CN101198684B - Fabric conditioning composition and use - Google Patents
Fabric conditioning composition and use Download PDFInfo
- Publication number
- CN101198684B CN101198684B CN2006800212530A CN200680021253A CN101198684B CN 101198684 B CN101198684 B CN 101198684B CN 2006800212530 A CN2006800212530 A CN 2006800212530A CN 200680021253 A CN200680021253 A CN 200680021253A CN 101198684 B CN101198684 B CN 101198684B
- Authority
- CN
- China
- Prior art keywords
- purposes
- alkyl
- fabric
- rinsing
- composition
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 80
- 239000004744 fabric Substances 0.000 title claims abstract description 26
- 230000003750 conditioning effect Effects 0.000 title abstract 2
- 238000005406 washing Methods 0.000 claims abstract description 53
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- -1 alkyl quaternary ammonium compound Chemical class 0.000 claims description 29
- 239000007788 liquid Substances 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 20
- 125000000217 alkyl group Chemical group 0.000 claims description 14
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 claims description 12
- 125000003342 alkenyl group Chemical group 0.000 claims description 11
- 150000002500 ions Chemical class 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 125000002768 hydroxyalkyl group Chemical group 0.000 claims description 7
- JZMJDSHXVKJFKW-UHFFFAOYSA-M methyl sulfate(1-) Chemical compound COS([O-])(=O)=O JZMJDSHXVKJFKW-UHFFFAOYSA-M 0.000 claims description 7
- 241000370738 Chlorion Species 0.000 claims description 6
- 125000004432 carbon atom Chemical group C* 0.000 claims description 6
- 239000004215 Carbon black (E152) Substances 0.000 claims description 4
- 229930195733 hydrocarbon Natural products 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 claims description 3
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 claims description 3
- 229960000686 benzalkonium chloride Drugs 0.000 claims description 3
- CADWTSSKOVRVJC-UHFFFAOYSA-N benzyl(dimethyl)azanium;chloride Chemical compound [Cl-].C[NH+](C)CC1=CC=CC=C1 CADWTSSKOVRVJC-UHFFFAOYSA-N 0.000 claims description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 3
- KIWBPDUYBMNFTB-UHFFFAOYSA-M ethyl sulfate Chemical compound CCOS([O-])(=O)=O KIWBPDUYBMNFTB-UHFFFAOYSA-M 0.000 claims description 3
- 239000001257 hydrogen Substances 0.000 claims description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 3
- YPJKMVATUPSWOH-UHFFFAOYSA-N nitrooxidanyl Chemical compound [O][N+]([O-])=O YPJKMVATUPSWOH-UHFFFAOYSA-N 0.000 claims description 3
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 2
- 150000001735 carboxylic acids Chemical class 0.000 claims 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims 1
- 238000000034 method Methods 0.000 abstract description 7
- 230000008569 process Effects 0.000 abstract description 5
- 239000000463 material Substances 0.000 description 18
- 239000003795 chemical substances by application Substances 0.000 description 17
- 150000001875 compounds Chemical class 0.000 description 17
- 239000003599 detergent Substances 0.000 description 17
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 14
- 239000000047 product Substances 0.000 description 13
- 239000006185 dispersion Substances 0.000 description 10
- 239000008139 complexing agent Substances 0.000 description 8
- 239000006260 foam Substances 0.000 description 8
- 239000013543 active substance Substances 0.000 description 7
- 239000013530 defoamer Substances 0.000 description 7
- 150000002148 esters Chemical class 0.000 description 7
- 229920001296 polysiloxane Polymers 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 150000003856 quaternary ammonium compounds Chemical group 0.000 description 6
- 239000012487 rinsing solution Substances 0.000 description 6
- 238000003756 stirring Methods 0.000 description 6
- 239000003760 tallow Substances 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 5
- 239000004902 Softening Agent Substances 0.000 description 5
- QRUFUHLEVQQZRF-UHFFFAOYSA-N azanium ethanol methyl sulfate Chemical compound [NH4+].CCO.CCO.CCO.COS([O-])(=O)=O QRUFUHLEVQQZRF-UHFFFAOYSA-N 0.000 description 5
- 125000002091 cationic group Chemical group 0.000 description 5
- 150000003839 salts Chemical class 0.000 description 5
- 239000000654 additive Substances 0.000 description 4
- 125000005466 alkylenyl group Chemical group 0.000 description 4
- NLYCKYFADQUGOV-UHFFFAOYSA-N azane;propane;hydrochloride Chemical compound N.Cl.CCC NLYCKYFADQUGOV-UHFFFAOYSA-N 0.000 description 4
- 150000001721 carbon Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000003993 interaction Effects 0.000 description 4
- 239000004753 textile Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 125000004423 acyloxy group Chemical group 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000014121 butter Nutrition 0.000 description 3
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 3
- 239000003153 chemical reaction reagent Substances 0.000 description 3
- 150000005690 diesters Chemical class 0.000 description 3
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 150000002191 fatty alcohols Chemical class 0.000 description 3
- 238000005189 flocculation Methods 0.000 description 3
- 230000016615 flocculation Effects 0.000 description 3
- 239000003112 inhibitor Substances 0.000 description 3
- 229910052500 inorganic mineral Inorganic materials 0.000 description 3
- 238000004900 laundering Methods 0.000 description 3
- 150000002632 lipids Chemical class 0.000 description 3
- 239000011707 mineral Substances 0.000 description 3
- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 150000003333 secondary alcohols Chemical class 0.000 description 3
- 235000013599 spices Nutrition 0.000 description 3
- 238000005303 weighing Methods 0.000 description 3
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- GBFLZEXEOZUWRN-VKHMYHEASA-N S-carboxymethyl-L-cysteine Chemical compound OC(=O)[C@@H](N)CSCC(O)=O GBFLZEXEOZUWRN-VKHMYHEASA-N 0.000 description 2
- 230000009471 action Effects 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 239000007859 condensation product Substances 0.000 description 2
- 239000004205 dimethyl polysiloxane Substances 0.000 description 2
- 125000004185 ester group Chemical group 0.000 description 2
- 239000002979 fabric softener Substances 0.000 description 2
- 150000002194 fatty esters Chemical class 0.000 description 2
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 2
