CN101339971B - Light emitting diode packaging structure - Google Patents
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Abstract
Description
技术领域technical field
本发明是关于一种发光二极管封装结构,特别是关于一种具有高反射率、高耐热的发光二极管封装结构。The invention relates to a light emitting diode packaging structure, in particular to a light emitting diode packaging structure with high reflectivity and high heat resistance.
背景技术Background technique
为响应节约能源的目标,寻找出能够取代已知发光效率不佳的发光源业已成为发光技术的主流研究,以目前的技术而言,最具潜力的替代发光源应属发光二极管而当之无愧。In response to the goal of saving energy, it has become the mainstream research of luminous technology to find out the luminous source that can replace the known poor luminous efficiency. In terms of the current technology, the most potential alternative luminous source should be the light-emitting diode.
不过,众所周知地,就现有的发光二极管封装结构而言,以反射杯结构为例,其可由树脂或陶瓷材料所构成,其中,陶瓷材料的反射杯热传导效果较树脂材料的反射杯佳,然而,陶瓷材料(例如:氮化铝)所制作成的发光二极管封装结构在长、宽、高的最小尺寸极限仅能达到约3.0毫米*2.0毫米*1.2毫米的规格,且只能形成具有直角型态的封装结构,无法符合小型化发光二极管封装结构的需求,且不利于光线的反射,故,对于需使用小型化发光二极管封装结构作为发光源的携带式显示装置,仍需采用由树脂材(例如:聚对苯二酰对苯二胺,PPA)构成的反射杯。但,由于树脂材料本身的耐热性不佳,举例来说,聚对苯二酰对苯二胺在摄氏140度的操作温度下操作126小时后,会发生明显的黄化、劣化问题。However, it is well known that in terms of the existing light emitting diode packaging structure, taking the reflection cup structure as an example, it can be made of resin or ceramic materials, wherein the heat conduction effect of the reflection cup of ceramic material is better than that of resin material, but , the light-emitting diode package structure made of ceramic materials (such as: aluminum nitride) can only reach the specifications of about 3.0 mm * 2.0 mm * 1.2 mm in the minimum size limit of length, width, and height, and can only be formed with a right-angle shape. The packaging structure of the state cannot meet the needs of the miniaturized LED packaging structure, and is not conducive to the reflection of light. Therefore, for portable display devices that need to use the miniaturized LED packaging structure as a light source, it is still necessary to use a resin material ( For example: reflective cups made of poly(p-phenylene terephthalamide, PPA). However, due to the poor heat resistance of the resin material itself, for example, after 126 hours of operation at an operating temperature of 140 degrees Celsius, poly-p-phenylene terephthalamide will suffer from obvious yellowing and deterioration problems.
因此,如何提供一种发光二极管封装结构,其与已知的树脂材料反射杯相较,具有较高的反射率以及较长的操作时间,实属当前重要课题之一。Therefore, how to provide a light emitting diode packaging structure, which has higher reflectivity and longer operation time compared with the known reflective cup made of resin material, is one of the current important issues.
发明内容Contents of the invention
有鉴于上述课题,本发明的目的在于提供一种发光二极管封装结构,其可有效地反射发光二极管芯片发射出的光线以增加发光二极管封装结构的出光效率,同时可使发光二极管封装结构可承受更长时间的操作而不发生黄化或劣化的现象。In view of the above problems, the purpose of the present invention is to provide a light emitting diode packaging structure, which can effectively reflect the light emitted by the light emitting diode chip to increase the light extraction efficiency of the light emitting diode packaging structure, and at the same time make the light emitting diode packaging structure more durable. Long-term operation without yellowing or deterioration.
