CN101207088A - Method for manufacturing well extension structure of nonvolatile memory - Google Patents
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Abstract
Description
技术领域 technical field
本发明涉及一种半导体元件的制造方法,尤其涉及一种非易失性存储器的井区延伸结构的制造方法。The invention relates to a manufacturing method of a semiconductor element, in particular to a manufacturing method of a well area extension structure of a nonvolatile memory.
背景技术 Background technique
非易失性存储器元件由于具有可进行多次数据存入、读取、抹除等动作,且存入的数据在断电后也不会消失的优点,因此已成为个人计算机和电子设备所广泛采用的一种存储器元件。Non-volatile memory components have become widely used in personal computers and electronic devices due to their advantages of multiple data storage, reading, erasing, etc., and the stored data will not disappear after power failure. A memory element used.
典型的非易失性存储器元件,一般是被设计成具有堆叠式栅极(Stacked-Gate)结构,其中包括以掺杂多晶硅制作的浮置栅极(Floating Gate)与控制栅极(Control Gate)。浮置栅极位于控制栅极和基底之间,且处于浮置状态,没有和任何电路相连接,而控制栅极则与字线(Word Line)相接,此外还包括穿隧氧化层(Tunneling Oxide)和栅间电介质层(Inter-Gate DielectricLayer)分别位于基底和浮置栅极之间以及浮置栅极和控制栅极之间。Typical non-volatile memory elements are generally designed to have a stacked gate (Stacked-Gate) structure, including a floating gate (Floating Gate) and a control gate (Control Gate) made of doped polysilicon . The floating gate is located between the control gate and the substrate, and is in a floating state, not connected to any circuit, while the control gate is connected to the word line (Word Line), and also includes the tunneling oxide layer (Tunneling Oxide) and the inter-gate dielectric layer (Inter-Gate DielectricLayer) are respectively located between the substrate and the floating gate and between the floating gate and the control gate.
另一方面,目前业界较常使用的闪存阵列包括或非(NOR)型阵列结构和与非(NAND)型阵列结构。由于与非型阵列的非易失性存储器结构是使各存储单元串接在一起,其集成度与面积利用率比或非型阵列的非易失性存储器更佳,已经广泛地应用在多种电子产品中。On the other hand, flash memory arrays commonly used in the industry include a NOR array structure and a NAND array structure. Since the non-volatile memory structure of the NAND array is to connect the memory cells in series, its integration and area utilization are better than the non-volatile memory of the NAND array, and it has been widely used in various applications. in electronic products.
在公知的与非型非易失性存储器中,在基底中设置有存储单元井区(Cellwell)。由于此存储单元井区的电阻极高,使得元件沟道区的导电度很差,进而影响元件操作速率与效能。因此,在公知的与非型非易失性存储器中,通常会形成足够数目的井区延伸(well pick-up)结构以降低井区的电阻。举例来说,在对与非型非易失性存储器进行读取操作时,利用井区延伸结构可维持存储单元井区处于良好接地状态以避免存储器的启始电压分布变大。在对与非型非易失性存储器进行抹除操作时,利用井区延伸结构可快速地将存储单元井区充电至抹除电压(约20伏特)而可以加快抹除速度。In a known NAND nonvolatile memory, a memory cell well (Cellwell) is provided in the substrate. Because the resistance of the well region of the memory cell is extremely high, the conductivity of the channel region of the device is poor, thereby affecting the operating speed and performance of the device. Therefore, in the known NAND nonvolatile memory, a sufficient number of well pick-up structures are usually formed to reduce the resistance of the well. For example, when performing a read operation on a NAND nonvolatile memory, the well extension structure of the memory cell can be used to maintain the well of the memory cell in a good grounding state to avoid the initial voltage distribution of the memory from becoming large. When performing an erasing operation on the NAND nonvolatile memory, the well area of the storage unit can be quickly charged to the erasing voltage (about 20 volts) by using the well extension structure, thereby speeding up the erasing speed.
