CN101164926B - A domestic waste landfill treatment technology and bioreactor with in-situ denitrification function - Google Patents
A domestic waste landfill treatment technology and bioreactor with in-situ denitrification function Download PDFInfo
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- 238000011065 in-situ storage Methods 0.000 title claims abstract description 13
- 238000005516 engineering process Methods 0.000 title abstract description 8
- 239000010791 domestic waste Substances 0.000 title description 7
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 claims abstract description 16
- 241000894006 Bacteria Species 0.000 claims abstract description 9
- 238000005273 aeration Methods 0.000 claims abstract description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000006243 chemical reaction Methods 0.000 claims abstract description 5
- 229910021529 ammonia Inorganic materials 0.000 claims abstract description 3
- 230000001651 autotrophic effect Effects 0.000 claims abstract description 3
- 239000007791 liquid phase Substances 0.000 claims abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000002699 waste material Substances 0.000 claims description 9
- 239000012071 phase Substances 0.000 claims description 8
- 238000000034 method Methods 0.000 claims description 4
- 239000004576 sand Substances 0.000 claims description 3
- 241000108664 Nitrobacteria Species 0.000 claims 1
- 230000015572 biosynthetic process Effects 0.000 claims 1
- 230000000694 effects Effects 0.000 claims 1
- 239000005416 organic matter Substances 0.000 abstract description 4
- 230000015556 catabolic process Effects 0.000 abstract description 3
- 238000006731 degradation reaction Methods 0.000 abstract description 3
- 230000001546 nitrifying effect Effects 0.000 abstract description 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract description 2
- 239000007789 gas Substances 0.000 description 12
- XKMRRTOUMJRJIA-UHFFFAOYSA-N ammonia nh3 Chemical compound N.N XKMRRTOUMJRJIA-UHFFFAOYSA-N 0.000 description 8
- 230000000696 methanogenic effect Effects 0.000 description 5
- IOVCWXUNBOPUCH-UHFFFAOYSA-M Nitrite anion Chemical compound [O-]N=O IOVCWXUNBOPUCH-UHFFFAOYSA-M 0.000 description 3
- 239000000149 chemical water pollutant Substances 0.000 description 3
- 230000006641 stabilisation Effects 0.000 description 2
- 238000011105 stabilization Methods 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- JVMRPSJZNHXORP-UHFFFAOYSA-N ON=O.ON=O.ON=O.N Chemical compound ON=O.ON=O.ON=O.N JVMRPSJZNHXORP-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 125000004122 cyclic group Chemical group 0.000 description 1
- 238000005261 decarburization Methods 0.000 description 1
- 230000001934 delay Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000000813 microbial effect Effects 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 230000001105 regulatory effect Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000001360 synchronised effect Effects 0.000 description 1
Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W10/00—Technologies for wastewater treatment
- Y02W10/20—Sludge processing
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Abstract
本发明公开了一种具有原位脱氮功能的生活垃圾填埋处理技术,在硝化反应器内实现上层曝气,形成上层好氧、中间缺氧、下层厌氧的环境,在好氧区,氨在自养型硝化细菌的作用下将其氧化成NO3 -,在缺氧区,由反硝化细菌以有机物作为电子供体,使NO3 -还原为N2而从液相中释放,实现NH4 +-N的转化和去除,在厌氧区,实现有机物的降解产甲烷。本发明还提供了采用上述处理技术的生物反应器。本发明将垃圾填埋主体、填埋气和渗滤液作为一个有机整体考虑,在硝化反应器上层设置曝气层,使得硝化反应器内形成一个上层好氧、中间缺氧、下层厌氧的环境,实现了在生物反应器填埋场内部生物原位脱氮功能,无需单独针对渗滤液进行场外处理,投资运行费用低,处理效率高。
The invention discloses a domestic garbage landfill treatment technology with in-situ denitrification function. In the nitrification reactor, the upper layer is aerated to form an environment with aerobic upper layer, anoxic middle layer and anaerobic lower layer. In the aerobic area, Ammonia is oxidized to NO 3 - under the action of autotrophic nitrifying bacteria. In the anoxic zone, the denitrifying bacteria use organic matters as electron donors to reduce NO 3 - to N 2 and release it from the liquid phase. The conversion and removal of NH 4 + -N, in the anaerobic zone, realizes the degradation of organic matter to produce methane. The present invention also provides a bioreactor using the above treatment technology. The present invention considers the landfill body, landfill gas and leachate as an organic whole, and sets an aeration layer on the upper layer of the nitrification reactor to form an aerobic upper layer, anoxic middle layer, and anaerobic lower layer environment in the nitrification reactor , Realize the biological in-situ denitrification function in the bioreactor landfill, without the need for separate off-site treatment of leachate, low investment and operation costs, and high treatment efficiency.
