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CN101226241A - Single-layer polarization and alignment function integrated film, manufacturing method thereof and liquid crystal display comprising same - Google Patents

Single-layer polarization and alignment function integrated film, manufacturing method thereof and liquid crystal display comprising same Download PDF

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Publication number
CN101226241A
CN101226241A CNA2007100039088A CN200710003908A CN101226241A CN 101226241 A CN101226241 A CN 101226241A CN A2007100039088 A CNA2007100039088 A CN A2007100039088A CN 200710003908 A CN200710003908 A CN 200710003908A CN 101226241 A CN101226241 A CN 101226241A
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orientation function
conformity membrane
polarizing
substrate
function conformity
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CN101226241B (en
Inventor
赖奕颖
郭惠隆
林圣文
陈品诚
彭美枝
谢依萍
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Industrial Technology Research Institute ITRI
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Industrial Technology Research Institute ITRI
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Abstract

A single-layer polarization and alignment function integrated film comprises an optical anisotropic material layer, wherein the surface of the optical anisotropic material layer is provided with a plurality of strip-shaped convex structures, the plurality of strip-shaped convex structures have an alignment function and can enable liquid crystal molecules to be regularly arranged, and the optical anisotropic material has a polarization effect, so that the single-layer structure has the polarization and alignment functions at the same time.

Description

Monolayer polarizing and orientation function conformity membrane and method for making thereof and the LCD that contains it
Technical field
The present invention is particularly to a kind of single layer optical film that has polarisation and orientation function concurrently that is applied to LCD relevant for a kind of monolayer polarizing and orientation function conformity membrane.
Background technology
Flat liquid crystal display extensively is applied to every hyundai electronics product, as personal computer, notebook, digital camera, mobile phone, individual digital assistant (PDA) and LCD TV etc.Traditional LCD as shown in Figure 6, comprise a pair of upper and lower light polarizing film 103,104, be located at the outside of upper substrate 101 and infrabasal plate 102 respectively, 105,106 of alignment films are arranged between the upper and lower base plate, folder is established liquid crystal layer 110, makes liquid crystal molecule regularly arranged.
Light polarizing film is the optical module that a kind of natural light of will not have polarization characteristic is transformed into the polarisation with polarization characteristic, and it has many usability on industry, for example is applied on the LCD, and light polarizing film shows on the effectiveness at it plays the part of critical role.In addition, light polarizing film also can be used for optical mirror slip, and for example: the polariscope of camera, snowfield all have great commercial exploitation with glasses or the like.
Traditional light polarizing film manufacture method; the method that disclosed for No. 2237567 and No. 2454515 of United States Patent (USP) for example; it utilizes high-molecular organic materials such as polyvinyl alcohol (PVA) (PVA) or derivatives thereof absorption iodine and makes 3~5 times of uniaxial tensions; to cause wherein optical anisotropy composition for example to contain the crystal generation rule arrangement of I; make the light inject light polarizing film be absorbed and produce polarisation at the electric-field vector of certain specific direction; yet this light polarizing film is not good to the anti-patience of envirment factors such as moisture and heat; therefore can't under hot and humid environment, use; and this polaroid diaphragm of generally still needing; as the protection of Triafol T (TAC) film, and this suitable TAC film is difficult for obtaining.In addition, this method for making needs very accurate drawing process, and is very inconvenient in the making.
Another kind of dyestuff is light polarizing film then has preferred moisture and heat compared to iodine polarizing film an anti-patience, but its shortcoming is the injury that degree of polarization is lower and be easy to be subjected to UV light and mechanical friction, simultaneously it utilizes that impregnation, heating, multiple tracks are accurate to stretch and multiple tracks technologies such as applying are made, during production costs and complexity.
