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CN101170178B - Fuel battery system for apartment building and control method of the system - Google Patents

Fuel battery system for apartment building and control method of the system Download PDF

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CN101170178B
CN101170178B CN2007101673583A CN200710167358A CN101170178B CN 101170178 B CN101170178 B CN 101170178B CN 2007101673583 A CN2007101673583 A CN 2007101673583A CN 200710167358 A CN200710167358 A CN 200710167358A CN 101170178 B CN101170178 B CN 101170178B
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CN101170178A (en
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洪紸瀚
金宅根
赵大熙
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SK Innovation Co Ltd
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04201Reactant storage and supply, e.g. means for feeding, pipes
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04082Arrangements for control of reactant parameters, e.g. pressure or concentration
    • H01M8/04089Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants
    • H01M8/04097Arrangements for control of reactant parameters, e.g. pressure or concentration of gaseous reactants with recycling of the reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/04694Processes for controlling fuel cells or fuel cell systems characterised by variables to be controlled
    • H01M8/04746Pressure; Flow
    • H01M8/04753Pressure; Flow of fuel cell reactants
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/10Fuel cells in stationary systems, e.g. emergency power source in plant
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M2250/00Fuel cells for particular applications; Specific features of fuel cell system
    • H01M2250/40Combination of fuel cells with other energy production systems
    • H01M2250/405Cogeneration of heat or hot water
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Steam Or Hot-Water Central Heating Systems (AREA)
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Abstract

在此公开了一种用于公寓大楼的燃料电池系统。多个燃料电池堆安装在公寓大楼的各个住宅单元内,并使用氢气产生电和热。一个或多个燃料处理器安装在服务区域内,并将产生的氢气通过管线供给至各用于多个住宅单元的各供应模块。公共转换器通过管线接收由燃料处理器过量产生的剩余氢气,并产生公共电和热能。控制器自动检测由外部主电源供至燃料处理器的主配电,并选择性地输出控制信号。辅助供电单元接收来自控制器的控制信号并选择性地供电。

Figure 200710167358

A fuel cell system for an apartment complex is disclosed herein. Multiple fuel cell stacks are installed in individual dwelling units in the apartment complex and use hydrogen to generate electricity and heat. One or more fuel processors are installed in the service area and supply the generated hydrogen through pipelines to respective supply modules each for a plurality of dwelling units. The common converter receives surplus hydrogen produced in excess by the fuel processor via pipeline and generates common electricity and heat. The controller automatically detects the main power distribution supplied by the external main power supply to the fuel processor, and selectively outputs a control signal. The auxiliary power supply unit receives a control signal from the controller and selectively supplies power.

Figure 200710167358

Description

用于公寓大楼的燃料电池系统及该系统的控制方法Fuel cell system for apartment building and control method for the system

技术领域 technical field

本发明一般涉及一种用于公寓大楼的燃料电池系统,其中在服务区域安装一个或多个用于通过重整燃料来产生氢气的燃料处理器,并在各个住宅单元内安装用于使用氢气产生电和热的燃料电池堆,尤其是涉及一种能够提供供电故障安全保护并且即使外部供电断开也能使燃料处理器稳定供电的用于公寓大楼的燃料电池系统,以及该系统的操作方法。The present invention generally relates to a fuel cell system for an apartment complex in which one or more fuel processors for generating hydrogen by reforming fuel are installed in the service area and in each dwelling unit are installed for using hydrogen to generate An electrical and thermal fuel cell stack, and more particularly, to a fuel cell system for an apartment building capable of providing fail-safe protection of power supply and enabling stable power supply to fuel processors even if the external power supply is disconnected, and an operating method of the system.

背景技术 Background technique

通常,燃料电池系统是通过由重整气体燃料获得的氢气或者纯氢气与来自空气中的氧气反应产生电能的装置。燃料电池系统与通过化学反应产生电的电池相似。然而,燃料电池系统从外部接收反应物,例如氢气和氧气,使得燃料电池系统不需要充电,只要向该燃料电池供给燃料就产生电,并且无需燃料燃烧反应产生电,因此具有环境方面的优点。In general, a fuel cell system is a device that generates electricity by reacting hydrogen obtained from reformed gaseous fuel or pure hydrogen with oxygen from air. Fuel cell systems are similar to batteries that generate electricity through chemical reactions. However, the fuel cell system receives reactants such as hydrogen and oxygen from the outside, so that the fuel cell system does not require charging, generates electricity as long as fuel is supplied to the fuel cell, and generates electricity without a fuel combustion reaction, thus having an environmental advantage.

燃料电池系统的基本操作原理是,电解质夹在两个电极之间,当氢离子和氧离子通过两个电极时产生电,并且热和水作为副产品产生。此处,当通过燃料电池的阳极供给氢气且通过燃料电池的阴极供给氧气时,通过阳极进入的氢气分子通过催化剂分离成质子和电子,并且分离的质子和电子通过不同的路径达到阴极。也就是说,质子流过燃料电池中间的电解质,且电子流过外部回路,由此产生电流流动,并且电子和质子在阴极与氧气结合,由此产生水。The basic operating principle of a fuel cell system is that an electrolyte is sandwiched between two electrodes, electricity is generated when hydrogen and oxygen ions pass through the two electrodes, and heat and water are produced as by-products. Here, when hydrogen is supplied through the anode of the fuel cell and oxygen is supplied through the cathode of the fuel cell, hydrogen molecules entering through the anode are separated into protons and electrons by a catalyst, and the separated protons and electrons reach the cathode through different paths. That is, protons flow through the electrolyte in the middle of the fuel cell, and electrons flow through the outer circuit, thereby generating current flow, and the electrons and protons combine with oxygen at the cathode, thereby producing water.

换句话说,燃料电池是直接将氢气和氧气的化学反应能量转换成电能的生产系统,氢气和氧气含在烃基材料,例如甲醇、乙醇或天然气中。这种燃料电池依据所使用电解质的类型分成磷酸燃料电池(Phosphoric Acid FuelCell)(PAFC)、熔融碳酸酯燃料电池(Molten Carbonate Fuel Cell)(MCFC)、固体氧气化物燃料电池(Solid Oxide Fuel Cell)(SOFC)以及质子交换膜燃料电池(Proton Exchange Membrane Fuel Cell)(PEMFC)。尽管基本上基于相同的原理来操作各种燃料电池,但是它们在燃料的种类、操作温度、催化剂和使用的电解质上不同。In other words, a fuel cell is a production system that directly converts the chemical reaction energy of hydrogen and oxygen contained in hydrocarbon-based materials such as methanol, ethanol or natural gas into electrical energy. This fuel cell is divided into Phosphoric Acid Fuel Cell (PAFC), Molten Carbonate Fuel Cell (MCFC) and Solid Oxide Fuel Cell (Solid Oxide Fuel Cell) according to the type of electrolyte used. SOFC) and Proton Exchange Membrane Fuel Cell (PEMFC). Although various fuel cells operate basically on the same principle, they differ in the kind of fuel, operating temperature, catalyst, and electrolyte used.

传统燃料电池系统的结构包括,通过重整燃料将诸如天然气的燃料转换成氢气燃料的燃料处理器,从燃料处理器接收氢气引起氢气与氧气间的化学反应并产生电和热的燃料电池堆,用于将由于燃料电池堆中的化学反应产生的直流电转换为家用的交流电的逆变器即电源转换装置,以及用于提取排向外部的废热并将该废热再利用作为加热水的热能的热交换器。The structure of a conventional fuel cell system includes a fuel processor that converts fuel such as natural gas into hydrogen fuel by reforming the fuel, a fuel cell stack that receives hydrogen from the fuel processor to cause a chemical reaction between hydrogen and oxygen and generates electricity and heat, Inverter or power conversion device for converting direct current generated due to chemical reactions in the fuel cell stack to alternating current for home use, and heat for extracting waste heat discharged to the outside and reusing it as thermal energy for heating water switch.

燃料处理器通过燃料泵接收燃料槽中的燃料,通过重整燃料产生氢气,并将氢气供给燃料电池堆。The fuel processor receives the fuel in the fuel tank through the fuel pump, generates hydrogen by reforming the fuel, and supplies the hydrogen to the fuel cell stack.