Description
技术领域technical field
本发明涉及一种生活垃圾填埋处理技术,具体来说是指一种具有原位脱氮功能的生活垃圾填埋处理技术及生物反应器。The invention relates to a domestic garbage landfill treatment technology, in particular to a domestic garbage landfill treatment technology with in-situ denitrification function and a bioreactor.
背景技术Background technique
渗滤液直接回灌型生物反应器填埋场由于厌氧环境和循环积累作用,渗滤液中氨氮浓度远高于传统卫生填埋场,造成填埋场内生态环境恶化,延缓填埋场稳定化进程。然而目前渗滤液中氨氮的脱除普遍采用物化处理法和场外生物处理法,投资建设费用高,而且存在环境风险,因此不适宜推广使用。采用本设计不仅解决生物原位脱氮功能,实现生活垃圾的快速稳定化,而且最大限制避免填埋场的二次污染问题。The concentration of ammonia nitrogen in the leachate is much higher than that of the traditional sanitary landfill due to the anaerobic environment and cyclic accumulation of the bioreactor landfill with direct recirculation of leachate, which leads to the deterioration of the ecological environment in the landfill and delays the stabilization of the landfill process. However, physical and chemical treatment and off-site biological treatment are generally used for the removal of ammonia nitrogen in leachate. The investment and construction costs are high, and there are environmental risks, so it is not suitable for popularization. This design not only solves the biological in-situ denitrification function, realizes the rapid stabilization of domestic waste, but also avoids the secondary pollution of the landfill to the greatest extent.
发明专利申请200410088806.7公开了一种处理垃圾渗滤液的一体化生物反应器,由两个生物反应区和一个调节区组成,每个生物反应区内均填充生物填料,形成好氧区和厌氧区。在好氧区内,有机物被好氧异养菌降解为无机碳,并控制氨氮的硝化过程在亚硝化阶段,将50%的氨氮氧化为亚硝酸盐,好氧区的出水在调节区中与pH调节剂混合均匀后,进入厌氧区。在厌氧区,厌氧氨氧化菌以氨氮为电子供体还原亚硝酸盐,以亚硝酸盐为电子受体来氧化氨氮,将氨氮和亚硝态氮转变为氮气,部分有机物贝其它厌氧微生物吸收或降解。该技术方案是单独针对垃圾渗滤液进行液体处理,将垃圾填埋主体和渗滤液分开考虑,这样投资运行费用高。Invention patent application 200410088806.7 discloses an integrated bioreactor for treating landfill leachate, which consists of two biological reaction areas and a regulating area, each biological reaction area is filled with biological fillers to form an aerobic area and an anaerobic area . In the aerobic zone, the organic matter is degraded into inorganic carbon by aerobic heterotrophic bacteria, and the nitrification process of ammonia nitrogen is controlled. In the nitrification stage, 50% of the ammonia nitrogen is oxidized to nitrite, and the effluent from the aerobic zone is mixed with After the pH regulator is mixed evenly, it enters the anaerobic zone. In the anaerobic zone, anammox bacteria use ammonia nitrogen as the electron donor to reduce nitrite, use nitrite as the electron acceptor to oxidize ammonia nitrogen, and convert ammonia nitrogen and nitrite nitrogen into nitrogen gas, and some organic matter becomes anaerobic microbial uptake or degradation. The technical solution is to separately treat the landfill leachate, and consider the main body of the landfill and the leachate separately, so the investment and operation costs are high.
发明内容Contents of the invention
本发明提供了一种为解决垃圾渗滤液中氨氮浓度过高的突出问题,实现生物脱碳和生物原位脱氮功能有机结合的生活垃圾填埋处理技术。The invention provides a domestic waste landfill treatment technology for solving the outstanding problem of excessively high ammonia nitrogen concentration in landfill leachate and realizing the organic combination of biological decarburization and biological in-situ denitrification.