In addition, when making LCD, also need to do liquid crystal molecule regularly arranged according to design, traditional alignment technique is brushing orientation (rubbing process) method, but this method is in brushing technology, and it all is the disappearance that is difficult to overcome that the dirt bits that friction film caused pollute (dust), static residual (static charge), brush mark defective (rubbingdefect) etc.In addition, currently used alignment materials is the polyimide series macromolecular, it can be divided into polyamic acid (polyamic acid) and soluble polyimide (soluble PI) two classes, the former toasts for a long time with high temperature in technology, be cracked into micromolecule during preservation easily, long preservation is not good; Therefore the latter is insoluble in the common organic solvents usually because polyimide has been state of polymer, and coating is not easy regulation and control, and synthetic difficulty is higher, will face the predicament that can't overcome so make LCD alignment in a conventional manner.
Single blooming can't satisfy the demand of display to all characteristics of light, therefore often need other various blooming of collocation, in LCD, in order to reach the demonstration purpose, several membranes materials such as light polarizing film, alignment film on need in substrate, inserting or be coated with, except that must establishing the multiple film material of produce in factory in addition, also need multiple tracks technology just can finish, quite complicated on technology.
Therefore, industry is needed a kind of multi-functional conformability film of individual layer badly, to improve the shortcoming that needs to use multiple film material in traditional liquid crystal display.
Summary of the invention
The object of the present invention is to provide a kind of monolayer polarizing and orientation function conformity membrane and method for making thereof, it can have the function of polarisation and orientation simultaneously concurrently.
For reaching above-mentioned purpose, the invention provides a kind of monolayer polarizing and orientation function conformity membrane, comprise the optical anisotropic material layer, its surface has a plurality of strip projected parts structures.
For reaching above-mentioned purpose, the present invention more provides the manufacture method of a kind of monolayer polarizing and orientation function conformity membrane, at first optical anisotropic material is coated in the substrate, forms the optical anisotropic material layer; Then, with mould with a plurality of strips depression to carrying out imprint process on the optical anisotropic material layer; At last,, on the optical anisotropic material laminar surface, form a plurality of strip projected parts structures, form monolayer polarizing and orientation function conformity membrane the mould demoulding.
In addition, the present invention provides a kind of LCD again, and it comprises liquid crystal layer, and a pair of monolayer polarizing of the present invention and orientation function conformity membrane, be arranged at respectively on first substrate and second substrate, and be provided with a plurality of strip projected parts structures mode subtend inwardly, folder is established liquid crystal layer.
The present invention more provides another kind of LCD, and it comprises liquid crystal layer; Alignment film is arranged on first substrate; Light polarizing film is arranged on first substrate, and with alignment film be opposition side; And monolayer polarizing of the present invention and orientation function conformity membrane be arranged on second substrate, and with a plurality of strip projected parts structures inwardly mode and alignment film subtend be provided with, folder is established liquid crystal layer.
For above and other objects of the present invention, feature and advantage can be become apparent, cited below particularlyly go out preferred embodiment, and cooperate appended graphicly, be described in detail below.
Description of drawings
Fig. 1 to 3 is the manufacturing process sectional view of monolayer polarizing of the present invention and orientation function conformity membrane;
Fig. 4 is the planimetric map of monolayer polarizing of the present invention and orientation function conformity membrane;
Fig. 5 is the stereographic map of the making mould of monolayer polarizing of the present invention and orientation function conformity membrane;
Fig. 6 is the section of structure of known LCD;
Fig. 7 A is the section of structure of the LCD of one embodiment of the invention, and wherein this strip projected parts structure to monolayer polarizing and orientation function conformity membrane is parallel to each other;
Fig. 7 B is the section of structure of the LCD of one embodiment of the invention, and wherein this strip projected parts structure to monolayer polarizing and orientation function conformity membrane is orthogonal;
Fig. 8 is the section of structure of the LCD of another embodiment of the present invention;
Fig. 9 is the section of structure of the LCD of another embodiment of the present invention;
Figure 10 is monolayer polarizing and the degree of polarization of orientation function conformity membrane and the test result of average penetration rate of the embodiment of the invention 1;
Figure 11 applies the test result of voltage to penetration for the LCD of the embodiment of the invention 8.