目前业界常用的形成井区延伸结构的方法有两种。一种是在定义有源区时,在存储单元阵列区域中沿有源区的延伸方向预先保留部分区域作为形成井区延伸结构的区域。由于此种井区延伸结构位于存储单元阵列中而会占去部分字线的面积。而且,作为形成井区延伸结构的区域与字线的宽度不同,在定义有源区时,因光学邻近效应(proximity effect)而会造成线宽的差异,而且对于后续用于形成字线、位线插塞和位线的光掩模也需要进行精密的调整,而会降低工艺裕度(process window)。另一种是在两个存储单元阵列之间,沿位线的延伸方向预先保留部分区域作为形成井区延伸结构的区域。同样地,此种井区延伸结构也会占去部分位线的面积,并因光学邻近效应(proximity effect)而造成线宽的差异,而降低工艺裕度。At present, there are two methods commonly used in the industry to form the well extension structure. One is to pre-reserve a part of the area along the extending direction of the active area in the memory cell array area as the area for forming the extended structure of the well area when defining the active area. Because the well region extension structure is located in the memory cell array, it will occupy part of the area of the word line. Moreover, the width of the region forming the well extension structure is different from that of the word line. When defining the active region, the difference in line width will be caused by the optical proximity effect (proximity effect), and for the subsequent formation of the word line, bit The photomasks of the line plugs and bit lines also need to be finely tuned, which reduces the process window. The other is to pre-reserve a part of the area between the two memory cell arrays along the extending direction of the bit line as the area for forming the extended structure of the well region. Similarly, this well extension structure will also occupy part of the area of the bit line, and cause a difference in line width due to the optical proximity effect (proximity effect), thereby reducing the process margin.
发明内容 Contents of the invention
有鉴于此,本发明的目的之一就是提供一种非易失性存储器的井区延伸结构的制造方法,可以不占据字线或位线的面积,而能够增加元件的集成度。In view of this, one of the objectives of the present invention is to provide a method for manufacturing a well extension structure of a nonvolatile memory, which can increase the integration of components without occupying the area of word lines or bit lines.
本发明的另一目的是提供一种非易失性存储器的井区延伸结构的制造方法,此种方法简单,可避免因光学邻近效应造成线宽差异,而可减少制作精密光掩模的成本,并提升工艺裕度。Another object of the present invention is to provide a method for manufacturing a well area extension structure of a nonvolatile memory, which is simple, can avoid line width differences caused by optical proximity effects, and can reduce the cost of making precision photomasks , and improve the process margin.
本发明提出一种非易失性存储器的井区延伸结构的制造方法,包括下列步骤。首先,提供基底,此基底中已形成有第一导电型井区。然后,于基底中形成多个元件隔离结构,并于基底上形成多个虚拟存储单元行。各虚拟存储单元行包括第二导电型源极区和第二导电型漏极区。于基底上形成第一层间绝缘层后,于第一层间绝缘层中形成开口。此开口至少暴露出虚拟存储单元行的第二导电型漏极区以及位于第二导电型漏极区之间的元件隔离结构。移除开口所暴露的部分元件隔离结构,并于开口所暴露的基底中形成第一导电型延伸掺杂区。于开口中形成井区延伸导体层,此井区延伸导体层经由第一导电型延伸掺杂区电连接第一导电型井区。之后,于基底上形成多条虚拟位线,其中虚拟位线电连接井区延伸导体层。The invention proposes a method for manufacturing a well extension structure of a nonvolatile memory, which includes the following steps. Firstly, a substrate is provided, and a well region of the first conductivity type has been formed in the substrate. Then, a plurality of device isolation structures are formed in the substrate, and a plurality of dummy memory cell rows are formed on the substrate. Each dummy memory cell row includes a second conductivity type source region and a second conductivity type drain region. After forming the first interlayer insulating layer on the base, an opening is formed in the first interlayer insulating layer. The opening at least exposes the second conductivity type drain region of the dummy memory cell row and the element isolation structure between the second conductivity type drain region. A part of the device isolation structure exposed by the opening is removed, and a first conductive type extended doping region is formed in the substrate exposed by the opening. A well extension conductor layer is formed in the opening, and the well extension conductor layer is electrically connected to the first conductivity type well region through the first conductivity type extension doping region. After that, a plurality of dummy bit lines are formed on the substrate, wherein the dummy bit lines are electrically connected to the extended conductor layer in the well region.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,井区延伸导体层的形成方法是首先在基底上形成第一导体材料层,此第一导体材料层填满开口,然后移除第一层间绝缘层上的第一导体材料层,以在开口中形成井区延伸导体层。According to the manufacturing method of the well extension structure of the non-volatile memory according to an embodiment of the present invention, the formation method of the well extension conductor layer is to firstly form a first conductor material layer on the substrate, and the first conductor material layer is filled with The opening is filled, and then the first conductive material layer on the first interlayer insulating layer is removed to form a well extending conductive layer in the opening.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中第一导体材料层的材质包括钨、铜或铝。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the material of the first conductive material layer includes tungsten, copper or aluminum.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中移除第一层间绝缘层上的第一导体材料层的方法包括进行化学机械研磨工艺。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the method for removing the first conductive material layer on the first interlayer insulating layer includes performing a chemical mechanical polishing process.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中在第一层间绝缘层中形成开口之后,且在开口中形成井区延伸导体层之前还包括形成粘着层/阻障层。According to the method for manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, after forming the opening in the first interlayer insulating layer and before forming the well extension conductor layer in the opening, it further includes forming Adhesion layer/barrier layer.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中粘着层/阻障层的材质为选自钽、氮化钽、钛和氮化钛所组成的族群的其中之一。According to the method for manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the material of the adhesion layer/barrier layer is selected from the group consisting of tantalum, tantalum nitride, titanium and titanium nitride one of the .
