CN101208073B - Makeup cosmetic - Google Patents

Abstract

The present invention provides a make-up cosmetic that is not sticky, has a refreshing feeling of use, has an elastic touch, a soft feeling, and good impact resistance, and has the ability to be filled into a metal dish-shaped container or a resin-made dish-shaped container and compressed. Molding, the ease and convenience of combining the above-mentioned dish-shaped container into a compact container with the ease and convenience of using multiple colors. This cosmetic cosmetic contains: component (A) a partially crosslinked organopolysiloxane polymer containing a long chain alkyl group, component (B) a partially crosslinked organopolysiloxane polymer other than component (A) Material, ingredient (C) silicone oil, ingredient (D) one or more liquid oils selected from hydrocarbon oils and/or ester oils, and ingredient (E) powder, the above is composed of (A)-(E) The composition is filled into a dish-shaped vessel, and compressed to obtain color cosmetics.

Description

Makeup Cosmetics

technical field

The present invention relates to make-up cosmetics and a preparation method thereof, more specifically, to a composition (A) composed of a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group, composed of ingredients other than (A) Component (B) composed of an external partially crosslinked organopolysiloxane polymer, component (C) composed of silicone oil, composed of one or more liquid oils selected from hydrocarbon oils and/or ester oils The component (D) and the component (E) made of powder make-up cosmetics and the preparation method thereof. the

Background technique

Cosmetics such as make-up cosmetics are items that are directly applied to the face, nails, etc., so it is very important to use them with a pleasant mood, perfect use, and a beautiful makeup look. The effect of use determines the value of cosmetics. The first step when applying cosmetics is to first tilt the bottle to allow the contents to flow into the palm of the hand, scoop out the container with fingertips, pour the contents from a metal or plastic tube, and the second step is to apply on the surface of the skin, thin Spread and rub in thinly. During such a process, the fluidity of the cosmetic will change, and the skin's feel will also change from the beginning to the end of the cosmetic application due to the absorption of oil by the skin and the evaporation of water. Therefore, the physical properties are very complex. Use words such as hard, soft, supple, stretched, wrinkled, sticky, rough, and powdery to express the evaluation of cosmetics. These manifestations are the sensory response from the beginning of using the cosmetic to the end of use. the

It is classified according to the flow characteristics and feeling of use of the cosmetics in the use stage. First, the appearance, the characteristics when touching the cosmetics to be used, the ease of taking out the cosmetics from the container, etc. were evaluated before use. The characteristics when touching the cosmetics were evaluated by the force with which the thumb or forefinger pressed the cosmetics. In addition, the ease of taking out the cosmetics from the container was evaluated based on the flow resistance and deformation state when taking the cosmetics out of the container. Next, the adhesiveness of the application site, the ease of stretching the sample on the skin, and the feeling of penetration through the skin were used as evaluations during use. Stretchability and permeability were also evaluated sensory, respectively. More specifically, after applying cosmetics or applying them at regular intervals, the post-use evaluation is based on the appearance of the skin at the site of application, the ease of wiping off the remaining cosmetics, etc. based on touch and vision. It has been reported that in order to accurately evaluate the flow characteristics, feeling in use, and effect of use of cosmetics, it is necessary to use rheological techniques (see, for example, Non-Patent Document 1). the

Liquids that flow according to Newton's laws are called Newtonian fluids, and their flow behavior is called Newtonian flow; on the other hand, dynamic liquids that do not flow according to Newton's laws are called non-Newtonian fluids, and their flow behavior is called non-Newtonian flow. Most emulsions, suspensions, polymer solutions, semi-solid substances, etc. are suitable for non-Newtonian fluids. The flow form that is not proportional to the applied shear stress and flows faster is called pseudoplastic flow; the flow form that is not proportional to the applied shear stress and is difficult to flow is called dilation flow (dialantancy) (for example, see non-patent Document 2). the

Recently, an expansive composition with one of the above-mentioned flow forms has been developed as an applicable material for cosmetic composition components such as moisturizers and massage agents. It is known that the composition is composed of the following components (A), (B) and (C) composition, that is, an expandable composition containing (A) polyethylene oxide having a weight average molecular weight of 100,000 or more, (B) water-swellable clay mineral, and (C) water (for example, see Patent Document 1) or an expandable composition with the same characteristics consisting of the following components (A) and (B), said composition containing (A) O/W containing ceramides or fatty acids with an average particle size of oil droplets below 0.2 μm type emulsion and (B) a water-soluble polymer having an average molecular weight of 300,000 or more (for example, see Patent Document 2). the

On the other hand, a variety of rheological improvement strategies have been tried in cosmetics. For example, oil-based solid cosmetics combine a lot of oil, so they appear greasy and sticky. In order to overcome poor stretchability, spreading and strong oily film feeling, cosmetics using silicone oil have been developed. Due to the excellent properties of silicone oil, a variety of silicone oils are used, and they are especially widely used as oily ingredients useful in cosmetics. This is because silicone oil has good characteristics and conditions of low viscosity, smoothness, good stretchability, refreshing touch feeling, lubricity and hydrophobicity, and tasteless and odorless. Such silicone oils are typified by chain dimethyl polysiloxanes having different molecular weights and viscosities, and examples thereof include cyclic octamethylcyclotetrasiloxane and tolyl polysiloxane. the

In order to improve the above-mentioned silicone oil and obtain safe cosmetics with a smooth and refreshing sense of use, ease of use, and good long-term stability, a polysiloxane gel composition has appeared. Although it is insoluble in benzene, it can contain and Benzene with the same weight as itself, a silicone polymer with a three-dimensional cross-linked structure consisting of R ₂ SiO units and RSiO _1.5 units at a ratio of 1-30:1, and low-viscosity silicone oil below 50cs, and the silicone polymer and the weight ratio of low-viscosity silicone oil is 5:95-30:70 (for example, refer to Patent Document 3); in addition, a composition of oily solid cosmetics has appeared, which will not cause wrinkling of the cosmetic film or low melt filling performance, It can remove the luster of the makeup film and has a cushion texture; it is suitable for oily solid cosmetics and consists of components (A)-(D), that is, it contains (A) part of the cross-linked organopolysiloxane polymer 0.5-10 wt. %, (B) low-viscosity silicone oil 5-50% by weight, (C) spherical powder 10-50% by weight, (D) solid oil and/or semi-solid oil 1-50% by weight (for example, see Patent Document 4) .

In addition, powder cosmetics are known to contain the following components (a)-(e) in order to have good adhesion and smooth spreadability, improve the uniformity and stability of the chemical film, that is, Powder cosmetics (for example, see Patent Document 5); In addition, a powder cosmetic composition containing at least one particle phase and at least one fat phase is also known, which further contains at least one gelling agent in the silicone elastomer type with surface active properties , and the particle phase in the composition is 50-98% by weight relative to the total amount of the composition (for example, see Patent Document 6). the

In addition, a composition composed of a crosslinked organopolysiloxane polymer and an oil agent other than silicone oil, and a cosmetic containing the composition are known (for example, see Patent Document 7). the

Patent Document 1: Patent Publication No. 10-182403

Patent Document 2: Patent Publication No. 2002-317124

Patent Document 3: Patent Publication No. 8-6035

Patent Document 4: Patent Publication No. 2000-281532

Patent Document 5: Patent Publication No. 2001-278730

Patent Document 6: Patent Publication No. 2003-55150

Patent Document 7: WO2003/024413 Republished Patent Gazette

Non-Patent Document 1: "Cosmetics Matters" compiled by the Japan Cosmetic Technologists Association, second edition on September 25, 2016, published by Maruzen Co., Ltd., pages 215-216

Non-Patent Document 2: "Cosmetics Matters" compiled by Japan Cosmetic Technologists Association, published by Maruzen Co., Ltd. on September 25, 2016, page 217

