CN101386474B - Method for producing colored plating glass products - Google Patents
Method for producing colored plating glass products Download PDFInfo
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- CN101386474B CN101386474B CN2008101399812A CN200810139981A CN101386474B CN 101386474 B CN101386474 B CN 101386474B CN 2008101399812 A CN2008101399812 A CN 2008101399812A CN 200810139981 A CN200810139981 A CN 200810139981A CN 101386474 B CN101386474 B CN 101386474B
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- China
- Prior art keywords
- glass
- paint
- film
- color
- plating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000011521 glass Substances 0.000 title claims abstract description 47
- 238000007747 plating Methods 0.000 title claims abstract description 17
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 13
- 239000003973 paint Substances 0.000 claims abstract description 19
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 8
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 8
- 229920003180 amino resin Polymers 0.000 claims abstract description 7
- 229920001187 thermosetting polymer Polymers 0.000 claims abstract description 4
- 239000011248 coating agent Substances 0.000 claims description 25
- 238000000576 coating method Methods 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 12
- 239000012046 mixed solvent Substances 0.000 claims description 12
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 10
- 239000004593 Epoxy Substances 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 9
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 7
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 claims description 5
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 claims description 5
- 229920005989 resin Polymers 0.000 claims description 5
- 239000011347 resin Substances 0.000 claims description 5
- -1 polysiloxane Polymers 0.000 claims description 4
- 229920001296 polysiloxane Polymers 0.000 claims description 4
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 3
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000007711 solidification Methods 0.000 claims description 3
- 230000008023 solidification Effects 0.000 claims description 3
- 239000000203 mixture Substances 0.000 claims description 2
- 238000000034 method Methods 0.000 abstract description 9
- 230000000694 effects Effects 0.000 abstract description 7
- 239000003086 colorant Substances 0.000 abstract description 4
- 230000007547 defect Effects 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 3
- 239000000853 adhesive Substances 0.000 abstract description 2
- 230000001070 adhesive effect Effects 0.000 abstract description 2
- 229920000180 alkyd Polymers 0.000 abstract 1
- 239000003822 epoxy resin Substances 0.000 abstract 1
- 229920000647 polyepoxide Polymers 0.000 abstract 1
- 238000001771 vacuum deposition Methods 0.000 abstract 1
- 239000010408 film Substances 0.000 description 16
- 238000003756 stirring Methods 0.000 description 8
- 238000012360 testing method Methods 0.000 description 8
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 6
- 239000000047 product Substances 0.000 description 6
- 239000002023 wood Substances 0.000 description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 230000015572 biosynthetic process Effects 0.000 description 4
- 238000001704 evaporation Methods 0.000 description 4
- 238000009713 electroplating Methods 0.000 description 3
- 230000008020 evaporation Effects 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000000758 substrate Substances 0.000 description 3
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 3
- 229910052721 tungsten Inorganic materials 0.000 description 3
- 239000010937 tungsten Substances 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- 239000002253 acid Substances 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- 239000008199 coating composition Substances 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012467 final product Substances 0.000 description 2
- 239000005357 flat glass Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 230000036548 skin texture Effects 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 239000005995 Aluminium silicate Substances 0.000 description 1
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 1
- 241001122767 Theaceae Species 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 229910052750 molybdenum Inorganic materials 0.000 description 1
- 239000011733 molybdenum Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 238000005201 scrubbing Methods 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 239000006200 vaporizer Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The invention provides a method for producing colorized and plated glass products. The method comprises the following steps: spreading color transparent glass paint on a cleaned glass surface; then roasting the glass at a temperature of between 170 and 190 DEG C for 6 to 10 minutes to allow the paint to solidify into a film; and placing the roasted glass on a vacuum coating machine to carry out vacuum plating on the side with the paint film of the glass. The main film-forming materials of the color transparent paint include alkyd resin, amino resin, thermosetting acrylic resin and epoxy resin. After being formed, the paint film is characterized by bright color, high gloss, good transparency, strong adhesive force, excellent waterproof and heat-resistance performance. The method can make single or various colors and various textures or patterns on glass surfaces. The method is environmentally-friendly, energy-saving and easy to operate, and can make the surfaces of the glass products bright by plating a layer of film and create a magic effect of a single color by means of the reflection of a mirror surface generated by plating, thereby solving the defect that the color of the glass products made by the prior art is dim and lacks a bright sense.
Description
Technical field
The invention belongs to the painted production technique of glasswork, particularly a kind of production method of colored plating glass products.
