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CN101406778A - Air cleaning filter, and air cleaner device - Google Patents

Air cleaning filter, and air cleaner device Download PDF

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Publication number
CN101406778A
CN101406778A CNA2008100096672A CN200810009667A CN101406778A CN 101406778 A CN101406778 A CN 101406778A CN A2008100096672 A CNA2008100096672 A CN A2008100096672A CN 200810009667 A CN200810009667 A CN 200810009667A CN 101406778 A CN101406778 A CN 101406778A
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air
filter
cleaning filter
raw materials
water
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稻垣纯
加藤亮
须贺亮介
中岛隆弘
森丰
相马尚胤
桥口幸平
源水和夫
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Panasonic Holdings Corp
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Matsushita Electric Industrial Co Ltd
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Abstract

本发明公开了一种空气清洁过滤片,其特征在于,添附了从具有抗变态反应原性的原材料、具有抗菌性的原材料、具有抗病毒性的原材料、具有防霉性的原材料中选择的两个以上的原材料。

The invention discloses an air-cleaning filter, which is characterized in that two materials selected from antiallergenic raw materials, antibacterial raw materials, antiviral raw materials, and mildew-proof raw materials are added. more than one raw material.

Description

空气清洁过滤片及装置 Air Cleaning Filters and Devices

本申请是申请人“松下电器产业株式会社”提交的申请日为2004年3月26日、申请号为200480016352.0、发明名称为“空气清洁机、功能性过滤片及其制造方法、空气清洁过滤片及装置”的申请的分案申请。This application is submitted by the applicant "Matsushita Electric Industrial Co., Ltd." The application date is March 26, 2004, the application number is 200480016352.0, and the invention name is "air cleaner, functional filter and its manufacturing method, air cleaning filter and devices” application.

技术领域 technical field

本发明有关可以降低螨及花粉等引起的变态反应原的空气清洁机。此外,本发明还有关空气中或水中浮游微粒子捕捉过滤片及其制造方法,以及有关控制捕捉的微粒子物质有害性的功能性过滤片及其简便制造方法。另外,本发明,还有关空气中及水中浮游微粒子的捕捉过滤片及其装置,以及有关控制捕捉的微粒子物质有害性的空气清洁过滤片及其用途。The present invention relates to an air cleaner capable of reducing allergens caused by mites and pollen. In addition, the present invention relates to a filter sheet for trapping floating particulate matter in air or water and a manufacturing method thereof, and to a functional filter sheet for controlling harmfulness of captured particulate matter and a simple manufacturing method thereof. In addition, the present invention also relates to a filter for capturing floating particulate matter in the air and water and its device, and an air cleaning filter for controlling the harmfulness of captured particulate matter and its use.

背景技术 Background technique

现在,作为这种空气清洁机,众所周知有从前面吸入污染空气从上面吹出清洁空气的空气清洁机(例如,特公昭63-45607号公报的第2页~第3页,参照图4)。以下参照图6说明该空气清洁机。At present, as such an air cleaner, there is known an air cleaner that sucks polluted air from the front and blows clean air from above (for example, pages 2 to 3 of Japanese Patent Publication No. 63-45607, see FIG. 4 ). This air cleaner will be described below with reference to FIG. 6 .

如图6所示,前面有吸入口101,上面设置了朝向上方的吹出口102,由内部收容了送风装置103的本体壳104和设在吸入口101上的过滤片105构成。As shown in FIG. 6 , there is a suction port 101 on the front, and an upward blowing port 102 is provided on the top.

此外,关于可以降低螨及花粉等变态反应原的变态反应原降低剂,这是大家众所周知的(例如,特开2003-81727号公报的[0033],参照表1)。In addition, allergen reducing agents capable of reducing allergens such as mites and pollen are well known (for example, [0033] of JP-A-2003-81727, see Table 1).

在这种现有的空气清洁机的构成中,把吸入口101设在本体壳104略微前面的整个面上,由于是从上面吹出口102吹出到上方,所以可以从本体壳104前面的吸入口101吸入香烟的烟及浮游粉尘并收集到过滤片105中,但是却难以吸入落在室内地面上的花粉以及包含在棉类等灰尘中的螨的尸体及粪等,当因人走动等引起地面上的灰尘飞扬时,对人体产生不良影响,即使收集到过滤片105时也存在着不能完全进行非活性化的课题。In the composition of this existing air cleaner, the suction port 101 is located on the entire surface slightly in front of the body shell 104, and since it is blown out from the top blowing port 102 to the top, it can be blown out from the suction port 104 front of the body shell 104. 101 Inhale cigarette smoke and floating dust and collect them in the filter sheet 105, but it is difficult to inhale pollen falling on the indoor floor and mite corpses and feces contained in dust such as cotton, etc. When the ground is caused by people walking, etc. When the dust on the surface is flying, it will have a bad effect on the human body, and even if it is collected on the filter sheet 105, there is a problem that it cannot be completely deactivated.

此外,现在这种过滤片对螨、花粉、细菌、霉、病毒等浮游有害物质进行过滤和过滤片捕捉。这种过滤片,作为对具有螨及花粉等变态反应原性的蛋白质、或者细菌及病毒等有害物质进行捕捉,并使捕捉的有害物质进行非活性化的过滤片,正在试图推广应用于空气清洁机及换气装置中。In addition, this filter currently filters and captures harmful substances floating in the air such as mites, pollen, bacteria, mold, and viruses. This kind of filter is trying to be widely used in air cleaning as a filter that captures allergenic proteins such as mites and pollen, or harmful substances such as bacteria and viruses, and deactivates the captured harmful substances. machine and ventilator.

可是,使特开2000-5531号公报及特开2003-81727号公报所记载的抗变态反应原剂添附在过滤片而构成的抗变态反应原过滤片单独时只不过具有抗变态反应原作用,存在着为了抗菌和防霉作用及着色等另需进行加工的问题。However, the anti-allergen filter sheet formed by attaching the anti-allergen agent described in the Japanese publication No. 2000-5531 and the Japanese publication No. 2003-81727 only has an anti-allergen effect when it is alone. There is a problem that additional processing is required for antibacterial and antifungal effects, coloring, and the like.

此外,特开2003-33612号公报所记载的变态反应原非活性化方法,是使用不锈钢制面发热体对捕捉的变态反应原物质进行加热,引起蛋白变性以进行非活性化处理。但是,它存在着需要加热机构之类的附带设备和机器,同时非常耗能等问题。In addition, the allergen deactivation method described in JP-A-2003-33612 uses a surface heating element made of stainless steel to heat captured allergens to cause protein denaturation for deactivation. However, it has problems such as requiring ancillary equipment and machines such as a heating mechanism, and being very energy-consuming.

另外,在特开2001-89974号公报中,抗菌性纤维是在纤维表面上用水溶性聚合物固定控制细菌增殖的物质。为了固定,需要使用水溶性聚合物或在水溶液中成为胶乳的聚合物,当在水中混合存在引起沉淀的物质时则不能使用,所以存在着可加工的原材料受到限制的问题。In addition, in Japanese Unexamined Patent Application Publication No. 2001-89974, the antibacterial fiber is a substance immobilized with a water-soluble polymer on the surface of the fiber to control bacterial growth. For fixation, it is necessary to use a water-soluble polymer or a polymer that becomes a latex in an aqueous solution, and it cannot be used when a substance causing precipitation is mixed in water, so there is a problem that the raw materials that can be processed are limited.

因此,本发明的目的是,解决现有的这些问题,提供可以有效地吸入位于地面附近的花粉及螨的尸体等,并且长时间发挥抗过敏特性的空气清洁机。Therefore, the object of the present invention is to solve these conventional problems, and to provide an air cleaner capable of effectively sucking pollen and mite corpses etc. located near the ground, and exhibiting antiallergic properties for a long time.

此外,本发明还有关空气中或水中浮游微粒子捕捉过滤片及其制造方法,目的在于提供控制捕捉的微粒子物质有害性的功能性过滤片及其简便的制造方法。In addition, the present invention also relates to a filter sheet for trapping floating particulate matter in air or water and a manufacturing method thereof, and aims to provide a functional filter sheet capable of controlling the harmfulness of captured particulate matter and a simple manufacturing method thereof.

另外,本发明还有关空气中或水中浮游微粒子捕捉过滤片及其装置,目的在于提供控制捕捉的微粒子物质有害性的空气清洁过滤片及其用途。In addition, the present invention also relates to a filter for trapping floating particulate matter in the air or water and its device, and aims to provide an air cleaning filter and its use for controlling the harmfulness of captured particulate matter.

发明内容 Contents of the invention

本发明,为解决上述现有的课题,形成吸入口和吹出口,并具备在内部设置送风机构的本体和被配设在设于该本体内的送风机构的空气通道上的具备芳香族羟基化合物的抗变态反应原过滤片,为了把设于上述本体的吸入口沿地面以形成吸入空气流而设在前面下方部。The present invention, in order to solve the above-mentioned existing problems, forms a suction port and an air outlet, and is equipped with a main body with an air blowing mechanism inside and an aromatic air blower arranged on the air passage of the air blowing mechanism in the main body. The anti-allergen filter of hydroxy compound is arranged at the front lower part in order to form the suction airflow along the ground to form the suction port arranged on the above-mentioned main body.

此外,由聚4乙烯酚构成芳香族羟基化合物。In addition, the aromatic hydroxy compound is composed of polyvinylphenol.

另外,吹出口设在本体的两侧面。In addition, the air outlet is provided on both sides of the main body.

还有,设置设于本体下方部的灰尘传感器,以及做成利用该灰尘传感器检测到灰尘时上述本体自动进行运转的构成。In addition, a dust sensor is provided at the lower part of the main body, and the above-mentioned main body is configured to automatically operate when dust is detected by the dust sensor.

再有,在本体的侧面设置辅助吸入口。Furthermore, an auxiliary suction port is provided on the side of the main body.

再者,在设于本体侧面上的辅助吸入口的前方,为了不能从前方侧直视上述辅助吸入口而设置了从上述本体侧面突出的屏蔽部。Furthermore, in front of the auxiliary suction port provided on the side surface of the main body, a shielding portion protruding from the side surface of the main body is provided so that the auxiliary suction port cannot be seen directly from the front side.

此外,具备设在本体内部的除臭过滤片和设在上述本体上部的气体传感器,并做成利用上述气体传感器检测到气体时,上述本体将自动进行运转的构成。In addition, a deodorizing filter provided inside the main body and a gas sensor provided on the upper part of the main body are provided, and the main body is configured to automatically operate when gas is detected by the gas sensor.

解决上述课题的本发明的处理液,其特征在于,使水溶性材料和非水溶性材料溶解及/或分散到水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中进行调制。The treatment solution of the present invention that solves the above-mentioned problems is characterized in that a water-soluble material and a water-insoluble material are dissolved and/or dispersed in a mixed solvent of water and celluloids and/or ethoxyethanols. .

此外,其特征在于,水溶性材料和非水溶性材料,混合了从具有抗菌性的原材料、具有防霉性的原材料、具有抗病毒性的原材料、具有抗变态反应原性的原材料、作为着色剂使用的原材料以及具有吸湿性的原材料中选择的两个以上的原材料。In addition, it is characterized in that the water-soluble material and the water-insoluble material are mixed from raw materials having antibacterial properties, raw materials having antifungal properties, raw materials having antiviral properties, raw materials having antiallergenic properties, as a coloring agent Two or more raw materials selected from the raw materials used and hygroscopic raw materials.

另外,其特征在于,水溶性材料是儿茶素类。In addition, it is characterized in that the water-soluble material is catechins.

还有,其特征在于,非水溶性材料是具有高分子酚性氢氧基的高分子抗变态反应原剂。Also, it is characterized in that the water-insoluble material is a polymeric antiallergic agent having a polymeric phenolic hydroxyl group.

再有,其特征在于,水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中所包含的赛璐索芙类及/或乙氧基乙醇类的比率(容量比)在20%至99%之间。Furthermore, it is characterized in that the ratio (volume ratio) of the celluloids and/or ethoxyethanols contained in the mixed solvent of water and celluloids and/or ethoxyethanols is 20 % to 99%.

再者,本发明的功能性过滤片的制造方法,其特征在于,把上述的处理液添附在过滤片基材上后进行干燥。Furthermore, the method for producing a functional filter of the present invention is characterized in that the above-mentioned treatment liquid is applied to the filter substrate and then dried.

