CN101338093A - Water-soluble ageing resistance dye ink for jet printer and method for preparing same - Google Patents
Water-soluble ageing resistance dye ink for jet printer and method for preparing same Download PDFInfo
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- CN101338093A CN101338093A CN 200710118285 CN200710118285A CN101338093A CN 101338093 A CN101338093 A CN 101338093A CN 200710118285 CN200710118285 CN 200710118285 CN 200710118285 A CN200710118285 A CN 200710118285A CN 101338093 A CN101338093 A CN 101338093A
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- Prior art keywords
- water
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- jet printer
- ethylene glycol
- ageing resistance
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Links
- 230000032683 aging Effects 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims description 10
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims abstract description 47
- 238000002360 preparation method Methods 0.000 claims abstract description 20
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 claims abstract description 16
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 claims abstract description 16
- 230000003712 anti-aging effect Effects 0.000 claims abstract description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000008367 deionised water Substances 0.000 claims abstract description 11
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 29
- 239000000463 material Substances 0.000 claims description 22
- 239000002904 solvent Substances 0.000 claims description 19
- 238000003756 stirring Methods 0.000 claims description 17
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 claims description 15
- 239000006096 absorbing agent Substances 0.000 claims description 10
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 claims description 8
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical group OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 claims description 8
- WXMKPNITSTVMEF-UHFFFAOYSA-M sodium benzoate Chemical compound [Na+].[O-]C(=O)C1=CC=CC=C1 WXMKPNITSTVMEF-UHFFFAOYSA-M 0.000 claims description 8
- 235000010234 sodium benzoate Nutrition 0.000 claims description 8
- 239000004299 sodium benzoate Substances 0.000 claims description 8
- 238000005352 clarification Methods 0.000 claims description 7
- 238000001914 filtration Methods 0.000 claims description 7
- ZIUSSTSXXLLKKK-KOBPDPAPSA-N (1e,4z,6e)-5-hydroxy-1,7-bis(4-hydroxy-3-methoxyphenyl)hepta-1,4,6-trien-3-one Chemical compound C1=C(O)C(OC)=CC(\C=C\C(\O)=C\C(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 ZIUSSTSXXLLKKK-KOBPDPAPSA-N 0.000 claims description 5
- VFLDPWHFBUODDF-FCXRPNKRSA-N Curcumin Natural products C1=C(O)C(OC)=CC(\C=C\C(=O)CC(=O)\C=C\C=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-FCXRPNKRSA-N 0.000 claims description 5
- VFLDPWHFBUODDF-UHFFFAOYSA-N diferuloylmethane Natural products C1=C(O)C(OC)=CC(C=CC(=O)CC(=O)C=CC=2C=C(OC)C(O)=CC=2)=C1 VFLDPWHFBUODDF-UHFFFAOYSA-N 0.000 claims description 5
- MEIRRNXMZYDVDW-MQQKCMAXSA-N (2E,4E)-2,4-hexadien-1-ol Chemical compound C\C=C\C=C\CO MEIRRNXMZYDVDW-MQQKCMAXSA-N 0.000 claims description 4
- 239000003153 chemical reaction reagent Substances 0.000 claims 1
- 239000003755 preservative agent Substances 0.000 abstract description 5
- 230000002335 preservative effect Effects 0.000 abstract description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 abstract 1
- 239000003086 colorant Substances 0.000 abstract 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 37
- 239000000975 dye Substances 0.000 description 10
- 238000002156 mixing Methods 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- 238000007639 printing Methods 0.000 description 6
- 239000003973 paint Substances 0.000 description 5
- 230000006866 deterioration Effects 0.000 description 4
- 239000003643 water by type Substances 0.000 description 4
- 238000004040 coloring Methods 0.000 description 3
- 238000009792 diffusion process Methods 0.000 description 3
- 230000008014 freezing Effects 0.000 description 3
- 238000007710 freezing Methods 0.000 description 3
- 238000010992 reflux Methods 0.000 description 3
- 229910052724 xenon Inorganic materials 0.000 description 3
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 3
- 239000012752 auxiliary agent Substances 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 230000004075 alteration Effects 0.000 description 1
- PZTQVMXMKVTIRC-UHFFFAOYSA-L chembl2028348 Chemical compound [Ca+2].[O-]S(=O)(=O)C1=CC(C)=CC=C1N=NC1=C(O)C(C([O-])=O)=CC2=CC=CC=C12 PZTQVMXMKVTIRC-UHFFFAOYSA-L 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 230000002596 correlated effect Effects 0.000 description 1
- 238000010612 desalination reaction Methods 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000007641 inkjet printing Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
Landscapes
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention relates to the ink of a waterborne anti-aging dye ink jet printer; the composition and the content percent of the ink are as follows: 3 percent to 9 percent of colorant, 30 percent to 80 percent of deionized water, 5 percent to 25 percent of diethylene glycol monobutyl ether, 3 percent to 20 percent of glycol monobutyl ether, 3 percent to 10 percent of glycol, 5 percent to 15 percent of drier, 0.1 percent to 2.0 percent of ph regulator, 0.2 percent to 0.5 percent of preservative and 0.1 percent 0.5 percent of aging resistant. The preparation method of the invention is simple; the prepared ink has very strong aging resistance and is four-color compatible ink applicable to all models of ink jet printers.