- 235000010979 hydroxypropyl methyl cellulose Nutrition 0.000 description 2
- 229920003088 hydroxypropyl methyl cellulose Polymers 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 2
- 239000000843 powder Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 125000002769 thiazolinyl group Chemical group 0.000 description 2
- PFFANLXVTHIIBE-UHFFFAOYSA-N 1-methyl-4-pyridin-4-ylpyridin-1-ium Chemical compound C1=C[N+](C)=CC=C1C1=CC=NC=C1 PFFANLXVTHIIBE-UHFFFAOYSA-N 0.000 description 1
- 125000002853 C1-C4 hydroxyalkyl group Chemical group 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 1
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical class CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 1
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 1
- 206010053615 Thermal burn Diseases 0.000 description 1
- 150000008431 aliphatic amides Chemical class 0.000 description 1
- 230000002882 anti-plaque Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 230000003078 antioxidant effect Effects 0.000 description 1
- 229940027983 antiseptic and disinfectant quaternary ammonium compound Drugs 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000001697 butter ester Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000001311 chemical methods and process Methods 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 238000005352 clarification Methods 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000007046 ethoxylation reaction Methods 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 235000019197 fats Nutrition 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 238000005187 foaming Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940075507 glyceryl monostearate Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- ACDUHTSVVVHMGU-UHFFFAOYSA-N hexadecan-3-ol Chemical compound CCCCCCCCCCCCCC(O)CC ACDUHTSVVVHMGU-UHFFFAOYSA-N 0.000 description 1
- 229920006158 high molecular weight polymer Polymers 0.000 description 1
- 230000002209 hydrophobic effect Effects 0.000 description 1
- 230000003165 hydrotropic effect Effects 0.000 description 1
- BTTMZEBIMDNSPK-UHFFFAOYSA-N icosan-4-ol Chemical compound CCCCCCCCCCCCCCCCC(O)CCC BTTMZEBIMDNSPK-UHFFFAOYSA-N 0.000 description 1
- WLIISNIPNDLIFS-UHFFFAOYSA-N icosan-5-ol Chemical compound CCCCCCCCCCCCCCCC(O)CCCC WLIISNIPNDLIFS-UHFFFAOYSA-N 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000016507 interphase Effects 0.000 description 1
- 238000012690 ionic polymerization Methods 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 239000002085 irritant Substances 0.000 description 1
- 231100000021 irritant Toxicity 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 125000005647 linker group Chemical group 0.000 description 1
- 239000002502 liposome Substances 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000001788 mono and diglycerides of fatty acids Substances 0.000 description 1
- 238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 239000006174 pH buffer Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 229920000867 polyelectrolyte Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 125000001453 quaternary ammonium group Chemical group 0.000 description 1
- 239000011347 resin Substances 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229960001866 silicon dioxide Drugs 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910021653 sulphate ion Inorganic materials 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- XREXPQGDOPQPAH-QKUPJAQQSA-K trisodium;[(z)-18-[1,3-bis[[(z)-12-sulfonatooxyoctadec-9-enoyl]oxy]propan-2-yloxy]-18-oxooctadec-9-en-7-yl] sulfate Chemical compound [Na+].[Na+].[Na+].CCCCCCC(OS([O-])(=O)=O)C\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O)COC(=O)CCCCCCC\C=C/CC(CCCCCC)OS([O-])(=O)=O XREXPQGDOPQPAH-QKUPJAQQSA-K 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2079—Monocarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/835—Mixtures of non-ionic with cationic compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/0005—Other compounding ingredients characterised by their effect
- C11D3/001—Softening compositions
- C11D3/0015—Softening compositions liquid
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/201—Monohydric alcohols linear
- C11D3/2013—Monohydric alcohols linear fatty or with at least 8 carbon atoms in the alkyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2027—Monohydric alcohols unsaturated
- C11D3/2031—Monohydric alcohols unsaturated fatty or with at least 8 carbon atoms in the alkenyl chain
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2003—Alcohols; Phenols
- C11D3/2006—Monohydric alcohols
- C11D3/2037—Terpenes
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2082—Polycarboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2075—Carboxylic acids-salts thereof
- C11D3/2086—Hydroxy carboxylic acids-salts thereof
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/37—Polymers
- C11D3/3703—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C11D3/373—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds containing silicones
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/38—Cationic compounds
- C11D1/62—Quaternary ammonium compounds
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Detergent Compositions (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The use of a non-ionic ethoxylated surfactant having an EO value of at least about 20, preferably at least 25, more preferably at least 30, in a fabric conditioning composition used in the rinse liquor in a domestic wash process comprising washing-by-hand or non-automatic washing machine, to improve the appearance of the rinse liquor at the end of the rinse.
Description
Technical field
The present invention relates to be used for the fabric-conditioning compositions that the rinsing of fabric is added, particularly during with the hand rinse fabric and in the non-automatic washing machine of maximum load with compositions for use during the rinsing after the detergent composition laundering of textile fabrics.
Background of invention
In developed country, the trend of washing is by using automatic washing machine, laundry detergent and softening compositio are by distributing from washing machine between two isolation thus, thereby guarantee to discharge washing composition automatically at the initial period of washing process, and softening compositio be released in rinse cycle, usually in last rinse cycle.