再者,其特征在于,把上述处理液涂布在过滤片空隙率较高的部分上后进行干燥。Furthermore, it is characterized in that the treatment liquid is applied to a portion of the filter having a high porosity and then dried.

再者,本发明的功能性过滤片的制造方法,其特征在于,纤维原料浸渍在上述处理液中,并把干燥后得到的纤维加工成过滤片形状。Furthermore, the method for producing a functional filter according to the present invention is characterized in that the fiber raw material is immersed in the treatment liquid, and the dried fiber is processed into a filter shape.

再者,其特征在于,干燥温度在150℃以下。Furthermore, it is characterized in that the drying temperature is below 150°C.

再者,其特征在于,本发明的功能性过滤片,由上述方法制造。Furthermore, it is characterized in that the functional filter sheet of the present invention is manufactured by the above-mentioned method.

再者,本发明的加湿过滤片,其特征在于,把上述处理液涂布在由吸水性过滤片基材制成的过滤片上。Furthermore, the humidification filter of the present invention is characterized in that the treatment liquid is applied to a filter made of a water-absorbing filter base material.

再者,本发明的装置,其特征在于,把上述功能性过滤片及/或上述加湿过滤片配置在空气的吸入口和吹出口之间。Furthermore, the device of the present invention is characterized in that the functional filter and/or the humidification filter are arranged between the air inlet and outlet.

再者,其特征在于,在过滤片的后段设置吸尘过滤片。Furthermore, it is characterized in that a dust-absorbing filter is arranged at the back stage of the filter.

再者,其特征在于,装置是空气清洁装置、换气装置、加湿装置、加温装置、除湿装置、被褥干燥器和空调中任何一个。Furthermore, it is characterized in that the device is any one of an air cleaning device, a ventilation device, a humidifying device, a heating device, a dehumidifying device, a quilt dryer and an air conditioner.

再者,本发明的水处理装置,其特征在于,把上述功能性过滤片及/或上述加湿过滤片配置在水的吸入口和排出口之间。Furthermore, the water treatment device of the present invention is characterized in that the functional filter and/or the humidification filter are arranged between the water suction port and the water discharge port.

再者,其特征在于,把上述处理液涂布在本体的外框表面上。Furthermore, it is characterized in that the above treatment liquid is applied to the outer frame surface of the main body.

再者,本发明的面罩,其特征在于,由上述功能性过滤片构成。Furthermore, the mask of the present invention is characterized in that it is composed of the above-mentioned functional filter sheet.

再者,本发明的功能性过滤片,其特征在于,使用含有作为着色剂使用的原材料的处理液进行着色。Furthermore, the functional filter sheet of the present invention is characterized in that it is colored using a treatment liquid containing a raw material used as a colorant.

再者,本发明的装置,其特征在于,使用含有作为着色剂使用的原材料的处理液进行着色。Furthermore, the apparatus of the present invention is characterized in that coloring is performed using a treatment liquid containing a raw material used as a colorant.

解决上述课题的本发明的空气清洁过滤片,其特征在于,添附了从具有抗变态反应原性的原材料、具有抗菌性的原材料、具有抗病毒性的原材料、具有防霉性的原材料中选择的两个以上的原材料。The air-cleaning filter of the present invention that solves the above-mentioned problems is characterized in that it contains a material selected from materials having antiallergenic properties, materials having antibacterial properties, materials having antiviral properties, and materials having antifungal properties. More than two raw materials.

此外,其特征在于,具有抗变态反应原性的原材料,是具有高分子酚性氢氧基的抗变态反应原剂。In addition, it is characterized in that the raw material having antiallergenic properties is an antiallergenic agent having a polymeric phenolic hydroxyl group.

另外,其特征在于,作为具有抗病毒性的原材料包含儿茶素类。In addition, it is characterized in that catechins are included as raw materials having antiviral properties.

还有,其特征在于,作为具有抗菌性的原材料包含酵素类。In addition, it is characterized in that enzymes are contained as raw materials having antibacterial properties.

再有,其特征在于,使用作为着色剂使用的原材料进行着色。Furthermore, it is characterized in that it is colored using a raw material used as a colorant.

再者,其特征在于,向空气清洁过滤片添附的原材料的添附量在0.1至10g/m2的范围。Furthermore, it is characterized in that the amount of the raw material added to the air cleaning filter is in the range of 0.1 to 10 g/m 2 .

再者,其特征在于,原材料被涂布在过滤片空隙率较高的部分上。Furthermore, it is characterized in that the raw material is coated on a portion of the filter having a higher porosity.

再者,本发明的装置,其特征在于,把上述空气清洁过滤片配置在空气的吸入口和吹出口之间。Furthermore, the device of the present invention is characterized in that the above-mentioned air cleaning filter is disposed between the air suction port and the air discharge port.

再者,其特征在于,在空气清洁过滤片的后段设置吸尘过滤片。Furthermore, it is characterized in that a dust-absorbing filter is provided behind the air-cleaning filter.

再者,其特征在于,装置是空气清洁装置、换气装置、加湿装置、加温装置、除湿装置、被褥干燥器和空调中任何一个。Furthermore, it is characterized in that the device is any one of an air cleaning device, a ventilation device, a humidifying device, a heating device, a dehumidifying device, a quilt dryer and an air conditioner.

再者,本发明的面罩,其特征在于,由上述空气清洁过滤片构成。Furthermore, the mask of the present invention is characterized in that it is composed of the above-mentioned air cleaning filter.

附图简单说明Brief description of the drawings

图1是表示本发明空气清洁机构成的纵剖面图。Fig. 1 is a longitudinal sectional view showing the structure of the air cleaner of the present invention.

图2是从该空气清洁机右侧看的立体图。Fig. 2 is a perspective view seen from the right side of the air cleaner.

图3是从该空气清洁机左侧看的立体图。Fig. 3 is a perspective view seen from the left side of the air cleaner.

图4是表示该空气清洁机送风机构构成的剖面图。Fig. 4 is a cross-sectional view showing the structure of the blower mechanism of the air cleaner.

图5是表示该空气清洁机辅助吸入口和屏蔽部关系的横剖面图。Fig. 5 is a cross-sectional view showing the relationship between the auxiliary suction port and the shielding portion of the air cleaner.

图6是现有的空气清洁机的剖面图。Fig. 6 is a sectional view of a conventional air cleaner.

图7是表示实施例5中的处理液总添附量和吸尘效率关系的图。7 is a graph showing the relationship between the total amount of treatment liquid added and dust collection efficiency in Example 5. FIG.

图8是实施例6中的空气清洁装置的概略剖面图。Fig. 8 is a schematic sectional view of an air cleaning device in Example 6.

图9是实施例7中的换气装置的概略剖面图。9 is a schematic sectional view of a ventilator in Example 7. FIG.

图10是实施例8中的面罩的概略图。FIG. 10 is a schematic diagram of a mask in Example 8. FIG.

图11是实施例9中的加湿装置的概略剖面图。Fig. 11 is a schematic sectional view of a humidifier in Example 9.

图12是实施例10中的加湿装置或被褥干燥器的概略剖面图。Fig. 12 is a schematic cross-sectional view of a humidifier or futon dryer in Embodiment 10.

图13是实施例11中的空调的概略剖面图。Fig. 13 is a schematic sectional view of the air conditioner in Embodiment 11.

具体实施方式 Detailed ways

本发明第一部分所述的内容,通过形成吸入口和吹出口,并具备在内部设置送风机构的本体和被配设在设于该本体内的送风机构的空气通道上的具备芳香族羟基化合物的抗变态反应原过滤片,为了把设于上述本体的吸入口沿地面以形成吸入空气流而设在前面下方部,因此具有地面上或从地面飞扬的花粉及螨的尸体等可以有效地吸进吸入口,通过抗变态反应原过滤片使过敏活性非活性化的作用。According to the content described in the first part of the present invention, by forming the suction port and the blowing port, and having a body with an air blowing mechanism inside, and an aromatic hydroxyl The anti-allergen filter of the compound is arranged at the front lower part in order to form the suction port of the above-mentioned main body along the ground to form the suction air flow, so pollen and mite corpses etc. which are flying on the ground or from the ground can be effectively removed. Aspirated into the inhalation port, the action of allergenic activity is deactivated by the anti-allergen filter.

本发明第二部分所述的内容,通过由聚4乙烯酚构成芳香族羟基化合物,因此具有即使过滤片上附着水分也可以发挥长期稳定的抗过敏效果的作用。According to the content of the second part of the present invention, since the aromatic hydroxy compound is composed of poly(4-vinylphenol), it has the effect of exerting a long-term stable antiallergic effect even if moisture adheres to the filter.

本发明第三部分所述的内容,通过把吹出口设在本体的两侧面,因此具有从本体侧面吹出的气流,沿着房间壁面流动循环,把包含有在地面附近浮游的变态反应原物质的灰尘等引导到吸入口的作用。According to the content described in the third part of the present invention, by setting the air outlet on both sides of the main body, the air flow blown from the side of the main body will flow and circulate along the wall of the room, and the allergens containing the allergens floating near the ground will be discharged. Dust, etc. are guided to the suction port.

本发明第四部分所述的内容,通过设置设于本体下方部的灰尘传感器,以及做成利用该灰尘传感器检测到灰尘时上述本体自动进行运转的构成,因此可以用灰尘传感器立刻检测出伴随人的移动等而飞扬的灰尘等并及时地使空气清洁机运转。According to the content described in the fourth part of the present invention, by setting the dust sensor located at the lower part of the main body, and making the above-mentioned main body automatically operate when dust is detected by the dust sensor, it is possible to immediately detect the accompanying person with the dust sensor. The movement of the air and other flying dust, etc., and make the air cleaner run in a timely manner.

本发明第五部分所述的内容,通过在本体的侧面设置辅助吸入口,并且通过不仅从本体前面侧,而且从侧面侧吸入,因此可以在较大范围内吸收室内飞扬的灰尘等,从而可以进一步减少室内的过敏物质。According to the content of the fifth part of the present invention, by setting the auxiliary suction port on the side of the main body, and by sucking in not only from the front side of the main body, but also from the side side, it is possible to absorb the flying dust in the room in a wide range, so that the Further reduce indoor allergens.

本发明第六部分所述的内容,通过在设于本体侧面上的辅助吸入口的前方,为了不能从前方侧直视上述辅助吸入口而设置从上述本体侧面突出的屏蔽部,因此可以用屏蔽部对从辅助吸入口发生的噪音进行隔音,同时可以做成不能从前方直视容易污染的辅助吸入口以提高设计性。According to the content described in the sixth part of the present invention, a shielding part protruding from the side of the body is provided in front of the auxiliary suction port provided on the side of the body so that the auxiliary suction port cannot be directly viewed from the front side, so the shielding part can be used. The noise generated from the auxiliary suction port is sound-proofed at the bottom, and at the same time, the auxiliary suction port that is easy to be polluted cannot be directly seen from the front to improve design.

本发明第七部分所述的内容,通过具备设在本体内部的除臭过滤片和设在上述本体上部的气体传感器,并做成利用上述气体传感器检测出气体时,上述本体将自动进行运转的构成,因此可以利用设在本体上部的气体传感器立刻检测容易扩散到上方的气体成分,并及时地使空气清洁机进行运转,从而可以有效地去除香烟气味及氨气臭味等。The content described in the seventh part of the present invention is provided with a deodorizing filter installed inside the main body and a gas sensor arranged on the upper part of the above-mentioned main body, and when gas is detected by the above-mentioned gas sensor, the above-mentioned main body will automatically operate Therefore, the gas sensor on the upper part of the main body can be used to immediately detect the gas components that are easy to diffuse upward, and the air cleaner can be operated in time, so that the smell of cigarettes and ammonia can be effectively removed.

本发明的功能性过滤片的制造方法,其特征在于,使水溶性材料和非水溶性材料溶解及/或分散到水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中进行调制,把调制后的处理液涂布在过滤片上后进行干燥。由于使用水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒,所以不会发生水溶性材料和赛璐索芙类溶媒及/或乙氧基乙醇类、或者非水溶性材料和水混合时产生的沉淀,从而可以调制使水溶性材料和非水溶性材料溶解及/或分散的处理液。通过把处理液涂布在过滤片上后使之干燥,可以用一次加工使水溶性材料和非水溶性材料添附在过滤片上。The method for producing the functional filter sheet of the present invention is characterized in that the water-soluble material and the water-insoluble material are dissolved and/or dispersed in a mixed solvent of water and celluloids and/or ethoxyethanols. For preparation, apply the prepared treatment solution on a filter plate and then dry it. Since a mixed solvent of water and celluloids and/or ethoxyethanols is used, water-soluble materials and celluloids and/or ethoxyethanols, or non-water-soluble materials and Precipitation generated when water is mixed can prepare a treatment liquid for dissolving and/or dispersing water-soluble and water-insoluble materials. By coating the treatment liquid on the filter and drying it, the water-soluble material and the water-insoluble material can be attached to the filter in one process.