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中在形成第一导电型延伸掺杂区之后,还包括进行快速热退火工艺。According to an embodiment of the present invention, the method for manufacturing the extended structure of the well region of the non-volatile memory further includes performing a rapid thermal annealing process after forming the extended doped region of the first conductivity type.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,还包括在基底上形成电连接虚拟位线与井区延伸导体层的多个插塞。The manufacturing method of the well extension structure of the non-volatile memory according to an embodiment of the present invention further includes forming a plurality of plugs electrically connecting the dummy bit line and the well extension conductor layer on the substrate.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中插塞的形成方法是首先在基底上形成第二层间绝缘层。然后,图案化第二层间绝缘层和第一层间绝缘层以形成暴露出井区延伸导体层的多个插塞开口。接着,在第二层间绝缘层上形成第二导体材料层,以填满插塞开口。之后,移除第二层间绝缘层上的部分第二导体材料层。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the plug is formed by first forming the second interlayer insulating layer on the substrate. Then, the second interlayer insulating layer and the first interlayer insulating layer are patterned to form a plurality of plug openings exposing the well region extending conductor layer. Next, a second conductive material layer is formed on the second interlayer insulating layer to fill up the opening of the plug. Afterwards, part of the second conductor material layer on the second interlayer insulating layer is removed.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中第二导体材料层的材料包括钨、铜、铝或掺杂多晶硅。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the material of the second conductive material layer includes tungsten, copper, aluminum or doped polysilicon.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中在第一层间绝缘层中形成开口的方法是首先在第一层间绝缘层上形成图案化的掩模层。然后,以掩模层为掩模,移除部分第一层间绝缘层以形成开口。之后,移除掩模层。According to the method for manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the method for forming the opening in the first interlayer insulating layer is to firstly form a patterned opening on the first interlayer insulating layer mask layer. Then, using the mask layer as a mask, part of the first interlayer insulating layer is removed to form an opening. Afterwards, the mask layer is removed.
本发明提出一种非易失性存储器的井区延伸结构的制造方法,包括下列步骤。首先,提供基底,此基底中已形成有第一导电型井区。然后,于基底中形成多个元件隔离结构,这些元件隔离结构往第一方向延伸。在基底上形成多个存储单元行。各存储单元行包括第二导电型源极区和第二导电型漏极区。接着,在基底上形成第一层间绝缘层,并在第一层间绝缘层中形成开口和沟渠。开口至少暴露出存储单元行之中相邻的两个第二导电型漏极区以及此两个第二导电型漏极区之间的元件隔离结构。沟渠往第二方向延伸并暴露出第二导电型源极区,第二方向与第一方向交错。然后,移除开口所暴露的部分元件隔离结构,并于开口所暴露的基底中形成第一导电型延伸掺杂区。在开口中形成井区延伸导体层,并在沟渠中形成源极线。井区延伸导体层经由第一导电型延伸掺杂区电连接第一导电型井区。之后,在基底上形成多条位线和多个虚拟位线,其中位线电连接第二导电型漏极区,虚拟位线分别电连接井区延伸导体层和源极线,且虚拟位线在井区延伸导体层和源极线之间为断路。The invention proposes a method for manufacturing a well extension structure of a nonvolatile memory, which includes the following steps. Firstly, a substrate is provided, and a well region of the first conductivity type has been formed in the substrate. Then, a plurality of device isolation structures are formed in the substrate, and the device isolation structures extend toward the first direction. A plurality of memory cell rows are formed on the substrate. Each memory cell row includes a second conductivity type source region and a second conductivity type drain region. Next, a first interlayer insulating layer is formed on the base, and openings and trenches are formed in the first interlayer insulating layer. The opening at least exposes two adjacent drain regions of the second conductivity type in the memory cell row and an element isolation structure between the two drain regions of the second conductivity type. The trench extends in a second direction and exposes the source region of the second conductivity type, and the second direction is intersected with the first direction. Then, part of the device isolation structure exposed by the opening is removed, and a first conductive type extended doping region is formed in the substrate exposed by the opening. A well extending conductor layer is formed in the opening, and a source line is formed in the trench. The well region extension conductor layer is electrically connected to the first conductivity type well region through the first conductivity type extended doped region. Afterwards, a plurality of bit lines and a plurality of dummy bit lines are formed on the substrate, wherein the bit lines are electrically connected to the drain region of the second conductivity type, and the dummy bit lines are respectively electrically connected to the extended conductor layer of the well region and the source line, and the dummy bit lines There is an open circuit between the well extension conductor layer and the source line.