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CN101165959B - High power charging battery manufacture process - Google Patents

High power charging battery manufacture process Download PDF

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Publication number
CN101165959B
CN101165959B CN2006100324326A CN200610032432A CN101165959B CN 101165959 B CN101165959 B CN 101165959B CN 2006100324326 A CN2006100324326 A CN 2006100324326A CN 200610032432 A CN200610032432 A CN 200610032432A CN 101165959 B CN101165959 B CN 101165959B
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negative
positive
negative pole
nickel
high power
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CN101165959A (en
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杨书胜
王旭
周建明
钟发平
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Yiyang Keliyuan Battery Co., Ltd.
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HUNAN CORUN NEW ENERGY CO Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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  • Cell Electrode Carriers And Collectors (AREA)
  • Secondary Cells (AREA)
  • Battery Electrode And Active Subsutance (AREA)

Abstract

This invention relates to a process technology of a high power charge battery including a positive, a negative and membranes, in which, the positive and negative are filled with active substances and electrolyte is injected in the steel shell, the collecting structure of the positive is composed of a positive matrix foam Ni, plated Ni or a pure Ni upper collecting plate connected, a bore burr nickel-plated sheet lower collecting plate is spot-welded at the bottom of the shell with a foam Ni or foam Cu pad on it, and the negative is held down to be connected with the pad, the lower collecting plate and the steel shell to form a negative collecting structure.