Description
Technical field
The present invention relates to a kind of water soluble dyestuffs ink for ink-jet printer, particularly, relate to a kind of water-soluble ageing resistance dye ink for jet printer.
The invention still further relates to the preparation method of above-mentioned ink.
Background technology
Tinting material has two kinds in the ink for ink-jet printer prescription commonly used now: a kind of is dyestuff, and a kind of is pigment.Paint ink cost height, its complete processing requires also very high, particularly because paint ink is the dispersion system that is in the steady state that is situated between, multiple auxiliary agents such as the certain dispersion agent of the stable needs of system, stablizer.The preparation of paint ink needs earlier pigment to be ground to form the following particle of micron by special equipment mostly, through classification, under the effect of various auxiliary agents, be dispersed in the dispersion medium kind, be prepared into paint ink, so paint ink market price costliness is not suitable for the use of average family.The dye ink cost is lower, but the problem of ubiquity ageing resistance difference.
Summary of the invention
The object of the present invention is to provide a kind of water-soluble ageing resistance dye ink for jet printer, good resistance to deterioration is arranged.
Another purpose of the present invention is to provide the method for the above-mentioned ink of preparation, and its preparation method is simple.
For achieving the above object, water-soluble ageing resistance dye ink-jet printing ink provided by the invention, it is formed and percentage composition is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
The method of the above-mentioned water-soluble ageing resistance dye ink for jet printer of preparation provided by the invention, step is as follows:
A) preparation solvent: add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol in the deionized water in proportion, stir;
B) in the solvent of steps A preparation, add siccative and tinting material, stirring and dissolving;
C) add pH regulator agent, sanitas, ultraviolet antiaging agent successively, stir;
D) leave standstill the clarification after-filtration.
Tinting material of the present invention is black SP, turmeric yellow, reactive red or sun blue.
Solvent of the present invention is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol.
Siccative of the present invention is a Virahol.
PH regulator agent of the present invention is a diethanolamine.
Sanitas of the present invention is that Sodium Benzoate is or/and sorbyl alcohol.
Ultraviolet antiaging agent of the present invention is a uv-absorbing agent.
Uv-absorbing agent of the present invention is that Uv-531 is or/and Uv-104.
Water-soluble ageing resistance dye ink for jet printer provided by the invention has very strong resistance to deterioration, is can be for the compatible ink of four looks that the ink-jet printer of various models is used.
Embodiment
Describe technical characterictic of the present invention below in detail.
Water-soluble ageing resistance dye ink for jet printer provided by the invention is by the adjustment of aberration, go for four look ink-jet printers of various models, it comprises following composition: tinting material, solvent, siccative, PH conditioning agent, sanitas, ultraviolet antiaging agent.