The primary clustering symbol description
10,101~upper substrate;
11,102~infrabasal plate;
20~optical anisotropic material layer;
22,23~monolayer polarizing and orientation function conformity membrane;
The strip projected parts structure of 24~monolayer polarizing and orientation function conformity membrane;
25,110~liquid crystal layer;
30~mould;
103,104,28~light polarizing film;
105,106,26~alignment film.
Embodiment
For the function with light polarizing film and alignment film combines, the microstructure that has a plurality of nanometer strips on monolayer polarizing provided by the invention and the orientation function conformity membrane surface, this microstructure can be so that the arrangement of liquid crystal molecule generation rule, in addition, because the material of monolayer polarizing of the present invention and orientation function conformity membrane has optical anisotropy, therefore can make light have different extinction effects, and then produce the polarisation effect at different directions.
The structure of monolayer polarizing of the present invention and orientation function conformity membrane is provided with optical anisotropic material layer 22 as shown in Figure 3 in substrate 10, substrate 10 is a transparency carrier, and the material of optical anisotropic material layer 22 is a composition, comprising:
(a) 97.5~50 weight % liquid crystal; And
(b) 50~0.1 weight % optical dichroic quality materials.
It is preferably (a) 96.5~90 weight % liquid crystal; And (b) 10~1 weight % optical dichroic quality materials; Be more preferred from (a) 95.5~90 weight % liquid crystal; And (b) 10~2 weight % optical dichroic quality materials.
On the surface of optical anisotropic material layer 22, have a plurality of strip projected parts structures 24, form monolayer polarizing of the present invention and orientation function conformity membrane.
The manufacture method of monolayer polarizing of the present invention and orientation function conformity membrane sees also Fig. 1 to 3, as shown in Figure 1, at first optical anisotropic material masking liquid 20 is coated in the substrate 10, its coating method for example is rotary coating, scraper coating or chip coating (die coating) etc., substrate 10 is a transparent base, its material can be the material that blendes together that is mixed with inorganic particle in glass, transparent polymer or the organic polymer, and can be coated with the ITO electrode in substrate.
The optical anisotropic material masking liquid is a composition, and its principal ingredient comprises:
(a) 80~5 weight % solid contents comprise liquid crystal and optical dichroic quality material;
(b) 2~0.01 weight % cross-linked evocating agents; And
(c) 94.5~18 weight % solvents.
It is preferably (a) 60~10 weight % solid contents, comprises liquid crystal and optical dichroic quality material; (b) 2~0.05 weight % cross-linked evocating agents; And (c) 89.5~38 weight % solvents.Be more preferred from (a) 50~15 weight % solid contents, comprise liquid crystal and optical dichroic quality material; (b) 2~0.05 weight % cross-linked evocating agents; And (c) 84.5~48 weight % solvents.
Wherein, liquid crystal for example is a nematic crystal, and its whole compositions or part composition have the polymerizable crosslinking feature; The optical dichroic quality material comprises dichroic dye, nano metal particles, CNT, high index of refraction column type or pin type particle, wherein the length of nano metal particles and CNT is 10~200nm, the refractive index of high index of refraction column type or pin type particle is 2~1.5, is of a size of 0.1~5 μ m; Visual used liquid crystal of solvent and optical dichroic quality material are selected the suitable organic solvent or the solvent of combination, preferred person for example for toluene, dimethylbenzene, contain the ketone of ring texture.
In addition, can also comprise 0~5 weight % macromolecule, macromolecule precursor, cross-linked network polybenzazole precursor thing or aforesaid combination in optical anisotropic material, wherein macromolecule for example is epoxy resin or acryl resin; The macromolecule precursor for example is methyl-propyl esters of gallic acid or propyl group esters of gallic acid; Cross-linked network polybenzazole precursor thing for example is SLM 90519 (available from Wacker Silicone), NOA65 or NOA81 (all available from Norland Products inc.), multiple functional radical methyl-propyl esters of gallic acid or multiple functional radical propyl group esters of gallic acid, aforesaid macromolecule or its composition can with the liquid crystal molecule blending to help the polymerization of optical anisotropic material; And cross-linked evocating agent for example is I369 or I907 (all available from Ciba), and it helps to form the polymkeric substance of cross-linked network.