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中井区延伸导体层与源极线的形成方法如下。首先,在基底上形成第一导体材料层,此第一导体材料层并填满开口和沟渠。然后,移除第一层间绝缘层上的第一导体材料层,以在开口中形成井区延伸导体层以及在沟渠中形成源极线。According to the manufacturing method of the well extension structure of the non-volatile memory according to an embodiment of the present invention, the formation method of the well extension conductor layer and the source line is as follows. Firstly, a first conductive material layer is formed on the substrate, and the first conductive material layer fills the opening and the trench. Then, the first conductive material layer on the first interlayer insulating layer is removed to form a well extension conductive layer in the opening and a source line in the trench.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中移除第一层间绝缘层上的第一导体材料层的方法包括进行化学机械研磨工艺。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the method for removing the first conductive material layer on the first interlayer insulating layer includes performing a chemical mechanical polishing process.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中第一导体材料层的材质包括钨、铜或铝。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the material of the first conductive material layer includes tungsten, copper or aluminum.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,还包括在移除开口中的部分元件隔离结构的步骤之前,在第一层间绝缘层上形成掩模层,掩模层覆盖住沟渠,并暴露出开口。然后在基底中形成第一导电型延伸掺杂区的步骤之后,移除掩模层。The method for manufacturing the well extension structure of the nonvolatile memory according to an embodiment of the present invention further includes forming a mask on the first interlayer insulating layer before the step of removing part of the element isolation structure in the opening layer, the mask layer covers the trench and exposes the opening. Then after the step of forming the extended doped region of the first conductivity type in the substrate, the mask layer is removed.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中在形成第一导电型延伸掺杂区之后,还包括进行快速热退火工艺。According to an embodiment of the present invention, the method for manufacturing the extended structure of the well region of the non-volatile memory further includes performing a rapid thermal annealing process after forming the extended doped region of the first conductivity type.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,还包括在基底上形成分别电连接位线和第二导电型漏极区的多个第一插塞、电连接虚拟位线和井区延伸导体层的多个第二插塞以及电连接虚拟位线和源极线的多个第三插塞。The method for manufacturing the extended well region structure of the nonvolatile memory according to an embodiment of the present invention further includes forming a plurality of first plugs electrically connecting the bit line and the drain region of the second conductivity type on the substrate, A plurality of second plugs are electrically connected to the dummy bit lines and the well extension conductor layer, and a plurality of third plugs are electrically connected to the dummy bit lines and the source lines.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中第一插塞、第二插塞和第三插塞的形成方法如下。首先,在基底上形成第二层间绝缘层。然后,图案化第二层间绝缘层和第一层间绝缘层以形成暴露第二导电型漏极区的多个第一插塞开口、暴露出井区延伸导体层的多个第二插塞开口和暴露出源极线的多个第三插塞开口。接着,在第二层间绝缘层上形成第二导体材料层以填满第一插塞开口、第二插塞开口和第三插塞开口。之后,移除第二层间绝缘层上的部分第二导体材料层。According to the method of manufacturing the well extension structure of the non-volatile memory according to an embodiment of the present invention, the forming methods of the first plug, the second plug and the third plug are as follows. First, a second interlayer insulating layer is formed on a substrate. Then, pattern the second interlayer insulating layer and the first interlayer insulating layer to form a plurality of first plug openings exposing the drain region of the second conductivity type, and a plurality of second plug openings exposing the extended conductor layer of the well region and a plurality of third plug openings exposing the source lines. Next, a second conductive material layer is formed on the second interlayer insulating layer to fill up the first plug opening, the second plug opening and the third plug opening. Afterwards, part of the second conductor material layer on the second interlayer insulating layer is removed.
