CN1011945B - 采用新型捕收剂组合物的泡沫浮选法 - Google Patents
采用新型捕收剂组合物的泡沫浮选法Info
- Publication number
- CN1011945B CN1011945B CN86101646A CN86101646A CN1011945B CN 1011945 B CN1011945 B CN 1011945B CN 86101646 A CN86101646 A CN 86101646A CN 86101646 A CN86101646 A CN 86101646A CN 1011945 B CN1011945 B CN 1011945B
- Authority
- CN
- China
- Prior art keywords
- alkyl
- thioether
- mineral
- hydrocarbon
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 48
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000009291 froth flotation Methods 0.000 title claims abstract description 20
- 229910052569 sulfide mineral Inorganic materials 0.000 claims abstract description 39
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 30
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 30
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 25
- 229910052751 metal Inorganic materials 0.000 claims abstract description 21
- 239000002184 metal Substances 0.000 claims abstract description 21
- 229910052799 carbon Inorganic materials 0.000 claims abstract description 19
- 125000001931 aliphatic group Chemical group 0.000 claims abstract description 17
- RYYWUUFWQRZTIU-UHFFFAOYSA-K thiophosphate Chemical compound [O-]P([O-])([O-])=S RYYWUUFWQRZTIU-UHFFFAOYSA-K 0.000 claims abstract description 11
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract 3
- -1 hydrocarbon thioether Chemical class 0.000 claims description 88
- 229910052500 inorganic mineral Inorganic materials 0.000 claims description 65
- 239000011707 mineral Substances 0.000 claims description 65
- 239000003795 chemical substances by application Substances 0.000 claims description 40
- 238000005987 sulfurization reaction Methods 0.000 claims description 21
- 238000005188 flotation Methods 0.000 claims description 19
- 125000003118 aryl group Chemical group 0.000 claims description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 10
- 150000002148 esters Chemical class 0.000 claims description 10
- 239000011734 sodium Substances 0.000 claims description 10
- 229910052708 sodium Inorganic materials 0.000 claims description 10
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 claims description 9
- 239000002002 slurry Substances 0.000 claims description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 8
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 8
- 230000003647 oxidation Effects 0.000 claims description 5
- 238000007254 oxidation reaction Methods 0.000 claims description 5
- 239000011591 potassium Chemical group 0.000 claims description 5
- 229910052700 potassium Chemical group 0.000 claims description 5
- 125000000853 cresyl group Chemical group C1(=CC=C(C=C1)C)* 0.000 claims description 4
- 125000004435 hydrogen atom Chemical class [H]* 0.000 claims description 4
- 229910052783 alkali metal Inorganic materials 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 125000002723 alicyclic group Chemical group 0.000 claims description 2
- 229910052739 hydrogen Inorganic materials 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- GNVMUORYQLCPJZ-UHFFFAOYSA-M Thiocarbamate Chemical compound NC([S-])=O GNVMUORYQLCPJZ-UHFFFAOYSA-M 0.000 claims 2
- 125000000101 thioether group Chemical group 0.000 claims 1
- 238000011084 recovery Methods 0.000 abstract description 31
- 239000002245 particle Substances 0.000 abstract description 14
- 150000002430 hydrocarbons Chemical class 0.000 abstract description 13
- 229910052592 oxide mineral Inorganic materials 0.000 abstract description 7
- 230000002209 hydrophobic effect Effects 0.000 abstract description 6
- 125000004434 sulfur atom Chemical group 0.000 abstract 1
- 235000010755 mineral Nutrition 0.000 description 64
- 239000010949 copper Substances 0.000 description 34
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 29
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical compound S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 22
- 150000003568 thioethers Chemical group 0.000 description 20
- 229910044991 metal oxide Inorganic materials 0.000 description 17
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 15
- 229910052742 iron Inorganic materials 0.000 description 14