燃料电池堆形成燃料电池的主体,并通过由燃料处理器接收的氢气与氧气间引起电化学反应来产生电能。此处,燃料电池堆具有几个至几十个电池一个堆叠到另一个顶部的结构,每个电池包括膜电极组件(MembraneElectrode Assembly)(MEA)和紧密附着到MEA两侧的两极极板。MEA具有阳极电极和阴极电极附着到插置在阳极电极和阴极电极间的电解质膜的结构。The fuel cell stack forms the bulk of the fuel cells and generates electrical energy by causing an electrochemical reaction between hydrogen and oxygen received by the fuel processor. Here, the fuel cell stack has a structure in which several to dozens of cells are stacked one on top of the other, and each cell includes a Membrane Electrode Assembly (MEA) and bipolar plates closely attached to both sides of the MEA. The MEA has a structure in which an anode electrode and a cathode electrode are attached to an electrolyte membrane interposed between the anode electrode and the cathode electrode.

在燃料电池堆中,通过两级极板,将氢气供给阳极电极,将氧气供给阴极电极。在此过程中,在阳极电极发生氢气的氧化反应,同时在阴极电极发生氧气的还原反应。另外,由于在此过程中产生的电子的运动因而产生了电,随之产生了热和水。In a fuel cell stack, hydrogen is supplied to the anode electrode and oxygen to the cathode electrode through two-stage plates. During this process, an oxidation reaction of hydrogen occurs at the anode electrode, while a reduction reaction of oxygen occurs at the cathode electrode. In addition, electricity is generated due to the movement of electrons generated in this process, and heat and water are generated accordingly.

逆变器是将上述燃料电池堆中产生的直流电转换成交流电,以用作民用电。The inverter converts the direct current generated in the above-mentioned fuel cell stack into alternating current for use as domestic electricity.

上述构成的燃料电池系统具有高能量效率、对环境友好、能量供应来源的灵活性以及氢气制备经济的各种优点。因此,最近,集中开发并运行了产生等于或小于5kW的能量而不是大规模发电设备的用于住宅单元的燃料电池系统。The fuel cell system constituted as above has various advantages of high energy efficiency, environmental friendliness, flexibility of energy supply sources, and economical hydrogen production. Therefore, recently, a fuel cell system for a residential unit that generates energy equal to or less than 5 kW instead of a large-scale power generation facility has been intensively developed and operated.

然而,已经开发了传统燃料电池系统的发电容量以适合单独的家庭住宅。因此,由于当总体发电容量增长时,应该开发环境技术并应该解决安全方面的限制,所以存在难以将传统燃料电池系统应用于多家庭住宅即公寓大楼的问题,公寓大楼例如公寓或商住两用公寓。However, the power generation capacity of conventional fuel cell systems has been developed to be suitable for single family homes. Therefore, there is a problem that it is difficult to apply the conventional fuel cell system to a multi-family house, that is, an apartment complex such as an apartment building or a commercial-residential complex, since environmental technology should be developed and safety restrictions should be resolved when the overall power generation capacity increases apartment.

也就是说,作为产生氢气的重整装置的燃料处理器由于安全和技术方面的原因具有容量增长的限制。另外,当整个系统被分配时,主要的问题是必须提供有效运行系统的方案。That is to say, the fuel processor as a hydrogen-generating reformer has limitations in capacity growth for safety and technical reasons. Also, when the entire system is distributed, the main problem is that a solution must be provided to efficiently run the system.

为了解决上述问题,本申请人提出了一种用于公寓大楼的燃料电池系统,其中在公寓大楼的服务区域安装一个或多个燃料处理器,和多个燃料电池堆,用于接收来自相应燃料处理器的氢气和产生电,并且逆变器独立安装在各个住宅单元内。In order to solve the above problems, the present applicant proposed a fuel cell system for an apartment building, in which one or more fuel processors and a plurality of fuel cell stacks are installed in the service area of the apartment building for receiving fuel from the corresponding Processors for hydrogen and electricity generation, and inverters are independently installed in each residential unit.

即,本申请人已经申请专利的用于公寓大楼的燃料电池系统具有这样的结构,即其中通过从外部电力公司获得运行燃料处理器所需的最小电来运行所述燃料处理器,并且燃料电池堆接收来自相应燃料处理器的重整氢气并产生电和热。That is, the fuel cell system for an apartment building to which the present applicant has applied for a patent has a structure in which the fuel processor is operated by obtaining the minimum electricity required to operate the fuel processor from an external power company, and the fuel cell The stacks receive reformed hydrogen from corresponding fuel processors and generate electricity and heat.

在这种结构中,当其中燃料电池系统构造成在系统内部产生和接收电而不是从外部电力公司例如韩国电力公司(KEPCO)接收用于运行燃料处理器的电的封闭回路系统时,由于各种附带设施的增加和维持而需要巨大的耗资,并且由于低能量效率而降低了功效。因此,从外部电力公司供给运行燃料处理器最小运行电力。In this configuration, when the fuel cell system is configured as a closed loop system in which electricity is generated and received inside the system instead of receiving electricity for operating the fuel processor from an external power company such as Korea Electric Power Company (KEPCO), since each The addition and maintenance of such ancillary facilities requires huge costs, and reduces efficacy due to low energy efficiency. Therefore, the minimum operating power to operate the fuel processor is supplied from an external power company.

然而,本申请人已经申请专利的用于公寓大楼的燃料电池系统配置成这样的结构,即运行安装在服务区域的燃料处理器所需的电来自外部电力公司,使得当发生供电故障时,由于燃料处理器停止运行,存在各燃料电池堆不能产生电和热的问题。However, the fuel cell system for an apartment building that the present applicant has applied for a patent is configured in such a structure that the electricity required to run the fuel processor installed in the service area comes from an external power company so that when a power failure occurs, due to The fuel processor stops operating, and there is a problem that each fuel cell stack cannot generate electricity and heat.

发明内容 Contents of the invention

因此,本发明为了克服现有技术出现的上述问题,本发明的目的是提供一种用于公寓大楼的燃料电池系统,该燃料电池系统即使在外部电源由于各种原因停止供应时,仍能使燃料处理器稳定运行,从而维持安装在各个住宅单元的燃料电池堆的稳定供电。Therefore, in order to overcome the above-mentioned problems in the prior art, an object of the present invention is to provide a fuel cell system for an apartment complex that can enable The fuel processor operates stably, thereby maintaining stable power supply to the fuel cell stack installed in each dwelling unit.

为了实现上述目的,本发明提供了一种用于公寓大楼的燃料电池系统,该系统包括多个燃料电池堆,该多个燃料电池堆安装在公寓大楼的各个住宅单元,并配置成使用氢气产生电和热;一个或多个燃料处理器,安装在服务区域,并配置成通过管线向各用于多个住宅单元的各个供应模块供应产生的氢气;公共转换器,该公共转换器配置成通过管线接收由燃料处理器过量产生的剩余氢气并产生公共电和公共热能;控制器,该控制器配置成自动检测来自外部供给燃料处理器的主电源的主配电,并选择性地输出控制信号;以及辅助供电单元,该辅助供电单元配置成接收来自控制器的控制信号和选择性地供电。In order to achieve the above object, the present invention provides a fuel cell system for an apartment building, the system includes a plurality of fuel cell stacks installed in each dwelling unit of the apartment building and configured to generate electricity and heat; one or more fuel processors installed in the service area and configured to supply generated hydrogen through pipelines to respective supply modules each for a plurality of dwelling units; a common converter configured to pass through a pipeline receiving surplus hydrogen produced in excess by the fuel processor and generating utility electricity and utility heat; a controller configured to automatically detect main power distribution from a main power source externally supplied to the fuel processor and selectively output a control signal and an auxiliary power supply unit configured to receive a control signal from the controller and selectively supply power.