Contents of the invention

In the past, cosmetics such as oil-based and powder-solid eye shadows were filled in pan-shaped containers, and it was convenient to pack them in a compact container. sexual products. However, it still lacks refreshing touch and soft feeling in use, and also lacks elasticity. On the other hand, water-based gel-type cosmetics have a refreshing touch and a soft feeling, but are difficult to fill in a dish-shaped container, so it is inconvenient that a variety of colors cannot be packed in a compact container. The problem to be solved by the present invention is to provide a non-sticky, refreshing feeling of use, elastic touch and softness, good impact resistance, and the product can be filled into metal or resin dish-shaped containers. , These dish-shaped containers are used in compact containers, and various colors can be packed in one compact container, color cosmetics with simplicity and convenience. the

The inventors of the present invention paid attention to the characteristics of various organopolysiloxane polymers conventionally used in color cosmetics such as eye shadows, and earnestly studied combinations of various organopolysiloxane polymers with different physical properties. Two kinds of organopolysiloxane polymers and one or more liquid oils selected from hydrocarbon oils and/or ester oils, silicone oils, components of powders, and solvents (for example, as low-polymerized linear dimethyl Silicone oil such as simethicone based polysiloxane) is added together to obtain a paste-like substance, which is compressed and molded while absorbing the solvent, and a non-sticky, refreshing feeling of use, soft touch, and good elasticity will be obtained. The present invention has been completed by confirming that the color cosmetics are impact-resistant and can be filled in a container, and that they are simple and convenient to use. the

In other words, the present invention relates to: (1) a color cosmetic cosmetic characterized in that the cosmetic contains: an ingredient (A) consisting of a partially cross-linked organopolysiloxane polymer containing a long-chain alkyl group; Component (B) consisting of a partially crosslinked organopolysiloxane polymer other than component (A), component (C) consisting of silicone oil, one or both components selected from hydrocarbon oils and/or ester oils Component (D) composed of more than one liquid oil and component (E) composed of powder; (2) the color cosmetic cosmetic as described in (1) above, characterized in that the cosmetic is oily; (3) such as The color cosmetics described in (1) or (2) above are characterized in that component (A) is (vinyl dimethicone/dodecyl dimethicone) crosslinked polymer (crosspolymer); (4) as The color cosmetics described in any one of the above (1)-(3), is characterized in that the component (B) is a (simethicone/vinyl dimethicone) cross-linked polymer; (5) as in the above (1) - (4) The color cosmetics described in any one of the above, characterized in that component (C) is simethicone; (6) The color cosmetics described in any one of the above (1)-(5), characterized in that Containing 30-70% by mass of component (C); (7) The color cosmetic cosmetic as described in any one of (1)-(6) above, characterized by containing 0.5-10% by mass of component (D); (8) The make-up cosmetic as described in any one of the above (1)-(7), characterized in that component (E) contains a shiny plate-shaped powder; (9) as in the above-mentioned (1)-(8) The make-up cosmetics described in any one, characterized in that component (E) contains spherical powder; (10) the make-up cosmetics described in any one of the above (1)-(9), characterized in that it is filled into a dish (11) The color cosmetic cosmetic as described in any one of (1)-(10) above, characterized in that the compression-molded cosmetic The load value of the pin is 20-120gf; (12) The color cosmetic cosmetic as described in any one of the above (1)-(11), characterized in that the compression-molded cosmetic is passed through the TPA (texture profile The elasticity value (L2/L1) measured by analysis) is 0.48-0.99; (13) The color makeup cosmetic as described in any one of the above (1)-(12), characterized in that the color makeup cosmetic is eye shadow. the

In addition, the present invention also relates to (14) a method for preparing color cosmetics, which is characterized in that an ingredient (A) consisting of a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group, ), component (B) consisting of partially crosslinked organopolysiloxane polymer, component (C) consisting of silicone oil, liquid The composition of component (D) consisting of oil and component (E) consisting of powder is dispersed in a solvent such as silicone oil, filled into a dish-shaped container after dispersion, and compression-molded while absorbing the solvent. the

Description of drawings

[ Fig. 1 ] is a graph showing the measurement results of dynamic viscoelasticity of the product of the present invention (Example 1). The horizontal axis represents the deformation (%), the vertical axis G' represents the storage elastic modulus (elastic term), and G" represents the loss elastic modulus (viscous term). 

[ Fig. 2 ] shows the TPA measurement results of the product of the present invention (Example 1) obtained by a texture analyzer. the

Detailed ways

As long as the color cosmetics of the present invention contain: an ingredient (A) consisting of a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group; Component (B) consisting of an alkyl partially crosslinked organopolysiloxane polymer, component (C) consisting of a silicone oil, one or more liquid oils selected from hydrocarbon oils and/or ester oils The component (D) of the composition and the component (E) composed of powder are not particularly limited, but it is more preferable that the composition containing the above-mentioned components is oily. Furthermore, it is preferable to add a solvent such as silicone oil to the composition containing the above-mentioned components, and to compress and mold it while absorbing the solvent; further preferred is a product filled into a dish-shaped container after compression molding. The dish-shaped container can be packed into a compact container, and several can be packed into a compact container to make a set. Here, the dish-shaped container means a small and thin metal or synthetic resin dish-shaped container that can be accommodated in a compact container. According to the present invention, the oil-based cosmetics refers to products in which powder is dispersed in an oily base, which is different from powder solid cosmetics, water-based gel cosmetics, and emulsified cosmetics. The above-mentioned color cosmetics also include eye shadow, foundation, concealer, primer, blush, lipstick, mascara, eyeliner, eyebrow pencil, and the like. the

Partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups as the above-mentioned component (A) are those that contain long chain The compound of the alkyl group is sufficient, and there is no other special limitation; the above-mentioned long-chain alkyl group may preferably be a straight-chain alkyl group with 8-30 carbon atoms. The component (A) is obtained by addition polymerization of organohydrogenated diene polysiloxane and _{organopolysiloxane} ; the organohydrogenated diene polysiloxane is selected from, for example, _SiO2 units, _HSiO1. Unit, RHSiO unit, R ₂ SiO unit, R ₃ SiO _0.5 unit and R ₂ HSiO _0.5 unit (wherein, R is a substituted or unsubstituted monovalent hydrocarbon group with 1-30 carbon atoms except the aliphatic unsaturated group) At least one structural unit, the number of hydrogen atoms bonded to silicon atoms in the molecule is more than 1.5 on average; the organopolysiloxane is composed of SiO ₂ units, (CH ₂ =CH)SiO _1.5 units, RSiO _1.5 unit, R(CH ₂ =CH)SiO unit, R ₂ SiO unit, R ₃ SiO _0.5 unit and R ₂ (CH ₂ CH)SiO _0.5 unit (wherein, R is a substituted or Unsubstituted monovalent hydrocarbon groups with 1-30 carbon atoms) are composed of structural units, and the number of vinyl groups bonded to silicon atoms in the molecule is more than 1.5 on average.

Such partially cross-linked organopolysiloxanes containing long-chain alkyl groups include, for example, INCI names (International Nomenclature Cosmetic Ingredient labeling names) as (vinyl dimethicone/lauryl dimethicone) cross-linked polymers . Commercially available products include polysiloxane gels in which hydrocarbon oil or ester oil is blended with a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group. For example, KSG-41 containing 65-75% by mass (hereinafter abbreviated as "%) mineral oil; KSG-42 containing 70-80% isododecane; containing 65-75% trioctane ( Tri-2-ethylhexanoin KSG-43; KSG-44 containing 65-75% squalane (all are manufactured by Shin-Etsu Chemical Co., Ltd.); the

Depending on the purpose, one or two or more components (A) of the present invention may be used, and although the content thereof is not particularly limited, it is preferably contained in cosmetics at 0.001-15%, particularly preferably at 0.1-10%. When the ingredient (A) is added, the compatibility of the oil as a whole can be improved and the oil and powder can be mixed uniformly. In addition, an oil agent with high skin adhesion can be used in combination with silicone oil with poor skin adhesion. the

The partially cross-linked organopolysiloxane polymer other than the component (A) used as the above-mentioned component (B) may be a polysiloxane-based elastomer exhibiting a three-dimensional structure having a partially cross-linked bond, There are no other special restrictions, and examples that can be cited are polymers obtained by crosslinking and bonding organopolysiloxanes, which partially contain three-dimensional crosslinked structures, and are composed of R ₂ SiO units and RSiO _1.5 units, and may also contain R ₃ Compounds of SiO _0.5 units and/or SiO ₂ units (However, R in each constituent unit may be, for example, a hydrogen atom; an alkyl group such as a methyl group, an ethyl group, a propyl group; an aryl group such as a phenyl group or a tolyl group; and a vinyl group such as aliphatic unsaturated groups such as radicals; substituents of groups such as fluorine groups and oxiranyl groups, which may be of the same or different types), more specifically, Japanese Patent Publication No. 8-6035, Japanese Patent Publication No. Polymers described in KOKAI Publication No. 2001-342255 and the like.