根据本发明一实施例所述的非易失性存储器的井区延伸结构的制造方法,其中位线和虚拟位线的形成方法如下。首先,在第二层间绝缘层上,形成第三导体材料层。然后,将第三导体材料层图案化,以形成位线和虚拟位线,其中形成于第二插塞和第三插塞上的虚拟位线为断路。According to the manufacturing method of the well extension structure of the non-volatile memory according to an embodiment of the present invention, the forming method of the bit line and the dummy bit line is as follows. First, a third conductor material layer is formed on the second interlayer insulating layer. Then, the third conductor material layer is patterned to form a bit line and a dummy bit line, wherein the dummy bit line formed on the second plug and the third plug is an open circuit.
在本发明的非易失性存储器的井区延伸结构的制造方法中,首先在存储单元阵列中两相邻的第二导电型漏极区之间,形成第一导电型延伸掺杂区,以作为第一导电型井的延伸。接着再利用井区延伸导体层与井区延伸插塞将第一导电型延伸掺杂区与位线作连结。如此一来,便可以降低第一导电型井的电阻,而增加沟道区的导电度。进而可以加速元件的操作速率,并提升元件效能。In the manufacturing method of the well extension structure of the non-volatile memory of the present invention, firstly, an extended doping region of the first conductivity type is formed between two adjacent drain regions of the second conductivity type in the memory cell array, so as to As an extension of the first conductivity type well. Then use the well extension conductor layer and the well extension plug to connect the first conductive type extended doped region and the bit line. In this way, the resistance of the well of the first conductivity type can be reduced, and the conductivity of the channel region can be increased. In turn, the operating speed of the device can be accelerated, and the performance of the device can be improved.
而且,在本发明的非易失性存储器的井区延伸结构的制造方法中,由于井区延伸结构和源极线插塞是位于相同的两个存储单元行上,因此井区延伸结构并不额外占用存储单元阵列的面积或字线与位线的区域,且没有线宽差异的问题。于是,可以避免发生邻近效应,并提升工艺裕度。Moreover, in the manufacturing method of the well extension structure of the non-volatile memory of the present invention, since the well extension structure and the source line plug are located on the same two memory cell rows, the well extension structure does not The additional area of the memory cell array or the area of the word line and the bit line is occupied, and there is no problem of line width difference. Therefore, the proximity effect can be avoided and the process margin can be improved.
此外,本发明的井区延伸结构是与源极线插塞同时形成,可以简化工艺步骤,更提高工艺裕度。In addition, the well extension structure of the present invention is formed simultaneously with the source line plug, which can simplify the process steps and improve the process margin.
为让本发明的上述和其他目的、特征和优点能更明显易懂,下文特举较佳实施例,并配合所附图式,作详细说明如下。In order to make the above and other objects, features and advantages of the present invention more comprehensible, preferred embodiments will be described in detail below together with the accompanying drawings.
附图说明 Description of drawings
图1A至图1F是根据本发明一实施例的非易失性存储器的井区延伸结构的制造流程的上视图。1A to 1F are top views of the manufacturing process of the well extension structure of the non-volatile memory according to an embodiment of the present invention.
图2A至图2F分别是图1A至图1F中沿切线A-A’的剖面图。Figures 2A to 2F are cross-sectional views along line A-A' in Figures 1A to 1F respectively.
图3A至图3F分别是图1A至图1F中沿切线B-B’的制造流程剖面图。3A to 3F are cross-sectional views of the manufacturing process along the line B-B' in FIGS. 1A to 1F .
图4A至图4F分别是图1A至图1F中沿切线C-C’的制造流程剖面图。4A to 4F are cross-sectional views of the manufacturing process along the line C-C' in FIGS. 1A to 1F .
【主要附图标记说明】[Description of main reference signs]
100:基底100: base
102:第一导电型井区102: Well area of the first conductivity type
104:元件隔离结构104: Component isolation structure
106:有源区106: Active area
108:存储单元行108: Memory cell row
108a:虚拟存储单元行108a: Virtual memory cell row
110a、110b:选择晶体管110a, 110b: selection transistors
112:存储单元112: storage unit
114:第二导电型漏极区114: second conductivity type drain region
116:第二导电型源极区116: second conductivity type source region
118:掺杂区118: doped area
120a:穿隧电介质层120a: tunneling dielectric layer
120b:浮置栅极120b: floating gate
120c:栅间电介质层120c: inter-gate dielectric layer
120d:控制栅极120d: Control grid
122:字线122串接在一起。122: the word lines 122 are connected in series.