为达上述目的,本发明揭露一种发光二极管封装结构,其包含一承载单元、一发光二极管芯片,位于承载单元上,以及一复合材料层,完全或局部覆盖于靠近发光二极管芯片的承载单元的表面上,复合材料层包含一树脂材料,具有一第一折射系数;以及一无机介电材料,掺混于树脂材料内,无机介电材料具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。To achieve the above purpose, the present invention discloses a light emitting diode packaging structure, which includes a carrying unit, a light emitting diode chip, located on the carrying unit, and a composite material layer, completely or partially covering the carrying unit close to the light emitting diode chip On the surface, the composite material layer includes a resin material with a first refractive index; and an inorganic dielectric material mixed in the resin material, the inorganic dielectric material has a second refractive index, wherein the first refractive index is less than a second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.
为达上述目的,本发明亦同时揭露一种发光二极管封装结构,其包含一承载单元以及一发光二极管芯片。承载单元具有一底部与一侧壁而形成一容置空间,发光二极管芯片位于底部上且位于容置空间内。承载单元包含一树脂材料以及一无机介电材料,树脂材料具有一第一折射系数,无机介电材料掺混于树脂材料内,且无机介电材料具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。To achieve the above purpose, the present invention also discloses a light emitting diode packaging structure, which includes a carrying unit and a light emitting diode chip. The carrying unit has a bottom and a side wall to form an accommodating space, and the LED chip is located on the bottom and in the accommodating space. The carrying unit includes a resin material and an inorganic dielectric material, the resin material has a first refractive index, the inorganic dielectric material is mixed in the resin material, and the inorganic dielectric material has a second refractive index, wherein the first refractive index The index is smaller than the second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.
而上述的树脂材料的材质可为硅胶,且树脂材料的折射系数(第一折射系数)介于1.3至1.6之间。The above-mentioned resin material can be made of silica gel, and the refractive index (first refractive index) of the resin material is between 1.3 and 1.6.
无机介电材料则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁或氧化锆,且无机介电材料(第二折射系数)则是介于1.7至2.3之间。The inorganic dielectric material can choose boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, magnesium oxide or zirconium oxide, and the inorganic dielectric material (second refractive index) is between 1.7 and 2.3 .
另外,无机介电材料掺混于树脂材料的重量百分比大于10%,更明确地说,此重量百分比应介于10%至40%之间。In addition, the weight percentage of the inorganic dielectric material mixed with the resin material is greater than 10%, more specifically, the weight percentage should be between 10% and 40%.
而由树脂材料与无机介电材料所构成的复合材料层对于可见光或紫外光的反射率大于或等于85%。And the reflectivity of the composite material layer composed of resin material and inorganic dielectric material to visible light or ultraviolet light is greater than or equal to 85%.
承上所述,依据本发明的一种发光二极管封装结构,其利用无机介电材料掺混于树脂材料内以提升复合材料的反射率,藉以使位于承载单元上或位于承载单元的容置空间内的发光二极管芯片所产生出的光线在经过有效的反射后射出至封装结构外,同时通过此一复合材料较佳的光反射及耐热特性,使得光线能量及芯片产生的热量不至于大量地累积或影响发光二极管封装结构。因此,纵使对于具有较强能量的紫外光发光二极管芯片而言,本发明所揭露的发光二极管封装结构仍可通过复合材料的光反射特性以降低光线能量的累积而导致的黄化、劣化等现象。Based on the above, according to a light-emitting diode packaging structure of the present invention, it utilizes inorganic dielectric materials mixed in the resin material to improve the reflectivity of the composite material, so that the light-emitting diodes located on the carrying unit or in the accommodating space of the carrying unit The light generated by the light-emitting diode chip inside is emitted out of the packaging structure after being effectively reflected. Accumulate or affect the LED packaging structure. Therefore, even for ultraviolet light-emitting diode chips with relatively strong energy, the light-emitting diode packaging structure disclosed in the present invention can still reduce yellowing and deterioration caused by the accumulation of light energy through the light reflection characteristics of the composite material. .
与已知技术相较,本发明可通过材料改质以提升发光二极管封装结构对于光线的反射率,且由于无须改变现有的制作方法即可实现上述的目的,因此,本发明除了可提升发光二极管封装结构的出光效率,更因其优异的反射及耐热特性,大幅延长了发光二极管封装结构的使用寿命。Compared with the known technology, the present invention can improve the light reflectance of the light-emitting diode packaging structure by modifying the material, and the above-mentioned purpose can be achieved without changing the existing manufacturing method. Therefore, the present invention can not only improve the luminous The light extraction efficiency of the diode packaging structure, and because of its excellent reflection and heat resistance characteristics, greatly prolongs the service life of the light emitting diode packaging structure.
