CN101264464B - Purification technique of steel scoria magnetic separation product - Google Patents
Purification technique of steel scoria magnetic separation product Download PDFInfo
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- CN101264464B CN101264464B CN 200710010644 CN200710010644A CN101264464B CN 101264464 B CN101264464 B CN 101264464B CN 200710010644 CN200710010644 CN 200710010644 CN 200710010644 A CN200710010644 A CN 200710010644A CN 101264464 B CN101264464 B CN 101264464B
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- 229910000831 Steel Inorganic materials 0.000 title claims abstract description 39
- 239000010959 steel Substances 0.000 title claims abstract description 39
- 238000007885 magnetic separation Methods 0.000 title claims abstract description 37
- 238000000746 purification Methods 0.000 title claims abstract description 7
- 241000876852 Scorias Species 0.000 title 1
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 90
- 229910052742 iron Inorganic materials 0.000 claims abstract description 45
- 239000002893 slag Substances 0.000 claims abstract description 37
- 239000000843 powder Substances 0.000 claims abstract description 30
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000000463 material Substances 0.000 claims abstract description 10
- 239000004576 sand Substances 0.000 claims abstract description 9
- 239000002562 thickening agent Substances 0.000 claims abstract description 6
- 239000007921 spray Substances 0.000 claims abstract description 5
- 238000001914 filtration Methods 0.000 claims abstract 2
- 238000000034 method Methods 0.000 claims description 17
- 239000002994 raw material Substances 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 7
- 238000000227 grinding Methods 0.000 claims description 3
- 239000000126 substance Substances 0.000 claims description 3
- 238000011049 filling Methods 0.000 claims description 2
- 239000000696 magnetic material Substances 0.000 abstract description 3
- 238000011084 recovery Methods 0.000 abstract description 3
- 238000007873 sieving Methods 0.000 abstract 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 4
- 239000002184 metal Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000000926 separation method Methods 0.000 description 3
- 238000004064 recycling Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 238000009628 steelmaking Methods 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- WUKWITHWXAAZEY-UHFFFAOYSA-L calcium difluoride Chemical compound [F-].[F-].[Ca+2] WUKWITHWXAAZEY-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000003912 environmental pollution Methods 0.000 description 1
- 239000010436 fluorite Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000006028 limestone Substances 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000008188 pellet Substances 0.000 description 1
- 238000012958 reprocessing Methods 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Abstract
本发明公开了一种钢渣磁选产品提纯工艺,将钢渣磁选产品送入球磨机并加水,充分研磨后经球磨机排料端自然排出,再经圆筒筛分成筛上和筛下两个产品,筛上产品经磁滑轮分选出块铁和尾渣,块铁经烘干机烘干后,含水量减为2%以下;筛下产品经分级机分选出溢流和返砂,通过控制喷淋水的大小来控制分级机溢流品位,进而控制分级机返砂品位,返砂通过皮带运输进入精粉粉料槽,分级机溢流经泵送至浓缩机,浓缩机底流通过过滤机过滤后进入尾粉粉料槽。本发明避免了非磁性或弱磁性的物料流失,使物料回收更充分、更彻底。粒铁含铁量由60%~65%提高到90%以上,磁选粉品位由40%~50%提高到60%以上,全面提高了钢渣产品的含铁量,提高了钢渣的综合利用率。
The invention discloses a steel slag magnetic separation product purification process. The steel slag magnetic separation product is sent into a ball mill and water is added, and after being fully ground, it is naturally discharged from the discharge end of the ball mill, and then sieved into two products on the sieve and under the sieve by cylinder sieving. The products on the sieve are sorted by magnetic pulleys to get lump iron and tailings. After the lump iron is dried by the dryer, the water content is reduced to less than 2%; The size of the spray water is used to control the overflow grade of the classifier, and then control the sand return grade of the classifier. The returned sand is transported into the fine powder tank through the belt, the overflow of the classifier is pumped to the thickener, and the underflow of the thickener passes through the filter. After filtering, it enters the tail powder powder trough. The invention avoids the loss of non-magnetic or weakly magnetic materials, and makes the recovery of materials more complete and thorough. The iron content of granular iron is increased from 60% to 65% to more than 90%, and the grade of magnetic separation powder is increased from 40% to 50% to more than 60%, which comprehensively increases the iron content of steel slag products and improves the comprehensive utilization rate of steel slag .