124a:选择栅极电介质层124a: Select gate dielectric layer
124b:选择栅极124b: select gate
126:选择栅极线126: select gate line
128、146:层间绝缘层128, 146: interlayer insulating layer
130、136:掩模层130, 136: mask layer
132、138:开口132, 138: Opening
134:沟渠134: Ditch
140:第一导电型延伸掺杂区140: first conductivity type extended doping region
142a、144a:粘着层/阻障层142a, 144a: Adhesion layer/barrier layer
142b、144b:导体材料层142b, 144b: conductor material layer
142:井区延伸导体层142: Extended conductor layer in the well area
144:源极线144: Source line
148、150、152:插塞开口148, 150, 152: plug opening
154:井区延伸插塞154: Well extension plug
156:位线插塞156: bit line plug
158:源极线插塞158: Source line plug
160a、160b:虚拟位线160a, 160b: dummy bit lines
162:位线162: bit line
具体实施方式 Detailed ways
图1A至图1F为根据本发明一实施例的非易失性存储器的井区延伸结构的制造流程上视图。图2A至图2F分别为图1A至图1F中沿切线A-A’的剖面图。图3A至图3F分别为图1A至图1F中沿切线B-B’的制造流程剖面图。图4A至图4F分别为图1A至图1F中沿切线C-C’的制造流程剖面图。1A to 1F are top views of the manufacturing process of the well extension structure of the non-volatile memory according to an embodiment of the present invention. 2A to 2F are cross-sectional views along the line A-A' in FIGS. 1A to 1F respectively. 3A to 3F are cross-sectional views of the manufacturing process along the line B-B' in FIGS. 1A to 1F . 4A to 4F are cross-sectional views of the manufacturing process along the line C-C' in FIGS. 1A to 1F .
请同时参照图1A、图2A、图3A和图4A,首先提供基底100,基底100例如是硅基底。此基底100中已形成有第一导电型井区102。然后,在基底100中形成多个元件隔离结构104,以在相邻的元件隔离结构104之间定义出有源区106。元件隔离结构104例如是浅沟渠隔离结构或是场氧化层。浅沟渠隔离结构或是场氧化层的形成方法可采用任何公知的方法。元件隔离结构104在X方向(行方向)上平行排列。Please refer to FIG. 1A , FIG. 2A , FIG. 3A and FIG. 4A at the same time. Firstly, a
接着,在基底100上形成多个存储单元行108。存储单元行108例如是由两个选择晶体管110a、110b、多个存储单元112、第二导电型漏极区114和第二导电型源极区116所构成。多个存储单元112串联连接于第二导电型源极区116和第二导电型漏极区112之间。选择晶体管110b形成于存储单元112与第二导电型源极区116之间;选择晶体管110a形成于存储单元112与第二导电型漏极区114之间。而且,各存储单元112之间以及存储单元112与选择晶体管110a、110b之间例如是由掺杂区118连接在一起。Next, a plurality of
每一存储单元112从基底100起至少包括穿隧电介质层120a(tunnelingdielectric layer)、浮置栅极120b(floating gate)、栅间电介质层120c(inter-gatedielectric layer)以及控制栅极120d(control gate)。在Y方向(列方向)上,每一列的存储单元112的控制栅极120d例如是由在Y方向(列方向)上平行排列的字线122串接在一起。Each
选择晶体管110a、110b从基底100起至少包括选择栅极电介质层124a以及选择栅极124b。在Y方向(列方向)上,每一列的选择晶体管110a、110b的选择栅极124b是由在Y方向(列方向)上平行排列的选择栅极线126串接在一起。存储单元行108的形成方法可采用任何公知的方法,在此不再赘述。在本发明中,在存储单元行108中,至少两个存储单元行108上将形成源极线插塞和本发明的井区延伸结构,此两个存储单元行108不用于储存数据,因此在下述说明中,将其称为虚拟存储单元行108a。The