Background technology
Glass is extensive application in daily life, except the glass curtain wall of all kinds of buildingss, and tea table, dining table, desk, teacup or the like; Especially some artworks also often adopt the glass manufacturing.Glass itself generally is the water white transparency shape, in making product, often need painted, to satisfy the requirement of Glass Craft, two kinds of methods are generally arranged at present glass coloring: a kind of is that pigment is directly admixed with other raw materials of glass, be put in the crucible through 1300-1500 degree high melt, but because pigment is mobile relatively poor, color is difficult to control; Another kind is that pigment is coated in the glassy product surface, comes off easily.
Summary of the invention
Technical problem to be solved by this invention provides a kind of production method of colored plating glass products, can make glass article surface vivid, embody a kind of color through electroplating the dreamlike effect of specular reflectance, being faint in color that glasswork occurs in the solution prior art is unglazed, can not very vivid sensory defect.
The production method of a kind of colored plating glass products of the present invention, it is characterized in that at cleaned glass surface coating chromatic transparent glass coating, under 170～190 ℃ of conditions, toast 6～10 minutes paint solidification film forming then, glass after roasting is put on the vacuum plating unit and is electroplated, the one side vacuum plating of paint film is being arranged, wherein said colour transparent glass paint is according to the parts by weight meter, comprise Synolac 16～19, aminoresin 12～15, thermosetting acrylic resin 16～19, Resins, epoxy 3～5, silane coupling agent 1～2 and mass concentration are 20% solvent-borne type metallized dye solution, solvent-borne type metallized dye solution is made up of metallized dye and fugitive constituent mixed solvent, wherein metallized dye is 5～7 weight parts, described fugitive constituent mixed solvent is according to the parts by weight meter, by dimethylbenzene 25～35, propyl carbinol 10～20 and pimelinketone 10～20 mix to be formed.
Also comprise flow agent 0.1～0.3 weight part in the above-mentioned colour transparent glass paint, described flow agent is polyether-modified polysiloxane flow agent.
Described silane coupling agent is Y-aminopropyl triethoxysilane, Y-(2,3-epoxy third oxygen) propyl trimethoxy silicane or N-(B-aminoethyl)--Y-aminopropyl trimethoxysilane.
Described metallized dye is selected from commercially available Red-04 type, Yellow-20 type, Blue-06 type or Green-975 type dye.
Prepare the method for this colour transparent glass paint, comprise the steps:
At first, the fugitive constituent mixed solvent is prepared: according to the parts by weight meter, form by dimethylbenzene 25～35, propyl carbinol 10～20 and pimelinketone 10～20 mixing, stand-by.
Secondly, the metallized dye powder is added in the above-mentioned fugitive constituent mixed solvent that has prepared, fully stirring formation mass concentration is 20% solvent-borne type metallized dye solution, and is stand-by;
Prepare coating then: accurately take by weighing Synolac, thermal-curable acrylic resin, aminoresin, Resins, epoxy, silane coupling agent and solvent-borne type metallized dye solution, flow agent if desired, add flow agent again, stir the colo(u)r coating that can form transparent homogeneous in 3～5 minutes.
This colour transparent glass paint is a main film forming substance with Synolac, aminoresin, thermosetting acrylic resin and Resins, epoxy, film after the coating film forming have beautiful in colour, gloss is high, transparency good, the characteristics of strong adhesion, water-fast good heat resistance.Problems such as another technical characterstic of this coating is to have overcome the storing temperature height that present most of coating exists aspect baking condition, and the time is long have shortened storing temperature and time on largely.Under 170 ℃ of bakings, 10 minutes is curable film-forming; Under 180 ℃ of baking conditions, 8 minutes is curable film-forming; Under 190 ℃ of baking conditions, 6 minutes is curable film-forming.
Colour transparent glass paint of the present invention makes coating have shades of colour owing to add the solvent-borne type metallized dye, when the glass article surface coating composition, can adopt the coating of one or more different colours to mix the multiple color of formation as required, perhaps the coating of different zones coating different colours is perhaps arbitrarily arranged in pairs or groups and is produced more natural color effects.Behind coating composition, can do different effect (skin texture, pattern etc.) as required, make pattern, color more diversified.