In less developed country, human consumer's washing habits for or with non-automatic maximum load washing machine (just comprise two separated spaces, is used for washing or rinsing, and an equipment that is used to rotate), perhaps with basin or bucket washing clothes.In basin or bucket washing comprise soak fabric, with detergent washing, wring out and the manipulation process of the heavy step of thorough rinsing.Similarly, in non-automatic maximum load washing machine, washing need place fabric and washing composition the compartment that contains water and stirring is provided.Fabric is moved out of the compartment that contains detergent liquid then, places the rotation compartment, and fabric is rotated to remove most washing composition and dirt therein.Detergent liquid shifts out from another compartment, replaces with clear water.Fabric is retracted rinsing.Rotation and the common repeated several times of rinse step are to obtain the fabric of acceptable rinsing.
Wash by hand and wash, and/or with the one side of non-automatic maximum load washing machine washing, be washing composition to water at high proportion and/or fabric to water at high proportion.Usually bring the washing composition of remnants into rinse step with the fabric that this detergent composition is handled.Modern (automatically) washing machine of contrast, wash by hand and wash and/or during with the washing of non-automatic maximum load washing machine, this carries the problem of (carry over) washing composition even more outstanding, and this is because the rotation between washing and rinse step and/or wring out inefficiency.
The traditional Betengent product that is used at present hand-wash and/or handle with non-automatic maximum load washing machine is so-called " high sudsing detergent ".A common known features of this type of Betengent product is a large amount of foams to occur by stirring at the top of washing soln.The problem that the human consumer runs into is that most this class A foam A is brought in the rinsing solution, need be by the continuous rinsing of water and rotation/wring out and remove troublesomely.
The use of the fabric-conditioning compositions of detergent composition coordination application can produce other problems therewith.The fabric softener actives can with appear in the rinsing solution, interact as the residual detergent surfactant of anion surfactant.Consequently produce the throw out of the indissoluble at the top that floats on rinsing solution.Can infer that the appearance of throw out arises from the interaction of the water-insoluble of tenderizer compound and/or tenderizer compound and anionic detergent liquid.Especially, when the high foamy detergent composition of formation was used for the situation of laundering of textile fabrics, the formation of this throw out bothered especially in washing link process.
In addition, the tenderizer compound trends towards forming slight muddiness and muddy rinsing body lotion.Signal when the clarification of rinsing liquid is felt as fabric by complete rinsing by the human consumer usually.Therefore, rinsing liquid is muddy more, and the human consumer can carry out more rinsings more.So pay close attention to the application of the fabric-conditioning compositions that provides muddy rinsing body lotion its fabric of excessive rinsing that can misguide the consumer.
The darker problem of washing composition coordination use fabric-conditioning compositions is that the interaction between tenderizer actives and residual detergent surfactant can cause reducing significantly end effect therewith.In the presence of residual detergent surfactant, the preferred soft feel that the fabric of handling with traditional care composition may be not typically be given by fabric-conditioning compositions during use when not having the tensio-active agent situation under.Can believe that the interaction between tenderizer actives and detergent surfactant reduces the effect of said tenderizer actives.
Therefore, when composition is used to carry rinsing solution under the washing composition condition, need to reduce that foam forms, transparent rinsing solution is provided and gives the fabric-conditioning compositions of using in the detergent-free tensio-active agent is the fabric-conditioning compositions of typical soft feel.And then needs can alleviate or weaken the method or the composition of the burden of hand and non-automatic washing, form the benefit that detergent composition combines the application fabric-conditioning compositions so that the human consumer can enjoy with high foam.So the hand that needs a kind of effective rinse composition to be used for fabric is handled, and provides submissive for the fabric of handling simultaneously.
WO 02/072745 discloses a kind of fabric treatment composition, comprise the fabric softener actives, foam inhibition system and tensio-active agent absorption agent, wherein the foam minimizing value of composition is at least about 90%, do not form throw out and when making an addition to the rinsing solution that contains residual detergent surfactant, give to the fabric softening feel.Composition preferably contains the fabric softening actives, froth suppressor, tensio-active agent absorption agent and optional ancillary component.
Composition can comprise dispersion agent, and nonionic ethoxylated surfactant for example is used at the rinsing suspension material and stops it to be deposited on the laundering of textile fabrics.
WO99/09122, WO99/42547, WO95/29980, US0523922, US5670476 and US6502325 disclose and have contained the fabric-conditioning compositions that a kind of EO value is at least 20 nonionic ethoxylated surfactant.Yet these reference disclose in rinsing without any one and have finished the outward appearance of rinsing liquid constantly.
Have been found that now specific tensio-active agent improves the outward appearance of rinsing liquid, when rinsing finishes, therefore can stop the excessive rinsing of human consumer especially.
Summary of the invention
According to an aspect of of the present present invention, provide a kind of EO value to be at least about 20, preferably at least 25, more preferably at least 30 the purposes of nonionic ethoxylated surfactant, it is used in the fabric-conditioning compositions in the rinsing liquid in the family expenses washing process that comprises hand washing or non-automatic washing machine the outward appearance of the rinsing liquid when improving rinsing and finish.
According to another aspect of the present invention, a kind of fabric-conditioning compositions is provided, comprise:
(i) quaternary ammonium soften compound,
(ii) water-soluble mono alkyl quaternary ammonium compound, its general formula is:
R
3-N
+-(CH
2)-Y-R′
X
-
Wherein:
Each R substituting group is represented hydrogen, short chain C independently
1-C
6, preferred C
1-C
3Alkyl or hydroxyalkyl, for example methyl, ethyl, propyl group, hydroxyethyl etc., poly-(C
2-3Alkoxyl group), preferred polyethoxye, phenmethyl or its mixing;
N is 1-about 4, preferred 2;
Y is a key;-O-(O) C-,-C (O)-O-,-NR-C (O)-or-C (O)-NR-;
R ' contains at least 8 carbon atoms, preferred 8-25, and be alkyl or substituted hydrocarbon radical, preferred 8-25 alkyl or alkenyl, preferred 8-20 carbon atom; With
X
-Can be the negatively charged ion of tenderizer compatibility arbitrarily, preferred chlorion, bromide anion, methylsulfate, ethyl sulphate, sulfate radical and nitrate radical, more preferably chlorion or methylsulfate;
(iii) nonionic ethoxylated surfactant, its EO value is at least 20, and preferably at least 25, more preferably at least 30,
(iv) pH regulator agent, it is lower than 8 poly carboxylic acid for consumption can make the pH of rinsing liquid
(v) organosilicon defoaming compounds
(vi) be selected from C
8-C
22Fatty Alcohol(C12-C14 and C12-C18) and C
8-C
22The fatty complexing agent of lipid acid.