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 14
- 229910052802 copper Inorganic materials 0.000 description 13
- 239000004088 foaming agent Substances 0.000 description 13
- 239000011701 zinc Substances 0.000 description 13
- 239000012990 dithiocarbamate Substances 0.000 description 12
- 239000012141 concentrate Substances 0.000 description 11
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 11
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 10
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 10
- 239000011133 lead Substances 0.000 description 10
- 239000007787 solid Substances 0.000 description 10
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 9
- 239000006260 foam Substances 0.000 description 9
- 239000007788 liquid Substances 0.000 description 9
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 9
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 description 8
- 239000002253 acid Substances 0.000 description 8
- 125000005012 alkyl thioether group Chemical group 0.000 description 8
- 229910052736 halogen Inorganic materials 0.000 description 8
- 150000002367 halogens Chemical class 0.000 description 8
- 229910052725 zinc Inorganic materials 0.000 description 8
- 150000001721 carbon Chemical group 0.000 description 7
- 125000004093 cyano group Chemical group *C#N 0.000 description 7
- 239000007789 gas Substances 0.000 description 7
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 7
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 229910052750 molybdenum Inorganic materials 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 238000003756 stirring Methods 0.000 description 7
- HIXDQWDOVZUNNA-UHFFFAOYSA-N 2-(3,4-dimethoxyphenyl)-5-hydroxy-7-methoxychromen-4-one Chemical compound C=1C(OC)=CC(O)=C(C(C=2)=O)C=1OC=2C1=CC=C(OC)C(OC)=C1 HIXDQWDOVZUNNA-UHFFFAOYSA-N 0.000 description 6
- 235000008733 Citrus aurantifolia Nutrition 0.000 description 6
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 6
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 6
- 235000011941 Tilia x europaea Nutrition 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 6
- 125000000753 cycloalkyl group Chemical group 0.000 description 6
- 239000004571 lime Substances 0.000 description 6
- 239000011733 molybdenum Substances 0.000 description 6
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 5
- 229910052770 Uranium Inorganic materials 0.000 description 5
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 229910052804 chromium Inorganic materials 0.000 description 5
- 239000011651 chromium Substances 0.000 description 5
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 5
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- 125000000623 heterocyclic group Chemical group 0.000 description 5
- 125000001183 hydrocarbyl group Chemical group 0.000 description 5
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 5
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 5
- JFALSRSLKYAFGM-UHFFFAOYSA-N uranium(0) Chemical compound [U] JFALSRSLKYAFGM-UHFFFAOYSA-N 0.000 description 5
- 229910052984 zinc sulfide Inorganic materials 0.000 description 5
- RKYMVQJWYYOIJB-UHFFFAOYSA-N 1-decylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCCC RKYMVQJWYYOIJB-UHFFFAOYSA-N 0.000 description 4
- LHNRHYOMDUJLLM-UHFFFAOYSA-N 1-hexylsulfanylhexane Chemical compound CCCCCCSCCCCCC LHNRHYOMDUJLLM-UHFFFAOYSA-N 0.000 description 4
- KMKSVAGOBVUFRO-UHFFFAOYSA-N 1-nonylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCCCC KMKSVAGOBVUFRO-UHFFFAOYSA-N 0.000 description 4
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical group CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 description 4
- 239000005864 Sulphur Substances 0.000 description 4
- 125000003710 aryl alkyl group Chemical group 0.000 description 4
- DKVNPHBNOWQYFE-UHFFFAOYSA-N carbamodithioic acid Chemical compound NC(S)=S DKVNPHBNOWQYFE-UHFFFAOYSA-N 0.000 description 4
- 125000000392 cycloalkenyl group Chemical group 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000007667 floating Methods 0.000 description 4
- CWQXQMHSOZUFJS-UHFFFAOYSA-N molybdenum disulfide Chemical compound S=[Mo]=S CWQXQMHSOZUFJS-UHFFFAOYSA-N 0.000 description 4