Such component (B) can be, for example, INCI name (International Nomenclature Cosmetic Ingredient labeling names) as (simethicone/vinyl simethicone) cross-linked polymer. Moreover, although component (B) may be a homopolymer, it is usually used in combination with low-viscosity silicone oil in large quantities. Examples of such mixtures include KSG-15 (5 parts of partially cross-linked methyl polysiloxane and 95 parts of decamethylcyclopentyl siloxane), KSG-16 (partially cross-linked methyl polysiloxane 20-30 parts of oxane and 70-80 parts of methylpolysiloxane), KSG-17 (5 parts of partially cross-linked methylpolysiloxane and 95 parts of octamethylcyclotetramethylsiloxane), Commercial items such as KSG-18 (10-20 parts of partially cross-linked methylpolysiloxane and 80-90 parts of methylphenylpolysiloxane) (all manufactured by Shin-Etsu Chemical Co., Ltd.). the

One or two or more components (B) can be used depending on the purpose, and the content is not particularly limited, but it is preferably contained in cosmetics at 1-20%, particularly preferably at 5-15%. By compounding the component (B), the elasticity of the cosmetics can be maintained, and the compression-molded structure in the dish-shaped container can be maintained. the

The silicone oil as the above-mentioned component (C) can be either linear or cyclic, for example, with a viscosity of 50 cs or less; from the purpose of non-sticky and refreshing feeling of use (feel), and from its use as a Starting from an excellent solvent for the paste-like composition before compression molding related to the cosmetics manufacturing process, silicone oil with a low viscosity below 30cs is preferred. Low-viscosity silicone oils include, for example, low-polymerized linear dimethylpolysiloxane (dimethicone), tolylpolysiloxane, and dimethylpolysiloxane-tolylsiloxane copolymers. , and cyclic octamethylcyclotetramethylsiloxane, decamethylcyclopentasiloxane, specific examples can also be cited, such as the substance named Simethicone in INCI (Silicon KF-96 (6CS ), Siricon KF-96 (10CS), and Siricon KF-96 (20CS): manufactured by Shin-Etsu Chemical Co., Ltd.), one or more of them may be used in combination depending on the purpose. In addition, regarding the compounding form of the silicone oil, it is possible to mix a partially crosslinked organopolysiloxane polymer other than the component (A) as the component (B), and a gel form such as KSG-16. The form in which polysiloxane is used, and the form used alone are preferably used in combination. In addition, the silicone oil as a solvent is preferably a linear dimethylpolysiloxane with a low degree of polymerization as a low-viscosity silicone oil, and more specifically, Silicone KF-96 (6CS), Silicone KF-96 ( 10CS), Silicon KF-96 (20CS). the

The content of component (C) silicone oil in cosmetics is 30-70%, preferably 40-60%. As long as more than 30% is added, it can ensure a special refreshing feeling during use. In addition, as long as it is added below 70%, it can especially make makeup last longer. Even if it is compressed and molded in a dish-shaped container, it can reduce the possibility of damage to the impact resistance of the molded product. sex. In addition, in the preparation process of make-up cosmetics, adding silicone oil such as simethicone as a solvent to the composition before compression molding can be absorbed during compression molding, but sometimes a part of the added component (C) silicone oil will also be absorbed. the

Liquid oils selected from hydrocarbon oils and/or ester oils as component (D), whether derived from animal oils, vegetable oils, synthetic oils, etc., are preferably liquid substances at 25°C, such as liquid paraffin, heavy liquid isochain Alkanes, squalane, polybutene, polyisobutene, etc. as hydrocarbon oils, and, for example, glyceryl tris 2-ethylhexanoate, 2-ethylhexyl p-methoxycinnamate, cetyl isooctanoate Alkyl Esters, Isopropyl Myristate, Isopropyl Palmitate, Octyl Lauryl Myristate, Glyceryl Tricaprylate, Polyglyceryl Diisostearate, Diglyceryl Isostearate, Malic Acid Diisostearyl, neopentyl glycol dicaprylate, jojoba oil, and the like are used as the ester oil, and one or two or more of these may also be used. the

By blending the component (D), it is possible to impart affinity to the skin, a feeling of adhesion, etc. during use. Although the content of component (D) is not particularly limited, it is preferably contained in cosmetics at 0.5-10%, more preferably at 1-8%, from the viewpoint of absorbing more solvents such as silicone oil used for filling. In addition, the compounding form of the component (D) includes, for example, a form in which the component (A) is used in combination with a partially crosslinked organopolysiloxane polymer containing a long-chain alkyl group like KSG-43, or used alone. Shape. the

The powder of component (E) is not particularly limited as long as it is a powder commonly used in cosmetics, but it is preferably contained in cosmetics at 30-70%. In addition, the component (E) powder is preferably one containing platy powder, and more preferably contains platy powder having luster such as pearl luster. Furthermore, it is more preferable to contain spherical powder. 10-50%, preferably 20-40%, more preferably about 30% of plate-shaped powder can be mixed in the transformed product. In addition, it is preferable to mix 30-98% of the glossy plate-shaped powder in the powder. If it is within this range, there will be less rough deposits and a better feeling when applied to the skin. In addition, 1-10% of spherical powder can be added to cosmetics, preferably 1-5%, and 0.01%-30% of spherical powder is preferably added to the powder, more preferably 0.5%-10%. Spherical powder has a powdery feel, good stretching and extensibility, and can obtain a better non-sticky and refreshing feeling of use. In addition, since the homogenization of the system has the effect of applying cosmetics on fingers, small tablets, sponges, brushes, and other applicators, it is difficult to remove them, and it is preferable to use them in combination with powders that are not homogeneous and disintegrate well in the opposite system. , to adjust how easy it is to remove makeup from your fingers. By appropriately combining spherical powder and well-disintegrated powder in the range of 0.001:99.99-90:10, it is easy to adjust the removal of cosmetics from fingers. The average particle diameter (laser diffraction method) of the spherical powder is preferably 0.1-80 μm, more preferably 0.5-50 μm. the

In addition, the material of the component (E) includes titanium oxide, black titanium oxide, dark blue, ultramarine blue, crimson alum, iron oxide yellow, iron oxide black, zinc oxide, aluminum oxide, silicon dioxide, magnesium oxide, and zirconium oxide. , magnesium carbonate, calcium carbonate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, nitrogen Inorganic powders such as silicon dioxide; nylon, polymethyl methacrylate salt, polyalkyl acrylate, organopolysiloxane elastomer, polymethylsilsesquioxane, cross-linked polysiloxane mesh polysiloxane block copolymer, polystyrene, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-methacrylic acid copolymer, polyethylene, urethane, wool, silk, crystalline cellulose, N -Organic powders such as acyl lysine; pigment powders such as organic tar pigments and lake pigments such as organic pigments; mica titanium coated with microparticles of titanium oxide, mica titanium coated with microparticles of zinc oxide, and barium sulfate coated Mica titanium, silicon dioxide containing titanium oxide, silicon dioxide containing zinc oxide and other composite powders; and these powders with fluorine compounds, polysiloxane compounds, metal soaps, lecithin, Phospholipids, collagens, hydrocarbons, higher fatty acids, higher alcohols, esters, waxes (wax), waxes (ロゥ), surfactants, and other surface-coated powders that have been surface-treated with one or two or more of these can also be used. One or more than two types of body.