作为赛璐索芙类,可以举出乙基赛璐索芙、丁基赛璐索芙、赛璐索芙醋脂等,最好具有烷基,特别理想的是具有丁基的丁基赛璐索芙。乙氧基乙醇类,可以举出甲基乙氧基乙醇、乙基乙氧基乙醇、丁基乙氧基乙醇、丁基乙氧基乙醇醋脂、乙氧基乙醇醋脂、醋酸乙氧基乙醇等,最好具有烷基,特别理想的是具有丁基的丁基乙氧基乙醇。Examples of celluloids include ethyl celluloid, butyl celluloid, and celluloid acetate, preferably having an alkyl group, particularly preferably butyl celluloid having a butyl group. soph. Ethoxyethanols include methyl ethoxyethanol, ethyl ethoxyethanol, butyl ethoxyethanol, butyl ethoxyethanol acetate, ethoxyethanol acetate, ethoxy acetate Ethanol and the like preferably have an alkyl group, and butyl ethoxyethanol having a butyl group is particularly preferable.

虽然并未特别限定水和赛璐索芙类及/或乙氧基乙醇类的混合比例,但是赛璐索芙类及/或乙氧基乙醇类的混合比率(体积比率)最好在20%至99%的范围,为25%至60%则更好。在不超过水和赛璐索芙类及/或乙氧基乙醇类的总量的范围内,也可以把乙基乙醇及异丙醇等低级乙醇类、乙二醇及丙三醇等多价乙醇类、丙酮等单独或者多种组合进行混合。Although the mixing ratio of water and celluloids and/or ethoxyethanols is not particularly limited, the mixing ratio (volume ratio) of celluloids and/or ethoxyethanols is preferably 20% 99% range, 25% to 60% is better. Within the range not exceeding the total amount of water and celluloids and/or ethoxyethanols, lower alcohols such as ethyl alcohol and isopropanol, polyvalent alcohols such as ethylene glycol and glycerin, etc. Ethanol, acetone, etc. are mixed alone or in combination.

作为被溶解及/或分散到水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中的水溶性材料和非水溶性材料,可以举出具有抗菌性的原材料、具有防霉性的原材料、具有抗病毒性的原材料、具有抗变态反应原性的原材料、作为着色剂使用的原材料以及具有吸湿性的原材料等。水溶性材料及非水溶性材料的含量最好为10%至40%,为10%至20%则更好。Examples of the water-soluble and water-insoluble materials to be dissolved and/or dispersed in a mixed solvent of water and celluloids and/or ethoxyethanols include materials with antibacterial properties, mold-proof raw materials, anti-viral raw materials, anti-allergenic raw materials, raw materials used as colorants and hygroscopic raw materials, etc. The content of the water-soluble material and the water-insoluble material is preferably 10% to 40%, more preferably 10% to 20%.

作为上述具有抗菌性的原材料,可以举出溶解银·铜·锌等金属离子的无机化合物,银·铜·锌金属微粒子,碘化合物类、酚类、季铵盐类、咪唑化合物类、安息香酸类、过氧化氢、甲酚、洗必泰、氯苯酚、醛类、山梨酸等试剂及溶菌酶·纤维素酶·蛋白酶等酵素制剂,儿茶素类、竹提取物、柏提取物、山葵提取物、辣椒提取物等天然成分提取物等。Examples of the antibacterial material include inorganic compounds that dissolve metal ions such as silver, copper, and zinc, silver, copper, and zinc metal fine particles, iodine compounds, phenols, quaternary ammonium salts, imidazole compounds, and benzoic acid. Hydrogen peroxide, cresol, chlorhexidine, chlorophenol, aldehydes, sorbic acid and other reagents and enzyme preparations such as lysozyme cellulase protease, catechins, bamboo extract, cypress extract, wasabi extracts, pepper extracts and other natural ingredient extracts, etc.

作为上述具有防霉性的原材料,可以举出有机氮化合物·硫磺系化合物,有机酸酯类,有机碘系咪唑化合物,ベンザゾ一ル化合物等。Examples of the above-mentioned raw materials having antifungal properties include organic nitrogen compounds and sulfur-based compounds, organic acid esters, organic iodine-based imidazole compounds, Benzazol compounds, and the like.

作为上述具有抗病毒性的原材料,可以举出溶解银·铜·锌等金属离子的无机化合物,银·铜·锌金属微粒子,低级乙醇类,儿茶素类,桧醇等。Examples of the antiviral material include inorganic compounds in which metal ions such as silver, copper, and zinc are dissolved, silver, copper, and zinc metal fine particles, lower alcohols, catechins, hinokitiol, and the like.

作为儿茶素类,表儿茶酸(エピガロカテキンガレ一ド、エピカテキンガレ一ド、エピガロカテキン、(+)儿茶素及它们的属性体)、茶黄素(游离型テアフラビン、エアフラビンモノガレ一ドA、エアフラビンモノガレ一ドB以及エアフラビンジガレ一ド)等比较有效,可以从绿茶·红茶·柿子等提取成分而获得。As catechins, epicatechin (Epigalocatechingared, Epigalocatechingared, Epigalocatechin, (+) catechin and their attributes), theaflavins (free type Teafrabin, Eya Flabin Monogared A, Eafrabin Monogared B, and Eafrabin Jigared) are relatively effective, and can be obtained by extracting components from green tea, black tea, persimmon, and the like.

作为上述具有抗变态反应原性的原材料,可以举出单宁酸、羟安息香酸系化合物、芳香族羟基化合物、或者其盐、或者其聚合体、碱金属的碳酸盐、明矾、月桂苯磺酸盐、月桂硫酸盐、聚氧乙烯十二酯醚硫酸盐、儿茶素类等。此外,作为蛋白性变态反应原物质,有螨的尸体、粪或这些粉碎物、或者花粉、细菌、霉、宠物排泄物及其他蛋白屑等。Examples of the aforementioned antiallergenic raw materials include tannic acid, hydroxybenzoic acid-based compounds, aromatic hydroxy compounds, or salts thereof, or polymers thereof, carbonates of alkali metals, alum, laurylbenzenesulfonate, etc. salt, lauryl sulfate, polyoxyethylene lauryl ether sulfate, catechins, etc. In addition, as proteinaceous allergen substances, there are mite corpses, feces, or these crushed materials, or pollen, bacteria, mold, pet excrement, and other protein debris.

作为上述作为着色剂使用的原材料,可以使用在水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中不产生沉淀及相分离等不良情况的众所周知的颜料及染料。作为颜料,可以举出偶氮系、多偶氮系、蒽醌系、芥子喹丫因系(キナクリドン系)、异吲哚系、异吲哚满系、酞菁系、二萘嵌苯系、DPP系、荧光颜料等有机颜料以及碳黑、合成二氧化硅、氧化铬、氧化铁、氧化钛、烧制颜料、硫化锌等无机颜料。作为染料,可以举出乙醇可溶性染料、油溶性染料、荧光染料、聚光性染料等。As the raw materials used as the above-mentioned coloring agent, well-known pigments and dyes that do not cause problems such as precipitation and phase separation in a mixed solvent of water and celluloids and/or ethoxyethanols can be used. Examples of pigments include azo-based, polyazo-based, anthraquinone-based, quinacrydon-based (kinacridon-based), isoindole-based, isoindoline-based, phthalocyanine-based, perylene-based, Organic pigments such as DPP series and fluorescent pigments, and inorganic pigments such as carbon black, synthetic silica, chromium oxide, iron oxide, titanium oxide, fired pigments, and zinc sulfide. Examples of the dye include ethanol-soluble dyes, oil-soluble dyes, fluorescent dyes, and light-gathering dyes.

作为上述具有吸湿性的原材料,除了聚醚-酯系聚合物、聚醚-酯酰胺系聚合物、聚乙烯吡咯烷酮系聚合物、聚氧乙烯交联物等吸湿性聚合物外,还可以举出硅烷偶合剂系交联物、硅胶及泡沸石等各种无机化合物等。此外,混合具有潮解性的阳离子·阴离子·非离子系的界面活性剂也是有效的。Examples of the aforementioned hygroscopic raw materials include hygroscopic polymers such as polyether-ester polymers, polyether-ester amide polymers, polyvinylpyrrolidone-based polymers, and polyoxyethylene cross-linked products. Silane coupling agent is a cross-linked product, various inorganic compounds such as silica gel and zeolite, etc. In addition, it is also effective to mix a deliquescent cationic, anionic, and nonionic surfactant.

上述处理液向过滤片基材涂布的涂布方法,可以举出浸泡法、喷涂法、凹版印刷法等,可以根据作为对象的过滤片基材的厚度及表面润湿性适当地选择。涂布处理液的过滤片基材,可以使用把无纺织布剪成希望大小的过滤片基材、以及用粘合剂及热融粘合成形为希望大小的过滤片基材及树脂制蜂窝形状过滤片基材等。也可以把纤维原料浸渍在处理液进行干燥以得到纤维并对该纤维进行纺丝,然后用编织方法加工成过滤片形状。The coating method for applying the treatment liquid to the filter substrate includes immersion method, spray method, gravure printing method, etc., and can be appropriately selected according to the thickness and surface wettability of the target filter substrate. The filter base material for coating the treatment liquid can be a filter base material cut into a desired size from a non-woven fabric, a filter base material formed into a desired size with an adhesive or hot-melt bonding, and a resin honeycomb shape. Filter substrates, etc. It is also possible to immerse the fiber raw material in a treatment liquid and dry it to obtain a fiber, spin the fiber, and then process it into a filter shape by a weaving method.

作为本发明的功能性过滤片基材的材质,虽然可以举出聚丙烯、聚乙烯、聚酯、聚酰胺等有机系纤维和玻璃、硅酸镁、氧化铝等无机系纤维、棉等天然纤维、纸、树脂渗透纸等,但是只要是与处理液反应不发生溶解和变形等的材质,则没有特别限定。此外,只要像泡沫尿烷、泡沫苯乙烯等泡沫树脂,泡沫铝、泡沫钛、泡沫铁等泡沫金属类那样,可以流通空气的具有连续的气孔的话,同样可以使用。As the material of the functional filter substrate of the present invention, organic fibers such as polypropylene, polyethylene, polyester, and polyamide, inorganic fibers such as glass, magnesium silicate, and alumina, and natural fibers such as cotton can be mentioned. , paper, resin-impregnated paper, etc., but there is no particular limitation as long as it is a material that does not dissolve or deform when it reacts with the treatment liquid. In addition, as long as it has continuous pores that allow air to flow, such as foamed resin such as foamed urethane and foamed styrene, and foamed metal such as foamed aluminum, titanium foam, and iron foam, it can also be used.

本发明的功能性过滤片的干燥方法,既可以是自然干燥,也可以是加热,亦可以是减压使溶剂蒸发的方法。但是,高温下的干燥,由于担心伴随过滤片纤维的收缩引起变形及处理液中的原材料发生变质,所以最好温度在150℃以下,为100℃以下则更好。The drying method of the functional filter of the present invention can be either natural drying, heating, or a method of evaporating the solvent under reduced pressure. However, in drying at high temperature, the temperature is preferably below 150° C., more preferably below 100° C., due to fear of deformation due to shrinkage of the filter fiber and deterioration of raw materials in the treatment liquid.

