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CN101339971B - Light emitting diode packaging structure - Google Patents

Light emitting diode packaging structure Download PDF

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Publication number
CN101339971B
CN101339971B CN2008101313879A CN200810131387A CN101339971B CN 101339971 B CN101339971 B CN 101339971B CN 2008101313879 A CN2008101313879 A CN 2008101313879A CN 200810131387 A CN200810131387 A CN 200810131387A CN 101339971 B CN101339971 B CN 101339971B
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package structure
light
emitting diode
inorganic dielectric
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CN101339971A (en
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杨健理
洪春长
林睿腾
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AUO Corp
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AU Optronics Corp
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Abstract

The invention provides a light emitting diode packaging structure which comprises a bearing unit, a light emitting diode chip and a composite material layer. The light emitting diode chip is positioned on the bearing unit; the composite material layer partially or completely covers the surface of the bearing unit close to the light-emitting diode chip. The composite material layer comprises a resin material and an inorganic dielectric material, wherein the resin material has a first refractive index; the inorganic dielectric material is mixed in the resin material and has a second refractive index, wherein the first refractive index is smaller than the second refractive index, and the difference between the first refractive index and the second refractive index is at least larger than 0.2. The invention can improve the reflectivity of the light-emitting diode packaging structure to light rays through material modification, improve the light-emitting efficiency of the light-emitting diode packaging structure and greatly prolong the service life of the light-emitting diode packaging structure.

Description

发光二极管封装结构 Light-emitting diode packaging structure

技术领域technical field

本发明是关于一种发光二极管封装结构,特别是关于一种具有高反射率、高耐热的发光二极管封装结构。The invention relates to a light emitting diode packaging structure, in particular to a light emitting diode packaging structure with high reflectivity and high heat resistance.

背景技术Background technique

为响应节约能源的目标,寻找出能够取代已知发光效率不佳的发光源业已成为发光技术的主流研究,以目前的技术而言,最具潜力的替代发光源应属发光二极管而当之无愧。In response to the goal of saving energy, it has become the mainstream research of luminous technology to find out the luminous source that can replace the known poor luminous efficiency. In terms of the current technology, the most potential alternative luminous source should be the light-emitting diode.

不过,众所周知地,就现有的发光二极管封装结构而言,以反射杯结构为例,其可由树脂或陶瓷材料所构成,其中,陶瓷材料的反射杯热传导效果较树脂材料的反射杯佳,然而,陶瓷材料(例如:氮化铝)所制作成的发光二极管封装结构在长、宽、高的最小尺寸极限仅能达到约3.0毫米*2.0毫米*1.2毫米的规格,且只能形成具有直角型态的封装结构,无法符合小型化发光二极管封装结构的需求,且不利于光线的反射,故,对于需使用小型化发光二极管封装结构作为发光源的携带式显示装置,仍需采用由树脂材(例如:聚对苯二酰对苯二胺,PPA)构成的反射杯。但,由于树脂材料本身的耐热性不佳,举例来说,聚对苯二酰对苯二胺在摄氏140度的操作温度下操作126小时后,会发生明显的黄化、劣化问题。However, it is well known that in terms of the existing light emitting diode packaging structure, taking the reflection cup structure as an example, it can be made of resin or ceramic materials, wherein the heat conduction effect of the reflection cup of ceramic material is better than that of resin material, but , the light-emitting diode package structure made of ceramic materials (such as: aluminum nitride) can only reach the specifications of about 3.0 mm * 2.0 mm * 1.2 mm in the minimum size limit of length, width, and height, and can only be formed with a right-angle shape. The packaging structure of the state cannot meet the needs of the miniaturized LED packaging structure, and is not conducive to the reflection of light. Therefore, for portable display devices that need to use the miniaturized LED packaging structure as a light source, it is still necessary to use a resin material ( For example: reflective cups made of poly(p-phenylene terephthalamide, PPA). However, due to the poor heat resistance of the resin material itself, for example, after 126 hours of operation at an operating temperature of 140 degrees Celsius, poly-p-phenylene terephthalamide will suffer from obvious yellowing and deterioration problems.

因此,如何提供一种发光二极管封装结构,其与已知的树脂材料反射杯相较,具有较高的反射率以及较长的操作时间,实属当前重要课题之一。Therefore, how to provide a light emitting diode packaging structure, which has higher reflectivity and longer operation time compared with the known reflective cup made of resin material, is one of the current important issues.

发明内容Contents of the invention

有鉴于上述课题,本发明的目的在于提供一种发光二极管封装结构,其可有效地反射发光二极管芯片发射出的光线以增加发光二极管封装结构的出光效率,同时可使发光二极管封装结构可承受更长时间的操作而不发生黄化或劣化的现象。In view of the above problems, the purpose of the present invention is to provide a light emitting diode packaging structure, which can effectively reflect the light emitted by the light emitting diode chip to increase the light extraction efficiency of the light emitting diode packaging structure, and at the same time make the light emitting diode packaging structure more durable. Long-term operation without yellowing or deterioration.

为达上述目的,本发明揭露一种发光二极管封装结构,其包含一承载单元、一发光二极管芯片,位于承载单元上,以及一复合材料层,完全或局部覆盖于靠近发光二极管芯片的承载单元的表面上,复合材料层包含一树脂材料,具有一第一折射系数;以及一无机介电材料,掺混于树脂材料内,无机介电材料具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。To achieve the above purpose, the present invention discloses a light emitting diode packaging structure, which includes a carrying unit, a light emitting diode chip, located on the carrying unit, and a composite material layer, completely or partially covering the carrying unit close to the light emitting diode chip On the surface, the composite material layer includes a resin material with a first refractive index; and an inorganic dielectric material mixed in the resin material, the inorganic dielectric material has a second refractive index, wherein the first refractive index is less than a second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.

为达上述目的,本发明亦同时揭露一种发光二极管封装结构,其包含一承载单元以及一发光二极管芯片。承载单元具有一底部与一侧壁而形成一容置空间,发光二极管芯片位于底部上且位于容置空间内。承载单元包含一树脂材料以及一无机介电材料,树脂材料具有一第一折射系数,无机介电材料掺混于树脂材料内,且无机介电材料具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。To achieve the above purpose, the present invention also discloses a light emitting diode packaging structure, which includes a carrying unit and a light emitting diode chip. The carrying unit has a bottom and a side wall to form an accommodating space, and the LED chip is located on the bottom and in the accommodating space. The carrying unit includes a resin material and an inorganic dielectric material, the resin material has a first refractive index, the inorganic dielectric material is mixed in the resin material, and the inorganic dielectric material has a second refractive index, wherein the first refractive index The index is smaller than the second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.

而上述的树脂材料的材质可为硅胶,且树脂材料的折射系数(第一折射系数)介于1.3至1.6之间。The above-mentioned resin material can be made of silica gel, and the refractive index (first refractive index) of the resin material is between 1.3 and 1.6.

无机介电材料则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁或氧化锆,且无机介电材料(第二折射系数)则是介于1.7至2.3之间。The inorganic dielectric material can choose boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, magnesium oxide or zirconium oxide, and the inorganic dielectric material (second refractive index) is between 1.7 and 2.3 .