在一种实施方式中,所述燃料处理器与用于将氢气供给燃料电池堆的主供应管线连接,并与包括阀门的辅助供应管线连接,以选择性地将剩余氢气供给公共转换器,所述燃料电池堆形成用于各住宅单元的相应供应模块。In one embodiment, the fuel processor is connected to a main supply line for supplying hydrogen to the fuel cell stack, and to an auxiliary supply line including a valve to selectively supply surplus hydrogen to a common converter, so The fuel cell stacks form respective supply modules for each dwelling unit.

在该实施方式中,各个燃料处理器电连接,以选择性地接收来自外部电力公司或辅助供电单元的电。In this embodiment, each fuel processor is electrically connected to selectively receive electricity from an external power company or an auxiliary power supply unit.

在该实施方式中,公共转换器使用公共燃料电池堆和氢气锅炉中的一个或者两个配置而成,所述燃料电池堆通过各具有阀门的管线与各燃料处理器连接,选择性地接收氢气并产生电和热,所述氢气锅炉通过各具有阀门的管线与各个燃料处理器连接,选择性接收氢气并产生热。In this embodiment, the common converter is configured by using one or both of the common fuel cell stack and the hydrogen boiler, and the fuel cell stack is connected to each fuel processor through a pipeline with a valve to selectively receive hydrogen And generate electricity and heat. The hydrogen boiler is connected to each fuel processor through pipelines with valves, selectively receives hydrogen and generates heat.

在该实施方式中,所述控制器包括用于自动检测主电源电压状态的电压传感器。In this embodiment, the controller includes a voltage sensor for automatically detecting the voltage state of the main power supply.

在该实施方式中,所述辅助供电单元为与公共转换器连接的电容器,接收并储存产生的电。In this embodiment, the auxiliary power supply unit is a capacitor connected to the common converter to receive and store generated electricity.

在该实施方式中,所述辅助供电单元为使用柴油机或燃气机作为发动机的发电机。In this embodiment, the auxiliary power supply unit is a generator using a diesel engine or a gas engine as an engine.

为了完成上述目的,本发明提供了一种用于公寓大楼的燃料电池系统的运行方法,该方法包括接收来自外部主电源的电并通过使用一个或多个安装在公寓大楼服务区域的燃料处理器重整燃料并产生氢气;将氢气独立供给供应模块并为各个住宅单元产生电和热,供应模块包括为多个住宅单元安装的多个燃料电池堆;将由各个燃料处理器过量产生的剩余氢气供给用于产生公共电和热的公共转换器;以及使用控制器选择性地控制辅助供电装置的运行,所述辅助供电装置与燃料处理器电连接并供电,所述控制器接收自动检测主电源信息的电压。To accomplish the above objects, the present invention provides a method of operating a fuel cell system for an apartment complex, the method comprising receiving electricity from an external mains Reforming fuel and generating hydrogen; independently supplying hydrogen to a supply module that includes multiple fuel cell stacks installed for multiple dwelling units and generating electricity and heat for each dwelling unit; supplying surplus hydrogen produced in excess by individual fuel processors a common converter for generating common electricity and heat; and selectively controlling operation of an auxiliary power supply electrically connected to and supplying power to the fuel processor using a controller that receives auto-detect main power supply information voltage.

在另一种实施方式中,所述辅助供电单元使用电容器和发电机配置而成,所述电容器与各个燃料处理器连接并接收和储存产生的电,所述发电机使用柴油机或燃气机作为发动机。In another embodiment, the auxiliary power supply unit is configured using a capacitor and a generator, the capacitor is connected to each fuel processor and receives and stores generated electricity, and the generator uses a diesel engine or a gas engine as an engine .

在该实施方式中,在控制所述辅助供电单元运行的过程中,当接收到来自电压传感器的主配电中止状态的信息时,所述控制器进行电控制,使得辅助供电单元运行并将电供给燃料处理器。In this embodiment, in the process of controlling the operation of the auxiliary power supply unit, when receiving the information of the suspension state of the main power distribution from the voltage sensor, the controller performs electrical control so that the auxiliary power supply unit operates and powers Supply Fuel Processor.

在该实施方式中,所述公共转换器使用公共燃料电池堆和氢气锅炉中的一个或者两个配置而成,所述公共燃料电池堆产生电和热并通过管线将电供给公共区域,所述氢气锅炉产生热并将热气和热水供给各个住宅单元,并且所述公共转换器由控制器控制。In this embodiment, the common converter is configured by using one or both of a common fuel cell stack and a hydrogen boiler. The common fuel cell stack generates electricity and heat and supplies electricity to the common area through pipelines. The hydrogen boiler generates heat and supplies hot air and hot water to each dwelling unit, and the common converter is controlled by a controller.

附图说明 Description of drawings

通过下述结合附图的具体描述可以更清楚地理解本发明的上述和其它目的、特征和其它优点,其中:The above-mentioned and other objects, features and other advantages of the present invention can be more clearly understood through the following detailed description in conjunction with the accompanying drawings, wherein:

图1和2为显示本发明的用于公寓大楼的燃料电池系统构造的示意图;1 and 2 are schematic diagrams showing the construction of a fuel cell system for an apartment complex of the present invention;

图3为显示本发明的用于公寓大楼的燃料电池系统构造的示意图;3 is a schematic view showing the configuration of the fuel cell system for an apartment building of the present invention;

图4为显示本发明的用于公寓大楼的燃料电池系统控制结构的示意图。FIG. 4 is a schematic diagram showing a control structure of a fuel cell system for an apartment complex of the present invention.

具体实施方式 Detailed ways

下面参照附图,其中在所有不同的附图中用相同的参考标记表示相同或相似的部件。Reference is now made to the drawings, wherein the same reference numerals are used to designate the same or similar parts throughout the different views.

下文中参照附图详细描述本发明的实施方式。Hereinafter, embodiments of the present invention will be described in detail with reference to the accompanying drawings.

下面参照附图,其中在所有不同的附图中用相同的参考标记表示相同或相似的部件。Reference is now made to the drawings, wherein the same reference numerals are used to designate the same or similar parts throughout the different views.

下面结合附图的以下描述,本发明的特征和优点将变得更明显。The features and advantages of the present invention will become more apparent from the following description in conjunction with the accompanying drawings.

本说明书和权利要求书中所用的术语和词语不必解释为具有常规的词典中的意义,而是应当解释为基于发明人为了以最适当的方式描述发明人自己的发明而可能适当定义术语的概念的原则而具有的符合本发明技术精神的意义和概念。The terms and words used in the specification and claims need not be interpreted as having conventional dictionary meanings, but should be interpreted as based on the concept that the inventor may properly define the terms in order to describe the inventor's own invention in the most appropriate manner The meanings and concepts that conform to the technical spirit of the present invention are based on the principles of the present invention.

下面参照附图详细描述本发明的用于公寓大楼的燃料电池系统的实施方式。Embodiments of the fuel cell system for an apartment building of the present invention will be described in detail below with reference to the accompanying drawings.

图1为显示本发明用于公寓大楼的燃料电池系统中燃料处理器的有关安装的构造的示意图;以及图2为显示本发明的燃料电池堆的有关安装的构造的示意图。1 is a schematic view showing the installation-related construction of a fuel processor of the present invention in a fuel cell system for an apartment complex; and FIG. 2 is a schematic view showing the installation-related construction of a fuel cell stack of the present invention.

如图所示,本发明的燃料电池系统1主要应用于公寓大楼,例如公寓和商住两用公寓。即,用于通过重整燃料产生氢气的燃料处理器3安装在服务区域(未示出),例如机器间,用于接收氢气和产生电和热的包括逆变器(未示出)的燃料电池堆(燃料电池系统)5安装在各个住宅单元内。As shown in the figure, the fuel cell system 1 of the present invention is mainly applied to apartment buildings, such as apartments and commercial and residential apartments. That is, a fuel processor 3 for generating hydrogen by reforming fuel is installed in a service area (not shown), such as a machine room, for receiving hydrogen and generating fuel including an inverter (not shown) for electricity and heat. A battery stack (fuel cell system) 5 is installed in each dwelling unit.