本发明的功能性过滤片,由于在过滤片中添附了从具有抗菌性的原材料、具有防霉性的原材料、具有抗病毒性的原材料、具有抗变态反应原性的原材料、作为着色剂使用的原材料以及具有吸湿性的原材料中选择的两个以上的原材料,所以可以把在空气中或水中浮游的螨·花粉·细菌·霉·病毒等浮游有害物质过滤、并进行过滤片捕捉,使捕捉的有害物质非活性化。添附的原材料可以根据希望捕捉并进行非活性化的物质进行适当选择。The functional filter sheet of the present invention is due to the addition of antibacterial raw materials, mildew-proof raw materials, antiviral raw materials, anti-allergenic raw materials, and used as colorants in the filter sheet. Two or more raw materials selected from raw materials and hygroscopic raw materials, so it is possible to filter floating harmful substances such as mites, pollen, bacteria, mold, viruses floating in the air or water, and capture them with filters, so that the captured Hazardous substances are deactivated. The raw material to be added can be appropriately selected according to the substance to be captured and deactivated.

此外,通过在处理液中同时混合着色剂,可以使过滤片在视觉上没有异样感,并且可以得到在色彩方面可以进行自由创造设计的效果。In addition, by mixing the coloring agent with the treatment liquid, the filter can be visually unobtrusive, and the effect of freely creating and designing the color can be obtained.

进而,由于通过同时混合具有吸湿性的原材料,可以使空气中的水分凝缩在过滤片上,所以可以有效地溶解具有抗菌·防霉·抗变态反应原·抗病毒作用的有效成分,与有害物质接触,使有害物质非活性化。Furthermore, by mixing hygroscopic raw materials at the same time, moisture in the air can be condensed on the filter, so active ingredients with antibacterial, antifungal, antiallergen, and antiviral effects can be effectively dissolved, and harmful substances can be dissolved. Contact will inactivate harmful substances.

当本发明的过滤片基材的密度非均匀,有空隙率高的部分和低的部分时,希望在高的部分上涂布处理液。这里,所谓空隙率是指单位体积的重量大小,空隙率越大过滤片纤维间的间隙越大。通过在空隙率高的部分上进行处理,可以控制过滤片压力损失的上升,同时可以得到提高有害物质捕捉效率的作用。When the density of the filter base material of the present invention is non-uniform, and there are parts with high porosity and parts with low porosity, it is desirable to coat the treatment liquid on the high parts. Here, the so-called porosity refers to the weight per unit volume, and the larger the porosity, the larger the gap between the fibers of the filter sheet. By treating the portion with a high porosity, the increase in pressure loss of the filter can be suppressed, and at the same time, the effect of improving the efficiency of capturing harmful substances can be obtained.

本发明的功能性过滤片,既可以单独使用具有上述效果的添附过滤片,也可以在后段设置网眼更细的吸尘过滤片。在后段使用网眼更细的吸尘过滤片时,为了使过滤片具有强度可以对它们单个进行粘合。通过通风,添附过滤片和吸尘过滤片进行物理性接触时,也可以只使两者重合。The functional filter of the present invention can be used alone as an additional filter having the above effects, or can be provided with a dust-absorbing filter with a finer mesh at the rear. When using a dust suction filter with a finer mesh in the latter stage, they can be bonded individually in order to make the filter stronger. When the additional filter and the suction filter are in physical contact through ventilation, it is also possible to only overlap the two.

以上制造的功能性过滤片,例如配置在空气清洁装置及换气装置及加湿装置及加温装置等的空气的吸入口和吹出口之间使用。利用这些装置,可以净化室内的空气,得到预防霉菌病·细菌感染·流感等病毒感染的作用。The functional filter sheet manufactured above is used, for example, to be arranged between air inlets and air outlets of air cleaning devices, ventilation devices, humidifiers, heating devices, and the like. These devices can purify indoor air and prevent viral infections such as mold disease, bacterial infection, and influenza.

此外,通过把以上制造的功能性过滤片设置在面罩的局部或者整个通风部上,可以防止螨·花粉·细菌·霉·病毒等浮游有害物质被吸入人体,得到预防霉菌病·细菌感染·流感等病毒感染的作用。In addition, by placing the above-made functional filter on a part or the entire ventilation part of the mask, it is possible to prevent floating harmful substances such as mites, pollen, bacteria, mold, and viruses from being inhaled into the human body, and to obtain protection against mycoses, bacterial infections, and influenza. and other viral infections.

本发明的加湿过滤片,在吸水性过滤片基材上添附了从具有抗菌性的原材料、具有防霉性的原材料、具有抗病毒性的原材料、具有抗变态反应原性的原材料、作为着色剂使用的原材料以及具有吸湿性的原材料中选择的两个以上的原材料。通过把吸水性过滤片基材的一部分浸渍在水中,或者从上部供应水,可以对通过过滤片的空气进行加湿外,还可以把在空气中及水中浮游的螨·花粉·细菌·霉·病毒等浮游有害物质过滤、并进行过滤片捕捉,使捕捉的有害物质非活性化。添附的原材料可以根据希望捕捉并进行非活性化的物质进行适当选择。此外,通过同时混合着色剂,可以使过滤片在视觉上没有异样感,并且可以得到在色彩方面可以进行自由创造设计的效果。In the humidifying filter of the present invention, materials having antibacterial properties, antifungal properties, antiviral properties, antiallergenic properties, and coloring agents are added to the water-absorbing filter base material. Two or more raw materials selected from the raw materials used and hygroscopic raw materials. By immersing a part of the base material of the water-absorbing filter in water, or supplying water from above, the air passing through the filter can be humidified, and mites, pollen, bacteria, mold, and viruses floating in the air and water can be removed. Such as floating harmful substances are filtered and captured by the filter sheet to inactivate the captured harmful substances. The raw material to be added can be appropriately selected according to the substance to be captured and deactivated. In addition, by mixing colorants at the same time, it is possible to make the filter visually unobtrusive, and it is possible to obtain the effect of freely creating design in terms of color.

本发明的空气清洁过滤片,由于在过滤片中添附了从具有抗变态反应原性的原材料、具有抗菌性的原材料、具有抗病毒性的原材料、具有防霉性的原材料中选择的一个以上的原材料,所以可以把在空气中浮游的螨·花粉·细菌·霉·病毒等浮游有害物质过滤、并进行过滤片捕捉,使捕捉的有害物质非活性化。添附的原材料可以根据希望捕捉并进行非活性化的物质进行适当选择。The air-cleaning filter sheet of the present invention is due to adding more than one selected from raw materials with antiallergenic properties, raw materials with antibacterial properties, raw materials with antiviral properties, and raw materials with antifungal properties in the filter discs. Therefore, it is possible to filter floating harmful substances such as mites, pollen, bacteria, mold, and viruses floating in the air, and capture them with a filter to inactivate the captured harmful substances. The raw material to be added can be appropriately selected according to the substance to be captured and deactivated.

作为上述具有抗变态反应原性的原材料,可以举出单宁酸、羟安息香酸系化合物、芳香族羟基化合物、或者其盐、或者其聚合体、碱金属的碳酸盐、明矾、月桂苯磺酸盐、月桂硫酸盐、聚氧乙烯十二酯醚硫酸盐、儿茶素类等。此外,作为蛋白性变态反应原物质,有螨的尸体、粪或这些粉碎物、或者花粉、细菌、霉、宠物排泄物及其他蛋白屑等。Examples of the aforementioned antiallergenic raw materials include tannic acid, hydroxybenzoic acid-based compounds, aromatic hydroxy compounds, or salts thereof, or polymers thereof, carbonates of alkali metals, alum, laurylbenzenesulfonate, etc. salt, lauryl sulfate, polyoxyethylene lauryl ether sulfate, catechins, etc. In addition, as proteinaceous allergen substances, there are mite corpses, feces, or these crushed materials, or pollen, bacteria, mold, pet excrement, and other protein debris.

作为上述具有抗病毒性的原材料,可以举出溶解银·铜·锌等金属离子的无机化合物,银·铜·锌金属微粒子,低级乙醇类,儿茶素类,桧醇等。Examples of the antiviral material include inorganic compounds in which metal ions such as silver, copper, and zinc are dissolved, silver, copper, and zinc metal fine particles, lower alcohols, catechins, hinokitiol, and the like.

作为儿茶素类,表儿茶酸(エピガロカテキンガレ一ド、エピカテキンガレ一ド、エピガロカテキン、(+)儿茶素及它们的属性体)、茶黄素(游离型テアフラビン、エアフラビンモノガレ一ドA、エアフラビンモノガレ一ドB以及エアフラビンジガレ一ド)等比较有效,可以从绿茶·红茶·柿子等提取成分而获得。As catechins, epicatechin (Epigalocatechingared, Epigalocatechingared, Epigalocatechin, (+) catechin and their attributes), theaflavins (free type Teafrabin, Eya Flabin Monogared A, Eafrabin Monogared B, and Eafrabin Jigared) are relatively effective, and can be obtained by extracting components from green tea, black tea, persimmon, and the like.

作为上述具有抗菌性的原材料,可以举出溶解银·铜·锌等金属离子的无机化合物,银·铜·锌金属微粒子,碘化合物类、酚类、季铵盐类、咪唑化合物类、安息香酸类、过氧化氢、甲酚、洗必泰、氯苯酚、醛类、山梨酸等试剂及溶菌酶·纤维素酶·蛋白酶等酵素制剂,儿茶素类、竹提取物、柏提取物、山葵提取物、辣椒提取物等天然成分提取物等。Examples of the antibacterial material include inorganic compounds that dissolve metal ions such as silver, copper, and zinc, silver, copper, and zinc metal fine particles, iodine compounds, phenols, quaternary ammonium salts, imidazole compounds, and benzoic acid. Hydrogen peroxide, cresol, chlorhexidine, chlorophenol, aldehydes, sorbic acid and other reagents and enzyme preparations such as lysozyme cellulase protease, catechins, bamboo extract, cypress extract, wasabi extracts, pepper extracts and other natural ingredient extracts, etc.

作为上述具有防霉性的原材料,可以举出有机氮化合物·硫磺系化合物,有机酸酯类,有机碘系咪唑化合物,苯乍硼酸(ベンザゾ一ル)化合物等。Examples of the above-mentioned raw material having antifungal properties include organic nitrogen compounds and sulfur-based compounds, organic acid esters, organic iodine-based imidazole compounds, benzazol compounds, and the like.

向空气清洁过滤片添附的原材料的添附量,过少的话,则不能充分发挥抗变态反应原性·抗菌性·抗病毒性·防霉性等的功能,过多的话,过滤片的压力损失较高,通气性降低,从而不能充分捕捉空气中的有害物质,此外,搭载在装置上时,引起消耗电能增加及噪音发生等问题。添附到过滤片中的添附量最好在0.1至10g/m2的范围,为1至5g/m2则更好。If the amount of raw materials added to the air cleaning filter is too small, the functions of antiallergenicity, antibacterial, antiviral, and mildew resistance cannot be fully exerted, and if it is too large, the pressure loss of the filter will be lower. If the air permeability is high, the harmful substances in the air cannot be sufficiently captured, and when mounted on a device, problems such as increased power consumption and noise generation will occur. The amount added to the filter sheet is preferably in the range of 0.1 to 10 g/m 2 , more preferably 1 to 5 g/m 2 .

上述原材料向过滤片中添附的添附方法,可以举出浸泡法、喷涂法、凹版印刷法等,可以根据作为对象的过滤片的厚度及表面润湿性适当地选择。涂布使原材料溶解及/或分散了的处理液的过滤片基材,可以使用把无纺织布剪成希望大小的过滤片、以及用粘合剂及热融粘合成形为希望大小的过滤片及树脂制蜂窝形状过滤片等。也可以把纤维原料浸渍在处理液进行干燥以得到纤维并对该纤维进行纺丝,然后用编织方法加工成过滤片形状。The method of adding the above-mentioned raw material to the filter includes dipping method, spraying method, gravure printing method, etc., and can be appropriately selected according to the thickness and surface wettability of the target filter. For the filter substrate coated with the treatment liquid in which the raw material is dissolved and/or dispersed, a filter sheet cut into a desired size from a non-woven fabric, and a filter sheet formed into a desired size with an adhesive or thermal fusion can be used And resin honeycomb filter, etc. It is also possible to immerse the fiber raw material in a treatment liquid and dry it to obtain a fiber, spin the fiber, and then process it into a filter shape by a weaving method.