- 229910052759 nickel Inorganic materials 0.000 description 4
- YCWSUKQGVSGXJO-NTUHNPAUSA-N nifuroxazide Chemical group C1=CC(O)=CC=C1C(=O)N\N=C\C1=CC=C([N+]([O-])=O)O1 YCWSUKQGVSGXJO-NTUHNPAUSA-N 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000012991 xanthate Substances 0.000 description 4
- LEMIDOZYVQXGLI-UHFFFAOYSA-N 1-heptylsulfanylheptane Chemical group CCCCCCCSCCCCCCC LEMIDOZYVQXGLI-UHFFFAOYSA-N 0.000 description 3
- BRUZQRBVNRKLJG-UHFFFAOYSA-N 2-methylpropyl carbamate Chemical compound CC(C)COC(N)=O BRUZQRBVNRKLJG-UHFFFAOYSA-N 0.000 description 3
- KBRSJPHSCOAFDR-UHFFFAOYSA-N 3-chloro-6-methyl-5,5-dioxo-11h-benzo[c][2,1]benzothiazepin-11-ol Chemical compound O=S1(=O)N(C)C2=CC=CC=C2C(O)C2=CC=C(Cl)C=C21 KBRSJPHSCOAFDR-UHFFFAOYSA-N 0.000 description 3
- HTIRHQRTDBPHNZ-UHFFFAOYSA-N Dibutyl sulfide Chemical compound CCCCSCCCC HTIRHQRTDBPHNZ-UHFFFAOYSA-N 0.000 description 3
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000002877 alkyl aryl group Chemical group 0.000 description 3
- 125000000304 alkynyl group Chemical group 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- 229910052951 chalcopyrite Inorganic materials 0.000 description 3
- DVRDHUBQLOKMHZ-UHFFFAOYSA-N chalcopyrite Chemical compound [S-2].[S-2].[Fe+2].[Cu+2] DVRDHUBQLOKMHZ-UHFFFAOYSA-N 0.000 description 3
- 150000001924 cycloalkanes Chemical class 0.000 description 3
- FTAORUVBXKFVDA-UHFFFAOYSA-N cyclohexylsulfanylcyclohexane Chemical compound C1CCCCC1SC1CCCCC1 FTAORUVBXKFVDA-UHFFFAOYSA-N 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 238000000227 grinding Methods 0.000 description 3
- 125000004051 hexyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- XCAUINMIESBTBL-UHFFFAOYSA-N lead(ii) sulfide Chemical compound [Pb]=S XCAUINMIESBTBL-UHFFFAOYSA-N 0.000 description 3
- 229910052954 pentlandite Inorganic materials 0.000 description 3
- 239000002994 raw material Substances 0.000 description 3
- 235000017550 sodium carbonate Nutrition 0.000 description 3
- 229910000029 sodium carbonate Inorganic materials 0.000 description 3
- WGPCGCOKHWGKJJ-UHFFFAOYSA-N sulfanylidenezinc Chemical compound [Zn]=S WGPCGCOKHWGKJJ-UHFFFAOYSA-N 0.000 description 3
- 230000002195 synergetic effect Effects 0.000 description 3
- 125000002769 thiazolinyl group Chemical group 0.000 description 3
- UDEGFCKHAFPFNS-UHFFFAOYSA-N thionane-2,9-dione Chemical compound C1(CCCCCCC(=O)S1)=O UDEGFCKHAFPFNS-UHFFFAOYSA-N 0.000 description 3
- YSQZSPCQDXHJDJ-UHFFFAOYSA-N 1-(pentyldisulfanyl)pentane Chemical compound CCCCCSSCCCCC YSQZSPCQDXHJDJ-UHFFFAOYSA-N 0.000 description 2
- VSSRSPLEFYQIEK-UHFFFAOYSA-N 1-ethylsulfanyldecane Chemical compound CCCCCCCCCCSCC VSSRSPLEFYQIEK-UHFFFAOYSA-N 0.000 description 2
- PYPULUCCVXMPFP-UHFFFAOYSA-N 1-ethylsulfanylheptane Chemical compound CCCCCCCSCC PYPULUCCVXMPFP-UHFFFAOYSA-N 0.000 description 2
- MGVUJBCOCITTRS-UHFFFAOYSA-N 1-ethylsulfanylhexane Chemical compound CCCCCCSCC MGVUJBCOCITTRS-UHFFFAOYSA-N 0.000 description 2
- LUAABLIRQSWMGZ-UHFFFAOYSA-N 1-ethylsulfanylnonane Chemical compound CCCCCCCCCSCC LUAABLIRQSWMGZ-UHFFFAOYSA-N 0.000 description 2
- HKGUUZAACYBIID-UHFFFAOYSA-N 1-methylsulfanyldecane Chemical compound CCCCCCCCCCSC HKGUUZAACYBIID-UHFFFAOYSA-N 0.000 description 2
- FJDWJOQOEZRIDJ-UHFFFAOYSA-N 1-methylsulfanylheptane Chemical compound CCCCCCCSC FJDWJOQOEZRIDJ-UHFFFAOYSA-N 0.000 description 2
- LZRXQHHKXDXOIC-UHFFFAOYSA-N 1-methylsulfanylhexane Chemical compound CCCCCCSC LZRXQHHKXDXOIC-UHFFFAOYSA-N 0.000 description 2
- FCRSULZJMFDBIK-UHFFFAOYSA-N 1-methylsulfanylnonane Chemical compound CCCCCCCCCSC FCRSULZJMFDBIK-UHFFFAOYSA-N 0.000 description 2
- AHCJTMBRROLNHV-UHFFFAOYSA-N 1-methylsulfanyloctane Chemical compound CCCCCCCCSC AHCJTMBRROLNHV-UHFFFAOYSA-N 0.000 description 2
- LOXRGHGHQYWXJK-UHFFFAOYSA-N 1-octylsulfanyloctane Chemical compound CCCCCCCCSCCCCCCCC LOXRGHGHQYWXJK-UHFFFAOYSA-N 0.000 description 2
- JOZDADPMWLVEJK-UHFFFAOYSA-N 1-pentylsulfanylpentane Chemical group CCCCCSCCCCC JOZDADPMWLVEJK-UHFFFAOYSA-N 0.000 description 2
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 description 2
