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CN101284305B - A fine-grained casting process for high manganese steel castings - Google Patents

A fine-grained casting process for high manganese steel castings Download PDF

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CN101284305B
CN101284305B CN2008100115014A CN200810011501A CN101284305B CN 101284305 B CN101284305 B CN 101284305B CN 2008100115014 A CN2008100115014 A CN 2008100115014A CN 200810011501 A CN200810011501 A CN 200810011501A CN 101284305 B CN101284305 B CN 101284305B
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casting
manganese steel
high manganese
fine
temperature
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CN101284305A (en
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傅排先
康秀红
夏立军
李殿中
李依依
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Zhongke Xiwang Special Steel Co ltd
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Institute of Metal Research of CAS
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Abstract

本发明涉及高锰钢铸件细晶化制造技术,具体地说是一种高锰钢铸件细晶化铸造工艺方法,包括:1)钢水高温出炉,出炉温度为1580±20℃,出炉后进行炉外吹氩气、喂丝精炼,严格控制磷、硫含量,P≤0.025%,S≤0.018%,浇注温度为1480±20℃;2)高锰钢铸件浇注过程中,随金属液添加重量比为0.5~10%、尺寸为

Figure 200810011501.4_AB_0
0.5~10mm的金属颗粒;3)金属颗粒从铸件的浇注系统加入,金属颗粒预热温度150℃~350℃;4)铸件快速浇注,采用底漏包避免夹杂卷入。本发明在浇注过程中添加金属颗粒,降低金属液的温度,增加形核质点细化晶粒。从而,解决了高锰钢铸件晶粒粗大、疏松、微裂纹等问题,生产出了晶粒细化、强度高的高锰钢铸件。The present invention relates to high-manganese steel casting fine-grain manufacturing technology, specifically a high-manganese steel casting fine-grain casting process method, comprising: 1) molten steel is discharged from the furnace at high temperature, the temperature of the furnace is 1580±20°C, and the furnace is carried out after the furnace is discharged. External argon blowing, wire feeding and refining, strict control of phosphorus and sulfur content, P≤0.025%, S≤0.018%, pouring temperature is 1480±20°C; 2) During the pouring process of high manganese steel castings, the weight ratio is 0.5~10%, the size is
Figure 200810011501.4_AB_0
0.5-10mm metal particles; 3) Metal particles are added from the gating system of the casting, and the metal particle preheating temperature is 150°C to 350°C; 4) The casting is poured quickly, and the bottom leak bag is used to avoid inclusions. In the invention, metal particles are added during the pouring process, the temperature of molten metal is lowered, and nucleation particles are increased to refine crystal grains. Thus, problems such as coarse grains, looseness, and microcracks of high manganese steel castings are solved, and high manganese steel castings with fine grains and high strength are produced.

Description

A kind of high manganese steel casting grain refinement casting technique
Technical field
The present invention relates to high manganese steel casting grain refining manufacturing technology, specifically a kind of high manganese steel casting grain refinement casting technique.
Background technology
High manganese steel casting is used very extensive, especially particularly outstanding aspect mine and railway at present.Yet, the thick serviceability that has a strong impact on potassium steel of high manganese steel casting crystal grain.High manganese steel casting crystal grain is thick, makes field trash and low melting point enrichment on crystal boundary in the foundry goods, has reduced casting strength, causes high manganese steel casting in use to produce peeling off, defective such as crackle, has a strong impact on the service life of foundry goods.Railroad frog is a high manganese steel casting, and the grain refining technology is particularly important for railroad crossing of high manganese steel.Past gathers a large amount of field trashes and low melting point because railroad frog crystal grain is thick on crystal boundary, the grain-boundary strength that weakened makes potassium steel that heel and toe wear in use take place, and problems such as flake-off piece occur.China is with world's railway 6% operation mileage, finished 24% transportation total amount, make railway be in extremely busy state, increased the probability of railway breakage, make the railroad frog consumption very big, the railroad frog requirement in the annual whole nation is greatly about about 50,000, and this numeral also will increase along with the increase of trunk railway.