作为添附原材料的过滤片基材的材质,虽然可以举出聚丙烯、聚乙烯、聚酯、聚酰胺等有机系纤维和玻璃、硅酸镁、氧化铝等无机系纤维、棉等天然纤维、纸、树脂渗透纸等,但是只要是与处理液反应不发生溶解和变形等的材质,则没有特别限定。此外,只要像泡沫尿烷、泡沫苯乙烯等泡沫树脂,泡沫铝、泡沫钛、泡沫铁等泡沫金属类那样,可以流通空气的具有连续的气孔的话,同样可以使用。As the material of the filter substrate to which raw materials are attached, organic fibers such as polypropylene, polyethylene, polyester, and polyamide, inorganic fibers such as glass, magnesium silicate, and alumina, natural fibers such as cotton, and paper , resin impregnated paper, etc., but there is no particular limitation as long as it is a material that does not dissolve or deform when it reacts with the treatment liquid. In addition, as long as it has continuous pores that allow air to flow, such as foamed resin such as foamed urethane and foamed styrene, and foamed metal such as foamed aluminum, titanium foam, and iron foam, it can also be used.

本发明的空气清洁过滤片的干燥方法,既可以是自然干燥,也可以是加热,亦可以是减压使溶剂蒸发的方法。材质是纤维等有机系时,高温下的干燥,由于担心伴随过滤片纤维的收缩引起变形及处理液中原材料发生变质,所以最好温度在150℃以下,为100℃以下则更好。无机系或金属系材质时,可以在可保持材质形状的范围温度下进行处理。The drying method of the air-cleaning filter sheet of the present invention can be natural drying, heating, or a method of depressurizing to evaporate the solvent. When the material is organic such as fiber, drying at high temperature may cause deformation due to shrinkage of the filter fiber and deterioration of raw materials in the treatment solution, so the temperature is preferably below 150°C, more preferably below 100°C. In the case of inorganic or metallic materials, it can be processed at a temperature within the range where the shape of the material can be maintained.

当本发明的过滤片基材的密度非均匀,有空隙率高的部分和低的部分时,希望在高的部分上涂布处理液。这里,所谓空隙率是指单位体积的重量大小,空隙率越大过滤片纤维间的间隙越大。通过在空隙率高的部分上进行处理,可以控制过滤片压力损失的上升,同时可以得到提高有害物质捕捉效率的作用。When the density of the filter base material of the present invention is non-uniform, and there are parts with high porosity and parts with low porosity, it is desirable to coat the treatment liquid on the high parts. Here, the so-called porosity refers to the weight per unit volume, and the larger the porosity, the larger the gap between the fibers of the filter sheet. By treating the portion with a high porosity, the increase in pressure loss of the filter can be suppressed, and at the same time, the effect of improving the efficiency of capturing harmful substances can be obtained.

此外,通过在添附原材料时同时混合着色剂,可以使过滤片在视觉上没有异样感,并且可以得到在色彩方面可以进行自由创造设计的效果。In addition, by mixing the coloring agent at the time of adding the raw material, the filter can be visually unobtrusive, and the effect of freely creating and designing the color can be obtained.

作为上述作为着色剂使用的原材料,可以使用众所周知的颜料及染料。作为颜料,可以举出偶氮系、多偶氮系、蒽醌系、キナクリドン系、异吲哚系、异吲哚满系、酞菁系、二萘嵌苯系、DPP系、荧光颜料等有机颜料以及碳黑、合成二氧化硅、氧化铬、氧化铁、氧化钛、烧制颜料、硫化锌等无机颜料。作为染料,可以举出乙醇可溶性染料、油溶性染料、荧光染料、聚光性染料等。Well-known pigments and dyes can be used as the raw material used as the said coloring agent. Examples of pigments include organic pigments such as azo-based, polyazo-based, anthraquinone-based, kinacridon-based, isoindole-based, isoindoline-based, phthalocyanine-based, perylene-based, DPP-based, and fluorescent pigments. Pigments and inorganic pigments such as carbon black, synthetic silica, chromium oxide, iron oxide, titanium oxide, fired pigments, and zinc sulfide. Examples of the dye include ethanol-soluble dyes, oil-soluble dyes, fluorescent dyes, and light-gathering dyes.

本发明的空气清洁过滤片,既可以单独使用具有上述效果的添附过滤片,也可以在后段设置网眼更细的吸尘过滤片。在后段使用网眼更细的吸尘过滤片时,为了使过滤片具有强度可以对它们单个进行粘合。通过通风,添附过滤片和吸尘过滤片进行物理性接触时,也可以只使两者重合。The air-cleaning filter of the present invention can be used alone as an additional filter having the above-mentioned effects, or can be provided with a dust-absorbing filter with a finer mesh in the rear section. When using a dust suction filter with a finer mesh in the latter stage, they can be bonded individually in order to make the filter stronger. When the additional filter and the suction filter are in physical contact through ventilation, it is also possible to only overlap the two.

虽然使制造本发明空气清洁过滤片时使用的原材料溶解及/或分散的处理液可以是任何一种处理液,但是作为原材料包含水溶性材料和非水溶性材料两者时,希望使用使水溶性材料和非水溶性材料溶解及/或分散到水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒中进行调制的处理液。通过使用水和赛璐索芙类及/或乙氧基乙醇类的混合溶媒,不会发生水溶性材料和赛璐索芙类溶媒及/或乙氧基乙醇类、或者非水溶性材料和水混合时产生的沉淀,从而可以调制使水溶性材料和非水溶性材料溶解及/或分散的处理液。作为赛璐索芙类,可以举出乙基赛璐索芙、丁基赛璐索芙、赛璐索芙醋脂等,最好具有烷基,特别理想的是具有丁基的丁基赛璐索芙。乙氧基乙醇类,可以举出甲基乙氧基乙醇、乙基乙氧基乙醇、丁基乙氧基乙醇、丁基乙氧基乙醇醋脂、乙氧基乙醇醋脂、醋酸乙氧基乙醇等,最好具有烷基,特别理想的是具有丁基的丁基乙氧基乙醇。Although any treatment liquid may be used to dissolve and/or disperse the raw materials used in the manufacture of the air cleaning filter of the present invention, when both water-soluble materials and water-insoluble materials are included as raw materials, it is desirable to use water-soluble materials. The treatment liquid prepared by dissolving and/or dispersing the material and the water-insoluble material in a mixed solvent of water, celluloids and/or ethoxyethanol. By using a mixed solvent of water and celluloids and/or ethoxyethanols, water-soluble materials and celluloids and/or ethoxyethanols, or water-insoluble materials and water Precipitation generated during mixing can prepare a treatment liquid for dissolving and/or dispersing water-soluble materials and water-insoluble materials. Examples of celluloids include ethyl celluloid, butyl celluloid, and celluloid acetate, preferably having an alkyl group, particularly preferably butyl celluloid having a butyl group. soph. Ethoxyethanols include methyl ethoxyethanol, ethyl ethoxyethanol, butyl ethoxyethanol, butyl ethoxyethanol acetate, ethoxyethanol acetate, ethoxy acetate Ethanol and the like preferably have an alkyl group, and butyl ethoxyethanol having a butyl group is particularly preferable.

以上制造的空气清洁过滤片,例如配置在空气清洁装置及换气装置及加湿装置及加温装置等的空气的吸入口和吹出口之间使用。利用这些装置,可以净化室内空气,得到预防霉菌病·细菌感染·流感等病毒感染的作用。The air-cleaning filter produced above is used, for example, to be disposed between air inlets and outlets of air cleaners, ventilators, humidifiers, and warmers. These devices can purify indoor air and prevent viral infections such as mold disease, bacterial infection, and influenza.

此外,通过把以上制造的过滤片设置在面罩的局部或者整个通风部上,可以防止螨·花粉·细菌·霉·病毒等浮游有害物质被吸入人体,得到预防霉菌病·细菌感染·流感等病毒感染的作用。In addition, by setting the above-made filter on a part or the entire ventilating part of the mask, it is possible to prevent harmful floating substances such as mites, pollen, bacteria, mold, and viruses from being inhaled into the human body, and to obtain protection against viruses such as mold disease, bacterial infection, and influenza. The role of infection.

实施例Example

以下,用实施例详细说明本发明,然而本发明在以下记述中丝毫未受任何限定进行解释。Hereinafter, the present invention will be described in detail using examples, but the present invention is not limited at all in the following description.

(实施例一)(Embodiment 1)

如图1~图5所示,在内部设置了送风机构1的本体2的前面下方部设置沿着本体2所设置的地面3形成吸入空气流的吸入口4和在本体2的两侧面设置吹出口5。As shown in Figures 1 to 5, the lower front part of the body 2 with the blower mechanism 1 installed inside is provided with a suction port 4 that forms a suction air flow along the ground 3 of the body 2 and is set on both sides of the body 2. Blow outlet 5.

送风机构1的空气通道上配置抗变态反应原过滤片6和除臭过滤片7。抗变态反应原过滤片6虽然是把由聚4乙烯酚制成的芳香族羟基化合物涂布在玻璃纤维制的高性能过滤片上,但是过滤片可以用于无纺织布、驻极过滤片、蜂窝过滤片、ヘバフイルタ一等,可以根据需要适当地选择。An anti-allergen filter sheet 6 and a deodorizing filter sheet 7 are arranged on the air channel of the blower mechanism 1 . Although the anti-allergen filter sheet 6 is to coat the aromatic hydroxyl compound made of polyvinylphenol on the high-performance filter sheet made of glass fiber, the filter sheet can be used for non-woven fabrics, electret filter sheets, honeycomb Filters, ヘバフイルタ, etc. can be appropriately selected according to needs.

此外,本体2的侧面设置辅助吸入口8,在辅助吸入口8的前方,为了不能从前方侧直视辅助吸入口8而设置从本体2侧面突出的屏蔽部9。在本体2的下方部设置灰尘传感器10,以便用该灰尘传感器10检测时能够使组装在本体2上的送风机构1自动运转。In addition, an auxiliary suction port 8 is provided on the side of the main body 2, and in front of the auxiliary suction port 8, a shielding portion 9 protruding from the side of the main body 2 is provided so that the auxiliary suction port 8 cannot be directly seen from the front side. A dust sensor 10 is provided on the lower part of the main body 2, so that the blower mechanism 1 assembled on the main body 2 can be automatically operated when detected by the dust sensor 10.

此外,在本体2的上部设置气体传感器11,用气体传感器11检测到气体时设在本体2内部的送风机构1自动运转,利用设在本体2内部的除臭过滤片7进行除臭。In addition, a gas sensor 11 is arranged on the upper part of the body 2, and when the gas sensor 11 detects gas, the blower mechanism 1 inside the body 2 operates automatically, and the deodorizing filter 7 inside the body 2 is used for deodorization.

在上述构成中,当用灰尘传感器10在设置了空气清洁机本体2的地面3附近检测到存在花粉及灰尘等的话,则送风机构1接到来自灰尘传感器10的信号并介于控制部(图中未显示)自动运转。这时通过设在本体2下方部的吸入口4,形成沿着地面3的吸入空气流,地面3附近的花粉及灰尘等被吸进吸入口4,通过设在本体2内的抗变态反应原过滤片6,在灰尘内的花粉及螨的尸体等被捕捉,由抗变态反应原过滤片6变成非活性化。In the above structure, when the dust sensor 10 is used to detect the presence of pollen and dust near the ground 3 where the air cleaner body 2 is installed, the blower mechanism 1 receives a signal from the dust sensor 10 and intervenes in the control unit ( not shown in the figure) operates automatically. At this time, the suction air flow along the ground 3 is formed through the suction port 4 located at the lower part of the body 2, pollen and dust near the ground 3 are sucked into the suction port 4, and the anti-allergen The filter sheet 6 captures pollen and mite corpses in the dust, and the anti-allergen filter sheet 6 becomes inactivated.

此外,当用设在本体2上部的气体传感器11检测到香烟的烟及氨气等的话,则送风机构1接到来自气体传感器11的信号并介于控制部自动运转,利用设在本体2内的除臭过滤片7,去除香烟气味及氨气臭味等。In addition, when the gas sensor 11 located at the top of the body 2 detects smoke and ammonia from cigarettes, etc., the blower mechanism 1 receives a signal from the gas sensor 11 and operates automatically through the control section. The deodorizing filter sheet 7 inside removes cigarette smell and ammonia stink etc.

