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CN101392203A - High efficiency environment friendly fuel for vehicle - Google Patents

High efficiency environment friendly fuel for vehicle Download PDF

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Publication number
CN101392203A
CN101392203A CNA2008101989716A CN200810198971A CN101392203A CN 101392203 A CN101392203 A CN 101392203A CN A2008101989716 A CNA2008101989716 A CN A2008101989716A CN 200810198971 A CN200810198971 A CN 200810198971A CN 101392203 A CN101392203 A CN 101392203A
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China
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parts
high efficiency
water
environment friendly
efficiency environment
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CNA2008101989716A
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CN101392203B (en
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梁千豪
黄登生
丘大金
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Abstract

The invention discloses a highly effective and environmentally friendly vehicle fuel which is prepared by raw materials with the following parts by weight: 40 parts to 60 parts of methanol or ethanol, 20 parts to 40 parts of naphtha, 2 parts to 5 parts of intensifier, 3 parts to 5 parts of etherifying agent, 2 parts to 6 parts of combustion-supporting agonist, 0.2 part to 0.5 part of water-resistant solubilizer, 0.1 part to 0.3 part of metal corrosion inhibitor and 0.1 part to 0.3 part of antioxidizing and antigum agent, wherein, the water-resistant solubilizer is prepared by the following method: oleic acid and ethanolamine are mixed for 10min to 20min at normal temperature according to the weight ratio of 1 : 0.1 to 0.4. The highly effective and environmentally friendly vehicle fuel has full conversion of ethers, is improved in water solubility due to the adoption of the water-resistant solubilizer, is not affected by slop and water in a storage tank and a refuel tank, does not cause two-phase stratification, can increase the permissible content of water or slop of alcoholic gasoline from 0.3 percent to more than 1 percent, can simultaneously guarantee the large dosage of methanol or ethanol and the stability of fuel, and can prepare 93<model> and 97<model> high-grade and environmentally friendly clean vehicle which meets various national standards.