Summary of the invention
The object of the present invention is to provide a kind of high manganese steel casting grain refinement casting technique, solved problems such as high manganese steel casting crystal grain is thick, loose, micro-crack, produced grain refinement, high manganese steel casting that intensity is high; Adopt advanced alloying process and metallic particles to accelerate the foundry goods cooling technology and improved material property, the railroad crossing of high manganese steel mechanical property has had large increase, σ b〉=850MPa, ak 〉=240J/cm 2, δ 〉=45%.
Technical scheme of the present invention is:
The present invention has developed a kind of high manganese steel casting grain refinement casting technique, comprises the steps:
1) potassium steel is in smelting process, and molten steel high temperature is come out of the stove, and carries out the outer blowing argon gas of stove after coming out of the stove, feeds the silk refining, phosphorus, sulfur content in the strict control molten steel;
2) in the high manganese steel casting casting process, adopt with stream and add metallic particles, reduce the molten metal energy storage and accelerate the foundry goods cooling;
3) metallic particles adds from the running gate system of foundry goods, and the joining day carried out in the middle and later periods of whole casting process, disposable or evenly adding in batches;
4) foundry goods will be poured into a mould fast, adopts end bottom pour ladle to avoid being mingled with and is involved in.
Described step 1), tapping temperature are 1580 ± 20 ℃.
Described step 1), in the refining process, argon pressure is 0.3~0.6MPa, the pressure pipeline internal diameter 5~10mm, 0.5~1 minute/ton molten steel of argon blowing time is fed the silk amount and is 0.5~2% of pour steel gross weight.
Described step 1), phosphorus, sulfur content in the strict control molten steel, P≤0.025%, S≤0.018%, pouring temperature is 1480 ± 20 ℃.
Described step 2), the weight of adding metallic particles is 0.5~10% of pour steel gross weight.
Described step 2), adding metal particle size is
Figure G2008100115014D00022
0.5~10mm, 150 ℃~350 ℃ of metallic particles preheat temperatures.
Described step 2), add the metallic particles kind: straight carbon steel or potassium steel.
Described step 3), metallic particles adds with molten metal from the running gate system of foundry goods, and the metallic particles interpolation time is 1/3~1/2 of the casting pouring time.
Described step 4), poring rate are 20kg/s~40kg/s.
The used potassium steel of the present invention be a kind of serve as main traditional steel grade with elements such as carbon, manganese, by weight percentage, the potassium steel chemical composition comprises: C 0.7~1.1%, Si 0.6~0.7%, Mn 12.5~13.5%, P≤0.025%, S≤0.018%, in the high manganese steel casting casting process, add weight ratio with molten metal and be 0.5~10%, be of a size of
Figure G2008100115014D00023
0.5 the metallic particles of~10mm.Metallic particles adds from the running gate system of foundry goods, and the joining day should carry out in the middle and later periods of whole casting process, disposable or evenly adding in batches.
The present invention has following beneficial effect:
1. the present invention reduces the temperature of molten metal by adding metallic particles in casting process, increases forming core particle crystal grain thinning, the rapid solidification foundry goods, significantly refinement the crystal grain of high manganese steel casting, reduce the field trash size simultaneously, significantly improved casting quality.
2. technological design of the present invention is reasonable, shortens the high manganese steel casting setting time, reduces the production cycle of foundry goods, has improved productivity ratio.
3. the present invention is applicable to the manufacturing of thick big high manganese steel casting.The high manganese steel casting that utilizes the present invention to produce has high-performance, characteristics cheaply.
4. railway frog is because crystal grain is thick, and shrinkage cavity, casting flaw such as loose in use, are easy to wearing and tearing, and generally speaking, the goods of high manganese steel frog is no more than 1.2 hundred million tons by gross weight.Adopt the high manganese steel frog goods of grain refining of the present invention can reach 200,000,000 tons by gross weight.Therefore, this technology has obtained railway user's abundant affirmation.