参考标记‘3a’表示用于接收来自燃料罐(未示出)的燃料的燃料管线,参考标记‘3b’表示用于将重整氢气供至燃料电池堆5的氢气供应管线。Reference numeral '3a' denotes a fuel line for receiving fuel from a fuel tank (not shown), and reference numeral '3b' denotes a hydrogen supply line for supplying reformed hydrogen to the fuel cell stack 5 .

上述构造与公知的用于公寓大楼的燃料电池系统的构造基本相同。然而,本发明包括一个或多个小容量燃料处理器和燃料电池堆,所述燃料处理器为危险设施;所述燃料电池堆独立安装在各住宅单元内,形成用于多个住宅单元的单供电模块,并接收来自相应燃料处理器的氢气。The above configuration is basically the same as that of a known fuel cell system for apartment buildings. However, the present invention includes one or more small-capacity fuel processors and fuel cell stacks, said fuel processors being hazardous installations; said fuel cell stacks being independently installed in each dwelling unit to form a single power module and receive hydrogen from the corresponding fuel processor.

图3为显示本发明的用于公寓大楼的燃料电池系统构造的示意图,以及图4为显示本发明的用于公寓大楼的燃料电池系统控制结构的示意图。FIG. 3 is a schematic view showing the configuration of the fuel cell system for apartment buildings of the present invention, and FIG. 4 is a schematic view showing the control structure of the fuel cell system for apartment buildings of the present invention.

如图3和4所示,本发明的燃料电池系统1包括一个或多个安装在公寓大楼服务区域并配置成通过重整燃料产生氢气并通过管线对用于多个住宅单元的各个供应模块提供氢气的燃料处理器3,独立安装在公寓大楼各个住宅单元内并配置成接收来自燃料处理器3的氢气并产生电和热的燃料电池堆5,配置成基于燃料电池堆5的工作状态控制燃料处理器3运行的控制器10,配置成将在燃料处理器3中过量产生的剩余氢气转化成电和热能的公共转换器20,以及用于接收来自控制器10的控制信号并选择性供电至燃料处理器3的辅助供电单元40。As shown in Figures 3 and 4, the fuel cell system 1 of the present invention includes one or more modules installed in the service area of an apartment complex and configured to generate hydrogen by reforming fuel and supplying hydrogen to various supply modules for a plurality of residential units through pipelines. The hydrogen fuel processor 3 is independently installed in each residential unit of the apartment building and is configured to receive hydrogen from the fuel processor 3 and generate electricity and heat. The fuel cell stack 5 is configured to control the fuel cell stack 5 based on the working state of the fuel cell stack 5. The controller 10 operated by the processor 3 is configured as a common converter 20 for converting surplus hydrogen generated in excess in the fuel processor 3 into electricity and heat, and for receiving a control signal from the controller 10 and selectively supplying power to Auxiliary power supply unit 40 of fuel processor 3 .

这种燃料处理器3是用于通过重整燃料将广泛使用的燃料如液化天然气(LNG)、液化石油气(LPG)、汽油或甲醇转化成氢气并将氢气供给燃料电池的装置。燃料处理器3执行基于催化剂的过程,即脱硫反应、重整反应、水煤气转换反应(water gas shift reaction)和化学选择反应(chemoselective reaction)。Such a fuel processor 3 is a device for converting widely used fuel such as liquefied natural gas (LNG), liquefied petroleum gas (LPG), gasoline, or methanol into hydrogen by reforming the fuel and supplying the hydrogen to the fuel cell. The fuel processor 3 performs catalyst-based processes, namely desulfurization reactions, reforming reactions, water gas shift reactions, and chemoselective reactions.

即,燃料处理器3包括用于在常温下进行反应的金属-沸石脱硫器、用于进行吸热反应的蒸汽重整器、水煤气转换反应器(一氧化碳转换器)和优选的氧化反应器。由于具有上述构造的燃料处理器可以使用公知的技术实现,因此在此省略其具体描述。That is, the fuel processor 3 includes a metal-zeolite desulfurizer for performing a reaction at normal temperature, a steam reformer for performing an endothermic reaction, a water gas shift reactor (carbon monoxide converter), and preferably an oxidation reactor. Since the fuel processor having the above configuration can be realized using known techniques, a detailed description thereof is omitted here.

同时,将本发明的上述燃料处理器3应用于公寓大楼如公寓或商住两用公寓。优选情况下,将燃料处理器3用于服务区域如公寓大楼的机器间、配电室或锅炉房。燃料处理器3是用于产生氢气的相当危险的设施,并且具有危险性随氢气产量的增加而成比例增加的缺点。也就是说,存在如下缺点:当燃料处理器的容量增加时,需要额外的安全装置如防爆装置,使得经济负担增加,并且由于各种限制,燃料处理器不能安装在居民区。Meanwhile, the above-mentioned fuel processor 3 of the present invention is applied to an apartment complex such as an apartment or a commercial-residential apartment. Preferably, the fuel processor 3 is used for service areas such as machine rooms, switch rooms or boiler rooms of apartment buildings. The fuel processor 3 is a rather dangerous facility for generating hydrogen, and has the disadvantage that the danger increases proportionally with the hydrogen production. That is, there are disadvantages that when the capacity of the fuel processor increases, additional safety devices such as explosion-proof devices are required, so that the economic burden increases, and the fuel processor cannot be installed in residential areas due to various restrictions.

因此,本发明提出安装一个或多个经济且从安全方面易于控制的小容量燃料处理器3。将各个燃料处理器3与主供应管线‘p1’连接以将氢气供给燃料电池堆5,这将在下文描述,并与辅助供应管线‘p2’连接以将剩余的氢气供给公共转换器20。燃料处理器3通过主电源‘mp’接收来自外部电力公司的电。此外,当主电源‘mp’发生供电故障时,燃料处理器3接收来自辅助供电单元40的电,这将在下文描述。Therefore, the present invention proposes to install one or more small-capacity fuel processors 3 that are economical and easy to control from a safety point of view. Each fuel processor 3 is connected to a main supply line 'p1' to supply hydrogen to the fuel cell stack 5, which will be described later, and an auxiliary supply line 'p2' to supply the remaining hydrogen to the common converter 20. The fuel processor 3 receives electricity from an external power company through a main power supply 'mp'. In addition, the fuel processor 3 receives power from the auxiliary power supply unit 40 when a power failure occurs in the main power supply 'mp', which will be described later.

虽然在图中未示出一个或多个燃料处理器,但在优选情况下,所述燃料处理器通过管线选择性地彼此连接。Although one or more fuel processors are not shown in the figures, preferably the fuel processors are selectively connected to each other by lines.

具有上述构造的燃料处理器的容量选择方法具体如下:The capacity selection method of the fuel processor with the above structure is specifically as follows:

(1)用于公寓大楼的氢气供应总容量(1) Total hydrogen supply capacity for apartment complexes

考虑各个住宅单元的耗电量,用于各个住宅单元的氢气供应量基于燃料电池系统1的容量来决定。一般地,将容量为0.5-5kW的燃料电池系统1应用于各个住宅单元。用于各个住宅单元的燃料电池系统1所需的氢气供应量可以基于燃料电池系统1的电转化效率(一般为20-50%)根据下述等式1计算出:The hydrogen supply amount for each dwelling unit is decided based on the capacity of the fuel cell system 1 in consideration of the power consumption of each dwelling unit. Generally, a fuel cell system 1 with a capacity of 0.5-5 kW is applied to each dwelling unit. The hydrogen supply amount required by the fuel cell system 1 for each residential unit can be calculated based on the electrical conversion efficiency of the fuel cell system 1 (generally 20-50%) according to the following Equation 1:

氢气供应量(最大值)=P÷E×860÷2732[Nm3/hr]    (1)Hydrogen supply (maximum value) = P÷E×860÷2732[Nm 3 /hr] (1)

其中燃料电池容量(最大值):P(kW),Among them, fuel cell capacity (maximum value): P (kW),

电容量至热容量的转化率为:860Kcal/kWh。The conversion rate from electric capacity to heat capacity: 860Kcal/kWh.