这样利用本发明的实施例1的空气清洁机的话,由于形成吸入口4和吹出口5,并在内部设置了送风机构1的本体2内设置了配设在送风机构1空气通道上的具备芳香族羟基化合物的抗变态反应原过滤片7,为了把设于本体2的吸入口4沿着设置了空气清洁机本体2的地面3以形成吸入空气流而设在前面下方部,所以可以从本体2的下方部有效地吸入落在室内地面3上后飞扬的花粉及包含在棉灰尘等中的螨的尸体及粪,由抗变态反应原过滤片7使之非活性化,还可以在灰尘再次飞散时维持过敏活性的非活性化。Utilize the word of the air cleaner of embodiment 1 of the present invention like this, owing to form suction port 4 and outlet 5, and be provided with in the body 2 that air blower mechanism 1 is arranged on the air passage of blower mechanism 1 inside Possess the anti-allergen filter sheet 7 of aromatic hydroxy compound, in order to be located at the suction port 4 of body 2 along the ground 3 that is provided with air cleaner body 2 to form suction airflow and be located at front lower part, so can The pollen that falls on the indoor floor 3 and the corpses and feces of mites contained in cotton dust and the like are effectively sucked from the lower part of the main body 2, and are inactivated by the anti-allergen filter sheet 7. Inactivation that maintains allergy activity when dust is scattered again.

此外,通过由聚4乙烯酚构成芳香族羟基化合物,即使过滤片附着水分,聚4乙烯酚也不会从过滤片上脱离,可带来长期稳定的抗变态反应原效果。In addition, since the polyvinyl phenol is composed of an aromatic hydroxy compound, even if water adheres to the filter, the polyvinyl phenol does not detach from the filter, and a long-term stable anti-allergen effect can be achieved.

另外,通过把吹出口5设在本体2的两侧面,从吹出口5吹出的两个气流沿着左右壁面流动并在吸入口4循环,从而可以有效地把包含有在地面3上浮游的变态反应原物质的灰尘等引导到吸入口4。In addition, by setting the air outlet 5 on both sides of the main body 2, the two airflows blown out from the air outlet 5 flow along the left and right walls and circulate through the suction port 4. Dust and the like of reactant substances are guided to the suction port 4 .

还有,通过在本体2的下方部设置灰尘传感器10,并做成用灰尘传感器10检测到灰尘时使本体2自动运转的构成,可以用灰尘传感器10检测从地面3飞扬的灰尘并且本体2自动运转,从而可以及时地去除变态反应原物质。In addition, by setting the dust sensor 10 at the lower part of the main body 2, and making the main body 2 automatically run when dust is detected by the dust sensor 10, the dust sensor 10 can be used to detect dust flying from the ground 3 and the main body 2 can automatically operation, so that allergens can be removed in a timely manner.

再有,通过在本体2的侧面设置辅助吸入口8,可以从跨过地面上三个方向的较大范围吸入室内浮游的灰尘,从而可以进一步减少室内的变态反应原物质。Furthermore, by setting the auxiliary suction port 8 on the side of the body 2, the indoor floating dust can be inhaled from a large range across three directions on the ground, thereby further reducing indoor allergens.

再者,通过在设于本体2侧面的辅助吸入口8的前方,为了不能从前方侧直视辅助吸入口8而设置从本体2侧面突出的屏蔽部9,可以用屏蔽部9对从辅助吸入口8发生的噪音进行隔音,同时不会从本体2的前方直视到辅助吸入口8的污垢,通过呈现清洁感的外观还提高了设计性。Moreover, by being located at the front of the auxiliary suction port 8 on the side of the main body 2, the shielding part 9 protruding from the side of the main body 2 is set in order not to look directly at the auxiliary suction port 8 from the front side, and the shielding part 9 can be used to protect the auxiliary suction port from the auxiliary suction port. The noise generated by the port 8 is sound-proofed, and at the same time, the dirt on the auxiliary suction port 8 is not directly seen from the front of the main body 2, and the design is improved by a clean appearance.

再者,通过在本体2的内部设置除臭过滤片7,在本体的上部设置气体传感器11,当气体传感器11检测到气体时使本体2自动运转,则可以用除臭过滤片7对气体传感器11检测到的气体进行除臭,从而及时有效地去除气体成分中香烟气味及氨气臭味。Furthermore, by setting the deodorizing filter sheet 7 inside the body 2, the gas sensor 11 is set on the top of the body, and the body 2 is automatically operated when the gas sensor 11 detects gas, then the gas sensor can be paired with the deodorizing filter sheet 7. 11 The detected gas is deodorized, so as to timely and effectively remove the smell of cigarettes and ammonia in the gas components.

由以上实施例可知,利用本发明的话,由于形成吸入口和吹出口,并具备在内部设置了送风机构的本体和被配设在设于该本体内的送风机构的空气通道上的具备芳香族羟基化合物的抗变态反应原过滤片,为了把设于上述本体的吸入口沿地面以形成吸入空气流而设在前面下方部,所以可以提供可有效地吸入存在于地面附近的包含花粉及螨的尸体的灰尘等,并使过敏活性非活性化的空气清洁机。Can know by above embodiment, utilize the word of the present invention, owing to form suction port and outlet, and be provided with the main body that is provided with blower mechanism inside and be arranged on the air passage of the blower mechanism that is arranged in this body. The anti-allergen filter of the aromatic hydroxy compound is arranged at the front lower part in order to form the suction port of the above-mentioned main body along the ground to form the suction air flow, so it can effectively inhale pollen and pollen that exist near the ground. An air cleaner that deactivates allergy activity such as dust from mite corpses.

此外,由于由聚4乙烯酚构成芳香族羟基化合物,所以可带来长期稳定的抗变态反应原效果。In addition, since the aromatic hydroxy compound is composed of polyvinylphenol, it can bring about long-term stable anti-allergen effect.

另外,由于把吹出口设在本体的两侧面,所以可以把包含有在地面附近飞扬起来的变态反应原物质的灰尘等引导到吸入口侧,从而可以有效地去除变态反应原物质。In addition, since the air outlet is provided on both sides of the main body, it is possible to guide dust, etc. containing allergens flying around the ground to the suction port side, thereby effectively removing allergens.

还有,由于在本体的下方部设置灰尘传感器,并做成用该灰尘传感器检测到灰尘时使上述本体自动运转的构成,所以可以及时地运转空气清洁机以去除变态反应原物质。In addition, since a dust sensor is set on the lower part of the main body, and the above-mentioned main body is automatically operated when dust is detected by the dust sensor, the air cleaner can be operated in time to remove allergens.

再有,由于在本体的侧面设置了辅助吸入口,所以可以从较大范围吸入灰尘,从而可以进一步减少室内的变态反应原物质。Furthermore, since an auxiliary suction port is provided on the side of the main body, dust can be sucked in from a wide range, thereby further reducing indoor allergens.

再者,由于在设于本体侧面的辅助吸入口的前方,为了不能从前方侧直视上述辅助吸入口而设置从上述本体侧面突出的屏蔽部,所以可以降低从辅助吸入口发生的噪音,并且由于看不到辅助吸入口的污垢且呈现清洁的外观还提高了设计性。Furthermore, since the shield portion protruding from the side of the main body is provided in front of the auxiliary suction port provided on the side of the main body in order not to look directly at the auxiliary suction port from the front side, the noise generated from the auxiliary suction port can be reduced, and The design is also improved because the dirt on the auxiliary suction port is not visible and the appearance is clean.

再者,由于具备设于本体内部的除臭过滤片、以及设于上述本体上部的气体传感器,并且做成用上述气体传感器检测到恶臭成分等的气体时使上述本体自动运转的构成,所以可以及时地使空气清洁机运转,从而还可以有效地去除香烟气味及氨气臭味等。Furthermore, since the deodorizing filter is provided inside the main body and the gas sensor is located on the upper part of the main body, and the above-mentioned main body is automatically operated when the gas sensor detects a gas such as a malodorous component, it can Timely operation of the air cleaner can also effectively remove the smell of cigarettes and ammonia.

(实施例二)(Example 2)

水溶性材料和非水溶性材料的混合Mixture of water-soluble and water-insoluble materials

如表1所示,对水溶性材料和非水溶性材料进行了混合。成分相对溶媒以15%的比例(容量比)进行混合后,用搅拌器进行一分钟搅拌,目视观察搅拌后的溶液状态。As shown in Table 1, water-soluble materials and water-insoluble materials were mixed. After the components were mixed at a ratio (volume ratio) of 15% to the solvent, the mixture was stirred with a stirrer for one minute, and the state of the solution after stirring was visually observed.

在单一成分的溶媒中,水溶性材料和非水溶性材料混合存在的话,则可以看到沉淀的发生、两相分离及只能少量溶解的状态。在沉淀发生及两相分离状态的混合液中,涂布于过滤片上时由于不能均匀涂布,所以不适合实用。此外,只能少量溶解时,由于在一次加工中只能在过滤片上涂布少量成分,所以制造上损失较大。In a single-component solvent, if a water-soluble material and a water-insoluble material are mixed, precipitation, two-phase separation, and a state where only a small amount of dissolution is observed. In the mixed liquid in which precipitation occurs and the two phases are separated, it is not suitable for practical use because it cannot be applied uniformly when applied to a filter. In addition, when only a small amount can be dissolved, only a small amount of components can be coated on the filter in one process, so the loss in production is large.

当混合溶媒中丁基赛璐索芙和水的比率为1∶1时,可以在不引起沉淀发生及两相分离等不良情况下制作使成分溶解的处理液,从而可以均匀地涂布在过滤片上。即使丁基赛璐索芙的比率上升,处理液也不发生沉淀。相反使水的比率上升时,当比率大于1∶4时则可看到成分的沉淀。When the ratio of butyl celusoff and water in the mixed solvent is 1:1, it is possible to prepare a treatment solution that dissolves the components without causing precipitation and two-phase separation, so that it can be evenly coated on the filter. Chip. Even if the ratio of butyl celusoff was increased, precipitation did not occur in the treatment liquid. Conversely, when the ratio of water is increased, when the ratio exceeds 1:4, precipitation of components is observed.

表1Table 1

Figure A20081000966700191
Figure A20081000966700191

Figure A20081000966700201
Figure A20081000966700201

(比较例1)(comparative example 1)

表2Table 2

Figure A20081000966700202
Figure A20081000966700202

(实施例三)(Embodiment 3)

向过滤片涂布处理液和干燥Apply treatment liquid to the filter and dry

以15%浓度(容量比)把儿茶素和聚乙烯酚溶解到水/赛璐索芙类的混合溶媒中调制成处理液,使聚酯系无纺织布的过滤片浸渍在该处理液中。把过滤片从处理液中提起,分别在室温、100℃、150℃、200℃进行干燥。在室温干燥时过滤片面用手触摸感到没有液体附着约需4小时。在100℃干燥时15分钟达到同等程度的干燥状态。在150℃干燥时虽10分钟达到同等程度的干燥状态但局部变色。在200℃时10分钟可看到过滤片变色及收缩变形。即使使用聚丙烯制的蜂窝状过滤片时,也是同样结果。Prepare a treatment solution by dissolving catechin and polyvinylphenol in a mixed solvent of water/cellusophane at a concentration (volume ratio) of 15%, and immerse a polyester non-woven fabric filter in the treatment solution . The filter was lifted from the treatment liquid, and dried at room temperature, 100°C, 150°C, and 200°C, respectively. When drying at room temperature, it takes about 4 hours for the filter surface to feel that there is no liquid attached to it by hand. When drying at 100°C, it takes 15 minutes to reach the same degree of dry state. When dried at 150°C, the same degree of dry state was achieved in 10 minutes, but the color changed locally. Discoloration and shrinkage of the filter can be seen in 10 minutes at 200°C. The same result was obtained even when a polypropylene honeycomb filter was used.

(实施例四)(embodiment four)

向过滤片涂布处理液和压力损失的测定Measurement of application of treatment liquid to filter and pressure loss

以15%浓度(容量比)把聚乙烯酚和吸湿性聚合物及儿茶素溶解到水/赛璐索芙类的混合溶媒中调制成处理液,把该处理液喷涂在聚丙烯制纤维上,在100℃干燥15分钟制造功能性过滤片。以各种速度让空气向该功能性过滤片通风,测定压力损失和吸尘效率。由表3可知,通过把聚乙烯酚和吸湿性聚合物及儿茶素添附到过滤片上,与无处理过滤片相比,压力损失和吸尘效率都略有增加。Dissolve polyvinylphenol, hygroscopic polymer, and catechin in a water/cellusophane mixed solvent at a concentration (volume ratio) of 15% to prepare a treatment solution, and spray the treatment solution on polypropylene fibers , and dried at 100°C for 15 minutes to manufacture functional filter sheets. Air was ventilated through the functional filter at various speeds to measure pressure loss and suction efficiency. It can be seen from Table 3 that by adding polyvinylphenol, hygroscopic polymer and catechin to the filter, both the pressure loss and dust collection efficiency were slightly increased compared with the untreated filter.