Description of drawings
Add the metallic particles pattern in Fig. 1 (a)-Fig. 1 (c) foundry goods;
Fig. 2 casting process is implemented schematic diagram;
Among the figure, 1. foundry goods; 2. rising head; 3. warming plate; 4. coverture; 5. cross gate; 6. sprue; 7. cup; 8. metallic particles.
Fig. 3 foundry goods schematic diagram;
Fig. 4 casting finished products diagram;
Fig. 5 is without field trash distribution situation in the high manganese steel casting of grain refining;
Field trash distribution situation in the high manganese steel casting of Fig. 6 grain refining;
Fig. 7 (a)-Fig. 7 (b) is without the high manganese steel casting crystal grain distribution situation of grain refining;
The high manganese steel casting crystal grain distribution situation of Fig. 8 (a)-Fig. 8 (b) grain refining.
The specific embodiment
The concrete operations of a kind of high manganese steel casting crystal fining method of the present invention are as follows:
1) material is prepared: straight carbon steel or potassium steel metallic particles are of a size of
Figure G2008100115014D00031
0.5~
Figure G2008100115014D00032
The metallic particles of 10mm, 150 ℃~350 ℃ of metallic particles preheat temperatures;
2) equipment is prepared: special funnel.
3) molten steel is smelted: molten steel high temperature is come out of the stove, and tapping temperature is 1580 ± 20 ℃, carries out the outer blowing argon gas of stove after coming out of the stove, feeds the silk refining, strict control phosphorus, sulfur content, P≤0.025%, S≤0.018%;
In the refining process, argon pressure is 0.3~0.6MPa, the pressure pipeline internal diameter
Figure G2008100115014D00033
5~10mm, 0.5~1 minute/ton molten steel of argon blowing time is fed the silk amount and is 0.5~2% of pour steel gross weight, feeds silk and is refining Si-Ca silk commonly used, and its effect is deoxidation, refining.
4) strict control pouring temperature, pouring temperature is 1480 ± 20 ℃.Potassium steel is when selecting pouring temperature, and simple heavy section casting pouring temperature is taken off limit, complex thin-wall spare pouring temperature capping.
5) addition: in the high manganese steel casting casting process, add weight ratio with metal liquid stream and be 0.5~10%, be of a size of
Figure G2008100115014D00034
0.5~
Figure G2008100115014D00035
The metallic particles of 10mm is seen Fig. 1 (a)-Fig. 1 (c), 150 ℃~350 ℃ of metallic particles preheat temperatures.
6) adding method: foundry goods will be poured into a mould fast, adopts end bottom pour ladle to avoid being mingled with and is involved in, and cast is applying argon gas in die cavity before, pours into a mould under argon shield; Utilize special equipment to add metallic particles, metallic particles adds from the running gate system of foundry goods, and the joining day should carry out in the middle and later periods of whole casting process, disposable or evenly adding in batches;
7) foundry goods is handled: adopt hot shake-out technology, in order to reduce the tension of foundry goods, casting temperature is not less than 800 ℃ during shake out.Adopt Methods of OFC-A to carry out heat and cut rising head, cutting temperature is not less than 600 ℃, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles.
Below in conjunction with drawings and Examples in detail the present invention is described in detail.
Embodiment 1
As shown in Figure 2, adopt insulated feeder and thermal-insulating covering agent.The molten steel tapping temperature is 1580 ℃, carries out refining in the refining bag, remove to be mingled with, and 0.6 ton of casting of molten metal weight, 32 seconds durations of pouring, the cast of end bottom pour ladle, 1480 ℃ of pouring temperatures, cast is applying argon gas in die cavity before, pours into a mould under argon shield.In casting process from running gate system add the molten steel gross weight 5%, be of a size of
Figure G2008100115014D00041
The metallic particles of 2mm, metallic particles are ZG 55,180 ℃ of metallic particles temperature; Metallic particles begins in the time of 11 seconds to add at casting pouring, and the metallic particles joining day is 12 seconds.Foundry goods adopts hot shake-out technology, carries out heat with Methods of OFC-A and cuts rising head, and heat is cut 650 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, and homogenization temperature is 1080 ℃, and temperature retention time is 4.5h.