Found to utilize the EO value to be at least 20, preferably at least 25, the outward appearance of the rinsing liquid when more preferably at least 30 nonionic ethoxylated surfactant significantly improves rinsing and finishes.In many cases, last rinsing liquid will be translucent (translucent) dispersion liquid, not flocculate or scum, thereby will provide the indication directly perceived of suitable rinsing to the human consumer, and avoid excessive rinsing.When fabric-conditioning compositions contains poly carboxylic acid, make rinsing liquid be lower than at 8 o'clock as the amount of citric acid, effect significantly strengthens.No matter still be during the rinsing when clothing is worn, the benefit that this pH reduces is to reduce skin irritant chance.
The positively charged ion soften compound
The positively charged ion soften compound can form lamellar phase dispersion, particularly liposome dispersion usually in water.
Cationic softening agent generally is quaternary ammonium compound (" QAC "), particularly has two C that link to each other with the nitrogen end group
12-28Group, it can be an alkyl or alkenyl independently, preferably connects by at least one ester to link to each other with the nitrogen end group, more preferably by two esters connections.
Alkyl and/the preferred C at least of the mean chain length of thiazolinyl
14, more preferably C at least
16The preferred especially chain length of the group of half at least is C
18Usually, alkyl and/or thiazolinyl mainly are straight chains.
Being suitable for use in first group of QAC of the present invention is represented by general formula (I):
[(CH
2)
n(TR)]
m
|
R
1-N
+-[(CH
2)
n(OH)]
3-m?X
- (I)
Wherein each R independently is selected from C
5-35Alkyl or alkenyl; R
1Represent C
1-4Alkyl, C
2-4Thiazolinyl or C
1-4Hydroxyalkyl; T is generally O-CO (promptly passing through the ester group of its carbon atom and R bonding), but can replace with CO.O (promptly passing through the ester group of its Sauerstoffatom and R bonding); N is the numeral that is selected from 1-4; M is selected from 1,2 or 3 numeral; X
-Be the negatively charged ion gegenion, as halogenide or alkyl-sulphate, for example muriate or Methylsulfate.The diester variations of general formula I (being m=2) is preferred, typically contains the list or three ester analogs that are associated with it.This type of material is particularly suitable for being applied to the present invention.
Special preferred reagent is the diester of methylsulfuric acid triethanol ammonium, perhaps is expressed as " TEA ester quaternary ammonium compound (quats) ".Commercial embodiment comprise Tetranyl AHT-1 available from Kao (a kind of two [hardened tallow esters] of methylsulfuric acid triethanol ammonium, available from the AT-1 (two [butter esters] of methylsulfuric acid triethanol ammonium) of Kao and L5/90 (two [palm esters] of methylsulfuric acid triethanol ammonium) with available from the RewoquatWE18 (a kind of two butter of methylsulfuric acid triethanol ammonium) of Degussa.
Being suitable for use in second group of QAC of the present invention is represented by general formula (II):
(R
1)
3N
+-(CH
2)
n-CH-TR
2?X
- (II)
|
CH
2TR
2
Each R wherein
1Be independently to be selected from C
1-4Alkyl, hydroxyalkyl or C
2-4Thiazolinyl; And R wherein
2Be independently to be selected from C
8-28Alkyl or alkenyl; N wherein, T and X
-Definition as above.
Preferred this second group of material comprises 1,2-two [butter acyloxy]-3-trimethyl propane ammonium chloride, 1,2-two [hardened tallow acyloxy]-3-trimethyl propane ammonium chloride, 1,2-two [oily acyloxy]-3-trimethyl propane ammonium chloride and 1,2-two [stearoyl-oxy]-3-trimethyl propane ammonium chloride.This type of material is disclosed in US 4,137, among 180 (the Lever Brothers).Preferably, this type of material also comprises a certain amount of corresponding monoesters.
Being suitable for use in the 3rd group of QAC of the present invention is represented by general formula (III):
(R
1)
2-N
+-[(CH
2)
n-T-R
2]
2X
-(III)
Each R wherein
1Be independently to be selected from C
1-4Alkyl or C
2-4Thiazolinyl; Each R wherein
2Be independently to be selected from C
8-28Alkyl or alkenyl; And n, T and X
-Definition as above.Preferred this 3rd group of material comprises two (2-butter acyloxy ethyl) alkyl dimethyl ammonium chloride and its hardened form.
Being suitable for use in the 4th group of QAC of the present invention is represented by general formula (IV):
(R
1)
2-N
+-(R
2)
2X
- (IV)
Each R wherein
1Be independently to be selected from C
1-4Alkyl or C
2-4Thiazolinyl; Each R wherein
2Be independently to be selected from C
8-28Alkyl or alkenyl; And X
-Definition as above.Preferred this 4th group of material comprises two (hardened tallow base) alkyl dimethyl ammonium chloride, and be commercially available with trade mark Arquad 2HT.
The preferred 0-120 of the iodine number of tenderizer, more preferably 0-100, most preferably 0-90.Basic saturated material, i.e. iodine number 0-1 is used for the composition of high especially operation.In low iodine number, submissive performance is remarkable, and composition has the oxidation-resistance of improvement and the smell problem of following when storing.
Iodine number is the gram number definition that absorbs iodine with every 100g test material.NMR spectrum is the suitable technology of determining the iodine number of tenderizer of the present invention, according to Johnson and Shoolery at Anal.Chem., 34,1136 (1962) and the method that illustrates at EP 593,542 (Unilever, 1993).