Its mass percent is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
Wherein:
Tinting material is the desalination dyestuff: can be black SP, its mass percent in component be 5-9%; Can be turmeric yellow also, the mass percent in component be 3-7%; Can be reactive red also, the mass percent in component be 3-7%; Can be sun blue also, the mass percent in component be 3-7%;
Solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, glycol ether, ethylene glycol;
Siccative is a Virahol;
The pH regulator agent is a diethanolamine;
Sanitas is that Sodium Benzoate is or/and sorbyl alcohol etc.;
The ultraviolet antiaging agent is a uv-absorbing agent.
Its preparation method is: prepare solvent earlier, promptly in water, add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, the abundant stirring and evenly mixing of ethylene glycol promptly in above-mentioned ratio, the tinting material that in solvent, adds siccative and aforementioned proportion again, fully stir and make the tinting material dissolving, and add pH regulator agent, sanitas, antiaging agent etc. successively, stir.Leaving standstill for some time treats ink clarification after-filtration.
Embodiment 1
Preparation 100 gram black inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add the black SP7 gram of Virahol 15 grams and tinting material again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-531 0.1 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment 2
Preparation 100 gram blue inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material sun blue 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-104 0.2 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment 3
Preparation 100 gram red inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material reactive red 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-104 0.2 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
Embodiment outer 4
Preparation 100 gram yellow inks: first preparation solvent, promptly in 50 gram deionized waters, add diethylene glycol monobutyl ether 10 grams, ethylene glycol monoethyl ether 5 grams, ethylene glycol 10 grams, and abundant stirring and evenly mixing is promptly; In the above-mentioned solvent that has prepared, add Virahol 15 grams and tinting material turmeric yellow 7 grams again, fully stir and make the tinting material dissolving, and add pH regulator agent diethanolamine 0.5 gram, preservative sodium benzoate 0.20 gram, uv-absorbing agent Uv-531 0.5 gram successively, stirred then one hour, it is even to make it thorough mixing.Leaving standstill for some time treats ink clarification after-filtration.Technological process of the present invention is carried out at normal temperatures.
The present invention fills a prescription rationally, and production technique is simple, and cost is low, and printing effect is good, and the ink ageing resistance is strong.Table 1 compares with the original-pack ink of EPSON and other a kind of compatible inks for the present invention.
Table 1
This ink (black yellow red blue four looks) | The original-pack ink of EPSON (black yellow red blue four looks) | Other a kind of compatible inks (black yellow red blue four looks) | |
The pH value | 8-9 | 8-9 | 7-10 |
Surface tension (mN/m) | 30-33 | 31-35 | 30-32 |
Viscosity (mPa.s) | 1.9-2.5 | 2.0-2.7 | 1.8-2.9 |
Specific conductivity (mS/cm) | 2.5-3.2 | 1.8-3.0 | 2.8-4.0 |
Printing effect | Image, writing is clear, no diffusion of coloring matter phenomenon | Image, writing is clear, no diffusion of coloring matter phenomenon | Image, writing is clear, no diffusion of coloring matter phenomenon |
Thermotolerance | Reflux, performance is constant | Reflux, performance is constant | Reflux has solid to separate out |
Winter hardiness | -20 the degree freezing be returned to room temperature after performance constant | -20 the degree freezing be returned to room temperature after performance constant | -20 the degree freezing be returned to room temperature after performance constant |
The intermittent printing effect | Intermittently can print in 7 days, printing effect is constant | Intermittently can print in 7 days, printing effect is constant | Intermittently can print in 7 days, printing effect is constant |
Resistance to deterioration | Xenon lamp aging 24 hours is colour-fast | Xenon lamp aging had slightly and fades in 24 hours | Xenon lamp aging had obviously and fades in 24 hours |
The present invention is identical with original-pack ink fundamental property as can be seen from Table 1, and the resistance to deterioration aspect obviously is better than original-pack ink and other inks.But cost of the present invention is well below above-mentioned correlated ink.
Claims (10)
1, a kind of water-soluble ageing resistance dye ink for jet printer, it is formed and percentage composition is:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
2, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, tinting material is black SP, turmeric yellow, reactive red or sun blue.
3, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol.
4, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, siccative is a Virahol.
5, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, the pH regulator agent is a diethanolamine.
6, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, sanitas is that Sodium Benzoate is or/and sorbyl alcohol.