For example, glossy plate-shaped powders include glass powder coated with titanium oxide, synthetic phlogopite treated with titanium oxide, titanium mica, bismuth hydroxide coated with titanium oxide, titanium iron oxide mica, titanium mica coated with dark blue, Mica titanium coated with carmine, bismuth oxychloride, fish scale foil, iron oxide coated mica, organic pigment coated titanium mica, aluminum powder, polyethylene terephthalate, aluminum, epoxy resin lamination Powder, polyethylene terephthalate-polymethyl methacrylate laminated film powder, silica-purple-treated aluminum powder, etc. In addition, examples of the spherical powder include polymethyl methacrylate, nylon, polystyrene, silica, polysiloxane resin, and the like. Good disintegration powder that has the opposite effect to the spherical powder, not spherical or plate-shaped, for example: football-shaped, potato-shaped, golden rice candy-shaped and other irregular-shaped powders, the material can be listed : Nylon, polymethyl methacrylate, methyl methacrylate crosspolymer. the

In the color cosmetics of the present invention, in addition to the above-mentioned essential ingredients, ingredients that are usually blended in cosmetics such as oily ingredients, surfactants, water, polyhydric alcohols, and lower alcohols may be added within the range that does not impair the effects of the present invention. , water-soluble polymers, water-based ingredients such as humectants, sugars, ultraviolet absorbers, antioxidants, preservatives, enzymes such as lipase and protease, various drugs such as resorcinol and sulfur, coolants, pigments, fragrances wait. the

The above-mentioned oily components include, in addition to the essential components, hydrocarbons and oils that are not related to the properties of solid oils, semi-solid oils, liquid oils, volatile oils, etc. derived from animal oils, vegetable oils, and synthetic oils that are generally used in the field of cosmetics. waxes, hardened oils, ester oils, fatty acids, higher alcohols, silicone oils, fluorine oils, lanolin derivatives, oily gelling agents, etc. More specifically, non-liquid hydrocarbons such as petrolatum, polyethylene wax, ethylene-propylene copolymer, paraffin wax, montan wax, Fischer-Tropsch synthetic wax, ozokerite, mineral ozokerite, wood wax, olive oil, etc. Oil, castor oil, mink oil, macadamia nut tree (macademia natsu) oil and other fats, beeswax, ゲイロウ, carnauba wax, candelilla wax and other waxes, abietic acid pentaerythritol ester, cholesterol fatty acid ester, phytosterol Non-liquid esters such as fatty acid esters, fatty acids such as stearic acid, lauric acid, myristic acid, behenic acid, isostearic acid, oleic acid, stearyl alcohol, cetyl alcohol, lauryl alcohol, oleyl alcohol, iso Higher alcohols such as stearyl alcohol and behenyl alcohol, trimethylsiloxane silicic acid, highly polymerized tolyl polysiloxane, polyoxyalkylene modified organopolysiloxane, cross-linked polyether modified Methyl polysiloxane, methacrylic acid modified polysiloxane, stearyl (acyl) modified methyl polysiloxane, oil-based modified methyl polysiloxane, behenyl modified Methylpolysiloxane, polyvinylpyrrolidone modified methylpolysiloxane, highly polymerized dimethylpolysiloxane, polyoxyalkylene alkylmethylpolysiloxane methylpolysiloxane Oxane copolymer, alkoxy-modified polysiloxane, fluorine-modified polysiloxane and other non-liquid polysiloxanes, perfluorodecane, perfluorooctane, perfluoropolyether and other fluorine-based oils lanolin, lanolin, lanolin acetate, lanolin fatty acid isopropyl ester, lanolin alcohol and other lanolin derivatives, sucrose fatty acid ester, aluminum isostearate, calcium stearate, 12-hydroxystearic acid and other oily gel Gelling agents and the like can also be used in combination of one or more of the above. the

As the above-mentioned surfactant, any one can be used as long as it is generally used in cosmetics, and examples thereof include nonionic surfactants, anionic surfactants, cationic surfactants, and amphoteric surfactants. For example, glycerin fatty acid ester and its alkylene glycol adduct, polyglycerol fatty acid ester and its alkylene glycol adduct, sorbitan fatty acid ester and its alkylene glycol adduct, Sucrose fatty acid ester, polyoxyethylene hardened castor oil, polyoxyalkylene alkyl co-modified organopolysiloxane, polyether modified organopolysiloxane, lecithin, etc., or one or both of the above Use more than one species. the

Examples of the above-mentioned water-soluble polymers include natural water-soluble polymers such as guaiac gum, sodium chondroitin sulfate, sodium hyaluronate, gum arabic, sodium alginate, and carrageenan; methylcellulose, hydroxyethyl Semi-synthetic water-soluble polymers such as cellulose and hydroxymethyl cellulose; synthetic water-soluble polymers such as carboxyvinyl polymers, alkyl-added carboxyvinyl polymers, polyvinyl alcohol, polyvinylpyrrolidone, and sodium polyacrylate polymer. Other examples include protein, mucopolysaccharide, collagen, elastin, and keratin, and one or more of these may be used in combination. the

Examples of the above-mentioned antioxidants include α-tocopherol, ascorbic acid, etc.; examples of cosmetic ingredients include vitamins, anti-inflammatory drugs, herbal medicines, etc.; Use one or more of the above in combination. the

Examples of the above ultraviolet absorbers include benzophenones, PABAs, cinnamic acids, salicylic acids, 4-t-butyl-4'-methoxydibenzoylmethane, hydroxyphenol etc., and one or more of the above-mentioned ones can also be used in combination.

The pin load value of the color cosmetics cosmetics of the present invention after compression molding is preferably 20-120gf (gram force), more preferably 20-70gf, when used within this value range, it will obtain a completely non-sticky, refreshing touch and good impact resistance. For example, if it is less than 20gf, although you can get a refreshing touch that is not sticky at all, it may have poor impact resistance. If it exceeds 120gf, although it has good impact resistance, the feeling of powder is too strong and may be used. Will lack elasticity. In addition, the pin load value according to the present invention refers to filling cosmetics into a mold with a thickness of 4 mm as a sample, and using "RHEO TECH FUDOH RHEO METER" manufactured by Leotech Co., Ltd. as a measuring instrument, and the hardness measurement conditions It is set as the numerical value measured using the adapter (adapter) 3 mmφ, the penetration distance 1.5 mm, and the ascending speed 2 cm/min. the

In addition, the elastic value (L2/L1) in the TPA (testure profile analysis) measurement of the color cosmetics of the present invention by a texture analyzer is preferably 0.48-0.99, more preferably 0.50-0.99, within this range of values Get bouncy makeup. In addition, in the present invention, the elastic value (L2/L1) in the TPA measurement by the texture analyzer refers to a mold with a thickness of 4 mm filled with makeup cosmetics as a sample, and the "mass sample" manufactured by Hideo Seiki Co., Ltd. "Structural Analyzer" as a measuring machine, the TPA measuring condition is a cylindrical probe of 2mmφ, the probe speed is 0.5mm/sec, and the deformation is adjusted to 25% without destroying the sample (non-destructive area). Add 2 times of force to the sample, the time difference between the first and second time is kept at 3sec, the height change caused by the first deformation is counted as L1, and the height change caused by the second deformation is counted as L2, using L2/L1 The value obtained from the evaluation represents the return ratio of the deformation caused by the external force when the external force is removed (see "Dictionary of Food Physical Properties" (Yoxiando) co-authored by Suichi Tanaya, Hirotsu Hayashi, and Akiko Kawabata). the

The preparation method of the color cosmetics of the present invention is as long as the composition containing the above-mentioned component (A), component (B), component (C), component (D) and component (E) is dispersed in a solvent and filled into a container. , Compression molding can be done while absorbing the solvent, there is no other limitation, but the amount of solvent added is preferably 30-100 parts by weight relative to 100 parts by weight of cosmetics, more preferably 40-90 parts by weight, and even more preferably 45-60 parts by weight parts by weight, because the viscosity can be reduced under the said ratio, making it easy to fill and obtain a uniform cosmetic. As a solvent, as long as the composition containing components (A)-(E) can be dispersed in it, and then filled into the container, the solvent can be absorbed. It can be any one of silicone oil, hydrocarbon oil, and ester oil. , but silicone oil is preferred, more preferably linear dimethylpolysiloxane (simethicone) with a low degree of polymerization. More specifically, the preparation method is to uniformly disperse the powder of component (E) in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.); The silicone polymer and the component (B) partially crosslinked organopolysiloxane polymer other than the component (A) are pre-dispersed with a disperser, and the component (C) silicone oil, the component ( D) Liquid oil selected from hydrocarbon oils and ester oils, mixed uniformly, and the above-mentioned components (E) dispersed uniformly with a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.), and at the same time, the above-mentioned components (A)-(D) were added thereto , and then add simethicone and other silicone oil as a solvent to make it evenly mixed into a slurry. Fill the slurry-like composition into a metal dish-shaped container, and compress and mold it in the metal dish-shaped container while absorbing the added solvent to obtain color cosmetics. In addition, the filled metal dish-shaped container can be packed into a small container. the