另外,无机介电材料掺混于树脂材料的重量百分比大于10%,更明确地说,此重量百分比应介于10%至40%之间。In addition, the weight percentage of the inorganic dielectric material mixed with the resin material is greater than 10%, more specifically, the weight percentage should be between 10% and 40%.

而由树脂材料与无机介电材料所构成的复合材料层对于可见光或紫外光的反射率大于或等于85%。And the reflectivity of the composite material layer composed of resin material and inorganic dielectric material to visible light or ultraviolet light is greater than or equal to 85%.

承上所述,依据本发明的一种发光二极管封装结构,其利用无机介电材料掺混于树脂材料内以提升复合材料的反射率,藉以使位于承载单元上或位于承载单元的容置空间内的发光二极管芯片所产生出的光线在经过有效的反射后射出至封装结构外,同时通过此一复合材料较佳的光反射及耐热特性,使得光线能量及芯片产生的热量不至于大量地累积或影响发光二极管封装结构。因此,纵使对于具有较强能量的紫外光发光二极管芯片而言,本发明所揭露的发光二极管封装结构仍可通过复合材料的光反射特性以降低光线能量的累积而导致的黄化、劣化等现象。Based on the above, according to a light-emitting diode packaging structure of the present invention, it utilizes inorganic dielectric materials mixed in the resin material to improve the reflectivity of the composite material, so that the light-emitting diodes located on the carrying unit or in the accommodating space of the carrying unit The light generated by the light-emitting diode chip inside is emitted out of the packaging structure after being effectively reflected. Accumulate or affect the LED packaging structure. Therefore, even for ultraviolet light-emitting diode chips with relatively strong energy, the light-emitting diode packaging structure disclosed in the present invention can still reduce yellowing and deterioration caused by the accumulation of light energy through the light reflection characteristics of the composite material. .

与已知技术相较,本发明可通过材料改质以提升发光二极管封装结构对于光线的反射率,且由于无须改变现有的制作方法即可实现上述的目的,因此,本发明除了可提升发光二极管封装结构的出光效率,更因其优异的反射及耐热特性,大幅延长了发光二极管封装结构的使用寿命。Compared with the known technology, the present invention can improve the light reflectance of the light-emitting diode packaging structure by modifying the material, and the above-mentioned purpose can be achieved without changing the existing manufacturing method. Therefore, the present invention can not only improve the luminous The light extraction efficiency of the diode packaging structure, and because of its excellent reflection and heat resistance characteristics, greatly prolongs the service life of the light emitting diode packaging structure.

附图说明Description of drawings

图1A为发光二极管封装结构的立体图;1A is a perspective view of a light emitting diode packaging structure;

图1B为沿图1A中截线L的发光二极管封装结构截面图;FIG. 1B is a cross-sectional view of the light emitting diode package structure along the section line L in FIG. 1A;

图1C为图1A的另一种态样的立体图;Fig. 1C is a perspective view of another aspect of Fig. 1A;

图2为本发明的发光二极管封装结构的另一实施例;Fig. 2 is another embodiment of the light emitting diode packaging structure of the present invention;

图3为本发明的发光二极管封装结构的再一实施例;以及Fig. 3 is yet another embodiment of the LED packaging structure of the present invention; and

图4为本发明的发光二极管封装结构的又一实施例。FIG. 4 is another embodiment of the packaging structure of the light emitting diode of the present invention.

附图标号:Figure number:

1a、1a’、1b、1c、1d:发光二极管封装结构1a, 1a', 1b, 1c, 1d: LED packaging structure

11:容置空间11: Storage space

12、12’:承载单元12, 12': carrying unit

121:底部121: Bottom

122、122’:侧壁122, 122': side wall

13:封装胶体13: Packaging colloid

14:发光二极管芯片14: LED chip

16:复合材料层16: Composite layer

161:树脂材料161: resin material

162:无机介电材料162: Inorganic Dielectric Materials

18:反射电极18: reflective electrode

L:截线L: cut line

具体实施方式Detailed ways

以下将参照相关图式,说明本发明较佳实施例的一种发光二极管封装结构。A light emitting diode packaging structure according to a preferred embodiment of the present invention will be described below with reference to related drawings.

首先,请同时参照图1A、图1B与图1C所示,其中图1A为发光二极管封装结构的立体图,而图1B则为沿图1A中截线L的发光二极管封装结构截面图,图1C则为图1A的另一种态样的立体图。First, please refer to FIG. 1A, FIG. 1B and FIG. 1C at the same time, wherein FIG. 1A is a perspective view of the LED package structure, and FIG. 1B is a cross-sectional view of the LED package structure along the section line L in FIG. 1A, and FIG. It is a perspective view of another aspect of FIG. 1A.

首先,根据图1A及图1B中所示的发光二极管封装结构1a可知,其包含有一承载单元12、一发光二极管芯片14、一复合材料层16及一反射电极18。承载单元12与发光二极管芯片14之间设置反射电极18,换言之,反射电极18设置于承载单元12上,且发光二极管芯片14位于反射电极18上;在本实施例中,复合材料层16局部覆盖于靠近发光二极管芯片14的承载单元12的表面上。Firstly, according to the LED package structure 1 a shown in FIG. 1A and FIG. 1B , it includes a carrying unit 12 , an LED chip 14 , a composite material layer 16 and a reflective electrode 18 . A reflective electrode 18 is set between the carrying unit 12 and the LED chip 14, in other words, the reflective electrode 18 is set on the carrying unit 12, and the light emitting diode chip 14 is located on the reflective electrode 18; in this embodiment, the composite material layer 16 partially covers the on the surface of the carrying unit 12 close to the LED chip 14 .

其中,承载单元12包含一底部121与一侧壁122,形成容置空间11,在本实施例中,底部121呈矩形,而发光二极管芯片14与反射电极18则是设置在底部121上且位于此容置空间11内。且,根据图1A与图1B所示可知,于此的反射电极18是以未完全遮蔽承载单元12底部121的态样为例说明,不过实际上,反射电极18亦可为完全遮蔽承载单元12底部121的型态(图未显示)。另外,于此所述的底部121与侧壁122虽各自为单独结构者,然而,亦可为一体成型的结构者。Wherein, the carrying unit 12 includes a bottom 121 and a side wall 122 to form the accommodating space 11. In this embodiment, the bottom 121 is rectangular, and the LED chip 14 and the reflective electrode 18 are arranged on the bottom 121 and located at Inside this accommodating space 11. Moreover, according to FIG. 1A and FIG. 1B, it can be seen that the reflective electrode 18 here is described as an example in which the bottom 121 of the carrying unit 12 is not completely covered, but in fact, the reflective electrode 18 can also completely cover the carrying unit 12. The shape of the bottom 121 (not shown). In addition, although the bottom 121 and the side wall 122 described here are of separate structures, they can also be integrally formed.

