CN101168627A - Single-layer contamination-resisting highly effective water-proof elastic dope - Google Patents
Single-layer contamination-resisting highly effective water-proof elastic dope Download PDFInfo
- Publication number
- CN101168627A CN101168627A CNA200610143888XA CN200610143888A CN101168627A CN 101168627 A CN101168627 A CN 101168627A CN A200610143888X A CNA200610143888X A CN A200610143888XA CN 200610143888 A CN200610143888 A CN 200610143888A CN 101168627 A CN101168627 A CN 101168627A
- Authority
- CN
- China
- Prior art keywords
- percent
- contamination
- water
- highly effective
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002356 single layer Substances 0.000 title claims abstract description 11
- 239000011248 coating agent Substances 0.000 claims abstract description 26
- 238000000576 coating method Methods 0.000 claims abstract description 26
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 24
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims abstract description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 12
- 229920000642 polymer Polymers 0.000 claims abstract description 8
- DAFHKNAQFPVRKR-UHFFFAOYSA-N (3-hydroxy-2,2,4-trimethylpentyl) 2-methylpropanoate Chemical compound CC(C)C(O)C(C)(C)COC(=O)C(C)C DAFHKNAQFPVRKR-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000080 wetting agent Substances 0.000 claims abstract description 6
- 238000011109 contamination Methods 0.000 claims description 22
- 239000006185 dispersion Substances 0.000 claims description 12
- 239000000839 emulsion Substances 0.000 claims description 12
- 238000000034 method Methods 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 11
- 239000012752 auxiliary agent Substances 0.000 claims description 9
- 230000008569 process Effects 0.000 claims description 9
- 239000004408 titanium dioxide Substances 0.000 claims description 9
- 239000013530 defoamer Substances 0.000 claims description 8
- 230000000694 effects Effects 0.000 claims description 8
- 239000000463 material Substances 0.000 claims description 8
- 230000008719 thickening Effects 0.000 claims description 8
- 239000002245 particle Substances 0.000 claims description 6
- 239000002002 slurry Substances 0.000 claims description 6
- 239000010410 layer Substances 0.000 claims description 4
- 238000004519 manufacturing process Methods 0.000 claims description 4
- 230000009467 reduction Effects 0.000 claims description 4
- 239000000428 dust Substances 0.000 claims description 3
- 238000012856 packing Methods 0.000 claims description 3
- 238000010521 absorption reaction Methods 0.000 claims description 2
- 239000002253 acid Substances 0.000 claims description 2
- 238000005660 chlorination reaction Methods 0.000 claims description 2
- 238000004140 cleaning Methods 0.000 claims description 2
- 125000000524 functional group Chemical group 0.000 claims description 2
- 230000014759 maintenance of location Effects 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 239000002105 nanoparticle Substances 0.000 claims description 2
- 229920000620 organic polymer Polymers 0.000 claims description 2
- 229920000333 poly(propyleneimine) Polymers 0.000 claims description 2
- 239000011148 porous material Substances 0.000 claims description 2
- 150000003839 salts Chemical class 0.000 claims description 2
- 230000003068 static effect Effects 0.000 claims description 2
- 238000005303 weighing Methods 0.000 claims description 2
- 208000037656 Respiratory Sounds Diseases 0.000 abstract description 2
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 abstract 2
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 abstract 2
- 239000004615 ingredient Substances 0.000 abstract 2
- 206010011376 Crepitations Diseases 0.000 abstract 1
- 229910000019 calcium carbonate Inorganic materials 0.000 abstract 1
- 230000007812 deficiency Effects 0.000 abstract 1
- 239000002270 dispersing agent Substances 0.000 abstract 1
- 239000004816 latex Substances 0.000 abstract 1
- 229920000126 latex Polymers 0.000 abstract 1
- 239000000843 powder Substances 0.000 abstract 1
- 239000002562 thickening agent Substances 0.000 abstract 1
- 235000010215 titanium dioxide Nutrition 0.000 abstract 1
- 238000004078 waterproofing Methods 0.000 abstract 1
- 239000003973 paint Substances 0.000 description 5
- 239000003513 alkali Substances 0.000 description 2
- 230000008901 benefit Effects 0.000 description 2
- 238000005336 cracking Methods 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000008367 deionised water Substances 0.000 description 2
- 229910021641 deionized water Inorganic materials 0.000 description 2
- 238000009499 grossing Methods 0.000 description 2
- 239000006254 rheological additive Substances 0.000 description 2
- 230000008961 swelling Effects 0.000 description 2
- 238000009736 wetting Methods 0.000 description 2
- 235000019738 Limestone Nutrition 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- 238000003776 cleavage reaction Methods 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005202 decontamination Methods 0.000 description 1