Optical anisotropic material after overbaking is removed solvent, is formed the optical anisotropic material layer 20 that has an even surface.Then, see also Fig. 2, utilize 30 pairs of optical anisotropic material layers of mould 20 to carry out imprint process, have a plurality of periodicity strip concaveconvex structures on the mould 30.See also Fig. 5, the degree of depth a of a plurality of periodicity strip concaveconvex structures on the mould 30 is about 0.1~2.5 μ m, bulge-structure width b is about 0.025~10 μ m, period p is about 0.05~15 μ m, visual mould of length c and impression board size and adjusting, the wide ratio of its live width and paddy is about 0.2 to 5, and mould can be flat, circular arc type or roller type.By pressure sintering (hot embossing), crosslinked (UV curing) method of UV or both and usefulness, rete 20 is presented and mould 30 periodic pattern of mapping mutually.The force value of pressure sintering is about 3~30psi; Temperature must be decided on employed optical anisotropic material, if material is a liquid crystal, then hot pressing temperature is less than the temperature of its grade to (isotropic) attitude; Time is about 1~20 minute.
Optical anisotropic material of the present invention can utilize pressure sintering, UV photo-hardening method or both are also with being solidified, the macromolecule kind of looking closely wherein to be comprised and deciding, for example containing the high molecular optical anisotropic material of thermmohardening type can utilize pressure sintering to solidify, can utilize UV photo-crosslinking initiation method to be solidified and contain the high molecular optical anisotropic material of photo-hardening type, contain thermmohardening type and the high molecular optical anisotropic material of photo-hardening type simultaneously and then can utilize pressure sintering and UV photo-crosslinking initiation method to solidify.
As Fig. 3,, promptly finish monolayer polarizing of the present invention and orientation function conformity membrane 22 at last, have strip projected parts structure 24 thereon with mould 30 corresponding periodic patterns with mould 30 demouldings.
Fig. 4 is the planimetric map of monolayer polarizing of the present invention and orientation function conformity membrane 22, has a plurality of strip projected parts structures 24 on it.In monolayer polarizing of the present invention and orientation function conformity membrane, optical anisotropic material layer 22 comprises the strip projected parts thickness of structure and is about 0.1~5 μ m, the height of strip projected parts structure 24 is about 0.1~2.5 μ m, width is about 0.025~10 μ m, gap periods (pitch) is about 0.05~15 μ m, and the wide ratio of live width and paddy is about 0.2 to 5.
Fig. 7 A and 7B are the section of structure of the LCD of one embodiment of the invention, be arranged at respectively on upper substrate 10 and the infrabasal plate 11 comprising a pair of monolayer polarizing of the present invention and orientation function conformity membrane 22,23, and wherein all with strip projected parts structure 24 mode subtend configuration inwardly, therebetween is established liquid crystal layer 25 for monolayer polarizing and orientation function conformity membrane 22,23.Aforesaid upper and lower substrate can be transparency carrier, and upper substrate and infrabasal plate have drive electrode, for example is passive electrode, and wherein one of upper substrate or infrabasal plate can be the substrate that contains colored filter, and another substrate is then for containing the substrate of TFT array electrode.
Wherein, shown in Fig. 7 A, the strip projected parts structure 24 in upper and lower polarisation and the orientation function conformity membrane 22,23 can be mode parallel to each other and disposes; Or shown in Fig. 7 B, strip projected parts structure 24 in upper and lower polarisation and the orientation function conformity membrane 22,23 also can be mutually perpendicular mode and disposes, look closely the liquid crystal molecule that is adopted and decide, for example with the nematic crystal molecule, the strip projected parts structure 24 in upper and lower polarisation and the orientation function conformity membrane 22,23 can adopt the vertical mode configuration.