是以,由于在本实施例中局部的底部121表面并未被反射电极18遮蔽,因此复合材料层16除了可完全覆盖在靠近发光二极管芯片14的承载单元12的侧壁122表面上之外,更同时覆盖在上述未被反射电极18遮蔽的底部121表面上,如图1A与图1B所示。Therefore, since the surface of the part of the bottom 121 is not covered by the reflective electrode 18 in this embodiment, the composite material layer 16 can completely cover the surface of the side wall 122 of the carrying unit 12 close to the LED chip 14, At the same time, it covers the surface of the bottom 121 that is not covered by the reflective electrode 18 , as shown in FIG. 1A and FIG. 1B .

而复合材料层16则包含一树脂材料161以及一无机介电材料162(如图1B中放大的部分所示),树脂材料161具有一第一折射系数;无机介电材料162掺混于树脂材料161内,并具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。The composite material layer 16 then includes a resin material 161 and an inorganic dielectric material 162 (as shown in the enlarged part in FIG. 1B ), the resin material 161 has a first refractive index; the inorganic dielectric material 162 is mixed with the resin material 161, and has a second refraction index, wherein the first refraction index is smaller than the second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.

对于复合材料层16的形成位置来说,除了如图1A(或图1B)所示的态样外,复合材料层16亦可完全覆盖于靠近发光二极管芯片14的承载单元12的表面上,亦即,除了可完全覆盖在靠近发光二极管芯片14的承载单元12的侧壁122表面上之外,更同时覆盖在上述反射电极18与未被反射电极18遮蔽的底部121表面上;或者,复合材料层16更可局部地覆盖于承载单元12的侧壁122上,如图1C所示的发光二极管封装结构1a’,当然,此时的复合材料层16亦覆盖于局部的底部121表面上。值得注意的是,由于图1C中所示的发光二极管封装结构1a’的底部121与侧壁122所构成的容置空间11亦为长方体,为了减少复合材料层16的用量,但仍维持一定的均热与光线反射的效率,复合材料层16是选择性地覆盖于较靠近于发光二极管芯片14的侧壁122上,也就是复合材料层16覆盖于具有较长长度的侧壁122表面上。由此可知,无论复合材料层16是以局部覆盖于承载单元12(包含底部121与侧壁122)的态样,或是完全覆盖于承载单元12的态样,最主要的特征在于复合材料层16必须至少覆盖于较靠近发光二极管芯片14的承载单元12的表面,当然,底部121的形状不限于上述的矩形态样,亦可为其他形状,例如可为椭圆形,此时,复合材料层16可选择性地覆盖于较靠近于发光二极管芯片14的侧壁上,也就是复合材料层16至少覆盖于靠近椭圆形短轴附近的侧壁表面上。For the formation position of the composite material layer 16, in addition to the aspect shown in FIG. That is, in addition to completely covering the surface of the side wall 122 of the carrying unit 12 close to the light-emitting diode chip 14, it also covers the above-mentioned reflective electrode 18 and the surface of the bottom 121 not covered by the reflective electrode 18; or, the composite material The layer 16 can also partially cover the sidewall 122 of the carrying unit 12 , as shown in the LED package structure 1 a ′ shown in FIG. 1C . Of course, the composite material layer 16 also partially covers the surface of the bottom 121 . It should be noted that since the accommodating space 11 formed by the bottom 121 and the side wall 122 of the light emitting diode package structure 1a' shown in FIG. For heat uniformity and light reflection efficiency, the composite material layer 16 is selectively covered on the sidewall 122 closer to the LED chip 14 , that is, the composite material layer 16 is covered on the surface of the longer sidewall 122 . It can be seen that no matter whether the composite material layer 16 partially covers the bearing unit 12 (including the bottom 121 and the side wall 122), or completely covers the bearing unit 12, the most important feature is that the composite material layer 16 must at least cover the surface of the carrying unit 12 that is closer to the light-emitting diode chip 14. Of course, the shape of the bottom 121 is not limited to the above-mentioned rectangular shape, and can also be other shapes, such as an ellipse. At this time, the composite material layer 16 may selectively cover the sidewall closer to the LED chip 14, that is, the composite material layer 16 covers at least the sidewall surface near the short axis of the ellipse.

并且,上述的复合材料层16的厚度大于或等于0.1毫米(mm),不过在实际的应用上,复合材料层16的厚度可依据不同产品的设计而变化,例如,复合材料层16更可能为均匀厚度者或是有厚度变化者。And, the thickness of above-mentioned composite material layer 16 is greater than or equal to 0.1 millimeter (mm), but in actual application, the thickness of composite material layer 16 can change according to the design of different products, for example, composite material layer 16 is more likely to be Uniform thickness or thickness variation.

以材料来说,上述承载单元12的底部121可为电路板,例如由环氧树脂(EPOXY)构成,而承载单元12的侧壁122可选择硅胶、聚对苯二酰对苯二胺(PPA)、聚甲基丙烯酸甲酯(PMMA)、环氧树脂(EPOXY)、聚乙烯对苯二甲酸酯(PET)、聚碳酸树脂(PC)或聚四氟乙烯(PTFE)为材料;然而,承载单元12亦可为一体成型的结构,亦即,其底部121与侧壁122为相同材质,例如硅胶、聚对苯二酰对苯二胺(PPA)、聚甲基丙烯酸甲酯(PMMA)、环氧树脂(EPOXY)、聚乙烯对苯二甲酸酯(PET)、聚碳酸树脂(PC)或是聚四氟乙烯(PTFE)。In terms of materials, the bottom 121 of the carrying unit 12 can be a circuit board, for example, made of epoxy resin (EPOXY), and the side wall 122 of the carrying unit 12 can be selected from silica gel, poly-p-phenylene terephthalamide (PPA ), polymethyl methacrylate (PMMA), epoxy resin (EPOXY), polyethylene terephthalate (PET), polycarbonate resin (PC) or polytetrafluoroethylene (PTFE) as materials; however, The supporting unit 12 can also be an integrated structure, that is, the bottom 121 and the side wall 122 are made of the same material, such as silica gel, poly-p-phenylene terephthalamide (PPA), polymethyl methacrylate (PMMA) , epoxy resin (EPOXY), polyethylene terephthalate (PET), polycarbonate resin (PC) or polytetrafluoroethylene (PTFE).

而上述的复合材料层16中的树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而复合材料层16中的无机介电材料162则可根据不同产品的设计与需求,以选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。另外,上述无机介电材料162掺混于树脂材料161的重量百分比大于10%,较佳的是,此重量百分比介于10%至40%之间,藉以使所形成的复合材料层16在可见光或紫外光的环境下,可达到大于或等于85%的反射率。The above-mentioned resin material 161 in the composite material layer 16 is silica gel, and its corresponding first refractive index is between 1.3 and 1.6, while the inorganic dielectric material 162 in the composite material layer 16 can be made according to the requirements of different products. Design and requirements to select the group consisting of boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, magnesium oxide, zirconium oxide and their combinations, and the second refractive index corresponding to the above materials is Between 1.7 and 2.3. In addition, the weight percentage of the above-mentioned inorganic dielectric material 162 blended in the resin material 161 is greater than 10%. Or under the environment of ultraviolet light, it can achieve a reflectivity greater than or equal to 85%.