The reference of the level of cationic softening agent is the aggregate level of cationic softening agent in this specification sheets, comprises whole cation constituents of the compound material that can enter moisture lamellar phase jointly.Use the diester tenderizer, it comprises any monoesters that is associated that can exist or three ester compositions.
Preparation for convenience, the amount of tenderizer is generally 50% or lower in the weight of total composition, and particularly 40% or lower, especially 30% or lower.Preferred compositions contains the tenderizer of 0.5-8 weight %.
The water-soluble mono alkyl quaternary ammonium compound
Fabric-conditioning compositions contains one or more water-soluble mono alkyl quaternary ammonium compounds (monoquat).This type of material has little molecular dimension and the diffusion potential higher than the positively charged ion soften compound.The function of monoalkyl quaternary ammonium compound be in and detergent active, the effect of lauryl sodium alkyl sulfate normally, it brings rinse stage into by clothing, thereby stays the compliance function of expectation.The residue that is formed by washing composition and the interphase interaction of monoalkyl quaternary ammonium compound is dispersed well by the existence of nonionic ethoxylated surfactant and pH additive.
The general formula of water-soluble mono alkyl quaternary ammonium compound compound:
R
3-N
+-(CH
2)
n-T-R′
X
-
Wherein each R substituting group is hydrogen, short chain C independently
1-C
6, preferred C
1-C
3Alkyl or hydroxyalkyl, for example methyl, ethyl, propyl group, hydroxyethyl etc., poly-(C
2-3Alkoxyl group), preferred polyethoxye, phenmethyl or its mixture;
N is 1-4, preferred 2;
Y be a key ,-O-(O) C-,-C (O)-O-or-C (O)-NR-;
R ' is for containing at least 8 carbon atoms, preferred 8-25, alkyl or substituted hydrocarbon radical, preferred 8-25 alkyl or alkenyl, preferred 8-20 carbon atom; And X-can be the compatible negatively charged ion of tenderizer arbitrarily, preferred chlorion, bromide anion, methylsulfate, ethyl sulphate and nitrate radical, more preferably chlorion or methylsulfate;
Preferred monoalkyl quaternary ammonium compound is a benzalkonium chloride.
The content of monoalkyl quaternary ammonium compound is generally the 0.25-2 weight % of fabric-conditioning compositions, preferred 0.3-1.0 weight %.
The nonionic ethoxylated surfactant
The existence of nonionic ethoxylated surfactant is in order to improve the outward appearance of rinsing liquid.It prevents the formation of scum, and scum can potentially cause the scum precipitate on the fabric after the washing.Particularly it makes from the anion surfactant of washings and the reaction product of monoalkyl quaternary ammonium compound and disperses, thereby stops flocculation and form scum, thereby obtains translucent dispersion liquid.
The nonionogenic tenside that is fit to is the adduct of alkoxylate material, particularly oxyethane and/or propylene oxide and Fatty Alcohol(C12-C14 and C12-C18), lipid acid and aliphatic amide.
Preferred material has general formula:
R-Y-(CH
2CH
2O)
ZH
Wherein R is a hydrophobic part, is typically alkyl or alkenyl, and said group is the straight or branched type, the uncle or the second month in a season, preferably have 8-25, more preferably 10-20, most preferably 10-18 carbon atom; R can be an aromatic base also, as phenolic group, is replaced by aforesaid alkyl or alkenyl; Y is a linking group, is typically O, CO.O or CO.N (R
1), R wherein
1Be H or C
1-4Alkyl; With the unitary mean number of ethoxylate (EO) that z representative exists, said numeral is 20 or bigger, preferably at least 25, more preferably at least 30.
The embodiment of the nonionogenic tenside that is fit to comprises and mixes the natural or synthetic ethoxylate with the alcohol of " cocounut oil " or " butter " chain length.Preferred material is coconut oil fat alcohol and the condensation product of 20-50 moles of ethylene oxide and the condensation product of tallow fatty alcohol and 20-50 moles of ethylene oxide.
The ethoxylate of secondary alcohol can be used as 3-hexadecanol, 2-stearyl alcohol, 4-eicosanol and 5-eicosanol.The ethoxylation secondary alcohol that can be embodiment has general formula C
12-EO (20), C
14-EO (20), C
14-EO (25) and C
16-EO (30).The commercially available ionic surfactant pack that is fit to is drawn together Lutensol AT25, LutensolAT50 and Unitol CE 200F.
Choose wantonly, composition comprises emulsifying agent, and its HBL is 7-20, more preferably 10-20, most preferably 15-20.
Special tensio-active agent can be united use in the independent use of the present composition or with other tensio-active agents.The preferred amounts of following nonionogenic tenside refers to the total amount of this material of occurring in composition.
In the gross weight of composition, nonionogenic tenside is generally 0.05-10 weight %, often is 0.1-5 weight %, often is 3-4 weight %.
PH controls additive
Found when with contact with clothing from washing section after, the pH of rinsing liquid should keep below pH=8 to stop flocculation and to form scum.
The pH control additive that is fit to is organic acid, particularly poly carboxylic acid, optimization citric acid or succsinic acid, and it is usually with composition weight meter 0.25-1%, and preferred 0.3-0.8% measures in the present fabric-conditioning compositions.
Defoamer compound
Said composition comprises one or more defoamer compound, to suppress foam or the foaming by the washing composition generation of washings, particularly during stirring.