附图说明Description of drawings
图1A为发光二极管封装结构的立体图;1A is a perspective view of a light emitting diode packaging structure;
图1B为沿图1A中截线L的发光二极管封装结构截面图;FIG. 1B is a cross-sectional view of the light emitting diode package structure along the section line L in FIG. 1A;
图1C为图1A的另一种态样的立体图;Fig. 1C is a perspective view of another aspect of Fig. 1A;
图2为本发明的发光二极管封装结构的另一实施例;Fig. 2 is another embodiment of the light emitting diode packaging structure of the present invention;
图3为本发明的发光二极管封装结构的再一实施例;以及Fig. 3 is yet another embodiment of the LED packaging structure of the present invention; and
图4为本发明的发光二极管封装结构的又一实施例。FIG. 4 is another embodiment of the packaging structure of the light emitting diode of the present invention.
附图标号:Figure number:
1a、1a’、1b、1c、1d:发光二极管封装结构1a, 1a', 1b, 1c, 1d: LED packaging structure
11:容置空间11: Storage space
12、12’:承载单元12, 12': carrying unit
121:底部121: Bottom
122、122’:侧壁122, 122': side wall
13:封装胶体13: Packaging colloid
14:发光二极管芯片14: LED chip
16:复合材料层16: Composite layer
161:树脂材料161: resin material
162:无机介电材料162: Inorganic Dielectric Materials
18:反射电极18: reflective electrode
L:截线L: cut line
具体实施方式Detailed ways
以下将参照相关图式,说明本发明较佳实施例的一种发光二极管封装结构。A light emitting diode packaging structure according to a preferred embodiment of the present invention will be described below with reference to related drawings.
首先,请同时参照图1A、图1B与图1C所示,其中图1A为发光二极管封装结构的立体图,而图1B则为沿图1A中截线L的发光二极管封装结构截面图,图1C则为图1A的另一种态样的立体图。First, please refer to FIG. 1A, FIG. 1B and FIG. 1C at the same time, wherein FIG. 1A is a perspective view of the LED package structure, and FIG. 1B is a cross-sectional view of the LED package structure along the section line L in FIG. 1A, and FIG. It is a perspective view of another aspect of FIG. 1A.
首先,根据图1A及图1B中所示的发光二极管封装结构1a可知,其包含有一承载单元12、一发光二极管芯片14、一复合材料层16及一反射电极18。承载单元12与发光二极管芯片14之间设置反射电极18,换言之,反射电极18设置于承载单元12上,且发光二极管芯片14位于反射电极18上;在本实施例中,复合材料层16局部覆盖于靠近发光二极管芯片14的承载单元12的表面上。Firstly, according to the LED package structure 1 a shown in FIG. 1A and FIG. 1B , it includes a
其中,承载单元12包含一底部121与一侧壁122,形成容置空间11,在本实施例中,底部121呈矩形,而发光二极管芯片14与反射电极18则是设置在底部121上且位于此容置空间11内。且,根据图1A与图1B所示可知,于此的反射电极18是以未完全遮蔽承载单元12底部121的态样为例说明,不过实际上,反射电极18亦可为完全遮蔽承载单元12底部121的型态(图未显示)。另外,于此所述的底部121与侧壁122虽各自为单独结构者,然而,亦可为一体成型的结构者。Wherein, the carrying