Description

High efficiency environment friendly fuel for vehicle
Technical field
The present invention relates to a kind of fuel oil, is a kind of high efficiency environment friendly fuel for vehicle specifically.
Background technology
Along with the minimizing day by day of natural oil resource, and the aggravation that various countries' industrialization is developed by leaps and bounds, consumption of petroleum amount are increasing year by year significantly, and this disposable energy availability and demand contradiction of earth Heaven burning petroleum is become increasingly conspicuous.Petroleum resources limited on the earth are being subjected to unconfined exploitation, will certainly oil exhaustion to the greatest extent.The fuel expert of countries in the world is constantly seeking and is exploring for this reason, wishes and seeks out the various oil-fired energy that substitute.Through unremitting effort for many years, studies have shown that exploitation is that the Aalcohols fuel of major ingredient is a kind of oil replacement energy that the most ripe, tool is wished with methyl alcohol or ethanol.
Mix methyl alcohol or ethanol in the gasoline by weight 10~25% ratio at present existing a plurality of countries and regions, adds a certain amount of mutual solvent material again, can directly use as vehicle fuel behind stir-concoction.But because the various places temperature difference, the humidity difference, methyl alcohol or ethanol water-absorbent are more intense again, are difficult to control its stability, this alcohols oil product be easy to be subjected to assorted oil in the storage tank filler tank and moisture content influence, cause the two-phase layering, vehicle motor can't normally be moved, and, vehicles dynamic performance occurs after directly adding and obviously descend owing to reasons such as pure fuel value are low, and air-fuel ratio is excessive, phenomenons such as fuel consumption increase influence its popularization and use.
Summary of the invention
The purpose of this invention is to provide the high efficiency environment friendly fuel for vehicle that strong, the molten water-based of a kind of stability can be high.
High efficiency environment friendly fuel for vehicle provided by the invention, it is made by the raw material of following parts by weight: 40~60 parts of methyl alcohol or ethanol, 20~40 parts of petroleum naphthas, 2~5 parts of tougheners, 3~5 parts of etherifying agents, combustion-supporting 0.1~0.3 part of 2~6 parts of agent, 0.2~0.5 part of anti-water solubilizer, 0.1~0.3 part of metal corrosion inhibitor and the antioxidizing and antigum agent that urges;
Described anti-water solubilizer adopts following method preparation: the weight proportion of oleic acid, thanomin being pressed 1:0.1~0.4 mixes 10~20 minutes promptly at normal temperature and pressure.
Described toughener is isopropylcarbinol or primary isoamyl alcohol.
Described etherifying agent is ether or isopropyl ether.
It is described that combustion-supporting to urge agent be toluene or dimethylbenzene.
Described metal corrosion inhibitor is a stearylamine.
Described antioxidizing and antigum agent is Resorcinol or T501.
The preparation method of this high efficiency environment friendly fuel for vehicle, it comprises the steps:
A, oleic acid, thanomin mixed by the weight proportion of 1:0.1~0.4 made anti-water solubilizer in 10~20 minutes;
B, under stirring condition, count by weight, successively methyl alcohol or 40~60 parts of ethanol, 20~40 parts of petroleum naphthas, 2~5 parts of tougheners, 3~5 parts of etherifying agents, combustion-supporting 2~6 parts of agent, 0.2~0.5 part of anti-water solubilizer, 0.1~0.3 part of metal corrosion inhibitor and the antioxidizing and antigum agent of urging are joined in the container for 0.1~0.3 part, after treating reinforced finishing, restir 20~30 minutes, afterwards, leave standstill and promptly got this fuel oil in 8~16 hours;
Above-mentionedly all carry out at normal temperatures and pressures.
Conversion of ethers of the present invention is abundant, changes methyl alcohol or alcoholic acid combustionproperty, and methyl alcohol or alcoholic acid incorporation are big.Anti-water solubilizer is made by oleic acid, thanomin, its molten water-based is further improved, be not subjected to the assorted oil in the storage tank filler tank and the influence of moisture content, can not cause the two-phase layering, can make alcohol gasoline that water or assorted oil filled perhaps that content does high to more than 1% by 0.3%, join again and various auxiliary agents, make it when guaranteeing that methyl alcohol or ethanol incorporation are big, can guarantee the stability of fuel oil again, and the dynamic performance of oil product strengthens obviously, fuel consumption descends, and does not have phenomenons such as corrosion swelling.Can modulate and meet 93 of national every standard #, 97 #The high-grade environment protection clean gasoline.
Through the quality test chamber sampling check of Maoming branch office of China Petrochemical Industry, assay sees Table one.
Embodiment
Embodiment one: oleic acid, thanomin are mixed promptly to get in 10 minutes by the weight proportion of 1:0.1 resist water solubilizer;
Then under stirring condition, successively methyl alcohol or ethanol 400Kg, petroleum naphtha 400Kg, primary isoamyl alcohol 20Kg, isopropyl ether 50Kg, dimethylbenzene 20Kg, anti-water solubilizer 5Kg, stearylamine 1Kg and Resorcinol 3Kg are joined in the container, after treating reinforced finishing, restir 20 minutes, afterwards, leave standstill and promptly got fuel oil in 8 hours;
Above-mentionedly all carry out at normal temperatures and pressures.Wherein methyl alcohol adopts the one-level anhydrous product, and all the other raw materials adopt product sold on the market.
Embodiment two: oleic acid, thanomin are mixed promptly to get in 20 minutes by the weight proportion of 1:0.4 resist water solubilizer;
Then under stirring condition, successively methyl alcohol or ethanol 600Kg, petroleum naphtha 200Kg, primary isoamyl alcohol 50Kg, isopropyl ether 30Kg, dimethylbenzene 60Kg, anti-water solubilizer 2Kg, stearylamine 3Kg and Resorcinol 1Kg are joined in the container, after treating reinforced finishing, restir 30 minutes, afterwards, leave standstill and promptly got fuel oil in 16 hours;
Above-mentionedly all carry out at normal temperatures and pressures.Wherein methyl alcohol adopts the one-level anhydrous product, and all the other raw materials adopt product sold on the market.
Embodiment three: oleic acid, thanomin are mixed promptly to get in 15 minutes by the weight proportion of 1:0.25 resist water solubilizer;
Then under stirring condition, successively methyl alcohol or ethanol 500Kg, petroleum naphtha 300Kg, primary isoamyl alcohol 35Kg, isopropyl ether 40Kg, dimethylbenzene 40Kg, anti-water solubilizer 3.5Kg, stearylamine 2Kg and Resorcinol 2Kg are joined in the container, after treating reinforced finishing, restir 25 minutes, afterwards, leave standstill and promptly got fuel oil in 12 hours;
Above-mentionedly all carry out at normal temperatures and pressures.Wherein methyl alcohol adopts the one-level anhydrous product, and all the other raw materials adopt product sold on the market.
Embodiment four: with embodiment one, just replace methyl alcohol with ethanol.
Embodiment five: with embodiment two, just replace methyl alcohol with ethanol.
Embodiment six: with embodiment three, just replace methyl alcohol with ethanol.
Table one:
Project Analytical results Test method
Boiling range: initial boiling point, ℃ 10% vaporization temperature, ℃ 50% vaporization temperature, ℃ 90% vaporization temperature, ℃ final boiling point, ℃ residual amount of heating up in a steamer, % (V/V) 48 56 62 139 170 1.2 GB/T6536
Mercaptan sulfur content, % (m/m) 0.0004 GB/T1792
The doctor test By SH/T0174
Copper corrosion (50 ℃, 3h) 1a GB/T5096
Mechanical impurity and moisture Do not have Range estimation
Water soluble acid or alkali Do not have GB/T259
Aromaticity content, % 17.2 GB/T11132
Olefin(e) centent, % 1.1 GB/T11132
Benzene content, % 0.39 SH/T0713
Research octane number (RON) (RON) 93 GB/T5487
Vapour pressure, KPa 56.8 GB/T8017
Inductive phase, min >1000 GB/T8018
Sulphur content, % (m/m) 0.019 GB/T380
Existent gum, mg/100ml 4 GB/T8019
Density (50 ℃), kg/m 3 735 GB/T1884 1885