氢气热值:2732Kcal/Nm3[较低热值],以及Calorific value of hydrogen: 2732Kcal/Nm 3 [lower calorific value], and

电转化效率:E[%]Electric conversion efficiency: E[%]

因此,为构造和计算燃料处理器的容量,可以使用下述等式2计算用于公寓大楼的氢气供应总容量:Therefore, to construct and calculate the capacity of the fuel processor, the total hydrogen supply capacity for the apartment complex can be calculated using Equation 2 below:

Capa,CpH2,CpH2[Nm3/hr]=(氢气供应量,最大值)×(单元住宅总数量)(2)Capa, Cp H2 , Cp H2 [Nm 3 /hr] = (hydrogen gas supply, maximum value) × (total number of residential units) (2)

(2)燃料处理器容量的选择和模块的安装(2) Selection of fuel processor capacity and installation of modules

当公寓大楼为公寓且住宅区域内包括的建筑物的数量为M时,安装燃料处理器的机器间的数量为M,因而一般安装M个燃料处理器。然而,燃料处理器可以基于市售燃料处理器所需容量按照下述多种方式进行安装:When the apartment building is an apartment and the number of buildings included in the residential area is M, the number of machine rooms where fuel processors are installed is M, and thus M fuel processors are generally installed. However, fuel processors can be installed in a number of ways based on the required capacity of commercially available fuel processors as follows:

实施例1Example 1

当燃料处理器安装在各个建筑物内时,When fuel processors are installed in individual buildings,

待安装的燃料处理器的数量=MNumber of fuel processors to be installed = M

用于各个模块的燃料处理器的容量CFP=Int[CpH2/M]+1Capacity of fuel processor for each module C FP =Int[Cp H2 /M]+1

其中Int[X]=将X数值的小数四舍五入后的整数值。Wherein Int[X]=integer value after rounding off decimals of X value.

实施例2Example 2

当每两个建筑物安装一个燃料处理器时:When installing one fuel processor for every two buildings:

待安装的燃料处理器的数量=M/2Number of fuel processors to be installed = M/2

用于各个模块的燃料处理器的容量CFP=Int[2CpH2/M]+1Capacity of fuel processor for each module C FP =Int[2Cp H2 /M]+1

即,当使用容量为1kW的燃料电池系统的住宅单元的总数为600且建筑物的数量为20,则供应的氢气的总容量(CaPa)确定为约420Nm3/hr。虽然各个燃料处理器的容量可以在确定按如上所述安装的模块的数量之后再计算,但待安装的模块的数量可以在确定各个燃料处理器的容量之后计算。That is, when the total number of dwelling units using the fuel cell system with a capacity of 1 kW is 600 and the number of buildings is 20, the total capacity (CaPa) of supplied hydrogen gas is determined to be about 420 Nm 3 /hr. Although the capacity of each fuel processor may be calculated after determining the number of modules installed as described above, the number of modules to be installed may be calculated after determining the capacity of each fuel processor.

构造为如上所述的燃料处理器3接收燃料罐(未示出)中的燃料,重整燃料产生氢气,并将氢气供给用于多个住宅单元的相应的供应模块‘a’,即形成供应模块‘a’的燃料电池堆5。The fuel processor 3 configured as described above receives fuel in a fuel tank (not shown), reforms the fuel to generate hydrogen, and supplies the hydrogen to corresponding supply modules 'a' for a plurality of dwelling units, that is, forms a supply Fuel cell stack 5 of module 'a'.

燃料电池堆5是安装在各个公寓大楼内包括的各个住宅单元内并配置成使用氢气产生电和热的设备。在本发明的实施方式中,燃料电池堆5组成用于多个住宅单元的单供应模块,并接收来自相应燃料处理器3的氢气。The fuel cell stack 5 is a device installed in each dwelling unit included in each apartment complex and configured to generate electricity and heat using hydrogen gas. In an embodiment of the present invention, the fuel cell stack 5 constitutes a single-supply module for a plurality of dwelling units and receives hydrogen from the respective fuel processors 3 .

这种燃料电池堆5是用于当从燃料处理器3产生的氢气与空气中的氧气反应时产生电的设备。燃料电池堆5主要包括用于引起反应的催化剂、用于传递氢离子的电解质膜(electrolyte membrane)以及用于控制电的收集和气体的流动的两极极板。This fuel cell stack 5 is a device for generating electricity when hydrogen gas generated from the fuel processor 3 reacts with oxygen in the air. The fuel cell stack 5 mainly includes a catalyst for causing a reaction, an electrolyte membrane for transferring hydrogen ions, and bipolar plates for controlling collection of electricity and flow of gas.

即,燃料电池堆5是用于通过引起从燃料处理器3接收的氢气和氧气之间的电化学反应产生电能的装置。所述燃料电池堆具有其中几个甚至几十个电池一个堆叠到另一个顶部的结构,各电池包括MEA和紧紧附着在MEA两面的两极极板。MEA具有这样的结构,即其中阳极电极和阴极电极附着在夹在它们中间的电解质膜上。通过上述构造,氢气和氧气通过两极极板分别供给阳极电极和阴极电极。在该过程中,在阳极电极氢气发生氧化反应,而在阴极电极氧气发生还原反应。进一步地,由于电子的移动产生电,同时伴随热和水的产生。由于产生的电为直流电,因此使用设置在一侧的逆变器7将电转化为交流电,然后用作商业电。That is, the fuel cell stack 5 is a device for generating electrical energy by causing an electrochemical reaction between hydrogen gas and oxygen gas received from the fuel processor 3 . The fuel cell stack has a structure in which several or even dozens of cells are stacked one on top of the other, and each cell includes an MEA and bipolar plates tightly attached to both sides of the MEA. The MEA has a structure in which an anode electrode and a cathode electrode are attached to an electrolyte membrane sandwiched between them. With the above configuration, hydrogen gas and oxygen gas are respectively supplied to the anode electrode and the cathode electrode through the bipolar plates. In this process, the oxidation reaction of hydrogen occurs at the anode electrode, while the reduction reaction of oxygen occurs at the cathode electrode. Further, electricity is generated due to the movement of electrons, along with the generation of heat and water. Since the generated electricity is direct current, it is converted into alternating current using the inverter 7 provided on one side, and then used as commercial electricity.

由于具有上述构造的燃料电池堆5与上述燃料处理器3一样可以使用公知的方法实现,因此在此省略其具体描述。Since the fuel cell stack 5 having the above-mentioned configuration can be realized using a known method like the above-mentioned fuel processor 3 , a detailed description thereof is omitted here.

然而,在本发明中,燃料电池堆5安装在公寓大楼例如公寓和商住两用公寓的各个住宅单元内,形成住宅单元的单供应模块,并接收来自相应燃料处理器3的氢气。However, in the present invention, the fuel cell stack 5 is installed in each dwelling unit of an apartment complex such as an apartment and a condominium, forms a single supply module of the dwelling unit, and receives hydrogen from the corresponding fuel processor 3 .

控制器10是一种微处理器,将控制信号输出到上述燃料电池堆5、燃料处理器3、公共转换器20和辅助供电单元40,以便维持系统稳定运行。控制器10可以构造成控制器控制各种形成该系统的电局部装配(electric subassemblies)或者构造成控制器(未示出)独立设置在各个电局部装配中即多个燃料电池堆、燃料处理器、公共转换器20和辅助供电单元40中并进行控制。由于这种控制器10可以使用公知的技术实现,因此在此省略其具体描述。为方便描述,本发明将基于以回路方式与多个电局部装配连接并对其施加控制信号的单控制器进行描述。The controller 10 is a microprocessor that outputs control signals to the aforementioned fuel cell stack 5, fuel processor 3, common converter 20 and auxiliary power supply unit 40 in order to maintain stable operation of the system. The controller 10 may be configured such that the controller controls various electric subassemblies (electric subassemblies) forming the system, or may be configured such that a controller (not shown) is independently provided in each electric subassembly, that is, a plurality of fuel cell stacks, fuel processors, etc. , the common converter 20 and the auxiliary power supply unit 40 and are controlled. Since such a controller 10 can be implemented using known techniques, its detailed description is omitted here. For ease of description, the present invention will be described based on a single controller connected in a loop to and applying control signals to a plurality of electrical subassemblies.