Hereinafter, the present invention will be described more specifically based on examples, but the scope of protection of the present invention is not limited by these illustrated examples. the

[Synthesis of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups] 

After adding 0.1 g of 2% chloroplatinic acid ethanol solution to 160.8 g of methylhydrogenated diene polysiloxane represented by the following formula (1) and 499.8 g of methyl dienyl polysiloxane represented by the following formula (2), The temperature was kept at 70-80° C. to carry out polymerization for 2 hours to obtain a siloxane polymer (I) which is a cross-linked organopolysiloxane polymer containing a long-chain alkyl group. the

[Synthesis of Partially Crosslinked Organopolysiloxane Polymer] 

_{Potassium hydroxide} solution ₍ ethanol: water = 2:1), heated and refluxed for polymerization to obtain a reaction product. Then, the reaction product was washed with water to remove the alkaline agent, and then naturally dried to obtain a siloxane polymer (II) which is a partially crosslinked organopolysiloxane polymer.

[Example 1-10 and Comparative Example 1-3]

Preparation of eye shadows with the composition shown in Table 1, the "finger removal properties", "elasticity when using", "not sticky but refreshing feeling", "skin adhesion", "water resistance, sebum resistance "Makeup durability" and "impact resistance" were judged according to the evaluation methods and criteria shown below, and the results are shown in Table 1 together. the

[Table 1]

(%)

ND: Cannot be observed (the contents fall off from the metal container, and the surface wrinkles cannot be observed)

*1: Gottutoball D11-796C (spherical powder with a particle size of 2-5 μm: manufactured by Suzuki Oil Industry Co., Ltd.)

*2: リルサンパウダー-S (powder with a particle size of 10-14 μm: manufactured by ATOFZNA Japan Co., Ltd.)

*3: The polysiloxane polymer (I) of the above synthesis example

*4: The polysiloxane polymer (II) of the above synthesis example

*5: KF-96(20CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

*6: Hikoichiru K-500 (manufactured by Kaneda Corporation)

*7: TIO(N) (manufactured by Nissin Oiliyo Group Co., Ltd.)

(Preparation)

A. Components 1-7 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. After pre-dispersing ingredients 8 and 9, add ingredients 10-12 and mix evenly. the

C. While stirring A in a Henschel mixer, add B and disperse evenly. the

D. Add 50 parts of simethicone (KF-96(10CS)) (manufactured by Shin-Etsu Chemical Co., Ltd.) as a solvent to 100 parts of C, and mix uniformly. the

E. Fill D into a metal container, absorb the solvent with paper, and compress to form an eye shadow. the

(Evaluation method 1): "Finger removal property", "elasticity during use", "clean feeling without stickiness", "skin adhesion", "makeup durability such as water resistance and sebum resistance"

Let 20 members of the cosmetics evaluation special research group use the eye shadows of the above-mentioned examples and comparative examples, respectively, according to the following evaluation criteria, "finger removal performance", "elasticity when using", "non-sticky and refreshing feeling of use", " Each sample was evaluated on 7 levels in terms of "skin adhesion" and "makeup durability such as water resistance and sebum resistance", and the average value of the scores of all the research team members was based on the following criteria Make a judgment. the

Evaluation Benchmark

(comment content)

6: very good

5: good

4: slightly better

3: Normal

2: slightly worse

1: Poor

0: very bad

Judgment criteria

(average score) (judgment)

Above 5.0: ◎(very good)

More than 3.5 but less than 5.0: ○ (good)

Above 2.0 but below 3.5: △(Normal)

Less than 2.0: × (not good)

(Evaluation Method 2): "Shock Resistance"

The eye shadows of the above-mentioned examples and comparative examples filled in metal containers were freely dropped from a height of 50 cm to the vertical direction of the acrylic plate, and the surface state after the drop was observed, and each eye shadow passed the following 3-level evaluation criteria. determination. the

(Evaluation Judgment Criteria)

(evaluation) (judgment)

No change at all: ○

There are wrinkles on the surface:       △

Wrinkles on large surfaces: ×

(Determination of pin load value)

Make-up cosmetics are filled into a mold with a thickness of 4mm as a sample, and "RHEO TECH FUDOH RHEO METER" manufactured by Leotech Co., Ltd. is used as a measuring machine, and the hardness measurement conditions are set to use an adapter of 3mmφ, an entry distance of 1.5mm, and a rising speed of 2cm /min, to measure the pin load value. the

As can be seen from Table 1, the eye shadows of Examples 1-9, which are products of the present invention, are excellent in "finger removal", "elasticity when using", "refreshing feeling without stickiness", and "skin adhesion". ", "Water resistance, sebum resistance, long-lasting makeup", and "Impact resistance" were excellent in all items. Especially in terms of "elasticity in use" and "non-sticky feeling in use", as explained in Figure 1 below, the initial elastic feeling is very good, but as it expands, the elastic feeling disappears and slowly expands, giving people a feeling of The texture becomes powdery to the touch. In contrast, Comparative Example 1, which did not contain the polysiloxane polymer (I) containing the component (A), had inferior "skin adhesion" and "makeup durability such as water resistance and sebum resistance"; , Comparative Example 2 without the silicone polymer (II) compounded with component (B) was superior in terms of "elasticity at the time of use", "durability of makeup such as water resistance and sebum resistance", and "impact resistance". Poor; and Comparative Example 3 without the compounding component (D) is a product with poor "skin adhesion". the

(Determination of dynamic viscoelasticity) 

The color makeup cosmetics of the present invention are different from conventional oily eye shadows and powder solid eye shadows in that they have the characteristics of elasticity and unique touch. Therefore, the dynamic viscoelasticity of the eye shadow described in the above-mentioned Example 1 was measured with a Fruid spectrometer (manufactured by Leotric, RES-II). Using a 25-50mm parallel plate or kuetto, mainly use the measurement mode of deformation amplitude dependence (dynamic frequency sweep, dynamic frequency sweep) to measure geometric characteristics. For the deformation here, the case where the parallel plates are moved with a deformation amplitude equal to the distance between the parallel plates is counted as 100%, the frequency is fixed at 1 Hz, and the deformation amplitude is varied between 10 ⁻⁸ and 10 ³ . Measure under this condition, obtain storage elastic modulus (G'), loss elastic modulus (G"). Like this, Fig. 1 has shown the use cosmetic (eye shadow of embodiment 1) of the present invention to measure and obtain G' (storage elastic modulus: elastic term), G" (loss elastic modulus: viscous term) curves. G' on the vertical axis represents the storage elastic modulus (elastic term), G" represents the loss elastic modulus (viscous term), and the horizontal axis (%) represents the deformation. In Figure 1, the elastic term decreases significantly after increasing the share , but the viscous item did not increase, and decreased slightly less than the elastic item. Therefore, corresponding to the touch, the initial elastic feeling is very good, and the elastic feeling disappears with the expansion, and the feeling of slowly expanding becomes powdery. Sensitive texture.