是以,由于在本实施例中局部的底部121表面并未被反射电极18遮蔽,因此复合材料层16除了可完全覆盖在靠近发光二极管芯片14的承载单元12的侧壁122表面上之外,更同时覆盖在上述未被反射电极18遮蔽的底部121表面上,如图1A与图1B所示。Therefore, since the surface of the part of the bottom 121 is not covered by the
而复合材料层16则包含一树脂材料161以及一无机介电材料162(如图1B中放大的部分所示),树脂材料161具有一第一折射系数;无机介电材料162掺混于树脂材料161内,并具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。The
对于复合材料层16的形成位置来说,除了如图1A(或图1B)所示的态样外,复合材料层16亦可完全覆盖于靠近发光二极管芯片14的承载单元12的表面上,亦即,除了可完全覆盖在靠近发光二极管芯片14的承载单元12的侧壁122表面上之外,更同时覆盖在上述反射电极18与未被反射电极18遮蔽的底部121表面上;或者,复合材料层16更可局部地覆盖于承载单元12的侧壁122上,如图1C所示的发光二极管封装结构1a’,当然,此时的复合材料层16亦覆盖于局部的底部121表面上。值得注意的是,由于图1C中所示的发光二极管封装结构1a’的底部121与侧壁122所构成的容置空间11亦为长方体,为了减少复合材料层16的用量,但仍维持一定的均热与光线反射的效率,复合材料层16是选择性地覆盖于较靠近于发光二极管芯片14的侧壁122上,也就是复合材料层16覆盖于具有较长长度的侧壁122表面上。由此可知,无论复合材料层16是以局部覆盖于承载单元12(包含底部121与侧壁122)的态样,或是完全覆盖于承载单元12的态样,最主要的特征在于复合材料层16必须至少覆盖于较靠近发光二极管芯片14的承载单元12的表面,当然,底部121的形状不限于上述的矩形态样,亦可为其他形状,例如可为椭圆形,此时,复合材料层16可选择性地覆盖于较靠近于发光二极管芯片14的侧壁上,也就是复合材料层16至少覆盖于靠近椭圆形短轴附近的侧壁表面上。For the formation position of the
并且,上述的复合材料层16的厚度大于或等于0.1毫米(mm),不过在实际的应用上,复合材料层16的厚度可依据不同产品的设计而变化,例如,复合材料层16更可能为均匀厚度者或是有厚度变化者。And, the thickness of above-mentioned
以材料来说,上述承载单元12的底部121可为电路板,例如由环氧树脂(EPOXY)构成,而承载单元12的侧壁122可选择硅胶、聚对苯二酰对苯二胺(PPA)、聚甲基丙烯酸甲酯(PMMA)、环氧树脂(EPOXY)、聚乙烯对苯二甲酸酯(PET)、聚碳酸树脂(PC)或聚四氟乙烯(PTFE)为材料;然而,承载单元12亦可为一体成型的结构,亦即,其底部121与侧壁122为相同材质,例如硅胶、聚对苯二酰对苯二胺(PPA)、聚甲基丙烯酸甲酯(PMMA)、环氧树脂(EPOXY)、聚乙烯对苯二甲酸酯(PET)、聚碳酸树脂(PC)或是聚四氟乙烯(PTFE)。In terms of materials, the
而上述的复合材料层16中的树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而复合材料层16中的无机介电材料162则可根据不同产品的设计与需求,以选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。另外,上述无机介电材料162掺混于树脂材料161的重量百分比大于10%,较佳的是,此重量百分比介于10%至40%之间,藉以使所形成的复合材料层16在可见光或紫外光的环境下,可达到大于或等于85%的反射率。The above-mentioned
据此,由于图1B的实施例中的发光二极管芯片14位于承载单元12上的反射电极18上,且复合材料层16覆盖相邻于反射电极18的该承载单元12的表面。因此,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1a外,如图1B中的实线箭头所示,而部分的光线则会通过复合材料层16的高反射特性以反射至发光二极管封装结构1a之外,如图1B中的虚线箭头所示。是以,本发明所揭露的发光二极管封装结构1a所提供的亮度将会因为反射的光线量增加而提升,并且,因复合材料层16为掺混无机介电材料162的树脂材料161,具有较佳的导热特性而可达均热效果,使原集中于发光二极管芯片14附近的热能够通过复合材料层16与反射电极18的配合设置而均匀分散。同理,虽然图1C中所揭露的复合材料层16仅局部覆盖于靠近于发光二极管芯片14的承载单元12的表面上,不过通过此种复合材料层16的配置仍可使发光二极管封装结构1a’达成与上述近似的效果,故于此将不再赘述。Accordingly, since the
另外,虽图1A至图1C中所示的实施例均以复合材料层16覆盖于反射杯的态样为例说明,但图中所示的反射杯结构并不用以限定本发明的范围。In addition, although the embodiments shown in FIG. 1A to FIG. 1C all take the