- 230000003588 decontaminative effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000009775 high-speed stirring Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000010071 organism adhesion Effects 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920005575 poly(amic acid) Polymers 0.000 description 1
- 230000004044 response Effects 0.000 description 1
- 230000007017 scission Effects 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention relates to single layer fouling resistant water proof elastic coating, which comprises components with the weight proportion being as follows: 10-20 percent of water, 0.1-0.2 percent of multi-purpose accessory ingredient, 0.1-0.2 percent of wetting agent, 0.4-0.8 percent of dispersant, 0.3-0.8 percent of antibubbling agent, 1.5-3.0 percent of propylene glycol, 16-20 percent of rutile type titanium white powder, 6-8 percent of precipitated barium sulfate, 5-8 percent of large calcium carbonate, 3-5 percent of nontransparent polymer, 38-45 percent of latex, 0.8-1.5 percent of Texanol, 0.5-1 percent of fouling resistant accessory ingredient, 0.1-0.2 percent of anticorrosion agent, and 0.6-0.9 percent of thickening agent. The product overcomes the deficiencies of poor water tolerance, poor water resistance, poor fouling resistance, etc. of the traditional elastic coating, and has the outstanding waterproof performance, fouling resistant performance and good breaking strength, and can obviously improve the performances of waterproofing, fouling resistant and crack resistant. The invention can prevent and cover the crackles on the building and can ensure that the outer wall surface of the building can keep clean and magnificent for a long time.
Description
Technical field
The present invention relates to a kind of coating, particularly a kind of protection and decoration that is used for the skin surface, the elastic coating with high dirt resistance, covering crackle ability belongs to the chemistry painting industry technical field.
Background technology
The current domestic whole elastic coating market of making a general survey of, most product is only limited to and possesses elastomeric feature, and its water tolerance and water-repellancy are relatively poor, and tensile strength is low, and sticking power is general.Because it is not water-fast, non-watertight, will integral body peel off through its paint film after the rain drop erosion, or because the difference of water ratio causes cracking or peels off, and rainwater just infiltrates metope, the corrosion metope.Because the contamination resistance of elastic coating is relatively poor, construction is subjected to being suspended in the dust in the atmosphere afterwards easily, the pollution of oily matter is polluted coating surface simultaneously.For example publication number CN1737069A name is called the elastic coating that relates in the patent application of " decoration of exterior wall with elastic coating and manufacture method " and also has the problems referred to above.These disadvantages that exist have had a strong impact on protection and the decorative effect to basic unit that it had at present.Therefore research has individual layer elastic coating significant of good contamination resistance, high-effective water-proof.
Summary of the invention
The purpose of this invention is to provide a kind of individual layer elastic coating, this elastic coating not only has snappiness, and the contamination resistance, the tensile strength that also have high-effective water-proof, excellence are good, can significantly improve the advantages such as cracking performance of body of wall.
A kind of concrete component and part by weight of single-layer contamination-resisting highly effective water-proof elastic dope are: water: 10-20%; Multifunctional assistant: 0.1-0.2%; Wetting agent: 0.1-0.2%; Dispersion agent: 0.4-0.8%; Defoamer: 0.3-0.8%; Propylene glycol: 1.5-3.0%; Rutile type Titanium Dioxide: 16-20%; Process white: 6-8%; Water-ground limestone: 5-8%; Opacifying polymers: 3-5%; Emulsion: 38-45%; Texanol:0.8-1.5%; The auxiliary agent of anti-contamination the: 0.5-1%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%.
In general, the elasticity of elastic coating and the contamination resistance relation of being inversely proportional to, promptly coating has lower contamination resistance under high-elastic state.The pollution channel of paint film mainly contains organism adhesion, electrostatic adhesion and imbedibility and pollutes.Filming of stain resistance excellence, from the angle that prevents to adhere to, hard, that anti-electrostatic effect good and surface smoothing is considered to get well films, as the angle from decontamination, rain mark and non-the manifesting effect of spot that the clean effect of wetting ability film coated surface rainwater causes with even pollution the in surface are considered to good filming.The present invention can form rigidity, the soap-free emulsion that contains special hydrophilic radical antistatic and surface smoothing is filmed, make paint film not only have snappiness also have antistatic, paint film is level and smooth, hydrophilic advantage, elastic coating possesses snappiness, high-effective water-proof, has excellent water-resistance, the performance of anti-contamination thereby make.