Particularly preferred defoamer compound is the silicone antifoam agent compound, is defined herein as any defoamer compound that comprises silicone ingredients.This type of silicone antifoam agent compound also typically contains silica composition.Herein, and usually at whole industrial used term " organosilicon ", comprise multiple relative high molecular weight polymers, it contains siloxane unit and polytype alkyl such as organopolysiloxane oil, the for example combination of the dispersion of polydimethylsiloxane, organopolysiloxane oil or resin or emulsion and organopolysiloxane and silica dioxide granule, wherein organopolysiloxane is with chemical process absorption or fuses on silicon-dioxide.The silicon foams inhibitor is well-known in this area, and is disclosed in US 4265779,3455839,3933672 and 4652392.Preferred defoamer compound is a polydimethylsiloxane.Usually in the weight 0.1-1% of fabric-conditioning compositions, the amount of preferred 0.3-0.7% exists defoamer compound.
Aqueous base
Composition of the present invention is that the typical case is aqueous.
Aqueous base generally comprises 80% or more by weight water; Sometimes this numeral can rise to 90% or higher, and perhaps 95% or higher.In the weight of total prescription, the water in aqueous base typically comprises 40% or more; Preferred this numeral is 60% or more, and more preferably it is 70% or more.
Aqueous base can also comprise water-soluble kind, as mineral salt or short chain (C
1-4) alcohol.Mineral salt can help composition to reach the viscosity of expectation, and as water-soluble organic salt and positively charged ion deflocculate polymkeric substance, this illustrates in EP 41,698 A2 (Unilever).This type of salt can exist with the 0.001-1% of the weight of total composition, preferred 0.005-0.1 weight %.The embodiment that is fit to the mineral salt of this purpose comprises calcium chloride, magnesium chloride and Repone K.The short chain alcohol that can exist comprises primary alconol, as ethanol, propyl alcohol and butanols, and secondary alcohol such as Virahol and polyvalent alcohol such as propylene glycol and glycerine.Short chain alcohol can be added with cationic softening agent in the preparation of compositions process.
Fatty complexing agent
Preferred supplementary component is a fatty complexing agent in composition of the present invention.This type of reagent typically has C
8-C
22Hydrocarbyl chain as the part of its molecular structure.The fatty complexing agent that is fit to comprises C
8-C
22Fatty Alcohol(C12-C14 and C12-C18) and C
8-C
22Lipid acid; Wherein, C most preferably
8-C
22Fatty Alcohol(C12-C14 and C12-C18).Fatty complexing agent is valuable especially in comprising the composition of QAC, and this QAC contains the single C that is connected with the nitrogen end group
12-C
28Group, as be connected in the monoesters of TEA ester quaternary ammonium compound, or the tenderizer of general formula I I, because product stability and validity.
Preferred lipid acid complexing agent comprises hardened tallow lipid acid (can be available from Uniqema, trade(brand)name Pristerene).
Preferred Fatty Alcohol(C12-C14 and C12-C18) complexing agent comprises C
16/ C
18Fatty Alcohol(C12-C14 and C12-C18) (can be available from Cognis, trade(brand)name Stenol and Hydrenol and available from Albright and Wilson, trade(brand)name Laurex CS) be with behenyl alcohol, a kind of C
22Fatty Alcohol(C12-C14 and C12-C18), available from Henkel, trade(brand)name Lanette 22.
Based on the gross weight meter of composition, the consumption of fatty complexing agent can be 0.1-10 weight %, particularly 0.2-5 weight %, especially 0.3-0.4 weight %.
Spices
Composition of the present invention typically comprises-kind or multiple spices.Based on the gross weight meter of composition, flavour content is preferably 0.01-10 weight %, more preferably 0.05-5 weight %, most preferably 0.5-4.0 weight %.
Auxiliary tenderizer
Auxiliary tenderizer can use jointly with cationic softening agent.When using, based on the gross weight of composition, it typically is 0.1-20%, special 0.5-10%.Preferred auxiliary tenderizer comprises fatty ester and fatty N-oxide compound.
The available fatty ester comprises fatty monoesters, as glyceryl monostearate, and fatty sugar esters, as be disclosed among the WO01/46361 (Unilever) those.
Other optional members
Composition of the present invention can contain one or more other compositions.This composition comprises sanitas (as sterilant), pH buffer reagent, fragrance carrier, fluorescent agent, tinting material, hydrotropic agent, defoamer, anti redeposition agent, stain remover, polyelectrolyte, enzyme, white dyes, antishrinking agent, anti wrinkling agent, antiplaque agent, antioxidant, opalizer, corrosion inhibitor, drape imparting agent, static inhibitor, helps and scald agent and dyestuff.
Particularly preferred optional member is opalizer or pearling agent.Specific examples of such components can further strengthen the emulsus outward appearance of composition of the present invention.The material that is fit to can be selected from Aquasol 0P30X series (available from Rohm andHaas), PuriColour White series (available from Ciba) and LameSoft TM series (available from Cognis).The typical amounts of this type of material is the weight 0.01-1 weight % in total composition.
Product application
Composition of the present invention is the rinse conditioner composition, can be used for the rinse cycle of home washings process.
Composition is used for the rinse cycle of family's textile washing operation, and at this, it can directly directly make an addition in the tube of maximum load washing machine with undiluted state.Composition also can be used for family's hand washing washing operation.
The present invention will do explanation by following examples:
Embodiment
The prescription that preparation is reported in following table:
| Embodiment | 1 | 2 | 3 | 4 | 5 | 6 | 7 | 8 | 9 | A | B | C | D | 10 | 11 |
| Arquad?2HT | 2 | 2 | 2 | 2 | 2 | 3.6 | 2 | 3.6 | 3.8 | 4 | 4 | 2 | 2 | 2 | 3.35 |
| Tallow alcohol | 0.45 | 0.45 | 0.45 | 0.45 | 0.45 | 0.36 | 0.45 | 0.36 | 0.38 | 0.4 | 0.4 | 0.45 | 0.45 | 0.45 | 0.34 |
| Lutensol?AT5o | 0.3 | 0.5 | |||||||||||||
| Lutensol?AT25 | 0.5 | 0.3 | 0.5 | 0.3 | 0.5 | 0.3 | 0.3 | 0.5 | 0.3 | ||||||
| Unitol?CE200F | |||||||||||||||
| BKC | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 | 0.9 | 0.7 | 0.38 | 1.35 | 1.35 | 0.9 | 0.9 | 0.9 | 0.34 |
| Citric acid | 0.8 | 0.8 | 0.7 | 0.7 | 0.8 | 0.8 | 0.8 | 0.5 | 0.825 | 0.9 | 0.75 | 0.9 | 0.8 | 0.025 | 0.7 |
| SAG?470 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | |||||
| DSP | 0.5 | 0.5 | 0.5 | 0.5 | 0.5 | ||||||||||
| SCMC | 0.35 | 0.35 | 0.3 | ||||||||||||
| HPMC | 0.3 |
BKC is a benzalkonium chloride.