Description

A kind of high power charging battery manufacture process
Technical field:
The present invention relates to a kind of high power charging battery manufacture process, be specifically related to a kind of high power nickel-hydrogen charging battery manufacture process.
Background technology:
Entered since 21st century, along with the unprecedented attention of the mankind to environmental protection and energy crisis, greatly promoted the demand in environmental protection rechargeable battery market, meanwhile, raising along with social modernization's level, people are also more and more higher to the performance requirement of rechargeable battery, be embodied in the output to rechargeable battery power, the requirement that adapts to electric tool just must reduce the internal resistance of rechargeable battery, realize the heavy-current discharge of rechargeable battery, for realizing this performance, prior art mainly contains following several method: both positive and negative polarity carries out the face weldering with the nickel sheet; Both positive and negative polarity carries out afflux with a plurality of lugs; Anodal employing face weldering, negative pole carries out spot welding etc. with wire netting.But above method all will be used negative pole face weldering or point in the box hat bottom, and the negative pole effect of confluxing is all undesirable, and contact resistance is big, generate heat during work, and just increased making workload and production cost, even destroy the outward appearance of battery, influence the security performance and the power output of battery.
Summary of the invention:
Technical problem to be solved by this invention is: solve the problem that above-mentioned prior art exists, and provide a kind of by to the improvement of the optimization of the selection of active material, positive and negative afflux structure, utmost point group structure, realize that internal resistance is little, specific power is high, satisfy the high power charging battery manufacture process that high-rate battery discharge requires.
The technical solution used in the present invention is: this high power charging battery manufacture process, comprise positive pole, negative pole, barrier film, just, negative pole is filled active material, in the box hat and inject electrolyte, positive pole adopts nickel foam to make basis material in manufacturing process, the anode collection structure is by anodal matrix nickel foam, the afflux dish connects and composes on nickel plating or the pure nickel, negative pole adopts expanded metal to make basis material, end spot welding burr nickel plating with holes sheet next part flow table in the box hat, place nickel foam or foam copper pad on the next part flow table, negative pole presses down and pad, the next part flow table, box hat connects and composes the negative pole currect collecting structure.
In the technique scheme, anodal top is left the nickel foam of certain width and is not filled active material, and negative pole bottom is a toothed edge.
In the technique scheme, when positive pole, barrier film, negative pole coiling, positive and negative electrode staggers, and has the active material face to carry out corresponding separating with barrier film.
In the technique scheme, the positive and negative electrode Capacity Ratio is 1: 1.3~2.1.
In the technique scheme, positive active material comprises anode additive, anodal spherical hickelous nydroxide, and negative electrode active material comprises negative alloy powder.
In the technique scheme, anode additive is Y 2O 3, Er 2O 3And Ca (OH) 2In at least a, negative alloy powder adopts low cobalt power type alloyed powder.
The present invention sums up following 2 points:
1, improves structure
Traditional power type Ni-MH battery generally has two kinds of structures, a kind of is multipole ear, a kind of is the end face weldering, experimental results show that, the internal resistance and the specific power of end face weldering battery are better than multipole ear mode, and end face weldering battery is divided into two kinds, and a kind of is the weldering of negative pole end face, anodal multipole ear, and another kind is that both positive and negative polarity all adopts the end face weldering.No matter be any, the bus structure of its negative pole is all undesirable, even because adopt the negative pole of end face weldering, though its end face welds finely, but on can only being welded at the bottom of the box hat by an elongated capillary point with the contact site of box hat, thereby be difficult to guarantee the good condition of confluxing, because of contact resistance generates heat just unavoidable greatly.Super high power Ni-MH battery of the present invention adopts unique bus structure, and positive/negative plate all directly contacts with anodal (top cover), negative pole (at the bottom of the box hat) with end pattern, thereby the internal resistance that guarantees battery is enough little.
2, rational formula
In order to improve discharge platform, increase specific power, to improve battery high-temperature behavior, we adopt the high-power Ni (OH) of high temperature power alloyed powder (as golden peak flying height temperature power alloyed powder or tall building tungsten high temperature power alloyed powder etc.) and high-quality 2Powder is (as Cologne, Henan or the long excellent power-type Ni (OH) in Jiangmen 2Powder etc.), add an amount of conduction (as inferior cobalt or nickel powder etc.) simultaneously, battery high-temperature behavior and discharge platform are of great benefit to.Through a large amount of tests, we have selected the good barrier film of rational potassium, sodium, lithium ternary electrolyte prescription and gas permeability (as Mitsubishi, NKK, German FS series, Britain SciMaT series etc.) in addition.Facts have proved this type of prescription, the high 40-60mV of 10C discharge meta voltage ratio regular convention formula.
Therefore, structure optimization of the present invention is made simply, satisfies the high-rate battery discharge requirement, and internal resistance is little, and the specific power height has improved battery high-temperature behavior, and battery safety is good, the power output height.
Description of drawings:
Fig. 1 is the anodal structural representation of the present invention
Fig. 2 is a negative pole structure schematic diagram of the present invention
Fig. 3 is positive and negative electrode of the present invention, barrier film, winding needle combination schematic diagram
Fig. 4 is a battery pack assembling structure generalized section of the present invention
Fig. 5 is last afflux dish floor map
Fig. 6 is a next part flow table floor map
Fig. 7 is embodiment 1 a test data table
The accompanying drawing marking explanation;
1---anodal 2---negative pole 3---nickel foam substrate
4---active material face 5---toothed edge 6---barrier films
7---winding needle 8---last afflux dish 9---next part flow tables
10---nickel foam or foam copper pad 11---box hat
Embodiment:
The present invention mainly is by to the optimization of the selection of active material, positive and negative afflux structure, the improvement of utmost point group structure, thereby reaches the requirement of satisfying high-rate battery discharge.
Above-mentioned active material comprises anodal basis material, anode additive, anodal spherical hickelous nydroxide, diaphragm paper, negative alloy powder; Negative alloy powder adopts low cobalt power type alloyed powder, anodal matrix adopting high areal density foaming nickel, and above-mentioned anode additive is Y 2O 3, Er 2O 3And Ca (OH) 2In at least a, barrier film is the barrier film of special processing.