The emulsion that the present invention uses is the soap-free emulsion that contains special hydrophilic radical, have performances such as excellent in resistance contamination again in order to give the basic physical properties of filming, film coated surface is designed to wetting ability, make the emulsion particle surface have effective hydrophilic functional group, thereby the water tolerance of making and wettability while also deposit, and sticking power is good.
The Rutile type Titanium Dioxide that the titanium dioxide that the present invention uses is made as chlorination process is characterized in having high gloss, fabulous color, opacifying power and dispersed and good exterior durability.Its performance has substantial connection with opacifying power, weathering resistance and the chalking resistance of filming.
The dispersion agent that the present invention uses is low-molecular-weight polypropylene amine acid salt dispersion agent, can significantly improve concentration and stability thereof that color stuffing disperses slurry,, can surround a layer charge at the color stuffing particle surface by this dispersion agent, make repulsion mutually between the particle, thereby reach the effect of stable slurry.
The Opacifying polymers that the present invention uses is the hollow polymer spheroid, can show extremely strong covering performance, improve coating contamination resistance (dirt pickup resistant), strengthen outdoor tint retention.
The auxiliary agent of anti-contamination that the present invention uses is the nano modification auxiliary agent of anti-the contamination, and in the coating film process, nanoparticle plays the hinge point effect, and the organic polymer hinge of line style is reticulated structure, improves film coated surface hardness; Pore dimension by reduction is filmed improves the smooth coating degree; By the reduction static charge of filming, reduce the absorption of atmospheric dust; Making films possesses good self-cleaning, has improved the contamination resistance energy of coating.
Thickening material used in the present invention mainly contains newton-type nonionic polyoxyalkylene class rheology modifier and alkali swelling class thickening material.
Production technique of the present invention is mixed above-mentioned components in part by weight at normal temperatures, under stirring at low speed, add portion water, multifunctional assistant, wetting agent, dispersion agent, early stage defoamer, propylene glycol, titanium dioxide, process white, water-ground limestone, after being ground to slurry fineness≤50um after the high speed dispersion, stirring at low speed adds emulsion, Texanol, later stage defoamer, sanitas, thickening material, the auxiliary agent of anti-contamination the, excess water, after meeting the requirements of viscosity, stirring at low speed 10min passes through the packing of checking, filter, weigh again again.
Embodiment
Be one embodiment of the present of invention below.
Composition of elastic coating of the present invention (weight percent) and production technique are: the stirring at low speed stage adds 11 parts deionized water according to order, 0.15 the multifunctional assistant AMP-95 of part, 0.1 the wetting agent X405 of part, 0.55 part poly amic acid dipersant PR03,0.15 the defoamer NXZ of part, 2.5 the propylene glycol of part, 18 parts titanium dioxide 595,7 parts of fineness 800 purpose process whites, 8 parts of fineness 1250 purpose water-ground limestones, enter the high-speed stirring stage after treating all to add, the back high speed of waiting to stir is ground to fineness≤50um, the soap-free emulsion AP5085 that under stirring at low speed, adds 42 parts then successively, 4 parts Opacifying polymers Unihub, 0.8 the Texanol of part, 0.8 the auxiliary agent of anti-contamination NM-1 of part, 0.15 the defoamer NXZ of part, 0.15 the sanitas MV of part, 0.4 newton-type nonionic polyoxyalkylene class rheology modifier thickening material DSX2000 and 0.25 part of alkali swelling thickening material TT935 of part, 4 parts deionized water and stirring is even, stirring at low speed 10min passes through check more again, filter, the packing of weighing.
Its every index of elastic coating of making according to the present invention all reaches the requirement of JG/T172-2005 about the elastic building paint defined, and have excellent water resistance, contamination resistance energy, a good tensile, can significantly improve the waterproof of body of wall, anti-contamination, resistance to cleavage.Prevent and cover cracklin on the buildings, can guarantee the skin surface energy magnificent surface that keeps clean muchly.Customer response is respond well.