In addition, the section of structure of the LCD of another embodiment of the present invention as shown in Figure 8, be arranged at respectively on upper substrate 10 and the infrabasal plate 11 comprising a pair of monolayer polarizing of the present invention and orientation function conformity membrane 22,23, and wherein monolayer polarizing on the upper substrate 10 and orientation function conformity membrane 22 dispose in strip projected parts structure 24 mode outwardly, with alignment film 26 on the upper substrate 10 be opposition side.Monolayer polarizing on alignment film 26 and the infrabasal plate 11 and the configuration of strip projected parts structure 24 subtends of orientation function conformity membrane 23, therebetween is established liquid crystal layer 25.Aforesaid upper and lower substrate can be transparency carrier, and upper substrate and infrabasal plate have drive electrode, for example be passive electrode, wherein one of upper substrate or infrabasal plate can be the substrate that contains colored filter or public electrode, and another substrate is then for containing the substrate of TFT array electrode.
In the LCD of Fig. 8, be positioned at monolayer polarizing of the present invention on the upper substrate 10 and orientation function conformity membrane 22, therefore alignment film 26 need be set in addition on upper substrate 10, use so that LCD alignment to be provided as light polarizing film usefulness.
Fig. 9 is the section of structure of the LCD of further embodiment of this invention, comprising a pair of upper substrate 10 and infrabasal plate 11, monolayer polarizing of the present invention and orientation function conformity membrane 23 are arranged on the infrabasal plate 11, its strip projected parts structure 24 and the alignment film 26 subtend settings that are arranged on the upper substrate 10, therebetween is established liquid crystal layer 25, comprise that in addition light polarizing film 28 is arranged on the upper substrate 10, with alignment film 26 be opposition side.Aforesaid upper and lower substrate can be transparency carrier, and upper substrate and infrabasal plate have drive electrode, for example be passive electrode, wherein one of upper substrate or infrabasal plate can be the substrate that contains colored filter or public electrode, and another substrate is then for containing the substrate of TFT array electrode.In the LCD of Fig. 9, have only and have monolayer polarizing of the present invention and orientation function conformity membrane 23 on the infrabasal plate 11, therefore alignment film 26 and light polarizing film 28 need be set in addition on upper substrate 10, so that being provided, LCD alignment and polarisation use.
Because monolayer polarizing of the present invention and orientation function conformity membrane have the function of polarisation and orientation simultaneously concurrently, therefore not needing will have each other light polarizing film 103,104 and alignment film 105,106 as traditional LCD (Fig. 6), it can replace traditional employed light polarizing film and alignment film, directly a kind of LCD of designs simplification is made in encapsulation, makes the thickness of display and the number of plies reduce.
In addition, because monolayer polarizing of the present invention and orientation function conformity membrane are arranged at LCD inside with polarizing layer, variety of problems in the time of can avoiding traditional light polarizing film to fit in the outside, and it is not more fragile in material is coated on yet, simultaneously, monolayer polarizing of the present invention and orientation function conformity membrane more have increase to when promoting the usefulness at visual angle.In addition, because therefore the rete that the present invention adopts nano-imprint process to form has the orientation function need not use the method for making of conventional brush film orientation to make alignment film, and then overcome the problems such as static, break flour of traditional alignment film.
[embodiment 1]
Polymerisable nematic (nemetic) liquid crystal is evenly sneaked in the solvent toluene (toluene), its liquid crystal phase is 30% for solvent toluene (toluene) percentage by weight, and to add with respect to SLM 90519 content be 5% dichroic dye, and this material is coated on the glass substrate that is coated with the ITO electrode with method of spin coating.After solvent is removed in baking, insert the impression board, carry out imprint process with mould with a plurality of periodicity strip concaveconvex structures, the cycle of die surface structure is that 1.8 μ m, the degree of depth are 0.2 μ m, the rete integral width is 3cm, and length is 4cm, and the force value of imprint process is 1.5bar, temperature is 100 ℃, and the time is 20 minutes.Carry out crosslinked (curing) with UV light after the impression, then carry out demoulding again, promptly finish the monolayer polarizing and the orientation function conformity membrane of the embodiment of the invention 1.The thickness of the monolayer polarizing of the embodiment of the invention 1 and orientation function conformity membrane is about 3 μ m, (Lambda 900 with spectrometer, PerkinElmer) and polarisation measure assembly and make polarisation and measure, the result of gained as shown in figure 10, degree of polarization is 97.78% at wavelength during for 550nm, and the average penetration rate is 14.75%.