Description
技术领域 technical field
本发明涉及一种钢渣处理工艺,是一种对钢渣磁选产品(粒铁和磁选粉)进行深加工的工艺。The invention relates to a steel slag treatment process, which is a process for deep processing steel slag magnetic separation products (granulated iron and magnetic separation powder).
背景技术 Background technique
钢渣是炼钢过程中排除的废渣。钢渣主要来源于铁水与废钢中所含元素氧化后形成的氧化物,金属炉料带入的杂质,加入的造渣剂如石灰石、萤石、硅石以及氧化剂、脱硫产物和被侵蚀的炉衬材料等。根据炼钢所用炉型的不同,钢渣分为转炉钢渣、平炉钢渣和电炉钢渣。目前,国内的钢渣加工技术单一,普遍采用破碎——磁选选别,如鞍钢现有一条240万吨/年磁选加工线用来处理转炉所产生的钢渣。该生产线采用两段破碎两段磁滑轮选别,选别后的精矿产品重新再利用,选别的尾矿产品(钢渣磁选产品)为粒铁和磁选粉。生产线年产出粒铁10万吨左右,粒铁的含铁量在60%~65%,因其碱度波动大,回送高炉重复利用存在一定困难;生产线年产出磁选粉4万吨左右,磁选粉品位40%~50%,不能直接作为高炉生产的原料,只能做烧结球团添加原料,返回烧结重复使用,但回收利用率较低。因此,需要对钢渣磁选产品进一步处理来提高钢渣利用率。尽管专利申请号为00123358.0的发明专利公开了一种磁选钢渣再处理工艺,但由于该工艺的选别方法只采用了磁选,对非磁性或弱磁性的含铁物料不能够及时选别出来,造成一定量的金属流失。Steel slag is the waste residue removed during the steelmaking process. Steel slag mainly comes from the oxides formed after the oxidation of elements contained in molten iron and scrap steel, impurities brought by metal furnace charges, slagging agents added such as limestone, fluorite, silica, oxidants, desulfurization products, and eroded furnace lining materials. According to the different furnace types used in steelmaking, steel slag is divided into converter steel slag, open hearth furnace steel slag and electric furnace steel slag. At present, the domestic steel slag processing technology is single, and crushing-magnetic separation is generally used. For example, Anshan Iron and Steel currently has a 2.4 million tons/year magnetic separation processing line to process steel slag produced by converters. The production line adopts two stages of crushing and two stages of magnetic pulley separation, the separated concentrate products are reused, and the separated tailings products (steel slag magnetic separation products) are granular iron and magnetic separation powder. The annual output of the production line is about 100,000 tons of granular iron, and the iron content of granular iron is 60% to 65%. Because of the large fluctuations in alkalinity, it is difficult to return to the blast furnace for reuse; the annual output of the production line is about 40,000 tons of magnetic separation powder , The grade of magnetic separation powder is 40% to 50%. It cannot be directly used as raw material for blast furnace production. It can only be used as sintered pellets to add raw materials and return to sintering for reuse, but the recycling rate is low. Therefore, it is necessary to further process the steel slag magnetic separation products to improve the utilization rate of steel slag. Although the invention patent with the patent application No. 00123358.0 discloses a magnetic separation steel slag reprocessing process, since the separation method of this process only uses magnetic separation, the non-magnetic or weakly magnetic iron-containing materials cannot be separated in time , resulting in a certain amount of metal loss.
发明内容 Contents of the invention
本发明的目的在于提供一种钢渣磁选产品(粒铁和磁选粉)提纯工艺,避免非磁性或弱磁性的物料流失,使物料回收更充分、更彻底,提高钢渣利用率。The purpose of the present invention is to provide a steel slag magnetic separation product (granulated iron and magnetic separation powder) purification process, to avoid the loss of non-magnetic or weak magnetic material, to make material recovery more fully and thoroughly, and to improve the utilization rate of steel slag.