再者,请参照图2所示,其为本发明所揭露的发光二极管封装结构的另一实施例。在此发光二极管封装结构1b中亦包含有一承载单元12、一发光二极管芯片14以及一复合材料层16。承载单元12包含一底部121与一侧壁122,并藉以形成一容置空间11,而发光二极管芯片14位于承载单元12的底部121上且位于容置空间11内。Furthermore, please refer to FIG. 2 , which is another embodiment of the LED packaging structure disclosed in the present invention. The LED packaging structure 1 b also includes a carrying
其中,承载单元12中的底部121与侧壁122虽以独立结构者为例,然而,底部121与侧壁122亦可为一体成型者,换言之,承载单元12中的底部121与侧壁122可通过各种加工方法以构成一体成型的结构。Wherein, although the bottom 121 and the
并且,为搭配本实施例中的承载单元12结构,于此所揭露的复合材料层16的设置位置完全覆盖于侧壁122的表面,但不限于此,复合材料层16亦可局部或完全覆盖于靠近发光二极管芯片14的侧壁122与底部121的表面,或仅局部覆盖于靠近发光二极管芯片14的侧壁122的表面。就复合材料层16的构成来说,其仍包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),且无机介电材料162掺混于树脂材料161内;其中,树脂材料161具有一第一折射系数,无机介电材料162则具有一第二折射系数,并且,第一折射系数与第二折射系数的关系仍符合第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2的关系。另外,复合材料层16的厚度仍符合于大于或等于0.1毫米的范围。Moreover, in order to match the structure of the bearing
以材料来说,承载单元12、复合材料层16中的树脂材料161以及复合材料层16中的无机介电材料162可选用如图1B中所载的材料,于此不再赘述。而承载单元12中的底部121可为电路板、导线架...等结构。另外,侧壁122所选用的材质则与承载单元12相似,换言之,也就是包括有硅胶、聚对苯二酰对苯二胺、聚甲基丙烯酸甲酯、环氧树脂、聚乙烯对苯二甲酸酯、聚碳酸树脂、聚四氟乙烯。In terms of materials, the carrying
据此,虽本实施例中的发光二极管芯片14位于承载单元12的容置空间11内,不过由于复合材料层16仍至少形成于靠近发光二极管芯片14的承载单元12的表面(也就是复合材料层16可环绕着发光二极管芯片14周边以形成,亦可选择性地形成在承载单元12的局部表面上),因此,与图1B所示的实施例相似,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1b外,如图2中的实线箭头所示,而部分的光线则会通过复合材料层16的高反射特性以反射至发光二极管封装结构1b之外,如图2中的虚线箭头所示。是以,本发明所揭露的发光二极管封装结构1b所提供的亮度可通过反射光线量的增加而提升。Accordingly, although the light-emitting
本发明的发光二极管封装结构除上述图1B与图2所示的实施例之外,于图3中则揭露本发明的另一种实施例。于此实施例的发光二极管封装结构1c中包含有一承载单元12’以及一发光二极管芯片14。承载单元12’具有一底部121与一侧壁122’,发光二极管芯片14位于承载单元12’的底部121上。其中,承载单元12’的侧壁122’为复合材料层16,包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),树脂材料161具有一第一折射系数,无机介电材料162掺混于树脂材料161内,且无机介电材料162具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。In addition to the above-mentioned embodiments shown in FIG. 1B and FIG. 2 , another embodiment of the present invention is disclosed in FIG. 3 for the packaging structure of the light emitting diode of the present invention. The LED packaging structure 1c of this embodiment includes a carrying unit 12' and a
就承载单元12’的结构而言,图3所揭露的底部121与侧壁122’虽是以独立结构为例,不过亦可为一体成型的结构,换言之,承载单元12’中的底部121与侧壁122’可通过各种加工方法以构成一体成型的结构。As far as the structure of the carrying unit 12' is concerned, although the bottom 121 and the side wall 122' disclosed in FIG. The sidewall 122' can be formed as an integral structure through various processing methods.