Above-mentioned both positive and negative polarity afflux structure carries out afflux with nickel plating, pure nickel afflux dish or other wire netting, can reach catchment effect and can play the heat diffusion effect again, and this kind technology negative pole does not adopt utmost point group face welder skill, not only simply but also practical.The negative pole currect collecting structure is at the barbed hole of circle afflux dish of box hat bottom weldering, fills up a circular nickel foam or a foam copper again, by pressing the utmost point group negative pole wire netting is connected with the box hat bottom by nickel foam or foam copper on the limit grinningly, thereby reaches face contact effect.The both positive and negative polarity Capacity Ratio is between 1:1.3 to 1:2.1, and powder craft (as patent " electrode of rechargeable battery and electrode manufacturing method and equipment thereof ") on the simple dry method of prior art is adopted in the both positive and negative polarity manufacturing.
The improvement of utmost point group structure of the present invention is: the anodal foaming nickel that adopts is done basis material, and anodal top is left the wide foaming nickel of a 2-6mm limit and do not filled active material and the welding of last afflux dish; Utmost point group bottom negative pole exposes toothed edge, and positive and negative electrode staggers during coiling, and there have the active material face to carry out with barrier film to be corresponding, exposed portions serve negative pole tooth limit, utmost point group bottom, and anodal foaming nickel limit of not filling active material is exposed on utmost point group top.
Above-mentioned nickel plating afflux dish, the nickel plating pad of the present invention generally all is to be basis material with the steel band, as plating is the nickel dam of one deck 1~10 μ m (micron) on the surface again behind the part.φ 17.2 * 0.2 * 28.4 plating afflux dishes that example SC electrokinetic cell is used are after becoming the afflux dish with the punching out of 0.2mm high-quality steel band, plate the nickel dam of one deck 1 μ m on its surface.The nickel plating pad is that shape is different with the afflux dish, and it is same with material and nickel plating.
Embodiment 1, SC4200mAh nickel-hydrogen high-power electrokinetic cell
Manufacture craft of the present invention is: negative alloy powder uses the low cobalt power alloyed powder of Jin Feng boat, and negative current collector adopts the porous metals copper mesh, and utmost point group bottom negative pole exposes barrier film 0.3-1.3mm zigzag negative pole limit; The continuous foamed nickel that anodal matrix adopting Changsha new material company of power unit produces is done basis material, and surface density is at 350-550g/m 2The anode additive yittrium oxide, erbium oxide or calcium hydroxide, addition is 0.5%-4%, hickelous nydroxide contains zinc ball-type hickelous nydroxide with Cologne, Henan, crude fibre film that the barrier film employing is fluoridized or scion grafting is handled or special nylon diaphragm are (as Mitsubishi, NKK, Germany FS2226 series, Britain SciMaT series etc.), anodal top is left a foaming nickel limit and is not filled active material, the both positive and negative polarity Capacity Ratio is 1:1.3-2.1, positive pole carries out afflux with nickel plating or pure nickel afflux dish, the negative pole currect collecting structure is at box hat bottom weldering one barbed hole afflux dish, fill up a circular nickel foam or a foam copper again, by the pressure utmost point group negative pole wire netting is connected with the box hat bottom by nickel foam or foam copper on the limit grinningly, thereby reach face contact effect.Positive and negative electrode adopts simple dry process, the schematic construction of positive and negative electrode is seen accompanying drawing 1,2, positive pole, negative pole, barrier film are reeled then, positive and negative electrode stagger (as Fig. 3) during coiling, there is the face of active material to carry out correspondence with barrier film, negative pole exposed portions serve tooth limit, box hat bottom, top exposed portions serve positive pole is not filled the foaming nickel limit of active material.Load onto box hat, point burn-on afflux dish (go up afflux dish such as Fig. 5), the electrolyte that reinjects, some cap seal mouth then, produce SC4200mAh nickel-hydrogen high-power electrokinetic cell.The SC4200mAh battery of producing with this technology can satisfy 10 multiplying power current discharges, and running current can reach 10-40A, and threshold voltage is more than 1.18V in the 30A discharge, and the internal resistance of battery discharge attitude is less than 4 milliohms.The partial test data are tables of data as shown in Figure 7.
Embodiment 2, D10000mAh Ni-MH power cell
Manufacture craft of the present invention is: negative alloy powder uses tall building tungsten high temperature power alloyed powder, negative pole matrix adopting porous metals copper mesh, and utmost point group bottom negative pole stays 0.5-1.5mm tooth limit; The continuous foamed nickel of anodal matrix adopting is done basis material, and surface density is at 320-550g/m 2Anode additive is 0.5%-4% with yittrium oxide, erbium oxide and calcium hydroxide addition, hickelous nydroxide is with containing the zinc hickelous nydroxide, barrier film is with fluoridizing or the barrier film (as Mitsubishi, NKK, German FS2226 series, Britain SciMaT series etc.) of the good permeability that scion grafting is handled, anodal top is left the wide foaming nickel of 2-5mm limit and is not filled active material, positive and negative Capacity Ratio is 1:1.7, anodal carries out afflux with the nickel plating bipolar ear afflux dish (as Fig. 5) of slotting; Negative pole fills up a circular nickel foam or a foam copper again at box hat bottom weldering one barbed hole nickel plating afflux dish (as Fig. 6), by pressing the utmost point group negative pole wire netting is connected with the box hat bottom by nickel foam or foam copper on the limit grinningly, thereby reaches best negative pole face afflux.Both positive and negative polarity adopts powder craft on the simple dry method of prior art, positive pole, negative pole, barrier film reel (the coiling schematic construction is seen accompanying drawing 3) then, positive and negative electrode staggers during coiling, there is the face of active material to carry out corresponding with barrier film, box hat bottom negative pole exposes the tooth limit, the anodal foaming of top exposed portions serve nickel limit.Load onto box hat (as Fig. 4), burn-on afflux dish, the electrolyte that reinjects, some cap seal mouth more then, produce the D10000mAh Ni-MH power cell.The D10000mAh battery of producing with this technology can satisfy 10 multiplying power current discharges, and running current can reach 30-50A, and threshold voltage is more than 1.22V in the 30A discharge, and the internal resistance of battery discharge attitude is less than 3 milliohms.
Therefore, structure optimization of the present invention is made simply, satisfies the high-rate battery discharge requirement, and internal resistance is little, and the specific power height has improved battery high-temperature behavior, and battery safety is good, the power output height.