7, water-soluble ageing resistance dye ink for jet printer as claimed in claim 1, wherein, the ultraviolet antiaging agent is a uv-absorbing agent.
8, water-soluble ageing resistance dye ink for jet printer as claimed in claim 7, wherein, uv-absorbing agent is that Uv-531 is or/and Uv-104.
9, prepare the method for the described water-soluble ageing resistance dye ink for jet printer of claim 1, step is as follows:
A) preparation solvent: add diethylene glycol monobutyl ether, ethylene glycol monoethyl ether, ethylene glycol in the deionized water in proportion, stir;
B) in the solvent of steps A preparation, add siccative and tinting material, stirring and dissolving;
C) add pH regulator agent, sanitas, ultraviolet antiaging agent successively, stir;
D) leave standstill the clarification after-filtration;
The add-on of mentioned reagent is by mass percentage:
Tinting material 3-9%;
Deionized water 30-80%;
Diethylene glycol monobutyl ether 5-25%;
Ethylene glycol monoethyl ether 3-20%;
Ethylene glycol 3-10%;
Siccative 3-15%;
PH regulator agent 0.1-2.0%;
Sanitas 0.2-0.5%;
Ultraviolet antiaging agent 0.1-0.5%.
10, method as claimed in claim 9, wherein:
Tinting material is black SP, turmeric yellow, reactive red or sun blue;
Solvent is the mixture of deionized water and diethylene glycol monobutyl ether, ethylene glycol monoethyl ether and ethylene glycol;
Siccative is a Virahol;
The pH regulator agent is a diethanolamine;
Sanitas is that Sodium Benzoate is or/and sorbyl alcohol;
The ultraviolet antiaging agent is a uv-absorbing agent.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN 200710118285 CN101338093A (en) | 2007-07-04 | 2007-07-04 | Water-soluble ageing resistance dye ink for jet printer and method for preparing same |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN 200710118285 CN101338093A (en) | 2007-07-04 | 2007-07-04 | Water-soluble ageing resistance dye ink for jet printer and method for preparing same |
Publications (1)
Publication Number | Publication Date |
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CN101338093A true CN101338093A (en) | 2009-01-07 |
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CN 200710118285 Pending CN101338093A (en) | 2007-07-04 | 2007-07-04 | Water-soluble ageing resistance dye ink for jet printer and method for preparing same |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105440799A (en) * | 2015-12-08 | 2016-03-30 | 北海市天硌打印耗材有限公司 | Water-based inkjet ink and preparation method thereof |
CN110079155A (en) * | 2019-05-18 | 2019-08-02 | 北京联创佳艺影像新材料技术有限公司 | A kind of high fastness aqueous dye ink |
CN113580795A (en) * | 2021-07-13 | 2021-11-02 | 硕包科技(扬州)有限公司 | Printing process for forming multilayer three-dimensional pattern by prism refraction |
CN115109466A (en) * | 2022-07-28 | 2022-09-27 | 佛山市帆思科材料技术有限公司 | Anti-aging water-based color ink-jet printing ink product and manufacturing method thereof |
-
2007
- 2007-07-04 CN CN 200710118285 patent/CN101338093A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105440799A (en) * | 2015-12-08 | 2016-03-30 | 北海市天硌打印耗材有限公司 | Water-based inkjet ink and preparation method thereof |
CN110079155A (en) * | 2019-05-18 | 2019-08-02 | 北京联创佳艺影像新材料技术有限公司 | A kind of high fastness aqueous dye ink |
CN113580795A (en) * | 2021-07-13 | 2021-11-02 | 硕包科技(扬州)有限公司 | Printing process for forming multilayer three-dimensional pattern by prism refraction |
CN113580795B (en) * | 2021-07-13 | 2023-02-10 | 硕包科技(扬州)有限公司 | Printing process for forming multilayer three-dimensional pattern by prism refraction |
CN115109466A (en) * | 2022-07-28 | 2022-09-27 | 佛山市帆思科材料技术有限公司 | Anti-aging water-based color ink-jet printing ink product and manufacturing method thereof |
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Open date: 20090107 |