本发明的目的是这样实现的,一种钢渣磁选产品提纯工艺,其特征在于将钢渣磁选产品送入球磨机并加水,充分研磨后物料中的金属铁与其他物质分开,在水流动的作用下,经球磨机排料端自然排出,球磨机排料经圆筒筛分成筛上和筛下两个产品;筛上产品经磁滑轮分选出块铁和尾渣,块铁进块铁中间仓,尾渣进尾渣仓,块铁经烘干机烘干后,含水量减为2%以下,进入块铁成品仓,尾渣由于含有少量的金属铁返回到原料仓;筛下产品经螺旋分级机分选出溢流和返砂,在螺旋分级机的上方设有喷淋水,通过控制喷淋水的大小来控制分级机溢流品位,进而控制分级机返砂品位,分级机返砂通过皮带运输进入精粉粉料槽,分级机溢流经泵送至浓缩机,浓缩机底流通过过滤机过滤后进入尾粉粉料槽。The object of the present invention is achieved in this way, a steel slag magnetic separation product purification process is characterized in that the steel slag magnetic separation product is sent into a ball mill and water is added, and the metal iron in the material is separated from other substances after sufficient grinding, and the effect of water flow Down, it is naturally discharged through the discharge end of the ball mill, and the discharge of the ball mill is sieved by a cylinder into two products: the upper screen and the lower screen; the upper screen product is sorted by a magnetic pulley to produce lump iron and tailings, and the lump iron enters the lump iron intermediate warehouse. The tailings enter the tailings bin. After the lump iron is dried by the dryer, the water content is reduced to less than 2%, and then enters the lump iron finished product bin. The tailings return to the raw material bin because it contains a small amount of metallic iron; the products under the screen are classified by the spiral The machine sorts out the overflow and sand return, and spray water is installed above the spiral classifier. The overflow grade of the classifier is controlled by controlling the size of the spray water, and then the sand return grade of the classifier is controlled. The sand return of the classifier passes through The belt is transported into the powder trough for fine powder, the overflow of the classifier is pumped to the thickener, and the underflow of the thickener is filtered by the filter and then enters the powder trough for tailing powder.
由于本发明采用将重选与磁选相结合的方法,避免了非磁性或弱磁性的物料流失,使物料回收更充分、更彻底,粒铁含铁量由60%~65%提高到90%以上,磁选粉品位由40%~50%提高到60%以上。全面提高了钢渣产品的含铁量,有效地利用了钢渣资源,提高了钢渣的综合利用率,减少了环境污染,解决了占用大量土地的问题,给社会创造了极大的经济效益。Because the present invention adopts the method of combining gravity separation and magnetic separation, the loss of non-magnetic or weakly magnetic materials is avoided, the material recovery is more sufficient and thorough, and the iron content of granular iron is increased from 60% to 65% to 90%. Above, the grade of magnetic separation powder is increased from 40% to 50% to more than 60%. The iron content of steel slag products has been comprehensively improved, steel slag resources have been effectively utilized, the comprehensive utilization rate of steel slag has been improved, environmental pollution has been reduced, the problem of occupying a large amount of land has been solved, and great economic benefits have been created for the society.
附图说明 Description of drawings
图1是工艺流程设备形象联系图。Figure 1 is an image connection diagram of process equipment.
具体实施方式 Detailed ways
下面结合附图和实施例对本发明进一步说明。The present invention will be further described below in conjunction with the accompanying drawings and embodiments.
本发明是一种对钢渣磁选产品提纯工艺,以粒度为50~0mm钢渣磁选产品(粒铁含铁量为60%~65%,粒度为50~0mm;磁选粉品位为40%~50%,粒度为5~0mm)为原料,经选别后最终产生三种产品,分别为块铁,精粉,尾粉。该工艺既可以单独处理粒铁和磁选粉,还可以处理粒铁和磁选粉的混合物料。The invention relates to a purification process for steel slag magnetic separation products. The steel slag magnetic separation products with a particle size of 50-0mm (iron content of granular iron is 60%-65%, particle size is 50-0mm; magnetic separation powder grade is 40%- 50%, the particle size is 5-0mm) as raw materials, and after sorting, three products are finally produced, namely lump iron, refined powder and tail powder. This process can not only process granular iron and magnetic separation powder alone, but also process the mixture of granular iron and magnetic separation powder.
