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CN101338093A - Water-soluble ageing resistance dye ink for jet printer and method for preparing same - Google Patents

Water-soluble ageing resistance dye ink for jet printer and method for preparing same Download PDF

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Publication number
CN101338093A
CN101338093A CN 200710118285 CN200710118285A CN101338093A CN 101338093 A CN101338093 A CN 101338093A CN 200710118285 CN200710118285 CN 200710118285 CN 200710118285 A CN200710118285 A CN 200710118285A CN 101338093 A CN101338093 A CN 101338093A
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CN
China
Prior art keywords
water
percent
jet printer
ethylene glycol
ageing resistance
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN 200710118285
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Chinese (zh)
Inventor
陈凯
肖珂
李英锋
宋延林
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BEIJING JINGDE ZICAI SCIENCE AND TECHNOLOGY Co Ltd
Original Assignee
BEIJING JINGDE ZICAI SCIENCE AND TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by BEIJING JINGDE ZICAI SCIENCE AND TECHNOLOGY Co Ltd filed Critical BEIJING JINGDE ZICAI SCIENCE AND TECHNOLOGY Co Ltd
Priority to CN 200710118285 priority Critical patent/CN101338093A/en
Publication of CN101338093A publication Critical patent/CN101338093A/en
Pending legal-status Critical Current

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Abstract

The invention relates to the ink of a waterborne anti-aging dye ink jet printer; the composition and the content percent of the ink are as follows: 3 percent to 9 percent of colorant, 30 percent to 80 percent of deionized water, 5 percent to 25 percent of diethylene glycol monobutyl ether, 3 percent to 20 percent of glycol monobutyl ether, 3 percent to 10 percent of glycol, 5 percent to 15 percent of drier, 0.1 percent to 2.0 percent of ph regulator, 0.2 percent to 0.5 percent of preservative and 0.1 percent 0.5 percent of aging resistant. The preparation method of the invention is simple; the prepared ink has very strong aging resistance and is four-color compatible ink applicable to all models of ink jet printers.

Description

A kind of water-soluble ageing resistance dye ink for jet printer and preparation method
Technical field
The present invention relates to a kind of water soluble dyestuffs ink for ink-jet printer, particularly, relate to a kind of water-soluble ageing resistance dye ink for jet printer.
The invention still further relates to the preparation method of above-mentioned ink.
Background technology
Tinting material has two kinds in the ink for ink-jet printer prescription commonly used now: a kind of is dyestuff, and a kind of is pigment.Paint ink cost height, its complete processing requires also very high, particularly because paint ink is the dispersion system that is in the steady state that is situated between, multiple auxiliary agents such as the certain dispersion agent of the stable needs of system, stablizer.The preparation of paint ink needs earlier pigment to be ground to form the following particle of micron by special equipment mostly, through classification, under the effect of various auxiliary agents, be dispersed in the dispersion medium kind, be prepared into paint ink, so paint ink market price costliness is not suitable for the use of average family.The dye ink cost is lower, but the problem of ubiquity ageing resistance difference.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble ageing resistance dye ink for jet printer, good resistance to deterioration is arranged.
Another purpose of the present invention is to provide the method for the above-mentioned ink of preparation, and its preparation method is simple.
For achieving the above object, water-soluble ageing resistance dye ink-jet printing ink provided by the invention, it is formed and percentage composition is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
The method of the above-mentioned water-soluble ageing resistance dye ink for jet printer of preparation provided by the invention, step is as follows:
A) preparation solvent: add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol in the deionized water in proportion, stir;
B) in the solvent of steps A preparation, add siccative and tinting material, stirring and dissolving;
C) add pH regulator agent, sanitas, ultraviolet antiaging agent successively, stir;
D) leave standstill the clarification after-filtration.
Tinting material of the present invention is black SP, turmeric yellow, reactive red or sun blue.
Solvent of the present invention is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol.
Siccative of the present invention is a Virahol.
PH regulator agent of the present invention is a diethanolamine.
Sanitas of the present invention is that Sodium Benzoate is or/and sorbyl alcohol.
Ultraviolet antiaging agent of the present invention is a uv-absorbing agent.
Uv-absorbing agent of the present invention is that Uv-531 is or/and Uv-104.
Water-soluble ageing resistance dye ink for jet printer provided by the invention has very strong resistance to deterioration, is can be for the compatible ink of four looks that the ink-jet printer of various models is used.
Embodiment
Describe technical characterictic of the present invention below in detail.
Water-soluble ageing resistance dye ink for jet printer provided by the invention is by the adjustment of aberration, go for four look ink-jet printers of various models, it comprises following composition: tinting material, solvent, siccative, PH conditioning agent, sanitas, ultraviolet antiaging agent.
Its mass percent is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
Wherein:
Tinting material is the desalination dyestuff: can be black SP, its mass percent in component be 5-9%; Can be turmeric yellow also, the mass percent in component be 3-7%; Can be reactive red also, the mass percent in component be 3-7%; Can be sun blue also, the mass percent in component be 3-7%;
Solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, glycol ether, ethylene glycol;
Siccative is a Virahol;
The pH regulator agent is a diethanolamine;
Sanitas is that Sodium Benzoate is or/and sorbyl alcohol etc.;
The ultraviolet antiaging agent is a uv-absorbing agent.
Its preparation method is: prepare solvent earlier, promptly in water, add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, the abundant stirring and evenly mixing of ethylene glycol promptly in above-mentioned ratio, the tinting material that in solvent, adds siccative and aforementioned proportion again, fully stir and make the tinting material dissolving, and add pH regulator agent, sanitas, antiaging agent etc. successively, stir.Leaving standstill for some time treats ink clarification after-filtration.
Embodiment 1
Preparation 100 gram black inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add the black SP7 gram of Virahol 15 grams and tinting material again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-531 0.1 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment 2
Preparation 100 gram blue inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material sun blue 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-104 0.2 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment 3
Preparation 100 gram red inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material reactive red 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-104 0.2 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment outer 4
Preparation 100 gram yellow inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material turmeric yellow 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-531 0.5 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
The present invention fills a prescription rationally, and production technique is simple, and cost is low, and printing effect is good, and the ink ageing resistance is strong.Table 1 compares with the original-pack ink of EPSON and other a kind of compatible inks for the present invention.
Table 1
This ink (black yellow red blue four looks) The original-pack ink of EPSON (black yellow red blue four looks) Other a kind of compatible inks (black yellow red blue four looks)
The pH value 8-9 8-9 7-10
Surface tension (mN/m) 30-33 31-35 30-32
Viscosity (mPa.s) 1.9-2.5 2.0-2.7 1.8-2.9
Specific conductivity (mS/cm) 2.5-3.2 1.8-3.0 2.8-4.0
Printing effect Image, writing is clear, no diffusion of coloring matter phenomenon Image, writing is clear, no diffusion of coloring matter phenomenon Image, writing is clear, no diffusion of coloring matter phenomenon
Thermotolerance Reflux, performance is constant Reflux, performance is constant Reflux has solid to separate out
Winter hardiness -20 the degree freezing be returned to room temperature after performance constant -20 the degree freezing be returned to room temperature after performance constant -20 the degree freezing be returned to room temperature after performance constant
The intermittent printing effect Intermittently can print in 7 days, printing effect is constant Intermittently can print in 7 days, printing effect is constant Intermittently can print in 7 days, printing effect is constant
Resistance to deterioration Xenon lamp aging 24 hours is colour-fast Xenon lamp aging had slightly and fades in 24 hours Xenon lamp aging had obviously and fades in 24 hours
The present invention is identical with original-pack ink fundamental property as can be seen from Table 1, and the resistance to deterioration aspect obviously is better than original-pack ink and other inks.But cost of the present invention is well below above-mentioned correlated ink.