Vacuum plating is that solid material is placed in the vacuum chamber, and under vacuum condition, with the solid material heating evaporation, atom that is evaporated or molecular energy freely cover cloth to the wall of container.When the baseplate material that some are processed was placed on wherein, atom that is evaporated or molecule will be adsorbed on and form thin film on the substrate gradually.Vacuum plating has two kinds of methods, and the one, evaporation, the one, sputter.The present invention adopts known method of evaporating.The material heating evaporation of making film, it is deposited on the suitable surface in a vacuum.
Compared with prior art, the invention has the beneficial effects as follows: adhere to coating at glass surface, can make single or various color and different skin texture or pattern effects.Coating is strong at the film adhesive that glass surface forms, scrubbing resistance, and color is vivid attractive in appearance.The production method environmental protection, energy-conservation, easy handling.By electroplating a skim, can make glass article surface vivid, embody a kind of color through electroplating the dreamlike effect of specular reflectance, being faint in color of having solved that glasswork occurs in the prior art is unglazed, can not very vivid sensory defect.
Embodiment
Below in conjunction with embodiment the present invention is described.
Embodiment 1～2 is for preparing the method for colourful transparent coating, and the coating of different colours adopts the same way as preparation to get final product.
Embodiment 1:
At first, the fugitive constituent mixed solvent is prepared according to following weight part prescription: dimethylbenzene 30, pimelinketone 10, propyl carbinol 10.Stand-by.
Secondly, solvent-borne type metallized dye powder (Red-04 oil soluble transparency dye, Taiwan name Confucian scholar produces) is dissolved in the above-mentioned volatilization mixed solvent that has prepared, fully stirring formation mass concentration is 20% dye solution, and is stand-by.
The coating preparatory phase:
Accurately take by weighing 18g Synolac (model 3880, Jiangsu three wood are produced), thermal-curable acrylic resin 18g (model 9760, Jiangsu three wood are produced), aminoresin 13g (model 582-2, Jiangsu three wood are produced), Resins, epoxy 4g (model E-51, Jinan Tian Mao produces), (polyether-modified polysiloxane flow agent, model are F211 to flow agent, Weifang cloud flies chemical industry company limited and produces) 0.1g, silane coupling agent (Y-aminopropyl triethoxysilane) 1g, Red-04 solvent-borne type metallized dye solution (wherein Red-04 oil soluble transparency dye is 6g) stirs the colo(u)r coating that can form transparent homogeneous in 3～5 minutes.
During use, with the above-mentioned mixed solvent that has prepared the colo(u)r coating for preparing is diluted 1 times, after stirring, be painted on the clean sheet glass, under 180 ℃ of conditions, toasting 8 minutes is curable film-forming.Filming after testing has sticking power, hardness, water tolerance and weathering resistance preferably, and has glossiness height, advantage such as beautiful in colour.Film performance such as following table 1:
Table 1 film performance and testing method
| Test event | Grade | Testing method |
| Hardness | 6H | |
| Water tolerance | 24 hours 5H | |
| Acid resistance | 24 hours 3H | 5% acetum |
| Alkali resistance | 24 hours 3H | 5% sodium hydroxide solution |
Embodiment 2:
At first, the fugitive constituent mixed solvent is prepared according to following weight part prescription: dimethylbenzene 25, pimelinketone 20g, propyl carbinol 20g, stand-by.
Secondly, solvent-borne type metallized dye powder (Yellow-20 type oil soluble transparency dye, Taiwan name Confucian scholar produces) is dissolved in the above-mentioned fugitive constituent mixed solvent that has prepared, fully stirring formation mass concentration is 20% dye solution, and is stand-by;
The coating preparatory phase:
Accurately take by weighing 19g Synolac (model 3880, Jiangsu three wood are produced), thermal-curable acrylic resin 19g (model 9760, Jiangsu three wood are produced), aminoresin 15g (model 582-2, Jiangsu three wood are produced), Resins, epoxy 5g (model E-51, Jinan Tian Mao produces), flow agent (polyether-modified polysiloxane flow agent, model is F211, Weifang cloud flies chemical industry company limited and produces) 0.1g, silane coupling agent Y-(2,3-epoxy third oxygen) propyl trimethoxy silicane 1g, Yellow-20 solvent-borne type metallized dye solution (wherein Yellow-20 oil soluble transparency dye is 7g) stirs the colo(u)r coating that can form transparent homogeneous in 3～5 minutes.