如图1所示,将原料由汽车运至选别车间,用前装机给磨渣前原料仓1上料,磨渣前原料由胶带机送入球磨机2,在给球磨机2送入原料的同时加水配成浓度为70%~80%的物料,物料在球介质充填率为30%~40%球磨机2内充分研磨后,使原料中的金属铁与其他物质分开,在水流动的作用下,经球磨机排料端自然排出,球磨机排料经筛孔尺寸为1.5mm的圆筒筛3分成两个产品,即筛上产品和筛下产品。筛上产品和筛下产品经不同的工艺进行选别。As shown in Figure 1, the raw materials are transported by car to the sorting workshop, and the pre-loading machine is used to load the raw material warehouse 1 before the slag grinding. Add water to make a material with a concentration of 70% to 80%. After the material is fully ground in the ball mill 2 with a ball medium filling rate of 30% to 40%, the metallic iron in the raw material is separated from other substances. Under the action of water flow, It is naturally discharged through the discharge end of the ball mill, and the discharge of the ball mill is divided into two products through the cylindrical sieve 3 with a sieve size of 1.5 mm, namely the over-sieve product and the under-sieve product. The products on the sieve and the products under the sieve are sorted by different processes.
筛上产品经磁场场强为2000奥斯特磁滑轮5选出块铁(品位90%以上,含水量10%以上)和尾渣两种产品,分别存放在块铁中间仓4和尾渣仓6内。块铁经烘干机7烘干后,含水量减为2%以下,符合炼钢厂的工艺要求,存放在块铁成品仓8内,成品块铁经汽车运至炼钢厂。选出的尾渣由于含有少量的金属铁,返回到原料仓1重新进行选别。The products on the sieve are selected through the magnetic field strength of 2000 Oersted
筛下产品经螺旋分级机9分选出溢流和返砂(品位60%以上)两种产品。返砂通过皮带运输进入精粉粉料槽13,精粉经汽车运至烧结厂。分级机溢流经泵送至浓缩机10,浓缩机底流通过过滤机11过滤后进入尾粉粉料槽12,经汽车运至尾渣场。The products under the sieve are classified into overflow and sand-returning (grade above 60%) two products by spiral classifier 9. The returned sand is transported by a belt into the fine powder powder trough 13, and the fine powder is transported to the sintering plant by car. The overflow of the classifier is pumped to the concentrator 10, and the underflow of the concentrator is filtered by the filter 11 and then enters the tailing powder tank 12, and is transported to the tailings yard by car.
工艺流程中各作业的溢流水进入水处理系统处理后重新返回到工艺流程循环使用。The overflow water from each operation in the technological process enters the water treatment system for treatment and returns to the technological process for recycling.
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CN101748222B (en) * | 2008-12-19 | 2012-02-01 | 鞍山钢铁集团公司 | Treatment process of steel tailing sludge |
CN101823150B (en) * | 2010-05-28 | 2012-06-13 | 攀枝花钢城集团有限公司 | Method for preparing reduced iron powder |
CN103060493B (en) * | 2012-06-29 | 2014-10-29 | 南京梅山冶金发展有限公司 | Steel slag water washing ball milling manufacture processing craft |
CN104399584A (en) * | 2014-12-13 | 2015-03-11 | 唐山市丰润区华晨机械维修部 | Dry magnetic separation technology for waste steel slags |
CN106076506A (en) * | 2016-06-20 | 2016-11-09 | 镇江微鑫钢业有限公司 | A kind of process technique of slag deep processing |
CN110216009B (en) * | 2019-06-18 | 2021-01-29 | 周涛 | Method for sorting steel slag |
CN114471937B (en) * | 2022-02-23 | 2023-04-07 | 昆明学院 | Method for comprehensively recovering iron-manganese minerals from silicon-manganese alloy smelting water-quenched slag |
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