以材料来说,承载单元12’的底部121可为电路板,而承载单元12’的侧壁122’则为包含有树脂材料161及掺混于树脂材料161内的无机介电材料162的结构。In terms of materials, the
值得注意的是,本实施例中树脂材料161与无机介电材料162的选取则与上述图1B、图2所揭露的实施例相同,换言之,树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而无机介电材料162则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组以为材料,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。另外,上述无机介电材料162掺混于树脂材料161的重量百分比大于10%,更精确来说,此重量百分比应介于10%至40%之间,藉以使由树脂材料161与无机介电材料162所构成的侧壁122’在可见光或紫外光的环境下,可达到大于或等于85%的反射率,或者,若承载单元12’中的底部121与侧壁122’为一体成型的结构,此时承载单元12’在可见光或紫外光的环境下的反射率可达到大于或等于85%。It should be noted that the selection of the
因此,由于本实施例中的发光二极管芯片14位于承载单元12’的底部121上,且承载单元12’的侧壁122’包含有树脂材料161与无机介电材料162。因此,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1c外,如图3中的实线箭头所示,而部分的光线则会通过树脂材料161与无机介电材料162的高反射特性以反射至发光二极管封装结构1c之外,如图3中的虚线箭头所示。是以,与图1B、图2所揭露的实施例相似,本实施例通过包含有树脂材料161与无机介电材料162的承载单元12’,以有效地反射来自发光二极管芯片14的光线,使整体发光二极管封装结构1c所提供的亮度增加。Therefore, since the
另外,在如图4中所揭露的实施例中,此一发光二极管封装结构1d包含有一承载单元12、一发光二极管芯片14、至少一反射电极18以及一复合材料层16。发光二极管芯片14位于承载单元12上;反射电极18则是位于发光二极管芯片14与承载单元12之间,而复合材料层16可局部或完全覆盖承载单元12相邻于反射电极18的承载单元12的表面上,更详细来说,以俯视的角度观(图未显示),覆盖在承载单元12相邻于反射电极18表面上的复合材料层16是以完全或局部环设于发光二极管芯片14的型态呈现。In addition, in the embodiment disclosed in FIG. 4 , the
当然,于此所述的复合材料层16的厚度仍符合大于或等于0.1毫米的要求,且相同于前述的实施例,此复合材料层16包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),且无机介电材料162掺混于树脂材料161内;树脂材料161具有一第一折射系数;无机介电材料162则具有一第二折射系数,并且,第一折射系数与第二折射系数之间仍符合第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2的范围条件。Of course, the thickness of the
其中,承载单元12可为电路板。并且,就本实施例所揭露的树脂材料161与无机介电材料162来说,树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而无机介电材料162则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组以为材料,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。Wherein, the carrying
据此可知,由于本实施例中的发光二极管芯片14位于承载单元12上,且复合材料层16局部或完全覆盖于承载单元12相邻于反射电极18的表面上。是以,本实施例通过复合材料层16与反射电极18的配合运用,可以有效地反射来自发光二极管芯片14的光线,且能达均热效果,使发光二极管芯片14产生的光线可有效地通过复合材料层16与反射电极18以进行反射,使整体发光二极管封装结构1d的出光效率提升,且可使原集中于发光二极管芯片14附近的热能够通过复合材料层16与反射电极18的设置而均匀分散。It can be seen that, since the
而无论对于上述图1A、图1B、图1C、图2、图3或图4中所示的发光二极管封装结构1a、1a’、1b、1c、1d来说,其中的发光二极管芯片14可为可见光发光二极管芯片或紫外光发光二极管芯片。不论是使用可见光发光二极管芯片或紫外光发光二极管芯片,本发明的复合材料层16均能够提高发光二极管封装结构的发光效率以及延长发光二极管封装结构的使用寿命。但是,须注意的是,对于承载单元上覆盖复合材料层的发光二极管封装结构而言,若覆盖于承载单元上的复合材料层中的无机介电材料为氮化硼、氧化铝或氮化铝,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但是,若覆盖于承载单元上的复合材料层中的无机介电材料为氧化铍、硫酸钡、氧化镁或氧化锆,则仅适用于紫外光发光二极管芯片。另外,对于承载单元内包含掺混的树脂材料以及无机介电材料的发光二极管封装结构而言,若树脂材料为硅胶,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但若树脂材料为聚对苯二酰对苯二胺、聚甲基丙烯酸甲酯、环氧树脂、聚乙烯对苯二甲酸酯或聚碳酸树脂,则仅适用于可见光发光二极管芯片;而无机介电材料的选择同上述,即,若承载单元中的无机介电材料为氮化硼、氧化铝或氮化铝,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但是,若承载单元中的无机介电材料为氧化铍、硫酸钡、氧化镁或氧化锆,则仅适用于紫外光发光二极管芯片。Regardless of the above-mentioned light emitting diode packaging structures 1a, 1a', 1b, 1c, 1d shown in Figure 1A, Figure 1B, Figure 1C, Figure 2, Figure 3 or Figure 4, the light emitting