- ULUAUXLGCMPNKK-UHFFFAOYSA-N Sulfobutanedioic acid Chemical compound OC(=O)CC(C(O)=O)S(O)(=O)=O ULUAUXLGCMPNKK-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- RYYWUUFWQRZTIU-UHFFFAOYSA-N Thiophosphoric acid Chemical compound OP(O)(S)=O RYYWUUFWQRZTIU-UHFFFAOYSA-N 0.000 description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 150000001336 alkenes Chemical class 0.000 description 2
- 150000001345 alkine derivatives Chemical class 0.000 description 2
- 125000005466 alkylenyl group Chemical group 0.000 description 2
- 150000001491 aromatic compounds Chemical class 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- IOJUPLGTWVMSFF-UHFFFAOYSA-N benzothiazole Chemical compound C1=CC=C2SC=NC2=C1 IOJUPLGTWVMSFF-UHFFFAOYSA-N 0.000 description 2
- 229910052948 bornite Inorganic materials 0.000 description 2
- 230000005587 bubbling Effects 0.000 description 2
- SKKTUOZKZKCGTB-UHFFFAOYSA-N butyl carbamate Chemical compound CCCCOC(N)=O SKKTUOZKZKCGTB-UHFFFAOYSA-N 0.000 description 2
- HIZCIEIDIFGZSS-UHFFFAOYSA-N carbonotrithioic acid Chemical compound SC(S)=S HIZCIEIDIFGZSS-UHFFFAOYSA-N 0.000 description 2
- 239000003153 chemical reaction reagent Substances 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 239000003245 coal Substances 0.000 description 2
- BUGICWZUDIWQRQ-UHFFFAOYSA-N copper iron sulfane Chemical compound S.[Fe].[Cu] BUGICWZUDIWQRQ-UHFFFAOYSA-N 0.000 description 2
- ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- 238000009826 distribution Methods 0.000 description 2
- 229910052949 galena Inorganic materials 0.000 description 2
- 229910052749 magnesium Inorganic materials 0.000 description 2
- 239000011777 magnesium Substances 0.000 description 2
- 229910052748 manganese Inorganic materials 0.000 description 2
- 239000011572 manganese Substances 0.000 description 2
- 229910052961 molybdenite Inorganic materials 0.000 description 2
- YNTOKMNHRPSGFU-UHFFFAOYSA-N n-Propyl carbamate Chemical compound CCCOC(N)=O YNTOKMNHRPSGFU-UHFFFAOYSA-N 0.000 description 2
- 150000002894 organic compounds Chemical class 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 235000011007 phosphoric acid Nutrition 0.000 description 2
- 229940068124 pine tar Drugs 0.000 description 2
- 229910052697 platinum Inorganic materials 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 239000000725 suspension Substances 0.000 description 2
- 235000020679 tap water Nutrition 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 2
- 239000010936 titanium Substances 0.000 description 2
- 229910052719 titanium Inorganic materials 0.000 description 2
- 239000012989 trithiocarbonate Substances 0.000 description 2
- FOJGPFUFFHWGFQ-UHFFFAOYSA-N 1-(Methylthio)pentane Chemical compound CCCCCSC FOJGPFUFFHWGFQ-UHFFFAOYSA-N 0.000 description 1
- CLBLVLKZMJDLOT-UHFFFAOYSA-N 1-butylsulfanyldecane Chemical compound CCCCCCCCCCSCCCC CLBLVLKZMJDLOT-UHFFFAOYSA-N 0.000 description 1
- HYUPOCGXBZUYFY-UHFFFAOYSA-N 1-butylsulfanylheptane Chemical compound CCCCCCCSCCCC HYUPOCGXBZUYFY-UHFFFAOYSA-N 0.000 description 1
- YZUHMAFUXBPUKH-UHFFFAOYSA-N 1-butylsulfanylhexane Chemical compound CCCCCCSCCCC YZUHMAFUXBPUKH-UHFFFAOYSA-N 0.000 description 1
- FWRIVMHSSSZAFD-UHFFFAOYSA-N 1-butylsulfanylnonane Chemical compound CCCCCCCCCSCCCC FWRIVMHSSSZAFD-UHFFFAOYSA-N 0.000 description 1
- UNIAPWPIAGJFDG-UHFFFAOYSA-N 1-butylsulfanyloctane Chemical compound CCCCCCCCSCCCC UNIAPWPIAGJFDG-UHFFFAOYSA-N 0.000 description 1
- XJIRSLHMKBUGMR-UHFFFAOYSA-N 1-ethylsulfanylbutane Chemical compound CCCCSCC XJIRSLHMKBUGMR-UHFFFAOYSA-N 0.000 description 1
- HYNUNWWVWIDFNI-UHFFFAOYSA-N 1-heptylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCC HYNUNWWVWIDFNI-UHFFFAOYSA-N 0.000 description 1
- RGMJJEGCPWGPIO-UHFFFAOYSA-N 1-heptylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCCC RGMJJEGCPWGPIO-UHFFFAOYSA-N 0.000 description 1
- AHFXEIBVMODMFA-UHFFFAOYSA-N 1-hexylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCC AHFXEIBVMODMFA-UHFFFAOYSA-N 0.000 description 1
- MPSAONKRRWETTC-UHFFFAOYSA-N 1-hexylsulfanylheptane Chemical compound CCCCCCCSCCCCCC MPSAONKRRWETTC-UHFFFAOYSA-N 0.000 description 1
- OSCWDJOYYNCZON-UHFFFAOYSA-N 1-hexylsulfanylnonane Chemical compound CCCCCCCCCSCCCCCC OSCWDJOYYNCZON-UHFFFAOYSA-N 0.000 description 1