[embodiment 2~7]
The difference of the monolayer polarizing of embodiment 2~7 and orientation function conformity membrane and embodiment 1 is that the cycle of embodiment 2~7 die surface structure of using is respectively 3 μ m, 10 μ m, 250nm, 574nm, 697nm and 804nm, and other process conditions and materials used are all identical with embodiment 1.Similarly, the monolayer polarizing of embodiment 2~7 and orientation function conformity membrane are carried out degree of polarization and the test of average penetration rate, its test result is as shown in table 1.
The degree of polarization of the monolayer polarizing of table 1 embodiment 1~7 and orientation function conformity membrane and penetrance
The mould lines cycle Degree of polarization (%) Average penetration rate (%)
Embodiment 1 1.8μm 97.78 14.75
Embodiment 2 3μm 81.1 17.75
Embodiment 3 10μm 66.1 28.67
Embodiment 4 250nm 95.02 20
Embodiment 5 574nm 67 35.27
Embodiment 6 697nm 56.46 39.25
Embodiment 7 804nm 59.65 37
[embodiment 8]
With two embodiment 1 made be arranged at monolayer polarizing and orientation function conformity membrane on the transparency carrier, with the applying encapsulation relatively in vertical direction mutually of the strip projected parts structure on two plate bases, become a liquid crystal cell (cell), inject stable twisted nematic (TN) liquid crystal (MLC-13900-100, Merck), with 0~12 volt of driving of voltage, and measure it with ruddiness He-Ne Lasers (633nm) and apply penetration under the voltage in difference, the result as shown in figure 11, the contrast of resulting LCD is 19: 1.
Result by Figure 10 and Figure 11 can learn, monolayer polarizing of the present invention and orientation function conformity membrane, its degree of polarization and average penetration rate can meet in the LCD requirement to polaroid, and utilize polaroid and alignment film in the traditional LCD of monolayer polarizing of the present invention and orientation function conformity membrane replacement, still can reach the requirement of LCD contrast.
Though the present invention has disclosed preferred embodiment as above; right its is not in order to qualification the present invention, any those who are familiar with this art, without departing from the spirit and scope of the present invention; when can doing a little change and retouching, so protection scope of the present invention defines and is as the criterion when looking accompanying Claim.

Claims (17)

1. monolayer polarizing and orientation function conformity membrane comprise:
Optical anisotropic material layer, its surface have a plurality of strip projected parts structures, and wherein the height of these a plurality of strip projected parts structures is 0.1~2.5 μ m, layer polarisation and orientation function conformity membrane, and the gap periods of these a plurality of strip projected parts structures is 0.1~15 μ m.
2. monolayer polarizing as claimed in claim 1 and orientation function conformity membrane, wherein the live width of these a plurality of strip projected parts structures ratio wideer than the upper valley is 0.2 to 5.
3. monolayer polarizing as claimed in claim 1 and orientation function conformity membrane, wherein the material of this optical anisotropic material layer is a composition, comprising:
(a) 97.5~50 weight % liquid crystal; And
(b) 50~0.1 weight % optical dichroic quality materials.
4. monolayer polarizing as claimed in claim 3 and orientation function conformity membrane, wherein this optical dichroic quality material comprises dichroic dye, nano metal particles, CNT, high index of refraction column type or pin type particle.
5. monolayer polarizing as claimed in claim 3 and orientation function conformity membrane, wherein the refractive index of this high index of refraction column type or pin type particle is 2~1.5.