以图3所示的发光二极管封装结构1c为例,由于其中的承载单元12’是由复合材料层16(包含有树脂材料161与无机介电材料162)所构成,因此所制作成的发光二极管封装结构1c在长、宽、高的尺寸能缩小至2.6毫米*1.6毫米*1.0毫米或更小规格(制作的方式可为射出成型),符合小型化的规格,同时更可形成具有斜角型态的封装结构。Taking the LED packaging structure 1c shown in FIG. 3 as an example, since the carrying unit 12' is composed of a composite material layer 16 (including a
特别的是,对于紫外光发光二极管芯片来说,因复合材料层16的树脂材料161为硅胶,而无机介电材料162为氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁或氧化锆,使复合材料层16对介于波长范围300纳米至430纳米间的紫外光的反射率极佳(至少大于85%),举例来说,以硅胶掺混氮化硼所构成的复合材料层(silicone/BN)来说,在波长为365纳米、光源强度为200mw/cm2的紫外光线照射下,其反射率可保持在91%左右,且在48小时的操作时间下,silicone/BN的复合材料层的反射率仅衰退约2%左右。然而,已知的纯陶瓷材料对于紫外光的反射率低于80%,故本发明具有复合材料层的发光二极管封装结构对于紫外光的反射率较已知由纯陶瓷材料所构成的发光二极管封装结构佳。Especially, for the ultraviolet light emitting diode chip, because the
另外,如图2所示的发光二极管封装结构1b,其因为在侧壁122的表面上覆盖有复合材料层16,因此相较于一般已知的发光二极管封装结构来说,此发光二极管封装结构1b更适用于封装紫外光发光二极管芯片。In addition, the light emitting diode packaging structure 1b shown in FIG. 2, because the surface of the
另外,于上述图1A、图1B、图1C、图2、图3及图4中所示的发光二极管封装结构1a、1a’、1b、1c、1d中均揭露有封装胶体13的结构。而如同已知的封装胶体,于此所揭露的封装胶体13内可含有荧光物质(图未显示),以使发光二极管芯片14产生出的光线可透过封装胶体13内的荧光物质的吸收与转换而以特定波长范围的光线射出于发光二极管封装结构1a、1a’、1b、1c、1d,换言之,封装胶体13内的荧光物质可使发光二极管芯片14产生出的光线呈现出特定颜色,举例来说,采用不同的荧光物质可使得经过封装胶体13的光线可呈现出红色、绿色、蓝色、黄色、白色...等颜色。In addition, the structure of the
另外,根据实际的加速老化试验结果显示,复合材料层(例如:硅胶掺混重量百分比30%的氮化硼,silicone/BN)与一般已知的环氧树脂或聚对苯二酰对苯二胺比较,silicone/BN的复合材料层具有较佳的热稳定性,一般而言,在摄氏140度的操作温度下操作接近1000小时左右,silicone/BN的复合材料层的反射率仅衰退至85%左右,且直到操作接近10000小时后,silicone/BN的复合材料层仍可保持有接近于20%的反射率,反观环氧树脂或聚对苯二酰对苯二胺在摄氏140度的操作温度下操作接近1000小时左右,环氧树脂和聚对苯二酰对苯二胺的反射率则分别衰退至70%和25%,且直到操作接近10000小时后,则均完全不具有任何反射光线的能力,换言之,环氧树脂与聚对苯二酰对苯二胺在这样的操作状态下,材料本身已完全发生劣化的情形。更值得一提的是,silicone/BN的复合材料层在摄氏160度的操作温度下操作1000小时后,仍可保持有约85%的反射率,当然,此时的环氧树脂或聚对苯二酰对苯二胺的反射率则别衰退至约30%和3%左右。故,若以正常LED操作温度小于80度的条件来说,使用silicone/BN的复合材料层可以大幅增加发光二极管封装结构的使用寿命。In addition, according to the actual accelerated aging test results, the composite material layer (for example: silica gel mixed with 30% by weight of boron nitride, silicone/BN) and commonly known epoxy resin or polyterephthalamide Compared with amines, the composite material layer of silicone/BN has better thermal stability. Generally speaking, the reflectivity of the composite