In the present embodiment refining process, argon pressure is 0.4MPa, the pressure pipeline internal diameter 8mm, 0.8 minute/ton molten steel of argon blowing time is fed the silk amount and is 1% of pour steel gross weight, feeds silk and is refining Si-Ca silk commonly used.By weight percentage, potassium steel chemical composition: C 1.0, Si 0.6%, and Mn 12.5%, and P 0.022%, and S 0.012%.
Adopt following technology: (1) is adopted and is steadily filled the cup of type running gate system, helps the adding of metallic particles.(2) use insulated feeder and thermal-insulating covering agent, foundry goods (Fig. 3, Fig. 4) is inner without any shrinkage cavity, rarefaction defect.(3) add metallic particles, accelerate the setting time of solidifying the shortening foundry goods of foundry goods, crystal grain thinning.(4) the foundry goods gate end has inclusion defect, and the field trash size is big and have pore, but these defectives are all within the range of work of foundry goods, and genus can be removed defective.
The present invention adopts the interpolation metallic particles, increases foundry goods forming core particle, reduces the foundry goods energy storage, accelerates casting solidification speed, shortens technology such as casting solidification time, and the casting crystalline grain size significantly reduces, uniform crystal particles.Thereby make the performance of high manganese steel casting be significantly improved σ b〉=850MPa, ak 〉=240J/cm 2, δ 〉=45%.The grain refining casting crystalline grain pattern of Fig. 8 (a)-Fig. 8 (b) for adopting the present invention to produce.
Embodiment 2
Difference from Example 1 is:
As shown in Figure 2, adopt insulated feeder and thermal-insulating covering agent.The molten steel tapping temperature is 1560 ℃, carries out refining in the refining bag, remove to be mingled with, and 0.6 ton of casting of molten metal weight, 30 seconds durations of pouring, the cast of end bottom pour ladle, 1470 ℃ of pouring temperatures are poured into a mould under argon shield.In casting process, from running gate system, add account for the molten steel gross weight 2%, be of a size of The metallic particles of 5mm, metallic particles are ZG65,245 ℃ of metallic particles temperature; Metallic particles begins in the time of 10 seconds to add at casting pouring, and the metallic particles joining day is 14 seconds.Foundry goods adopts hot shake-out technology, carries out heat with Methods of OFC-A and cuts rising head, and heat is cut 630 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, and homogenization temperature is 1075 ℃, and temperature retention time is 5h.
In the present embodiment refining process, argon pressure is 0.3MPa, the pressure pipeline internal diameter
Figure G2008100115014D00052
8mm, 1 minute/ton molten steel of argon blowing time is fed the silk amount and is 2% of pour steel gross weight, feeds silk and is refining Si-Ca silk commonly used.By weight percentage, potassium steel chemical composition: C 1.05%, Si 0.62%, and Mn 12.8%, and P 0.021%, and S 0.016%.
Adopt following technology: (1) is adopted and is steadily filled the cup of type running gate system, is convenient to metallic particles and adds.Adopt end bottom pour ladle cast, reduce volume gas and slag inclusion, reduced secondary oxidation.(2) add metallic particles, accelerate solidifying of foundry goods, shorten the setting time of foundry goods, significantly crystal grain thinning.And using insulation to emit, foundry goods is without any shrinkage cavity, rarefaction defect.(4) cast(ing) surface, subsurface all are mingled with less than finding.Casting crystalline grain is tiny, and evenly it is more that the field trash size significantly reduces quantity in the foundry goods, and casting quality is intact.