SAG470 and DSP are the organosilicon antigassing additives.
SCMC is the anionoid polymerization dispersion agent.
HPMC is non-ionic polymerization dispersion agent.
Composition also comprises spices (0.4-0.8%), dyestuff (0.001-0.0025%), formaldehyde (0.05-0.1%), and all the other are water.
Prescription is through the test of hand washing scheme.
Test condition
Load
Washing: 1kg 100% knitted cotton T-shirt adds destarch HEAVY FLANNELETTE monitor.
Rinsing: 100g 100% knitted cotton T-shirt adds destarch HEAVY FLANNELETTE monitor.
Monitor
6 destarch heavy fleece towelling monitors (20cm * 20cm)
Wash conditions
Washing container: basin
The water hardness: Demin/US@6
H
Ca in the water: Mg ratio: 2: 1
Water temperature: 22+/-1 ℃
Water consumption: 10 liters
Liquid: clothing ratio: 10: 1
Product: OMO Multi Acao powder
Product dosage: 3.6g/l
Product is used: add the powder of weighing and also stir up to dissolving
Product soak time: 30 minutes
Stir: in basin, stirred 10 minutes
The extruding action: the excessive water of back-outing is extremely between (between) 150% amount of obtaining (pick-up)
Rinsing condition
The water hardness: Demin/US@6
H
Ca/Mg ratio in the water: 2: 1
Water temperature: 22+/-1 ℃
Rinsing number of times: 1
Water consumption: 1 liter
Liquid: clothing ratio rinsing: 10: 1
Product dosage 9.0g/l (unless otherwise indicated)
Product is used: add the fabric (fab con) (rinsing the resistates in the container of weighing) through weighing during basin is full of, and stirs up to dispersion with hand.Add load and immersion.
Product soak time: 7 minutes
Extruding action: back-out excessive water to about 150% amount of obtaining with hand
The remaining rinsing liquid in test back is done visual evaluation by Review Team with the resistates result standard of 0-3, and wherein 0 representative has the liquid of remarkable precipitation, flocculation and/or scum, the good translucent dispersion liquid of 3 representatives.The results are shown in following table:
| Embodiment | The resistates result |
| ?1 | ?3 |
| ?2 | ?2.5 |
| ?3 | ?3 |
| ?4 | ?3 |
| ?5 | ?3 |
| ?6 | ?3 |
| ?7 | ?3 |
| ?8 | ?3 |
| ?10 | ?2.5 |
| ?11 | ?3 |
| ?12 | ?3 |
| ?A | ?3 (1) |
| ?B | ?1.5 (1) |
| ?C | ?1.5 |
| ?D | ?0 |
| ?Downy?RF | ?1 |
| ?Suavitel?RF | ?1 |
| ?Vivere | ?0-0.5 |
(1) tests at 4.8g/l
Downy RF, Suavitel RF and Vivere are at the commercially available fabric-conditioning product of Mexico.
The result shows, compares with using negatively charged ion or nonionic polymeric dispersant, and what comprise the nonionic ethoxylated surfactant provides improved result according to prescription of the present invention.With current commercially available rinsing care composition: all produce the Downy RF (product innovation) of scum and/or obvious sediment, Suavitel RF compares with Vivere, and prescription of the present invention provides improved result.
Claims (15)
1. an EO value is at least the purposes of 30 nonionic ethoxylated surfactant, and it is used in the fabric-conditioning compositions used in the rinsing liquid in the family expenses washing process that comprises hand washing or non-automatic washing machine with by stoping the outward appearance of the rinsing liquid when forming scum and improving rinsing and finish.
2. purposes as claimed in claim 1, wherein fabric-conditioning compositions comprises poly carboxylic acid, and its consumption makes the pH of rinsing liquid be lower than 8.
3. purposes as claimed in claim 2, wherein said poly carboxylic acid is a citric acid.
4. purposes as claimed in claim 1 or 2, wherein fabric-conditioning compositions comprises the water-soluble mono alkyl quaternary ammonium compound, and its general formula is:
R
3-N
+-(CH
2)
n-Y-R’
X-
Wherein:
Each R substituting group is hydrogen independently, short chain C
1-C
6Alkyl or hydroxyalkyl, poly-C
2-3Alkoxyl group, phenmethyl or its mixing;
N is 1-4;
Y be a key ,-O-(O) C-,-C (O)-O-,-NR-C (O)-or-C (O)-NR-;
R ' contains at least 8 carbon atoms and is alkyl or substituted hydrocarbon radical; And
X-is the negatively charged ion of any tenderizer compatibility.
5. purposes as claimed in claim 4, wherein said short chain C
1-C
6Alkyl or hydroxyalkyl be short chain C
1-C
3Alkyl or hydroxyalkyl.
6. purposes as claimed in claim 4, wherein said short chain C
1-C
6Alkyl or hydroxyalkyl be methyl, ethyl, propyl group or hydroxyethyl.
7. purposes as claimed in claim 4, wherein said poly-C
2-3Alkoxyl group is a polyethoxye.
8. purposes as claimed in claim 4, wherein n is 2.