虽然图中未示出,但控制器10包括多个用于自动检测燃料处理器3和燃料电池堆5的运行状态的传感器。具体地,控制器10包括用于自动检测将从外部供给燃料处理器3的主电源‘mp’的电压状态的电压传感器15。Although not shown in the drawings, the controller 10 includes a plurality of sensors for automatically detecting the operating states of the fuel processor 3 and the fuel cell stack 5 . Specifically, the controller 10 includes a voltage sensor 15 for automatically detecting a voltage state of a main power source 'mp' to be externally supplied to the fuel processor 3 .

在此,电压传感器15对主电源‘mp’的电压状态进行实时监控,并将自动检测到的信息施加于与输出终端相连的控制器10。控制器10基于由主电源‘mp’所施加的电压信息判断是否发生供电故障。如果确定发生了供电故障,则控制器10运行辅助供电单元10,这将在下文进行描述,并进行控制器将电供给燃料处理器3。Here, the voltage sensor 15 monitors the voltage state of the main power supply 'mp' in real time, and applies the automatically detected information to the controller 10 connected to the output terminal. The controller 10 judges whether a power failure occurs based on voltage information applied by the main power source 'mp'. If it is determined that a power failure has occurred, the controller 10 operates the auxiliary power supply unit 10 , which will be described later, and supplies electricity to the fuel processor 3 .

虽然图中未示出,优选情况下,控制器10基于安装在各个住宅单元内的燃料电池堆5的运行状态控制相应的燃料处理器3的运行,从而产生所需量的氢气,并且当产生过量产生的剩余氢气时,将剩余氢气供给公共转换器20,从而产生公共电。Although not shown in the drawings, preferably, the controller 10 controls the operation of the corresponding fuel processor 3 based on the operating state of the fuel cell stack 5 installed in each dwelling unit so as to generate a required amount of hydrogen, and when generated When excess hydrogen is generated in excess, the excess hydrogen is supplied to the common converter 20 to generate utility electricity.

公共转换器20是用于接收燃料处理器3过量产生的剩余氢气并使用接收的氢气作为公共电或者将接收的氢气转化为热能并供给各个住宅单元的设备。The common converter 20 is a device for receiving excess hydrogen generated in excess by the fuel processor 3 and using the received hydrogen as public electricity or converting the received hydrogen into thermal energy and supplying each dwelling unit.

即,基于各个燃料电池堆的运行负荷来确定相应于形成用于多个住宅单元的单供应模块‘a’的燃料电池堆5的燃料处理器3的运行率(以下简称‘R’)。在此,当燃料处理器3的最小输出与最大输出的比值根据说明书确定在0-100%范围内,并将该比值称为调节比(Turn-Down-Ratio)(以下简称‘TRD’)时,基于燃料处理器3的‘TRD’和‘R’,由燃料处理器3产生的氢气的量控制为满足总耗氢量或留下剩余氢气。That is, the operating rate (hereinafter referred to as 'R') of the fuel processor 3 corresponding to the fuel cell stack 5 forming the single supply module 'a' for a plurality of dwelling units is determined based on the operating load of each fuel cell stack. Here, when the ratio of the minimum output to the maximum output of the fuel processor 3 is determined in the range of 0-100% according to the specification, and this ratio is called the Turn-Down-Ratio (hereinafter referred to as 'TRD') , based on 'TRD' and 'R' of the fuel processor 3, the amount of hydrogen generated by the fuel processor 3 is controlled to satisfy the total hydrogen consumption or to leave a surplus of hydrogen.

因此,本发明提出将产生的剩余氢气供给另外的公共转换器20,并通过将该氢气转化为公共电、作为过剩电力出售的电或热能进行利用,从而能够提高能量利用效率。Therefore, the present invention proposes to supply the generated surplus hydrogen to another common converter 20 and utilize it by converting the hydrogen into utility electricity, electricity sold as excess electricity, or thermal energy, so that energy utilization efficiency can be improved.

同时,公共转换器20可以是通过包括阀门的管线与各个燃料处理器3连接的公共燃料电池堆21,选择性地接收氢气并产生电。在此,公共燃料电池堆21可以将产生的电供给公共区域,例如街灯和电梯,或者输送到形成部分辅助供电单元40的电容器41,以储存电,这将在下文描述。此外,虽然图中未示出,剩余的电可以输送到电力公司出售。Meanwhile, the common converter 20 may be a common fuel cell stack 21 connected to each fuel processor 3 through a pipeline including valves, selectively receives hydrogen and generates electricity. Here, the common fuel cell stack 21 may supply generated electricity to public areas such as street lamps and elevators, or to a capacitor 41 forming part of an auxiliary power supply unit 40 to store electricity, which will be described later. In addition, although not shown in the figure, surplus electricity may be delivered to a power company for sale.

在此,形成部分公共转换器20的公共燃料电池堆21的容量可以使用下述实施例3的方法进行选择:Here, the capacity of the common fuel cell stack 21 forming part of the common converter 20 can be selected using the method of the following embodiment 3:

实施例3Example 3

假定公寓大楼为公寓,住宅区域内住宅单元的燃料电池堆5的总容量为600kW,‘TRD’为50%,基于最大量的剩余氢气,公共燃料电池堆21的容量可以选择为:Assuming that the apartment building is an apartment, the total capacity of the fuel cell stack 5 of the residential units in the residential area is 600kW, and 'TRD' is 50%, based on the maximum amount of remaining hydrogen, the capacity of the common fuel cell stack 21 can be selected as:

600kW×50%=300kW。600kW×50%=300kW.

此外,除了公共燃料电池堆21的形式外,公共转换器20可以以氢气锅炉23的形式设置。在此,氢气锅炉23是通过包括阀门的管线与各个燃料处理器3连接并使用供给的氢气产生热的设备。可以将氢气锅炉23与管道连接,以将热气和热水供给各个住宅单元或公共区域如控制室和老人厅(hall for the aged)。Furthermore, the common converter 20 may be provided in the form of a hydrogen boiler 23 in addition to the form of the common fuel cell stack 21 . Here, the hydrogen boiler 23 is a device that is connected to each fuel processor 3 through a pipeline including valves and generates heat using supplied hydrogen. A hydrogen boiler 23 can be connected with pipes to supply hot air and hot water to individual dwelling units or public areas such as control rooms and halls for the aged.

在此,形成部分公共转换器20的氢气锅炉23的容量可以使用下述实施例4的方法进行选择。Here, the capacity of the hydrogen boiler 23 forming part of the common converter 20 can be selected using the method of Embodiment 4 described below.

实施例4Example 4

假设公寓大楼为公寓,住宅区域内住宅单元的燃料电池堆5的总容量为600kW且‘TRD’为50%,则基于最大量的剩余氢气,氢气锅炉23的容量可以选择如下:Assuming that the apartment building is an apartment, the total capacity of the fuel cell stack 5 of the residential units in the residential area is 600kW and the 'TRD' is 50%, based on the maximum amount of remaining hydrogen, the capacity of the hydrogen boiler 23 can be selected as follows:

600kW×25%=150kW。600kW x 25% = 150kW.

同时,形成部分公共转换器20的公共燃料电池堆21和氢气锅炉23可以使用公知的技术实现,因而在此省略其具体描述。Meanwhile, the common fuel cell stack 21 and the hydrogen boiler 23 forming part of the common converter 20 can be implemented using known techniques, and thus a detailed description thereof is omitted here.

辅助供电单元20接收来自上述控制器10的控制信号,并选择性地以回路方式将电供给燃料处理器3。此外,用于储存电荷的电容器41或用于使用柴油机或燃气机作为发动机发电的发电机43可以作为辅助供电单元40使用。The auxiliary power supply unit 20 receives a control signal from the above-mentioned controller 10 and selectively supplies electricity to the fuel processor 3 in a loop manner. In addition, a capacitor 41 for storing charges or a generator 43 for generating electricity using a diesel engine or a gas engine as an engine may be used as the auxiliary power supply unit 40 .