请同时参照图1B、图2B、图3B和图4B,在基底100上形成层间绝缘层128。层间绝缘层128的材质例如是氧化硅、磷硅玻璃、硼磷硅玻璃或其他适合的电介质材料,其形成方法例如是化学气相沉积法。接着,在层间绝缘层128上形成掩模层130。掩模层130的材质例如是氮化硅或其他适合的材料,其形成方法例如是化学气相沉积法。Referring to FIG. 1B , FIG. 2B , FIG. 3B and FIG. 4B simultaneously, an
之后,在掩模层130上形成图案化光致抗蚀剂层(未示出),且图案化光致抗蚀剂层暴露对应虚拟存储单元行108a的第二导电型漏极区114的块状区域和对应第二导电型源极区116的条状区域。图案化光致抗蚀剂层的形成方法例如是先以旋涂法(spin-on coating)形成光致抗蚀剂层,再以光刻工艺构图。接着,以图案化光致抗蚀剂层为掩模移除暴露的掩模层130,其移除方法例如是蚀刻法。之后,移除图案化光致抗蚀剂层,其移除方法例如是先以灰化工艺移除大部分光致抗蚀剂层后,再进行洗净工艺移除残余的光致抗蚀剂层。然后,以图案化后的掩模层130为掩模,移除暴露的层间绝缘层120,以形成开口132与沟渠134。移除暴露的层间绝缘层120的方法例如是蚀刻法。其中,开口132暴露出两个相邻的第二导电型漏极区114以及位于上述两个相邻的第二导电型漏极区114之间的元件隔离结构104。另外,沟渠134则暴露出Y方向中的所有第二导电型源极区116。第一导电型例如是P型,则第二导电型例如是N型;当然第一导电型也可以是N型,第二导电型是P型。Afterwards, a patterned photoresist layer (not shown) is formed on the
而后,请同时参照图1C、图2C、图3C和图4C。在掩模层130上形成掩模层136,且掩模层136覆盖住整个沟渠134,并具有开口138。开口138与开口132一起暴露出第二导电型漏极区114。掩模层136的材质例如是光致抗蚀剂,其形成方法例如是先以旋涂法形成光致抗蚀剂层(未示出),再以光刻工艺图案化。之后,移除开口138与开口132所暴露的部分元件隔离结构104而形成元件隔离结构104a。元件隔离结构104a的表面低于基底100表面。移除开口124中的部分元件隔离结构104的方法,例如是以掩模层136和掩模层130为掩模,进行蚀刻工艺。Then, please refer to FIG. 1C, FIG. 2C, FIG. 3C and FIG. 4C at the same time. A
然后,在开口138与开口132所暴露的基底100中,形成第一导电型延伸掺杂区140。第一导电型延伸掺杂区140的形成方法例如是以掩模层136和掩模层130为掩模,进行离子注入工艺,以在开口124中暴露的基底100中形成第一导电型延伸掺杂区140。特别的是,由于移除了部分元件隔离结构104,因此离子注入工艺可以更深入,而形成掺杂面积更深更广的第一导电型延伸掺杂区140。Then, in the
接着,请同时参照图1D、图2D、图3D和图4D,移除掩模层136以暴露出沟渠134。掩模层136的移除方法例如先以灰化工艺移除大部分光致抗蚀剂层后,再进行洗净工艺移除残余的光致抗蚀剂层。在一实施例中,在移除掩模层136之后,还可以进行快速热退火工艺,以修补因蚀刻工艺而受伤害的暴露的基底100表面。Next, referring to FIG. 1D , FIG. 2D , FIG. 3D and FIG. 4D , the
然后,在开口132中形成井区延伸导体层142,且在沟渠134中形成源极线144。井区延伸导体层142藉由第一导电型延伸掺杂区140与第一导电型井区102电连接。井区延伸导体层142与源极线144的形成方法例如是先在基底100上形成导体材料层,此导体材料层填满开口132与沟渠134。接着,进行化学机械研磨工艺,以掩模层130为研磨终止层,移除部分导体材料层。在一实施例中,井区延伸导体层142例如是由粘着层/阻障层142a和导体层142b所构成;源极线144例如是由粘着层/阻障层144a和导体层144b所构成。粘着层/阻障层142a和粘着层/阻障层144a对于不同金属材料,可以达到增加金属材料的附着性;或者是可以阻挡金属材料的扩散,避免造成尖峰现象(spiking)。其中,粘着层/阻障层142a和粘着层/阻障层144a的材质例如是钽、氮化钽、钛和氮化钛所组成的族群其中之一,其形成方法例如是物理气相沉积法或化学气相沉积法。导体层142b和导体层144b的材质例如是铝、钨、铜,其形成方法例如是物理气相沉积法或化学气相沉积法。Then, a well
之后,请同时参照图1E、图2E、图3E和图4E,移除掩模层130。然后,在层间绝缘层128上形成层间绝缘层146。图案化层间绝缘层146和层间绝缘层138以形成插塞开口148、插塞开口150、插塞开口152。插塞开口148位于井区延伸导体层142上方,并暴露出井区延伸导体层142;插塞开口150暴露第二导电型漏极区114;插塞开口152暴露出源极线144。插塞开口148和插塞开口152是位于相同的二条相邻的虚拟存储单元行108a上方。图案化层间绝缘层146和层间绝缘层138的方法例如是光刻蚀刻技术。Afterwards, referring to FIG. 1E , FIG. 2E , FIG. 3E and FIG. 4E , the