- WCXXISMIJBRDQK-UHFFFAOYSA-N 1-methylsulfanylbutane Chemical compound CCCCSC WCXXISMIJBRDQK-UHFFFAOYSA-N 0.000 description 1
- UWHYFRCJGNMMSJ-UHFFFAOYSA-N 1-nonylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCCC UWHYFRCJGNMMSJ-UHFFFAOYSA-N 0.000 description 1
- YWNBSWRNQJVBMN-UHFFFAOYSA-N 1-octylsulfanyldecane Chemical compound CCCCCCCCCCSCCCCCCCC YWNBSWRNQJVBMN-UHFFFAOYSA-N 0.000 description 1
- PCPVCHFKVPNTBH-UHFFFAOYSA-N 1-propylsulfanylheptane Chemical compound CCCCCCCSCCC PCPVCHFKVPNTBH-UHFFFAOYSA-N 0.000 description 1
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical group [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- CZLSFNXDVGOZTR-UHFFFAOYSA-L C(C)SP(=S)([O-])[O-].[K+].[K+] Chemical compound C(C)SP(=S)([O-])[O-].[K+].[K+] CZLSFNXDVGOZTR-UHFFFAOYSA-L 0.000 description 1
- PMGYDDYLUXAPJB-UHFFFAOYSA-N C(O)(O)=S.C(C)(C)[K] Chemical group C(O)(O)=S.C(C)(C)[K] PMGYDDYLUXAPJB-UHFFFAOYSA-N 0.000 description 1
- SVXILUFQLPYZBX-UHFFFAOYSA-N C(O)(O)=S.C(C)(C)[Na] Chemical group C(O)(O)=S.C(C)(C)[Na] SVXILUFQLPYZBX-UHFFFAOYSA-N 0.000 description 1
- WESPTEMHIHBUEK-UHFFFAOYSA-N C(O)(O)=S.C(C)[K] Chemical group C(O)(O)=S.C(C)[K] WESPTEMHIHBUEK-UHFFFAOYSA-N 0.000 description 1
- LEVQTIHOKMIVTE-UHFFFAOYSA-N C(O)(O)=S.C(C)[Na] Chemical group C(O)(O)=S.C(C)[Na] LEVQTIHOKMIVTE-UHFFFAOYSA-N 0.000 description 1
- YLGDTUSJVCBLJA-UHFFFAOYSA-N C(S)(O)=S.C(C)(CC)[K] Chemical compound C(S)(O)=S.C(C)(CC)[K] YLGDTUSJVCBLJA-UHFFFAOYSA-N 0.000 description 1
- VLNHULDSDNVJRG-UHFFFAOYSA-N CCC(C)SC(S)=O Chemical class CCC(C)SC(S)=O VLNHULDSDNVJRG-UHFFFAOYSA-N 0.000 description 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 229910000570 Cupronickel Inorganic materials 0.000 description 1
- OTQVGYMGQKHLMY-UHFFFAOYSA-N Cyclopentyl-1-thiaethane Chemical group CSC1CCCC1 OTQVGYMGQKHLMY-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- MBMLMWLHJBBADN-UHFFFAOYSA-N Ferrous sulfide Chemical compound [Fe]=S MBMLMWLHJBBADN-UHFFFAOYSA-N 0.000 description 1
- BDAGIHXWWSANSR-UHFFFAOYSA-M Formate Chemical compound [O-]C=O BDAGIHXWWSANSR-UHFFFAOYSA-M 0.000 description 1
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical compound [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 1
- QQBIOCGHCKNYGP-UHFFFAOYSA-N Methylsulfanylcyclohexane Chemical group CSC1CCCCC1 QQBIOCGHCKNYGP-UHFFFAOYSA-N 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241000907663 Siproeta stelenes Species 0.000 description 1
- 238000003723 Smelting Methods 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- BYSSWLUTMQPCRR-UHFFFAOYSA-N [Na].CC(C)CCOP(S)(=S)OCCC(C)C Chemical compound [Na].CC(C)CCOP(S)(=S)OCCC(C)C BYSSWLUTMQPCRR-UHFFFAOYSA-N 0.000 description 1
- BMMMYFMIMMLCOD-UHFFFAOYSA-N [Na].CC(C)COP(S)(=S)OCC(C)C Chemical compound [Na].CC(C)COP(S)(=S)OCC(C)C BMMMYFMIMMLCOD-UHFFFAOYSA-N 0.000 description 1
- MODKXDSAIYDMCL-UHFFFAOYSA-N [Na].CCC(C)OP(O)(S)=S Chemical compound [Na].CCC(C)OP(O)(S)=S MODKXDSAIYDMCL-UHFFFAOYSA-N 0.000 description 1
- WUFOSEUICNZATQ-UHFFFAOYSA-N [Na].P(O)(O)(=S)S Chemical compound [Na].P(O)(O)(=S)S WUFOSEUICNZATQ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 230000000996 additive effect Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000008055 alkyl aryl sulfonates Chemical class 0.000 description 1
- 125000005667 alkyl propylene group Chemical group 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000005428 anthryl group Chemical group [H]C1=C([H])C([H])=C2C([H])=C3C(*)=C([H])C([H])=C([H])C3=C([H])C2=C1[H] 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 125000001204 arachidyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical group [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000005347 biaryls Chemical group 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052972 bournonite Inorganic materials 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CCNSPAURLTTWPO-UHFFFAOYSA-N butan-2-ylsulfanyl-dihydroxy-sulfanylidene-$l^{5}-phosphane Chemical class CCC(C)SP(O)(O)=S CCNSPAURLTTWPO-UHFFFAOYSA-N 0.000 description 1