Embodiment 3
Difference from Example 1 is:
As shown in Figure 2, adopt insulated feeder and thermal-insulating covering agent.The molten steel tapping temperature is 1590 ℃, carries out refining in the refining bag, remove to be mingled with, and 0.6 ton of casting of molten metal weight, 28 seconds durations of pouring, the cast of end bottom pour ladle, 1480 ℃ of pouring temperatures are poured into a mould under argon shield.In casting process, from running gate system, add the molten steel gross weight 1.5%, be of a size of
Figure G2008100115014D00053
The metallic particles of 10mm, metallic particles are common potassium steel, 320 ℃ of metallic particles temperature; Metallic particles begins in the time of 14 seconds to add at casting pouring, and the metallic particles joining day is 8 seconds.Foundry goods adopts hot shake-out technology, carries out heat with Methods of OFC-A and cuts rising head, and heat is cut 600 ℃ of rising head temperature, and the cutting after heat is fed into heat treatment kiln, carries out homogenising and handles, and homogenization temperature is 1080 ℃, and temperature retention time is 5h.
In the present embodiment refining process, argon pressure is 0.6MPa, the pressure pipeline internal diameter
Figure G2008100115014D00054
5mm, 1 minute/ton molten steel of argon blowing time is fed the silk amount and is 2% of pour steel gross weight, feeds silk and is refining Si-Ca silk commonly used.By weight percentage, potassium steel chemical composition: C 0.95%, Si 0.67%, and Mn 12.4%, and P 0.020%, and S 0.016%.
Adopt following technology: (1) is adopted and is steadily filled the cup of type running gate system, is convenient to metallic particles and adds.Adopt end bottom pour ladle cast, reduce volume gas and slag inclusion, reduced secondary oxidation.(2) add metallic particles, the casting solidification time significantly shortens, grain refinement.And using insulation to emit and the effect of adding metallic particles, foundry goods is without any shrinkage cavity, rarefaction defect.(4) cast(ing) surface, subsurface all are mingled with less than finding.Casting crystalline grain is carefully less, and uniformity is relatively poor, and the field trash size reduces in the foundry goods, and grade improves, no unreacted refractory metal particle in the foundry goods, and casting quality is intact.
The course of work of the present invention and result:
As shown in Figure 2, the cup 7 of running gate system is connected to foundry goods 1 by sprue 6, cross gate 5, and metallic particles 8 is introduced in the foundry goods 7 by cup 7, and foundry goods 7 tops are provided with insulated feeder 2, and rising head 2 outsides are provided with warming plate 3, and rising head 2 tops are placed with coverture 4.Carried out external refining because the present invention adopts in smelting process, carried out argon shield in casting process, and used steady stream and filled the type running gate system, in casting process, added metallic particles from running gate system with molten metal, liquid metal filling is steady; The setting time of foundry goods has been shortened in the adding of metallic particles, has accelerated solidifying of foundry goods, reduce the temperature of molten metal, refinement crystal grain, reduced the field trash size, reduce crackle and produced tendency, in the service life of improving foundry goods greatly, produced the high-performance foundry goods.
Potassium steel is a kind of based on elements such as carbon, manganese and contain traditional steel grade of multiple microalloy element, by weight percentage, its concrete composition C 0.7~1.1%, Si 0.6~0.7%, and Mn 12.5~13.5%.Adopt railway high manganese steel frog foundry goods to carry out the grain refining process implementing, THE STRUCTURE OF CASTINGS has obviously obtained refinement.Wherein, Fig. 5 is the metallograph of the field trash distribution situation of the high manganese steel frog foundry goods produced of traditional handicraft, and multiplication factor is 100 times, and the rank of field trash is the 2A level; Fig. 6 is the metallograph of the field trash distribution situation of the high manganese steel frog foundry goods produced of the present invention, and multiplication factor is 100 times, and the rank of field trash is the 1A level; Fig. 7 (a)-Fig. 7 (b) is the metallograph of the crystal grain situation of the high manganese steel frog foundry goods produced of traditional handicraft, and crystallite dimension is bigger as seen from the figure; Fig. 8 (a)-Fig. 8 (b) is the metallograph of the crystal grain situation of the high manganese steel frog foundry goods produced of the present invention, and crystal grain is tiny and even as seen from the figure.
0.6 ton of the weight of cast steel liquid metal of the present invention is carried out argon shield during cast, add the metallic particles of some and size with molten metal, makes the crystal grain of foundry goods obtain the service life that refinement improves foundry goods.Observe casting process, metallic particles adds evenly, plays the effect of accelerating cooling, and crystal grain is tiny evenly, and the field trash size reduces, and the high manganese steel casting performance significantly improves.