据此,由于图1B的实施例中的发光二极管芯片14位于承载单元12上的反射电极18上,且复合材料层16覆盖相邻于反射电极18的该承载单元12的表面。因此,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1a外,如图1B中的实线箭头所示,而部分的光线则会通过复合材料层16的高反射特性以反射至发光二极管封装结构1a之外,如图1B中的虚线箭头所示。是以,本发明所揭露的发光二极管封装结构1a所提供的亮度将会因为反射的光线量增加而提升,并且,因复合材料层16为掺混无机介电材料162的树脂材料161,具有较佳的导热特性而可达均热效果,使原集中于发光二极管芯片14附近的热能够通过复合材料层16与反射电极18的配合设置而均匀分散。同理,虽然图1C中所揭露的复合材料层16仅局部覆盖于靠近于发光二极管芯片14的承载单元12的表面上,不过通过此种复合材料层16的配置仍可使发光二极管封装结构1a’达成与上述近似的效果,故于此将不再赘述。Accordingly, since the LED chip 14 in the embodiment of FIG. 1B is located on the reflective electrode 18 on the carrier unit 12 , and the composite material layer 16 covers the surface of the carrier unit 12 adjacent to the reflective electrode 18 . Therefore, when the light-emitting diode chip 14 is supplied with current and generates light, part of the light will be directly emitted to the outside of the light-emitting diode packaging structure 1a, as shown by the solid arrow in FIG. 1B , and part of the light will pass through the composite material layer. 16 to reflect to the outside of the LED packaging structure 1a, as shown by the dotted arrow in FIG. 1B. Therefore, the brightness provided by the LED packaging structure 1a disclosed in the present invention will be improved due to the increase in the amount of reflected light, and because the composite material layer 16 is a resin material 161 mixed with an inorganic dielectric material 162, it has a higher Excellent heat conduction characteristics can achieve a heat uniform effect, so that the heat originally concentrated near the LED chip 14 can be evenly dispersed through the cooperative arrangement of the composite material layer 16 and the reflective electrode 18 . Similarly, although the composite material layer 16 disclosed in FIG. 1C only partially covers the surface of the carrying unit 12 close to the LED chip 14, the configuration of the composite material layer 16 can still make the LED packaging structure 1a 'Achieve an effect similar to the above, so it will not be repeated here.

另外,虽图1A至图1C中所示的实施例均以复合材料层16覆盖于反射杯的态样为例说明,但图中所示的反射杯结构并不用以限定本发明的范围。In addition, although the embodiments shown in FIG. 1A to FIG. 1C all take the composite material layer 16 covering the reflection cup as an example, the structure of the reflection cup shown in the figures is not intended to limit the scope of the present invention.

再者,请参照图2所示,其为本发明所揭露的发光二极管封装结构的另一实施例。在此发光二极管封装结构1b中亦包含有一承载单元12、一发光二极管芯片14以及一复合材料层16。承载单元12包含一底部121与一侧壁122,并藉以形成一容置空间11,而发光二极管芯片14位于承载单元12的底部121上且位于容置空间11内。Furthermore, please refer to FIG. 2 , which is another embodiment of the LED packaging structure disclosed in the present invention. The LED packaging structure 1 b also includes a carrying unit 12 , a LED chip 14 and a composite material layer 16 . The carrying unit 12 includes a bottom 121 and a side wall 122 to form an accommodating space 11 , and the LED chip 14 is located on the bottom 121 of the carrying unit 12 and is located in the accommodating space 11 .

其中,承载单元12中的底部121与侧壁122虽以独立结构者为例,然而,底部121与侧壁122亦可为一体成型者,换言之,承载单元12中的底部121与侧壁122可通过各种加工方法以构成一体成型的结构。Wherein, although the bottom 121 and the side wall 122 in the carrying unit 12 are taken as an example of an independent structure, however, the bottom 121 and the side wall 122 can also be integrally formed, in other words, the bottom 121 and the side wall 122 in the carrying unit 12 can be Various processing methods are used to form an integrally formed structure.

并且,为搭配本实施例中的承载单元12结构,于此所揭露的复合材料层16的设置位置完全覆盖于侧壁122的表面,但不限于此,复合材料层16亦可局部或完全覆盖于靠近发光二极管芯片14的侧壁122与底部121的表面,或仅局部覆盖于靠近发光二极管芯片14的侧壁122的表面。就复合材料层16的构成来说,其仍包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),且无机介电材料162掺混于树脂材料161内;其中,树脂材料161具有一第一折射系数,无机介电材料162则具有一第二折射系数,并且,第一折射系数与第二折射系数的关系仍符合第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2的关系。另外,复合材料层16的厚度仍符合于大于或等于0.1毫米的范围。Moreover, in order to match the structure of the bearing unit 12 in this embodiment, the position of the composite material layer 16 disclosed here completely covers the surface of the side wall 122, but it is not limited thereto, and the composite material layer 16 can also partially or completely cover on the surface close to the sidewall 122 and the bottom 121 of the LED chip 14 , or only partially cover the surface close to the sidewall 122 of the LED chip 14 . As far as the composition of the composite material layer 16 is concerned, it still includes a resin material 161 and an inorganic dielectric material 162 (as shown in the enlarged part in the figure), and the inorganic dielectric material 162 is mixed in the resin material 161; , the resin material 161 has a first refraction index, the inorganic dielectric material 162 has a second refraction index, and the relationship between the first refraction index and the second refraction index still conforms to the fact that the first refraction index is smaller than the second refraction index, and The difference between the first refractive index and the second refractive index is at least greater than 0.2. In addition, the thickness of the composite material layer 16 still conforms to the range greater than or equal to 0.1 mm.

以材料来说,承载单元12、复合材料层16中的树脂材料161以及复合材料层16中的无机介电材料162可选用如图1B中所载的材料,于此不再赘述。而承载单元12中的底部121可为电路板、导线架...等结构。另外,侧壁122所选用的材质则与承载单元12相似,换言之,也就是包括有硅胶、聚对苯二酰对苯二胺、聚甲基丙烯酸甲酯、环氧树脂、聚乙烯对苯二甲酸酯、聚碳酸树脂、聚四氟乙烯。In terms of materials, the carrying unit 12 , the resin material 161 in the composite material layer 16 and the inorganic dielectric material 162 in the composite material layer 16 can be selected from the materials shown in FIG. 1B , which will not be repeated here. The bottom 121 of the carrying unit 12 can be a circuit board, a lead frame, etc. structure. In addition, the material selected for the side wall 122 is similar to that of the bearing unit 12, in other words, it includes silica gel, poly-p-phenylene terephthalamide, polymethyl methacrylate, epoxy resin, polyethylene terephthalamide, etc. Formate, polycarbonate, polytetrafluoroethylene.