During use, with the above-mentioned mixed solvent that has prepared the colo(u)r coating for preparing is diluted 1 times, after stirring, be painted on the clean sheet glass, under 190 ℃ of conditions, toasting 6 minutes is curable film-forming.Filming after testing has sticking power, hardness, water tolerance and weathering resistance preferably, and has glossiness height, advantage such as beautiful in colour.Film and have testing method and film performance such as following table 2:
| Test event | Grade | Testing method |
| Hardness | 6H | |
| Water tolerance | 24 hours 5H | |
| Acid resistance | 24 hours 4H | 5% acetum |
| Alkali resistance | 24 hours 4H | 5% sodium hydroxide solution |
Embodiment 3:
(1) will need galvanized glass to clean up with the automatic glass cleaning machine.
(2) cleaned glass being coated with colour transparent glass paint (as embodiment 1 and 2), is 50Cm*65cm in the glass sheet size, and coating 48g coating gets final product (can do needed color and effect).Toast 6～10 minutes paint solidification film forming then under 170～190 ℃ of conditions, the glass after baking is put on the vacuum plating unit and is electroplated, and the one side vacuum plating of paint film is being arranged.
Experimental procedure following (known technology):
1. coiling tungsten basket cleans tungsten basket and slide glass, and aluminium wire is dispeled oxide on surface.
2. the making substrate hides on slide glass, so that plated film forms step after finishing on substrate with a narrow kaolin.
3. tungsten basket and molybdenum boat are fixed on the electrode in the bell jar, and put into aluminium wire.
4 are evacuated to vacuum tightness reaches more than the 10-6torr start vaporizer plated film.
5. after plated film is finished, handle the follow-up work of vacuum unit.
Claims (4)
1. the production method of a colored plating glass products, it is characterized in that at cleaned glass surface coating chromatic transparent glass coating, under 170～190 ℃ of conditions, toast 6～10 minutes paint solidification film forming then, glass after roasting is put on the vacuum plating unit the one side vacuum plating of paint film, wherein said colour transparent glass paint is according to the parts by weight meter, comprise Synolac 16～19, aminoresin 12～15, thermosetting acrylic resin 16～19, Resins, epoxy 3～5, silane coupling agent 1～2 and mass concentration are 20% solvent-borne type metallized dye solution, solvent-borne type metallized dye solution is made up of metallized dye and fugitive constituent mixed solvent, wherein metallized dye is 5～7 weight parts, described fugitive constituent mixed solvent is according to the parts by weight meter, by dimethylbenzene 25～35, propyl carbinol 10～20 and pimelinketone 10～20 mix to be formed.
2. production method according to claim 1 is characterized in that also comprising in the described colour transparent glass paint flow agent 0.1～0.3 weight part, and described flow agent is polyether-modified polysiloxane flow agent.
3. production method according to claim 1 is characterized in that described silane coupling agent is Y-aminopropyl triethoxysilane, Y-(2,3-epoxy third oxygen) propyl trimethoxy silicane or N-(B-aminoethyl)--T-aminopropyl trimethoxysilane.
4. production method according to claim 1 is characterized in that described metallized dye is selected from Red-04 type, Yellow-20 type, Blue-06 type or Green-975 type dye.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101399812A CN101386474B (en) | 2008-09-09 | 2008-09-09 | Method for producing colored plating glass products |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2008101399812A CN101386474B (en) | 2008-09-09 | 2008-09-09 | Method for producing colored plating glass products |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101386474A CN101386474A (en) | 2009-03-18 |
| CN101386474B true CN101386474B (en) | 2011-04-20 |
Family
ID=40476179
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2008101399812A Expired - Fee Related CN101386474B (en) | 2008-09-09 | 2008-09-09 | Method for producing colored plating glass products |
Country Status (1)
| Country | Link |
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| CN (1) | CN101386474B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102416732A (en) * | 2011-10-11 | 2012-04-18 | 常熟市华夏建筑节能材料有限公司 | Coated glass |
| CN104371455B (en) * | 2014-11-24 | 2015-11-18 | 邢台锦辉玻璃有限公司 | Colored mirror and manufacture method thereof |
| CN104973799B (en) * | 2015-07-24 | 2017-04-12 | 山东嘉业日用制品有限公司 | Preparation method of electroplated tinted glass product |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1948199A (en) * | 2006-11-10 | 2007-04-18 | 华南理工大学 | Coloured transparent glass paint and its preparation method and application |
-
2008
- 2008-09-09 CN CN2008101399812A patent/CN101386474B/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1948199A (en) * | 2006-11-10 | 2007-04-18 | 华南理工大学 | Coloured transparent glass paint and its preparation method and application |
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| Publication number | Publication date |
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| CN101386474A (en) | 2009-03-18 |
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