一种具有原位脱氮功能的生活垃圾填埋处理技术,包括以下步骤:在硝化反应器内实现上层曝气,形成上层好氧、中间缺氧、下层厌氧的环境,在好氧区,氨在自养型硝化细菌的作用下将其氧化成NO3 -,在缺氧区,由反硝化细菌以有机物作为电子供体,使NO3 -还原为N2而从液相中释放,实现NH4 +-N的转化和去除,在厌氧区,实现有机物的降解产甲烷。A domestic waste landfill treatment technology with in-situ denitrification function, comprising the following steps: aerating the upper layer in the nitrification reactor to form an aerobic environment in the upper layer, anoxic in the middle layer, and anaerobic environment in the lower layer; in the aerobic area, Ammonia is oxidized to NO 3 - under the action of autotrophic nitrifying bacteria. In the anoxic zone, the denitrifying bacteria use organic matters as electron donors to reduce NO 3 - to N 2 and release it from the liquid phase. The conversion and removal of NH 4 + -N, in the anaerobic zone, realizes the degradation of organic matter to produce methane.
本发明还提供了一种基于上述处理技术的生物反应器。The present invention also provides a bioreactor based on the above treatment technology.
一种具有原位脱氮功能的生活垃圾填埋生物反应器,是由三级反应器依次为新鲜垃圾填埋场、产甲烷反应器和硝化反应器通过前一级反应器的底部渗滤液出水口和后一级反应器的顶部渗滤液进水口连通组成的循环系统,各级反应器内均设有垃圾室和气室,硝化反应器垃圾室上层设有曝气层,硝化反应器垃圾室内由上至下依次为好氧区、缺氧区和厌氧区。A domestic waste landfill bioreactor with the function of in-situ denitrification is composed of three-stage reactors in order of fresh landfill, methane production reactor and nitrification reactor through the bottom leachate of the previous one-stage reactor. The water outlet and the leachate water inlet on the top of the last stage reactor are connected to form a circulation system. There are garbage chambers and gas chambers in the reactors at all levels. The upper layer of the garbage chamber in the nitrification reactor is equipped with an aeration layer. From top to bottom are the aerobic zone, anoxic zone and anaerobic zone.
所述的产甲烷反应器的底部渗滤液出水口经一三相分离器和硝化反应器的顶部渗滤液进水口连通,三相分离器的气相通路接入集气袋。The leachate water outlet at the bottom of the methanogenic reactor communicates with the leachate water inlet at the top of the nitrification reactor through a three-phase separator, and the gas-phase channel of the three-phase separator is connected to the gas collection bag.
所述的产甲烷反应器内设有若干集气管,集气管接入集气袋。A plurality of gas collecting pipes are arranged in the methanogenic reactor, and the gas collecting pipes are connected to the gas collecting bags.
所述的各级反应器与下一级反应器之间的渗滤液流通管道上均设有集水瓶和进水泵。Water collection bottles and water inlet pumps are provided on the leachate circulation pipelines between the reactors of each stage and the reactors of the next stage.
所述的各级反应器垃圾室底部垫有碎石层,以便于渗滤液流出。The bottoms of the garbage chambers of the reactors at all levels are covered with gravel layers to facilitate the outflow of leachate.
所述的各级反应器垃圾室顶部设有沙层。The tops of the garbage chambers of the reactors at all levels are provided with a sand layer.
本发明将垃圾填埋主体、填埋气和渗滤液作为一个有机整体进行考虑,在硝化反应器上层设置曝气层,使得硝化反应器内形成一个上层好氧、中间缺氧、下层厌氧的环境,实现了在生物反应器填埋场内部生物原位脱氮功能,无需单独针对渗滤液进行场外处理,投资运行费用低,处理效率高。In the present invention, the landfill body, landfill gas and leachate are considered as an organic whole, and an aeration layer is set on the upper layer of the nitrification reactor, so that an aerobic upper layer, anoxic middle layer, and anaerobic lower layer are formed in the nitrification reactor. Environment, realize the biological in-situ denitrification function in the bioreactor landfill, without the need for separate off-site treatment of leachate, low investment and operation costs, and high treatment efficiency.
附图说明Description of drawings
图1为本发明装置的结构示意图。Fig. 1 is a structural schematic diagram of the device of the present invention.