据此,虽本实施例中的发光二极管芯片14位于承载单元12的容置空间11内,不过由于复合材料层16仍至少形成于靠近发光二极管芯片14的承载单元12的表面(也就是复合材料层16可环绕着发光二极管芯片14周边以形成,亦可选择性地形成在承载单元12的局部表面上),因此,与图1B所示的实施例相似,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1b外,如图2中的实线箭头所示,而部分的光线则会通过复合材料层16的高反射特性以反射至发光二极管封装结构1b之外,如图2中的虚线箭头所示。是以,本发明所揭露的发光二极管封装结构1b所提供的亮度可通过反射光线量的增加而提升。Accordingly, although the light-emitting diode chip 14 in this embodiment is located in the accommodating space 11 of the carrying unit 12, the composite material layer 16 is still formed at least on the surface of the carrying unit 12 close to the light-emitting diode chip 14 (that is, the composite material The layer 16 can be formed around the periphery of the LED chip 14, and can also be selectively formed on a partial surface of the carrying unit 12), therefore, similar to the embodiment shown in FIG. 1B, when the LED chip 14 is fed with current and After the light is generated, part of the light will be directly emitted to the outside of the LED packaging structure 1b, as shown by the solid arrow in FIG. Outside of structure 1b, as shown by the dotted arrow in Fig. 2. Therefore, the brightness provided by the LED packaging structure 1b disclosed in the present invention can be improved by increasing the amount of reflected light.

本发明的发光二极管封装结构除上述图1B与图2所示的实施例之外,于图3中则揭露本发明的另一种实施例。于此实施例的发光二极管封装结构1c中包含有一承载单元12’以及一发光二极管芯片14。承载单元12’具有一底部121与一侧壁122’,发光二极管芯片14位于承载单元12’的底部121上。其中,承载单元12’的侧壁122’为复合材料层16,包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),树脂材料161具有一第一折射系数,无机介电材料162掺混于树脂材料161内,且无机介电材料162具有一第二折射系数,其中,第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2。In addition to the above-mentioned embodiments shown in FIG. 1B and FIG. 2 , another embodiment of the present invention is disclosed in FIG. 3 for the packaging structure of the light emitting diode of the present invention. The LED packaging structure 1c of this embodiment includes a carrying unit 12' and a LED chip 14. The carrying unit 12' has a bottom 121 and a side wall 122', and the LED chip 14 is located on the bottom 121 of the carrying unit 12'. Wherein, the side wall 122' of the carrying unit 12' is a composite material layer 16, including a resin material 161 and an inorganic dielectric material 162 (as shown in the enlarged part in the figure), the resin material 161 has a first refractive index, The inorganic dielectric material 162 is mixed in the resin material 161, and the inorganic dielectric material 162 has a second refractive index, wherein the first refractive index is smaller than the second refractive index, and the difference between the first refractive index and the second refractive index Value is at least greater than 0.2.

就承载单元12’的结构而言,图3所揭露的底部121与侧壁122’虽是以独立结构为例,不过亦可为一体成型的结构,换言之,承载单元12’中的底部121与侧壁122’可通过各种加工方法以构成一体成型的结构。As far as the structure of the carrying unit 12' is concerned, although the bottom 121 and the side wall 122' disclosed in FIG. The sidewall 122' can be formed as an integral structure through various processing methods.

以材料来说,承载单元12’的底部121可为电路板,而承载单元12’的侧壁122’则为包含有树脂材料161及掺混于树脂材料161内的无机介电材料162的结构。In terms of materials, the bottom 121 of the carrying unit 12' can be a circuit board, and the sidewall 122' of the carrying unit 12' is a structure including a resin material 161 and an inorganic dielectric material 162 mixed in the resin material 161 .

值得注意的是,本实施例中树脂材料161与无机介电材料162的选取则与上述图1B、图2所揭露的实施例相同,换言之,树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而无机介电材料162则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组以为材料,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。另外,上述无机介电材料162掺混于树脂材料161的重量百分比大于10%,更精确来说,此重量百分比应介于10%至40%之间,藉以使由树脂材料161与无机介电材料162所构成的侧壁122’在可见光或紫外光的环境下,可达到大于或等于85%的反射率,或者,若承载单元12’中的底部121与侧壁122’为一体成型的结构,此时承载单元12’在可见光或紫外光的环境下的反射率可达到大于或等于85%。It should be noted that the selection of the resin material 161 and the inorganic dielectric material 162 in this embodiment is the same as the above-mentioned embodiments disclosed in FIG. 1B and FIG. The refractive index is between 1.3 and 1.6, and the inorganic dielectric material 162 can be selected from the group consisting of boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, magnesium oxide, zirconium oxide, and combinations thereof to materials, and the second refractive index corresponding to the above materials is between 1.7 and 2.3. In addition, the weight percentage of the above-mentioned inorganic dielectric material 162 blended in the resin material 161 is greater than 10%, more precisely, the weight percentage should be between 10% and 40%, so that the resin material 161 and the inorganic dielectric The side wall 122' formed by the material 162 can achieve a reflectivity greater than or equal to 85% under the environment of visible light or ultraviolet light, or, if the bottom 121 and the side wall 122' in the carrying unit 12' are integrally formed At this time, the reflectivity of the carrying unit 12 ′ in the environment of visible light or ultraviolet light can reach greater than or equal to 85%.

因此,由于本实施例中的发光二极管芯片14位于承载单元12’的底部121上,且承载单元12’的侧壁122’包含有树脂材料161与无机介电材料162。因此,当发光二极管芯片14通入电流并产生光线后,部分的光线会直接射出至发光二极管封装结构1c外,如图3中的实线箭头所示,而部分的光线则会通过树脂材料161与无机介电材料162的高反射特性以反射至发光二极管封装结构1c之外,如图3中的虚线箭头所示。是以,与图1B、图2所揭露的实施例相似,本实施例通过包含有树脂材料161与无机介电材料162的承载单元12’,以有效地反射来自发光二极管芯片14的光线,使整体发光二极管封装结构1c所提供的亮度增加。Therefore, since the LED chip 14 in this embodiment is located on the bottom 121 of the carrying unit 12', and the sidewall 122' of the carrying unit 12' includes the resin material 161 and the inorganic dielectric material 162. Therefore, when the light-emitting diode chip 14 is supplied with current and generates light, part of the light will be emitted directly to the outside of the light-emitting diode package structure 1c, as shown by the solid arrow in FIG. 3 , and part of the light will pass through the resin material 161 Due to the high reflective properties of the inorganic dielectric material 162 , it can be reflected to the outside of the LED packaging structure 1c, as shown by the dotted arrow in FIG. 3 . Therefore, similar to the embodiments disclosed in FIG. 1B and FIG. 2 , this embodiment uses the carrying unit 12 ′ including the resin material 161 and the inorganic dielectric material 162 to effectively reflect the light from the LED chip 14 , so that The brightness provided by the overall LED package structure 1c is increased.