(Determination of TPA)

TPA was carried out to powder eye shadows and emulsion eye shadows (oily eye shadows) of the products of the present invention (Examples 1, 6, 10), the reference product (Comparative Example 2) and conventional products with a texture analyzer made by Yinghong Seiki Co., Ltd. (texture profile analysis) determination. The measurement conditions are a cylindrical probe of 2 mmφ, a probe speed of 0.5 mm/sec, and the amount of deformation is adjusted to 25% without destroying the sample at all (non-destructive area). The measurement of TPA is to apply force twice to the sample with a certain probe, keep the time difference between the first time and the second time at 3 sec, record the height change caused by the first deformation as L1, and record the height change caused by the second deformation as L1 It is L2, and L2/L1 is used as the index of springness. For example, in the case of a spring, since it is a perfectly elastic body, L1=L2, thus resulting in elasticity L2/L1=1. Table 2 shows the results for elasticity (L2/L1). Can be clear that product of the present invention has elasticity by table 2. In addition, FIG. 2 shows the results of TPA determination of the product of the present invention (Example 1) using a texture analyzer as a reference. the

[Table 2]

In addition, the prescription and preparation method of the conventional product (powder eye shadow) and the conventional product (emulsion eye shadow) are shown below. the

[Prescription and preparation method of powder eye shadow]

(Element) (%)

1. Silicone-treated mica*8 20.0

2. Talc powder treated with polysiloxane*8 The balance

3. Titanium oxide coated mica 30.0

4. Boron nitride 5.0

5. Ultramarine 2.0

6. Yellow No. 401 0.5

7. Synthetic hydrocarbon wax 2.5

8. Cross-linked polysiloxane network polysiloxane block copolymer*9 2.0

9. Preservatives 0.2

10. Liquid paraffin 2.0

11. Vaseline 1.0

12. Dimethylpolysiloxane 3.0

13. Spices 0.01

*8: 3% dimethyl polysiloxane treatment

*9: KSP-100 (spherical powder with a particle size of 5 μm: manufactured by Shin-Etsu Chemical Co., Ltd.)

(Preparation)

A. Components 1-9 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Heat ingredients 10-13 to disperse them evenly. the

C. While stirring A with a Henschel mixer, add B to make it evenly dispersed. the

D. Pulverize C in a pulverizer. the

E. Fill D into a metal vessel, compress and mold to obtain powder eye shadow. the

[Prescription and preparation method of emulsion eye shadow]

(Element) (%)

1. Paraffin 3.5

2. Ethylene glycol distearate 2.0

3. Carnauba wax 1.5

4. Methylpolysiloxane 15.0

5. Squalane 7.0

6. Glyceryl tris-2-ethylhexanoate 20.0

7. Cross-linked polysiloxane network polysiloxane block copolymer*9 5.0

8. Mica titanium treated with polysiloxane*8 35.0

9. Polysiloxane-treated alloy mica*8 The balance

10. Iron oxide 0.4

11. Ultramarine 0.1

12. Paraffin 0.5

13. Squalane 2.5

14. Spices 0.01

(Preparation)

A. Heat and dissolve 12-14 evenly. the

B. Add 9-11 to A and disperse in the drum. the

C. Heat 1-6 to dissolve evenly. the

D. Add B to C and heat to dissolve evenly. the

E. Add 7 and 8 into D, heat and dissolve evenly. the

F. Heat E to 80°C, fill it into a metal container, and get an emulsion eye shadow after cooling. the

[Example 11: Eyeshadow]

(Element) (%)

1. Mica balance

2. Titanium oxide coated mica (lustrous powder) 5.0

3. Silica*10 3.0

4. Nylon*11 1.0

5. Mica titanium (lustrous powder) 20.0

6. Iron oxide yellow 0.1

7. Iron oxide black 0.1

8. Crimson alum 0.1

9. Ultramarine 0.1

10. Titanium oxide treated with polysiloxane 1.0

11. Methyl p-hydroxybenzoate 0.1

12. Simethicone*12 20.0

13. A mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups*1 34.0

14. Mixture of partially cross-linked organopolysiloxane polymers*14 35.0

15. Heavy liquid isoparaffin*15 5.0

16. Glyceryl tris-2-ethylhexanoate 1.0

17. Spices Appropriate amount

(outside prescription)

18. Solvent: Simethicone*12 40 parts

*10: Gottutoball E2-824C (spherical powder with particle size: 0.9-1.4μm: manufactured by Suzuki Oil Industry Co., Ltd.)

*11: リルサンパウダ-L (special-shaped powder with particle size: 18-25μm: manufactured by ATOFINA Japan Co., Ltd.)

*12: KF-96(10CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

*13: KSG-43 (manufactured by Shin-Etsu Chemical Co., Ltd.)

*14: KSG-16 (manufactured by Shin-Etsu Chemical Industry Co., Ltd.)

*15: パルリム18 (manufactured by NOF Corporation)

(Preparation)

A. Components 1-11 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Mix ingredients 12-17 evenly. the

C. While stirring A in a Henschel mixer, add B to make it evenly dispersed. the

D. Add ingredient 18 to 100 parts of C and make it evenly mixed. the

E. Fill D into a metal container, absorb the solvent with paper, and compress to form an eye shadow. the

The eye shadow of the present invention is excellent in "finger removal properties", "elasticity when using", "refreshing use feeling without stickiness", "skin adhesion", "makeup durability such as water resistance and sebum resistance", " Excellent performance in all aspects including impact resistance. the

[Example 12: Eyeshadow]

(Element) (%)

1. Mica Surplus

2. Talc powder 7.0

3. Cross-linked polysiloxane network polysiloxane block copolymer*9 3.0

4. Nylon*2 2.0

5. Mica titanium (lustrous powder) 20.0

6. Iron oxide yellow treated with polysiloxane 0.1

7. Iron oxide black treated with polysiloxane 0.1

8. Titanium oxide treated with polysiloxane 0.1

9. Methyl p-hydroxybenzoate 0.1

10. Tolyl polysiloxane*16 20.0

11. A mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups*13 4.0

12. Mixture of partially cross-linked organopolysiloxane polymers*14 35.0

13. Polybutene 5.0

14. Glyceryl tris-2-ethylhexanoate 1.5

15. Appropriate amount of spices

(outside prescription)

16. Solvent: Simethicone*12 60 parts

*16: KF-56 (manufactured by Shin-Etsu Chemical Industry Co., Ltd.)

(Preparation)

A. Components 1-9 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Mix ingredients 10-15 evenly. the

C. While stirring A in the Henschel mixer, add B to make it evenly dispersed. the

D. Add ingredient 16 to 100 parts of C and make it evenly mixed. the

E. Fill D into a metal container, absorb the solvent with paper, and compress to form an eye shadow. the

The eye shadow of the present invention has long-lasting makeup in terms of "finger (small piece) removal properties", "elasticity during use", "refreshing use feeling without stickiness", "skin adhesion", "water resistance, sebum resistance, etc. ” and “impact resistance” were excellent in all aspects. the

[Example 13: Foundation]

(Element) (%)

1. Mica Surplus

2. Talc powder 5.0

3. Cross-linked polysiloxane network polysiloxane block copolymer*9 3.0

4. Polystyrene*17 2.0

5. Mica titanium (lustrous powder) 20.0

6. Iron oxide yellow treated with fluorine compound 0.1

7. Iron oxide black treated with fluorine compound 0.1

8. Crimson vitriol treated with fluorine compounds 0.1

9. Microparticle titanium oxide treated with fluorine compound 2.0

10. Simethicone*5 25.0

11. A mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups*13 5.0

12. Mixture of partially crosslinked organopolysiloxane polymers*14 30.0

13. 2-Ethylhexyl p-methoxycinnamate 4.0

14. Glyceryl tris-2-ethylhexanoate 1.5

15. Appropriate amount of spices

(outside prescription)

16. Solvent: Simethicone*18 45 parts

*17: Fain Pail 3000SP-Q (spherical powder with a particle size of 5-20 μm: manufactured by Matsuura Corporation)

*18: KF-96(6CS) (manufactured by Shin-Etsu Chemical Co., Ltd.)