表3table 3

Figure A20081000966700211
Figure A20081000966700211

(实施例五)(embodiment five)

向过滤片涂布处理液的部分和压力损失的测定Measuring the part of the treatment liquid applied to the filter and the pressure loss

在纤维具有稠密形状(空隙率小)的为使吸尘效率提高而使用的吸尘过滤片上和纤维虽是疏松状态(空隙率大)但粘合了强度优异的吸尘过滤片的过滤片(背面为疏松状态)上,用与实施例四相同的方法添附了聚乙烯酚和吸湿性聚合物及儿茶素。就在各总添附量及朝向情况下添附的功能性过滤片,对通风速度为0.5m/s的吸尘效率进行了测定,结果如图7所示。由图7可知,伴随总添附量的增加,吸尘效率增加。这时,在吸尘滤材的空隙率较大的面上添附了处理液的过滤片,与在空隙率较小的面上添附的过滤片相比,吸尘效率较好。On the dust collection filter used to improve the dust collection efficiency with fibers having a dense shape (small porosity), and the filter with a dust collection filter with excellent strength although the fibers are in a loose state (large porosity) ( On the back (in a loose state), polyvinylphenol, a hygroscopic polymer, and catechin were added in the same manner as in Example 4. With respect to the functional filter sheets attached under the conditions of each total amount of addition and orientation, the dust collection efficiency at a ventilation speed of 0.5m/s was measured, and the results are shown in Figure 7. It can be seen from Figure 7 that with the increase of the total amount of attachment, the dust collection efficiency increases. At this time, the filter sheet with the treatment liquid attached to the surface with a large porosity of the dust collection filter material has better dust collection efficiency than the filter sheet with a surface with a small porosity.

(实施例六)(Embodiment six)

如图8所示,空气清洁装置201,在框体202内具备功能性过滤片203、风扇204、吸入口205、吹出口206和外框213。As shown in FIG. 8 , the air cleaning device 201 includes a functional filter 203 , a fan 204 , an inlet 205 , an outlet 206 , and an outer frame 213 in a housing 202 .

混入了有害污染物质的污浊空气,从空气清洁装置201的吸入口205,被风扇204吸引,被送到功能性过滤片203,有害污染物质被过滤片过滤和净化,变成干净的空气,并从吹出口206排出及供给。Dirty air mixed with harmful pollutants is attracted by the fan 204 from the suction port 205 of the air cleaning device 201, and is sent to the functional filter sheet 203, and the harmful pollutants are filtered and purified by the filter sheet to become clean air, and It is discharged and supplied from the outlet 206 .

在上述构成中,功能性过滤片203把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可防止具有有害性的物质再次飞散的空气清洁机。In the above configuration, the functional filter sheet 203 filters and adsorbs and removes harmful floating substances such as mites, pollen, bacteria, mold, and viruses, and inactivates harmful floating substances such as mites, pollen, bacteria, mold, and viruses. By adding a deactivator for floating harmful substances to the filter, effective adsorption removal and deactivation can be performed, and an air cleaner that can prevent harmful substances from re-scattering can be provided.

此外,在空气清洁装置的外框213上涂覆了可使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化的成分。在使空气清洁装置运转时,特别容易在其吸入口205附近吸附浮游有害物质,因此,处于稍有一点冲击容易再次飞散和空气污染的状况。在上述构成中,在空气清洁装置的外框213,由于涂覆了可使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化的成分,所以浮游有害物质吸附在吸入口205附近时被非活性化,从而可以防止有害物质再次飞散和空气污染。In addition, the outer frame 213 of the air cleaner is coated with a component capable of inactivating floating harmful substances such as mites, pollen, bacteria, mold, and viruses. When the air cleaning device is operated, it is particularly easy to adsorb floating harmful substances near its suction port 205, so it is easy to be scattered again and pollute the air with a slight impact. In the above configuration, since the outer frame 213 of the air cleaning device is coated with components that can inactivate floating harmful substances such as mites, pollen, bacteria, mold, and viruses, when the floating harmful substances are adsorbed near the suction port 205 It is inactivated to prevent harmful substances from re-scattering and air pollution.

(实施例七)(Embodiment 7)

如图9所示,换气装置207,在通风道208内具备功能性过滤片212、送风机209、吸入口210、吹出口211和外框213。As shown in FIG. 9 , the ventilator 207 includes a functional filter 212 , a blower 209 , an inlet 210 , an outlet 211 , and an outer frame 213 in an air duct 208 .

混入了有害污染物质的污浊空气,从换气装置207的吸入口210,被送风机209吸引,被送到功能性过滤片212,有害污染物质被过滤片过滤和净化,变成干净的空气,并从吹出口211排出及供给。Dirty air mixed with harmful pollutants is attracted by the blower 209 from the suction port 210 of the ventilator 207, and is sent to the functional filter sheet 212, and the harmful pollutants are filtered and purified by the filter sheet to become clean air, and It is discharged and supplied from the outlet 211 .

在上述构成中,功能性过滤片212把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可防止具有有害性的物质再次飞散的空气清洁机。In the above configuration, the functional filter sheet 212 filters and adsorbs and removes harmful floating substances such as mites, pollen, bacteria, mold, and viruses, and inactivates harmful floating substances such as mites, pollen, bacteria, mold, and viruses. By adding a deactivator for floating harmful substances to the filter, effective adsorption removal and deactivation can be performed, and an air cleaner that can prevent harmful substances from re-scattering can be provided.

此外,在换气装置的外框213上涂覆了可使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化的成分。在使换气装置运转时,特别容易在其吸入口210附近吸附浮游有害物质,因此,处于稍有一点冲击容易再次飞散和空气污染的状况。在上述构成中,在换气装置的外框213,由于涂覆了可使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化的成分,所以浮游有害物质吸附在吸入口210附近时被非活性化,从而可以防止有害物质再次飞散和空气污染。In addition, the outer frame 213 of the ventilator is coated with a component capable of inactivating floating harmful substances such as mites, pollen, bacteria, mold, and viruses. When the ventilator is operated, it is particularly easy to absorb floating harmful substances near the suction port 210, and therefore, it is easy to be scattered again and pollute the air with a slight impact. In the above configuration, since the outer frame 213 of the ventilator is coated with components that can inactivate floating harmful substances such as mites, pollen, bacteria, mold, and viruses, when the floating harmful substances are adsorbed near the suction port 210 It is inactivated to prevent harmful substances from re-scattering and air pollution.

(实施例八)(Embodiment Eight)

如图10所示,面罩214,具备功能性过滤片215、面罩增强部216a·216b以及型套217a·217b。As shown in FIG. 10 , the mask 214 includes a functional filter 215 , mask reinforcing parts 216 a and 216 b , and mold covers 217 a and 217 b.

混入了有害污染物质的污浊空气,通过面罩214的功能性过滤片215,有害污染物质被过滤片过滤和净化。Dirty air mixed with harmful pollutants passes through the functional filter sheet 215 of the mask 214, and the harmful pollutants are filtered and purified by the filter sheet.

在上述构成中,功能性过滤片215把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可使使用者吸入的空气保持在清洁状态的面罩。In the above configuration, the functional filter sheet 215 filters and adsorbs and removes harmful floating substances such as mites, pollen, bacteria, mold, and viruses, and inactivates harmful floating substances such as mites, pollen, bacteria, mold, and viruses. Adding a deactivator for floating harmful substances to the filter sheet enables effective adsorption removal and deactivation, thereby providing a mask that can keep the air inhaled by the user clean.

(实施例九)(Embodiment nine)

如图11所示,加湿装置218,在通风道或框体208内具备加湿空气清洁过滤片219、送风机209、吸入口210、吹出口211、水供给部220和外框213。As shown in FIG. 11 , humidifier 218 includes humidified air cleaning filter 219 , blower 209 , suction port 210 , blowing port 211 , water supply unit 220 and outer frame 213 in air passage or frame 208 .

混入了有害污染物质的污浊空气,通过加湿装置218的加湿空气清洁过滤片219,被加湿的同时,有害污染物质被过滤片过滤和净化。Dirty air mixed with harmful pollutants passes through the humidified air of the humidifying device 218 to clean the filter sheet 219 , while being humidified, the harmful pollutants are filtered and purified by the filter sheet.

在上述构成中,加湿空气清洁过滤片219通过把由吸水性基材构成的过滤片的一部分浸渍在水中,或者从上部供给水,对通过过滤片的空气进行加湿的同时,把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可一边进行加湿一边防止有害性物质再次飞散的加湿装置。In the above-mentioned configuration, the humidifying air cleaning filter 219 immerses a part of the filter made of a water-absorbing base material in water, or supplies water from above to humidify the air passing through the filter, and remove mites, pollen, Bacteria, mildew, viruses and other harmful floating substances are filtered, adsorbed and captured, and the harmful floating substances such as mites, pollen, bacteria, mold and viruses are inactivated. By adding a deactivator for floating harmful substances to the filter, effective adsorption removal and deactivation can be performed, and a humidifier that can prevent harmful substances from re-scattering while humidifying can be provided.

(实施例十)(embodiment ten)

如图12所示,加温装置或被褥干燥器221,在框体208内具备送风机209、吸入口210、吹出口211、功能性过滤片212、热源222和外框213。As shown in FIG. 12 , a warming device or futon dryer 221 includes a blower 209 , a suction inlet 210 , an air outlet 211 , a functional filter 212 , a heat source 222 and an outer frame 213 in a frame 208 .

混入了有害污染物质的污浊空气,从加温装置或被褥干燥器221的吸入口210,被送风机209吸引,被送到功能性过滤片212,有害污染物质被过滤片过滤和净化,变成干净的空气后,由热源222变成热风,从吹出口211排出及供给。这里,吹出口211设置了储备热风的袋子,使用它对被褥进行干燥的装置就是被褥干燥器。Dirty air mixed with harmful pollutants is sucked by the air blower 209 from the suction port 210 of the heating device or bedding dryer 221 and sent to the functional filter 212. The harmful pollutants are filtered and purified by the filter to become clean. After the air is released, it is turned into hot air by the heat source 222, and is discharged and supplied from the outlet 211. Here, the air outlet 211 is provided with a bag for storing hot air, and the device using it to dry the bedding is exactly the bedding dryer.

在上述构成中,功能性过滤片212把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可防止具有有害性的物质再次飞散的加温装置或被褥干燥器。In the above configuration, the functional filter sheet 212 filters and adsorbs and removes harmful floating substances such as mites, pollen, bacteria, mold, and viruses, and inactivates harmful floating substances such as mites, pollen, bacteria, mold, and viruses. By adding a deactivator for floating harmful substances to the filter, effective adsorption removal and deactivation can be performed, thereby providing a warming device or futon dryer that can prevent harmful substances from re-scattering.

(实施例十一)(Embodiment Eleven)

如图13所示,空调223,在框体208内具备送风机209、吸入口210、吹出口211、功能性过滤片212、热交换器224和外框213。As shown in FIG. 13 , the air conditioner 223 includes a blower 209 , an air inlet 210 , an air outlet 211 , a functional filter 212 , a heat exchanger 224 , and an outer frame 213 in a housing 208 .

混入了有害污染物质的污浊空气,从空调223的吸入口210,被送风机209吸引,被送到功能性过滤片212,有害污染物质被过滤片过滤和净化,变成干净的空气后,由热交换器224进行热交换变成热风或者冷风,从吹出口211排出及供给。Dirty air mixed with harmful pollutants is sucked by the blower 209 from the suction port 210 of the air conditioner 223, and sent to the functional filter 212. The harmful pollutants are filtered and purified by the filter, and after becoming clean air, it is heated by heat. The exchanger 224 performs heat exchange to become hot air or cold air, which is discharged and supplied from the air outlet 211 .

在上述构成中,功能性过滤片212把螨、花粉、细菌、霉、病毒等浮游有害物质过滤及吸附捕捉去除,并且使螨、花粉、细菌、霉、病毒等浮游有害物质非活性化。通过把针对浮游有害物质的非活性化剂添附在过滤片中,可以进行有效的吸附去除和非活性化,从而可以提供可防止具有有害性的物质再次飞散的空调。In the above configuration, the functional filter sheet 212 filters and adsorbs and removes harmful floating substances such as mites, pollen, bacteria, mold, and viruses, and inactivates harmful floating substances such as mites, pollen, bacteria, mold, and viruses. By adding a deactivator for floating harmful substances to the filter, effective adsorption removal and deactivation can be performed, thereby providing an air conditioner that prevents harmful substances from re-scattering.