另外,在如图4中所揭露的实施例中,此一发光二极管封装结构1d包含有一承载单元12、一发光二极管芯片14、至少一反射电极18以及一复合材料层16。发光二极管芯片14位于承载单元12上;反射电极18则是位于发光二极管芯片14与承载单元12之间,而复合材料层16可局部或完全覆盖承载单元12相邻于反射电极18的承载单元12的表面上,更详细来说,以俯视的角度观(图未显示),覆盖在承载单元12相邻于反射电极18表面上的复合材料层16是以完全或局部环设于发光二极管芯片14的型态呈现。In addition, in the embodiment disclosed in FIG. 4 , the LED packaging structure 1 d includes a carrying unit 12 , a LED chip 14 , at least one reflective electrode 18 and a composite material layer 16 . The light-emitting diode chip 14 is located on the carrying unit 12; the reflective electrode 18 is located between the light-emitting diode chip 14 and the carrying unit 12, and the composite material layer 16 can partially or completely cover the carrying unit 12 adjacent to the reflective electrode 18. In more detail, from a top view (not shown), the composite material layer 16 covering the surface of the carrying unit 12 adjacent to the reflective electrode 18 is completely or partially surrounded by the light emitting diode chip 14 type of presentation.

当然,于此所述的复合材料层16的厚度仍符合大于或等于0.1毫米的要求,且相同于前述的实施例,此复合材料层16包含有一树脂材料161以及一无机介电材料162(如图中放大的部分所示),且无机介电材料162掺混于树脂材料161内;树脂材料161具有一第一折射系数;无机介电材料162则具有一第二折射系数,并且,第一折射系数与第二折射系数之间仍符合第一折射系数小于第二折射系数,且第一折射系数与第二折射系数的差值至少大于0.2的范围条件。Of course, the thickness of the composite material layer 16 described here still meets the requirement of greater than or equal to 0.1 mm, and is the same as the previous embodiment, the composite material layer 16 includes a resin material 161 and an inorganic dielectric material 162 (such as shown in the enlarged part of the figure), and the inorganic dielectric material 162 is mixed in the resin material 161; the resin material 161 has a first refractive index; the inorganic dielectric material 162 has a second refractive index, and the first The refraction index and the second refraction index still meet the range condition that the first refraction index is smaller than the second refraction index, and the difference between the first refraction index and the second refraction index is at least greater than 0.2.

其中,承载单元12可为电路板。并且,就本实施例所揭露的树脂材料161与无机介电材料162来说,树脂材料161为硅胶,且其所对应的第一折射系数介于1.3至1.6之间,而无机介电材料162则可选择氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁、氧化锆及其组合所组成的群组以为材料,且上述的材料所对应的第二折射系数则是介于1.7至2.3之间。Wherein, the carrying unit 12 can be a circuit board. Moreover, regarding the resin material 161 and the inorganic dielectric material 162 disclosed in this embodiment, the resin material 161 is silica gel, and its corresponding first refractive index is between 1.3 and 1.6, and the inorganic dielectric material 162 Boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, magnesium oxide, zirconium oxide and their combinations can be selected as materials, and the second refractive index corresponding to the above materials is medium Between 1.7 and 2.3.

据此可知,由于本实施例中的发光二极管芯片14位于承载单元12上,且复合材料层16局部或完全覆盖于承载单元12相邻于反射电极18的表面上。是以,本实施例通过复合材料层16与反射电极18的配合运用,可以有效地反射来自发光二极管芯片14的光线,且能达均热效果,使发光二极管芯片14产生的光线可有效地通过复合材料层16与反射电极18以进行反射,使整体发光二极管封装结构1d的出光效率提升,且可使原集中于发光二极管芯片14附近的热能够通过复合材料层16与反射电极18的设置而均匀分散。It can be seen that, since the LED chip 14 in this embodiment is located on the carrying unit 12 , and the composite material layer 16 partially or completely covers the surface of the carrying unit 12 adjacent to the reflective electrode 18 . Therefore, in this embodiment, through the combined use of the composite material layer 16 and the reflective electrode 18, the light from the LED chip 14 can be effectively reflected, and the heat uniform effect can be achieved, so that the light generated by the LED chip 14 can pass through effectively. The composite material layer 16 and the reflective electrode 18 are used for reflection, so that the light extraction efficiency of the overall LED packaging structure 1d is improved, and the heat originally concentrated near the LED chip 14 can be dissipated by the composite material layer 16 and the reflective electrode 18. Disperse evenly.

而无论对于上述图1A、图1B、图1C、图2、图3或图4中所示的发光二极管封装结构1a、1a’、1b、1c、1d来说,其中的发光二极管芯片14可为可见光发光二极管芯片或紫外光发光二极管芯片。不论是使用可见光发光二极管芯片或紫外光发光二极管芯片,本发明的复合材料层16均能够提高发光二极管封装结构的发光效率以及延长发光二极管封装结构的使用寿命。但是,须注意的是,对于承载单元上覆盖复合材料层的发光二极管封装结构而言,若覆盖于承载单元上的复合材料层中的无机介电材料为氮化硼、氧化铝或氮化铝,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但是,若覆盖于承载单元上的复合材料层中的无机介电材料为氧化铍、硫酸钡、氧化镁或氧化锆,则仅适用于紫外光发光二极管芯片。另外,对于承载单元内包含掺混的树脂材料以及无机介电材料的发光二极管封装结构而言,若树脂材料为硅胶,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但若树脂材料为聚对苯二酰对苯二胺、聚甲基丙烯酸甲酯、环氧树脂、聚乙烯对苯二甲酸酯或聚碳酸树脂,则仅适用于可见光发光二极管芯片;而无机介电材料的选择同上述,即,若承载单元中的无机介电材料为氮化硼、氧化铝或氮化铝,则适用于可见光发光二极管芯片或紫外光发光二极管芯片,但是,若承载单元中的无机介电材料为氧化铍、硫酸钡、氧化镁或氧化锆,则仅适用于紫外光发光二极管芯片。Regardless of the above-mentioned light emitting diode packaging structures 1a, 1a', 1b, 1c, 1d shown in Figure 1A, Figure 1B, Figure 1C, Figure 2, Figure 3 or Figure 4, the light emitting diode chip 14 can be Visible light-emitting diode chips or ultraviolet light-emitting diode chips. Regardless of whether visible light LED chips or ultraviolet light LED chips are used, the composite material layer 16 of the present invention can improve the luminous efficiency of the LED packaging structure and prolong the service life of the LED packaging structure. However, it should be noted that for the LED packaging structure covered with a composite material layer on the carrying unit, if the inorganic dielectric material in the composite material layer covering the carrying unit is boron nitride, aluminum oxide or aluminum nitride , it is suitable for visible light-emitting diode chips or ultraviolet light-emitting diode chips, but if the inorganic dielectric material in the composite material layer covering the carrying unit is beryllium oxide, barium sulfate, magnesium oxide or zirconium oxide, it is only applicable to Ultraviolet light-emitting diode chips. In addition, for the LED packaging structure containing mixed resin materials and inorganic dielectric materials in the carrying unit, if the resin material is silica gel, it is suitable for visible light LED chips or ultraviolet light LED chips, but if the resin material is Polyparaphenylene terephthalamide, polymethyl methacrylate, epoxy resin, polyethylene terephthalate or polycarbonate resin are only suitable for visible light-emitting diode chips; and the choice of inorganic dielectric materials Same as above, that is, if the inorganic dielectric material in the carrying unit is boron nitride, aluminum oxide or aluminum nitride, it is suitable for visible light-emitting diode chips or ultraviolet light-emitting diode chips, but if the inorganic dielectric material in the carrying unit If the material is beryllium oxide, barium sulfate, magnesium oxide or zirconium oxide, it is only suitable for ultraviolet light-emitting diode chips.