9. purposes as claimed in claim 4, wherein said R ' contains 8-25 carbon atom, and is alkyl or substituted hydrocarbon radical.
10. purposes as claimed in claim 4, wherein said R ' is the alkyl or alkenyl of 8-25 carbon atom.
11. purposes as claimed in claim 4, wherein said R ' is the alkyl or alkenyl of 8-20 carbon atom.
12. purposes as claimed in claim 4, wherein said X-is chlorion, bromide anion, methylsulfate, ethyl sulphate, sulfate radical and nitrate radical.
13. purposes as claimed in claim 4, wherein said X-is chlorion or methylsulfate.
14. purposes as claimed in claim 4, wherein the water-soluble mono alkyl quaternary ammonium compound is a benzalkonium chloride.
15. purposes as claimed in claim 1 or 2, it is by number of times water saving and minimizing work in family's washing process of restriction fabric rinsing.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB0512423A GB0512423D0 (en) | 2005-06-17 | 2005-06-17 | Fabric conditioning composition and use |
| GB0512423.5 | 2005-06-17 | ||
| PCT/EP2006/004891 WO2006133791A2 (en) | 2005-06-17 | 2006-05-23 | Fabric conditioning composition and use |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101198684A CN101198684A (en) | 2008-06-11 |
| CN101198684B true CN101198684B (en) | 2011-05-25 |
Family
ID=34855755
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN2006800212530A Expired - Fee Related CN101198684B (en) | 2005-06-17 | 2006-05-23 | Fabric conditioning composition and use |
Country Status (5)
| Country | Link |
|---|---|
| CN (1) | CN101198684B (en) |
| AR (1) | AR051015A1 (en) |
| BR (1) | BRPI0600039A (en) |
| GB (1) | GB0512423D0 (en) |
| WO (1) | WO2006133791A2 (en) |
Families Citing this family (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2007104387A1 (en) * | 2006-02-10 | 2007-09-20 | Unilever Plc | Fabric conditioner compositions |
| CN102057032A (en) * | 2008-06-06 | 2011-05-11 | 宝洁公司 | Hand fabric laundering system |
| WO2009148801A1 (en) * | 2008-06-06 | 2009-12-10 | The Procter & Gamble Company | Hand fabric laundering method |
| MX2013006250A (en) * | 2010-12-03 | 2013-10-01 | Unilever Nv | Fabric conditioners. |
| US10487292B2 (en) | 2016-08-31 | 2019-11-26 | The Procter & Gamble Company | Fabric enhancer composition |
| WO2018107410A1 (en) * | 2016-12-15 | 2018-06-21 | Rhodia Operations | Composition for fabric treatment |
| AU2017386271B2 (en) | 2016-12-29 | 2020-02-06 | Colgate-Palmolive Company | Home care compositions |
| US20190264136A1 (en) * | 2018-02-28 | 2019-08-29 | The Procter & Gamble Company | Fabric enhancer composition |
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|---|---|---|---|---|
| EP0334666A2 (en) * | 1988-03-23 | 1989-09-27 | Union Camp Corporation | Fragrance carriers for laundry compositions |
| US5505866A (en) * | 1994-10-07 | 1996-04-09 | The Procter & Gamble Company | Solid particulate fabric softener composition containing biodegradable cationic ester fabric softener active and acidic pH modifier |
| WO2002072745A1 (en) * | 2001-03-07 | 2002-09-19 | The Procter & Gamble Company | Rinse-added fabric conditioning composition for use where residual detergent is present |
| US20030114339A1 (en) * | 2001-09-10 | 2003-06-19 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric conditioning compositions |
| CN1531586A (en) * | 2001-04-09 | 2004-09-22 | ŵ�����˹ɷ�����˾ | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds |
| CN1582323A (en) * | 2001-09-10 | 2005-02-16 | 荷兰联合利华有限公司 | Fabric conditioning compositions |
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|---|---|---|---|---|
| PL336221A1 (en) * | 1998-02-19 | 2000-06-19 | Colgate Palmolive Co | Stable composition of a fabric softener for use in laundry rinsing cycles in combination with appropriate co-softener |
-
2005
- 2005-06-17 GB GB0512423A patent/GB0512423D0/en not_active Ceased
- 2005-08-25 AR ARP050103553 patent/AR051015A1/en not_active Application Discontinuation
-
2006
- 2006-01-11 BR BRPI0600039 patent/BRPI0600039A/en not_active Application Discontinuation
- 2006-05-23 WO PCT/EP2006/004891 patent/WO2006133791A2/en active Application Filing
- 2006-05-23 CN CN2006800212530A patent/CN101198684B/en not_active Expired - Fee Related
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| EP0334666A2 (en) * | 1988-03-23 | 1989-09-27 | Union Camp Corporation | Fragrance carriers for laundry compositions |
| US5505866A (en) * | 1994-10-07 | 1996-04-09 | The Procter & Gamble Company | Solid particulate fabric softener composition containing biodegradable cationic ester fabric softener active and acidic pH modifier |
| WO2002072745A1 (en) * | 2001-03-07 | 2002-09-19 | The Procter & Gamble Company | Rinse-added fabric conditioning composition for use where residual detergent is present |
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| CN1531586A (en) * | 2001-04-09 | 2004-09-22 | ŵ�����˹ɷ�����˾ | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds |
| US20030114339A1 (en) * | 2001-09-10 | 2003-06-19 | Unilever Home & Personal Care Usa, Division Of Conopco, Inc. | Fabric conditioning compositions |
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Also Published As
| Publication number | Publication date |
|---|---|
| WO2006133791A2 (en) | 2006-12-21 |
| WO2006133791A3 (en) | 2007-04-05 |
| GB0512423D0 (en) | 2005-07-27 |
| CN101198684A (en) | 2008-06-11 |
| BRPI0600039A (en) | 2007-02-13 |
| AR051015A1 (en) | 2006-12-13 |
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