具体实施方式Detailed ways
如图1所示,一种具有原位脱氮功能的生活垃圾填埋生物反应器,是由三级反应器依次为新鲜垃圾填埋场12、产甲烷反应器13和硝化反应器14通过前一级反应器的底部渗滤液出水口经一集水瓶9和一进水泵10和后一级反应器的顶部渗滤液进水口连通组成的循环系统,各级反应器内均设有垃圾室和气室3,气室3上设有导气管6,便于填埋气的收集和利用。As shown in Figure 1, a domestic waste landfill bioreactor with in-situ denitrification function consists of a three-stage reactor in which fresh waste landfill 12, methanogenic reactor 13 and nitrification reactor 14 pass through the front The leachate outlet at the bottom of the first-stage reactor is connected to the top leachate water inlet of the second-stage reactor through a water collecting bottle 9 and a water inlet pump 10 to form a circulation system. Garbage chambers and air chambers are provided in all reactors at all levels. 3. The air chamber 3 is provided with an air guide pipe 6 to facilitate the collection and utilization of landfill gas.
各级反应器垃圾室底部垫有便于渗滤液顺利排出的碎石层1,顶部设有沙层2。The bottom of the garbage chamber of the reactors at all levels is covered with a gravel layer 1 to facilitate the smooth discharge of leachate, and the top is provided with a sand layer 2 .
产甲烷反应器13的底部渗滤液出水口经一三相分离器8、集水瓶9和进水泵10与硝化反应器14的顶部渗滤液进水口连通,三相分离器8的气相通路接入集气袋7,产甲烷反应器13内设有若干集气管4,集气管4接入集气袋7。The leachate water outlet at the bottom of the methanogenic reactor 13 is communicated with the top leachate water inlet of the nitrification reactor 14 through a three-phase separator 8, water collection bottle 9 and water inlet pump 10, and the gas phase channel of the three-phase separator 8 is connected to the collection The gas bag 7 and the methanogenic reactor 13 are provided with several gas collecting pipes 4, and the gas collecting pipes 4 are connected to the gas collecting bag 7.
硝化反应器14垃圾室上层设有曝气层11,硝化反应器14垃圾室内由上至下依次为好氧区、缺氧区和厌氧区。The upper layer of the garbage chamber of the nitrification reactor 14 is provided with an aeration layer 11, and the garbage chamber of the nitrification reactor 14 is successively composed of an aerobic zone, an anoxic zone and an anaerobic zone from top to bottom.
将生活垃圾分别装入新鲜垃圾填埋场12、产甲烷反应器13和硝化反应器14中,运行装置,新鲜垃圾填埋场12的渗滤液流入产甲烷反应器13,经产甲烷反应器13中的三相分离器8后,流入硝化反应器14,硝化反应器14上层通过曝气泵12装置限氧曝气,实现上层好氧,中间缺氧,下部厌氧的环境,使其上层垃圾介质中硝化细菌为优势菌群,下层垃圾介质中反硝化细菌数量占优势,具备同步硝化、反硝化生物原位脱氮功能。经硝化反应器14同步硝化和反硝化生物脱氮后的渗滤液经进水泵循环到新鲜垃圾填埋场12中。如此循环进行,直至生活垃圾稳定化。Household garbage is respectively loaded into the fresh landfill 12, the methanation reactor 13 and the nitrification reactor 14, and the device is operated, and the leachate from the fresh landfill 12 flows into the methanation reactor 13, and passes through the methanation reactor 13 After the three-phase separator 8 in the middle, it flows into the nitrification reactor 14, and the upper layer of the nitrification reactor 14 is aerated by limiting oxygen through the aeration pump 12, so as to realize an aerobic environment in the upper layer, anoxic in the middle, and an anaerobic environment in the lower layer, so that the upper layer of garbage The nitrifying bacteria in the medium are the dominant flora, and the number of denitrifying bacteria in the lower garbage medium is dominant, and it has the function of synchronous nitrification and denitrification biological in-situ denitrification. The leachate after simultaneous nitrification and denitrification biological denitrification by the nitrification reactor 14 is circulated to the fresh garbage landfill 12 through the water inlet pump. This cycle is carried out until the domestic waste is stabilized.
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CN102252333A (en) * | 2011-05-05 | 2011-11-23 | 福建省丰泉环保控股有限公司 | Method and treatment system for reducing nitrogen oxides by using incineration of refuse landfill gas |
CN102252333B (en) * | 2011-05-05 | 2012-12-26 | 福建省丰泉环保控股有限公司 | Method and treatment system for reducing nitrogen oxides by using incineration of refuse landfill gas |
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