在此,电容器41包括能够重复进行充电和放电反应的蓄电池。在此,除了铅蓄电池和碱性蓄电池,使用非水溶液(有机电解液或固体电解液)的二次电池可以用作蓄电池。此外,发电机43是用于将机械能转化为电能的设备,并且使用柴油机或燃气机作为发动机的交流电发电机可以用作发电机43。Here, the capacitor 41 includes a secondary battery capable of repeating charging and discharging reactions. Here, besides the lead storage battery and the alkaline storage battery, a secondary battery using a non-aqueous solution (organic electrolyte or solid electrolyte) can be used as the storage battery. Furthermore, the generator 43 is a device for converting mechanical energy into electrical energy, and an alternator using a diesel engine or a gas engine as an engine may be used as the generator 43 .

如上所述,辅助供电装置40可以构造成具有电容器41或发电机43或兼具有电容器41和发电机43。此外,使用警示灯或警报器的显示单元可以额外安装在辅助供电单元40内,使得管理员或操作员可以注意到电容器41和发电机43的运行状态。由于电容器41和发电机43可以使用公知的技术实现,因此在此省略其具体描述。As described above, the auxiliary power supply device 40 may be configured to have the capacitor 41 or the generator 43 or both the capacitor 41 and the generator 43 . In addition, a display unit using a warning light or a siren may be additionally installed in the auxiliary power supply unit 40 so that a manager or operator can notice the operating states of the capacitor 41 and the generator 43 . Since the capacitor 41 and the generator 43 can be implemented using known technologies, their detailed descriptions are omitted here.

同时,形成辅助供电单元40的电容器41和发电机43的容量可以使用下述实施例5所述的等式进行选择:Meanwhile, the capacities of the capacitor 41 and the generator 43 forming the auxiliary power supply unit 40 can be selected using the equation described in Embodiment 5 below:

实施例5Example 5

假设公寓大楼为公寓,Assuming the apartment complex is an apartment,

各个住宅单元所需的最小电动势=Pi[kW]The minimum electromotive force required for each residential unit = Pi[kW]

住宅区域内住宅单元的数量=N住宅单元Number of residential units in a residential area = N residential units

住宅区域所需最小电动势=P[kW]÷pi×NThe minimum electromotive force required in the residential area = P total [kW] ÷ pi × N

住宅区域所需最小氢气供应量=P[kW]÷E×860÷2732=H2ups[Nm3/hr]其中860Kcal/kWh:将电容量转化为热容量的比率Minimum hydrogen supply required in residential areas = P total [kW] ÷ E × 860 ÷ 2732 = H2 ups [Nm 3 /hr] where 860Kcal/kWh: the ratio of converting electric capacity into heat capacity

2732kcal/Nm3[较低热值]:氢气热值2732kcal/Nm 3 [lower calorific value]: hydrogen calorific value

E[%]:电转化效率E[%]: Electric conversion efficiency

各个模块的燃料处理器的容量,CFP=CFP[Nm3/hr]Capacity of the fuel processor of each module, C FP = C FP [Nm 3 /hr]

在发生供电故障时将运行的燃料处理器模块的数量:Mups=Int[H2ups/CFP]+1Number of fuel processor modules that will be operational in the event of a power failure: M ups = Int[H2 ups /C FP ]+1

其中Int[x]=将X数值的小数四舍五入后的整数值Where Int[x]=Integer value after rounding the decimal value of X value

单燃料处理器所需功率:PFPi[kW/(Nm3/hr)]Power required for single fuel processor: P FP i[kW/(Nm 3 /hr)]

供电故障发生时燃料处理器的总运行功率:PFP=Mups×CFP×PFPiThe total operating power of the fuel processor when a power failure occurs: P FP = M ups × C FP × P FP i

电池或蓄电池的最小容量:CP=PFPαThe minimum capacity of the battery or accumulator: CP=P FP α

其中α=辅助供电单元的发电机初始运行所需的功率[kW]where α = power required for initial operation of the generator of the auxiliary power supply unit [kW]

根据本发明,构造如上所述的用于公寓大楼的燃料电池系统的运行将在下文进行描述。According to the present invention, the operation of the fuel cell system for an apartment building constructed as described above will be described below.

将各自具有预定产气容量的一个或多个燃料处理器3安装在公寓大楼的服务区域如机器间和配电室内,并通过重整燃料产生氢气。将产生的氢气供给安装在各个住宅单元内并通过管线与相应燃料处理器连接的燃料电池堆5,从而为住宅单元产生电和热。One or more fuel processors 3 each having a predetermined gas production capacity are installed in a service area of an apartment building such as a machine room and a switch room, and generate hydrogen by reforming fuel. The generated hydrogen gas is supplied to the fuel cell stack 5 installed in each dwelling unit and connected to a corresponding fuel processor through a pipeline, thereby generating electricity and heat for the dwelling unit.

在此,处理器3构造成通过管线与分别作为多个住宅单元的各自的供应模块‘a’相连,并供给通过重整燃料产生的氢气。将过量产生的剩余氢气供给通过管线连接的公共转换器20,并转化成公共电和热能以供使用,或者用作用于使电容器41充电的电力。所述电容器41形成部分辅助供电单元40。Here, the processor 3 is configured to be connected to respective supply modules 'a' respectively serving as a plurality of dwelling units through pipelines, and to supply hydrogen gas generated by reforming fuel. The surplus hydrogen produced in excess is supplied to the common converter 20 connected through pipelines, and is converted into common electricity and heat for use, or used as electricity for charging the capacitor 41 . Said capacitor 41 forms part of the auxiliary power supply unit 40 .

同时,当燃料处理器3的主电源‘mp’即由外部电力公司提供的电中断或切断时,控制器10使用自动检测主电源‘mp’的电压的电压传感器15实行实时监控,以确定是否发生供电故障。如果确定发生供电故障,则控制器10运行辅助供电装置40,并将电供给燃料处理器3。因此,即使当主电源‘mp’的主供电中断时,燃料处理器3仍然能够稳定产生氢气,使得无论是否有外部电力供给燃料处理器3,即尽管主电源‘mp’发生了供电故障,整个系统的运行都能够继续进行。At the same time, when the main power supply 'mp' of the fuel processor 3, that is, the electricity provided by the external power company, is interrupted or cut off, the controller 10 uses the voltage sensor 15 that automatically detects the voltage of the main power supply 'mp' to implement real-time monitoring to determine whether A power failure has occurred. If it is determined that a power failure has occurred, the controller 10 operates the auxiliary power supply device 40 and supplies electricity to the fuel processor 3 . Therefore, even when the main power supply of the main power supply 'mp' is interrupted, the fuel processor 3 can still generate hydrogen stably, so that regardless of whether there is external power supplied to the fuel processor 3, that is, despite the power supply failure of the main power supply 'mp', the entire system operations can continue.

此外,当主电源‘mp’的断电状态解除后,电压传感器自动检测到断电状态解除,并将自动检测到的信息传递到控制器10,使得控制器10切断由辅助供电单元40供给燃料处理器3的电并进行电控制,使得燃料处理器3接收来自主电源‘mp’的电。In addition, when the power-off state of the main power supply 'mp' is released, the voltage sensor automatically detects that the power-off state is released, and transmits the automatically detected information to the controller 10, so that the controller 10 cuts off the fuel supply from the auxiliary power supply unit 40 for processing. The power of the processor 3 is controlled electrically so that the fuel processor 3 receives power from the main power source 'mp'.

构造成如上所述的公寓大楼的燃料电池系统的优选运行方式将在下面进行描述。A preferred mode of operation of the fuel cell system configured as an apartment complex as described above will be described below.

在本发明的燃料电池系统1中,安装在公寓大楼服务区域的一个或多个燃料处理器3接收来自主电源‘mp’的电并通过重整燃料产生氢气。In the fuel cell system 1 of the present invention, one or more fuel processors 3 installed in a service area of an apartment complex receive electricity from a main power source 'mp' and generate hydrogen by reforming fuel.

