, between the outer peripheral surface of the shaft portion 25 and the inner peripheral surface of the injection hole 19 and the outer peripheral surface of the head 26 A slight gap is formed with the peripheral side surface of the concave portion 21 . Moreover, although it has been repeatedly described, since the relationship of D1<D2 and D3<D4 is satisfied, when the sealing plug 18 is dropped into the liquid injection port 17 from above, the shaft portion 25 and the head portion 26 will not be stuck in the injection hole 19 and the injection port 17. On the concave portion 21, the temporarily fixed state as shown in FIG. 4 can be made smoothly.

然后,如图5所示,从上方开口将操作销29压入到操作孔30的小径部31中,使轴部25扩展变形。由此,可以做成轴部25的直线部27的外周面按压在注入孔19的内周面的贴紧状态。换言之,通过使轴部25扩展变形,可以填补轴部25的外周面与注入孔19的内周面之间的间隙,从而使轴部25与注入孔19贴紧。在如上所述的操作销29的压入操作中,头部26的外径尺寸几乎不变。Then, as shown in FIG. 5 , the operation pin 29 is press-fitted into the small-diameter portion 31 of the operation hole 30 from the upper opening to expand and deform the shaft portion 25 . Thereby, a close contact state can be achieved in which the outer peripheral surface of the straight portion 27 of the shaft portion 25 is pressed against the inner peripheral surface of the injection hole 19 . In other words, by expanding and deforming the shaft portion 25 , the gap between the outer peripheral surface of the shaft portion 25 and the inner peripheral surface of the injection hole 19 can be filled and the shaft portion 25 and the injection hole 19 can be brought into close contact. During the pressing operation of the operation pin 29 as described above, the outer diameter dimension of the head portion 26 hardly changes.

从这种贴紧状态,如图1所示,对头部26的外周边缘与凹部21的周边部的边界部,从上方进行激光焊接。该焊接作业在头部26的整个外周边缘的范围内进行,由此能够完全封住注液口17。在上述焊接作业中,以填补头部26的外周边缘与凹部21的周边部之间的一点点间隙的方式进行焊接作业。在图1中,标记40表示由激光焊接进行的焊接处。From this close contact state, as shown in FIG. 1 , laser welding is performed from above on the boundary portion between the outer peripheral edge of the head portion 26 and the peripheral portion of the recessed portion 21 . This welding operation is carried out over the entire outer peripheral edge of the head 26, whereby the filling port 17 can be completely sealed. In the welding work described above, the welding work is performed so as to fill a slight gap between the outer peripheral edge of the head portion 26 and the peripheral portion of the concave portion 21 . In FIG. 1 , reference numeral 40 indicates a weld by laser welding.

如上所述,在本实施方式的注液口17的封口构造中,在操作孔30压入操作销29,通过使密封栓18的轴部25扩展变形,从而使轴部25的外周面按压在注入孔19的内周面上,可以使轴部25牢固地贴紧在该注入孔19上。As described above, in the sealing structure of the liquid injection port 17 in this embodiment, the operation pin 29 is press-fitted into the operation hole 30, and the shaft portion 25 of the sealing plug 18 is expanded and deformed, thereby pressing the outer peripheral surface of the shaft portion 25 against the sealing structure. On the inner peripheral surface of the injection hole 19 , the shaft portion 25 can be firmly attached to the injection hole 19 .

由此,能够提高在注入孔19的内周面与轴部25的外周面之间的整个圆周范围内的密合性,所以能够实现密封栓18的轴部25与注液口17的注入孔19的密封性的提高。因而,能切实地防止从注液口17的漏液,从而实现干电池1的可靠性的提高。As a result, the adhesion between the inner peripheral surface of the injection hole 19 and the outer peripheral surface of the shaft portion 25 can be improved over the entire circumference, so that the injection hole between the shaft portion 25 of the sealing plug 18 and the injection port 17 can be realized. 19 improved sealing. Therefore, the liquid leakage from the liquid injection port 17 can be reliably prevented, and the reliability of the dry battery 1 can be improved.

而且,由于在密封栓18的头部26与注液口17的凹部21之间能够在形成一点点间隙的状态下进行焊接作业,因此在焊接作业等中即使残留在承受面20上的电解液气化而产生气体的场合,能够使其从间隙漏掉。这样,若能够除去承受面20上的残留电解液,则能够消除在焊接作业后受到残留电解液的气化压力而使密封栓18脱落的不良情况。Moreover, since the welding operation can be performed with a slight gap formed between the head portion 26 of the sealing plug 18 and the concave portion 21 of the liquid injection port 17, even the electrolyte remaining on the receiving surface 20 during the welding operation or the like When vaporized to generate gas, it can be leaked through the gap. In this way, if the residual electrolyte solution on the receiving surface 20 can be removed, it is possible to eliminate the inconvenience that the sealing plug 18 falls off due to the gasification pressure of the residual electrolyte solution after the welding operation.