Claims (10)

1, a kind of water-soluble ageing resistance dye ink for jet printer, it is formed and percentage composition is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
2, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, tinting material is black SP, turmeric yellow, reactive red or sun blue.
3, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol.
4, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, siccative is a Virahol.
5, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, the pH regulator agent is a diethanolamine.
6, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, sanitas is that Sodium Benzoate is or/and sorbyl alcohol.
7, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, the ultraviolet antiaging agent is a uv-absorbing agent.
8, water-soluble ageing resistance dye ink for jet printer as claimed in claim 7, wherein, uv-absorbing agent is that Uv-531 is or/and Uv-104.
9, prepare the method for the described water-soluble ageing resistance dye ink for jet printer of claim 1, step is as follows:
A) preparation solvent: add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol in the deionized water in proportion, stir;
B) in the solvent of steps A preparation, add siccative and tinting material, stirring and dissolving;
C) add pH regulator agent, sanitas, ultraviolet antiaging agent successively, stir;
D) leave standstill the clarification after-filtration;
The add-on of mentioned reagent is by mass percentage:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
10, method as claimed in claim 9, wherein:
Tinting material is black SP, turmeric yellow, reactive red or sun blue;
Solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol;
Siccative is a Virahol;
The pH regulator agent is a diethanolamine;
Sanitas is that Sodium Benzoate is or/and sorbyl alcohol;
The ultraviolet antiaging agent is a uv-absorbing agent.
CN 200710118285 2007-07-04 2007-07-04 Water-soluble ageing resistance dye ink for jet printer and method for preparing same Pending CN101338093A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN 200710118285 CN101338093A (en) 2007-07-04 2007-07-04 Water-soluble ageing resistance dye ink for jet printer and method for preparing same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN 200710118285 CN101338093A (en) 2007-07-04 2007-07-04 Water-soluble ageing resistance dye ink for jet printer and method for preparing same

Publications (1)

Publication Number Publication Date
CN101338093A true CN101338093A (en) 2009-01-07

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Family Applications (1)

Application Number Title Priority Date Filing Date
CN 200710118285 Pending CN101338093A (en) 2007-07-04 2007-07-04 Water-soluble ageing resistance dye ink for jet printer and method for preparing same

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440799A (en) * 2015-12-08 2016-03-30 北海市天硌打印耗材有限公司 Water-based inkjet ink and preparation method thereof
CN110079155A (en) * 2019-05-18 2019-08-02 北京联创佳艺影像新材料技术有限公司 A kind of high fastness aqueous dye ink
CN113580795A (en) * 2021-07-13 2021-11-02 硕包科技(扬州)有限公司 Printing process for forming multilayer three-dimensional pattern by prism refraction
CN115109466A (en) * 2022-07-28 2022-09-27 佛山市帆思科材料技术有限公司 Anti-aging water-based color ink-jet printing ink product and manufacturing method thereof

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105440799A (en) * 2015-12-08 2016-03-30 北海市天硌打印耗材有限公司 Water-based inkjet ink and preparation method thereof
CN110079155A (en) * 2019-05-18 2019-08-02 北京联创佳艺影像新材料技术有限公司 A kind of high fastness aqueous dye ink
CN113580795A (en) * 2021-07-13 2021-11-02 硕包科技(扬州)有限公司 Printing process for forming multilayer three-dimensional pattern by prism refraction
CN113580795B (en) * 2021-07-13 2023-02-10 硕包科技(扬州)有限公司 Printing process for forming multilayer three-dimensional pattern by prism refraction
CN115109466A (en) * 2022-07-28 2022-09-27 佛山市帆思科材料技术有限公司 Anti-aging water-based color ink-jet printing ink product and manufacturing method thereof

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Open date: 20090107