- KQBUVDBNXZACHN-UHFFFAOYSA-N butylsulfanylcyclohexane Chemical group CCCCSC1CCCCC1 KQBUVDBNXZACHN-UHFFFAOYSA-N 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 125000001309 chloro group Chemical group Cl* 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000003750 conditioning effect Effects 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- WUUZKBJEUBFVMV-UHFFFAOYSA-N copper molybdenum Chemical compound [Cu].[Mo] WUUZKBJEUBFVMV-UHFFFAOYSA-N 0.000 description 1
- YOCUPQPZWBBYIX-UHFFFAOYSA-N copper nickel Chemical compound [Ni].[Cu] YOCUPQPZWBBYIX-UHFFFAOYSA-N 0.000 description 1
- BERDEBHAJNAUOM-UHFFFAOYSA-N copper(I) oxide Inorganic materials [Cu]O[Cu] BERDEBHAJNAUOM-UHFFFAOYSA-N 0.000 description 1
- LBJNMUFDOHXDFG-UHFFFAOYSA-N copper;hydrate Chemical compound O.[Cu].[Cu] LBJNMUFDOHXDFG-UHFFFAOYSA-N 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 239000010431 corundum Substances 0.000 description 1
- DQXXYXQMGCYQRE-UHFFFAOYSA-N decylsulfanylcyclohexane Chemical group CCCCCCCCCCSC1CCCCC1 DQXXYXQMGCYQRE-UHFFFAOYSA-N 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
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- 238000000151 deposition Methods 0.000 description 1
- FDDFLAKOJVXMRK-UHFFFAOYSA-N dihydroxy-(2-methylpropylsulfanyl)-sulfanylidene-$l^{5}-phosphane Chemical class CC(C)CSP(O)(O)=S FDDFLAKOJVXMRK-UHFFFAOYSA-N 0.000 description 1
- MQHRCVXVEKBXFA-UHFFFAOYSA-N dihydroxy-propan-2-ylsulfanyl-sulfanylidene-$l^{5}-phosphane Chemical class CC(C)SP(O)(O)=S MQHRCVXVEKBXFA-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- ZXOKVTWPEIAYAB-UHFFFAOYSA-N dioxido(oxo)tungsten Chemical compound [O-][W]([O-])=O ZXOKVTWPEIAYAB-UHFFFAOYSA-N 0.000 description 1
- KMWRZRJJXSNUKW-UHFFFAOYSA-L dipotassium;methanethioate Chemical compound [K+].[K+].[O-]C([S-])=S KMWRZRJJXSNUKW-UHFFFAOYSA-L 0.000 description 1
- ALVPFGSHPUPROW-UHFFFAOYSA-N dipropyl disulfide Chemical compound CCCSSCCC ALVPFGSHPUPROW-UHFFFAOYSA-N 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
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- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical compound CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 1
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- FVVLFIWMBGVBSA-UHFFFAOYSA-N ethylsulfanylmethanethioic s-acid Chemical class CCSC(S)=O FVVLFIWMBGVBSA-UHFFFAOYSA-N 0.000 description 1
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- 150000004675 formic acid derivatives Chemical class 0.000 description 1
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- 238000007499 fusion processing Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
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- 239000010931 gold Substances 0.000 description 1
- RMUGCJVAFZVYJS-UHFFFAOYSA-N heptylsulfanylcyclohexane Chemical group CCCCCCCSC1CCCCC1 RMUGCJVAFZVYJS-UHFFFAOYSA-N 0.000 description 1
- NNUJFRHPHPUNEC-UHFFFAOYSA-N hexylsulfanylcyclohexane Chemical compound CCCCCCSC1CCCCC1 NNUJFRHPHPUNEC-UHFFFAOYSA-N 0.000 description 1
- OUUQCZGPVNCOIJ-UHFFFAOYSA-N hydroperoxyl Chemical compound O[O] OUUQCZGPVNCOIJ-UHFFFAOYSA-N 0.000 description 1
- 239000003112 inhibitor Substances 0.000 description 1
- LIKBJVNGSGBSGK-UHFFFAOYSA-N iron(3+);oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Fe+3].[Fe+3] LIKBJVNGSGBSGK-UHFFFAOYSA-N 0.000 description 1
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 1
- 229910052745 lead Inorganic materials 0.000 description 1
- NUJOXMJBOLGQSY-UHFFFAOYSA-N manganese dioxide Inorganic materials O=[Mn]=O NUJOXMJBOLGQSY-UHFFFAOYSA-N 0.000 description 1
- ZAUUZASCMSWKGX-UHFFFAOYSA-N manganese nickel Chemical compound [Mn].[Ni] ZAUUZASCMSWKGX-UHFFFAOYSA-N 0.000 description 1
- 125000002960 margaryl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 125000001421 myristyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000001624 naphthyl group Chemical group 0.000 description 1
- 125000001196 nonadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- HGPWSQKPCIYOSL-UHFFFAOYSA-N nonylsulfanylcyclohexane Chemical group CCCCCCCCCSC1CCCCC1 HGPWSQKPCIYOSL-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 238000005456 ore beneficiation Methods 0.000 description 1
- JWUGLYQUFLOYCR-UHFFFAOYSA-N oxaheptathiocane Chemical compound O1SSSSSSS1 JWUGLYQUFLOYCR-UHFFFAOYSA-N 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052763 palladium Inorganic materials 0.000 description 1