由相应的燃料处理器3产生的氢气通过管线供给安装在各自住宅单元内并形成用于多个住宅单元的供应模块‘a’的燃料电池堆5。燃料电池堆5使用供给的氢气产生用于各自住宅单元的电和热。Hydrogen gas generated by the respective fuel processors 3 is supplied through pipelines to fuel cell stacks 5 installed in respective dwelling units and forming a supply module 'a' for a plurality of dwelling units. The fuel cell stack 5 generates electricity and heat for the respective dwelling units using the supplied hydrogen.

此外,将由各自燃料处理器3过量产生的剩余氢气供给公共转换器20以产生公共电和热。即,供给公共转换器20的氢气由公共燃料电池堆21用作公共电和热能,以产生电和热并通过管线供给公共区域,并由氢气锅炉23产生热并将热气和热水通过管线供给住宅单元内。In addition, surplus hydrogen overproduced by the respective fuel processors 3 is supplied to the common converter 20 to generate common electricity and heat. That is, the hydrogen gas supplied to the common converter 20 is used by the common fuel cell stack 21 as public electricity and thermal energy to generate electricity and heat and supply the common area through pipelines, and the hydrogen boiler 23 generates heat and supplies hot gas and hot water through pipelines Inside a residential unit.

同时,电压传感器15对主电源‘mp’的电压状态进行实时监控,并将自动检测信息传输到控制器10。当主电源‘mp’发生供电故障时,控制器10运行辅助供电单元40,并将电供给燃料处理器3,使得所述燃料处理器3即使在供电故障的情况下也能够通过重整燃料连续产生氢气,所述辅助供电单元40配置有电容器41和发电机43。At the same time, the voltage sensor 15 monitors the voltage state of the main power supply 'mp' in real time, and transmits the automatic detection information to the controller 10. When a power failure occurs in the main power supply 'mp', the controller 10 operates the auxiliary power supply unit 40, and supplies power to the fuel processor 3 so that the fuel processor 3 can continuously generate energy by reforming fuel even in the event of a power failure. hydrogen gas, the auxiliary power supply unit 40 is configured with a capacitor 41 and a generator 43 .

上述描述了本发明的优选实施方式,但对于本领域技术人员来说很显然可以在不背离本发明精神和技术范围的情况下作出各种修改。因此,必须认为各种修改均包括在所述权利要求公开的范围内。The preferred embodiments of the present invention have been described above, but it is obvious to those skilled in the art that various modifications can be made without departing from the spirit and technical scope of the present invention. Therefore, various modifications must be considered to be included in the scope disclosed in the claims.

在具有如上构造和进行如上运行的用于公寓大楼的燃料电池系统中,分布和安装有燃料处理器和燃料电池堆,使得可以提高系统的稳定性。特别地,即使当供给燃料处理器的外部供电中断或切断时,仍然可以通过使用由控制器控制的辅助供电单元对燃料处理器连续供电,使得可以在提前预防供电故障情况下燃料处理器停止运行的不便并且可以保证和维持系统操作的稳定性而具有有价值的优点。In the fuel cell system for an apartment complex having the above configuration and performing the above operation, the fuel processors and the fuel cell stack are distributed and installed, so that the stability of the system can be improved. In particular, even when the external power supply to the fuel processor is interrupted or cut off, it is possible to continuously supply power to the fuel processor by using the auxiliary power supply unit controlled by the controller, so that it is possible to prevent the fuel processor from stopping operation in case of power failure in advance The inconvenience and can guarantee and maintain the stability of the system operation and have valuable advantages.

此外,由各个燃料处理器过量产生的剩余氢气可以转化成公共电(用于街灯或电梯的电)和热能(用于热气和热水的能量)并供给形成部分辅助供电装置的电容器,如此提高了能量效率,并且不需要安装相当危险的高容量储氢罐来储存氢气,其结果是,具有大大提高用于公寓大楼的燃料电池系统应用自由度的优点。In addition, surplus hydrogen produced in excess by individual fuel processors can be converted into public electricity (electricity for street lamps or elevators) and thermal energy (energy for hot air and hot water) and supplied to capacitors forming part of the auxiliary power supply, thus increasing Energy efficiency is improved, and there is no need to install a rather dangerous high-capacity hydrogen storage tank to store hydrogen, and as a result, there is an advantage of greatly increasing the degree of freedom of application of the fuel cell system for apartment complexes.

Claims (11)

1. fuel cell system that is used for apartment building, this system comprises:
A plurality of fuel cell packs, these a plurality of fuel cell packs are installed in each housing unit of apartment building and are configured to use hydrogen to produce electricity and hot;
One or more fuel processors, this fuel processor is installed in the coverage and is configured to and by pipeline the hydrogen that produces is supplied to each supply module that respectively is used for a plurality of housing units, and each supply module comprises a plurality of fuel cell packs that are used for a plurality of housing units;
Public translation device, this public translation device are configured to receive by the remaining hydrogen of the excessive generation of described fuel processor and produce common electrical and heat energy by pipeline;
Controller, this controller are configured to detect automatically main distribution and the selectivity output control signal of being supplied with described fuel processor by outside main power source; And
The control signal that auxiliary power unit, this auxiliary power unit are configured to receive from described controller also optionally supplies power to described fuel processor.
2. fuel cell system according to claim 1, wherein, described each fuel processor is connected with the main supply pipeline that is used for hydrogen is supplied to described fuel cell pack, and be connected with the auxiliary supply pipeline that comprises valve that is used for optionally remaining hydrogen being supplied to described public translation device, described fuel cell pack is formed for the corresponding supply module of described each housing unit.
3. fuel cell system according to claim 1, wherein, described each fuel processor is electrically connected to described main power source and described auxiliary power unit, thereby optionally receive from external power company or described auxiliary power unit.
4. fuel cell system according to claim 1, wherein, described public translation device uses one or two configuration in common fuel battery pile and the hydrogen boiler to form, described common fuel battery pile is connected with each described fuel processor by the pipeline that has valve separately, optionally receive hydrogen and produce electricity and hot, described hydrogen boiler is connected with each described fuel processor by the pipeline that has valve separately, optionally receives hydrogen and produces heat.
5. fuel cell system according to claim 1, wherein, described controller comprises the voltage sensor that is used for detecting automatically described main power voltage state.
6. fuel cell system according to claim 1, wherein, described auxiliary power unit is a capacitor, this capacitor is connected and receives and store the electricity and the storage of generation with described public translation device.
7. fuel cell system according to claim 1, wherein, described auxiliary power unit is for using diesel engine or the gas engine generator as engine.
8. operation method that is used for the fuel cell system of apartment building, this method comprises:
Reception is from the electricity of outside main power source, and use is installed in the one or more fuel processor fuel reformings in the described apartment building coverage and produces hydrogen;
Hydrogen independently is supplied to comprises the supply module that is installed in a plurality of fuel cell packs in a plurality of housing units separately, and produce the electricity that is used for housing unit separately and hot;
To be supplied to the public translation device by the remaining hydrogen of the excessive generation of described fuel processor separately, be used to produce common electrical and heat; And
Use controller optionally to control the operation of auxiliary power unit, described auxiliary power unit is electrically connected with described fuel processor and powers, and the voltage that described controller receives described main power source detects information automatically.
9. method according to claim 8, wherein, described auxiliary power unit uses capacitor and generator configuration to form, and described capacitor is connected with each described fuel processor and receives and store the electricity that produces, and described generator uses diesel engine or gas engine as engine.
10. method according to claim 8, wherein, in the process of the described auxiliary power unit operation of control, when receiving from voltage sensor about the information of main distribution abort state, described controller carries out electric control, makes described auxiliary power unit operation and electricity is supplied to described fuel processor.
11. method according to claim 8, wherein, described public translation device uses one or two configurations in common fuel battery pile and the hydrogen boiler to form, and described public translation device is controlled by controller, described common fuel battery pile produces electricity and heat and by pipeline electricity is supplied to the public domain, described hydrogen boiler produce heat and with hot gas and hot water supply to each housing unit.
CN2007101673583A 2006-10-25 2007-10-25 Fuel battery system for apartment building and control method of the system Expired - Fee Related CN101170178B (en)

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