(Preparation)

A. Components 1-9 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Mix ingredients 10-15 evenly. the

C. While stirring A in a Henschel mixer, add B to make it evenly dispersed. the

D. Add ingredient 16 to 100 parts of C and make it evenly mixed. the

E. Fill D into a metal container, compress and mold while absorbing the solvent with paper, and obtain a foundation. the

The foundation of the present invention is durable in terms of "finger (sponge) removal", "elasticity during use", "clean feeling without stickiness", "skin adhesion", "water resistance, sebum resistance, etc. ", "Impact resistance" and other aspects are excellent. the

[Example 14: Blush (face color)]

(Element) (%)

1. Mica Surplus

2. Talc powder 5.0

3. Nylon*19 1.0

4. Methacrylic acid methyl cross-linked polymer*20 10.0

5. Mica titanium (lustrous powder) 10.0

6. Red 226 treated with fluorine compound 0.1

7. Iron oxide black treated with fluorine compound 0.1

8. Microparticle titanium oxide treated with fluorine compound 2.0

9. Simethicone*5 30.0

10. A mixture of partially crosslinked organopolysiloxane polymers containing long-chain alkyl groups*13 2.0

11. Mixture of partially cross-linked organopolysiloxane polymers*14 30.0

12. Liquid paraffin 2.0

13. Polybutene 2.0

14. Glyceryl tris-2-ethylhexanoate 1.5

15. Appropriate amount of spices

(outside prescription)

16. Solvent: Simethicone*18 55 parts

*19: Nylon powder SP-500 manufactured by Toray (spherical powder with a particle size of 1-23 μm: manufactured by Toray Corporation)

*20: Gantsu Par GMI-0804 (special-shaped powder with a particle size of 4-15 μm: manufactured by Gantsu Chemical Co., Ltd.)

(Preparation)

A. Components 1-8 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Mix ingredients 9-15 evenly. the

C. While stirring A in a Henschel mixer, add B to make it evenly dispersed. the

D. Add ingredient 16 to 100 parts of C and make it evenly mixed. the

E. Fill D into a metal container, compress and mold it while absorbing the solvent with paper, and obtain a blush. the

The blush of the present invention is excellent in "finger removal properties", "elasticity when using", "refreshing feeling without stickiness", "skin adhesion", "makeup durability such as water resistance and sebum resistance", It was excellent in all aspects including "impact resistance". the

[Example 15: lip gloss]

(Element) (%)

1. Titanium oxide coated glass powder (lustrous powder) 20.0

2. Silica*10 2.0

3. Polystyrene*17 2.0

4. Simethicone (20cs) 15.0

5. A mixture of partially cross-linked organopolysiloxane polymers containing long-chain alkyl groups*13 10.0

6. Mixture of partially cross-linked organopolysiloxane polymers*14 35.0

7. Heavy liquid isoparaffin*15 4.0

8. Diisostearyl malate The balance

9. Glyceryl tris-2-ethylhexanoate 1.5

10. 1,3-Butanediol 1.0

11. Beauty ingredients (matricaria extract) 0.1

12. Refined water 3.0

13. Appropriate amount of spices

(outside prescription)

14. Solvent: Simethicone (6cs) 35 parts

(Preparation)

A. Components 1-3 are uniformly dispersed in a Henschel mixer (manufactured by Mitsui Miike Co., Ltd.). the

B. Mix ingredients 4-13 evenly. the

C. While stirring A in a Henschel mixer, add B to make it evenly dispersed. the

D. Add ingredient 14 to 100 parts of C and make it evenly mixed. the

E. Fill D into a metal vessel, compress and mold it while absorbing the solvent with paper to obtain a lip gloss. the

The lip gloss of the present invention is long-lasting in terms of "finger (brush) removal properties", "elasticity when using", "refreshing feeling without stickiness", "skin adhesion", "water resistance, sebum resistance, etc. Performance" and "impact resistance" are excellent in all aspects. the

Industrial applicability

The color cosmetics of the present invention not only have a non-sticky, refreshing feeling of use, soft touch and elasticity, but also have good water resistance, sebum resistance, and impact resistance. In addition, they can be used on metal utensils or synthetic resins. It is compressed and molded in a container, and then packed into a small container as a set, so that multiple colors can be combined and used, which is simple and convenient. the

Claims (25)