- 125000000913 palmityl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000002958 pentadecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 125000005561 phenanthryl group Chemical group 0.000 description 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 1
- 239000011297 pine tar Substances 0.000 description 1
- 239000001794 pinus palustris tar oil Substances 0.000 description 1
- 229940072033 potash Drugs 0.000 description 1
- BWHMMNNQKKPAPP-UHFFFAOYSA-L potassium carbonate Substances [K+].[K+].[O-]C([O-])=O BWHMMNNQKKPAPP-UHFFFAOYSA-L 0.000 description 1
- 235000015320 potassium carbonate Nutrition 0.000 description 1
- JCBJVAJGLKENNC-UHFFFAOYSA-M potassium ethyl xanthate Chemical compound [K+].CCOC([S-])=S JCBJVAJGLKENNC-UHFFFAOYSA-M 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- MBASXNZSHBOEQE-UHFFFAOYSA-N propan-2-ylsulfanylmethanethioic s-acid Chemical class CC(C)SC(O)=S MBASXNZSHBOEQE-UHFFFAOYSA-N 0.000 description 1
- 238000010298 pulverizing process Methods 0.000 description 1
- 229910052683 pyrite Inorganic materials 0.000 description 1
- NIFIFKQPDTWWGU-UHFFFAOYSA-N pyrite Chemical compound [Fe+2].[S-][S-] NIFIFKQPDTWWGU-UHFFFAOYSA-N 0.000 description 1
- 239000011028 pyrite Substances 0.000 description 1
- DCKVNWZUADLDEH-UHFFFAOYSA-N sec-butyl acetate Chemical group CCC(C)OC(C)=O DCKVNWZUADLDEH-UHFFFAOYSA-N 0.000 description 1
- 125000000467 secondary amino group Chemical class [H]N([*:1])[*:2] 0.000 description 1
- 230000011218 segmentation Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 239000002893 slag Substances 0.000 description 1
- MNWBNISUBARLIT-UHFFFAOYSA-N sodium cyanide Chemical compound [Na+].N#[C-] MNWBNISUBARLIT-UHFFFAOYSA-N 0.000 description 1
- HYHCSLBZRBJJCH-UHFFFAOYSA-M sodium hydrosulfide Chemical compound [Na+].[SH-] HYHCSLBZRBJJCH-UHFFFAOYSA-M 0.000 description 1
- 238000007619 statistical method Methods 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229910052959 stibnite Inorganic materials 0.000 description 1
- IHBMMJGTJFPEQY-UHFFFAOYSA-N sulfanylidene(sulfanylidenestibanylsulfanyl)stibane Chemical compound S=[Sb]S[Sb]=S IHBMMJGTJFPEQY-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 229910052718 tin Inorganic materials 0.000 description 1
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 1
- 125000002889 tridecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 238000005303 weighing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/012—Organic compounds containing sulfur
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D1/00—Flotation
- B03D1/001—Flotation agents
- B03D1/004—Organic compounds
- B03D1/014—Organic compounds containing phosphorus
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2201/00—Specified effects produced by the flotation agents
- B03D2201/02—Collectors
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B03—SEPARATION OF SOLID MATERIALS USING LIQUIDS OR USING PNEUMATIC TABLES OR JIGS; MAGNETIC OR ELECTROSTATIC SEPARATION OF SOLID MATERIALS FROM SOLID MATERIALS OR FLUIDS; SEPARATION BY HIGH-VOLTAGE ELECTRIC FIELDS
- B03D—FLOTATION; DIFFERENTIAL SEDIMENTATION
- B03D2203/00—Specified materials treated by the flotation agents; Specified applications
- B03D2203/02—Ores
- B03D2203/025—Precious metal ores
Landscapes
- Manufacture And Refinement Of Metals (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US75432885A | 1985-07-12 | 1985-07-12 | |
| US754,328 | 1985-07-12 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN86101646A CN86101646A (zh) | 1987-01-07 |
| CN1011945B true CN1011945B (zh) | 1991-03-13 |
Family
ID=25034323
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN86101646A Expired CN1011945B (zh) | 1985-07-12 | 1986-02-17 | 采用新型捕收剂组合物的泡沫浮选法 |
Country Status (16)
| Country | Link |
|---|---|
| CN (1) | CN1011945B (fi) |
| AU (1) | AU576422B2 (fi) |
| BR (1) | BR8606770A (fi) |
| CA (1) | CA1267979A (fi) |
| ES (1) | ES8706046A1 (fi) |
| FI (1) | FI81975C (fi) |
| MX (1) | MX165319B (fi) |
| PH (1) | PH22952A (fi) |
| PL (1) | PL148165B1 (fi) |
| RU (1) | RU1831373C (fi) |
| SE (1) | SE461256B (fi) |
| WO (1) | WO1987000451A1 (fi) |
| YU (1) | YU45767B (fi) |