Claims (5)

1. the manufacture craft of a high power charging battery, comprise positive pole, negative pole, barrier film, just, negative pole is filled active material, inject electrolyte in the box hat, positive pole adopts foaming nickel to do basis material in manufacturing process, the anode collection structure is by anodal matrix nickel foam, the afflux dish connects and composes on nickel plating or the pure nickel, negative pole adopts expanded metal to make basis material, end spot welding burr nickel plating with holes sheet next part flow table in the box hat, place nickel foam or foam copper pad on the next part flow table, negative pole presses down and pad, the next part flow table, box hat connects and composes the negative pole currect collecting structure, it is characterized in that: anodal top is left the wide foaming nickel of a 2-6mm limit and is not filled active material and the welding of last afflux dish; Negative current collector adopts expanded metal, and utmost point group bottom negative pole exposes barrier film 0.3-1.3mm zigzag negative pole limit; Positive plate, negative plate directly contact with at the bottom of top cover, the box hat with end pattern respectively.
2. according to the manufacture craft of the high power charging battery of claim 1, it is characterized in that positive pole, barrier film, when negative pole is reeled, positive and negative electrode staggers, and has the active material face to carry out corresponding separating with barrier film.
3. according to the manufacture craft of the high power charging battery of claim 1, it is characterized in that the positive and negative electrode Capacity Ratio is 1: 1.3-2.1.
4. according to the manufacture craft of the high power charging battery of claim 1, it is characterized in that positive active material comprises anode additive, anodal spherical hickelous nydroxide, negative electrode active material comprises negative alloy powder;
5. according to the manufacture craft of the high power charging battery of claim 1, it is characterized in that anode additive is Y 2O 3, Er 2O 3, and Ca (OH) 2In at least a.
CN2006100324326A 2006-10-20 2006-10-20 High power charging battery manufacture process Active CN101165959B (en)

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Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101997103A (en) * 2009-08-19 2011-03-30 深圳市倍特力电池有限公司 Welding of battery nickel sheets
CN102263266A (en) 2011-06-22 2011-11-30 广东博特动力能源有限公司 Cathode material for zinc-nickel secondary battery, cathode and preparation method for cathode
CN106785098A (en) * 2016-12-14 2017-05-31 湖南格兰博智能科技有限责任公司 A kind of column sealed ni-mh temperature cell making process wide
CN108400386A (en) * 2018-01-25 2018-08-14 柔电(武汉)科技有限公司 Improve the preparation method of the flexible battery of bending property

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1505197A (en) * 2002-11-28 2004-06-16 三洋电机株式会社 Nickel hydrogen secondary battery
CN2770106Y (en) * 2005-01-11 2006-04-05 深圳市格瑞普电池有限公司 Novel nickek-hydrogen power battery
CN1835271A (en) * 2005-03-14 2006-09-20 河南环宇集团有限公司 Dynamic column sealed Zn-Ni alkaline battery
CN1848486A (en) * 2005-04-11 2006-10-18 黄长庚 Negative electrode alloy material for nickel-hydrogen power battery

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1505197A (en) * 2002-11-28 2004-06-16 三洋电机株式会社 Nickel hydrogen secondary battery
CN2770106Y (en) * 2005-01-11 2006-04-05 深圳市格瑞普电池有限公司 Novel nickek-hydrogen power battery
CN1835271A (en) * 2005-03-14 2006-09-20 河南环宇集团有限公司 Dynamic column sealed Zn-Ni alkaline battery
CN1848486A (en) * 2005-04-11 2006-10-18 黄长庚 Negative electrode alloy material for nickel-hydrogen power battery

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