以图3所示的发光二极管封装结构1c为例,由于其中的承载单元12’是由复合材料层16(包含有树脂材料161与无机介电材料162)所构成,因此所制作成的发光二极管封装结构1c在长、宽、高的尺寸能缩小至2.6毫米*1.6毫米*1.0毫米或更小规格(制作的方式可为射出成型),符合小型化的规格,同时更可形成具有斜角型态的封装结构。Taking the LED packaging structure 1c shown in FIG. 3 as an example, since the carrying unit 12' is composed of a composite material layer 16 (including a resin material 161 and an inorganic dielectric material 162), the manufactured LED The packaging structure 1c can be reduced to 2.6 mm*1.6 mm*1.0 mm or smaller in length, width, and height (the manufacturing method can be injection molding), which meets the miniaturization specifications, and can also form a beveled shape Stateful packaging structure.

特别的是,对于紫外光发光二极管芯片来说,因复合材料层16的树脂材料161为硅胶,而无机介电材料162为氮化硼、氧化铝、氮化铝、氧化铍、硫酸钡、氧化镁或氧化锆,使复合材料层16对介于波长范围300纳米至430纳米间的紫外光的反射率极佳(至少大于85%),举例来说,以硅胶掺混氮化硼所构成的复合材料层(silicone/BN)来说,在波长为365纳米、光源强度为200mw/cm2的紫外光线照射下,其反射率可保持在91%左右,且在48小时的操作时间下,silicone/BN的复合材料层的反射率仅衰退约2%左右。然而,已知的纯陶瓷材料对于紫外光的反射率低于80%,故本发明具有复合材料层的发光二极管封装结构对于紫外光的反射率较已知由纯陶瓷材料所构成的发光二极管封装结构佳。Especially, for the ultraviolet light emitting diode chip, because the resin material 161 of the composite material layer 16 is silica gel, and the inorganic dielectric material 162 is boron nitride, aluminum oxide, aluminum nitride, beryllium oxide, barium sulfate, oxide Magnesium or zirconia, so that the composite material layer 16 has an excellent reflectivity (at least greater than 85%) to ultraviolet light in the wavelength range of 300 nanometers to 430 nanometers, for example, silica gel mixed with boron nitride constitutes For the composite material layer (silicone/BN), under the irradiation of ultraviolet light with a wavelength of 365 nanometers and a light source intensity of 200mw/cm2, its reflectivity can be maintained at about 91%, and under 48 hours of operation time, the silicone/BN The reflectivity of the BN composite material layer only degrades by about 2%. However, the reflectance of known pure ceramic materials for ultraviolet light is lower than 80%, so the reflectivity of the light emitting diode package structure with composite material layer of the present invention for ultraviolet light is higher than that of known light emitting diode packages made of pure ceramic materials. Good structure.

另外,如图2所示的发光二极管封装结构1b,其因为在侧壁122的表面上覆盖有复合材料层16,因此相较于一般已知的发光二极管封装结构来说,此发光二极管封装结构1b更适用于封装紫外光发光二极管芯片。In addition, the light emitting diode packaging structure 1b shown in FIG. 2, because the surface of the side wall 122 is covered with a composite material layer 16, compared with the generally known light emitting diode packaging structure, this light emitting diode packaging structure 1b is more suitable for packaging ultraviolet light emitting diode chips.

另外,于上述图1A、图1B、图1C、图2、图3及图4中所示的发光二极管封装结构1a、1a’、1b、1c、1d中均揭露有封装胶体13的结构。而如同已知的封装胶体,于此所揭露的封装胶体13内可含有荧光物质(图未显示),以使发光二极管芯片14产生出的光线可透过封装胶体13内的荧光物质的吸收与转换而以特定波长范围的光线射出于发光二极管封装结构1a、1a’、1b、1c、1d,换言之,封装胶体13内的荧光物质可使发光二极管芯片14产生出的光线呈现出特定颜色,举例来说,采用不同的荧光物质可使得经过封装胶体13的光线可呈现出红色、绿色、蓝色、黄色、白色...等颜色。In addition, the structure of the encapsulant 13 is disclosed in the LED packaging structures 1a, 1a', 1b, 1c, and 1d shown in FIGS. 1A, 1B, 1C, 2, 3, and 4. And like the known packaging colloid, the packaging colloid 13 disclosed here may contain fluorescent substances (not shown in the figure), so that the light generated by the LED chip 14 can pass through the absorption and absorption of the fluorescent substance in the packaging colloid 13. The light converted to a specific wavelength range is emitted out of the LED packaging structures 1a, 1a', 1b, 1c, and 1d. In other words, the fluorescent substance in the encapsulant 13 can make the light generated by the LED chip 14 present a specific color, for example In other words, the use of different fluorescent substances can make the light passing through the encapsulating colloid 13 present red, green, blue, yellow, white, etc. colors.

另外,根据实际的加速老化试验结果显示,复合材料层(例如:硅胶掺混重量百分比30%的氮化硼,silicone/BN)与一般已知的环氧树脂或聚对苯二酰对苯二胺比较,silicone/BN的复合材料层具有较佳的热稳定性,一般而言,在摄氏140度的操作温度下操作接近1000小时左右,silicone/BN的复合材料层的反射率仅衰退至85%左右,且直到操作接近10000小时后,silicone/BN的复合材料层仍可保持有接近于20%的反射率,反观环氧树脂或聚对苯二酰对苯二胺在摄氏140度的操作温度下操作接近1000小时左右,环氧树脂和聚对苯二酰对苯二胺的反射率则分别衰退至70%和25%,且直到操作接近10000小时后,则均完全不具有任何反射光线的能力,换言之,环氧树脂与聚对苯二酰对苯二胺在这样的操作状态下,材料本身已完全发生劣化的情形。更值得一提的是,silicone/BN的复合材料层在摄氏160度的操作温度下操作1000小时后,仍可保持有约85%的反射率,当然,此时的环氧树脂或聚对苯二酰对苯二胺的反射率则别衰退至约30%和3%左右。故,若以正常LED操作温度小于80度的条件来说,使用silicone/BN的复合材料层可以大幅增加发光二极管封装结构的使用寿命。In addition, according to the actual accelerated aging test results, the composite material layer (for example: silica gel mixed with 30% by weight of boron nitride, silicone/BN) and commonly known epoxy resin or polyterephthalamide Compared with amines, the composite material layer of silicone/BN has better thermal stability. Generally speaking, the reflectivity of the composite material layer of silicone/BN only declines to 85 when operating at an operating temperature of 140 degrees Celsius for about 1000 hours. %, and until the operation is close to 10,000 hours, the silicone/BN composite layer can still maintain a reflectivity close to 20%, in contrast to the operation of epoxy resin or poly-p-phenylene terephthalamide at 140 degrees Celsius The reflectivity of epoxy resin and poly(p-phenylene terephthalamide) declines to 70% and 25% respectively when the temperature is close to 1000 hours, and there is no reflected light at all until the operation is close to 10,000 hours In other words, epoxy resin and poly-p-phenylene terephthalamide are in such an operating state that the material itself has completely deteriorated. What's more worth mentioning is that the composite layer of silicone/BN can still maintain a reflectivity of about 85% after operating at an operating temperature of 160 degrees Celsius for 1000 hours. The reflectance of diamide-p-phenylenediamide declines to about 30% and 3%. Therefore, if the normal LED operating temperature is less than 80 degrees, the use of the silicone/BN composite material layer can greatly increase the service life of the LED packaging structure.