6. the manufacture method of monolayer polarizing and orientation function conformity membrane comprises:
Substrate is provided;
Optical anisotropic material is coated in this substrate, formed the optical anisotropic material layer;
Mould is provided, has a plurality of periodicity strip concaveconvex structures;
With this mould this optical anisotropic material layer is carried out imprint process; And
With this mould demoulding, on this optical anisotropic material laminar surface, form a plurality of strip projected parts structures, form this monolayer polarizing and orientation function conformity membrane.
7. the manufacture method of monolayer polarizing as claimed in claim 6 and orientation function conformity membrane, wherein this optical anisotropic material layer is with pressure sintering, UV optical cross-linking method or aforesaid combination and solidification.
8. the manufacture method of monolayer polarizing as claimed in claim 6 and orientation function conformity membrane, wherein the size of a plurality of periodicity strip concaveconvex structures of this mould is identical with a plurality of strip projected parts structures of this optical anisotropic material layer, it highly is 0.1~2.5 μ m, and its gap periods is 0.1~15 μ m.
9. the manufacture method of monolayer polarizing as claimed in claim 6 and orientation function conformity membrane, wherein the live width of a plurality of periodicity strip concaveconvex structures of this mould ratio wideer than the upper valley is 0.2 to 5.
10. the manufacture method of monolayer polarizing as claimed in claim 6 and orientation function conformity membrane, wherein this optical anisotropic material is a composition, comprising:
(a) 80~5 weight % liquid crystal and optical dichroic quality material;
(b) 2~0.01 weight % cross-linked evocating agents; And
(c) 94.5~18 weight % solvents.
11. the manufacture method of monolayer polarizing as claimed in claim 10 and orientation function conformity membrane, wherein said composition also comprises 0~5 weight % macromolecule, macromolecule precursor, cross-linked network polybenzazole precursor thing or aforesaid combination.
12. the manufacture method of monolayer polarizing as claimed in claim 10 and orientation function conformity membrane, wherein this optical dichroic quality material comprises dichroic dye, nano metal particles, CNT, high index of refraction column type or pin type particle.
13. a LCD comprises:
Liquid crystal layer; And
A pair of monolayer polarizing as claimed in claim 1 and orientation function conformity membrane are arranged at respectively on first substrate and second substrate, and with the mode subtend setting inwardly of these a plurality of strip projected parts structures, folder is established this liquid crystal layer.
14. LCD as claimed in claim 13, the line orientations that wherein is arranged at these a plurality of strip projected parts structures on this first substrate and this second substrate respectively is orthogonal.
15. LCD as claimed in claim 13, the line orientations that wherein is arranged at these a plurality of strip projected parts structures on this first substrate and this second substrate respectively is parallel to each other.
16. a LCD comprises:
Liquid crystal layer;
Alignment film is arranged on first substrate;
Light polarizing film is arranged on this first substrate, and with this alignment film be opposition side; And
Monolayer polarizing as claimed in claim 1 and orientation function conformity membrane are arranged on second substrate, and with mode and the setting of this alignment film subtend inwardly of these a plurality of strip projected parts structures, folder is established this liquid crystal layer.
17. LCD as claimed in claim 16, wherein this light polarizing film is monolayer polarizing as claimed in claim 1 and orientation function conformity membrane.
CN2007100039088A 2007-01-18 2007-01-18 Single-layer polarizing and alignment function integrated film and its preparation method and liquid crystal display containing it Active CN101226241B (en)

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CN102687591A (en) * 2009-11-10 2012-09-19 住友化学株式会社 Method for manufacturing organic electroluminescent element
CN102687591B (en) * 2009-11-10 2015-05-06 住友化学株式会社 Method for manufacturing organic electroluminescent element
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CN103323899A (en) * 2012-03-20 2013-09-25 东友精细化工有限公司 Polarizing plate and image display device comprising the same
CN103472617A (en) * 2013-10-11 2013-12-25 张家港康得新光电材料有限公司 PDLC (polymer dispersed liquid crystal) three-dimensional grating and manufacturing method thereof as well as liquid crystal display device
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CN108287429A (en) * 2017-01-09 2018-07-17 三星Sdi株式会社 Polarizer and the liquid crystal display for including the polarizer
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