Claims (7)
1. the concrete component and the part by weight of a single-layer contamination-resisting highly effective water-proof elastic dope are: water: 10-20%; Multifunctional assistant: 0.1-0.2%; Wetting agent: 0.1-0.2%; Dispersion agent: 0.4-0.8%; Defoamer: 0.3-0.8%; Propylene glycol: 1.5-3.0%; Rutile type Titanium Dioxide: 16-20%; Process white: 6-8%; Water-ground limestone: 5-8%; Opacifying polymers: 3-5%; Emulsion: 38-45%; Texanol:0.8-1.5%; The auxiliary agent of anti-contamination the: 0.5-1%; Sanitas: 0.1-0.2%; Thickening material: 0.6-0.9%;
2. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that this elastic coating production stage is: under stirring at low speed, add portion water, multifunctional assistant, wetting agent, dispersion agent, the early stage defoamer, propylene glycol, titanium dioxide, process white, water-ground limestone, after being ground to slurry fineness≤50um after the high speed dispersion, stirring at low speed adds emulsion, Texanol, the later stage defoamer, sanitas, thickening material, the auxiliary agent of anti-the contamination, excess water, after meeting the requirements of viscosity, stirring at low speed 10min passes through check more again, filter, the packing of weighing;
3. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that said emulsion is the soap-free emulsion that contains special hydrophilic radical, make the emulsion particle surface have effective hydrophilic functional group, thereby the water tolerance of making and wettability are simultaneously and deposit, and sticking power is good;
4. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that said titanium dioxide is the Rutile type Titanium Dioxide that chlorination process is made, be characterized in having high gloss, fabulous color, opacifying power and dispersed and good exterior durability;
5. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that said dispersion agent is a low-molecular-weight polypropylene amine acid salt dispersion agent, can significantly improve concentration and stability thereof that color stuffing disperses slurry, by this dispersion agent, can surround a layer charge at the color stuffing particle surface, make repulsion mutually between the particle, thereby reach the effect of stable slurry;
6. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that said Opacifying polymers is the hollow polymer spheroid, can show extremely strong covering performance, improve coating contamination resistance (dirt pickup resistant), strengthen outdoor tint retention;
7. single-layer contamination-resisting highly effective water-proof elastic dope according to claim 1, it is characterized in that the said auxiliary agent of anti-the contamination is the nano modification auxiliary agent of anti-the contamination, in the coating film process, nanoparticle plays the hinge point effect, the organic polymer hinge of line style is reticulated structure, improve film coated surface hardness; Pore dimension by reduction is filmed improves the smooth coating degree; By the reduction static charge of filming, reduce the absorption of atmospheric dust; Making films possesses good self-cleaning, has improved the contamination resistance energy of coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610143888XA CN101168627A (en) | 2006-10-29 | 2006-10-29 | Single-layer contamination-resisting highly effective water-proof elastic dope |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA200610143888XA CN101168627A (en) | 2006-10-29 | 2006-10-29 | Single-layer contamination-resisting highly effective water-proof elastic dope |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN101168627A true CN101168627A (en) | 2008-04-30 |
Family
ID=39389408
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CNA200610143888XA Pending CN101168627A (en) | 2006-10-29 | 2006-10-29 | Single-layer contamination-resisting highly effective water-proof elastic dope |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN101168627A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402816A (en) * | 2008-11-04 | 2009-04-08 | 杭州传化涂料有限公司 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
| CN101514085B (en) * | 2008-12-30 | 2012-04-11 | 上海东升新材料有限公司 | Barium-titanium organic composite emulsion and application thereof in preparation of external wall heat-insulation finishing mortar |
| CN101845261B (en) * | 2009-03-24 | 2013-01-09 | 上海三银制漆有限公司 | Self-cleaning water-based fluorocarbon paint for external walls |
| CN102888190A (en) * | 2012-09-18 | 2013-01-23 | 张立功 | Pitch angle variable structure of vertical axis wind-driven generating system and control method |
| CN103614025A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市高华电子有限公司 | Environmentally-friendly highly-elastic waterproof coating |