| ZA (1) | ZA861172B (fi) |
| ZM (1) | ZM1386A1 (fi) |
| ZW (1) | ZW3986A1 (fi) |
Families Citing this family (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| PH23458A (en) * | 1985-11-29 | 1989-08-07 | Dow Chemical Co | Collector compositions for the froth flotation of mineral values |
| US4904374A (en) * | 1987-10-08 | 1990-02-27 | Sentrachem Limited | Froth flotation |
| CN105344491B (zh) * | 2015-09-30 | 2017-09-15 | 广西大学 | 一种锑金矿物捕收剂的制备方法 |
| CN107442267B (zh) * | 2017-07-28 | 2019-03-15 | 西部矿业股份有限公司 | 一种微细粒难选铁闪锌矿的浮选方法 |
| WO2019075169A2 (en) * | 2017-10-12 | 2019-04-18 | Cytec Industries Inc. | METHODS OF RECOVERING BY FLOTATION OF VALUE MATERIAL FROM PARTICLES OF RUGGED SIZE |
| CN108435432B (zh) * | 2018-04-03 | 2019-11-05 | 中南大学 | 一种用于高砷含碳黄铁矿型金矿浮选的组合浮选剂及其应用 |
| CN108816521B (zh) * | 2018-05-22 | 2019-10-08 | 中南大学 | 三羟基苯及其衍生物作为铋抑制剂在浮选过程中的应用 |
| CN110280394A (zh) * | 2019-06-09 | 2019-09-27 | 沈阳有研矿物化工有限公司 | 一种异戊基黄原酸丙炔酯及其制备方法 |
| CN110280393A (zh) * | 2019-06-09 | 2019-09-27 | 沈阳有研矿物化工有限公司 | 一种异丙基黄原酸丙炔酯及其制备方法 |
| CN113680535B (zh) * | 2021-08-24 | 2023-03-21 | 中南大学 | 一种烷基醚基二硫代磷酸盐捕收剂及其制备方法与应用 |
| CN114011583B (zh) * | 2021-11-09 | 2022-07-12 | 中国矿业大学(北京) | 一种煤泥浮选剂及其制备方法 |
Family Cites Families (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US1833740A (en) * | 1926-03-19 | 1931-11-24 | Peter C Reilly | Process of ore flotation |
| US1819112A (en) * | 1929-04-22 | 1931-08-18 | Nat Aniline & Chem Co Inc | Froth flotation of minerals |
| US2127375A (en) * | 1935-07-17 | 1938-08-16 | Du Pont | Esters of dithiocarbamic acids |
| US2169313A (en) * | 1938-09-24 | 1939-08-15 | Minerals Separation North Us | Concentration of metalliferous ores by flotation |
| US2691635A (en) * | 1953-05-20 | 1954-10-12 | Dow Chemical Co | Process for the manufacture of dialkyl thionocarbamates |
| AU509346B2 (en) * | 1976-12-02 | 1980-05-08 | The Dow Chemical Company | Forth flotation process |
| CA1105156A (en) * | 1978-10-11 | 1981-07-14 | William A. Rickelton | Flotation of sulfide minerals |
| ES8800077A1 (es) * | 1985-05-31 | 1987-10-16 | Dow Chemical Co | Un procedimiento para recuperar minerales de sulfuro, que contienen metales, o minerales de oxido sulfurados, que contienen metales, a partir de una mena |
-
1986
- 1986-02-07 ZM ZM13/86A patent/ZM1386A1/xx unknown
- 1986-02-14 PH PH33417A patent/PH22952A/en unknown
- 1986-02-14 CA CA000501881A patent/CA1267979A/en not_active Expired - Lifetime
- 1986-02-14 ES ES552028A patent/ES8706046A1/es not_active Expired
- 1986-02-17 YU YU23186A patent/YU45767B/sh unknown
- 1986-02-17 PL PL1986257992A patent/PL148165B1/pl unknown
- 1986-02-17 MX MX001574A patent/MX165319B/es unknown
- 1986-02-17 ZW ZW39/86A patent/ZW3986A1/xx unknown
- 1986-02-17 ZA ZA861172A patent/ZA861172B/xx unknown
- 1986-02-17 CN CN86101646A patent/CN1011945B/zh not_active Expired
- 1986-02-18 AU AU55497/86A patent/AU576422B2/en not_active Expired
- 1986-02-18 WO PCT/US1986/000336 patent/WO1987000451A1/en active IP Right Grant
- 1986-02-18 BR BR8606770A patent/BR8606770A/pt not_active IP Right Cessation
-
1987
- 1987-03-09 FI FI871017A patent/FI81975C/fi not_active IP Right Cessation
- 1987-03-11 SE SE8701018A patent/SE461256B/sv not_active IP Right Cessation
- 1987-03-11 RU SU4202192A patent/RU1831373C/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| RU1831373C (ru) | 1993-07-30 |
| ZA861172B (en) | 1987-10-28 |
| BR8606770A (pt) | 1987-10-13 |
| PL257992A1 (en) | 1987-05-18 |
| FI81975B (fi) | 1990-09-28 |
| YU45767B (sh) | 1992-07-20 |
| CA1267979A (en) | 1990-04-17 |
| AU5549786A (en) | 1987-02-10 |
| FI871017A (fi) | 1987-03-09 |
| YU23186A (en) | 1988-06-30 |
| SE461256B (sv) | 1990-01-29 |
| SE8701018L (sv) | 1987-03-11 |
| SE8701018D0 (sv) | 1987-03-11 |
| ZW3986A1 (en) | 1987-09-09 |
| ES552028A0 (es) | 1987-06-01 |
| ZM1386A1 (en) | 1988-12-30 |
| FI81975C (fi) | 1991-01-10 |
| AU576422B2 (en) | 1988-08-25 |
| WO1987000451A1 (en) | 1987-01-29 |
| ES8706046A1 (es) | 1987-06-01 |
| CN86101646A (zh) | 1987-01-07 |
| PH22952A (en) | 1989-02-03 |
| PL148165B1 (en) | 1989-09-30 |
| FI871017A0 (fi) | 1987-03-09 |
| MX165319B (es) | 1992-11-05 |
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