Claims (7)

1, a kind of high efficiency environment friendly fuel for vehicle is characterized in that it is made by the raw material of following parts by weight: 40~60 parts of methyl alcohol or ethanol, 20~40 parts of petroleum naphthas, 2~5 parts of tougheners, 3~5 parts of etherifying agents, combustion-supporting 0.1~0.3 part of 2~6 parts of agent, 0.2~0.5 part of anti-water solubilizer, 0.1~0.3 part of metal corrosion inhibitor and the antioxidizing and antigum agent that urges;
Described anti-water solubilizer adopts following method preparation: the weight proportion of oleic acid, thanomin being pressed 1:0.1~0.4 mixes 10~20 minutes promptly at normal temperature and pressure.
2, high efficiency environment friendly fuel for vehicle according to claim 1 is characterized in that described toughener is isopropylcarbinol or primary isoamyl alcohol.
3, high efficiency environment friendly fuel for vehicle according to claim 1 is characterized in that described etherifying agent is ether or isopropyl ether.
4, high efficiency environment friendly fuel for vehicle according to claim 1 is characterized in that described combustion-supporting to urge agent be toluene or dimethylbenzene.
5, high efficiency environment friendly fuel for vehicle according to claim 1 is characterized in that described metal corrosion inhibitor is a stearylamine.
6, high efficiency environment friendly fuel for vehicle according to claim 1 is characterized in that described antioxidizing and antigum agent is Resorcinol or T501.
7, the preparation method of the described high efficiency environment friendly fuel for vehicle of claim 1 is characterized in that it comprises the steps:
A, oleic acid, thanomin mixed by the weight proportion of 1:0.1~0.4 made anti-water solubilizer in 10~20 minutes;
B, under stirring condition, count by weight, successively methyl alcohol or 40~60 parts of ethanol, 20~40 parts of petroleum naphthas, 2~5 parts of tougheners, 3~5 parts of etherifying agents, combustion-supporting 2~6 parts of agent, 0.2~0.5 part of anti-water solubilizer, 0.1~0.3 part of metal corrosion inhibitor and the antioxidizing and antigum agent of urging are joined in the container for 0.1~0.3 part, after treating reinforced finishing, restir 20~30 minutes, afterwards, leave standstill and promptly got this fuel oil in 8~16 hours;
Above-mentionedly all carry out at normal temperatures and pressures.
CN2008101989716A 2008-09-28 2008-09-28 High efficiency environment friendly fuel for vehicle Expired - Fee Related CN101392203B (en)