1. Make-up cosmetics characterized by containing: 0.001-15% by mass of component (A) consisting of a partially crosslinked organopolysiloxane polymer containing a linear alkyl group having 8-30 carbon atoms, Ingredient (B) 1-20% by mass consisting of a partially crosslinked organopolysiloxane polymer other than ingredient (A), Ingredient (C) consisting of linear and/or cyclic silicone oil 30- 70% by mass, 0.5-10% by mass of component (D) consisting of one or more liquid oils selected from liquid hydrocarbon oils and/or ester oils at 25°C, and 0.5-10% by mass selected from inorganic powders , organic powders, pigment powders, composite powders, and these surface-coated powders, the component (E) consisting of one or more than two powders is 30-70% by mass, Wherein, the inorganic powder is selected from titanium oxide, black titanium oxide, dark blue, ultramarine blue, crimson alum, iron oxide yellow, iron oxide black, zinc oxide, aluminum oxide, silicon dioxide, magnesium oxide, zirconium oxide, magnesium carbonate , calcium carbonate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, silicon nitride, Bismuth oxychloride and aluminum powder; The organic powders are selected from nylon, polymethyl methacrylate, polyalkyl acrylate, organopolysiloxane elastomer, polymethylsilsesquioxane, cross-linked polysiloxane mesh Polysiloxane block copolymer, polystyrene, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-methacrylic acid copolymer, polyethylene, urethane, wool, silk, crystalline cellulose and N- Acyl lysine, fish scale foil, and methyl methacrylate crosspolymer; The pigment powders are selected from the lake pigments of organic tar pigments and organic pigments; The composite powder is selected from mica titanium, microparticle titanium oxide coated mica titanium, microparticle zinc oxide coated mica titanium, barium sulfate coated mica titanium, silicon dioxide containing titanium oxide, silicon dioxide containing zinc oxide, Titanium oxide-coated glass powder, titanium oxide-coated synthetic phlogopite, titanium oxide-coated bismuth hydroxide, iron oxide titanium mica, dark blue-coated titanium mica, carmine-coated titanium mica, iron oxide-coated mica, organic pigment coating Mica titanium, polyethylene terephthalate · aluminum · epoxy resin laminated powder, polyethylene terephthalate · polymethyl methacrylate laminated film powder, and silica · crimson Aluminum powder treated with alum; The component (A) is obtained by addition polymerization of organohydrogenated diene polysiloxane and organopolysiloxane, The organohydrogenated diene polysiloxane is composed of at least one structural unit selected from SiO ₂ units, HSiO _1.5 units, RSiO _1.5 units, RHSiO units, R ₂ SiO units, R ₃ SiO _0.5 units and R ₂ HSiO _0.5 units Composition, the average number of hydrogen atoms bonded to silicon atoms in the molecule is more than 1.5, wherein R is a substituted or unsubstituted monovalent hydrocarbon group with 1-30 carbon atoms except for aliphatic unsaturated groups; The organopolysiloxane is composed of SiO ₂ units, (CH ₂ =CH)SiO _1.5 units, RSiO _1.5 units, R(CH ₂ =CH)SiO units, R ₂ SiO units, R ₃ SiO _0.5 units and R ₂ (CH ₂ ＝CH)SiO _0.5 units of structural units, and the average number of vinyl groups bonded to silicon atoms in the molecule is more than 1.5, wherein, R is substituted or unsubstituted except for aliphatic unsaturated groups A monovalent hydrocarbon group with 1-30 carbon atoms; The component (B) contains R ₂ SiO units and RSiO _1.5 units. In the formula, R is an alkyl group, an aryl group, an aliphatic unsaturated group, a fluoro group or an oxirane group, and the component (B) may also contain R ₃ SiO _0.5 unit and/or SiO ₂ unit, in the formula, R is an alkyl group, an aryl group, an aliphatic unsaturated group, a fluoro group or an oxirane group. 2. The make-up cosmetic according to claim 1, wherein the make-up cosmetic is oily. 3. The make-up cosmetic according to claim 1 or 2, wherein the component (A) is a (vinyl dimethicone/lauryl dimethicone) crosslinked polymer. 4. The make-up cosmetic according to claim 1 or 2, wherein the component (B) is a (simethicone/vinyl dimethicone) crosslinked polymer. 5. The make-up cosmetic according to claim 4, wherein the component (A) is a (vinyl dimethicone/lauryl dimethicone) crosslinked polymer. 6. The color cosmetic cosmetic according to claim 1 or 2, wherein component (C) is simethicone. 7. The make-up cosmetic as claimed in claim 6, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl Simethicone) crosspolymer. 8. The color cosmetic cosmetic according to claim 1 or 2, wherein the component (E) contains a glossy plate-like powder. 9. The make-up cosmetic as claimed in claim 8, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) vinyl simethicone) crosslinked polymer, component (C) is simethicone. 10. The color cosmetic cosmetic according to claim 1 or 2, wherein the component (E) contains spherical powder. 11. The make-up cosmetics according to claim 10, characterized in that component (A) is (vinyl dimethicone/lauryl dimethicone) cross-linked polymer, and component (B) is (dimethicone/lauryl dimethicone) vinyl simethicone) crosslinked polymer, component (C) is simethicone. 12. The make-up cosmetic according to claim 1 or 2, wherein the dish-shaped containers are filled and compression-molded, and at least one of the dish-shaped containers is housed in a compact container. 13. The make-up cosmetic according to claim 1 or 2, characterized in that the pin load value of the compression-molded make-up cosmetic is 20-120gf, wherein the pin load value refers to filling the compression-molded make-up cosmetic Put it into a mold with a thickness of 4mm as a sample, and use "RHEO TECH FUDOH RHEO METER" manufactured by Leotech Co., Ltd. as a measuring instrument. measured value. 14. The make-up cosmetic according to claim 13, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl Simethicone) crosspolymer. 15. The make-up cosmetic as claimed in claim 13, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) vinyl simethicone) crosslinked polymer, component (C) is simethicone. 16. The make-up cosmetic according to claim 1 or 2, wherein the elasticity value L2/L1 of the compression-molded make-up cosmetic is 0.48-0.99, wherein the elasticity value L2/L1 means that the compression-molded make-up Cosmetics are filled into a mold with a thickness of 4mm as a sample, and a texture analyzer manufactured by Hideo Seiki Co., Ltd. is used as a measuring machine. The measuring conditions are a cylindrical probe of 2mmφ, and the probe speed is 0.5mm/sec. In the case of a sample, adjust the amount of deformation to 25%, use the above-mentioned probe to apply force twice to the sample, and keep the time difference between the first and second times at 3 sec. The height change caused by the first deformation is counted as L1, and the second The height change caused by secondary deformation is counted as L2, and the obtained value is calculated by L2/L1. 17. The make-up cosmetic according to claim 16, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl Simethicone) crosspolymer. 18. The make-up cosmetic according to claim 16, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) vinyl simethicone) crosslinked polymer, component (C) is simethicone. 19. The make-up cosmetic according to claim 16, characterized in that the pin load value of the compression-molded make-up cosmetic is 20-120gf, wherein the pin load value refers to filling the compression-molded make-up cosmetic into a thick A 4mm mold was used as a sample, and "RHEO TECHFUDOH RHEO METER" manufactured by Leotech Co., Ltd. was used as a measuring instrument, and the hardness measurement conditions were set to the values obtained by measuring with an adapter of 3mmφ, an entry distance of 1.5mm, and a rising speed of 2cm/min. . 20. The make-up cosmetic as claimed in claim 19, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl Simethicone) crosspolymer. 21. The make-up cosmetic as claimed in claim 19, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) vinyl simethicone) crosslinked polymer, component (C) is simethicone. 22. The make-up cosmetic according to claim 19, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl simethicone) crosslinked polymer, component (C) is simethicone, and component (E) contains glossy plate-like powder. 23. The make-up cosmetic according to claim 19, wherein component (A) is (vinyl dimethicone/lauryl dimethicone) crosslinked polymer, and component (B) is (dimethicone/lauryl dimethicone) Vinyl simethicone) crosslinked polymer, component (C) is simethicone, and component (E) contains spherical powder. 24. The make-up cosmetic according to claim 1 or 2, wherein the cosmetic is eye shadow. 25. A method for preparing color cosmetics, characterized in that the composition is dispersed in a solvent, filled into a dish-shaped container after dispersion, and compression-molded while absorbing the above-mentioned solvent, Wherein, the composition contains: Ingredient (A) 0.001-15% by mass consisting of a partially crosslinked organopolysiloxane polymer containing a straight-chain alkyl group having 8 to 30 carbon atoms, partially crosslinked by other than ingredient (A) Type organopolysiloxane polymer component (B) 1-20% by mass, component (C) 30-70% by mass of linear or cyclic silicone oil, liquid hydrocarbons selected from 25°C Component (D) 0.5-10% by mass of one or more liquid oils of oil and/or ester oil, and a composition selected from inorganic powders, organic powders, pigment powders, and composite powders Component (E) 30-70% by mass of one or more powders of these surface-coated powders, Wherein, the inorganic powder is selected from titanium oxide, black titanium oxide, dark blue, ultramarine blue, crimson alum, iron oxide yellow, iron oxide black, zinc oxide, aluminum oxide, silicon dioxide, magnesium oxide, zirconium oxide, magnesium carbonate , calcium carbonate, chromium oxide, chromium hydroxide, carbon black, aluminum silicate, magnesium silicate, aluminum magnesium silicate, mica, synthetic mica, sericite, talc, kaolin, silicon carbide, barium sulfate, silicon nitride, Bismuth oxychloride and aluminum powder; The organic powders are selected from nylon, polymethyl methacrylate, polyalkyl acrylate, organopolysiloxane elastomer, polymethylsilsesquioxane, cross-linked polysiloxane mesh Polysiloxane block copolymer, polystyrene, acrylonitrile-methacrylic acid copolymer, vinylidene chloride-methacrylic acid copolymer, polyethylene, urethane, wool, silk, crystalline cellulose and N- Acyl lysine, fish scale foil, and methyl methacrylate crosspolymer; The pigment powders are selected from the lake pigments of organic tar pigments and organic pigments; The composite powder is selected from mica titanium, microparticle titanium oxide coated mica titanium, microparticle zinc oxide coated mica titanium, barium sulfate coated mica titanium, silicon dioxide containing titanium oxide, silicon dioxide containing zinc oxide, Titanium oxide-coated glass powder, titanium oxide-coated synthetic phlogopite, titanium oxide-coated bismuth hydroxide, iron oxide titanium mica, dark blue-coated titanium mica, carmine-coated titanium mica, iron oxide-coated mica, organic pigment coating Mica titanium, polyethylene terephthalate · aluminum · epoxy resin laminated powder, polyethylene terephthalate · polymethyl methacrylate laminated film powder, and silica · crimson Aluminum powder treated with alum; The component (A) is obtained by addition polymerization of organohydrogenated diene polysiloxane and organopolysiloxane, The organohydrogenated diene polysiloxane is composed of at least one structural unit selected from SiO ₂ units, HSiO _1.5 units, RSiO _1.5 units, RHSiO units, R ₂ SiO units, R ₃ SiO _0.5 units and R ₂ HSiO _0.5 units Composition, the average number of hydrogen atoms bonded to silicon atoms in the molecule is more than 1.5, wherein R is a substituted or unsubstituted monovalent hydrocarbon group with 1-30 carbon atoms except for aliphatic unsaturated groups; The organopolysiloxane is composed of SiO ₂ units, (CH ₂ =CH)SiO _1.5 units, RSiO _1.5 units, R(CH ₂ =CH)SiO units, R ₂ SiO units, R ₃ SiO _0.5 units and R ₂ (CH ₂ ＝CH)SiO _0.5 units of structural units, and the average number of vinyl groups bonded to silicon atoms in the molecule is more than 1.5, wherein, R is substituted or unsubstituted except for aliphatic unsaturated groups A monovalent hydrocarbon group with 1-30 carbon atoms, The component (B) contains R ₂ SiO units and RSiO _1.5 units. In the formula, R is an alkyl group, an aryl group, an aliphatic unsaturated group, a fluoro group or an oxirane group, and the component (B) may also contain R ₃ SiO _0.5 unit and/or SiO ₂ unit, in the formula, R is an alkyl group, an aryl group, an aliphatic unsaturated group, a fluoro group or an oxirane group.

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