之后,请同时参照图1F、图2F、图3F和图4F,在层间绝缘层146上形成导体材料层(未绘示),并填满插塞开口148、插塞开口150、插塞开口152。导体材料层的材料例如是钨、铜、铝或掺杂多晶硅。在一实施例中,当导体材料层的材质为掺杂多晶硅时,其形成方法例如是先以化学气相沉积法形成多晶硅材料,再进行离子注入工艺;或者是以原位(in-situ)掺杂的方式进行化学气相沉积法。在另一实施例中,当导体材料层为钨、铜或铝时,其形成方法例如是物理气相沉积法或化学气相沉积法。当然亦可以选择性的形成粘着层/阻障层(未示出)。之后,进行化学机械研磨工艺,移除层间绝缘层146上的导体材料层。以在插塞开口148中形成井区延伸插塞154;在插塞开口150中形成位线插塞156;以及在插塞开口152中形成源极线插塞158。其中,每个位线插塞156分别与一个第二导电型漏极区112电连接;井区延伸插塞154与井区延伸导体层142电连接;而源极线插塞158与源极线144电连接。其中,源极线插塞158与井区延伸插塞154是位于相同的两个虚拟存储单元行108a上方。Afterwards, please refer to FIG. 1F, FIG. 2F, FIG. 3F and FIG. 4F at the same time, forming a conductive material layer (not shown) on the
随后,在层间绝缘层146上,形成导体材料层(未示出)。导体材料层的材料例如是钨、铜、铝或掺杂多晶硅。在一实施例中,当导体材料层的材质为掺杂多晶硅时,其形成方法例如是先以化学气相沉积法形成多晶硅材料,再进行离子注入工艺;或者是以原位掺杂的方式进行化学气相沉积法。在另一实施例中,当导体材料层为钨、铜或铝时,其形成方法例如是物理气相沉积法或化学气相沉积法。当然亦可以选择性地形成粘着层/阻障层(未示出)。然后,图案化导体材料层以形成多条位线162和虚拟位线160a、160b。其中,虚拟位线160a、160b是位于井区延伸插塞142和源极线插塞144上,且虚拟位线160a、160b在井区延伸插塞142和源极线插塞144之间形成断路。Subsequently, on the
值得一提的是,第一导电型延伸掺杂区140、井区延伸导体层142、井区延伸插塞154和虚拟位线160a互相电连接而串连成井区延伸结构。因此,井区延伸结构可作为第一导电型井区102的电性延伸路径,以降低第一导电型区102的电阻,而增加沟道区的导电度。如此一来,可以加速非易失性存储器的操作速率,并提升元件效能。It is worth mentioning that the first conductive type extended doped
而且,由于在公知工艺中,每形成一个源极线插塞158就会浪费掉两个存储单元行(虚拟存储单元行108a)的空间,而本发明的井区延伸结构和源极线插塞158是位于相同的两个虚拟存储单元行108a上。因此本发明的井区延伸结构不需要额外占用存储单元阵列的面积或字线与位线的区域,且没有线宽差异的问题。因此,可以避免发生邻近效应,并提升工艺裕度。此外,本发明的井区延伸结构的个数亦可以根据源极线插塞158的个数来设置。Moreover, since in the known process, the space of two memory cell rows (virtual
另外,本发明的井区延伸结构的形成方法是在形成源极线插塞的步骤前,增加一些简单的工艺步骤,在形成源极线插塞的同时形成井区延伸结构。因此本发明形成井区延伸结构的方法简单且具有高工艺裕度。In addition, the method for forming the well extension structure of the present invention is to add some simple process steps before the step of forming the source line plug, and form the well extension structure at the same time as the source line plug is formed. Therefore, the method for forming the well extension structure of the present invention is simple and has high process margin.
虽然本发明已以较佳实施例公开如上,然其并非用以限定本发明,任何本领域普通技术人员,在不脱离本发明的精神和范围内,可进行一些更动和润饰,因此本发明的保护范围应当以所附权利要求书界定的范围为准。Although the present invention has been disclosed above with preferred embodiments, it is not intended to limit the present invention. Any person skilled in the art can make some changes and modifications without departing from the spirit and scope of the present invention. Therefore, the present invention The scope of protection should be subject to the scope defined by the appended claims.
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