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CN101392203B CN101392203B (en) 2012-06-20

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Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103865596A (en) * 2013-12-20 2014-06-18 陈传伟 Method of preparing compound methanol gasoline additive
CN103987817A (en) * 2011-09-23 2014-08-13 布特马斯先进生物燃料有限责任公司 Isobutanol compositions for fuel blending and methods for the production thereof
CN104531235A (en) * 2014-12-09 2015-04-22 河南派尔生物技术有限公司 Methanol gasoline
CN105132046A (en) * 2015-07-07 2015-12-09 中国科学院广州能源研究所 Vehicle alcohol-hydrocarbon composite fuel and preparation method thereof
CN105885968A (en) * 2016-04-21 2016-08-24 梅州市中农新能源有限公司 Fuel oil for green-energy vehicles
CN108034461A (en) * 2017-12-13 2018-05-15 柳州市金升汽车配件有限公司 Alcohols fuel oil additive and preparation method thereof
CN108546575A (en) * 2018-05-15 2018-09-18 杨勇 Biological alcohol-based fuel oil hydrotropy solubilizer
CN108949254A (en) * 2018-07-17 2018-12-07 湖南绿盛源能源科技有限公司 A kind of methanol gasoline with protecting effect
CN109504473A (en) * 2018-12-10 2019-03-22 扬州全云通网络科技有限公司 Methanol gasoline
CN110066694A (en) * 2019-05-23 2019-07-30 金玖洲新能源有限公司 A kind of clean fuel and preparation method thereof

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE3307091A1 (en) * 1983-03-01 1984-09-06 Union Rheinische Braunkohlen Kraftstoff AG, 5000 Köln FUEL AND USE THEREOF
GB0110354D0 (en) * 2001-04-27 2001-06-20 Aae Technologies Internat Ltd Fuel additives
CN1740283A (en) * 2004-08-25 2006-03-01 翟雁萍 Co-solvent composition for compounding methanol gasoline
CN100344736C (en) * 2005-06-07 2007-10-24 上海精醇化工科技发展有限公司 Alcohol ether fuel additive

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103987817A (en) * 2011-09-23 2014-08-13 布特马斯先进生物燃料有限责任公司 Isobutanol compositions for fuel blending and methods for the production thereof
CN103865596A (en) * 2013-12-20 2014-06-18 陈传伟 Method of preparing compound methanol gasoline additive
CN103865596B (en) * 2013-12-20 2016-08-17 陈传伟 A kind of compound method of compound additive for methanol gasoline
CN104531235A (en) * 2014-12-09 2015-04-22 河南派尔生物技术有限公司 Methanol gasoline
CN105132046A (en) * 2015-07-07 2015-12-09 中国科学院广州能源研究所 Vehicle alcohol-hydrocarbon composite fuel and preparation method thereof
CN105885968A (en) * 2016-04-21 2016-08-24 梅州市中农新能源有限公司 Fuel oil for green-energy vehicles
CN108034461A (en) * 2017-12-13 2018-05-15 柳州市金升汽车配件有限公司 Alcohols fuel oil additive and preparation method thereof
CN108546575A (en) * 2018-05-15 2018-09-18 杨勇 Biological alcohol-based fuel oil hydrotropy solubilizer
CN108949254A (en) * 2018-07-17 2018-12-07 湖南绿盛源能源科技有限公司 A kind of methanol gasoline with protecting effect
CN109504473A (en) * 2018-12-10 2019-03-22 扬州全云通网络科技有限公司 Methanol gasoline
CN110066694A (en) * 2019-05-23 2019-07-30 金玖洲新能源有限公司 A kind of clean fuel and preparation method thereof

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