| CN105419536A (en) * | 2015-12-22 | 2016-03-23 | 青岛博泰美联化工技术有限公司 | Elastic hydrophobic construction exterior wall coating |
| CN105462314A (en) * | 2015-12-15 | 2016-04-06 | 三棵树涂料股份有限公司 | High-cost-performance and high-stain-resistance elastic flat-coating emulsion paint and preparation method thereof |
| CN107236401A (en) * | 2017-06-12 | 2017-10-10 | 广州立邦涂料有限公司 | A kind of organo-mineral complexing emulsion and the external wall elastic coating comprising the complex emulsions |
-
2006
- 2006-10-29 CN CNA200610143888XA patent/CN101168627A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101402816A (en) * | 2008-11-04 | 2009-04-08 | 杭州传化涂料有限公司 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
| CN101402816B (en) * | 2008-11-04 | 2011-05-18 | 杭州传化涂料有限公司 | Watersoluble fluorine-carbon modified elastic paint for exterior wall of construction |
| CN101514085B (en) * | 2008-12-30 | 2012-04-11 | 上海东升新材料有限公司 | Barium-titanium organic composite emulsion and application thereof in preparation of external wall heat-insulation finishing mortar |
| CN101845261B (en) * | 2009-03-24 | 2013-01-09 | 上海三银制漆有限公司 | Self-cleaning water-based fluorocarbon paint for external walls |
| CN102888190A (en) * | 2012-09-18 | 2013-01-23 | 张立功 | Pitch angle variable structure of vertical axis wind-driven generating system and control method |
| CN103614025A (en) * | 2013-10-28 | 2014-03-05 | 蚌埠市高华电子有限公司 | Environmentally-friendly highly-elastic waterproof coating |
| CN105462314A (en) * | 2015-12-15 | 2016-04-06 | 三棵树涂料股份有限公司 | High-cost-performance and high-stain-resistance elastic flat-coating emulsion paint and preparation method thereof |
| CN105419536A (en) * | 2015-12-22 | 2016-03-23 | 青岛博泰美联化工技术有限公司 | Elastic hydrophobic construction exterior wall coating |
| CN107236401A (en) * | 2017-06-12 | 2017-10-10 | 广州立邦涂料有限公司 | A kind of organo-mineral complexing emulsion and the external wall elastic coating comprising the complex emulsions |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103589260A (en) | Super-weather-resistant elastic exterior wall coating | |
| CN101168627A (en) | Single-layer contamination-resisting highly effective water-proof elastic dope | |
| CN103740198A (en) | Photocatalytic self-cleaning high-efficient waterproof single-layer elastic coating | |
| CN103666150A (en) | Mildew-resistant anti-algae pure acrylic emulsion exterior-wall paint | |
| CN1245465C (en) | Weatherability self-cleaning external wall coating material and its preparation method | |
| CN101851450B (en) | Waterborne fluorocarbon texture coating and preparation method and application thereof | |
| CN103666155A (en) | Nano modified high-stain-resistance elastic paint | |
| CN113861731B (en) | Building coating finish paint with fireproof self-cleaning function and preparation method thereof | |
| SK8852001A3 (en) | Forming or coating material and utilisation thereof | |
| CN102533028A (en) | Water-based, primer-free and high-performance exterior water coating | |
| KR101779826B1 (en) | Manufacturing method for aqueous ceramic paint for steel bridge painting and steel bridge painting method using the same | |
| CN104530882A (en) | Organosilicate composite exterior wall coating and preparation method thereof | |
| CN106752532A (en) | A kind of antifouling weather-resistant type external wall elastic plucking paint and preparation method thereof | |
| CN103740197A (en) | Modified acrylic acid high-efficient waterproof elastic coating | |
| CN103483941A (en) | Development of super-weatherproof acid-resistant efficient waterproof elastic coating | |
| CN103694833A (en) | Nanometer-modified high-stain-resistance elastic galling coating | |
| CN104479501A (en) | Self-cleaning waterborne epoxy coating for road guardrail and preparation method of self-cleaning waterborne epoxy coating | |
| CN101812263A (en) | Waterborne weather-resistant self-cleaning type silicone acrylic latex paint and production method thereof | |
| CN103666130A (en) | Preparation method of full water-borne fluorocarbon acid-resistant texture coating | |
| CN104817903A (en) | Spray-coating PVDF (polyvinylidene fluoride) fluorocarbon self-cleaning varnish and manufacturing method thereof | |
| CN103740278A (en) | Photocatalysis self-cleaning acrylic acid exterior wall coating | |
| CN105505086B (en) | A kind of dust-proof overlay coating of acid rain resistant and preparation method thereof | |
| CN103666126A (en) | Organic silicon self-cleaning transparent finishing varnish | |
| CN101063020A (en) | Tempering ceramic glaze paint | |
| CN104277637A (en) | Self-cleaning flame-retardant exterior wall coating and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Open date: 20080430 |