Claims (6)

1.一种高锰钢铸件细晶化铸造工艺方法,其特征在于包括如下步骤:1. A fine-grained casting process for high manganese steel castings, characterized in that it comprises the steps: 1)高锰钢在冶炼过程中,钢水高温出炉,出炉温度为1580±20℃,出炉后进行炉外吹氩气、喂丝精炼,严格控制钢水中磷、硫含量,P≤0.025%,S≤0.018%,浇注温度为1480±20℃;1) During the smelting process of high manganese steel, the molten steel is released at a high temperature at a temperature of 1580±20°C. After being released from the furnace, argon gas is blown outside the furnace and wire is fed for refining. The content of phosphorus and sulfur in the molten steel is strictly controlled, P≤0.025%, S ≤0.018%, pouring temperature is 1480±20℃; 2)高锰钢铸件浇注过程中,采用随流添加金属颗粒,降低金属液储能加快铸件冷却;2) During the pouring process of high manganese steel castings, metal particles are added with the flow to reduce the energy storage of molten metal and accelerate the cooling of castings; 3)金属颗粒从铸件的浇注系统加入,加入时间在整个浇注过程的中后期进行,一次性或分批次均匀加入;3) Metal particles are added from the pouring system of the casting, and the addition time is carried out in the middle and late stages of the entire pouring process, and they are added evenly in one go or in batches; 4)铸件要快速浇注,浇注速度为20kg/s~40kg/s,采用底漏包避免夹杂卷入。4) The castings should be poured quickly, the pouring speed is 20kg/s~40kg/s, and the bottom leakage ladle is used to avoid the inclusion of inclusions. 2.按照权利要求1所述的高锰钢铸件细晶化铸造工艺方法,其特征在于:所述步骤1),精炼过程中,氩气压力为0.3~0.6MPa,压力管道内径
Figure F2008100115014C00011
吹氩时间0.5~1分钟/吨钢水,喂丝量为浇注钢水总重量的0.5~2%。
2. The fine-grained casting process for high manganese steel castings according to claim 1, characterized in that in step 1), during the refining process, the argon pressure is 0.3-0.6 MPa, and the inner diameter of the pressure pipe is
Figure F2008100115014C00011
The argon blowing time is 0.5-1 minute per ton of molten steel, and the amount of wire feeding is 0.5-2% of the total weight of the poured molten steel.
3.按照权利要求1所述的高锰钢铸件细晶化铸造工艺方法,其特征在于:所述步骤2),加入金属颗粒的重量为浇注钢水总重量的1.5~5%。3. The fine-grained casting process for high manganese steel castings according to claim 1, characterized in that in step 2), the weight of metal particles added is 1.5-5% of the total weight of poured molten steel. 4.按照权利要求1所述的高锰钢铸件细晶化铸造工艺方法,其特征在于:所述步骤2),加入金属颗粒尺寸为金属颗粒预热温度150℃~350℃。4. according to the fine-grained casting process method of high manganese steel castings according to claim 1, it is characterized in that: described step 2), adding metal particle size is The metal particle preheating temperature is 150°C to 350°C. 5.按照权利要求1所述的高锰钢铸件细晶化铸造工艺方法,其特征在于:所述步骤2),加入金属颗粒种类:普碳钢或高锰钢。5. The fine-grained casting process for high manganese steel castings according to claim 1, characterized in that in step 2), the type of metal particles is added: ordinary carbon steel or high manganese steel. 6.按照权利要求1所述的高锰钢铸件细晶化铸造工艺方法,其特征在于:所述步骤3),金属颗粒从铸件的浇注系统随金属液加入,金属颗粒添加时间为铸件浇注时间的1/3~1/2。6. according to the high-manganese steel casting fine-grained casting process method of claim 1, it is characterized in that: described step 3), metal particle adds with molten metal from the gating system of casting, and metal particle adding time is casting pouring time 1/3~1/2 of that.
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