根据上述可知,本发明所揭露的发光二极管封装结构利用无机介电材料掺混于树脂材料内的复合材料较佳的光反射及耐热特性,使得光线能量及芯片产生的热量较不易局部累积或影响发光二极管封装结构。因此,纵使对于具有较强能量的紫外光发光二极管芯片而言,本发明所揭露的发光二极管封装结构仍可通过复合材料的光反射特性以降低光线能量的累积所导致的黄化、劣化等现象。According to the above, the light emitting diode packaging structure disclosed in the present invention utilizes the better light reflection and heat resistance characteristics of the composite material mixed with the inorganic dielectric material in the resin material, so that the light energy and the heat generated by the chip are less likely to accumulate locally or Affects the packaging structure of light-emitting diodes. Therefore, even for ultraviolet light emitting diode chips with strong energy, the light emitting diode packaging structure disclosed in the present invention can still reduce yellowing and deterioration caused by the accumulation of light energy through the light reflection characteristics of the composite material .

以上所述仅为举例性,而非为限制性本发明。任何未脱离本发明的精神与范畴,而对其进行的等效修改或变更,均应包含于权利要求中。The above descriptions are for illustration only, rather than limiting the present invention. Any equivalent modifications or changes made without departing from the spirit and scope of the present invention shall be included in the claims.

Claims (23)

1. a package structure for LED is characterized in that, described light-emitting diode comprises:
One load bearing unit;
One light-emitting diode chip for backlight unit is positioned on the described load bearing unit; And
One composite layer, local or be covered in the surface of described load bearing unit fully, described composite layer comprises:
One resin material has one first refraction coefficient, and first refraction coefficient is between 1.3 to 1.6; And
One Inorganic Dielectric Material, blending is in described resin material, described Inorganic Dielectric Material blending in the percentage by weight of described resin material greater than 10%, described Inorganic Dielectric Material has one second refraction coefficient, described second refraction coefficient is between 1.7 to 2.3, described first refraction coefficient is less than described second refraction coefficient, and the difference of described first refraction coefficient and described second refraction coefficient is at least greater than 0.2.
2. package structure for LED as claimed in claim 1 is characterized in that, described resin material is a silica gel.
3. package structure for LED as claimed in claim 1 is characterized in that, described Inorganic Dielectric Material is a boron nitride.
4. package structure for LED as claimed in claim 1 is characterized in that described Inorganic Dielectric Material is selected from the group that aluminium oxide, aluminium nitride, beryllium oxide, barium sulfate, magnesium oxide, zirconia and combination thereof are formed.
5. package structure for LED as claimed in claim 1 is characterized in that, described composite layer for the reflectivity of visible light or ultraviolet light more than or equal to 85%.
6. package structure for LED as claimed in claim 1 is characterized in that, described load bearing unit comprises a bottom and a sidewall and forms an accommodation space, and described light-emitting diode chip for backlight unit is positioned on the described bottom and is positioned at described accommodation space.
7. package structure for LED as claimed in claim 6 is characterized in that described composite layer is covered in the surface of described sidewall and described bottom.
8. package structure for LED as claimed in claim 1 is characterized in that described package structure for LED more comprises at least one reflecting electrode, and described reflecting electrode is between described light-emitting diode chip for backlight unit and described load bearing unit.
9. package structure for LED as claimed in claim 8 is characterized in that, described composite layer covers the surface adjacent to the described load bearing unit of described reflecting electrode.
10. package structure for LED as claimed in claim 1 is characterized in that, described light-emitting diode chip for backlight unit is a visible light emitting diode chip or a ultraviolet light-emitting diodes chip.
11. package structure for LED as claimed in claim 10 is characterized in that, the ultraviolet wavelength scope of described ultraviolet light-emitting diodes chip is between 300 nanometer to 430 nanometers.
12. package structure for LED as claimed in claim 1 is characterized in that, the dimensions of described load bearing unit is less than or equal to 1.0 millimeters of 1.6 millimeters * of 2.6 millimeters *.
13. a package structure for LED is characterized in that, described package structure for LED comprises:
One load bearing unit has a bottom and a sidewall and forms an accommodation space, and described sidewall is a composite layer, and described composite layer comprises:
One resin material has one first refraction coefficient, and first refraction coefficient is between 1.3 to 1.6; And
One Inorganic Dielectric Material, blending is in described resin material, described Inorganic Dielectric Material blending in the percentage by weight of described resin material greater than 10%, described Inorganic Dielectric Material has one second refraction coefficient, described second refraction coefficient is between 1.7 to 2.3, described first refraction coefficient is less than described second refraction coefficient, and the difference of described first refraction coefficient and described second refraction coefficient is at least greater than 0.2; And
One light-emitting diode chip for backlight unit is positioned on the described bottom and is positioned at described accommodation space.
14. package structure for LED as claimed in claim 13 is characterized in that, described resin material is a silica gel.
15. package structure for LED as claimed in claim 13 is characterized in that, described resin material is poly-terephthalate p-phenylenediamine (PPD), polymethyl methacrylate, epoxy resin, polyethylene terephthalate or polycarbonate resin.
16. package structure for LED as claimed in claim 13 is characterized in that, described Inorganic Dielectric Material is a boron nitride.
17. package structure for LED as claimed in claim 13 is characterized in that, described Inorganic Dielectric Material is selected from the group that aluminium oxide, aluminium nitride, beryllium oxide, barium sulfate, magnesium oxide, zirconia and combination thereof are formed.
18. package structure for LED as claimed in claim 13 is characterized in that, described Inorganic Dielectric Material blending in the percentage by weight of described resin material greater than 10%.
19. package structure for LED as claimed in claim 13 is characterized in that, described bottom or described sidewall for the reflectivity of visible light or ultraviolet light more than or equal to 85%.
20. package structure for LED as claimed in claim 13 is characterized in that, described bottom is a circuit board, and described sidewall then comprises described resin material and the described Inorganic Dielectric Material of blending in described resin material.
21. package structure for LED as claimed in claim 13 is characterized in that, described light-emitting diode chip for backlight unit is visible light emitting diode chip or ultraviolet light-emitting diodes chip.
22. package structure for LED as claimed in claim 21 is characterized in that, the ultraviolet wavelength scope of described ultraviolet light-emitting diodes chip is between 300 nanometer to 430 nanometers.
23. package structure for LED as claimed in claim 13 is characterized in that, the dimensions of described load bearing unit is less than or equal to 1.0 millimeters of 1.6 millimeters * of 2.6 millimeters *.
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