尤其是,通过使轴部25扩展变形,能够实现轴部25与注入孔19之间的密合性的提高,所以可以在吸收制作上的密封栓18和注液口17的尺寸公差的同时,切实地密封注液口17。换言之,根据该封口构造,能够消除由制作上的尺寸误差引起的密封栓18与注液口17之间的嵌合状态的波动,并且可通过密封栓18切实地焊接固定注液口17,能够切实地得到无漏液的可靠性优良的密封电池,在这一点上非常好。In particular, by expanding and deforming the shaft portion 25, the adhesion between the shaft portion 25 and the injection hole 19 can be improved, so while absorbing the dimensional tolerances of the sealing plug 18 and the liquid injection port 17 in manufacture, The liquid injection port 17 is securely sealed. In other words, according to this sealing structure, fluctuations in the fitting state between the sealing plug 18 and the liquid injection port 17 caused by dimensional errors in production can be eliminated, and the liquid injection port 17 can be securely welded and fixed by the sealing plug 18, enabling It is very good in that a sealed battery with excellent reliability and no liquid leakage can be reliably obtained.

若在操作孔30的上端部形成下窄锥状的被按压面33,则能够以该被按压面33作为导向面,在使操作销29切实地位于轴部25的轴心位置的同时,进行操作销29的压入操作。由此,能够使轴部25沿周向均匀地扩展变形,所以能够将密封栓18的轴部25的整个外周面均匀地接触在注液口17的注入孔19的内周面上。If the pressed surface 33 of lower narrow tapered shape is formed on the upper end portion of the operation hole 30, the pressed surface 33 can be used as a guide surface, and the operation pin 29 can be positioned at the axial center position of the shaft portion 25 reliably. Push-in operation of the operation pin 29. As a result, the shaft portion 25 can be expanded and deformed uniformly in the circumferential direction, so that the entire outer peripheral surface of the shaft portion 25 of the sealing plug 18 can be brought into uniform contact with the inner peripheral surface of the injection hole 19 of the liquid injection port 17 .

若包括尺寸公差的轴部25的最大外径尺寸D1设定为比包括尺寸公差的上述注入孔19的最小内径尺寸D2还小,包括尺寸公差的头部26的最大外径尺寸D3设定为比包括尺寸公差的凹部21的最小内径尺寸D4还小,则成为所谓的“过盈配合”状态,不存在密封栓18不能安装在注液口17的情况。因此,在将密封栓18切实地落入到注液口17内而成为临时固定状态之后,进行由操作销29进行的扩展变形作业,接着进行焊接作业,从而能够用密封栓18切实地密封注液口17。能够抑制由不能将密封栓18临时固定在注液口17上所引起的成品率的下降并实现生产率的提高,在这一点上非常好。If the maximum outer diameter dimension D1 of the shaft portion 25 including the dimensional tolerance is set to be smaller than the minimum inner diameter dimension D2 of the injection hole 19 including the dimensional tolerance, the maximum outer diameter dimension D3 of the head portion 26 including the dimensional tolerance is set as If it is smaller than the minimum inner diameter D4 of the concave portion 21 including dimensional tolerances, it becomes a so-called “interference fit” state, and there is no case where the sealing plug 18 cannot be installed in the liquid injection port 17 . Therefore, after the sealing plug 18 is reliably dropped into the liquid injection port 17 to become a temporarily fixed state, the expansion and deformation operation performed by the operation pin 29 is performed, and then the welding operation is performed, so that the injection port can be reliably sealed with the sealing plug 18 . Liquid port 17. It is very good in that it is possible to suppress a drop in yield due to the inability to temporarily fix the seal plug 18 to the liquid injection port 17 and to improve productivity.

Claims (3)

1. a sealed cell is characterized in that,
Have lid above the opening of blocking outer tinning, be located at the above-mentioned electrolyte that covers and inject the liquid injection port of usefulness and be installed in metal sealing bolt on this liquid injection port,
Above-mentioned liquid injection port has: be formed at the hand-hole of above-mentioned lid to connect shape up and down; With recess with the round shape that is formed at this hand-hole bearing plane up on every side,
Above-mentioned sealing bolt has the axial region that is inserted into from the top the above-mentioned hand-hole and the head of the circle that forms in the upper end of this axial region with stretching out and born by the bearing plane of above-mentioned recess, the shaft core position of above-mentioned axial region form recessedly have above the handle hole used of the expansion deformation of opening
Constitute if from the top opening operative pin is pressed into and makes above-mentioned axial region expansion deformation the aforesaid operations hole, the outer peripheral face that then becomes this axial region is by the state that is adjacent on the inner peripheral surface that is pressed in above-mentioned hand-hole,
Under this is adjacent to state, thereby the neighboring by welding above-mentioned head and the periphery of above-mentioned recess are sealed above-mentioned liquid injection port.
2. sealed cell according to claim 1 is characterized in that,
Be formed with the face that is pressed of narrow taper down in the upper end in aforesaid operations hole.
3. sealed cell according to claim 1 and 2 is characterized in that,
The maximum outside diameter size that comprises the axial region of dimensional tolerance is set at also littler than the minimum diameter size of the above-mentioned hand-hole that comprises dimensional tolerance,
The maximum outside diameter size that comprises the head of dimensional tolerance is set at also littler than the minimum diameter size of the above-mentioned recess that comprises dimensional tolerance.
CN2008102127707A 2007-10-12 2008-09-08 Sealed battery Expired - Fee Related CN101409332B (en)

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CN101409332A (en) 2009-04-15
HK1129159A1 (en) 2009-11-20

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