material layer of silicone/BN only declines to 85 when operating at an operating temperature of 140 degrees Celsius for about 1000 hours. %, and until the operation is close to 10,000 hours, the silicone/BN composite layer can still maintain a reflectivity close to 20%, in contrast to the operation of epoxy resin or poly-p-phenylene terephthalamide at 140 degrees Celsius The reflectivity of epoxy resin and poly(p-phenylene terephthalamide) declines to 70% and 25% respectively when the temperature is close to 1000 hours, and there is no reflected light at all until the operation is close to 10,000 hours In other words, epoxy resin and poly-p-phenylene terephthalamide are in such an operating state that the material itself has completely deteriorated. What's more worth mentioning is that the composite layer of silicone/BN can still maintain a reflectivity of about 85% after operating at an operating temperature of 160 degrees Celsius for 1000 hours. The reflectance of diamide-p-phenylenediamide declines to about 30% and 3%. Therefore, if the normal LED operating temperature is less than 80 degrees, the use of the silicone/BN composite material layer can greatly increase the service life of the LED packaging structure.
根据上述可知,本发明所揭露的发光二极管封装结构利用无机介电材料掺混于树脂材料内的复合材料较佳的光反射及耐热特性,使得光线能量及芯片产生的热量较不易局部累积或影响发光二极管封装结构。因此,纵使对于具有较强能量的紫外光发光二极管芯片而言,本发明所揭露的发光二极管封装结构仍可通过复合材料的光反射特性以降低光线能量的累积所导致的黄化、劣化等现象。According to the above, the light emitting diode packaging structure disclosed in the present invention utilizes the better light reflection and heat resistance characteristics of the composite material mixed with the inorganic dielectric material in the resin material, so that the light energy and the heat generated by the chip are less likely to accumulate locally or Affects the packaging structure of light-emitting diodes. Therefore, even for ultraviolet light emitting diode chips with strong energy, the light emitting diode packaging structure disclosed in the present invention can still reduce yellowing and deterioration caused by the accumulation of light energy through the light reflection characteristics of the composite material .
以上所述仅为举例性,而非为限制性本发明。任何未脱离本发明的精神与范畴,而对其进行的等效修改或变更,均应包含于权利要求中。The above descriptions are for illustration only, rather than limiting the present invention. Any equivalent modifications or changes made without departing from the spirit and scope of the present invention shall be included in the claims.
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