(实施例十二)(Example 12)

向过滤片涂布处理液和干燥Apply treatment liquid to the filter and dry

在聚乙烯酚的酒精溶液中,浸渍聚酯系无纺织布的过滤片。把过滤片从处理液中提起,分别在室温、100℃、150℃、200℃进行干燥。在室温干燥时过滤片面用手触摸感到没有液体附着约需4小时。在100℃干燥时15分钟达到同等程度的干燥状态。在150℃干燥时虽10分钟达到同等程度的干燥状态但局部变色。在200℃时10分钟可看到过滤片变色及收缩变形。即使使用聚丙烯制的蜂窝状过滤片时,也是同样结果。A filter made of polyester non-woven fabric is dipped in an alcohol solution of polyvinyl phenol. The filter was lifted from the treatment liquid, and dried at room temperature, 100°C, 150°C, and 200°C, respectively. When drying at room temperature, it takes about 4 hours for the filter surface to feel that there is no liquid attached to it by hand. When drying at 100°C, it takes 15 minutes to reach the same degree of dry state. When dried at 150°C, the same degree of dry state was achieved in 10 minutes, but the color changed locally. Discoloration and shrinkage of the filter can be seen in 10 minutes at 200°C. The same result was obtained even when a polypropylene honeycomb filter was used.

在上述处理的过滤片上喷涂溶解了儿茶素和有机氮系防霉剂的水溶液,制成了抗菌、防霉、抗变态反应原、抗病毒过滤片。An aqueous solution in which catechins and organic nitrogen antifungal agents are dissolved is sprayed on the above-mentioned treated filter sheet to make an antibacterial, antifungal, antiallergen, and antiviral filter sheet.

(实施例十三)(Example 13)

过滤片抗菌、防霉、抗病毒、抗变态反应原性能的评价Evaluation of antibacterial, anti-mildew, anti-virus, anti-allergen properties of filters

首先,就实施例十二制作的过滤片针对大肠菌和黄色葡萄球菌的效果进行了调查。使105个/ml水平的菌液接触过滤片,24小时后再调查菌数,结果没有检测出菌。用未处理的过滤片进行了相同的试验,结果没有发现菌数的减少。First, the effect of the filter made in Example 12 on coliform bacteria and Staphylococcus aureus was investigated. The bacterial solution at the level of 10 5 cells/ml was brought into contact with the filter, and the number of bacteria was checked after 24 hours, but no bacteria were detected. The same test was carried out with untreated filters, and no reduction in the bacterial count was found.

接着,就实施例十二制作的过滤片针对霉的效果进行了调查。把上述抗菌、防霉、抗变态反应原、抗病毒过滤片放在涂布了青霉孢子悬浊液的试验用培养地上,在室温下经过七天培养。在培养后的过滤片周边及过滤片上观察到没有生长霉菌的领域(阻止圆)。用未处理的过滤片进行了相同的试验,结果在培养地和过滤片一面繁殖了霉。Then, the effect of the filter sheet made in Example 12 on mildew was investigated. The above-mentioned antibacterial, anti-mildew, anti-allergen, anti-viral filter discs are placed on the test culture ground coated with penicillium spore suspension, and cultivated at room temperature for seven days. Areas without mold growth (stop circles) were observed around and on the cultured filter discs. The same test was carried out with an untreated filter, and as a result, mold multiplied on the cultivation site and on the side of the filter.

下面,就实施例十二制作的过滤片针对病毒的效果进行了调查。把包含107个/ml的流感病毒的试验液涂布在过滤片上,为了防止干燥在密闭的状态下保管6个小时,然后从过滤片回收病毒液。测定病毒对细胞的感染力,结果看到感染力降低了两位以上。而未处理的过滤片,感染力只是被认为是自然减少的微小降低。Next, the effect of the filter made in Example 12 on viruses was investigated. A test liquid containing 10 7 /ml of influenza virus was applied to the filter, and it was stored in an airtight state to prevent drying for 6 hours, and then the virus liquid was recovered from the filter. The infectivity of the virus to the cells was measured, and it was found that the infectivity was reduced by more than two digits. With untreated filters, there is only a small reduction in infectivity which is believed to be a natural reduction.

最后,就实施例十二制作的过滤片的抗变态反应原性能进行了调查。把从吸尘器采集的包含螨变态反应原的尘埃放在过滤片上,保管24小时。然后,用朝日啤酒药品公司制的螨变态反应原检测仪器(产品名:螨扫描(mite scan))进行变态反应原评价,结果确认到变态反应原减少。未处理过滤片及尘埃,得到的结果显示很高的变态反应原性。Finally, the anti-allergen performance of the filter made in Example 12 was investigated. Put the dust collected from the vacuum cleaner containing mite allergens on the filter and keep it for 24 hours. Then, allergens were evaluated using a mite allergen detector (product name: mite scan) manufactured by Asahi Beer Pharmaceutical Co., Ltd., and as a result, a decrease in allergens was confirmed. Untreated filters and dust, the results obtained showed high allergenicity.

(实施例十四)(Example 14)

向过滤片涂布处理液和压力损失的测定Measurement of application of treatment liquid to filter and pressure loss

把聚乙烯酚的酒精溶液喷涂在聚丙烯制纤维上,在100℃干燥15分钟并制造空气清洁过滤片。以各种速度让空气向该空气清洁过滤片通风,测定压力损失和吸尘效率。结果与实施例四的结果相同,通过把聚乙烯酚添附到过滤片上,与无处理过滤片相比,压力损失和吸尘效率都略有增加。An alcohol solution of polyvinylphenol was sprayed on polypropylene fibers and dried at 100°C for 15 minutes to produce an air cleaning filter. Air was ventilated through the air cleaning filter at various speeds, and pressure loss and suction efficiency were measured. The result is the same as that of Example 4. By adding polyvinyl phenol to the filter, compared with the untreated filter, the pressure loss and dust collection efficiency are slightly increased.

(实施例十五)(Example 15)

向过滤片涂布处理液的部分和压力损失的测定Measurement of the part of the treatment liquid applied to the filter and the pressure loss

在纤维具有稠密形状(空隙率小)的为使吸尘效率提高而使用的吸尘过滤片上和纤维虽是疏松状态(空隙率大)但粘合了强度优异的吸尘过滤片的过滤片(背面为疏松状态)上,用与实施例十四相同的方法添附了聚乙烯酚。就在各总添附量及朝向情况下添附的空气清洁过滤片,对通风速度为0.5m/s的吸尘效率进行了测定,结果与实施例五的结果相同,伴随总添附量的增加,吸尘效率增加。这时,在吸尘滤材的空隙率较大的面上添附了处理液的过滤片,与在空隙率较小的面上添附的过滤片相比,吸尘效率较好。On the dust collection filter used to improve the dust collection efficiency with dense fibers (small porosity) and the filter with loose fiber state (large porosity) but bonded dust suction filter with excellent strength ( The back is in a loose state), and polyvinyl phenol is added in the same way as in Example 14. With regard to the air cleaning filter sheets attached under each total amount of addition and orientation, the dust collection efficiency at a ventilation speed of 0.5m/s has been measured. Increased dust efficiency. At this time, the filter sheet with the treatment liquid attached to the surface with a large porosity of the dust collection filter material has better dust collection efficiency than the filter sheet with a surface with a small porosity.

(实施例十六)(Example 16)

制作了具有与实施例六相同构成的具备空气清洁过滤片的空气清洁装置。An air cleaning device equipped with an air cleaning filter having the same configuration as in Example 6 was produced.

(实施例十七)(Embodiment 17)

制作了具有与实施例七相同构成的具备空气清洁过滤片的换气装置。A ventilator equipped with an air-cleaning filter having the same configuration as in Example 7 was manufactured.

(实施例十八)(Embodiment eighteen)

制作了具有与实施例八相同构成的具备空气清洁过滤片的面罩。A mask equipped with an air-cleaning filter having the same structure as in Example 8 was produced.

(实施例十九)(Embodiment 19)

制作了具有与实施例十相同构成的具备空气清洁过滤片的加温装置或被褥干燥器。A warming device or futon dryer equipped with an air-cleaning filter having the same structure as in Example 10 was produced.

(实施例二十)(Example 20)

制作了具有与实施例十一相同构成的具备空气清洁过滤片的空调。An air conditioner equipped with an air-cleaning filter having the same structure as that of the eleventh embodiment was produced.

产业上利用可能性Possibility of industrial use

本发明在可以提供有效吸入位于地面附近的花粉及螨的尸体等且可长期发挥抗过敏特性的空气清洁机、控制捕捉的微粒子物质有害性的功能性过滤片和其简便制造方法及其用途、控制捕捉的微粒子物质有害性的空气清洁过滤片及其用途方面,具有产业上利用可能性。The present invention provides an air cleaner capable of effectively inhaling pollen and mite corpses located near the ground and exhibiting anti-allergic properties for a long period of time, a functional filter for controlling the harmfulness of captured particulate matter, a simple manufacturing method and its use, An air cleaning filter for controlling the harmfulness of captured particulate matter and its use may be industrially applicable.

Claims (11)

1.一种空气清洁过滤片,其特征在于,添附了从具有抗变态反应原性的原材料、具有抗菌性的原材料、具有抗病毒性的原材料、具有防霉性的原材料中选择的两个以上的原材料。1. An air-cleaning filter sheet, characterized in that two or more selected from raw materials with antiallergenic properties, raw materials with antibacterial properties, raw materials with antiviral properties, and raw materials with antifungal properties are attached. raw materials. 2.如权利要求1所述的空气清洁过滤片,其特征在于,具有抗变态反应原性的原材料,是具有高分子酚性氢氧基的抗变态反应原剂。2. The air cleaning filter according to claim 1, wherein the raw material having antiallergenic properties is an antiallergic agent having a high molecular weight phenolic hydroxyl group. 3.如权利要求1所述的空气清洁过滤片,其特征在于,作为具有抗病毒性的原材料包含儿茶素类。3. The air-cleaning filter according to claim 1, wherein catechins are contained as the antiviral material. 4.如权利要求1所述的空气清洁过滤片,其特征在于,作为具有抗菌性的原材料包含酵素类。4. The air-cleaning filter according to claim 1, wherein the antibacterial material contains enzymes. 5.如权利要求1所述的空气清洁过滤片,其特征在于,使用作为着色剂使用的原材料进行着色。5. The air-cleaning filter according to claim 1, wherein the material used as a colorant is used for coloring. 6.如权利要求1所述的空气清洁过滤片,其特征在于,向空气清洁过滤片添附的原材料的添附量在0.1至10g/m2的范围。6. The air-cleaning filter according to claim 1, wherein the amount of the raw material added to the air-cleaning filter is in the range of 0.1 to 10 g/m 2 . 7.一种空气清洁过滤片,其特征在于,权利要求1所述的原材料被涂布在过滤片空隙率较高的部分上。7. An air cleaning filter, characterized in that the raw material according to claim 1 is coated on the part of the filter with a higher porosity. 8.一种装置,其特征在于,把权利要求1所述的空气清洁过滤片配置在空气的吸入口和吹出口之间。8. A device characterized in that the air cleaning filter according to claim 1 is arranged between an air suction port and an air discharge port. 9.如权利要求8所述的装置,其特征在于,在空气清洁过滤片的后段设置吸尘过滤片。9. The device according to claim 8, characterized in that, a dust suction filter is arranged behind the air cleaning filter. 10.如权利要求9所述的装置,其特征在于,装置是空气清洁装置、换气装置、加湿装置、加温装置、除湿装置、被褥干燥器和空调中任何一个。10. The device according to claim 9, wherein the device is any one of an air cleaning device, a ventilation device, a humidifying device, a warming device, a dehumidifying device, a bedding dryer and an air conditioner. 11.一种面罩,其特征在于,由权利要求1所述的空气清洁过滤片构成。11. A mask, characterized in that it is made of the air cleaning filter according to claim 1.
CNA2008100096672A 2003-06-12 2004-03-26 Air cleaning filter, and air cleaner device Pending CN101406778A (en)

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